共查询到20条相似文献，搜索用时 750 毫秒
1.
LiYan He HuaNing Qiu HeSheng Shi JunZhang Zhu XiuJuan Bai JianBing Yun 《中国科学:地球科学(英文版)》2016,59(1):111-117
Noble and active gases are released from geological samples during gas extraction for noble gas isotope analyses. The active gases should be removed before inletting to mass spectrometers for the analyses. The normal noble gas preparation systems can clean up most geological samples. However, authigenic minerals from sedimentary rocks in oil/gas fields contain organic matter, which cannot be cleaned up by the normal preparation systems and thus influence the noble gas analyses. We introduce a novel gas purification system(PRC patent No. ZL201320117751.2), which includes several reversible purification pumps with different absorbing and degassing temperatures. It can well clean up water steam, carbon dioxide and organic gases. Mica minerals are often used for ~40Ar/~39 Ar dating. A muscovite sample(2082MS) which could not be cleaned up by the normal preparation system with two SAES NP10~#174; getters, becomes the test sample for a comparative experiment in this study. The experiment is assigned into 4 sections with the organic gas removal system(OGRS) "Closed/Opened" in turn. When the OGRS is closed only with two NP10 getters for purification, the ~40Ar intensities increase in curves with inlet time because of impurities, the ~40Ar/~39 Ar dating results yield age errors about ±2%–±1%(2σ). When the OGRS is opened for purification, in contrast, the ~40 Ar intensities decrease linearly with inlet time. This indicates that the gases have been cleaned up effectively, and the 4~0Ar/~39 Ar results yield ages with errors in ±0.4%. The OGRS is very helpful to obtain high-quality analysis data. 相似文献
2.
A new mechanism of generation of ULF geomagnetic pulsations near the Earth’s surface near the future earthquake epicenter is proposed. The mechanism is connected with the migration of fluid and gases during the active phase of the earthquake preparation. The motion of fluid and gases is accompanied by the formation of cracks and fast filling of them by fluid and gases. The variation of electrical conductivity in the layer induces the impulsive electric current. The magnetic field due to this current can be registered on the Earth’s surface. The corresponding equations for magnetic field perturbations caused by non-stationary conductivity are derived. The amplitude and temporal characteristics of the magnetic impulses are estimated. 相似文献
3.
Hervé Le Treut 《Surveys in Geophysics》2012,33(3-4):723-731
The past record of global earth surface temperatures is unable to offer quantitative evidence about the amplitude of climate sensitivity, due to the competing effects of long-lived greenhouse gases and short-lived aerosols. This factor constitutes one of the reasons why uncertainties about climate sensitivity have remained almost unchanged for more than 30 years, and it is also limiting our current capacity to propose reliable climate projections for the coming century. This paper offers a short review of the studies that have dealt with this issue. A number of approaches aim at a process-oriented diagnostic of current models. These studies are in constant progress since the launch of remote-sensing instruments, such as those from the A-train satellite constellation. Past climate fluctuations may also offer some limited possibilities to discriminate the effects of greenhouse gases and aerosols. There is therefore a real hope that climate projections may eventually become more accurate, which would be extremely useful in monitoring global warming during the next decades. 相似文献
4.
David L. Finnegan Janet P. Kotra Diane M. Hermann William H. Zoller 《Bulletin of Volcanology》1989,51(2):83-87
A simple system was designed using7LiOH-impregnated filters to collect acidic gases from ambient air and from highly concentrated volcanic plumes or gas streams. These filters were developed for analysis using instrumental neutron activation analysis, but other analytical techniques could be used as well. The sampling system was designed to use a series of 1–3 M7LiOH-impregnated filters to collect high concentrations of acidic gases found in gas plumes of active volcanoes. The filters are quantitative for SO2 and the halide acids when sufficient base is present to neutralize the acidic species. Extremely high concentrations of SO2 may not be collected quantitatively since SO2 is a relatively weak Lewis acid compared to the halide acids. The acidic oxides of Sb, As, and Se were also collected quantitatively. A particle filter preceded the impregnated filters in order to remove particles from the fumes. This system has proven effective under difficult sampling conditions and, since it is portable and light weight, it could be used for many volcanological applications where high levels of acidic gaseous phase species need to be collected. 相似文献
5.
结合断层气测量，对压电晶体吸附检测器检测气体浓度的基本原理、测量装置、石英晶片选择、测量气室构型、气体进样方式、化学涂层物质的选择、涂层的制备、载气的选择、水汽及其它气体的干扰影响及消除等作了较详尽的论述，并简略介绍了目前利用压电晶体吸附检测器实现气体测量的气体种类、所用涂层物质、干扰情况及所能达到的精度。指出压电晶体吸附检测器具有灵敏度高，气体选择性好，装置简单，易于实现现场连续监测等优点，将其 相似文献
6.
Mi JingKui Dai JinXing Zhang ShuiChang Zhang WenZheng Gong Se Li XianQing 《中国科学:地球科学(英文版)》2008,51(1):115-121
The components and carbon isotope of gases in inclusions are one of the most important geochemical indexes for gas pools. The analysis results of the components and carbon isotope of gases from inclusions in reservoir layers of Upper Palaeozoic gas pools in the Ordos Basin show that most inclusions grown in reservoir sandstone are primary inclusions. There is only a little difference about the components and carbon isotope between the well gases and the secondary inclusions gases. This indicated that the epigenetic change of gas pools is little. This difference between the well gases and the secondary inclusions gases is caused by two reasons: (i) The well gases come from several disconnected sand bodies buried in a segment of depth, while the inclusion gases come from a point of depth. (ii) The secondary inclusions trapped the gases generated in the former stage of source rock gas generation, and the well gases are the mixed gases generated in all the stages. It is irresponsible to reconstruct the palaeo-temperature and palaeo-pressure under which the gas pool formed using carbon dioxide inclusions.
相似文献7.
《Physics of the Earth and Planetary Interiors》2002,129(3-4):185-204
The migration mechanisms of endogenous gases in the geosphere are defined in relation to the fluid-rock conditions and analyzed by basic transport equations. Upon examining the geological factors that influence the physical parameters in the equations in porous and fracture media, and considering the widespread high-permeability of deep subsurface rocks, in terms of fracture aperture, (orders of 10−2 to 101 mm at depths of thousands meters, as suggested by recent crustal surveys) advection of carrier gases, in its several forms (gas-phase flow, water displacement by gas, gas slugs and bubbles) seems to represent a major migration process. Accordingly, in contrast with early views, the role of gas diffusion and water advection in the transport of endogenous gas to the Earth surface should be strongly minimized in many contexts. In a wide range of geological settings, carrier gases (CO2, CH4) may assume a dominant role in controlling transport and redistribution toward the Earth’s surface of trace gases (Rn, He). Bubble movement in fissured rocks seems to be an effective way of rapid (gas velocities in the order of 100 to 103 m per day) and long-distance gas migration. The evolution from bubble regimes to continuous phase flow and vice versa, as gas pressure and fracture width change, is the most suitable mechanism towards determining the surface geochemical processes of seismo-tectonic, environmental and geo-exploration relevance. The transport effectiveness of trace gases by a carrier gas has yet to be studied in quantitative terms. It is already clear, however, that further studies on the distribution and behavior of trace gases approaching the Earth’s surface may not be meaningful unless accompanied by carrier gas dynamics analyses. 相似文献
8.
利用现有水化学观测仪器设备对某些灵敏气体进行观测,比如使用水氡、水质、气体观测仪器设备进行断层土壤气氡、二氧化碳、气体观测的实验研究,并且给出了集气、采气装置的构成方式.氡气和气体观测采用真空负压采样法,使用水氡观测仪器和气相色谱仪.而土壤二氧化碳观测方法可采用碱溶液吸收法,采样时采用真空负压采样法或常压自然吸收法两种方式,还提出了氡气观测中设计采样装置时应注意的事项. 相似文献
9.
本文通过对西起安南坝,东至昌马车路口的阿尔金断裂东北段断层气体的分析,讨论了微量气体H_2、Hg、Rn、CO_2在断层上的分布特征。指出,在同一剖面上,四种气体浓度不仅对断层有同步显示规律,而且与断层的活动强度有一定的关系。另外,分析结果还显示了H_2、Hg、Rn、CO_2的浓度有西高东低的趋势。这一特征还与地质资料所表明的阿尔金山断裂东北段西部的现今活动比东部的现今活动较强的事实相吻合。文章还讨论了用对断层气体进行定点、定期观测的结果来判断断层的活动动态及进行地震短临预报的可能性。最后指出,利用断层气体来研究活动断层是一种切实可行的方法。 相似文献
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11.
We have developed a closed-system combustion technique and utilized it to progressively oxidize a gas-rich, highly carbonaceous acid residue and a fine-grained (<4 μm) matrix sample from the Allende C3V meteorite and analyze the released gases mass spectrometrically. For the residue complete gas mobilization occurs at temperatures below 600°C. The temperature interval over which most of the gases are released coincides with that for combustion of most of the carbon. Release is primarily due to chemical attack rather than thermal activation of the gases. There are somewhat different oxidation thresholds for the heavy gases (Ar, Kr, and Xe) and the light gases (He, Ne), indicating chemically different sites for the two groups. Relative enhancement of isotopically anomalous components near 600°C is as large as in any open-system oxidation method. Differential combustion of the matrix sample reveals three distinct outgassing peaks, the first matching the release from the carbonaceous residue (“combustibles”), the second attributed to sulfides, and the third tentatively assigned to silicates. They comprise about 53%, 7% and 40% of the total heavy gases respectively. While the “sulfides” exhibit a small fission-like component, the Xe in the “silicates” appears isotopically uniform with roughly AVCC composition. The “combustibles” of the matrix contain relatively less excess129Xe than the residue, perhaps indicating that ～10% of the total129Xe in the residue was acquired from “silicates” by redistribution during acid treatment. We cannot rule out the possibility that planetary gases assigned to “sulfides” or “silicates” actually reside in carbonaceous phases somehow sheltered within soluble mineral assemblages, or in acid-soluble carbonaceous phases resistant to oxidation. Integrated releases below and above 600°C during the matrix combustion exhibit virtually identical heavy gas elemental composition, implying similar fractionation during planetary gas entrapment in various materials or in the same material in various environments. 相似文献
12.
Keisuke Nagao Nobuo Takaoka Osamu Matsubayashi 《Earth and Planetary Science Letters》1981,53(2):175-188
Isotopic and elemental compositions of rare gases in various types of gas samples collected in the Japanese Islands were investigated. Excess3He was found in most samples. Many samples showed a regionally uniform high3He/4He ratio of about 7 times the atmospheric ratio. The He concentrations varied from 0.6 to 1800 ppm, and they were low in CO2-rich gases and high in N2-rich gases. Ne isotopic deviations from the atmospheric Ne were detected in most volcanic gases. The deviations and the elemental abundance patterns in volcanic gases can be explained by a mixing between two components, one is mass fractionated rare gases and the other is isotopically atmospheric and is enriched in heavy rare gas elements. Ar was a mixture of mass fractionated Ar, atmospheric Ar and radiogenic Ar, and the contribution of radiogenic40Ar was small in all samples. Except for He, elemental abundance patterns were progressively enriched in the heavier rare gases relative to the atmosphere. Several samples were highly enriched in Kr and Xe relative to the abundance pattern of dissolution equilibrium of atmospheric rare gases in water. The component which is highly enriched in heavy rare gases may be released from sedimentary materials in the crust. 相似文献
13.
D. PATELLA 《Geophysical Prospecting》1979,27(3):628-639
This paper deals with a new method of quantitative interpretation of induced polarization soundings in the frequency-domain. From the general expression of the apparent frequency-effect for soundings carried out on a multi-layered earth the application of Hankel's inversion theorem allows to introduce a new function, called here the “frequency-effect transform”. The new interpretation method consists of two steps: 1) the inversion of field data to obtain the frequency-effect transform graph and 2) the analysis of this graph to derive the layering parameters. The first step is performed by means of a slightly revised version of a simple numerical procedure, previously suggested by the author for the inversion of d.c. resistivity sounding data. The second step is carried out by a complete curve-matching procedure, applied directly on the transform graph. This implies suitable master curves, whose preparation doesn't meet all the mathematical difficulties which are present when preparing master curves of the apparent frequency-effect function. 相似文献
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15.
Abstract This paper describes a research project based in Cyprus to investigate a number of different methods for determining quantitative recharge to aquifers in semiarid areas. Large lysimeters and geochemical profile techniques have been used in the southeastern Mesaoria area of Cyprus where there has already been a quantitative water resources investigation and where a groundwater model is in preparation. Further joint geochemical and lysimeter studies are also being undertaken in the Akrotiri peninsula (average annual rainfall 430 mm). Excavation and piling techniques have been used to install the lysimeters which are up to 100 m2 in area by 4 m deep. The lysimeters have been made as large as possible to minimize edge effects whilst maintaining the soil and aquifer material within them in an ‘undisturbed’ state. A dry drilling method has been developed to obtain sand samples from the unsaturated zone together with a method for processing the core material to obtain data on moisture and solutes. Chloride profiles have been interpreted to provide estimates of the direct recharge component using a steady state, mass balance approach and initial results compare favourably with tritium estimates. The preliminary results for recharge obtained by the different techniques are compared with each other and with estimates obtained from conventional methods. Initial results from the lysimeters indicate a current annual recharge of 5 mm in southeastern Mesaoria (1978), whilst a mean annual recharge of 50 mm at Akrotiri has been obtained by the chloride profile method. 相似文献
16.
The Ordos Basin, the second largest sedimentary basin in China, contains the broad distribution of natural gas types. So far, several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin, each having over 1000×108m3 of proven gas reserves, and several gas pools have also been discovered in the Mesozoic. This paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs, and then discussed their origin. For hydrocarbons preserved in the Upper Paleozoic, the elevated δ 13C values of methane, ethane and propane indicate that the gases would be mainly coal-formed gases; the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different maturity. In the Lower Paleozoic, the δ 13C1 values are mostly similar with those in the Upper Paleozoic, but the δ 13C2 and δ 13C3 values are slightly lighter, suggesting that the gases would be mixing of coal-type gases as a main member and oil-type gases. There are multiple reversals in carbon isotopes for gaseous alkanes, especially abnormal reversal for methane and ethane (i.e. δ 13C1>δ 13C2), inferring that gases would be mixed between high-mature coal-formed gases and oil-type gases. In the Mesozoic, the δ 13C values for gaseous alkanes are enriched in 12C, indicating that the gases are mainly derived from sapropelic sources; the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different maturity. In contrast to the Upper Paleozoic gases, the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane, which may be caused by gases generated from different kerogen types. Finally, according to δ 13C1-R 0 relationship and extremely low total organic carbon contents, the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source, bycontrast, the Upper Paleozoic source as a main gas source is contributed to the Lower Paleozoic gases.
相似文献17.
The Ordos Basin, the second largest sedimentary basin in China, contains the broad distribution of natural gas types. So far, several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin, each having over 1000×108m3 of proven gas reserves, and several gas pools have also been discovered in the Mesozoic. This paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs, and then discussed their origin. For hydrocarbons preserved in the Upper Paleozoic, the elevated δ 13C values of methane, ethane and propane indicate that the gases would be mainly coal-formed gases; the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different maturity. In the Lower Paleozoic, the δ 13C1 values are mostly similar with those in the Upper Paleozoic, but the δ 13C2 and δ 13C3 values are slightly lighter, suggesting that the gases would be mixing of coal-type gases as a main member and oil-type gases. There are multiple reversals in carbon isotopes for gaseous alkanes, especially abnormal reversal for methane and ethane (i.e. δ 13C1>δ 13C2), inferring that gases would be mixed between high-mature coal-formed gases and oil-type gases. In the Mesozoic, the δ 13C values for gaseous alkanes are enriched in 12C, indicating that the gases are mainly derived from sapropelic sources; the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different maturity. In contrast to the Upper Paleozoic gases, the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane, which may be caused by gases generated from different kerogen types. Finally, according to δ 13C1-R 0 relationship and extremely low total organic carbon contents, the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source, bycontrast, the Upper Paleozoic source as a main gas source is contributed to the Lower Paleozoic gases. 相似文献
18.
Takuya Matsumoto Liang‐Feng Han Manfred Jaklitsch Pradeep K. Aggarwal 《Ground water》2013,51(3):461-468
To enable a wider use of dissolved noble gas concentrations and isotope ratios in groundwater studies, we have developed an efficient and portable sampling device using a commercially available membrane contactor. The device separates dissolved gases from a stream of water and collects them in a small copper tube (6 mm in diameter and 100 mm in length with two pinch‐off clamps) for noble gas analysis by mass spectrometry. We have examined the performance of the sampler using a tank of homogeneous water prepared in the laboratory and by field testing. We find that our sampling device can extract heavier noble gases (Ar, Kr, and Xe) more efficiently than the lighter ones (He and Ne). An extraction time of about 60 min at a flow rate of 3 L/min is sufficient for all noble gases extracted in the sampler to attain equilibrium with the dissolved phase. The extracted gas sample did not indicate fractionation of helium (3He/4He) isotopes or other noble gas isotopes. Field performance of the sampling device was tested using a groundwater well in Vienna and results were in excellent agreement with those obtained from the conventional copper tube sampling method. 相似文献
19.
In order to sample medium-temperature fumaroles, gases are collected by means of iron or glass tubings and conveyed to the condensation system through glass dewar tubes. One type of condenser was designed for condensate measurement and gas sampling for Radon activity determination; the other, with NaOH absorbing solution, for the S/Cl ratio measurement and the sampling of rare gases. With this method it is possible to obtain precise gas/vapour measurements as well as air free gas samples. 相似文献
20.
The restored compositions for approximately 70 new analyses reported recently for Erta'Alelava lake (LeGuern et al., 1979) are in good agreement with restored compositions (Gerlach, 1980a) based on previously published data. The results confirm earlier indications that gas collections taken at different times from the lava lake are related principally by variations in CO2 content. Restored compositions for gas samples collected in the final stages of a November 1978 Ardoukoba eruption along the Asal Rift spreading axis resemble the Erta'Ale gases except for a much lower CO2 content. The Ardoukoba gases fall close to a CO2-decreasing control line for gases with initial compositions similar to the 1971–1973 Erta'Ale gases. These results suggest that gases released from basaltic lava along zones of crustal spreading follow compositional trends dominated by changes in CO2 content. 相似文献