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1.
Abstract— The Elephant Moraine A79002 (EETA79002) diogenite is a fragmental breccia with a subtle lightdark structure. It is composed of orthopyroxene, with minor olivine, chromite, and ubiquitous, inhomogeneously distributed, approximately 5–500 μm sized troilite and metal grains. These latter are present in the matrix, and as inclusions in and as symplectic intergrowths with orthopyroxene and olivine. Trace amounts of silica and diopside are also present. Most orthopyroxene compositions (typical orthopyroxenes) are in the narrow range Wo2.1–2.7En74.1–75.6Fs22.2–23.8 like those of most diogenites. A few magnesian orthopyroxenes are present with compositions of Wo1.7‐2.5En77.5–80.2 Fs18.2–20.3. These are among the most magnesian orthopyroxenes known from diogenites. A few ferroan orthopyroxenes have compositions of Wo2.1–2.9En71.7–73.7Fs24.2–25.5. Differences in Al2O3, TiO2, and Cr2O3 between the different orthopyroxene groups are inconsistent with a simple igneous fractionation relationship between them. Olivine compositions are Fo75.0–76.9. The olivines could be in equilibrium with the magnesian orthopyroxenes, but not with the typical or ferroan orthopyroxenes that form the bulk of EETA79002. Metal grains exhibit a range of Ni and Co contents and Ni/Co ratios; their compositions indicate that they are primary igneous metal. Metal and troilite grains are more prevalent in the dark samples. The trace incompatible lithophile element contents of 16 samples are remarkably uniform. Their Yb concentrations are all within their 2s? analytical uncertainties of the mean. The uniformity and low content of light rare earth elements in EETA79002 indicate that negligible amounts of a trapped liquid component, or foreign material mixed in the breccia, could be present. The siderophile and chalcophile element data show that the light‐dark structure is due to the distribution of metal and troilite grains; dark samples contain higher Ni, Co, and Se compared to light samples. Meteorite EETA79002 appears to contain material from three or more related plutons, a magnesian harzburgite, and two orthopyroxenites, and is a genomict breccia.  相似文献   

2.
Northwest Africa (NWA) 1950 is a new member of the lherzolitic shergottite clan of the Martian meteorites recently found in the Atlas Mountains. The petrological, mineralogical, and geochemical data are very close to those of the other known lherzolitic shergottites. The meteorite has a cumulate gabbroic texture and its mineralogy consists of olivine (Fo66 to Fo75), low and high‐Ca pyroxenes (En78Fs19Wo2‐En60Fs26W14; En53Fs16Wo31‐En45Fs14Wo41), and plagioclase (An57Ab41Or1 to An40Ab57Or3; entirely converted into maskelynite during intense shock metamorphism). Accessory minerals include phosphates (merrillite), chromite and spinels, sulfides, and a glass rich in potassium. The oxygen isotopic values lie on the fractional line defined by the other SNC meteorites (Δ17O = 0.312 %o). The composition of NWA 1950 is very similar to the other lherzolitic shergottites and suggests an origin from the same magmatic system, or at least crystallization from a close parental melt. Cosmogenic ages indicate an ejection age similar to those of the other lherzolitic shergottites. The intensity of the shock is similar to that observed in other shergottites, as shown by the occurrence of small melt pockets containing glass interwoven with stishovite.  相似文献   

3.
Abstract– Northwest Africa (NWA) 4797 is an ultramafic Martian meteorite composed of olivine (40.3 vol%), pigeonite (22.2%), augite (11.9%), plagioclase (9.1%), vesicles (1.6%), and a shock vein (10.3%). Minor phases include chromite (3.4%), merrillite (0.8%), and magmatic inclusions (0.4%). Olivine and pyroxene compositions range from Fo66–72,En58–74Fs19–28Wo6–15, and En46–60Fs14–22Wo34–40, respectively. The rock is texturally similar to “lherzolitic” shergottites. The oxygen fugacity was QFM?2.9 near the liquidus, increasing to QFM?1.7 as crystallization proceeded. Shock effects in olivine and pyroxene include strong mosaicism, grain boundary melting, local recrystallization, and pervasive fracturing. Shock heating has completely melted and vesiculated igneous plagioclase, which upon cooling has quench‐crystallized plagioclase microlites in glass. A mm‐size shock melt vein transects the rock, containing phosphoran olivine (Fo69–79), pyroxene (En44–51Fs14–18Wo30–42), and chromite in a groundmass of alkali‐rich glass containing iron sulfide spheres. Trace element analysis reveals that (1) REE in plagioclase and the shock melt vein mimics the whole rock pattern; and (2) the reconstructed NWA 4797 whole rock is slightly enriched in LREE relative to other intermediate ultramafic shergottites, attributable to local mobilization of melt by shock. The shock melt vein represents bulk melting of NWA 4797 injected during pressure release. Calculated oxygen fugacity for NWA 4797 indicates that oxygen fugacity is decoupled from incompatible element concentrations. This is attributed to subsolidus re‐equilibration. We propose an alternative nomenclature for “lherzolitic” shergottites that removes genetic connotations. NWA 4797 is classified as an ultramafic poikilitic shergottite with intermediate trace element characteristics.  相似文献   

4.
Abstract— ALH84001, originally classified as a diogenite, is a coarse-grained, cataclastic, orthopyroxenite meteorite related to the martian (SNC) meteorites. The orthopyroxene is relatively uniform in composition, with a mean composition of Wo3.3En69.4Fs27.3. Minor phases are euhedral to subhedral chromite and interstitial maskelynite, An31.1Ab63.2Or5.7, with accessory augite, Wo42.2En45.1Fs12.7, apatite, pyrite and carbonates, Cc11.5Mg58.0Sd29.4Rd1.1. The pyroxenes and chromites in ALH84001 are similar in composition to these phases in EETA79001 lithology A megacrysts but are more homogeneous. Maskelynite is similar in composition to feldspars in the nakhlites and Chassigny. Two generations of carbonates are present, early (pre-shock) strongly zoned carbonates and late (post-shock) carbonates. The high Ca content of both types of carbonates indicates that they were formed at moderately high temperature, possibly ～700 °C. ALH84001 has a slightly LREE-depleted pattern with La 0.67x and Lu 1.85x CI abundances and with a negative Eu anomaly (Eu/Sm 0.56x CI). The uniform pyroxene composition is unusual for martian meteorites, and suggests that ALH84001 cooled more slowly than did the shergottites, nakhlites or Chassigny. The nearly monomineralic composition, coarse-grain size, homogenous orthopyroxene and chromite compositions, the interstitial maskelynite and apatite, and the REE pattern suggest that ALH84001 is a cumulate orthopyroxenite containing minor trapped, intercumulus material.  相似文献   

5.
Abstract— Dar al Gani 476, the 13th martian meteorite, was recovered from the Sahara in 1998. It is a basaltic shergottitic rock composed of olivine megacrysts reaching 5 mm (24 vol%) set in a finegrained groundmass of pyroxene (59 vol%) and maskelynitized plagioclase (12 vol%) with minor amounts of accessory phases (spinel, merrillite, ilmenite). Dar al Gani 476 is similar to lithology A of Elephant Moraine A79001 (EETA79001) in petrography and mineralogy, but is distinct in several aspects. Low‐Ca pyroxenes in the Dar al Gani 476 groundmass are more magnesian (En76Fs21 Wo3～En58Fs30Wo12) than those in lithology A of EETA79001 (En73Fs22Wo5～En45Fs43Wo12), rather similar to pyroxenes in lherzolitic martian meteorites (En76Fs21 Wo3～En63Fs22Wo15). Dar al Gani 476 olivine is less magnesian and shows a narrower compositional range (Fo76‐58) than EETA79001 olivine (Fo81‐53), and is also similar to olivines in lherzolitic martian meteorites (Fo74‐65). The orthopyroxene‐olivine‐chromite xenolith typical in the lithology A of EETA79001 is absent in Dar al Gani 476. It seems that Dar al Gani 476 crystallized from a slightly more primitive mafic magma than lithology A of EETA79001 and several phases (olivine, pyroxene, chromite, and ilmenite) in Dar al Gani 476 may have petrogenetic similarities to those of lherzolitic martian meteorites. Olivine megacrysts in Dar al Gani 476 are in disequilibrium with the bulk composition. The presence of fractured olivine grains in which the most Mg‐rich parts are in contact with the groundmass suggests that little diffusive modification of original olivine compositions occurred during cooling. This observation enabled us to estimate the cooling rates of Dar al Gani 476 and EETA79001 olivines, giving similar cooling rates of 0.03‐3 °C/h for Dar al Gani 476 and 0.05‐5 °C/h for EETA79001. This suggests that they were cooled near the surface (burial depth shallower than about 3 m at most), probably in lava flows during crystallization of groundmass. As is proposed for lithology A of EETA79001, it may be possible to consider that Dar al Gani 476 has an impact melt origin, a mixture of martian lherzolite and other martian rock (Queen Alexandra Range 94201, nakhlites?).  相似文献   

6.
Nepheline and sodalite have been found in association with glass in a barred olivine chondrule from the Allende C3V meteorite. The major minerals of the chondrule are olivine (Fo80–88), bronzite (En85Fs12Wo3), and chromite. Olivine bars are separated by glass of nearly pure plagioclase composition (An81–99). Olivine composition is more Fe-rich than predicted by olivine-liquid equilibria (Fo96). Conditions of non-equilibrium are implied from this and the presence of plagioclase glass and small amounts of subcalcic diopside (En75Fs12Wo13) in the chondrule. The properties of this chondrule are consistent with liquid condensation, but melting of an amoeboid olivine aggregate or similar object could also have generated the chondrule-forming liquid. Nepheline and sodalite appear to have crystallized from this liquid under non-equilibrium conditions.  相似文献   

7.
Abstract— The Loxton meteorite is a single stone of 22 g found in South Australia in 1968. It has been classified as an L5 chondrite, shock facies ‘a,’ and contains olivine (Fa24), orthopyroxene (Fs21–22), clinopyroxene (Wo44.7En45.9Fs9.4), nickel-iron, troilite, chromite and chlorapatite.  相似文献   

8.
Abstract— Based on optical microscopy and electron microprobe analysis, Linum is classified as an L6b chondrite that contains olivine (Fa24), orthopyroxene (Fs20), clinopyroxene (Wo45En47Fs8), plagioclase (An10Ab84Or6), nickel-iron, troilite, chromite and accessory amounts of chlorapatite and whitlockite.  相似文献   

9.
The Loop meteorite was found in 1962 in Gaines County, Texas, at a location very close to that where the Ashmore chondrite was found in 1969. The two specimens were assumed to be fragments of the same meteorite. The Loop meteorite is a type L6 chondrite composed of olivine (Fo75.4Fa24.6), orthopyroxene (En77.6Wo1.5Fs20.9), clinopyroxene (En47.5Wo45.1Fs7.4), plagioclase (Ab84.3Or5.5An10.2), Fe-Ni metal, troilite, and chromite. Fe-Ni metal is represented by kamacite (5.8-6.4 wt % Ni, 0.88-1.00 wt % Co), taenite (30.0–52.9 wt % Ni, 0.16-0.34 wt % Co), and plessite (16.8–28.5 wt % Ni, 0.38-0.54 wt % Co). Native copper occurs as rare inclusions in Fe-Ni metal. Both chondrules and matrix have similar mineral compositions. The mineral chemistry of the Loop meteorite is quite different from that of the Ashmore, which was classified as an H5 chondrite by Bryan and Kullerud (1975). Therefore, the Ashmore and Loop meteorites are two different chondrites, even though they were recovered from the same geographic location.  相似文献   

10.
Abstract— Frontier Mountain (FRO) 90054, from Antarctica, is a rare clino- and orthopyroxene-bearing ureilite with a coarse equigranular oriented texture (grains up to 3 mm); it is classified as a low-shock Ca-rich type. The crystal chemistry of its clinopyroxene (Wo39.3En54.6Fs6.1), orthopyroxene (En84 2Fs11Wo4.8) and olivine (Fa12.6Fo86.9) was investigated by single-crystal x-ray structural refinements and transmission electron microscope (TEM) observations to obtain data on the evolutionary history of the parent body. The M1 octahedron and unit cell volumes of the orthopyroxene and clinopyroxene are consistent with low-pressure crystallization. The closure temperatures for intracrystalline Mg-Fe2+ ordering yielded values of 674 °C and 804 °C for opx and 596 °C for cpx, which indicate high-temperature equilibration and fast cooling. Trasmission electron microscope investigations were performed on clinopyroxene, orthopyroxene and pigeonite. The (100) twin lamellae in the clinopyroxene and intergrowth of clino- and orthoenstatite lamellae in orthopyroxene most probably originated by deformation. Exsolution was not observed in any of the phases, which suggests rapid cooling. Analysis by TEM also revealed interstitial Na-rich glass and pigeonite with sharp h + k odd reflections and rare stacking faults parallel to (100). Textural and crystal chemical data, obtained by TEM, indicated rapid cooling that was probably due to fast radiative heat loss as a result of the disintegration of the parent body into small fragments, which subsequently reassembled into a larger body. One or more collisional events caused fine-scale stacking faults and partial melting.  相似文献   

11.
Abstract— Northwest Africa (NWA) 1670, contains olivines of up to 5 mm in size representing about 30% of the studied section. With subordinate clinopyroxene and chrome‐spinel microphenocrysts (0.2‐0.5 mm), they represent a xenocrystic association. Phenocrysts are surrounded by a groundmass, predominantly comprising bundles of plagioclase and clinopyroxene (typically 20 × 200 μm crystals). Olivine and kirschsteinite are present in the groundmass in lesser amounts. The olivine xenocrysts (Fo90) are significantly fractured and show mosaicism for their major part, the remaining showing faint undulatory extinction. They are surrounded with a rim of 100–200 μm zoned down to Fo80 and overgrown with serrated olivine, Fo80 to Fo60 (about 100 μm). Olivine in the groundmass is zoned from Mg# 0.55 to 0.15; its CaO content ranges 2.0 to 8.4%. Subcalcic kirschsteinite is zoned from Mg# 0.13 to 0.03, CaO increasing from 15.8 to 21.3%. Pyroxenes xenocrysts (Mg# = 0.77) are superseded in the groundmass by less magnesian pyroxenes, Mg# 0.61 to 0.17, with an average FeO/ MnO of 98. Their compositions range from En30 Fs22 Wo27 Al‐Ts28 Ti‐Ts2 to En2 Fs37 Wo22 Al‐Ts40 Ti‐Ts1. Anorthite microcrysts (An99‐100) are restricted to the groundmass. Accessories are pyrrhotite, kamacite, Ca‐phosphate, titanomagnetite, hercynite and Ca‐carbonate. The bulk chemical composition confirms that NWA 1670 corresponds to a normal angrite melt that incorporated olivine. High Mg olivine xenocrysts and the associated mineralogy are typical of angrites. We suggest that it is an impact melt with relict phenocrysts. The strong silica undersaturation, the presence of Fo90 olivine xenocrysts and carbonate support their derivation as melilite‐like melts in the presence of carbonate.  相似文献   

12.
The Jezersko meteorite is a newly confirmed stony meteorite found in 1992 in the Karavanke mountains, Slovenia. The meteorite is moderately weathered (W2), indicating short terrestrial residence time. Chondrules in partially recrystallized matrix are clearly discernible but often fragmented and have mean diameter of 0.73 mm. The meteorite consists of homogeneous olivine (Fa19.4) and low‐Ca pyroxenes (Fs16.7Wo1.2), of which 34% are monoclinic, and minor plagioclase (Ab83An11Or6) and Ca‐pyroxene (Fs6Wo45.8). Troilite, kamacite, zoned taenite, tetrataenite, chromite, and metallic copper comprise about 16.5 vol% of the meteorite. Phosphates are represented by merrillite and minor chlorapatite. Undulatory extinction in some olivine grains and other shock indicators suggests weak shock metamorphism between stages S2 and S3. The bulk chemical composition generally corresponds to the mean H chondrite composition. Low siderophile element contents indicate the oxidized character of the Jezersko parent body. The temperatures recorded by two‐pyroxene, olivine‐chromite, and olivine‐orthopyroxene geothermometers are 854 °C, 737–787 °C, and 750 °C, respectively. Mg concentration profiles across orthopyroxenes and clinopyroxenes indicate relatively fast cooling at temperatures above 700 °C. A low cooling rate of 10 °C Myr?1 was obtained from metallographic data. Considering physical, chemical, and mineralogical properties, meteorite Jezersko was classified as an H4 S2(3) ordinary chondrite.  相似文献   

13.
Abstract— Dar al Gani 489 (DaG 489) is a meteorite fragment of 2146 g found in the Libyan Sahara by a meteorite finder during one of his search campaigns in 1997–98. It is a porphyritic rock with millimetersized olivine crystals (Fo79–59) set in a fine‐grained groundmass (average grain size 0.1 mm) consisting of pigeonite (En75–57 Wo5–15) crystals and interstitial feldspathic glass (An67–56 Or0–1). Minor phases include enstatite (En82–71 Wo2–4), augite (En48–52 Wo29–32), chromite, Ti‐chromite, ilmenite, pyrrhotite, merrillite, and secondary calcite and iron oxides. On the basis of mineralogical, petrographic, bulk chemical, O‐isotopic, and noble gas data, DaG 489 can be classified as a highly shocked martian meteorite (e.g., Fe/Mn(bulk) = 42.1, Ni/Mg(bulk) = 0.002; δ17O = 2.89, δ18O = 4.98, and Δ17O = 0.305), belonging to the basaltic shergottite subgroup. The texture and modal composition of DaG 489 are indeed those of basalts; nonetheless, the bulk chemistry, the abundance of large olivine and chromite crystals, and enstatitic pyroxene suggest some relationship with lherzolitic shergottites. As such, DaG 489 is similar to the hybrid shergottite Elephant Moraine (EET) A79001 lithology A; however, there are some relevant differences including a higher olivine content (20 vol%), the lack of orthopyroxene megacrysts, a higher molar Mg/(Mg + Fe)(molar) = 0.68, and a lower rare earth element content in the bulk sample. Therefore, DaG 489 has the potential of providing us with a further petrogenetic link between the basaltic and lherzolitic shergottites. Noble gases data show that DaG 489 has an ejection age of ～1.3 Ma. This young age lends support to the requirement of several ejection events to produce the current population of shergottites, nakhlites, and chassignites (SNC) meteorites. In terms of texture, mineral and bulk compositions, shock level, and weathering features, DaG 489 is essentially identical to DaG 476, another basaltic shergottite independently found ～25 km due northnortheast of DaG 489. Because DaG 489 also has the same exposure history as DaG 476, it is very likely that both meteorites are fragments of the same fall. In addition to the existing hypotheses on the petrogenesis of the similar EETA79001 lithology A and the identical DaG 476, we propose that DaG 489 could have formed through high‐degree partial melting of a lherzolite‐like material.  相似文献   

14.
The iron‐bearing phases in a ureilite fragment (AS#051) from the Almahata Sitta meteorite are studied using Mössbauer spectroscopy, X‐ray diffraction (XRD), and electron microprobe analysis (EMPA). AS#051 has a typical ureilite texture of medium‐ to coarse‐grained silicates (olivine, orthopyroxene, and pigeonite) with minor opaques (Fe‐Ni metal, troilite, and graphite). The silicate compositions, determined by EMPA, are homogeneous: olivine (Fo90.2), orthopyroxene (En86.3Fs8.6Wo5.1), and pigeonite (En81.6Fs8.9Wo9.5), and are similar to those of magnesian ureilites. The modal abundance of mineral phases was determined by Rietveld refinement of the powder XRD data. The Mössbauer spectra at 295 K and 78 K are composed of two sharp well‐defined paramagnetic doublets superimposed on a well‐resolved magnetic sextet and other weak absorption features. The two paramagnetic doublets are assigned to olivine and pyroxene (orthopyroxene and pigeonite), and the ferromagnetic sextet to kamacite (magnetic hyperfine field ≈ 33.2 T), in agreement with the XRD characterization. The Mössbauer results also show the presence of small amounts of troilite (FeS) and cohenite ([Fe,Ni,Co]3C). Using the Mössbauer data, the relative abundance of each Fe‐bearing phase is determined and compared with the results obtained by XRD.  相似文献   

15.
Abstract– The Grove Mountains (GRV) 021663 meteorite was collected from the Grove Mountains region of Antarctica. The meteorite is composed primarily of olivine (Fa5.4), orthopyroxene (Fs4.7Wo3.0), chromian diopside (En53.6Fs2.4Wo44), troilite, kamacite, and plagioclase (Ab74.5Or4An21.5). Minor phases include schreibersite and K‐feldspar. The meteorite is highly weathered (W3) and weakly shocked (S2). We determine a whole rock oxygen isotopic composition of δ18O = 7.50‰, δ17O = 3.52‰. Comparisons of these data with other primitive achondrites have resulted in the reclassification of this meteorite as a member of the winonaite group. The occurrences of troilite, metal, and schreibersite in GRV 021663 indicate that these minerals were once completely molten. Euhedral inclusions of pyroxene within plagioclase further suggest that these may have crystallized from a silicate melt, while the depletion of plagioclase, metal, and troilite indicates that GRV 021663 could represent a residuum following partial melting on its parent asteroid. Trace element distributions in silicate minerals do not, however, confirm this scenario. As with other winonaite meteorites, the formation of GRV 021663 probably relates to brecciation and mixing of heterogeneous lithologies, followed by varying degrees of thermal metamorphism on the parent body asteroid. Peak metamorphic conditions may have resulted in localized partial melting of metal and silicate mineralogies, but our data are not conclusive.  相似文献   

16.
Abstract By mineral and bulk compositions, the Lewis Cliff (LEW) 88516 meteorite is quite similar to the ALHA77005 martian meteorite. These two meteorites are not paired because their mineral compositions are distinct, they were found 500 km apart in ice fields with different sources for meteorites, and their terrestrial residence ages are different. Minerals in LEW88516 include: olivine, pyroxenes (low- and high-Ca), and maskelynite (after plagioclase); and the minor minerals chromite, whitlockite, ilmenite, and pyrrhotite. Mineral grains in LEW88516 range up to a few mm. Texturally, the meteorite is complex, with regions of olivine and chromite poikilitically enclosed in pyroxene, regions of interstitial basaltic texture, and glass-rich (shock) veinlets. Olivine compositions range from Fo64 to Fo70, (avg. Fo67), more ferroan and with more variation than in ALHA77005 (Fo69 to Fo73). Pyroxene compositions fall between En77Wo4 and En65Wo15 and in clusters near En63Wo9 and En53Wo33, on average more magnesian and with more variation than in ALHA77005. Shock features in LEW88516 range from weak deformation through complete melting. Bulk chemical analyses by modal recombination of electron microprobe analyses, instrumental neutron activation, and radiochemical neutron activation confirm that LEW88516 is more closely related to ALHA77005 than to other known martian meteorites. Key element abundance ratios are typical of martian meteorites, as is its non-chondritic rare earth pattern. Differences between the chemical compositions of LEW88516 and ALHA77005 are consistent with slight differences in the proportions of their constituent minerals and not from fundamental petrogenetic differences. Noble gas abundances in LEW88516, like those in ALHA77005, show modest excesses of 40Ar and 129Xe from trapped (shock-implanted) gas. As with other ALHA77005 and the shergottite martian meteorites (except EETA79001), noble gas isotope abundances in LEW88516 are consistent with exposure to cosmic rays for 2.5–3 Ma. The absence of substantial effects of shielding from cosmic rays suggest LEW88516 spent this time as an object no larger than a few cm in diameter.  相似文献   

17.
Abstract— The Nova 001 [= Nuevo Mercurio (b)] and Nullarbor 010 meteorites are ureilites, both of which contain euhedral graphite crystals. The bulk of the meteorites are olivine (Fo79) and pyroxenes (Wo9En73Fs18, Wo3En77Fs20), with a few percent graphite and minor amounts of troilite, Ni-Fe metal, and possibly diamond. The rims of olivine grains are reduced (to Fo91) and contain abundant blebs of Fe metal. Silicate mineral grains are equant, anhedral, up to 2 mm across, and lack obvious preferred orientations. Euhedral graphite crystals (to 1 mm x 0.3 mm) are present at silicate grain boundaries, along boundaries and protruding into the silicates, and entirely within silicate mineral grains. Graphite euhedra are also present as radiating clusters and groups of parallel plates grains embedded in olivine; no other ureilite has comparable graphite textures. Minute lumps within graphite grains are possibly diamond, inferred to be a result of shock. Other shock effects are limited to undulatory extinction and fracturing. Both ureilites have been weathered significantly. Considering their similar mineralogies, identical mineral compositions, and identical unusual textures, Nova 001 and Nullarbor 010 are probably paired. Based on olivine compositions, Nova 001 and Nullarbor 010 are in Group 1 (FeO-rich) of Berkley et al. (1980). Silicate mineral compositions are consistent with those of other known ureilites. The presence of euhedral graphite crystals within the silicate minerals is consistent with an igneous origin, and suggests that large proportions of silicate magma were present locally and crystallized in situ.  相似文献   

18.
Abstract– A petrographic and geochemical study was undertaken to characterize Jiddat al Harasis (JaH) 556, a howardite find from the Sultanate of Oman. JaH 556 is a polymict impact melt breccia containing highly shocked clasts, including mosaicized olivine and recrystallized plagioclase, set in a finely recrystallized vesicular matrix (grain diameter <5–10 μm). Plagioclase (An76–92) and clinopyroxene (En48–62Wo7–15) are associated with orthopyroxene and olivine clasts like in a howardite. JaH 556 oxygen isotope data indicate that it has an anomalous bulk‐rock composition as howardite, resulting from a mixture between HED material and at least one second reservoir characterized by a higher Δ17O. The bulk meteorite has a composition consistent with howardites, but it is enriched in siderophile elements (Ni = 3940 and Co = 159 ppm) arguing for a chondritic material as second reservoir. This is independently confirmed by the occurrence of chondrule relics composed of olivine (Fo56–80), orthopyroxene (En79Wo2), and plagioclase (An61–66). Based on oxygen isotopic signature, siderophile composition, and chondrule core Mg number (Fo80 and En79Wo2), it is proposed that JaH 556 is a howardite containing approximately 20% H chondrite material. This percentage is high compared with that observed petrographically, likely because chondritic material dissolved in the impact melt. This conclusion is supported by the observed reaction of orthopyroxene to olivine, which is consistent with a re‐equilibration in a Si‐undersaturated melt. JaH 556’s unique composition enlarges the spectrum of howardite‐analogs to be expected on the surface of 4 Vesta. Our data demonstrate that oxygen isotopic anomalies can be produced by a mixture of indigenous and impactor materials and must be interpreted with extreme caution within the HED group.  相似文献   

19.
Petrology of Martian meteorite Northwest Africa 998   总被引：1，自引：0，他引：1  
Abstract— Nakhlite Northwest Africa (NWA) 998 is an augite-rich cumulate igneous rock with mineral compositions and oxygen isotopic composition consistent with an origin on Mars. This 456-gram, partially fusion-crusted meteorite consists of (by volume) ∼75% augite (core composition Wo39En39Fs22), ∼9% olivine (Fo35), ∼7% plagioclase (Ab61An35) as anhedra among augite and olivine, ∼3.5% low-calcium pyroxenes (pigeonite and orthopyroxene) replacing or forming overgrowths on olivine and augite, ∼1% titanomagnetite, and other phases including potassium feldspar, apatite, pyrrhotite, chalcopyrite, ilmenite, and fine-grained mesostasis material. Minor secondary alteration materials include “iddingsite” associated with olivine (probably Martian), calcite crack fillings, and iron oxide/hydroxide staining (both probably terrestrial). Shock effects are limited to minor cataclasis and twinning in augite. In comparison to other nakhlites, NWA 998 contains more low-calcium pyroxenes and its plagioclase crystals are blockier. The large size of the intercumulus feldspars and the chemical homogeneity of the olivine imply relatively slow cooling and chemical equilibration in the late- and post-igneous history of this specimen, and mineral thermometers give subsolidus temperatures near 730 °C. Oxidation state was near that of the QFM buffer, from about QFM-2 in earliest crystallization to near QFM in late crystallization, and to about QFM + 1.5 in some magmatic inclusions. The replacement or overgrowth of olivine by pigeonite and orthopyroxene (with or without titanomagnetite), and the marginal replacement of augite by pigeonite, are interpreted to result from late-stage reactions with residual melts (consistent with experimental phase equilibrium relationships). Apatite is concentrated in planar zones separating apatite-free domains, which suggests that residual magma (rich in P and REE) was concentrated in planar (fracture?) zones and possibly migrated through them. Loss of late magma through these zones is consistent with the low bulk REE content of NWA 998 compared with the calculated REE content of its parent magma.  相似文献   

20.
Abstract— Sayhal Uhaymir (SaU) 094 is a 223.3 g, partially crusted, strongly to very strongly shocked melanocratic olivine-porphyric rock of the shergottite group showing a microgabbroic texture. The rock consists of pyroxene (52.0–58.2 vol%)—dominantly prismatic pigeonite (En60–68Fs20–27Wo7–9) associated with minor augite (En46–49Fs15–16Wo28–31)—brown (shock-oxidized) olivine (Fo65–69; 22.1–31%), completely isotropic interstitial plagioclase glass (maskelynite; An50–64Or0.3-0.9; 8.6–13.0%), chromite and titanian magnesian chromite (0.9-1.0%), traces of ilmenite (Ilm80–86), pyrrhotite (Fe92–100; 0.1-0.2%), merrillite (<<0.1%), and pockets (4.8-6.7%) consisting of green basaltic to basaltic andesitic shock glass that is partially devitrified into a brown to black product along boundaries with the primary minerals. The average maximum dimensions of minerals are: olivine (1.5 mm), pyroxene (0.3 mm) and maskelynite (0.3 mm). Primary melt inclusions in olivine and chromite are common and account for 0.1-0.6% of the rock. X-ray tomography revealed that the specimen contains ˜0.4 vol% of shock-melt associated vesicles, up to 3 mm in size, which show a preferred orientation. Fluidization of the maskelynite, melting and recrystallization of pyroxene, olivine and pyrrhotite indicate shock stage S6. Minor terrestrial weathering resulted in calcite-veining and minor oxidation of sulfides. The meteorite is interpreted as paired with SaU 005/008/051. The modal composition is similar to Dar al Gani 476/489/670/735/876, with the exception that neither mesostasis nor titanomagnetite nor apatite are present and that all phases show little zonation. The restricted mineral composition, predominance of chromite among the oxides, and abundance of olivine indicate affinities to the lherzolitic shergottites.  相似文献   

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