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1.
Song‐Bae Kim 《水文研究》2005,19(20):4069-4079
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2.
The low bioavailability of hydrophobic organic compounds (HOCs) is one of the key sources of uncertainty in the implementation of in situ bioremediation. Bioavailability of HOCs in the subsurface is affected by sorption/desorption processes in two important ways. First, sorption causes high organic concentrations in microporous regions and impermeable zones to which bacterial access is obstructed. Second, because desorption and immobile zone diffusion must occur before biodegradation can proceed, the overall rate of bioremediation can be limited or even controlled by these mass transfer processes, not by the activity of the degrading microorganisms. Rate models that couple sorption/desorption—related mass transfer processes and biodegradation have been successfully applied to laboratory results and are beginning to offer some insight into the problem. Specifically, the influence of sorption on biodegradation is quantified here by defining a bioavailability factor, Bf. However, many questions remain and predictive modeling is elusive, especially in the context of complicated heterogeneous natural systems. Challenges facing environmental engineers are to develop a better understanding of these processes at both laboratory and field scales and ultimately to use such understanding toward the development of more effective and economical remediation technologies.  相似文献   

3.
Global peatlands store an unparalleled proportion of total global organic carbon but it is vulnerable to erosion into fluvial systems. Fluvial networks are being recognized as areas of carbon transformation, with eroded particulate organic carbon processed to dissolved organic carbon and CO2. Existing studies indicate biodegradation and photodegradation as key processes controlling the transformation of organic carbon in fluvial systems, with initial concentrations of dissolved organic carbon (DOC) identified as a control on the rate of carbon mineralization. This study manipulates temperature and incident light intensity to investigate carbon mineralization rates in laboratory simulations of peatland sediment transport into fluvial systems. By directly measuring gaseous CO2 emissions from sampled stream water, the relationship of temperature and light intensity with carbon efflux is identified. In simulations where sediment (as particulate organic matter, POM) is absent, temperature is consistently the dominant factor influencing carbon efflux rates. This influence is independent of the initial DOC concentration of the water sample. In simulations where POM was added, representing a peatland river receiving eroded terrestrial sediment, initial DOC concentration predicts 79% of the variation in total gaseous carbon efflux whereas temperature and light intensity predict 12% and 3%, respectively. When sampled stream water's mineralization rates in the presence of added POM are analysed independently, removing DOC as a model variable, the dominant variable affecting CO2 efflux is opposite for each sample. This study presents novel data suggesting peatland erosion introduces further complexity to dynamic stream systems where rates of carbon transformation processes and the influence of specific environmental variables are interdependent. Anthropogenic climate change is identified as a leading risk factor perpetuating peatland erosion; therefore, understanding the fate of terrestrial sediment in rivers and further quantifying the benefits of protecting peatland soils will be of increasing importance to carbon budgeting and ecosystem function studies.  相似文献   

4.
Input variable selection (IVS) is a necessary step in modeling water resources systems. Neglecting this step may lead to unnecessary model complexity and reduced model accuracy. In this paper, we apply the minimum redundancy maximum relevance (MRMR) algorithm to identifying the most relevant set of inputs in modeling a water resources system. We further introduce two modified versions of the MRMR algorithm (α-MRMR and β-MRMR), where α and β are correction factors that are found to increase and decrease as a power-law function, respectively, with the progress of the input selection algorithms and the increase of the number of selected input variables. We apply the proposed algorithms to 22 reservoirs in California to predict daily releases based on a set from a 121 potential input variables. Results indicate that the two proposed algorithms are good measures of model inputs as reflected in enhanced model performance. The α-MRMR and β-MRMR values exhibit strong negative correlation to model performance as depicted in lower root-mean-square-error (RMSE) values.  相似文献   

5.
Transport of nonsorbing solutes in a streambed with periodic bedforms   总被引：1，自引：0，他引：1  
Previous studies of hyporheic zone focused largely on the net mass transfer of solutes between stream and streambed. Solute transport within the bed has attracted less attention. In this study, we combined flume experiments and numerical simulations to examine solute transport processes in a streambed with periodic bedforms. Solute originating from the stream was subjected to advective transport driven by pore water circulation due to current–bedform interactions as well as hydrodynamic dispersion in the porous bed. The experimental and numerical results showed that advection played a dominant role at the early stage of solute transport, which took place in the hyporheic zone. Downward solute transfer to the deep ambient flow zone was controlled by transverse dispersion at the later stage when the elapsed time exceeded the advective transport characteristic time tc (= L/uc with L being the bedform length and uc the characteristic pore water velocity). The advection-based pumping exchange model was found to predict reasonably well solute transfer between the overlying water and streambed at the early stage but its performance deteriorated at the later stage. With dispersion neglected, the pumping exchange model underestimated the long-term rate and total mass of solute transfer from the overlying water to the bed. Therefore both advective and dispersive transport components are essential for quantification of hyporheic exchange processes.  相似文献   

6.
Transport and Biological Fate of Toluene in Low-Permeability Soils   总被引：1，自引：0，他引：1  
The effect of simultaneous sorption, diffusion, and biodegradation on the fate and transport of toluene in low-permeability soil formations was examined. A transport model accounting for vapor and liquid sorption, vapor diffusions, and first-order biodegradation was developed to describe the movement of volatile solute in unsaturated soils. Modeling studies were followed with laboratory batch and column studies on fine-grained soil samples obtained from a gasoline-contaminated site. Batch experiments yielded the sorption and diffusion coefficients for generating theoretical solute transport profiles. Column studies were conducted to examine toluene sorption, diffusion, and biodegradation under aerobic and denitrifying conditions. Results from the column studies indicated that vapor sorption onto the soil was minimal due to the high moisture content of the soil. Comparison of model predictions with experimental results indicated that the SASK model, which is based on the resistivity theory, provided a more accurate prediction of the vapor phase tortuosity than the frequently used Millington-Quirk equation. Laboratory results of toluene concentration profiles matched well with the model predictions and yielded degradation rates comparable to those obtained in the field. Column studies, examining toluene biodegradation under aerobic and denitrifying conditions in low-permeability soils, indicated that the presence of excess nitrate in aerobic environments yielded higher solute degradation rates than those observed under exclusively aerobic systems.  相似文献   

7.
When modeling the fate and transport of chemicals in ground water, a common assumption is that sorption equilibrium is achieved rapidly. This local equilibrium assumption is valid when the rate of chemical sorption to soil particles is more rapid than the rate of aqueous chemical change by other processes. However, for some chemicals (e.g., weathered hydrocarbons) this assumption is not necessarily correct. As a result, an increasing body of knowledge related to the extent and rate of release (ROR) of hydrocarbons from soil has been generated.
When evaluating site remediation options, it is important to know when nonequilibrium sorption conditions may have a significant impact on such decisions. In this study, a tiered procedure was developed to consistently evaluate the importance of ROR information at a site. The procedure consists of three tiers, each requiring more information and computational effort than the previous one. The first tier employs three power-law relationships between site parameters and the importance of ROR kinetics to quickly and easily estimate the importance of ROR information at a site. The second tier involves running and evaluating the deterministic component of a ground water fate and transport model. The third tier involves running and evaluating the probabilistic component of the ground water model. Given the sequential nature of the procedure, it is not necessary to perform Tier II (or Tier III) unless the Tier I (or Tier II) evaluation indicates that ROR kinetics may be important at the specific site under consideration. An example of applying the Tier I analysis to a specific site is provided. The results illustrate the influence of the chemical removal processes (e.g., advection and biodegradation) on the predicted importance of ROR kinetics. For the site considered, ROR kinetics had an important impact on model predictions when the biodegradation rate was high.  相似文献   

8.

By aid of gas chromatogram/mass spectrometry (GC-MS), the distributions and the compositions of biomarkers in a set of sequentially biodegraded oils from Liaohe Basin, China, have been quantitatively analyzed, and it has been found that during the biodegradation process of crude oils, the molecular maturity parameters such as Ts/Tm, homohopane C31 22S/(22S+22R) and sterane C29 20S/(20S+20R) ratios will be affected to different extent. The results show that except homohopane C31 22S/(22S+22R) ratio, Ts/Tm ratio will decrease with increasing biodegradation, but for C29 20S/(20S+20R) ratio, it will almost remain constant in slightly and moderately biodegraded oils, and then will increase quickly in severely biodegraded oils. The main reason is that there are some differences in the ability of resistant biodegradation for different isomer of biomarkers with different stereo configuration, resulting in the fact that destroying rate by bacteria for those biomarkers with weak ability will be higher than those with strong ability in resistant biodegradation. For example, 18α(H)-22,29,30-trisnorhopanes (Ts) will be destroyed more quickly than 17α(H)-22,29,30-trisnorshopanres (Tm), and 20R isomer is more quickly than 20S isomer for C29 sterane, resulting in the relative ratios changed with increasing biodegradation. Therefore, much more attention should be paid to the biodegradation extent of crude oils and the type of biomarker maturity indicators, when the distributions and the compositions of biomarkers in biodegraded oils are used to determine the maturity of biodegraded oils.

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9.
By aid of gas chromatogram/mass spectrometry (GC-MS), the distributions and the compositions of biomarkers in a set of sequentially biodegraded oils from Liaohe Basin, China, have been quantitatively analyzed, and it has been found that during the biodegradation process of crude oils, the molecular maturity parameters such as Ts/Tm, homohopane C31 22S/(22S+22R) and sterane C29 20S/(20S+20R) ratios will be affected to different extent. The results show that except homohopane C31 22S/(22S+22R) ratio, Ts/Tm ratio will decrease with increasing biodegradation, but for C29 20S/(20S+20R) ratio, it will almost remain constant in slightly and moderately biodegraded oils, and then will increase quickly in severely biodegraded oils. The main reason is that there are some differences in the ability of resistant biodegradation for different isomer of biomarkers with different stereo configuration, resulting in the fact that destroying rate by bacteria for those biomarkers with weak ability will be higher than those with strong ability in resistant biodegradation. For example, 18α(H)-22,29,30-trisnorhopanes (Ts) will be destroyed more quickly than 17α(H)-22,29,30-trisnorshopanres (Tm), and 20R isomer is more quickly than 20S isomer for C29 sterane, resulting in the relative ratios changed with increasing biodegradation. Therefore, much more attention should be paid to the biodegradation extent of crude oils and the type of biomarker maturity indicators, when the distributions and the compositions of biomarkers in biodegraded oils are used to determine the maturity of biodegraded oils.  相似文献   

10.
Modeling oil biodegradation is an important step in predicting the long term fate of oil on beaches. Unfortunately, existing models do not account mechanistically for environmental factors, such as pore water nutrient concentration, affecting oil biodegradation, rather in an empirical way. We present herein a numerical model, BIOB, to simulate the biodegradation of insoluble attached hydrocarbon. The model was used to simulate an experimental oil spill on a sand beach. The biodegradation kinetic parameters were estimated by fitting the model to the experimental data of alkanes and aromatics. It was found that parameter values are comparable to their counterparts for the biodegradation of dissolved organic matter. The biodegradation of aromatics was highly affected by the decay of aromatic biomass, probably due to its low growth rate. Numerical simulations revealed that the biodegradation rate increases by 3–4 folds when the nutrient concentration is increased from 0.2 to 2.0 mg N/L.  相似文献   

11.
The sorption behavior of nonylphenol (NP, a toxic endocrine disruptor) on marine sediments was studied in detail through a series of kinetic and thermodynamic sorption experiments. The results showed that the sorption reaction of NP on marine sediments reached equilibrium in 1.5 h and that it accorded well with the non-linear Ho-McKay pseudo-second-order model. The sorption isotherms of NP on H2O-treated sediments could be well described by the Linear isotherm model, while the sorption isotherm on H2O2-treated sediments could be well fitted with the Freundlich isotherm model. A positive correlation was found between the distribution coefficient (Kd) and the sediment organic carbon contents. The medium salinity showed a positive relation with the Kd and a negative relation with the dissolved organic carbon (DOC). Hexadecyl trimethyl ammonium bromide (CTAB) enhanced the sorption amount of NP the most, while sodium dodecylbenzenesulfonate (SDBS) enhanced it the least. The sorption reaction of NP on marine sediments was a spontaneous, physical, exothermic and entropy-decreasing process.  相似文献   

12.
Solute transport in subsurface environments is controlled by geological heterogeneity over multiple scales. In reactive transport characterized by a low Damköhler number, it is also controlled by the rate of kinetic mass transfer. A theory for addressing the impact of sedimentary texture on the transport of kinetically sorbing solutes in heterogeneous porous formations is derived using the Lagrangian-based stochastic methodology. The resulting model represents the hierarchical organization of sedimentary textures and associated modes of log conductivity (K) for sedimentary units through a hierarchical Markov Chain. The model characterizes kinetic sorption using a spatially uniform linear reversible rate expression. Our main interest is to investigate the effect of sorption kinetics relative to the effects of K heterogeneity on the dispersion of a reactive plume. We study the contribution of each scale of stratal architecture to the dispersion of kinetically sorbing solutes in the case of a low Damköhler number. Examples are used to demonstrate the time evolution and relative contributions of the auto- and cross-transition probability terms to dispersion. Our analysis is focused on the model sensitivity to the parameters defined at each hierarchical level (scale) including the integral scales of K spatial correlation, the anisotropy ratio, the indicator correlation scales, and the contrast in mean K between facies defined at different scales. The results show that the anisotropy ratio and integral scales of K have negligible effect upon the longitudinal dispersion of sorbing solutes. Furthermore, dispersion of sorbing solutes depends mostly on indicator correlation scales, and the contrast of the mean conductivity between units at different scales.  相似文献   

13.
Reactive contaminant transport models are used by hydrologists to simulate and study the migration and fate of industrial waste in subsurface aquifers. Accurate transport modeling of such waste requires clear understanding of the system’s parameters, such as sorption and biodegradation. In this study, we present an efficient sequential data assimilation scheme that computes accurate estimates of aquifer contamination and spatially variable sorption coefficients. This assimilation scheme is based on a hybrid formulation of the ensemble Kalman filter (EnKF) and optimal interpolation (OI) in which solute concentration measurements are assimilated via a recursive dual estimation of sorption coefficients and contaminant state variables. This hybrid EnKF-OI scheme is used to mitigate background covariance limitations due to ensemble under-sampling and neglected model errors. Numerical experiments are conducted with a two-dimensional synthetic aquifer in which cobalt-60, a radioactive contaminant, is leached in a saturated heterogeneous clayey sandstone zone. Assimilation experiments are investigated under different settings and sources of model and observational errors. Simulation results demonstrate that the proposed hybrid EnKF-OI scheme successfully recovers both the contaminant and the sorption rate and reduces their uncertainties. Sensitivity analyses also suggest that the adaptive hybrid scheme remains effective with small ensembles, allowing to reduce the ensemble size by up to 80% with respect to the standard EnKF scheme.  相似文献   

14.
A key challenge for predictive modeling of transverse mixing and reaction of solutes in groundwater is to determine values of transverse dispersivity (αT)(αT) in heterogeneous flow fields that accurately describe mixing and reaction at the pore scale. We evaluated the effects of flow focusing in high permeability zones on mixing enhancement using experimental micromodel flow cells and pore-scale lattice-Boltzmann-finite-volume model (LB-FVM) simulations. Micromodel results were directly compared to LB-FVM simulations using two different pore structures, and excellent agreement was obtained. Six different flow focusing pore structures were then systematically tested using LB-FVM, and both analytical solutions and a two-dimensional (2D) continuum-scale model were used to fit αTαT values to pore-scale results. Pore-scale results indicate that the overall rate of mixing-limited reaction increased by up to 40% when flow focusing occurred, and it was greater in pore structures with longer flow focusing regions and greater porosity contrast. For each pore structure, αTαT values from analytical solutions of transverse concentration profiles or total product at a given longitudinal location showed good agreement for nonreactive and reactive solutes, and values determined in flow focusing zones were always smaller than those downgradient after the flow focusing zone. Transverse dispersivity values from the 2D continuum model were between values within and downgradient from the flow focusing zone determined from analytical solutions. Also, total product and transverse concentration profiles along the entire pore structure from the 2D continuum model matched pore scale results. These results indicate that accurate quantification of pore-scale flow focusing with transverse dispersion coefficients is possible only when the entire flow and concentration fields are considered.  相似文献   

15.
Pump‐and‐treat systems can prevent the migration of groundwater contaminants and candidate systems are typically evaluated with groundwater models. Such models should be rigorously assessed to determine predictive capabilities and numerous tools and techniques for model assessment are available. While various assessment methodologies (e.g., model calibration, uncertainty analysis, and Bayesian inference) are well‐established for groundwater modeling, this paper calls attention to an alternative assessment technique known as screening‐level sensitivity analysis (SLSA). SLSA can quickly quantify first‐order (i.e., main effects) measures of parameter influence in connection with various model outputs. Subsequent comparisons of parameter influence with respect to calibration vs. prediction outputs can suggest gaps in model structure and/or data. Thus, while SLSA has received little attention in the context of groundwater modeling and remedial system design, it can nonetheless serve as a useful and computationally efficient tool for preliminary model assessment. To illustrate the use of SLSA in the context of designing groundwater remediation systems, four SLSA techniques were applied to a hypothetical, yet realistic, pump‐and‐treat case study to determine the relative influence of six hydraulic conductivity parameters. Considered methods were: Taguchi design‐of‐experiments (TDOE); Monte Carlo statistical independence (MCSI) tests; average composite scaled sensitivities (ACSS); and elementary effects sensitivity analysis (EESA). In terms of performance, the various methods identified the same parameters as being the most influential for a given simulation output. Furthermore, results indicate that the background hydraulic conductivity is important for predicting system performance, but calibration outputs are insensitive to this parameter (KBK). The observed insensitivity is attributed to a nonphysical specified‐head boundary condition used in the model formulation which effectively “staples” head values located within the conductivity zone. Thus, potential strategies for improving model predictive capabilities include additional data collection targeting the KBK parameter and/or revision of model structure to reduce the influence of the specified head boundary.  相似文献   

16.
Flow‐through column experiments were carried out to investigate the influence of pH on the sorption of three phenols (2‐methyl‐4, 6‐dinitrophenol, 2, 4, 6‐trichlorophenol, pentachlorophenol) onto a natural sandy aquifer material collected from a bank filtration site of River Elbe, Germany. For the phenols investigated, an increase in sorption (retardation) with decreasing pH is observed indicating a stronger sorption of the neutral species in comparison to that of the anions formed by dissociation. The anions of 2‐methyl‐4, 6‐dinitrophenol and 2, 4, 6‐trichlorophenol do not show significant sorption. On the contrary, pentachlorophenol showed sorption not only in neutral form but also in ionic form significantly which should be taken into account while assessing the fate and transport of such compound. A linear model based on the degree of protonation (calculated from pH and pKa) can be used to resolve the apparent (observed) sorption coefficient (Kd, app) into its neutral (Kd, n) and ionised (Kd, i) components. Knowing pKa, Kd, n, and Kd, i the apparent sorption coefficient for pH values other than experimentally investigated can be predicted.  相似文献   

17.
Historical seismic data and seismogenic information are quite scarce for the low seismicity region, and modeling the parameters uncertainties based on probabilistic model is suspicious. The convex set theory-based seismic hazard analysis approach is proposed. The uncertainties of b value, the annual occurrence rate v and the upper bound magnitude Mu are described by the envelop bound convex model and the ellipsoidal bound convex model. Convex analysis method and China probabilistic seismic hazard analysis methodology are combined to perform a bound seismic hazard analysis for Ningbo city, China. The seismic intensity interval obtained using the bound seismic hazard analysis is compared with that calculated using China probabilistic seismic hazard analysis methodology. The sensitivity analysis indicates that the interval of seismic intensity is most sensitive to the annual occurrence rate v. Furthermore, the different convex models have little effect on the interval of seismic intensity.  相似文献   

18.
To reduce the complexity and save computation time, an isotropic and a scalar dispersion model are explored and compared to the anisotropic advection/dispersion model to study the interstitial flow in a stream and lake sediment induced by a periodic pressure wave. In these systems, the solute transport is controlled by the ratio (R = a/(LS)) of the pressure wave steepness (a/L) to the stream slope (S), and the dispersivity ratio (λ = αL/L) that measures the longitudinal dispersivity (αL) relative to the pressure wave length (L). Through a series of numerical experiments, the conclusion is reached that a scalar dispersion model can be applied with satisfactory results for advection-dominated transport, i.e. when R ?  0.1 and λ ? 0.01, or λ ? 0.0001, i.e. Peclet number (Pe) ? 10000; an isotropic dispersion model can be applied when R ? 10 or λ ? 0.001, and the full anisotropic advection/dispersion model has to be applied when R > 10 and λ > 0.001.  相似文献   

19.
Ground water scientists have made significant advances in understanding the soil interactions, hydrogeology, fate and transport, and subsurface microbiology of aromatic hydrocarbons (BTEX) in aquifer systems. It is now generally recognized that a major factor responsible for the attenuation and mass reduction of BTEX in plumes is the widespread occurrence of hydrocarbon biodegradation by indigenous soil microorganisms in aquifer material. Most well-studied BTEX plumes that develop from the accidental release of gasoline fuels contain low levels of soluble hydrocarbons (< 1 to 5000 ppb) and have been shown to be spatially confined because of natural biotransformation mechanisms. These in situ processes are controlled by source and aquifer characteristics, permeability, sorption, and geochemical properties of the aquifer. Many laboratory subsoil-ground water microcosms and field studies (10 to 20 C) have demonstrated the rapid biodecay (1 to SO percent/day for microcosms and 0.5 to 1.5 percent/day for plumes) of these aromatic compounds under primarily aerobic conditions (i.e., those with sufficient dissolved oxygen). The ability to implement ground water bioremediation will depend upon our understanding of source control and aquifer recharge effects on the spatial distribution of plumes. In addition, estimating the biodegradation of sorbed BTEX, determining limits and potential for in situ biostimulation of soluble plumes, and establishing data requirements for predictive modeling of natural attenuation will be useful for this remediation technology. The use of these tools to manage ground water quality appears to represent the most practical alternative, particularly for low-risk ground water supplies.  相似文献   

20.
We investigate the effects of vertical relative motion between gas and liquid on eruption styles by formulating a model for 1-dimensional steady flow in volcanic conduits. As magma ascends and decompresses, volatiles exsolve and volume fraction of gas increases. As a result, magma fragmentation occurs and the flow changes from bubbly flow to gas-pyroclast flow. In our model, a transitional region (‘permeable flow region’) is introduced between the bubbly flow region and the gas-pyroclast flow region. In this region, both the gas and the liquid are continuous phases, allowing the efficient vertical escape of gas through the permeable structure. We describe the features of conduit flow with relative motion of gas and liquid using non-dimensional numbers α, γ and ε. The parameter α represents the ratio of effects of wall friction to gravitational load, and is proportional to magma flow rate. The parameter γ represents the degree of decompression for the gas-pyroclast flow to reach the sound velocity at α = 1, and is proportional to rc2/μ for given magma temperature and initial volatile content, where rc is conduit radius and μ is liquid viscosity. The parameter ε is defined as the ratio of liquid–wall friction force to liquid–gas interaction force in the permeable flow region, and represents the efficiency of gas escape from magma. The values of γ and ε are determined only by magma properties and geological conditions such as liquid viscosity, magma permeability and conduit radius. We formulate a 1-dimensional steady-state conduit flow model to find non-dimensional magma flow rate α as a function of magma properties and geological conditions (e.g., γ and ε) under given boundary conditions. When the relative motion is taken into account with the assumption that magma fragmentation occurs when the gas volume fraction reaches some critical values, the pressure at the fragmentation level (Pf) decreases as the magma flow rate (α) decreases or the efficiency of gas escape (ε) increases, because gas escape suppresses the increase in the gas volume fraction accompanying magma ascent. When ε is so large that Pf is below the atmospheric pressure (Pa), the flow reaches the vent before fragmentation at low α. On the other hand, when ε is so small that Pf is greater than Pa, the flow reaches the vent after fragmentation at high α. These steady-state solutions of the flow at low and high α correspond to effusive and explosive eruptions, respectively. We present a graphical method to systematically find α. On the basis of the graphical method, a simple regime map showing the relationship between the assemblage of the solutions of conduit flow and the magma properties or the geological conditions is obtained.  相似文献   

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