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1.
In this paper, we report that the ratio of broadband energy (0.01?C2?Hz) to high-frequency energy (0.3?C2?Hz), E r, estimated from regional seismograms of India, might be a useful parameter in estimating tsunami potential of earthquakes in the Sumatra?CAndaman region. E r is expected to be sensitive to the depth as well as to the source characteristics of an earthquake. Since a shallow and slow earthquake has a greater tsunamigenic potential, E r may be a useful diagnostic parameter. We base our analysis on broadband seismograms of the great earthquakes of Sumatra?CAndaman (2004, M w?~?9.2) and Nias (2005, M w 8.6), 41 of their aftershocks, and the earthquakes of north Sumatra (2010, M w 7.8) and Nicobar (2010, M w 7.4) recorded at VISK, a station located on the east coast of India. In the analysis, we also included the two recent, great strike-slip earthquakes of north Sumatra (2012, M w 8.6, 8.2) recorded at VISK and three south Sumatra earthquakes (2007, M w 8.5; 2007, M w 7.9; 2010, M w 7.8) recorded at PALK, a station in Sri Lanka. We find that E r is a function of depth; shallower earthquakes have higher E r values than the deeper ones. Thus, E r may be indicative of tsunamigenic potential of an earthquake. As M w and E r increase so does the tsunami potential. In addition to the parameter E r, the radiated seismic energy, E s, may be estimated from the regional seismograms in India using empirical Green??s function technique. The technique yields reliable E s for the great Sumatra and Nias earthquakes. E r and E s computed from VISK data, along with M w and focal mechanism, may be useful in estimating tsunami potential along the east coast of India from earthquakes in the Sumatra?CAndaman region in less than ~20?min.  相似文献   

2.
Magnetic analysis and 57Fe Mössbauer spectroscopy were used to find characteristic properties of obsidian samples collected from various localities in the Mediterranean area. Magnetic hysteresis parameters of ≈ 30 different obsidian samples, recorded at 294 K, and plotted in the form σ r /σ s versus H c /H cr (σ r =saturation remanent magnetization, σ s =saturation magnetization of ferrimagnetic phases in the obsidian samples, H c =coercive force, H cr =remanent coercive force) cluster in certain areas of the plot for obsidian samples of a given region. This property results from the formation of ferrimagnetic ore grains of various grain sizes, which appear to be Fe3O4-rich spinels (Curie temperatures T c ≈520–580°C), during the rapid cooling process of the silica-rich magma. For single domain, pseudosingle domain and multidomain particles of magnetic minerals, corresponding to different grain sizes, the data points are usually in different areas of the plot. The results show that there is obviously a characteristic difference in the ore grain size and in the grain size distribution for obsidian samples from different regions. 57Fe Mössbauer absorption spectra revealed two distinct kinds of patterns, characterized by contributions from Fe2+ and Fe3+ cations preferentially inside the glassy matrix. The poor resolution of the spectra precludes the application of this method for identification purposes. The Mössbauer parameters of quadrupole splitting, isomer shift and linewidth are compatible with the respective values for Fe2+ and Fe3+ cations in alkali and alkaline-earth silicate glasses.  相似文献   

3.
{M[UO2¦AsO4]2 · nH2O} with M=Cu2+, Co2+, Ni2+ has been synthesized from reagent grade chemicals and by ion exchange of trögerite {HUO2AsO4 · 4 H2O}. Synthetic meta-zeunerite (M=Cu2+), meta-kirchheimerite (M=Co2+) and nickel-uranylarsenate are all tetragonal. The cell parameters determined from Guinier-Hägg diffraction data for {Cu[UO2¦AsO4]2 · 8 H2O} are a=b=7.10 Å and c=17.42 Å, with Z=2 and the measured density 3.70 g cm?3. The cell parameters for {Co[UO2¦AsO4]2 · 7 H2O} and {Ni[UO2¦AsO4]2 · 7 H2O} are a=b=20.25 Å and c=17.20 Å, with Z=16 and the measured density 3.82 and 3.74 g cm?3, respectively. The solubility products for synthetic Cu-, Co- and Ni-uranylarsenate at 25° C are 10?49.20, 10?45.34 and 10?45.10, respectively. The zeta-potential remains negative between pH=2 and pH=9 and is strongly affected by the presence of different cations.  相似文献   

4.
Bond critical point properties calculated for the MN bonds in a number of geometry optimized nitride molecules containing first- and second-row M cations are compared with those calculated for a number of oxide molecules. As reported for the oxides, the value of the electron density, ρ(r c ), at the bond critical points, r c , increases with decreasing bond length while for the more electronegative cations, the local energy density, H(r c ) decreases nonlinearly in value as the relative electronegativities of the M-cations, χ M , tend to increase. In the majority of cases, χM, |λ1|/λ3 and ∇2ρ(r c ) increase with decreasing minimum energy bond lengths. The bond lengths adopted by the molecules are indicated to be an important determinant of the critical point properties of the electron density distributions. The relative electronegativities derived from the electron density distributions of the nitrides agree with those derived for the oxides and Pauling’s electronegativities to within ∼5%, on average. Received: 3 February 1997 / Revised, accepted: 11 July 1997  相似文献   

5.
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6.
 Minimum energy geometries and electron density distributions, ϱ(r), for ∼40 polyatomic oxide molecules containing first and second row M-cations have been calculated at the Hartree-Fock level with a 6-311++G** basis set. The nature of the bonded interactions in these molecules is examined in terms of the relative electronegativities, χ M , of the M-cations and the properties of the electron density distribution, ϱ(r c ), evaluated at the bond critical points, r c , along each MO bond. As ϱ(r c ) and the Laplacian of ϱ(r c ) increase, χ M increases indicating an increase in the covalent character of the bonded interactions between M and O. The ratios of the curvatures of ϱ(r c ) indicate that the NO bond is predominantly covalent, that the CO and SO bonds are of intermediate type and that the remaining MO bonds are indicated to be predominantly ionic in character. A comparison of the critical point properties of ϱ(r c ) and χ M indicates that the minimum energy MO bond length is an important determinate of the properties of ϱ(r c ) and the character of the MO bonds. On the other hand, values of the local energy density, H(r c ), indicate that the LiO, BeO, NaO, MgO and AlO bonds are predominantly ionic and that the BO, CO, NO, SiO, PO and SO bonds are predominantly covalent in character. The χ M -values provided by the properties of ϱ(r c ) indicate that the covalent component of a bond increases with decreasing bond length, coordination number and increasing bond strength. Each MO bond seems to represent a unique entity and to possess a distinct set of ϱ(r c ) properties, the distinction being greater for the more electronegative cations. The bonded radius of the oxide ion, r b (O), and the χ M -values determined from ϱ(r c ) correlate with values determined from promolecule electron density distributions. In addition, r b (O) and χ M -values determined from experimental electron density distributions for crystals correlate with values determined from procrystal electron density distributions. The number of critical points and bond paths are modeled rather faithfully by procrystal and promolecule electron density distributions, despite the neglect of the binding forces in their constructions. Received: October 15, 1996/Revised, accepted: February 10, 1997  相似文献   

7.
A simple method is developed to determine seismic moments of earthquakes. The method is qualified through criteria such as simplicity of calculations, coverage of wide magnitude range, and insensitivity to detailed instrumental response. The method is applied to 163 major earthquakes which occurred underneath Japan and the Japan Sea in the time from 1926 to 1977. Magnitudes of these earthquakes, which have been determined by the Japan Meteorological Agency, (MJMA) cover the range from 4.3 to 7.5. At first, source spectra are analyzed through a very simple way introducing two new parameters: characteristic period Tc and seismic-moment factor Mc. The former is defined as an average value of apparent periods of seismic waves with the maximum trace amplitude at many stations. The latter is an average of products of maximum trace amplitude and its apparent period multiplied by epicentral distance. It is shown that Tc corresponds to the period of the corner frequency of an earthquake and Mc to the seismic-moment density at the period of Tc. A scaling model of earthquake source spectra is presented which satisfies the empirical relations between the surface-wave magnitude Ms and MJMA, and MJMA and the body-wave magnitude mb. Those relations are independent of the Gutenberg and Richter relation between Ms and mb, because MJMA is determined from maximum amplitudes of seismic waves with a period of about 4 sec. The static seismic moment of each earthquake can be estimated from calculated Mc using the source spectra of the scaling model. Seismic moments of 18 earthquakes determined by conventional analyses from near- and/or far-field observations are consistent with static seismic moments thus estimated over the range from 2 × 1023 to 3 × 1027 dyne cm. This shows the potential in practice of the present method, especially in the routine processing of seismic data.  相似文献   

8.
The scaling relationships for stress drop and corner frequency with respect to magnitude have been worked out using 159 accelerograms from 34 small earthquakes (M w 3.3–4.9) in the Kachchh region of Gujarat. The 318 spectra of P and S waves have been analyzed for this purpose. The average ratio of P- to S-wave corner frequency is found to be 1.19 suggestive of higher corner frequency for P wave as compared to that for S wave. The seismic moments estimated from P waves, M 0(P), range from 1.98 × 1014 N m to 1.60 × 1016 N m and those from S waves, M 0(S), range from 1.02 × 1014 N m to 3.4 × 1016 N m with an average ratio, M 0(P)/M 0(S), of 1.11. The total seismic energy varies from 1.83 × 1010 J to 2.84 × 1013 J. The estimated stress drop values do not depend on earthquake size significantly and lie in the range 30–120 bars for most of the events. A linear regression analysis between the estimated seismic moment (M 0) and corner frequency (f c) gives the scaling relation M 0 f c 3  = 7.6 × 1016 N m/s3. The proposed scaling laws are found to be consistent with similar scaling relations obtained in other seismically active regions of the world. Such an investigation should prove useful in seismic hazard and risk-related studies of the region. The relations developed in this study may be useful for the seismic hazard studies in the region.  相似文献   

9.
The uncertainty in the spatial distributions of consolidation settlement (s c) and time (t p) for Songdo New City is evaluated by using a probabilistic procedure. Ordinary kriging and three theoretical semivariogram models are used to estimate the spatial distributions of geo-layers which affect s c and t p in this study. The spatial map of mean (μ) and standard deviation (σ) for s c and t p are determined by using a first-order second moment method based on the evaluated statistics and probability density functions (PDFs) of soil properties. It is shown that the coefficients of variation (COVs) of the compression ratio [C c/(1 + e 0)] and the coefficient of consolidation (c v) are the most influential factors on the uncertainties of s c and t p, respectively. The μ and σ of the s c and t p, as well as the probability that s c exceeds 100 cm [P(s c > 100 cm)] and the probability that t p exceeds 36 months [P(t p > 36 months)] in Sect. 1, are observed to be larger than those of other sections because the thickness of the consolidating layer in Sect. 1 is the largest in the entire study area. The area requiring additional fill after the consolidation appears to increase as the COV of C c/(1 + e 0) increases and as the probabilistic design criterion (α) decreases. It is also shown that the area requiring the prefabricated vertical drains installation increases as the COV of c v increases and as the α decreases. The design procedure presented in this paper could be used in the decision making process for the design of geotechnical structures at coastal reclamation area.  相似文献   

10.
A complete and homogeneous magnitude earthquake catalogue spanning the period 1900 to 2010 was created. The catalogue covers the area 29° to 37.5° N and 39° to 48° E. Entries in the new earthquake catalogue were cross checked and additions made from various sources of earthquake records to ensure that repetitions are not included in this analysis. Events were considered duplicates if they had a time difference of 10 s or less and space origin difference of 0.5° or less. In a given set of duplicate events, an event, which had a magnitude and International Seismological Center source, was retained as the record of the event. The unified magnitude scale, the moment magnitude (M w), was applied throughout the catalogue. The M w for 18 events was reported. The M w for other events was estimated using empirical relations between m b, M s, M L, and M w. Magnitude of completeness, M c, was estimated using the maximum curvature. It was 4.3 M w. Finally, a list of 213 events from 1900 to 2010 with M w?≥?4.3 is presented. The list is considered complete for the period from 1962 to 2010.  相似文献   

11.
Single-crystal study of the structure (R = 0.0268) was performed for garyansellite from Rapid Creek, Yukon, Canada. The mineral is orthorhombic, Pbna, a = 9.44738(18), b = 9.85976(19), c = 8.14154(18) Å, V = 758.38(3) Å3, Z = 4. An idealized formula of garyansellite is Mg2Fe3+(PO4)2(OH) · 2H2O. Structurally the mineral is close to other members of the phosphoferrite–reddingite group. The structure contains layers of chains of M(2)O4(OH)(H2O) octahedra which share edges to form dimers and connected by common edges with isolated from each other M(1)O4(H2O)2 octahedra. The neighboring chains are connected to the layer through the common vertices of M(2) octahedra and octaahedral layers are linked through PO4 tetrahedra.  相似文献   

12.
Soil layering has a pivotal role on the behavior and propagation of seismic waves, hence the ground response during seismic loading. Parametric study to estimate the effect of soil layering on ground response parameters is of prime importance considering the engineering significance of structure founded in seismic zone; nonetheless, it is yet to be well understood. The objective of this study was to investigate the effect of soil layering and soil properties on the ground response parameters. One-dimensional linear ground response analysis was conducted with variation in soil layer parameters including impedance ratio (?? z ), layer thickness (d r ), and damping ratio (D). The acceleration time history of the Bhuj Earthquake (M w ?=?7.7), India, was used in the analysis. The results obtained from the analysis were presented as variation of ground response parameters such as spectral acceleration (SA), amplification ratio (M) with the soil layer parameters. Results showed higher values of SA at lower D and then decreased with increase in D, that in fact depict the resistance offered to the particle oscillation at comparatively higher values of D. Similarly, variation in SA and M was very less or negligible when the ?? z was varied from 1 to 3 and the d r equal to 0.2, while for d r greater than 0.2 the variation increased with ?? z and d r . The outcome from the parametric study presented in this paper clearly demonstrates the significance of ?? z , D, and d r of the soil layers on the ground response parameters.  相似文献   

13.
We have modeled the Hα, Hβ, and Hγ (Balmer series), P14 (Paschen series), and Brγ (Brackett series) hydrogen lines formed in the inner regions of the accretion disk around the Herbig Ae star UX Ori. Our calculations are based on spectra obtained with the Nordic Optical Telescope (NOT) and the IRTF. We computed a grid of non-LTE models for a radiating area in the accretion disk and determined the basic parameters of the lines using the method of Sobolev. Analyzing the theoretical and observed line profiles, equivalent widths, and luminosities, we have estimated the accretion rate and electron-temperature distribution in the inner parts of the accretion disk. The accretion rate of UX Ori is about $\dot M_a = (3 - 10) \times 10^{ - 9} M_ \odot /yr$ , and the temperature distribution is consistent with the power law T(r)=T(r *)(r/r *)?1/n , where the electron temperature near the stellar surface T(r *) is 15000–20000 K and the power-law index n≈2–3 is about two to three. The resulting value for $\dot M_a $ eliminates problems connected with the application of magnetospheric accretion models to Herbig Ae/Be stars. Another important conclusion is that, at the estimated accretion rate, the energy release is substantially (about two orders of magnitude) lower than the stellar luminosity. Therefore, the optical radiation of UX Ori accretion disks cannot appreciably contribute to the observed variability of these stars, which must be determined mainly by variability in the circumstellar extinction.  相似文献   

14.
Hydrotalcite-like solid solutions have been synthesized by coprecipitation in basic solutions with variable SO 4 2? /CO 3 2? ratios. Chemical determination of CO 3 2? in the interlayer was impossible because of the presence of minor hydromagnesite. SO 4 2? was determined both by chemical analysis and X-ray photoelectron spectroscopy (XPS), the two methods giving similar results. A Raman spectrometry gave additional data on the SO 4 2? /CO 3 2? ratio. Then, the stoichiometry of the anionic interlayers, X s , X c , and X OH were determined, and the influence of X s on the c′ parameter (increasing from c′=7.97 Å to c′=8.63 Å between X s =0 and X s =1) was characterized. In addition, a partitioning curve of SO 4 2? and CO 3 2? between aqueous solutions and hydrotalcite-like compounds was established. Its general shape strongly suggests a miscibility gap between a sulfate-rich end and a carbonate-rich solid solution (maximum SO 4 2? /CO 3 2? about 0.2). This result explains why most of the hydrotalcites synthesized during experimental alteration of basaltic glasses by sea-water (a sulfate-rich solution) are CO 3 2? -rich solid solutions.  相似文献   

15.
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16.
We have measured the surface controlled dissolution rates of natural calcium carbonate minerals (limestone and marble) in H2O–CO2 solutions by using free drift batch experiments under closed system conditions with respect to CO2, at 10°C with an initial partial pressure of carbon dioxide of 5 · 10−2 atm. All experiments revealed reaction rates F, which can be described by the empirical relation: Fn1 = kn1 · (1 − c/ceq)n1 for c < cs, which switches to a higher order n2 for calcium concentrations c ≥ cs described by Fn2 = kn2 · (1 − c/ceq)n2. kn1 and kn2 are rate constants in mmole/(cm2 · s), ceq is the equilibrium concentration with respect to calcite. The values of the constants n1, n2, kn1, kn2 and cs depend on the V/A ratio employed, where V is the volume of the solution and A is the surface area of the reacting mineral. Different calcium carbonate minerals exhibit different values of the kinetic constants. But generally with increasing V/A, there is a steep variation in the values of all kinetic constants, such that the rates are reduced with increasing V/A ratio. Finally with sufficiently large V/A these values become constant. These results are explained by assuming intrinsic inhibitors in the bulk of the mineral. During dissolution these are released from the calcite matrix and are adsorbed irreversibly at the reacting surface, where they act as inhibitors. The thickness d of the mineral layer removed by dissolution is proportional to the V/A ratio. The amount of inhibitors released per surface area is given by d · cint, where cint is their concentration in the bulk of the mineral. At low thicknesses up to ≈3 · 10−4 cm in the investigated materials, the surface concentration of inhibitors increases until saturation is attained for thicknesses above this value.To analyze the surface concentration and the type of the inhibitors we have used Auger spectroscopy, which revealed the presence of aluminosilicate complexes at the surface of limestone, when a thickness of d ≈ 10−3 cm had been removed by dissolution. In unreacted samples similar signals, weaker by one order of magnitude, were observed. Depth profiles of the reacted sample obtained by Ar-ion sputtering showed the concentration of these complexes to decrease to the concentration observed in the unreacted sample within a depth of about 10 nm. No change of the concentration with depth was observed in unreacted samples. These data suggest that complexes of aluminosilicates act as inhibitors, although other impurities cannot be excluded.  相似文献   

17.
Magnetic properties of the Chelyabinsk meteorite: Preliminary results   总被引：1，自引：0，他引：1  
This paper presents the distribution of magnetic susceptibility, χ0, in fragments of the Chelyabinsk ordinary chondrite (LL5, S4, W0, fall of February 15, 2013) from the collection of the Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, and results obtained by standard magnetic techniques for the meteorite material, including thermomagnetic analysis, measurements of natural remanent magnetization (NRM) and saturation isothermal remanent magnetization (SIRM), as well as the spectra of their alternating field demagnetization at amplitudes up to 170 mT, measurements of hysteresis loops and back-field remanence demagnetization curves at temperatures from 10 K to 700°C etc. The mean logχ0 values for the light-colored (main) lithology of the meteorite material and impact-melt breccia from our collection are 4.54 ± 0.10 (n = 66) and 4.65 ± 0.09 (n = 38) (×10?9 m3/kg), respectively. According to international magnetic classification of meteorites, Chelyabinsk falls within the range of LL5 chondrites. The mean metal content was estimated from the saturation magnetization, M s, of the light- and dark-colored lithologies as 3.7 and 4.1 wt %, respectively. Hence, the dark lithology is richer in metal. The metal grains are multidomain at room temperature and show low coercive force, B c (<2 mT) and remanent coercive force, B cr (15–23 mT). The thermomagnetic analyses of the samples showed that the magnetic properties of the Chelyabinsk meteorite are controlled mainly by taenite and kamacite at temperatures >75 K. In the temperature range below 75 K, magnetic properties are controlled by chromite; the magnetic hardness of the samples is maximal at 10 K and equals to 606 and 157 mT for the light- and dark-colored lithologies, respectively.  相似文献   

18.
Geomechanical models are often used to predict the impact on land surface of fluid withdrawal from deep reservoirs, as well as investigating measures for mitigation. The ability to accurately simulate surface displacements, however, is often impaired by limited information on the geomechanical parameters characterizing the geological formations of interest. In this study, we employ an ensemble smoother, a data assimilation algorithm, to provide improved estimates of reservoir parameters through assimilation of measurements of both horizontal and vertical surface displacement into geomechanical model results. The method leverages the demonstrated potential of remote sensing techniques developed in the last decade to provide accurate displacement data for large areas of the land surface. For evaluation purposes, the methodology is applied to the case of a disk‐shaped reservoir embedded in a homogeneous, isotropic, and linearly elastic half space, subject to a uniform change in fluid pressure. Multiple sources of uncertainty are investigated, including the radius, R, the thickness, h, and the depth, c, of the reservoir; the pore pressure change, Δp; porous medium's vertical uniaxial compressibility, cM, and Poisson's ratio, ν, and the ratio, s, between the compressibilities of the medium during loading and unloading cycles. Results from all simulations show that the ensemble smoother has the capability to effectively reduce the uncertainty associated with those parameters to which the variability and the spatial distribution of land surface displacements are most sensitive, namely, R, c, cM, and s. These analyses demonstrate that the estimation of these parameters values depends on the number of measurements assimilated and the error assigned to the measurement values. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

19.
A new microscope vacuum heating stage and gas analyzer has been developed for measurement of H2O, CO2, SO2, and noncondensable gas (H2, CO, N2, Ar, CH4, etc.) evolved from samples, particularly natural glass, at temperatures up to 1280°C. The gas evolved upon heating to 1280δC is collected in a liquid nitrogen cold trap. Gas components are identified by the characteristic vapor pressure and temperature ranges over which solid and vapor are in equilibrium during sublimation of individual components. The masses of CO2, SO2, and H2O derived from samples and blanks are calculated using the ideal gas law, the molecular weights of the components, and the gauge constant (i.e. the ratio of the number of moles of a gas to its partial pressure in the constant volume). Results obtained by repeated determinations of H2O, CO2, and SO2 evolved from a submarine basaltic glass from Kilauea volcano, Hawaii, (average sample mass = 3 × 10?3 g) gave probable errors for the determinations of H2O (0.23%), CO2 (0.025%), and S (0.071%) equal to 4, 10, and 8% respectively, of the concentrations. Determinations of H2O in smaller samples of H2O-poor basaltic pumice show a linear proportionality (0.063%) between the measured H2O and the sample mass over the range 0.1 × 10?6 to 1.7 × 10?6 g H2O. Comparisons of H2O determinations by this technique with those obtained by Penfield, gas chromatic, microcoulometric, and vacuum fusion techniques used elsewhere show reasonably good agreement. Determinations of SO2 by this technique agree reasonably well X-ray fluorescence and electron microprobe determinations of sulfur. Determinations of CO2 by the present technique are reproducible but cannot be compared directly to measurements made in other labs because of differences in samples analyzed. The principle advantages of this analytical technique are the very small sample required, the simultaneous determination of H2O, CO2, SO2 and noncondensable gas, the avoidance of calibration procedures dependent on chemical standards, and the visual observations that can be made during sample outgassing.  相似文献   

20.
Evolutionary properties of the radial distribution of the gas density in the envelopes of 12 Galactic planetary nebulae are discussed. An evolutionary relationship between the maximum gas density n(r)max and the radius of the ionized segment of the nebula r c is derived. The ionized-gas masses in the envelopes of these nebulae M i /M ⊙ are determined. The relationship between the mass M i /M ⊙ and radius of the nebula is derived. The value of M i /M ⊙ changes by approximately a factor of 275 during a nebula’s evolution, ranging from 0.0038M ⊙ for “young” nebulae (IC 5117) to 1.05M ⊙ for “old” nebulae (NGC 7293). Distances to the nebulae are determined based on calculated photoionization models. These distances are in good agreement with those obtained independently byMalkov and with the distance to the planetary nebula K648 in the Galactic star cluster M15.  相似文献   

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