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1.
Application of a confluence‐based sediment‐fingerprinting approach to a dynamic sedimentary catchment,New Zealand 
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下载免费PDF全文 Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
2.
J. C. Varekamp G. B. Pasternack G. L. RoweJr. 《Journal of Volcanology and Geothermal Research》2000,97(1-4)
A database of 373 lake water analyses from the published literature was compiled and used to explore the geochemical systematics of volcanic lakes. Binary correlations and principal component analysis indicate strong internal coherence among most chemical parameters. Compositional variations are influenced by the flux of magmatic volatiles and/or deep hydrothermal fluids. The chemistry of the fluid entering a lake may be dominated by a high-temperature volcanic gas component or by a lower-temperature fluid that has interacted extensively with volcanic rocks. Precipitation of minerals like gypsum and silica can strongly affect the concentrations of Ca and Si in some lakes. A much less concentrated geothermal input fluid provides the mineralized components of some more dilute lakes. Temporal variations in dilution and evaporation rates ultimately control absolute concentrations of dissolved constituents, but not conservative element ratios.Most volcanic lake waters, and presumably their deep hydrothermal fluid inputs, classify as immature acid fluids that have not equilibrated with common secondary silicates such as clays or zeolites. Many such fluids may have equilibrated with secondary minerals earlier in their history but were re-acidified by mixing with fresh volcanic fluids. We use the concept of ‘degree of neutralization’ as a new parameter to characterize these acid fluids. This leads to a classification of gas-dominated versus rock-dominated lake waters. A further classification is based on a cluster analysis and a hydrothermal speedometer concept which uses the degree of silica equilibration of a fluid during cooling and dilution to evaluate the rate of fluid equilibration in volcano-hydrothermal systems. 相似文献
3.
Geochemical precursors to seismic activity 总被引：7，自引：0，他引：7
Donald Thomas 《Pure and Applied Geophysics》1988,126(2-4):241-266
Studies of earthquake precursory phenomena during the last several decades have found that significant geophysical and geochemical changes can occur prior to intermediate and large earthquakes. Among the more intensely investigated geochemical phenomena have been: (1) changes in the concentrations of dissolved ions and gases in groundwaters and (2) variations in the concentrations of crustal and mantle volatiles in ground gases. The concentration changes have typically showed no conanomalies trend (either increasing or decreasing), and the spatial and temporal distribution of the observed anomalies have been highly variable. As a result, there is little agreement on the physical or chemical processes responsible for the observed anomalies. Mechanisms proposed to account for precursory groundwater anomalies include ultrasonic vibration, pressure sensitive solubility, pore volume collapse, fracture induced increases in reactive surfaces, and aquifer breaching/fluid mixing. Precursory changes in soil gas composition have been suggested to result from pore volume collapse, micro-fracture induced exposure of fresh reactive silicate surfaces, and breaching of buried gas-rich horizons. An analysis of the available field and laboratory data suggests that the aquifer breaching/fluid mixing (AB/FM) model can best account for many of the reported changes in temperature, dissolved ion and dissolved gas concentrations in groundwater. Ultrasonic vibration and pressure sensitive solubility models cannot reasonably account for the geochemical variations observed and, although the pore collapse model could explain some of the observed chemical changes in groundwater and ground gas, uncertainties remain regarding its ability to generate anomalies of the magnitude observed. Other geochemical anomalies, in particular those associated with hydrogen and radon, seem best accounted for by increases in reactive surface areas (IRSA model) that may accompany precursory deformation around the epicenter of an impending earthquake. Analysis of the probable response of these models to the earthquake preparation process, as well as to other environmental factors, suggests that geochemical monitoring programs can provide information that may be valuable in forecasting the probability of an earthquake; however, because of the complexity of the earthquake preparation process, the absolute prediction of seismic events using geochemical methods alone, does not presently appear to be feasible. 相似文献
4.
In this study, the interactive effects of four independent variables (initial chemical oxygen demand (COD) concentration, rotational velocity, temperature, and retention time) on the sulfide generation process in municipal wastewater were investigated. The process was modeled and analyzed with the variables in a series batch experiments. Experiments were conducted based on a central composite face‐centered design and analyzed using response surface methodology. The region of exploration for the process was taken as the area enclosed by COD (250 and 650 mg/L), rotational velocity (40 and 200 rpm), temperature (16 and 28°C), and retention time (2 and 40 h) boundaries. Eleven dependent parameters were either directly measured or calculated as response. The most influential variable on H2S (g) production was found to be retention time. The results showed that simultaneous increase in temperature and rotational velocity caused an increasing trend in the amount of H2S (g) emitted. Total sulfide was decreased by increasing rotational velocity due to more H2S (g) secretion resulting from increased mixing rate. The present study provides valuable information about interrelations of quality and process parameters at different values of the studied variables. 相似文献
5.
6.
Annadasankar Roy Hemant Mohokar Diksha Pant Uday Kumar Sinha G. N. Mendhekar 《水文科学杂志》2020,65(6):951-968
ABSTRACTMultivariate statistical analysis and inverse geochemical modelling techniques were employed to deduce the mechanism of groundwater evolution in the hard-rock terrain of Telangana, South India. Q-mode hierarchical cluster analysis (HCA) and principal component analysis (PCA) were used to extract the hydrogeochemical characteristics and classify the groundwater samples into three principal groups. Use of thermodynamic stability diagrams and inverse geochemical modelling in PHREEQC identified the chemical reactions controlling hydrogeochemistry of each of the groups obtained from statistical analysis. The model output showed that a few phases are governing the water chemistry in this area and the geochemical reactions responsible for evolution of groundwater chemistry along the flow path are (i) dissolution of evaporite minerals (dolomite, halite); (ii) dissolution of primary silicate minerals (albite, anorthite, K-feldspar, biotite); (iii) precipitation of secondary silicate minerals (kaolinite, quartz, gibbsite, Ca-montmorillonite) along with anhydrite and calcite; and (iv) reverse ion exchange processes. 相似文献
7.
Coastal rivers represent a significant pathway for the delivery of natural and anthropogenic sediment‐associated chemical constituents to the Atlantic, Pacific and Gulf of Mexico coasts of the conterminous USA. This study entails an accounting segment using published average annual suspended sediment fluxes with published sediment‐associated chemical constituent concentrations for (1) baseline, (2) land‐use distributions, (3) population density, and (4) worldwide means to estimate concentrations/annual fluxes for trace/major elements and total phosphorus, total organic and inorganic carbon, total nitrogen, and sulphur, for 131 coastal river basins. In addition, it entails a sampling and subsequent chemical analysis segment that provides a level of ‘ground truth’ for the calculated values, as well as generating baselines for sediment‐associated concentrations/fluxes against which future changes can be evaluated. Currently, between 260 and 270 Mt of suspended sediment are discharged annually from the conterminous USA; about 69% is discharged from Gulf rivers (n = 36), about 24% from Pacific rivers (n = 42), and about 7% from Atlantic rivers (n = 54). Elevated sediment‐associated chemical concentrations relative to baseline levels occur in the reverse order of sediment discharges: Atlantic rivers (49%) > Pacific rivers (40%) > Gulf rivers (23%). Elevated trace element concentrations (e.g. Cu, Hg, Pb, Zn) frequently occur in association with present/former industrial areas and/or urban centres, particularly along the northeast Atlantic coast. Elevated carbon and nutrient concentrations occur along both the Atlantic and Gulf coasts but are dominated by rivers in the urban northeast and by southeastern and Gulf coast (Florida) ‘blackwater’ streams. Elevated Ca, Mg, K, and Na distributions tend to reflect local petrology, whereas elevated Ti, S, Fe, and Al concentrations are ubiquitous, possibly because they have substantial natural as well as anthropogenic sources. Almost all the elevated sediment‐associated chemical concentrations found in conterminous US coastal rivers are lower than worldwide averages. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
8.
A Visual Basic macro entitled BACKGROUND calculates geochemical background values of chemical parameters and estimates threshold values separating background data from anomalies. The macro uses two statistical methods, the iterative 2-sigma technique and the calculated distribution function, and integrates these model-based objective methods into a widely accessible platform (i.e., MS Excel). The macro offers the possibility for automated processing of geochemical data and enables an automated generation of background range and threshold values for chemical parameters. 相似文献
9.
混凝土框架模型结构参数的识别 总被引：2，自引：1，他引：1
框架结构是常见的建筑结构形式,也是结构损伤诊断的主要研究对象之一。本文以钢筋混凝土框架结构模型的振动测试数据为基础,采用灵敏度分析方法,对结构的物理参数进行识别。有限元分析中,考虑框架结构的节点转动,采用静凝聚方法得到结构刚度矩阵。参数识别结果表明,对于不同的固有频率和振型的测试信息组合所识别的物理参数有所不同。根据已知的概率分布,利用MonteCarlo方法,将模态参数的不确定性传递给物理参数,得到了物理参数的不确定性。 相似文献
10.
根据地震活动参数的数据特征,以2013年内蒙古科尔沁MS5.3地震为例,引入主成分分析和因子分析两种数据挖掘方法,在信息损失尽可能少的条件下,实现对参数变量的约简降维,并提取综合指标W.研究显示,2013年科尔沁MS5.3地震前两年,W值变化显著.在进一步的单因子分析中,从综合后的参数变量信息中重新提取了具有物理意义的多个单因子综合指标,消除了大量信息重叠所造成的不一致,实现了对综合指标的细化分析.在此基础上,对东北华北29次MS≥5.0地震的11个地震活动参数(频次N,b值,η值,A(b)值,Mf值,AC值,C值,D值,E值,Rm值,响应比Y)进行主成分分析,其结果显示,主成分综合指标W在震前1-2年均出现了明显的异常变化,这充分说明综合指标W可以用作地震预报研究的综合异常参考判据. 相似文献
11.
Geochemical reaction rate laws are often measured using crushed minerals in well-mixed laboratory systems that are designed to eliminate mass transport limitations. Such rate laws are often used directly in reactive transport models to predict the reaction and transport of chemical species in consolidated porous media found in subsurface environments. Due to the inherent heterogeneities of porous media, such use of lab-measured rate laws may introduce errors, leading to a need to develop methods for upscaling reaction rates. In this work, we present a methodology for using pore-scale network modeling to investigate scaling effects in geochemical reaction rates. The reactive transport processes are simulated at the pore scale, accounting for heterogeneities of both physical and mineral properties. Mass balance principles are then used to calculate reaction rates at the continuum scale. To examine the scaling behavior of reaction kinetics, these continuum-scale rates from the network model are compared to the rates calculated by directly using laboratory-measured reaction rate laws and ignoring pore-scale heterogeneities. In this work, this methodology is demonstrated by upscaling anorthite and kaolinite reaction rates under simulation conditions relevant to geological CO2 sequestration. Simulation results show that under conditions with CO2 present at high concentrations, pore-scale concentrations of reactive species and reaction rates vary spatially by orders of magnitude, and the scaling effect is significant. With a much smaller CO2 concentration, the scaling effect is relatively small. These results indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. This work demonstrates the use of pore-scale network modeling as a valuable research tool for examining upscaling of geochemical kinetics. The pore-scale model allows the effects of pore-scale heterogeneities to be integrated into system behavior at multiple scales, thereby identifying important factors that contribute to the scaling effect. 相似文献
12.
Multiple Discriminant Analysis of Marine Sediment Data 总被引：2，自引：0，他引：2
A multivariate statistical approach was used in the analysis of inter-relationships among marine benthic infaunal structure, physical and chemical characteristics of sediment samples and toxicity data derived from laboratory tests at 16 locations in shallow, inshore waters of Hong Kong. The method involved classification (cluster analysis using the Bray–Curtis similarity index) and ordination (multi-dimensional scaling) of infaunal patterns and the use of multiple discriminant analysis to relate groupings of the locations to the selected environmental and toxicity data. Analysis of the combined sediment physical, biological, chemical and toxicity dataset by stepwise multiple discriminant analysis allowed identification of those variables most sensitive for discriminating location groups. The use of multiple discriminant analysis in sediment quality characterization was evaluated against the Sediment Quality Triad approach and other statistical techniques. 相似文献
13.
《Limnologica》2014
Human activities in Lake Fuxian and its catchment have caused environmental changes that are preserved in the geochemical records of lake sediments. Human activities responsible for the environmental changes include agriculture, mining, industrial development, and fishery management. To elucidate human impacts on this deep water body during the past several decades, two short sediment cores were collected from the lake, dated by 137Cs, and analyzed for several geochemical variables (total organic carbon (TOC), total nitrogen (TN), δ13C and heavy metals). The multi-proxy geochemical and isotopic evidence can be used to divide the limnological record into a 3-part history. Although increasing inputs of chromium (Cr) had begun as early as the 1950s, human activities, including heavy metal contamination, apparently had little effect on lacustrine production, as δ13C, TOC, TN and TOC/TN were relatively constant until the 1980s. Mining and industry have generated large amounts of heavy metal elements such as Zn, Pb and Cd that have been deposited into the lake since the 1980s, increasing to their highest concentrations over the last decades. Zn, Pb and Cd probably were released by industrial processes such as the manufacture of cement. Cr concentrations increased at site FB, but declined at site FZ, most likely due to the closer proximity of site FB to the source of metal production. From the middle of the 1980s, the decreased δ13C, and increased TOC, TN and TOC/TN suggest a broad change in lake ecology. In the 1980s, a new fish species was introduced into Lake Fuxian and fish yields increased quickly, which may mark the beginning of a change in ecosystem structure. 相似文献
14.
The delivery of excessive fine sediment (particles<2 mm in diameter) to rivers can cause serious deleterious effects to aquatic ecosystems and is widely acknowledged to be one of the leading contributors to the degradation of rivers globally.Despite advances in using biological methods as a proxy,physical measures remain an important method through which fine sediment can be quantified.The aim of this study was to provide further insights into the environmental variables controlling sediment ... 相似文献
15.
Gene expression programing (GEP) is used to estimate the suspended sediment yield (SSY) in Euphrates River. SSY is considered to be a function of (i) discharge and (ii) time‐lagged discharge and SSY. The proposed models were trained to extrapolate natural stream data collected from five stations in Middle Euphrates Basin. A detailed sensitivity analysis is done to select the time‐lagged discharge and sediment yield variables. GEP implicitly evaluates the contribution of each independent variable on the fitness of candidate solution and eliminates the variable having no contribution. In this study, all input variables are observed to be included in the proposed GEP models, which prove the significance of each variable. Also, standard and modified sediment rating curves and regression‐based formulae are developed for the five stations. In verification, the estimations of GEP formulae agree well with the measured ones. The GEP models are evaluated by the results of the rating curves and regression formulae. In general, the GEP formulae give better results compared to the rating curves and regression‐based formulae. 相似文献
16.
In situ and high frequency monitoring of suspended sediment properties using a spectrophotometric sensor 下载免费PDF全文
下载免费PDF全文 Núria Martínez‐Carreras Michael P. Schwab Julian Klaus Christophe Hissler 《水文研究》2016,30(19):3533-3540
It is well known that sediment properties, including sediment‐associated chemical constituents and sediment physical properties, can exhibit significant variations within and between storm runoff events. However, the number of samples included in suspended sediment studies is often limited by time‐consuming and expensive laboratory procedures after stream water sampling. This restricts high frequency sampling campaigns to a limited number of events and reduces accuracy when aiming to estimate fluxes and loads of sediment‐associated chemical constituents. In this study, we address the potential of a portable ultraviolet–visible spectrophotometer (220–730 nm) to estimate suspended sediment properties in a resource efficient way. Several field deployable spectrophotometers are currently available for in‐stream measurements of environmental variables at high temporal resolution. These instruments have primarily been developed and used to quantify solute concentrations (e.g. dissolved organic carbon and NO3‐N), total concentrations of dissolved and particulate forms (e.g. total organic carbon) and turbidity. Here we argue that light absorbance values can be calibrated to estimate sediment properties. We present light absorbance data collected at 15‐min intervals in the Weierbach catchment (NW Luxembourg, 0.45 km2) from December 2013 to January 2015. In this proof‐of‐concept study, we performed a local calibration using suspended sediment loss‐on‐ignition (LOI) measurements as an example of suspended sediment property. We assessed the performance of several regression models that relate light absorbance measurements with the percentage weight LOI. The MM‐robust regression method presented the lowest standard error of prediction (0.48%) and was selected for calibration (adjusted r2 = 0.76 between observed and predicted values). The model was then used to predict LOI during a storm runoff event in December 2014. This study demonstrates that spectrophotometers can be used to estimate suspended sediment properties at high temporal resolution and for long‐time spans in a simple, non‐destructive and affordable manner. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
17.
This paper presents a regression model to predict the base displacement responses of biaxial base‐isolated buildings using independent component analysis. The model proposed utilizes multiple ground motion intensity measures from North American and Japanese earthquakes as inputs, and transforms them into an independent component space using independent component regression (ICR). Unlike other latent variable methods, such as principal component regression, ICR does not readily allow for dimensionality reduction of the components that do not contribute significantly to the explained variance of the original data set. Hence, a whitening‐step to transform the correlated variables into uncorrelated ones is introduced prior to performing ICR. Prediction results are presented and compared with the simulation results for two building models with increasing degree of complexity. The results show that the model based on ICR results in good estimates for the base displacement responses, and the standard errors remain relatively small and constant across a range of isolation periods. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
18.
Salvatore Inguaggiato Lorenzo Calderone Claudio Inguaggiato Agnes Mazot Sabina Morici Fabio Vita 《Bulletin of Volcanology》2012,74(8):1859-1863
Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO2 fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO2 and plume SO2 fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO2 concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results from this work suggest new prospects for strengthening geochemical monitoring of volcanic activity and for improving the constraints in the construction of a “geochemical model”, this being a necessary condition to better understand the functioning of volcanic systems. 相似文献
19.
Hamid Gholami Matt W. Telfer William H. Blake Abolhassan Fathabadi 《地球表面变化过程与地形》2017,42(14):2365-2376
Identifying sand provenance in depositional aeolian environments (e.g. dunefields) can elucidate sediment pathways and fluxes, and inform potential land management strategies where windblown sand and dust is a hazard to health and infrastructure. However, the complexity of these pathways typically makes this a challenging proposition, and uncertainties on the composition of mixed‐source sediments are often not reported. This study demonstrates that a quantitative fingerprinting method within the Bayesian Markov Chain Monte Carlo (MCMC) framework offers great potential for exploring the provenance and uncertainties associated with aeolian sands. Eight samples were taken from dunes of the small (~58 km2) Ashkzar erg, central Iran, and 49 from three distinct potential sediment sources in the surrounding area. These were analyzed for 61 tracers including 53 geochemical elements (trace, major and rare earth elements (REE)) and eight REE ratios. Kruskal–Wallis H‐tests and stepwise discriminant function analysis (DFA) allowed the identification of an optimum composite fingerprint based on six tracers (Rb, Sr, 87Sr, (La/Yb)n, Ga and δCe), and a Bayesian mixing model was applied to derive the source apportionment estimates within an uncertainty framework. There is substantial variation in the uncertainties in the fingerprinting results, with some samples yielding clear discrimination of components, and some with less clear fingerprints. Quaternary terraces and fans contribute the largest component to the dunes, but they are also the most extensive surrounding unit; clay flats and marls, however, contribute out of proportion to their small outcrop extent. The successful application of these methods to aeolian sediment deposits demonstrates their potential for providing quantitative estimates of aeolian sediment provenances in other mixed‐source arid settings, and may prove especially beneficial where sediment is derived from multiple sources, or where other methods of provenance (e.g. detrital zircon U–Pb dating) are not possible due to mineralogical constraints. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
20.
Pietro Mantovan Laura Menegazzo Vitturi Bruno Pavoni Sandro Rabitti 《Continental Shelf Research》1985,4(3):321-340
Data concerning grain-size distribution, mineralogy, geochemistry, and chlorinated hydrocarbon concentrations, obtained from 246 surface sediment samples collected in the Northern Adriatic sea (Italian area), provide the basis for a multivariate statistical analysis which evaluates the influence of riverine inputs, the differences among various depositional environments and the presence of polluted zones.Cluster analysis applied to grain size has identified nine groups of lithotypes associated with the morphology and the hydrology of the basin.In the Gulf of Venice, principal component analysis on clay minerals and carbonates has permitted recognition of two main areas located north and south of the Brenta river. More subareas correspond to other lithological types.Principal component analysis of nine metal (Hg, Cd, Cu, Pb, Cr, Zn, Fe, Ni, and Co) concentrations reveals that the studied sea area is more complex from the geochemical point of view. Three geochemical zones related to riverine inputs, different lithotypes and specific forms of contamination are identified. High pollution of both halocarbons and heavy metals is associated with fine grain size. 相似文献