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1.
The flushing time of the Providence River was estimated using three different data sets and three different methodologies. Dye concentrations were measured following instantaneous dye releases during wet weather experiments performed by the Narragansett Bay Project between October 1988 and June 1989. These data were analyzed to obtain flushing time estimates. Salinity measurements collected during the Sinbadd (Sampling In Narragansett Bay All During the Day) cruises, Spray (Sampling the Providence River All Year) cruises and wet weather experiments were used with the fraction of fresh water method and box model to calculate flushing time. The Sinbadd cruises performed 4 seasonal surveys at 22 stations in Narragansett Bay during 1986 to obtain a view of the whole Narragansett Bay with respect to the concentrations of nutrients and trace metals. The Spray cruises collected data in the Providence River at 10 stations to determine the relationship of nutrients and trace metals concentrations in the Seekonk and Providence rivers as a function of point source inputs. Based on the flushing time estimates, an exponential relationship between freshwater inflow and flushing time was developed (correlation coefficient of 0.826). The flushing time ranged from 0.8 d at high (90 m3 m?1) freshwater inflows to 4.4 d at low (20 m3 s?1) freshwater inflows. The average flushing time of the Providence River was estimated as 2.5 d for the mean freshwater inflow of 42.3 m3 s?1.  相似文献   

2.
Understanding the spatial distribution and variability of geochemical tracers is crucial for estimating groundwater influxes into a river and can contribute to better future water management strategies. Because of the much higher radon (222Rn) activities in groundwater compared to river water, 222Rn was used as the main tracer to estimate groundwater influxes to river discharge over a 323-km distance of the Big Sioux River, eastern South Dakota, USA; these influx estimates were compared to the estimates using Cl? concentrations. In the reaches overall, groundwater influxes using the 222Rn activity approach ranged between 0.3 and 6.4 m3/m/day (mean 1.8 m3/m/day) and the cumulative groundwater influx estimated during the study period was 3,982–146,594 m3/day (mean 40,568 m3/day), accounting for 0.2–41.9% (mean 12.5%) of the total river flow rate. The mean groundwater influx derived using the 222Rn activity approach was lower than that calculated based on Cl? concentration (35.6 m3/m/day) for most of the reaches. Based on the Cl? approach, groundwater accounted for 37.3% of the total river flow rate. The difference between the method estimates may be associated with minimal differences between groundwater and river Cl? concentrations. These assessments will provide a better understanding of estimates used for the allocation of water resources to sustain agricultural productivity in the basin. However, a more detailed sampling program is necessary for accurate influx estimation, and also to understand the influence of seasonal variation on groundwater influxes into the basin.  相似文献   

3.
Populations of suspension feeding bivalves constitute a metabolically important component of the benthos in Colorado Lagoon, Long Beach, California. Oxygen and nutrient flux were measuredin situ at monthly intervals over a two-year period. Estimates of bivalve metabolism were based on regressions of oxygen and ammonium flux on a measure of clam biomass adjusted allometrically. The introduced bivalve,Mercenaria mercenaria, occurs at maximum densities exceeding 400 per m2. Based on mean densities (143 per m2), bivalves contributed more than 50% of the 77 mg O2 per m2 per hr mean annual oxygen uptake and the 191 μM per m2 per hr mean ammonium release. Although bivalve biomass was not correlated with other inorganic nutrient flux, on an annual basis the sediments were a source of phosphate (26 μM per m2 per hr annual average, range 5 to 50) and a small sink for nitrate and nitrite. Net primary production, ammonium flux, and phosphate flux showed great annual variability while respiration was relatively constant. Total community oxygen uptake was not correlated with temperature. Long term incubations revealed no obvious rhythms having a period between four hours and four days. The benthic flux of ammonium and phosphate was calculated to supply more than the annual requirement of Lagoon phytoplankton.  相似文献   

4.
The groundwater of major karst systems and submarine springs in the coastal limestone aquifer of Syria has been investigated using chemical and isotopic techniques. The δ18O values of groundwater range from ?6.8 to ?5.05‰, while those for submarine springs vary from ?6.34 to +1.08‰ (eastern Mediterranean seawater samples have a mean of +1.7‰). Groundwater originates from the direct infiltration of atmospheric water. Stable isotopes show that the elevation of the recharge zones feeding the Banyas area (400–600 m a.s.l.) is higher than that feeding the Amrit area (100–300 m a.s.l.). The 18Oextracted (18O content of the seawater contribution) for the major submarine springs suggests a mean recharge area elevation of 600–700 m a.s.l., and lower than 400 m a.s.l. for the spring close to Amrit. Based on the measured velocity and the percentage of fresh water at the submarine springs outlet, the estimated discharge rate is 350 million m3/year. The tritium concentrations in groundwater (1.6–5.9 TU) are low and very close to the current rainfall values (2.9–5.6 TU). Adopting a model with exponential time distribution, the mean turnover time of groundwater in the Al-sen spring was evaluated to be 60 years. A value of about 3.7 billion m3 was obtained for the maximum groundwater reservoir size.  相似文献   

5.
Activity ratios (AR) of radium isotopes have been used with success to constrain estimates of water ages and to approximate residence times in coastal waters. We compared two common radium sampling methods (grab sampling and stationary moorings) to estimate water ages and the residence time of St. Andrew Bay waters in northwest Florida, USA. Both sampling methods utilize manganese dioxide fibers (“Mn fibers”) to adsorb dissolved radium from the water column. Grab samples capture radium activities at a discrete time while moorings integrate radium activities over longer deployments. The two methods yielded similar results in this study and thus both approaches are useful for water age comparisons and residence time approximations. However, since radium often varies as a function of tidal stage, deploying moorings over a complete tidal cycle is the preferred approach. An estimated residence time for North Bay and West Bay of 8–11 days was approximated using ARs for both ex224Ra/223Ra and ex224Ra/228Ra. Some complications were introduced as St. Andrew Bay is a tidally dominated, rather than a river-dominated bay system where this method has previously been applied. The largest freshwater source to this bay system is from a man-made reservoir, with an average freshwater flow of only 20 m3 s?1. The activity concentrations and ARs measured by both sampling methods suggest that while the reservoir is the prominent radium source, it is not the only radium source. Nonetheless, a tidal mixing model applied to the western half of the system yielded an approximate flushing time of 10–12 days, similar to that derived from our radium-based water age approach.  相似文献   

6.
In Fayetteville Green Lake, past sedimentation rates can be accurately and precisely estimated by separating annual couplets or varves in dried sediment samples. Two measures were used, which serve as upper and lower limits on estimated sedimentation rate. They agree within 5 % with average annual sedimentation rate in couplets for recent years. Between 3 and 5 replicate samples are needed to reduce the half-width of 95 % confidence intervals on individual couplet sedimentation rates to 30 g m?2 yr?1 about 5 % of average recent rates. In the late 1800s sedimentation rate averaged 392 g m?2 yr?1 and ranged between 324 and 466 g m?2 yr?1, while in the 1970s the rate averaged 581 g m?2 yr?1 by the same measure, and ranged between 384 and 646 g m?2 yr?1. Sedimentation rate averaged for 13 years does not vary over short distances in the profundal zone, but lateral variation in sedimentation rate can be detected for individual years over the same distance. Not all this variation was associated with the non-uniform distribution of dark sublaminae and thin turbidites which cannot be separated from the annual layers. This indicates that although precise estimates of sedimentation rates can be made at different points in the lake, estimates will have to be made at numerous points before annual sedimentation rates for the lake as a whole can be accurately assessed.  相似文献   

7.
The common killifish,Fundulus heteroclitus, is a euryhaline teleost common throughout estuaries of eastern North America. This symposium paper reviews the important contributions of the killifish to our present understanding of ionoregulation in seawater (SW) fish and their mechanisms of euryhalinity, and presents new data developing the killifish as a freshwater (FW) model system. Experiments on killifish have characterized (i) drinking in SW and its reduction in FW; (ii) the adaptive roles of the kidney to SW and FW conditions; (iii) the instantaneous (Phase I) and delayed (Phase II) reductions in Na+ outflux that occur upon transfer from SW to FW; (iv) the importance of prolactin secretion in the Phase II effect; (v) the cortisol-stimulated induction of branchial Na+, K+-ATPase that occurs upon transfer from FW to SW; (vi) the accompanying changes in morphology of the mitochondria-rich (MR) or “chloride cells” on the gills; (vii) the localization of this Na+, K+-ATPase activity to the basolateral membrane of chloride cells; and (viii) the NaCl-secretory function of these cells in SW. The opercular epithelium, which is rich in chloride cells, has been used as an in vitro model to characterize the mechanisms and control of NaCl secretion in SW fish. Much less is known about gill function in fresh water (inward NaCl transport), primarily due to the absence of a comparable freshwater model. Here we show that killifish acclimated to dilute FW ([NaCl] = 1 mmol I?1) possess large numbers of MR cells on the opercular epithelium. When mounted in vitro with FW on the outside, the preparation develops a large inside negative transepithelial potential (TEP) that is a Na+ diffusion potential. By the Ussing flux ratio criterion, Na+ fluxes are passive, but a small active influx of Cl? occurs, an observation that supports the involvement of MR cells in active Cl? uptake. This FW opercular epithelium if bathed with isotonic saline on both sides does not secrete Cl?, indicating that the MR cells indeed are of the FW type. In vivo, the fish exhibits a high rate of Na+ influx and outflux; Cl? outflux is much lower, and there is no detectable Cl? influx. Experimental variation of FW [NaCl] reveals a saturable, low affinity Na+ uptake mechanism, a Cl? influx mechanism that is activated only at much higher concentrations, and no evidence of exchange diffusion. Acid-base disturbance appears to be corrected by differential regulation of the outflux components only. Hence, the FW killifish ionoregulates somewhat differently from the few other FW teleosts that have been examined, and its opercular epithelium will serve as a very useful model system.  相似文献   

8.
The concentrations and physico-chemical states of 210Pb have been measured in Bikini Atoll and Washington State coastal waters, and 210Po in Washington coastal waters. Lead-210 concentrations of 113–133 dpm · m?3 were found in surface water collections near Bikini Atoll and 29–153 dpm · m?3 in Bikini Lagoon. The concentrations of 210Pb in near Bikini and in Washington State waters increased with depth in the upper 150m at a rate of 0.35–0.45dpm·m?3 · m?1. In the North Equatorial Current waters near Bikini Atoll 210Pb was found associated predominantly with the soluble (colloidal) fraction, but in Washington coastal waters 210Pb and 210Po were found associated with the paniculate (> 0.3 μm) fraction. The mean residence times of 210Pb, calculated from the atmospheric input to marine waters from precipitation and the concentrations measured in surface water, were consistent with the physico-chemical states of 210Pb found in samples collected in deep ocean and coastal waters. Approximate values of the mean residence times were calculated, for the upper 50 m, to be as follows: 58 days in the Strait of Juan de Fuca, 128 days at the 5-mile (8 km) station off Cape Flattery (Washington), 163 days at the 12-mile (19 km) station off Cape Flattery, and 2.6 yr near Bikini Atoll. It appears that 210Pb and 210Po can be used to trace particle removal rates in the upper layers of marine waters.  相似文献   

9.
The abundance of the marsh clamPolymesoda caroliniana at four stations on a Mississippi tidal marsh was followed from February 1977 through April 1978. The stations varied with respect to inundation time and vegetative cover. The largest population was found in an area flooded 12% of the year (136 individuals per m2) and in an area flooded 3.2% of the year (126 individuals per m2). However, the latter area contained no large clams (>25.5 mm). Smaller populations were found in the upper reaches of a tidal creek draining the marsh (68 individuals per m2) and in an area flooded 5.8% of the year (73 individuals per m2). The average abundance of the clams on the marsh was 100 per m2. At least three recruitment periods were apparent. In laboratory studies, clams larger than 15 mm survived longer than 30 days without water. Clams smaller than 12 mm survived less than 6 days without water. Several decapods (Callinectes sapidus, Uca longisignalis, andSesarma reticulatum) consumed clams smaller than 10 mm but were unable to eat larger clams under laboratory conditions.Polymesoda caroliniana may be important to the functioning of the marsh by removing large quantities of particulate matter from flooding water.  相似文献   

10.
We analyze photometry of the dwarf nova MN Dra carried out using various instruments at four observatories on 18 nights between May 20 and June 28, 2009. The observations cover a variety of activity states of the system: a superoutburst, three normal outbursts, and quiescence. Analysis of the system’s light curve during the superoutburst decline reveals positive superhumps that recur, on average, with a period of 0.105 days and are due to the direct apsidal precession of the accretion disk. These are observed until the end of the superoutburst, but their period decreases at a rate of −24.5 × 10−5 of the period per period. Both the positive-superhump period and its derivative are in good agreement with estimates made during previous superoutbursts. At the brightness minimum and in normal outbursts, MN Dra displays brightness variations with a period of 0.096 days, whose amplitude is much larger during the brightness minimum (0.8 m –1.5 m ) than during normal outbursts (0.1 m –0.2 m ). We suggest that these brightness variations could be negative superhumps due to nodal precession of the oblique accretion disk.  相似文献   

11.
The temporal variability in abundance and population structure of the gastropodChilina ovalis Sowerby was studied in the upper intertidal zone of Queule River estuary, south-central Chile (c. 40°S). Snails were collected monthly (September 1995–December 1997) from haphazardly-located quadrats (50×50 cm, n=5 each time), and counted and measured (shell height) in the laboratory. Water and sediment samples were collected at the same time to study the snail's habitat characteristics. Overall mean abundance was 115 individuals m?2 (SD=55). Monthly abundance estimates indicated a clear decrease during 1997. This decrease appeared to be related to the annual recruitment success of the species and at least partially to water temperature and sedimentological variability. Overall size range ofC. ovalis was 1.5–27.5 mm shell height. Growth varied seasonally with highest growth rates observed after recruitment (November–February). Slower growth continued throughout the austral winter months. Despite changes in abundance between 1996 and 1997, no differences were detected when population growth estimates were compared between years. A maximum longevity of approximately 4 yr was estimated from the growth curves of the cohorts, and a life cycle with more than one reproductive period is suggested.  相似文献   

12.
Calculations by others of the preindustrial deposition of inorganic nitrogen from the atmosphere in the area of Narragansett Bay compared with recent measurements suggest that this flux has increased almost 15 times over natural background. On the basis of modern studies of the export of nitrogen and phosphorus from temperate forests, the prehistoric watershed also probably contributed very little reactive N or P to the bay. New information from undisturbed old-growth forests suggests that most of the N that was exported from the watershed was probably associated with refractory dissolved organic matter and thus contributed little to the fertility of the bay. The largest source of reactive dissolved inorganic nitrogen (DIN) and phosphorus (DIP) for Narragansett Bay under prehistoric conditions was the coastal ocean water entrained in the bay in estuarine circulation. The total input of DIN to this estuary has increased about five-fold and the input of total DIP has approximately doubled as a result of human activities. Recent ecosystem-level experiments using large (13 m3, 5 m deep) mesocosms designed as living models of Narragansett Bay showed that the primary production of phytoplankton in the bay is limited by the supply of DIN and that annual phytoplankton production is strongly correlated with the rate of input of DIN. The relationship between DIN input and annual phytoplankton production in the mesocosms is consistent with observations published by others working in 10 different natural marine systems, and a functional regression of the field and experimental data provides a tool to calculate the rate of prehistoric phytoplankton production that would have been associated with the prehistoric DIN input estimates. The result of this calculation suggests that phytoplankton production in the bay has approximately doubled (from about 130 g C m?2 yr?1 to 290 g C m?2 yr?1 for a baywide average) since the time of European contact. It also seems likely that seagrasses and macroalgae once made a much larger contribution to total system production than they do today.  相似文献   

13.
The impacts of floods and droughts are intensified by climate change, lack of preparedness, and coordination. The average rainfall in study area is ranging from 200 to 400 mm per year. Rain gauge generally provides very accurate measurement of point rain rates and the amounts of rainfall but due to scarcity of the gauge locations provides very general information of the area on regional scale. Recognizing these practical limitations, it is essential to use remote sensing techniques for measuring the quantity of rainfall in the Middle Indus. In this research, Tropical Rainfall Measuring Mission (TRMM) estimation can be used as a proxy for the magnitude of rainfall estimates from classical methods (rain gauge), quantity, and its spatial distribution for Middle Indus river basin. In order to use TRMM satellite data for discharge measurement, its accuracy is determined by statistically comparing it with in situ gauged data on daily and monthly bases. The daily R 2 value (0.42) is significantly lower than monthly R 2 value (0.82), probably due to the time of summation of TRMM 3-hourly precipitation data into daily estimates. Daily TRMM data from 2003 to 2012 was used as input forcing in Soil and Water Assessment Tool (SWAT) hydrological model along with other input parameters. The calibration and validation results of SWAT model give R 2 = 0.72 and 0.73 and Nash-Sutcliffe coefficient of efficiency = 0.69 and 0.65, respectively. Daily and monthly comparison graphs are generated on the basis of model discharge output and observed data.  相似文献   

14.
Flushing of dense water from cavities of the upper reaches of the Swan River estuary in Western Australia was investigated using measured salinity and dissolved oxygen profiles and a two-dimensional, laterally averaged hydrodynamic model (TISAT). Seasonal flushing of dense, hypoxic bottom waters from a relatively deep site took place over ∼3 days at the onset of winter in 1994. Model simulations of the purging of this dense water did not correspond closely with changes in the densimetric Froude number. Purging, expressed as depth of the halocline as a fraction of the total cavity depth, occurred when the simulated mean horizontal velocity at 2 m depth (top of cavity) changed from negative to strongly positive, indicating arrest of upstream flow and continuous downstream flow. This corresponded to freshwater discharge of about 50 m3 s−1. Oxygen depletion of bottom waters was closely related to stratification. Oxygen dynamics at the onset of winter river flow was analysed using an exponential decay model, assuning that there was no net inflow or outflow across the halocline and thus no vertical transport of oxygen during a period of strong stratification. The rate constant for oxygen decay at Ron Courtney Island (RCI) was estimated to be 0.232 d−1 for this period. Bottom waters at RCI declined to less than 1 mg 1−1 prior to complete flushing through increased river flows. This study provided in sights to how freshwater flows may be allocated to maintain suitable oxygen levels in the bottom waters of estuarine cavities.  相似文献   

15.
Growth, mortality, and production rates for spot,Leiostomus xanthurus Lacépede, were studied from January 1977 through August 1978 in tidal creeks of the Cape Fear estuary, North Carolina. Winter growth rates were low, averaging 0.14 and 0.16 mm per day in 1977 and 1978, respectively. Mortality rates were significantly higher in polyhaline marshes during 1977, however, similar rates were observed in oligohaline marshes in 1978. The difference is believed due to higher freshwater flows experienced in 1978, which apparently increased mortality rates upriver. Pooled monthly production estimates for all sampling sites combined yielded a value of 0.17 g per m2 (257 cal per m2). This figure is similar to those reported for spot collected in seagrass meadows in the vicinity of the Cape Fear estuary (Adams 1976). Because spot migrate offshore in the fall, this production also represents potential export of energy to the marine environment in the form of living biomass.  相似文献   

16.
Increased nutrient loading to estuaries has led to eutrophication, degraded water quality, and ecological transformations. Quantifying nutrient loads in systems with significant groundwater input can be difficult due to the challenge of measuring groundwater fluxes. We quantified tidal and freshwater fluxes over an 8-week period at the entrance of West Falmouth Harbor, Massachusetts, a eutrophic, groundwater-fed estuary. Fluxes were estimated from velocity and salinity measurements and a total exchange flow (TEF) methodology. Intermittent cross-sectional measurements of velocity and salinity were used to convert point measurements to cross-sectionally averaged values over the entire deployment (index relationships). The estimated mean freshwater flux (0.19?m3/s) for the 8-week period was mainly due to groundwater input (0.21?m3/s) with contributions from precipitation to the estuary surface (0.026?m3/s) and removal by evaporation (0.048?m3/s). Spring?Cneap variations in freshwater export that appeared in shorter-term averages were mostly artifacts of the index relationships. Hydrodynamic modeling with steady groundwater input demonstrated that while the TEF methodology resolves the freshwater flux signal, calibration of the index?Csalinity relationships during spring tide conditions only was responsible for most of the spring?Cneap signal. The mean freshwater flux over the entire period estimated from the combination of the index-velocity, index?Csalinity, and TEF calculations were consistent with the model, suggesting that this methodology is a reliable way of estimating freshwater fluxes in the estuary over timescales greater than the spring?Cneap cycle. Combining this type of field campaign with hydrodynamic modeling provides guidance for estimating both magnitude of groundwater input and estuarine storage of freshwater and sets the stage for robust estimation of the nutrient load in groundwater.  相似文献   

17.
The Late Archaean Closepet Granite batholith in south India is exposed at different crustal levels grading from greenschist facies in the north through amphibolite and granulite facies in the south along a ∼400 km long segment in the Dharwar craton. Two areas, Pavagada and Magadi, located in the Main Mass of the batholith, best represent the granitoid of the greenschist and amphibolite facies crustal levels respectively. Heat flow estimates of 38 mW m−2 from Pavagada and 25 mW m−2 from Magadi have been obtained through measurements in deep (430 and 445 m) and carefully sited boreholes. Measurements made in four boreholes of opportunity in Pavagada area yield a mean heat flow of 39 ± 4 (s.d.) mW m−2, which is in good agreement with the estimate from deep borehole. The study, therefore, demonstrates a clear-cut heat flow variation concomitant with the crustal levels exposed in the two areas. The mean heat production estimates for the greenschist facies and amphibolite facies layers constituting the Main Mass of the batholith are 2.9 and 1.8 μW m−3, respectively. The enhanced heat flow in the Pavagada area is consistent with the occurrence of a radioelement-enriched 2-km-thick greenschist facies layer granitoid overlying the granitoid of the amphibolite facies layer which is twice as thick as represented in the Magadi area. The crustal heat production models indicate similar mantle heat flow estimates in the range 12–14 mW m−2, consistent with the other parts of the greenstone-granite-gneiss terrain of the Dharwar craton.  相似文献   

18.
This paper summarizes evidence that most of the considerable nitrogen loading (～8, 470 mmol total N m?2 yr?1) to Boston Harbor (Massachusetts, USA) is expelled to shallow shelf waters of Massachusetts Bay, where it strongly influences ecological dynamics. Examination of nitrogen concentrations in the harbor, compared with loading, indicated that removal processes are active in the harbor. Comparison to other estuarine systems showed that the harbor’s nitrogen concentrations are consistent with its loading, if they are corrected for tidal flushing effects on the water residence time. Furthermore, extensive measurements of sediment denitrification confirmed that rates of N2 gas loss are high in an absolute sense (～600–800 mmol N m?2 yr?1) but nonetheless remove only a small portion (<10%) of the annual land-derived nitrogen loading. Burial in sediments apparently removes only about 2% of the N input, implying export to offshore environments as the major removal process (～88–90% of N input). Western Massachusetts Bay receiving waters were examined for a signature of export from the harbor. Data consistently show a gradient of decreasing nitrogen concentrations from the harbor to about 10–20 km into the bay. In many cases, plots of nitrogen concentrations versus salinity show nearly conservative mixing character, which implies virtual export. Seasonally, the data suggest most of the export from the harbor in winter is as dissolved inorganic forms (NH4 +, NO3 ?, NO2 ?). In summer, export is dominated by the outflow of organic nitrogen forms. Chlorophyll export is evident as well, suggesting that the nutritional coupling of the harbor and bay in summer involves organic fertilization of the bay’s surface water. Finally, high-resolution studies over different stages of the tidal cycle help refine understanding of the advection of chlorophyll and stimulation of in situ chlorophyll growth at the seaward edge of the tidal excursion into the bay.  相似文献   

19.
This paper presents the glacial runoff characteristics of the Koxkar Glacier, China using flow records collected near the snout of the glacier in four consecutive years (2005–2008). The mean annual discharge of the Koxkar Glacier is 102.86 × 106 m3, in which 93.6% occurs in ablation season (May–October). August brings about maximum discharge of about 29.6% to the total streamflow followed by July of some 26.0%. During the study years, total discharge varies little from year to year, whereas the inter-annual variability in monthly discharge is prominent, particularly in the beginning and in the end of the melt season. Seasonal runoff variability shows great monthly variations in discharge with mean coefficient of variation ranging from 0.02 in January to 0.77 in April. The mean diurnal amplitudes are found to be 0.90, 1.86, 4.71, 4.92, 1.17 and 0.43 m3 s−1 for May, June, July, August, September and October, respectively. In the melt season, the maximum runoff is observed during 1800–0200 hours and the minimum occurs during 0700–1000 hours. Delaying effects are prominent in discharge over the ablation period. The time-lag between meltwater generation and its appearance in the streamflow near the snout of the glacier varies between 4.00 and 10.00 h, and time to peak varies between 10.00 and 17.00 h over the entire melt season. The relationship between discharge and temperature on monthly scale (R 2 = 0.77) is better than that on daily scale (R 2 = 0.55).  相似文献   

20.
A decade of studies of metal and nutrient inputs to the back-barrier area of Spiekeroog Island, NW German Wadden Sea, have concluded that pore water discharge provides a significant source of the enrichments of many components measured in the tidal channels during low tide. In this paper we add studies of radium isotopes to help quantify fluxes into and out of this system. Activities of radium isotopes in surface water from tidal channels in the back-barrier area exhibit pronounced changes in concert with the tide, with highest activities occurring near low tide. Other dissolved components: silica, total alkalinity (TA), manganese, and dissolved organic carbon (DOC) exhibit similar changes, with patterns matching the Ra isotopes. Uranium follows a reverse pattern with highest concentrations at high tide. Here we use radium isotope measurements in water column and pore water samples to estimate the fluxes of pore waters that enter the tidal channels during low tide. Using a flushing time of 4 days and the average activities of 224Ra, 223Ra, and 228Ra measured in the back-barrier surface and pore waters, we construct a balance of these isotopes, which is sustained by a deep pore water flux of (2-4) × 108 L per tidal cycle. This flux transports Ra and the other enriched components to the tidal channels and causes the observed low tide enrichments. An independent estimate of pore water recharge is based on the depletion of U in the tidal channels. The U-based recharge is about two times greater than the Ra-based discharge; however, other sinks of U could reduce the recharge estimate. The pore waters have wide ranges of enrichment in silica, alkalinity, manganese, DOC, and depletion of U with depth. We estimate concentrations of these components in pore water from the depth expected to contribute the majority of the pore water flux, 3.5 m, to determine fluxes of these components to the tidal channels. Samples from this depth have minimum concentrations of silica, alkalinity, manganese, and DOC. We also estimate the exports of these components (and import of U) due to mixing based on average measured concentrations in the tidal creeks and the 4-day flushing time. A comparison of these estimates reveals that the exports (negative in the case of U) equal or exceed the pore water fluxes. By using values slightly higher than the minimum concentrations at 3.5 m to calculate inputs, the two estimates could be forced to match. We conclude that pore water drainage is the major factor regulating fluxes of Ra isotopes, silica, alkalinity, manganese, DOC, and uranium in this system.  相似文献   

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