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1.
Peatlands cover a very small area of the Earth, but store globally significant quantities of carbon and export disproportionate quantities of fluvial organic carbon, especially when the peatlands are degraded or disturbed. Peatland headwater catchments with high concentrations of dissolved and particulate organic carbon (DOC and POC) provide an opportunity to investigate the possibility of competing effects that could lead to enhanced or diminished turnover of DOC in the presence of POC. Both POC and DOC can be degraded by light and microbes, producing smaller molecules and releasing CO2 and CH4 to the atmosphere, and POC can inhibit light penetration, stabilize DOC by providing adsorption sites and providing surfaces for microbes to interact with DOC. However, the majority of peatland fluvial carbon studies are conducted using filtered water samples, and measure only the DOC concentration, so the impact of the particulate organic matter (POM) on in-stream processing of organic carbon is relatively unknown. It is therefore possible that studies have underestimated carbon transformations in rivers as they have not considered the interaction of the particulate material on the dissolved concentrations; there could be higher losses than previously estimated, increasing the contribution of peatland headwaters to GHG emissions. In this study, we assessed if the current approach of DOC degradation studies accurately represent the impact of POM on DOC degradation, by quantifying DOC production from POM, and therefore POC, over time in water with manipulated POM concentrations. Both filtered and unfiltered water lost 60% of the DOC over 70 hours, whereas the treatment with additional POM lost only 35%. The results showed that filtering does not significantly impact the DOC degradation rates; however, when the POC concentration was doubled, there was a significant reduction in DOC degradation, suggesting that filtering would still be necessary to get accurate rates of DOC transformations in waters with high POC concentrations.  相似文献   

2.
We investigate sources of both dissolved and particulate organic carbon in the St Lawrence River from its source (the Great Lakes outlet) to its estuary, as well as in two of its tributaries. Special attention is given to seasonal interannual patterns by using data collected on a bi‐monthly basis from mid‐1998 to mid‐2003. δ13C measurements in dissolved inorganic carbon, dissolved organic carbon (DOC) and particulate organic carbon (POC), as well as molar C : N in particulate organic matter (POM), are used to bring insight into the dynamic between aquatic versus terrigenous sources. In addition, 14C activities of DOC were measured at the outlet of the St Lawrence River to its estuary to assess a mean age of the DOC exported to the estuary. In the St Lawrence River itself, aquatically produced POC dominates terrestrially derived POC and is depleted in 13C by approximately 12‰ versus dissolved CO2. In the Ottawa River, the St Lawrence River's most important tributary, the present dataset did not allow for convincing deciphering of POC sources. In a small tributary of the St Lawrence River, aquatically produced POC dominates in summer and terrestrially derived POC dominates in winter. DOC seems to be dominated by terrestrially derived organic matter at all sampling sites, with some influence of DOC derived from aquatically produced POC in summer in the St Lawrence River at the outlet of the Great Lakes and in one of its small tributaries. The overall bulk DOC is relatively recent (14C generally exceeding 100% modern carbon) in the St Lawrence River at its outlet to the estuary, suggesting that it derives mainly from recent organic matter from topsoils in the watershed. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

3.
The authors conducted a Rn222 survey in wells of the Larderello geothermal field (Italy) and observed considerable variations in concentrations. Simple models show that flow-rate plays an important part in the Rn222 content of each well, as it directly affects the fluid transit time in the reservoirs. Rn222 has been sampled from two wells of the Serrazzano area during flow-rate drawdown tests. The apparent volume of the steam reservoir of each of these two wells has been estimated from the Rn222 concentration versus flow-rate curves.List of symbols Q Flow-rate (kg h–1) - Decay constant of Rn222 (=7.553×10–3 h–1) - Porosity of the reservoir (volume of fluid/volume of rock) - 1 Density of the fluid in the reservoir (kg m–3) - 2 Density of the rock in the reservoir (kg m–3) - M Stationary mass of fluid filling the reservoir (kg). - E Emanating power of the rock in the reservoir (nCi kg rock –1 h–1). - P Production rate of Rn222 in the reservoir: number of atoms of Rn222 (divided by 1.764×107) transferred by the rock to the mass unit of fluid per unit time (nCi kg fluid –1 h–1). - N Specific concentration of Rn222 in the fluid (nCi kg–1) - Characteristic time of the steam reservoir at maximum flow-rate (=M/Q)  相似文献   

4.
Summary In this paper the quasi-static temperature and stress distributions set up in an elastic sphere by radiation from a point source at a finite distance from the centre of the sphere and out-side it, have been discussed. The temperature boundary condition has been taken in the general form involving an arbitrary function of time. The final solutions have been obtained in terms of series involving Legendre polynomials. Numerical calculations have been done on IBM 1620 Computer and a desk calculator. The results have been represented in graphs.Notation the del operator - u the displacement vector - T the excess of temperature over that at state of zero stress and strain - , Lamé's constants - /2(+) Poisson's ratio - coefficient of linear expansion - 2(1+) - a radius of the sphere - d distance of the point source from the centre of the sphere - d o a/d - K coefficient of thermal conductivity - h heat transfer coefficient of the surface  相似文献   

5.
This work is part of an attempt to quantify the relationship between the permeability tensor (K) and the micro-structure of natural porous media. A brief account is first provided of popular theories used to relate the micro-structure toK. Reasons for the lack of predictive power and restricted generality of current models are discussed. An alternative is an empirically based implicit model whereinK is expressed as a consequence of a few pore-types arising from the dynamics of depositional processes. The analytical form of that implicit model arises from evidence of universal association between pore-type and throat size in sandstones and carbonates. An explicit model, relying on the local change of scale technique is then addressed. That explicit model allows, from knowledge of the three-dimensional micro-geometry to calculateK explicitly without having recourse to any constitutive assumptions. The predictive and general character of the explicit model is underlined. The relevance of the change of scale technique is recalled to be contingent on the availability of rock-like three-dimensional synthetic media. A random stationary ergodic process is developed, that allows us to generate three-dimensional synthetic media from a two-dimensional autocorrelation functionr( x , y ) and associated probability density function measured on a single binary image. The focus of this work is to ensure the rock-like character of those synthetic media. This is done first through a direct approach:n two-dimensional synthetic media, derived from single set ( ,r( x , y )) yieldn permeability tensorsK i-1,n i (calculated by the local change of scale) of the same order. This is a necessary condition to ensure thatr( x , y ) and carry all structural information relevant toK. The limits of this direct approach, in terms of required Central Process Unit time and Memory is underlined, raising the need for an alternative. This is done by comparing the pore-type content of a sandstone sample andn synthetic media derived fromr( x , y ) and measured on that sandstone-sample. Achievement of a good match ensures that the synthetic media comprise the fundamental structural level of all natural sandstones, that is a domainal structure of well-packed clusters of grains bounded by loose-packed pores.  相似文献   

6.
Summary Measuring, with the aid of two filters, the instantaneous intensity of the solar radiation in two wave lengths ( B = 0.44 , R = 0.64 ) by means of a sun photometer designed byVolz, we carried out determinations of the decadic turbidity coefficientB (=0.5 ) and the wave length exponent of the haze extinction for Mexico City. Observations were made for almost two and a half years (1960 to 1962 period). A seasonal size distribution in both parameters was found. Although the data thus obtained are provenient of a contaminated atmosphere, comparison of our data is made with those found for higher latitudes ofÅngström, Schüepp andVolz. The height of the homogeneous haze layerH D was calculated showing pronounced variations for a given wind direction. The maximum and minimum values ofB enable us to get, by the first approximation, the aerosol size distribution ofJunge for our latitudes. However, for exceptional very clear days having maximum actinometric intensity of the solar radiation the sensitivity of the microamperimeter in theVolz sun photometer fails.  相似文献   

7.
Résumé Des mesures actinométriques de l'intensité solaire dans les domaines spectraux: <425, <525, >630 m ainsi que celle dans l'ensemble du spectre solaire (totale) ont été effectuées à Giza (lat. 30°N) à l'aide d'un actinomètre Linke-Feussner, pendant une année complète pour tous les jours le ciel étant parfaitement clair.D'après ces mesures on peut conclure que: l'intensité solaire totale en été est inférieure à sa valeur en hiver en raison de l'accroissement de la teneur en vapeur d'eau atmosphérique en été; la distribution spectrale de l'énergie solaire, au cours de l'année peut être considérée comme constante, pour une masse d'air déterminée; l'intensité solaire, arrivant au sol, dans la région spectrale en-dessous de =425 m peut donner une indication des fluctuations de l'épaisseur réduite de l'ozone.
Summary Actinometric measurements of the solar intensity in the spectral regions: <425, <525, >630 m as well as the total solar intensity for the whole spectrum of the sun have been undertaken at Giza (lat. 30°N) with a Linke-Feussner actinometer, for a whole year and for every day the sky was perfectly clear.From these measurements, one can conclude that: the total solar intensity in summer is less than that in winter because of the increase of atmospheric water vapor content; the spectral distribution of the solar energy, during the year could be considered constant for a certain air mass; the solar intensity, reaching the earth's surface, in the spectral region below =425 m can give an indication to the fluctuations in the reduced thickness of the ozone layer.
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8.
Summary The stress sensitivitiesS x andS R of susceptibility and remanence for titanomagnetite-bearing rocks are calculated in terms of magnetostriction constants 100 and 111 and anisotropy constantsK 1,K 2 of the magnetic minerals.S x andS R are represented by quite different algebraic expressions but happen to have comparable numerical values over the whole range of titanomagnetite compositions. Both increase strongly with titanium content. This leads to more optimistic calculations of tectonomagnetic effects than with the previously assumed stress sensitivity for pure magnetite.  相似文献   

9.
The Fitzroy estuary (Queensland, Australia) receives large, but highly episodic, river flows from a catchment (144,000 km(2)) which has undergone major land clearing. Large quantities of suspended sediments, and particulate and dissolved organic carbon are delivered. At peak flows, delta(13)C (-21.7+/-0.8 per thousand) and C/N (14.8+/-1.3) of the suspended solids indicate that the particulate organic material entering the estuary is principally soil organic carbon. At the lower beginning flows the particulate organic matter comes from in-stream producers (delta(13)C=-26 per thousand). The DOC load is about 10 times the POC load. Using the inverse method, budgets for POC and DOC were constructed for high and low flows. Under high flows, only a small portion of the POC and DOC load is lost in the estuary. Under dry season (low flow) conditions the estuary is a sink for DOC, but remains a source of POC to the coastal waters.  相似文献   

10.
Solar radiation of >175 nm and of Lyman-alpha at 121.6 nm is absorbed in the mesosphere and stratosphere by molecular oxygen (<242 nm) and also by ozone molecules at >200 nm. This paper describes the photodissociation processes resulting from absorption in the Schumann-Runge bands and Herzberg continuum of molecular oxygen and also in the Hartley, Huggins and Chappuis bands of ozone. Special consideration is given to differences between the stratospheric and mesospheric problems.  相似文献   

11.
The optical properties and spatial distribution of chromophoric dissolved organic matter (CDOM) in Meiliang Bay of Lake Taihu were evaluated and compared to the results in literature. Concentrations of dissolved organic carbon (DOC) ranged from 8.75 to 20.19 mg L?1 with an average of (13.10 ± 3.51) mg L?1. CDOM absorption coefficients a(λ) at 280 nm, 355 nm, and 440 nm were in the range 11.28...33.46 m?1 (average (20.95 ± 5.52) m?1), 2.42...7.90 m?1 (average (4.92 ± 1.29) m?1), and 0.65...2.44 m?1 (average (1.46 ± 0.44) m?1), respectively. In general, CDOM absorption coefficient and DOC concentration were found to decrease away from the river inflow to Meiliang Bay towards the lake center. The values of the DOC‐specific absorption coefficients a*(λ), given as absorption coefficient related to mass concentration of organic carbon (C) ranged from 0.28 to 0.47 L mg?1 m?1 at 355 nm. The determination coefficients between CDOM absorption and DOC concentration decreased with the increase of wavelength from 280 to 550 nm. The linear regression relationship between CDOM absorption at 280 nm and DOC concentration was following: a(280 nm) = 1.507 L mg?1 m?1 · DOC + 1.215 m?1. The spectral slope S values were dependent on the wavelength range used in the regression. The estimated S values decreased with increasing wavelength range used. A significant negative linear relationship was found between CDOM absorption coefficients, DOC‐specific absorption coefficients and estimated S values especially in longer wavelength range. The linear regression relationship between DOC‐specific absorption coefficients at 440 nm and estimated S values during the wavelength range from 280 to 500 nm was following: a*(440 nm) = (–0.021 μm · S + 0.424) L mg?1 m?1.  相似文献   

12.
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13.
A general formula for the Dieterich-Ruina friction constitutive law with rate and state (n-state variables,n=1, 2,...) dependences has been obtained and discussed under the assumption that the slip acceleration a varies ion a linearly with the slip displacement , namelya = a 0 + (-0). Wherea 0, 0 are initial constants, is the acceleration rate and constant.a 0 and may be arbitrary constants (positive, negative or zero).The extreme value of frictional resistance and the existence condition of the extreme value, which are very important and govern to some degree the motion process of a frictionally slipping mechanical system, have been analyzed. A critical value c which is the measure of the velocity weakening and velocity strengthening of the mechanical system, and its properties and the relationship to the extreme problem have been studied. Again, according to the critical value c, the concepts of light or strong velocity weakening (or strengthening) are introduced.A possibly new phenomenon that frictional resistance may vary in some kind of decayed oscillation is found. Finally, the condition for the smallest frictional resistance for a slipping mechanical system with nonuniform acceleration has been obtained.  相似文献   

14.
Dissolved and particulate organic matter (DOM and POM) have been investigated along a transect between Cherbourg and the Isle of Wight. In addition, the relative contribution of different sources of POM have been assessed by the use of lipid biomarkers (e.g. fatty acids). Seawater samples were collected at two depths (subsurface and above the bottom) at five stations located on the transect during five cruises (from September 1994 to July 1995). Particulate organic carbon (POC) and dissolved organic carbon (DOC) concentrations vary between 30–530 μg l−1 and 0.5–2.7 mg l−1, respectively, for all the cruises. Fluxes of POM and DOM have been estimated at 0.6×1012 g yr−1 and 6.5×1012 g yr−1 of carbon, respectively. General fluxes of water and therefore of DOC and POC are oriented eastward. However, around the Isle of Wight a westward oriented flux exists due to a gyre located in the area. The major DOC and POC fluxes occur in the central part of the Channel where the water column is deepest. Seasonal variations of different sources of POM (algal, bacterial and terrigenous) have been examined for the five cruises. The fresh algal organic fraction is relatively important in September in coastal waters with a predominance of diatom species on the English side, whereas it has a low or undetectable contribution during winter months. The bacterial fraction generally varies in concert with the algal component. It is low during the winter period and more important in bloom or post-bloom conditions, as for example in May. Terrestrial organic matter is restricted to coastal areas in September, and is present at low levels in May and July. Nevertheless, in November and February, terrigenous inputs have been clearly identified for the whole transect even in central waters.  相似文献   

15.
Summary A pressure transducer fixed to a sledge was towed over the bottom of the sea. Pressure variations corresponding to bottom displacement variations were recorded along different profiles in the area west of Sylt. From the time series obtained power spectra of bottom irregularities were computed as a function of wavenumberk or wavelength . Total rms bottom displacement in the wavelength band 50 to 500 m ranges from 3 cm to 36 cm depending on the location of the profile. Presumedly this is due to different types of sediment. Therefore the area cannot be considered as uniform or isotropic concerning the spatial and directional distribution of bottom irregularities. The approximation of spectra byE(k)k– yields -values between 0.4 and 2.9.
Bodenunebenheiten in der Nordsee
Zusammenfassung Mit Hilfe einer Druckdose, die von einem Schiff aus über den Meeresboden gezogen wurde, konnten auf ausgewählten Profilen westlich von Sylt Bodenunebenheiten registriert werden. Aus den gewonnenen Zeitserien wurden SpektrenE(k) für die Wellenzahlenk bzw. für die Wellenlänge berechnet. Hieraus lassen sich die Amplituden der Bodenunebenheiten im Wellenlängenbereich von 20 bis 500 m bestimmen. Die effektive Bodenwelligkeit im Bereich von 50 bis 500 m liegt je nach Profil zwischen 3 cm und 36 cm. Die Ursache dafür ist möglicherweise in der unterschiedlichen Sedimentzusammensetzung zu suchen. Eine Isotropie des Bodenspektrums im Meßgebiet ist nicht vorhanden. Die Annäherung der Spektren durchE(k)k– ergibt -Werte zwischen 0,4 und 2,9.
Irrégularités du fond en Mer du Nord
Résumé Un manomètre enregistreur fixé à un traîneau a été remorqué sur le fond de la mer. Les variations de pression correspondant aux variations du fond ont été enregistrées le long de différents profils dans la zone Ouest de Sylt. A partir de la série de mesures obtenues, on a calculé le spectre de puissance des irrégularités du fond en fonction du nombre d'ondek ou de la longueur d'onde . Globalement, les variations du fond dans la bande de longueurs d'onde de 50 à 500 m varient de 3 à 36 cm en moyenne quadratique selon la situation du profil. On présume que cela est dû aux différents types de sédiments. Aussi, la zone ne peut pas être considérée comme uniforme ou isotrope en ce qui concerne la distribution dans l'espace et en direction des irrégularités du fond. L'approximation de spectres parE(k)k– donne des valeurs de comprises entre 0,4 et 2,9.
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16.
To investigate the effects of anthropogenic activity, namely, land use change and reservoir construction, on particulate organic carbon (POC) transport, we collected monthly water samples during September 2007 to August 2009 from the Longchuanjiang River to understand seasonal variations in the concentrations of organic carbon species and their sources and the yield of organic and inorganic carbon from the catchment in the Upper Yangtze basin. The contents of riverine POC, total organic carbon and total suspended sediment (TSS) changed synchronously with water discharge, whereas the contents of dissolved organic carbon had a small variation. The POC concentration in the suspended sediment decreased non‐linearly with increasing TSS concentration. Higher molar C/N ratio of particulate organic matter (average 77) revealed that POC was dominated by terrestrially derived organic matter in the high flows and urban wastewaters in the low flows. The TSS transported by this river was 2.7 × 105 t/yr in 2008. The specific fluxes of total organic carbon and dissolved inorganic carbon (DIC) were 5.6 and 6 t/km2/yr, respectively, with more than 90% in the high flow period. A high carbon yield in the catchment of the upper Yangtze was due to human‐induced land use alterations and urban wastes. Consistent with most rivers in the monsoon climate regions, the dissolved organic carbon–POC ratio of the export flux was low (0.41). Twenty‐two percent (0.9 t/km2/yr) of POC out of 4 t/km2/yr was from autochthonous production and 78% (3.1 t/km2/yr) from allochthonous production. The annual sediment load and hence the organic carbon flux have been affected by environmental alterations of physical, chemical and hydrological conditions in the past 50 years, demonstrating the impacts of human disturbances on the global and local carbon cycling. Finally, we addressed that organic carbon flux should be reassessed using adequate samples (i.e. at least two times in low‐flow month, four times in high‐flow month and one time per day during the flood period), daily water discharge and sediment loads and appropriate estimate method. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

17.
The Senegal River is of intermediate size accommodating at present about 3.5 million inhabitants in its catchment. Its upstream tributaries flow through different climatic zones from the wet tropics in the source area in Guinea to the dry Sahel region at the border between Senegal and Mauritania. Total suspended matter, particulate and dissolved organic carbon and nitrogen as well as nutrient concentrations were determined during the dry and wet seasons at 19 locations from the up- to downstream river basin. The aims of the study were to evaluate the degree of human interference, to determine the dissolved and particulate river discharges into the coastal sea and to supply data to validate model results. Statistical analyses showed that samples from the wet and dry season are significantly different in composition and that the upstream tributaries differ mainly in their silicate and suspended matter contents. Nutrient concentrations are relatively low in the river basin, indicating low human impact. Increasing nitrate concentrations, however, show the growing agriculture in the irrigated downstream areas. Particulate organic matter is dominated by C4 plants during the wet season and by aquatic plankton during the dry season. The total suspended matter (TSM) discharge at the main gauging station Bakel was about 1.93 Tg yr−1 which is in the range of the only available literature data from the 1980s. The calculated annual discharges of particulate organic carbon (POC), dissolved organic carbon (DOC) and dissolved organic nitrogen (DON) are 55.8 Gg yr−1, 54.1 Gg yr−1, and 5.3 Gg yr−1, respectively. These first estimates from the Senegal River need to be verified by further studies.  相似文献   

18.
The temporal variability of suspended sediment, nitrates (NO3) and dissolved (DOC) and particulate organic carbon concentrations was analysed in the Alegria agricultural watershed over a 2‐year period. Nine storm events were studied, including an exhaustive analysis of hydrometeorological conditions, quantification of fluxes, and concentration‐discharge hysteresis loop characterization. The overall aim was to study the variability in these components during storm events and determine the mechanisms (flow paths) affecting the trajectories, from the source to the stream. The forms, rotational patterns and trends of hysteretic loops were investigated, and relationships between hysteresis features and hydrological parameters were studied. The results revealed clear differences between particulate (suspended sediment, particulate organic carbon) and dissolved (DOC, NO3) matter transport responses. Movement of the particulate matter was attributed to surface water, as reflected in clockwise hysteresis loops, whereas dissolved matter showed, in general, counterclockwise hysteresis loops, indicating a time delay in the arrival of solutes to the stream. This could be related to subsurface flow paths for DOC and a groundwater source for NO3. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

19.
The distribution of the metal ions Zn and Pb between particulate and dissolved phase in river Glatt was studied by field measurements and compared with calculated simulations, using parameters obtained by adsorption experiments with natural suspended particulate material. Differences in distribution coefficients obtained from field data are observed in function of the sampling locations and of the composition of the particulate matter.Experiments in which metal ion solutions are titrated with a suspension of natural particles and analyzed by anodic stripping voltammetry, are interpreted in terms of binding capacities and conditional stability constants of Zn and Pb with the surface sites. Binding constants of a particular metal ion varied very little for all samples. We obtained mean values for the conditional average complex formation constants at pH 8 of: logcond K Pb = 9.44 ± 0.18 and logcond K Zn = 8.17 ± 0.20. At this pH, binding capacities of 5 10–3 – 1.7 10–2 mol/kg of particles were obtained for samples collected at different locations and times; organic material, iron and manganese oxides are considered to be the main components that control the adsorption to the particles.Distribution coefficients are calculated from the experimentally obtained binding capacities and conditional stability constants. Calculated distribution coefficients for Zn agree with those obtained from the field data and are not very sensitive to changes in the composition of the solution. Good agreement was obtained for lead as well; for some samples it was important to take two types of sites with different affinity into consideration.  相似文献   

20.
The sandy littoral zone of Lake Tegel (Berlin, Germany) was investigated during 2004–2006 down to sediment depths ≥26 cm to derive a scheme of seasonal carbon turnover under induced bank filtration conditions. Carbon turnover processes were quantified regarding external and internal sources of dissolved and particulate organic matter (DOM and POM), primary production, community respiration, redox potential as well as specific loads of soluble chemical compounds such as nitrogen, iron, manganese and DOC.Over the course of the year, infiltrating DOC decreased by about 13–20% within the upper 26 cm sediment of the infiltration stretch. Gradients of all observed soluble compounds that are highly cross-linked to biological activities were highest in the topmost centimetre. In this depth mass balances (output–input) were negative concerning NO3-N (−1 mg dm−2 d−1, summer mean) and DOC (−2 mg dm−2 d−1, winter mean), respectively, while specific loads of cations such as manganese reached up to 0.2 mg dm−2 d−1 during summer. Carbon mineralization ranged between 3 and 7 mg C dm−2 d−1 and was nearly twice as high in summer as in winter. The turnover of the infiltrating DOC contributed maximally 25% in summer to 50% in winter to the entire organic carbon mineralization. Gross and net primary production differed up to a factor of >10, indicating very fast turnover reactions and the predominance of community respiration and mineralization, respectively. The POC in the upper sediment layer (10 cm) temporally varied around 1% sediment d.w.; benthic algae, organic seston input and autumnal leaf fall contributed similar percentages to the POC pool.  相似文献   

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