共查询到20条相似文献，搜索用时 15 毫秒
1.
Bruce A. Cantor 《Icarus》2007,186(1):60-96
From 15 September 1997 through 21 January 2006, only a single planet-encircling martian dust storm was observed by MGS-MOC. The onset of the storm occurred on 26 June 2001 (Ls=184.7°), earliest recorded to date. It was initiated in the southern mid-to-low latitudes by a series of local dust storm pulses that developed along the seasonal cap edge in Malea and in Hellas basin (Ls=176.2°-184.4°). The initial expansion of the storm, though asymmetric, was very rapid in all directions (3-32 m s−1). The main direction of propagation, however, was to the east, with the storm becoming planet encircling in the southern hemisphere on Ls=192.3°. Several distinct centers of active dust lifting were associated with the storm, with the longest persisting for 86 sols (Syria-Claritas). These regional storms helped generate and sustain a dust cloud (“haze”), which reached an altitude of about 60 km and a peak opacity of τdust∼5.0. By Ls=197.0°, the cloud had encircled the entire planet between 59.0° S and 60.0° N, obscuring all but the largest volcanoes. The decay phase began around Ls∼200.4° with atmospheric dust concentrations returning to nominal seasonal low-levels at Ls∼304.0°. Exponential decay time constants ranged from 30-117 sols. The storm caused substantial regional albedo changes (darkening and brightening) as a result of the redistribution (removal and deposition) of a thin veneer of surface dust at least 0.1-11.1 μm thick. It also caused changes in meteorological phenomena (i.e., dust storms, dust devils, clouds, recession of the polar caps, and possibly surface temperatures) that persisted for just a few weeks to more than a single Mars year. The redistribution of dust by large annual regional storms might help explain the long period (∼30 years) between the largest planet-encircling dust storms events. 相似文献
2.
The dramatic growth and evolution of the 2001 martian global dust storm were captured using the Submillimeter Wave Astronomy Satellite (SWAS). While the lower and middle atmosphere (pressures greater than 50 μbar, up to ∼45 km altitude) showed rapid heating of up to 40 K, the average surface brightness temperature plummeted by ∼20 K at the peak of the storm. The storm appears to have had little impact on the global temperature structure at altitudes above ∼ 10 μbar (∼ 60 km). 相似文献
3.
Michael D. Smith 《Icarus》2009,202(2):444-452
We use infrared images obtained by the Thermal Emission Imaging System (THEMIS) instrument on-board Mars Odyssey to retrieve the optical depth of dust and water ice aerosols over more than 3.5 martian years between February 2002 (MY 25, Ls=330°) and December 2008 (MY 29, Ls=183°). These data provide an important bridge between earlier TES observations and recent observations from Mars Express and Mars Reconnaissance Orbiter. An improvement to our earlier retrieval [Smith, M.D., Bandfield, J.L., Christensen, P.R., Richardson, M.I., 2003. J. Geophys. Res. 108, doi:10.1029/2003JE002114] to include atmospheric temperature information from THEMIS Band 10 observations leads to much improved retrievals during the largest dust storms. The new retrievals show moderate dust storm activity during Mars Years 26 and 27, although details of the strength and timing of dust storms is different from year to year. A planet-encircling dust storm event was observed during Mars Year 28 near Southern Hemisphere Summer solstice. A belt of low-latitude water ice clouds was observed during the aphelion season during each year, Mars Years 26 through 29. The optical depth of water ice clouds is somewhat higher in the THEMIS retrievals at ∼5:00 PM local time than in the TES retrievals at ∼2:00 PM, suggestive of possible local time variation of clouds. 相似文献
4.
The descent imager/spectral radiometer (DISR) instrument aboard the Huygens probe into the atmosphere of Titan measured the brightness of sunlight using a complement of spectrometers, photometers, and cameras that covered the spectral range from 350 to 1600 nm, looked both upward and downward, and made measurements at altitudes from 150 km to the surface. Measurements from the upward-looking visible and infrared spectrometers are described in Tomasko et al. [2008a. Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere. Planet. Space Sci., this volume]. Here, we very briefly review the measurements by the violet photometers, the downward-looking visible and infrared spectrometers, and the upward-looking solar aureole (SA) camera. Taken together, the DISR measurements constrain the vertical distribution and wavelength dependence of opacity, single-scattering albedo, and phase function of the aerosols in Titan's atmosphere.Comparison of the inferred aerosol properties with computations of scattering from fractal aggregate particles indicates the size and shape of the aerosols. We find that the aggregates require monomers of radius 0.05 μm or smaller and that the number of monomers in the loose aggregates is roughly 3000 above 60 km. The single-scattering albedo of the aerosols above 140 km altitude is similar to that predicted for some tholins measured in laboratory experiments, although we find that the single-scattering albedo of the aerosols increases with depth into the atmosphere between 140 and 80 km altitude, possibly due to condensation of other gases on the haze particles. The number density of aerosols is about 5/cm3 at 80 km altitude, and decreases with a scale height of 65 km to higher altitudes. The aerosol opacity above 80 km varies as the wavelength to the −2.34 power between 350 and 1600 nm.Between 80 and 30 km the cumulative aerosol opacity increases linearly with increasing depth in the atmosphere. The total aerosol opacity in this altitude range varies as the wavelength to the −1.41 power. The single-scattering phase function of the aerosols in this region is also consistent with the fractal particles found above 60 km.In the lower 30 km of the atmosphere, the wavelength dependence of the aerosol opacity varies as the wavelength to the −0.97 power, much less than at higher altitudes. This suggests that the aerosols here grow to still larger sizes, possibly by incorporation of methane into the aerosols. Here the cumulative opacity also increases linearly with depth, but at some wavelengths the rate is slightly different than above 30 km altitude.For purely fractal particles in the lowest few km, the intensity looking upward opposite to the azimuth of the sun decreases with increasing zenith angle faster than the observations in red light if the single-scattering albedo is assumed constant with altitude at these low altitudes. This discrepancy can be decreased if the single-scattering albedo decreases with altitude in this region. A possible explanation is that the brightest aerosols near 30 km altitude contain significant amounts of methane, and that the decreasing albedo at lower altitudes may reflect the evaporation of some of the methane as the aerosols fall into dryer layers of the atmosphere. An alternative explanation is that there may be spherical particles in the bottom few kilometers of the atmosphere. 相似文献
5.
The electrical conductivity and electrical charge on the aerosols in atmosphere of Titan are computed for altitudes between 0 and 400 km. Ionization of methane and nitrogen due to galactic cosmic rays (GCR) is important at night where these ions are converted to ion clusters such as CH+5CH4, C7H+7, C4H+7, and H4C7N+. The ubiquitous aerosols observed also play an important role in determining the charge distribution in the atmosphere. Because polycyclic aromatic hydrocarbons (PAHs) are expected in Titan's atmosphere and have been observed in the laboratory and found to be electrophilic, we consider the formation of negative ions. During the night, the very smallest molecular complexes accept free electrons to form negative ions. This results in a large reduction of the electron abundance both in the region between 150 and 350 km over that predicted when such aerosols are not considered. During the day time, ionization by photoemission from aerosols irradiated by solar ultraviolet (UV) radiation overwhelms the GCR-produced ionization. The presence of hydrocarbon and nitrile minor constituents substantially reduces the UV flux in the wavelength band from the cutoff of CH4 at 155 to 200 nm. These aerosols have such a low ionization potential that the bulk of the solar radiation at longer wavelengths is energetic enough to produce a photoionization rate sufficient to create an ionosphere even without galactic cosmic ray (GCR) bombardment. At altitudes below 60 km, the electron and positive ion abundances are influenced by the three-body recombination of ions and electrons. The addition of this reaction significantly reduces the predicted electron abundance over that previously predicted. Our calculations for the dayside show that the peaks of the charge distributions move to larger values as the altitude increases. This variation is the result of the increased UV flux present at the highest altitudes. Clearly, the situation is quite different than that for the night where the peak of the distribution for a particular size is nearly constant with altitude when negative ions are not present. The presence of very small aerosol particles (embryos) may cause the peak of the distribution to decrease from about 8 negative charges to as little as one negative charge or even zero charge. This dependence on altitude will require models of the aerosol formation to change their algorithms to better represent the effect of charged aerosols as a function of altitude. In particular, the charge state will be much higher than previously predicted and it will not be constant with altitude during the day time. Charging of aerosol particles, whether on the dayside or nightside, has a major influence on both the electron abundance and electrical conductivity. The predicted conductivities are within the measurement range of the HASI PWA instrument over most but not all, of the altitude range sampled. 相似文献
6.
Active dust devils were observed in Syria Planum in Mars Observer Camera - Wide Angle (MOC-WA) and High Resolution Stereo Camera (HRSC) imagery acquired on the same day with a time delay of ∼26 min. The unique operating technique of the HRSC allowed the measurement of the traverse velocities and directions of motion. Large dust devils observed in the HRSC image could be retraced to their counterparts in the earlier acquired MOC-WA image. Minimum lifetimes of three large (avg. ∼700 m in diameter) dust devils are ∼26 min, as inferred from retracing. For one of these large dust devil (∼820 m in diameter) it was possible to calculate a minimum lifetime of ∼74 min based on the measured horizontal speed and the length of its associated dust devil track. The comparison of our minimum lifetimes with previous published results of minimum and average lifetimes of small (∼19 m in diameter, avg. min. lifetime of ∼2.83 min) and medium (∼185 m in diameter, avg. min. lifetime of ∼13 min) dust devils imply that larger dust devils on Mars are active for much longer periods of time than smaller ones, as it is the case for terrestrial dust devils. Knowledge of martian dust devil lifetimes is an important parameter for the calculation of dust lifting rates. Estimates of the contribution of large dust devils (>300-1000 m in diameter) indicate that they may contribute, at least regionally, to ∼50% of dust entrainment by dust devils into the atmosphere compared to the dust devils <300 m in diameter given that the size-frequency distribution follows a power-law. Although large dust devils occur relatively rarely and the sediment fluxes are probably lower compared to smaller dust devils, their contribution to the background dust opacity by dust devils on Mars could be at least regionally large due to their longer lifetimes and ability of dust lifting into high atmospheric layers. 相似文献
7.
《Icarus》1986,66(1):2-21
A refined technique is presented for deriving 9-μm extinction opacities of the Mars atmosphere from brightness temperature measurements made by the Viking Infrared Thermal Mapper. Improvements include modeling of the vertical temperature profile, a surface-atmosphere temperature discontinuity, and the effects of surface emissitivity and particle scattering. The routine is applied to the Mars Average Data Set to yield zonal mean opacities for more than one Mars year. The mean 9-μm opacity for one year is 0.5, yet the mode value is only 0.056, due to the very skewed distribution. Time histories of opacity at the Viking Lander 1 and 2 sites are generated and compared to in situ data. Opacity maps are presented for the period Ls 168–270 covering the 1977a dust storm; these show the genesis and spread of the storm with 10° Ls resolution. 相似文献
8.
Marykutty Michael Sachchida N. Tripathi Pratima Arya Anne Wellbrock 《Planetary and Space Science》2011,59(9):880-885
Observations by several instruments onboard the Cassini spacecraft revealed the existence of heavy hydrocarbon and nitrile species with masses of several thousand atomic mass units in the ionosphere of Titan. These very large molecules are in fact aerosols. The goal of this paper is to compute the concentrations of the charged aerosols in the upper atmosphere (950-1200 km) of Titan. The charging of these aerosols has been studied using the charge balance equations, where positive ions, negative ions, electrons, neutral and charged aerosols are included. Number concentrations of charged aerosols are compared with those observed by the Cassini instruments. The present work estimates the aerosol mass density as 1-10 kg/m3, which is within the predicted range. The results show that the aerosols must be smaller than 10 nm in order to have reasonable agreement with observations by the Cassini Plasma Spectrometer. 相似文献
9.
Methods for the analysis of data from the Planetary Fourier Spectrometer on the Mars Express Mission
Davide Grassi N.I. Ignatiev L.V. Zasova A. Maturilli V. Formisano M. Giuranna 《Planetary and Space Science》2005,53(10):1017-1034
This work presents an algorithm for the scientific analysis of individual calibrated measurements from the Planetary Fourier spectrometer (PFS).The instrument, included in the scientific payload of the ESA Mars Express mission to Mars, acquires spectra in the range between 250 and 8200 cm−1, with a sampling step of ∼1 cm−1 and an effective resolution of ∼2 cm−1. The observed radiance depends on several parameters of the atmosphere and surface of Mars as described by the radiative transfer equation. Adopting the very general formalism of Bayesian analysis, we determined which quantities are actually retrievable from individual measurements. Namely, they are: the surface temperature, the column density of dust and water ice aerosols in the atmosphere, the air temperature as a function of altitude (in the indicative range 5-45 km above the surface), the surface pressure, and the column density of water vapor and carbon monoxide. These evaluations are carried out taking into account the noise equivalent radiance (NER) of the instrument and the natural variabilities of the investigated parameters in the Martian environment, as estimated from the expectations of the European Martian Climate Dataset v3.1 (EMCD). Other parameters included in the radiative transfer equation shall be assumed as known, because they are not retrievable from individual measurements due to the instrumental NER or an underconstrained inverse problem: the surface emissivity in the thermal infrared, the optical properties of suspended dust and the analytical shape of dust concentration vs. altitude.During the development of the algorithm devoted to these studies, different approaches were evaluated on the basis of formal, computational and scientific considerations, with the aim to develop the general design of an integrated software package.The resulting code was extensively tested on a wide set of simulated PFS spectra. These spectra were computed from the atmospheric and surface conditions extracted from the EMCD, assumed to be representative of the Martian environment for different values of latitude, local time and season. Their comparison with the retrievals from simulated observations allowed us to evaluate the systematic and random errors affecting the procedures with respect to the different quantities involved. The code evaluates the surface temperature with an error in the order of 1 K, while the vertical air temperature profile is computed with an uncertainty less than 2 K from in the region between 5 and 20 km above the surface, increasing up to 7 K at 50 km. The column opacity of dust, measured in terms of integrated optical thickness at 1100 cm−1, is computed with an error of around 0.13. The surface pressure determination is carried out with a typical uncertainty of 0.2-0.3 millibar. Several auxiliary tests allowed us to study the correlations between the different retrieval errors and the possible causes of incorrect PFS data interpretation. The choice of a suitable model for the dust optical properties is demonstrated to be particularly critical.This paper also presents the first discussion about application of the procedure to actual PFS Martian data. Despite the calibration issues still affecting the determination of absolute radiance in the near-infrared, the algorithm is able to achieve a satisfactory modeling of observations in a wide range of situations. 相似文献
10.
V. Vuitton P. Lavvas M. Galand G.R. Lewis A.J. Coates J.-E. Wahlund 《Planetary and Space Science》2009,57(13):1558-662
The Electron Spectrometer (ELS), one of the sensors making up the Cassini Plasma Spectrometer (CAPS) revealed the existence of numerous negative ions in Titan's upper atmosphere. The observations at closest approach (∼1000 km) show evidence for negatively charged ions up to ∼10,000 amu/q, as well as two distinct peaks at 22±4 and 44±8 amu/q, and maybe a third one at 82±14 amu/q. We present the first ionospheric model of Titan including negative ion chemistry. We find that dissociative electron attachment to neutral molecules (mostly HCN) initiates the formation of negative ions. The negative charge is then transferred to more acidic molecules such as HC3N, HC5N or C4H2. Loss occurs through associative detachment with radicals (H and CH3). We attribute the three low mass peaks observed by ELS to CN−, C3N−/C4H− and C5N−. These species are the first intermediates in the formation of the even larger negative ions observed by ELS, which are most likely the precursors to the aerosols observed at lower altitudes. 相似文献
11.
P.G.J. Irwin N.A. Teanby G.R. Davis L.N. Fletcher G.S. Orton D. Tice J. Hurley S.B. Calcutt 《Icarus》2011,216(1):141-158
Observations of Neptune were made in September 2009 with the Gemini-North Telescope in Hawaii, using the NIFS instrument in the H-band covering the wavelength range 1.477–1.803 μm. Observations were acquired in adaptive optics mode and have a spatial resolution of approximately 0.15–0.25″.The observations were analysed with a multiple-scattering retrieval algorithm to determine the opacity of clouds at different levels in Neptune’s atmosphere. We find that the observed spectra at all locations are very well fit with a model that has two thin cloud layers, one at a pressure level of ∼2 bar all over the planet and an upper cloud whose pressure level varies from 0.02 to 0.08 bar in the bright mid-latitude region at 20–40°S to as deep as 0.2 bar near the equator. The opacity of the upper cloud is found to vary greatly with position, but the opacity of the lower cloud deck appears remarkably uniform, except for localised bright spots near 60°S and a possible slight clearing near the equator.A limb-darkening analysis of the observations suggests that the single-scattering albedo of the upper cloud particles varies from ∼0.4 in regions of low overall albedo to close to 1.0 in bright regions, while the lower cloud is consistent with particles that have a single-scattering albedo of ∼0.75 at this wavelength, similar to the value determined for the main cloud deck in Uranus’ atmosphere. The Henyey-Greenstein scattering particle asymmetry of particles in the upper cloud deck are found to be in the range g ∼ 0.6–0.7 (i.e. reasonably strongly forward scattering).Numerous bright clouds are seen near Neptune’s south pole at a range of pressure levels and at latitudes between 60 and 70°S. Discrete clouds were seen at the pressure level of the main cloud deck (∼2 bar) at 60°S on three of the six nights observed. Assuming they are the same feature we estimate the rotation rate at this latitude and pressure to be 13.2 ± 0.1 h. However, the observations are not entirely consistent with a single non-evolving cloud feature, which suggests that the cloud opacity or albedo may vary very rapidly at this level at a rate not seen in any other giant-planet atmosphere. 相似文献
12.
During the period July 14–September 11, 1973, about 25 000 television pictures of Mars were obtained using a 0.7m telescope in ten spectral regions. A dust storm in moderate latitudes was recorded. It started before Mars passed perigee. During the observation period the atmosphere was gradually clearing.About 3000 pictures of Mars were taken using a 0.5m meniscus telescope during the period of Nobember 19, 1973–February 19, 1974. On November 19 the atmosphere was very hazy and heavy dust clouds were recorded. The second dust storm cleared during December through January. 相似文献
13.
Condensation in Titan’s atmosphere at the Huygens landing site 总被引：1，自引：0，他引：1
14.
The effects of metallicity and grain growth and settling on the early evolution of gaseous protoplanets 总被引：1，自引：0，他引：1
Giant protoplanets formed by gravitational instability in the outer regions of circumstellar disks go through an early phase of quasi-static contraction during which radii are large (∼1 AU) and internal temperatures are low (<2000 K). The main source of opacity in these objects is dust grains. We investigate two problems involving the effect of opacity on the evolution of isolated, non-accreting planets of 3, 5, and 7 MJ. First, we pick three different overall metallicities for the planet and simply scale the opacity accordingly. We show that higher metallicity results in slower contraction as a result of higher opacity. It is found that the pre-collapse time scale is proportional to the metallicity. In this scenario, survival of giant planets formed by gravitational instability is predicted to be more likely around low-metallicity stars, since they evolve to the point of collapse to small size on shorter time scales. But metal-rich planets, as a result of longer contraction times, have the best opportunity to capture planetesimals and form heavy-element cores. Second, we investigate the effects of opacity reduction as a result of grain growth and settling, for the same three planetary masses and for three different values of overall metallicity. When these processes are included, the pre-collapse time scale is found to be of order 1000 years for the three masses, significantly shorter than the time scale calculated without these effects. In this case the time scale is found to be relatively insensitive to planetary mass and composition. However, the effects of planetary rotation and accretion of gas and dust, which could increase the timescale, are not included in the calculation. The short time scale we find would preclude metal enrichment by planetesimal capture, as well as heavy-element core formation, over a large range of planetary masses and metallicities. 相似文献
15.
Richard W. Zurek 《Icarus》1978,35(2):196-208
This paper examines the solar heating of the Martian atmosphere during the 1971 global dust storm observed by Mariner 9. Radiative scattering as well as absorption is included by utilizing the delta-Eddington approximation to the full radiative transfer equation. The necessary optical parameters are generated by a Mie program which uses a size distribution and a complex refractive index inferred from a number of sources, particularly from recent analyces of Mariner 9 UVS and TV observations. Assuming uniform mixing of the dust, the solar heating per unit mass during a Martian global dust storm is remarkably uniform with height for small solar zenith angles. Heating rates may reach 80°K day? for overhead sunlight. Overall, 20% of the direct insolation is absorbed by the dust-laden atmosphere. Even optically thin widespread dust hazes may produce heating rates of several degrees Kelvin per day. 相似文献
16.
We acquired high spectral and spatial resolution hyperspectral imaging spectrometer observations of Mars from near-UV to near-IR wavelengths (∼300 to 1020 nm) using the STIS instrument on the Hubble Space Telescope during the 1999, 2001, and 2003 oppositions. The data sets have been calibrated to radiance factor (I/F) and map-projected for comparison to each other and to other Mars remote sensing measurements. We searched for and (where detected) mapped a variety of iron-bearing mineral signatures within the data. The strong and smooth increase in I/F from the near-UV to the visible that gives Mars its distinctive reddish color indicates that poorly crystalline ferric oxides dominate the spectral properties of the high albedo regions (as well as many intermediate and low albedo regions), a result consistent with previous remote sensing studies of Mars at these wavelengths. In the near-IR, low albedo regions with a negative spectral slope and/or a distinctive ∼900 nm absorption feature are consistent with, but not unique indicators of, the presence of high-Ca pyroxene or possibly olivine. Mixed ferric-ferrous minerals could also be responsible for the ∼900 nm feature, especially in higher albedo regions with a stronger visible spectral slope. We searched for the presence of several known diagnostic absorption features from the hydrated ferric sulfate mineral jarosite, but did not find any unique evidence for its occurrence at the spatial scale of our observations. We identified a UV contrast reversal in some dark region spectra: at wavelengths shorter than about 340 nm these regions are actually brighter than classical bright regions. This contrast reversal may be indicative of extremely “clean” low albedo surfaces having very little ferric dust contamination. Ratios between the same regions observed during the planet-encircling dust storm of 2001 and during much clearer atmospheric conditions in 2003 provide a good direct estimate of the UV to visible spectral characteristics of airborne dust aerosols. These HST observations can help support the calibration of current and future Mars orbital UV to near-IR spectrometers, and they also provide a dramatic demonstration that even at the highest spatial resolution possible to achieve from the Earth, spectral variations on Mars at these wavelengths are subtle at best. 相似文献
17.
A semiquantitative analysis of clearing in the 1971 great dust storm on Mars is presented as a function of time and altitude, using Mariner 9 orange- and visual-light photos. Steady settling of dust approximately accounts for the decline of the storm after December 22, 1971. Continuous settling cannot be invoked prior to that date; injection of dust into the atmosphere, i.e., a storm resurgence, occurred in mid-December 1971. Theoretical models of optical depth versus time are developed for various distributions of particles in the atmosphere. By intespreting settling in terms of Stokes' law, estimates of the maximum radii of dust particles throughout the atmosphere have been obtained. Models which best account for the dust-storm decline indicate particles ? 5μm in diameter high in the atmosphere, with a concentration of larger particles (? 10μm) near the ground in the lowest parts of Mars. Long-term thin high hazes should persist through much of the Martian year, perhaps clearing before perihelion. 相似文献
18.
Christina Stanzel Martin Pätzold Patrick L. Whelley Ronald Greeley the HRSC Co-Investigator Team 《Icarus》2008,197(1):39-51
A total of 205 dust devils were detected in 23 High Resolution Stereo Camera (HRSC) images taken between January 2004 and July 2006 with the ESA Mars Express orbiter, in which average dust devil heights were ∼660 m and average diameters were ∼230 m. For the first time, dust devil velocities were directly measured from orbit, and range from 1 to 59 m/s. The observed dust devil directions of motion are consistent with data derived from a General Circulation Model (GCM). In some respects HRSC dust devil properties agree favorably with data from the NASA Mars Exploration Rover Spirit dust devil analyses. The spatial distribution of the active dust devils detected by HRSC supports the conjecture that the ascending branch of the Hadley circulation is responsible for the increase in dust devil activity, especially observed during southern summer between 50° and 60° S latitude. Combining the dust-lifting rate of 19 kg/km2/sol derived from the Spirit observations with the fewer in number but larger in size dust devils from various other locations observed by HRSC, we suggest that dust devils make a significant contribution to the dust entrainment into the atmosphere and to the martian dust cycle. 相似文献
19.
E.C. Sittler Jr. A. Ali J.F. Cooper R.E. Johnson D.T. Young 《Planetary and Space Science》2009,57(13):1547-17884
Discovery by Cassini's plasma instrument of heavy positive and negative ions within Titan's upper atmosphere and ionosphere has advanced our understanding of ion neutral chemistry within Titan's upper atmosphere, primarily composed of molecular nitrogen, with ~2.5% methane. The external energy flux transforms Titan's upper atmosphere and ionosphere into a medium rich in complex hydrocarbons, nitriles and haze particles extending from the surface to 1200 km altitudes. The energy sources are solar UV, solar X-rays, Saturn's magnetospheric ions and electrons, solar wind and shocked magnetosheath ions and electrons, galactic cosmic rays (GCR) and the ablation of incident meteoritic dust from Enceladus’ E-ring and interplanetary medium. Here it is proposed that the heavy atmospheric ions detected in situ by Cassini for heights >950 km, are the likely seed particles for aerosols detected by the Huygens probe for altitudes <100 km. These seed particles may be in the form of polycyclic aromatic hydrocarbons (PAH) containing both carbon and hydrogen atoms CnHx. There could also be hollow shells of carbon atoms, such as C60, called fullerenes which contain no hydrogen. The fullerenes may compose a significant fraction of the seed particles with PAHs contributing the rest. As shown by Cassini, the upper atmosphere is bombarded by magnetospheric plasma composed of protons, H2+ and water group ions. The latter provide keV oxygen, hydroxyl and water ions to Titan's upper atmosphere and can become trapped within the fullerene molecules and ions. Pickup keV N2+, N+ and CH4+ can also be implanted inside of fullerenes. Attachment of oxygen ions to PAH molecules is uncertain, but following thermalization O+ can interact with abundant CH4 contributing to the CO and CO2 observed in Titan's atmosphere. If an exogenic keV O+ ion is implanted into the haze particles, it could become free oxygen within those aerosols that eventually fall onto Titan's surface. The process of freeing oxygen within aerosols could be driven by cosmic ray interactions with aerosols at all heights. This process could drive pre-biotic chemistry within the descending aerosols. Cosmic ray interactions with grains at the surface, including water frost depositing on grains from cryovolcanism, would further add to abundance of trapped free oxygen. Pre-biotic chemistry could arise within surface microcosms of the composite organic-ice grains, in part driven by free oxygen in the presence of organics and any heat sources, thereby raising the astrobiological potential for microscopic equivalents of Darwin's “warm ponds” on Titan. 相似文献
20.
《Icarus》1986,68(1):99-119
It is proposed that dust storms on Mars that develop during predawn hours may be triggered by a freeze/thaw dust injection process. The model is based on a phenomenon that was observed during the Viking Gas Exchange experiments on Mars, in which adsorbed gas was catastrophically desorbed from soil samples when exposed to humidification at ∼5°C. Similar conditions may develop at midlatitude locations on Mars near perihelion, and a similar humidification-driven desorption process might occur in the soil column. If soils are dampened during humikification, desorbed gases in confined pore spaces could possibly reach 8.6 bar. Diurnal freezing may possibly cause H2O to crystallize within the pores, possibly producing cohesive soil failure, release of the trapped gas, and explosive injection of freeze-dried powdery overburden dust into the atmospheric column. The process could potentially occur at 5–20 cm depth, and the freeze/thaw dust injection event may initiate after 10:00 PM local time (20°S lat). Dust would be injected at velocities approaching 450 m sec−1 and it would remain in the atmosphere for several hours before settling out. The plumes could potentially regenerate diurnally until the growing atmospheric dust load produced sufficient dampening of the diurnal thermal wave to prevent freeze/thaw. Seasonal replenishment of H2O could potentially occur by upward migration from depth during the period between 150 and 475 sols after perihelion. The model was experimentally tested and the results were in good agreement with predictions, although a factor of 14 times more gas evolved from the laboratory samples than from the Viking samples. Most of the characteristics of the predawn storms could possibly be adequately explained by the freeze/thaw injection model, including (1) predawn onsets, (2) postperihelion seasonal occurence, (3) daily recurrence during the initial phases of the storms, and (4) generation of blue clouds (H2O ice) at the storm sites. The process may possibly occur over widespread locations at midlatitudes during seasonal retreat of “tempofrost” from these latitude belts. Permanent low albedo features in these latitude belts may possibly be regions of preferential humidification-induced dust entrainment and net dust removal. The H2O injected into the atmosphere may potentially be a major source of H2SO4 and HCl aerosols, which may possibly chemically react with the regolith to form soluble sulfate and chloride salts. Mg2+ may be preferentially depleted from the dust. 相似文献