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1.
Headcut formation and migration was sometimes mistaken as the result of overland flow, without realizing that the headcut was formed and being influenced by flow through soil pipes into the headcut. To determine the effects of the soil pipe and flow through a soil pipe on headcut migration in loessic soils, laboratory experiments were conducted under free drainage conditions and conditions of a perched water table. Soil beds with a 3-cm deep initial headcut were formed in a flume with a 1.5-cm diameter soil pipe 15 cm below the bed surface. Overland flow and flow into the soil pipe was applied at a constant rate of 68 and 1 l min−1 at the upper end of the flume. The headcut migration rate and sediment concentrations in both surface (channel) and subsurface (soil pipe) flows were measured with time. The typical response was the formation of a headcut that extended in depth until an equilibrium scour hole was established, at which time the headcut migrated upslope. Pipeflow caused erosion inside the soil pipe at the same time that runoff was causing a scour hole to deepen and migrate. When the headcut extended to the depth of the soil pipe, surface runoff entering the scour hole interacted with flow from the soil pipe also entering the scour hole. This interaction dramatically altered the headcut processes and greatly accelerated the headcut migration rates and sediment concentrations. Conditions in which a perched water table provided seepage into the soil pipe, in addition to pipeflow, increased the sediment concentration by 42% and the headcut migration rate by 47% compared with pipeflow under free drainage conditions. The time that overland flow converged with subsurface flow was advanced under seepage conditions by 2.3 and 5.0 min compared with free drainage conditions. This study confirmed that pipeflow dramatically accelerates headcut migration, especially under conditions of shallow perched water tables, and highlights the importance of understanding these processes in headcut migration processes. © 2020 John Wiley & Sons, Ltd. 相似文献
2.
An investigation of elevated concentrations of nickel and chromium in certain ground water samples collected at Williams Air Force Base (AFB) indicated that type 304 stainless steel well materials are the source. Chloride in the ground water has apparently caused crevice corrosion of the stainless steel well screens installed during site characterization. An evaluation of site geochemistry suggested that chromium released from the well screen would precipitate, while nickel would remain dissolved. Thus, low-flow purging and sampling significantly reduces the chromium found in the ground water samples because such sampling minimizes the collection of artificially entrained particulates. In contrast to chromium, nickel concentrations did not decrease during low-flow purging and sampling, indicating that it is dissolved. Nickel and chromium concentrations are both low following high-volume purging when turbidity levels are stabilized below 10 nephelometric turbidity units prior to sampling. In the latter case, chromium concentration is low because particulate collection is minimized, and nickel concentration is low because of increased dilution. Based on these results, it is recommended that elevated levels of nickel and chromium in ground water samples collected from stainless steel monitoring wells be carefully evaluated, because well materials may be the source. In addition, although low-volume purging is increasingly becoming the sampling method of choice, high-volume purging may be a useful means of determining whether the well materials influence nickel and chromium concentrations. 相似文献
3.
In many smallholder farms in sub-Saharan Africa dambos are used for grazing and crop production especially horticultural crops. Increased use of dambos especially for crop production can result in ground and surface water pollution. Ground and surface water quality along a dambo transect in Chihota, Zimbabwe, was investigated between October 2013 and February 2014. The transect was divided into; upland (control), dambo gardens (mid-slope) and the river (valley bottom). Water samples for quality assessment were collected in October 2013 (peak of dry season) and February 2014 (peak of rainy season). The collected water samples were analysed for pH, faecal coliforms, total nitrogen, electrical conductivity, total dissolved solids (TDS), and some selected nutrients (P, K, Ca, Mg, Na, Zn, and Cu). Water pH was 7.0, 6.4 and 6.1 for river water, garden and upland wells respectively. During the wet season total nitrogen (TN) concentrations were 233 mg/L for uplands, 242 mg/L for gardens and 141 mg/L for the river. During the dry season, TN concentrations were all below 20 mg/L, and were not significantly different among sampling stations along the dambo transect. Dry season faecal coliform units (fcu) were significantly different and were 37.2, 30.0 and 5.0 for upland wells, garden wells and river respectively. Wet season faecal coliforms were also significantly different and were 428.5, 258.0 and 479.4 fcu for upland wells, garden wells and river respectively. The other measured physico-chemical parameters also varied with sampling position along the transect. It was concluded that TN and fcu in sampled water varied with season and that wet season concentrations were significantly higher than dry season concentrations. High concentrations of faecal coliforms and total N during the wet season was attributed to increased water movement. Water from upland wells, garden wells and river was not suitable for human consumption according to WHO standards during both the dry and wet seasons. 相似文献
4.
James C. Adamski 《水文研究》2000,14(5):849-866
Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate‐rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field‐measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water–rock interactions. Water from wells flow through small fractures, which restrict flow and increase water–rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
5.
Pesticides in Nebraska's Ground Water 总被引：1，自引：0，他引：1
《Ground Water Monitoring & Remediation》1989,9(4):126-133
More than 2263 well water samples were collected throughout Nebraska and analyzed for pesticides. Thirteen and one-half percent contained detectable levels of atrazine, but only 22 wells exceeded the health advisory of 3.0 ppb. Although the samples came from almost every county in the state, this sampling is not based solely on a randomly selected group of wells. The highest frequency of detections occurred in irrigated corn-growing areas with less than 50 feet to ground water. These areas were sampled at a greater frequency than the less vulnerable areas. Cyanazine, together with the additional triazines — simazine, propazine, prometone, and ametryne, also were detected in some well waters; however, their frequency of detection was well below that of atrazine. The triazine metribuzin was not detected.
Alachlor, propachlor, and metolachlor also were detected in trace levels in several wells. Five of 2072 samples analyzed for alachlor exceeded the health advisory of 0.4 ppb. Almost all of the contaminated wells were in vulnerable areas. The relatively high frequency of propachlor detections occurred in predominately irrigated corn-growing areas, rather than in areas where propachlor is traditionally applied.
The factors that appear most directly involved in the observed distribution of pesticides in ground water are the intensity of areal usage, pesticide persistence and mobility, irrigation, soil drainage capacity, and depth to ground water.
Fifteen pesticide residues were detected during this study. If ethylene dibromide and carbon tetrachloride, which were detected in ground water adjacent to grain elevators are included, a total of 17 pesticide residues have been detected in Nebraska's ground water. 相似文献
Alachlor, propachlor, and metolachlor also were detected in trace levels in several wells. Five of 2072 samples analyzed for alachlor exceeded the health advisory of 0.4 ppb. Almost all of the contaminated wells were in vulnerable areas. The relatively high frequency of propachlor detections occurred in predominately irrigated corn-growing areas, rather than in areas where propachlor is traditionally applied.
The factors that appear most directly involved in the observed distribution of pesticides in ground water are the intensity of areal usage, pesticide persistence and mobility, irrigation, soil drainage capacity, and depth to ground water.
Fifteen pesticide residues were detected during this study. If ethylene dibromide and carbon tetrachloride, which were detected in ground water adjacent to grain elevators are included, a total of 17 pesticide residues have been detected in Nebraska's ground water. 相似文献
6.
《国际泥沙研究》2017,(2)
The drainage channel network in Vojvodina,northern part of the Republic of Serbia,in total length of around 20,000 km,transfers excessive(under)ground waters from around 2.15 million ha of lowlands.Channels are mostly in direct connection with the surrounding arable agricultural land and are exposed to different run-off,leaching and/or wind erosion processes.Close to urban areas,some channel sections serve as recipients of unrefined sewage and industrial waste waters.Water flows and velocities,as well as the transportable capacity of fluvial materials(sediments) are relatively low.This,in combination with other natural and anthropogenic impacts,contributes to sediment generation in the drainage channel network.Based on around 100 sediment samples from 46 channels,concentrations of primary nutrients(N,P and K) were elaborated in this study.Detected concentrations of macronutrients in the channel sediments(e.g.N 1-1.2%,P 100-265 and K 100-380 mg 100 g~(-1)) exceeded their content in surrounding arable land by a few fold.Also,significantly higher nutrient concentrations(in average by 50%) were detected in downstream(vs.upstream) channel sections.An excessive presence of observed elements in channel sediments,due to interactive processes between water and sediment material,can adversely influence the water quality and life conditions for channel biota and caused other negative environmental impacts such as eutrophication.These results clearly confirm that the processes of nutrient accumulation in channel sediments are greater than those in the surrounding,mostly intensively arable land areas.The erosion of unprotected agricultural areas and sediment transport as the most important pollution pathways from the drainage basin to channel network may be essential factors responsible for detected condition of nutrient accumulation. 相似文献
7.
Paul J. Squillace James F. Pankow Jack E. Barbash Curtis V. Price John S. Zogorski 《Ground Water Monitoring & Remediation》1999,19(1):67-74
Water samples collected for the determination of volatile organic compounds (VOCs) are often preserved with hydrochloric acid (HCl) to inhibit the biotransformation of the analytes of interest until the chemical analyses can he performed. However, it is theoretically possible that residual free chlorine in the HCl can react with dissolved organic carbon (DOC) to form chloroform via the haloform reaction. Analyses of 1501 ground water samples preserved with HCl from the U.S. Geological Survey's National Water-Quality Assessment Program indicate that chloroform was the most commonly detected VOC among 60 VOCs monitored. The DOC concentrations were not significantly larger in samples with detectable chloroform than in those with no delectable chloroform, nor was there any correlation between the concentrations of chloroform and DOC. Furthermore, chloroform was detected more frequently in shallow ground water in urban areas (28.5% of the wells sampled) than in agricultural areas (1.6% of the wells sampled), which indicates that its detection was more related to urban land-use activities than to sample acidification. These data provide strong evidence that acidification with HCl does not lead to the production of significant amounts of chloroform in ground water samples. To verify these results, an acidification study was designed to measure the concentrations of all trihalomethanes (THMs) that can form as a result of HCl preservation in ground water samples and to determine if ascorbic acid (C6 H8 O6 ) could inhibit this reaction if it did occur. This study showed that no THMs were formed as a result of HCl acidification, and that ascorbic acid had no discernible effect on the concentrations of THMs measured. 相似文献
8.
William R. Wise Chi-Chung Chang Rick A. Klopp Philip B. Bedient 《Ground Water Monitoring & Remediation》1991,11(2):93-100
At an aviation gasoline spill site in Traverse City, Michigan, historical records indicate a positive correlation between significant rainfall events and increased concentrations of slightly soluble organic compounds in the monitoring wells of the site. To investigate the recharge effect on ground water quality due to infiltrating, water percolating past residual oil and into the saturated zone, an in situ infiltration experiment was performed at the site. Sampling cones were set at various depths below a circular test area, 13 feet (4 meters) in diameter. Rainfall was simulated by sprinkling the test area at a rate sufficiently low to prevent runoff. The sampling cones for soil-gas and ground water quality were installed in the unsaturated and saturated zones to observe the effects of the recharge process. At the time of the test, the water table was below the residual oil layer. The responses of the soil-gas and ground water quality were monitored during the recharge and drainage periods, which resulted from the sprinkling.
Infiltrated water was determined to have transported organic constituents of the residual oil, specifically benzene, toluene, ethylbenzene, and ortho-xylene (BTEX), into the ground water beneath the water table, elevating the aqueous concentrations of these constituents in the saturated zone. Soil-gas concentrations of the organic compounds in the unsaturated zone increased with depth and time after the commencement of infiltration. Reaeration of the unconfined aquifer via the infiltrated water was observed. It is concluded that water quality measurements are directly coupled to recharge events for the sandy type of aquifer with an overlying oil phase, which was studied in this work. Ground water sampling strategies and data analysis need to reflect the effect of recharge from precipitation on shallow, unconfined aquifers where an oil phase may be present. 相似文献
Infiltrated water was determined to have transported organic constituents of the residual oil, specifically benzene, toluene, ethylbenzene, and ortho-xylene (BTEX), into the ground water beneath the water table, elevating the aqueous concentrations of these constituents in the saturated zone. Soil-gas concentrations of the organic compounds in the unsaturated zone increased with depth and time after the commencement of infiltration. Reaeration of the unconfined aquifer via the infiltrated water was observed. It is concluded that water quality measurements are directly coupled to recharge events for the sandy type of aquifer with an overlying oil phase, which was studied in this work. Ground water sampling strategies and data analysis need to reflect the effect of recharge from precipitation on shallow, unconfined aquifers where an oil phase may be present. 相似文献
9.
The hydroclimatic conditions of water runoff formation and the hydrography of Parana and Uruguay river basins in the South America are considered. A survey of the recent studies of the hydrological regime of these rivers is given. Observation data are used to evaluate the long-term average values of water runoff and suspended sediment yield in the Parana and Uruguay and their variations along the rivers. Characteristics of many-year runoff variations in the rivers were evaluated. A climate-induced increase was identified in the Parana and Uruguay water runoff, and the corresponding present-day trends in river runoff variations in both rivers were evaluated. The total water runoff and suspended sediment yield of the Parana and Uruguay into La Plata estuary were calculated. Water balance of the drainage basin of La Plata estuary was characterized. 相似文献
10.
Water and cation budgets were calculated for two sub-basins within a small low relief watershed in South-Central Ontario during a period of ephemeral runoff which was initiated by spring snow melt. The hydrology of one (upland) sub-basin was strongly influenced by seasonal fluctuations in the level of regional ground water. Saturated contributing areas formed in low lying regions adjacent to the stream channel where the water table rose to the surface, and stream discharge was a mixture of ground water and saturation overland flow. In the second sub-basin a wetland provided a large and spatially less variable saturated contributing area. Clay soils underlying the wetland resulted in a shallow perched water table, poorly drained and highly organic soils, and greatly reduced inputs of regional ground water. Stream discharge was largely the result of surface runoff from the wetland and adjacent areas of saturated soil.Inter-basin variations in water export were by far greater than variations in stream chemistry. As a result, inter-basin variations in cation export strongly reflected variations in water export over the time interval in which the majority of a given ion was lost from the watershed. Spatial differences in water export were least at the onset of runoff when basin saturation was greatest and overland flow made large contributions to the discharge from both sub-basins. Potassium and hydrogen had high concentrations at this time which caused these ions to show only small spatial differences in export. With decreases in the areal extent of soil saturation, and increases in the storage capacity of the wetland, the hydrologic contrast between sub-basins increased. Greater water loss from the upland area resulted from a greater discharge of regional ground water, and a more rapid expansion of the saturated contributing areas during storm events. Calcium, magnesium, and sodium concentrations increased steadily during the first 3 weeks of runoff, so that the peak export of these cations occurred later in the runoff period at times of higher concentration, but lower and spatially more variable discharges. Consequently, spatial differences in the loss of these ions was great and favoured the upland sub-basin, since the majority of export occurred when the hydrologic contrast between sub-basins was largest. 相似文献
11.
Since the new outfall for Boston's treated sewage effluent began operation on September 6, 2000, no change has been observed in concentrations of silver or Clostridium perfringens spores (an ecologically benign tracer of sewage), in bottom sediments at a site 2.5 km west of the outfall. In suspended sediment samples collected with a time-series sediment trap located 1.3 km south of the outfall, silver and C. perfringens spores increased by 38% and 103%, respectively, in post-outfall samples while chromium, copper, and zinc showed no change. All metal concentrations in sediments are <50% of warning levels established by the Massachusetts Water Resources Authority. An 11-year data set of bottom sediment characteristics collected three times per year prior to outfall startup provides perspective for the interpretation of post-outfall data. A greater than twofold increase in concentrations of sewage tracers (silver and C. perfringens) was observed in muddy sediments following the exceptional storm of December 11-16, 1992 that presumably moved contaminated inshore sediment offshore. 相似文献
12.
We observed long-term changes in the concentrations of dissolved ions in ground water caused by leachate from new volcanic ejecta deposited on the ground surface of the volcanic Miyakejima Island, Japan. Water samples were collected from nine wells and two rain collectors over a period of more than 10 years, and samples of runoff water were collected periodically. The samples were analyzed for temperature, pH, alkalinity, Cl− , and SO4 2− ; some of the samples were also analyzed for δ13 C. Because the leachate from the volcanic ejecta contained sulfate, we recorded an increase in SO4 2 − concentrations in the (unconfined) well water. The increase in SO4 2 − was initially detected between less than 1.4 and 5.2 years after the eruption, showing peak concentrations from 2.4 to 6.4 years after the eruption. This delayed response reflects the transit time of downward-moving SO4 2 − in the vadose zone, corresponding to an apparent movement rate of 0.4 to 7.2 cm/d. The rate relates to the mean recharge, represented as a fraction of local mean rainfall, and is calculated using the Cl− balance method. The magnitude of the recorded increases reflects the volume of volcanic mudflow on the ground surface within the basin. For the management of ground water after an eruption, it is therefore important to know the chemical properties of the volcanic ejecta and the spatial distribution of mudflow to estimate the magnitude of the effect of ejecta on ground water quality. 相似文献
13.
lINTR0DUCTIONSoiler0si0ncanbeaseriousproblemonsl0pinguplands0fthes0uthemUnitedStatesthatareintensivelycr0pped.Conservati0nprovisionsofthel985U.S.FarmBillmandateddevelopmentofaconservati0nplanonhighlyer0diblelands.Researchwasinitiatedinl9870na28-haareaattheA-E.Nels0nFarrninn0rthernMississippit0determineiftheconservati0nprovisionscouldbeachievedwhileprofitablygr0wingrowcropsincludingcott0n(GosSyPiumhirsutumL.),soybean(GlyciDemax(L.)Merr.),sorghum(SOrghumbicolor(L.)Moench),c0rn(Zeam… 相似文献
14.
A number of studies in north Queensland over the past two decades have concluded that large amounts of nutrients and sediments are exported from agricultural watersheds, particularly during wet season rainfall events. With the co-operation of a number of growers, runoff from Queensland Wet Tropics banana and cane farm paddocks in two distinct tropical river catchments was examined to provide an estimate of nutrient and sediment concentrations and export, with comparison to water quality of flow through a small urban lakes system. Median total nitrogen concentrations in cane drainage runoff (3110 microg N/L) were higher than for banana paddock drainage (2580 microg N/L), although the maximum concentration was recorded from a banana paddock (20,900 microg N/L). Nitrogen losses during post-event drainage flow were supplemented by high proportions of NO(X) (nitrate + nitrite) sourced from groundwater inputs. Banana paddocks had the highest maximum and median total phosphorus and TSS concentrations (5120 and 286 microg P/L, and 7250 and 75 mg/L respectively) compared to the cane farms (1430 and 50 microg P/L, and 1840 and 14 mg/L respectively). The higher phosphorus and TSS concentrations in the banana runoff were attributed to higher paddock slopes and a greater proportion of exposed ground surface during the wet season. Highest nutrient and TSS concentrations corresponded with samples collected near the peak discharge periods; however, the rising stage of the drainage flows, where the highest nutrient and TSS concentrations are often reported, were difficult to target because of the manual sampling strategy used. This study shows that high concentrations of nutrients and TSS occur in the runoff from cane and banana paddocks. Median total nitrogen, total phosphorus and TSS concentrations in flow through the urban lakes were 369 microg N/L, 16 microg P/L and 11 mg/L, respectively. Flux estimates of 9.2 kg N, 0.8 kg P and 126 kg TSS/ha were determined for drainage runoff from a banana paddock during a single intensive storm event. 相似文献
15.
A study investigated the effect of truck‐traffic intensity and road water‐content on the quality of runoff water from unsealed forest roads. Three sections of a gravel‐surfaced forest road were instrumented and exposed to low and high levels of truck traffic during wet winter conditions and dry summer conditions between July 2001 and December 2002. Rainfall, runoff, road moisture, and traffic were measured continuously, and suspended and bedload sediments were integrated measurements over 2‐week site‐service intervals. The median suspended sediment concentration from the three road segments under low truck‐traffic conditions (less than nine return truck passes prior to a storm) was 269 mg l?1, increasing 2·7‐fold to a median of 725 mg l?1 under high truck‐traffic conditions (greater than or equal to nine return truck passes prior to a storm). These concentrations, and increases due to traffic, are substantially less than most previously reported values. When these data are expressed as modified universal soil loss equation (MUSLE) erodibility values K, accounting for differences in rainfall energy, site characteristics and runoff, high traffic resulted in a road surface that was four times more erodible than the same road under low traffic conditions. Using multiple regression, traffic explained 36% of the variation in MUSLE erodibility, whereas road water content was not significant in the model. There was little difference in the erodibility of the road when trafficked in low water‐content compared with high water‐content conditions (MUSLE K values of 0·0084 versus 0·0080 respectively). This study shows that, for a good quality well‐maintained gravel forest road, the level of truck traffic affects the sediment concentration of water discharging from the road, whereas the water content of the road at the time of that traffic does not (note that traffic is not allowed during runoff events in Victoria). These conclusions are conditional upon the road being adequately maintained so that trafficking does not compromise the lateral drainage of the road profile. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
16.
John R. Tinker Jr. 《Ground Water Monitoring & Remediation》1991,11(1):141-150
Water samples from private water supply wells in five unsewered subdivisions were tested for nitrate-nitrogen to determine the possible impact of septic systems on ground water quality. Three subdivisions are located in Eau Claire County and two in LaCrosse County, Wisconsin.
The nitrate-nitrogen concentrations in the wells were analyzed in relation to ground water flow direction, the location of septic systems within the subdivision, and the hydrogeologic and physical characteristics of the subdivisions. A comparison of three nitrogen mass balance models helped to identify the possible sources of nitrate-nitrogen in the wells.
The results indicate that nitrogen from septic systems and lawn fertilizer cause nitrate-nitrogen to increase in the ground water beneath the downgradient side of the subdivisions. In three of the five subdivisions the highest nitrate-nitrogen value exceeds the drinking water standard of 10 mg/L. 相似文献
The nitrate-nitrogen concentrations in the wells were analyzed in relation to ground water flow direction, the location of septic systems within the subdivision, and the hydrogeologic and physical characteristics of the subdivisions. A comparison of three nitrogen mass balance models helped to identify the possible sources of nitrate-nitrogen in the wells.
The results indicate that nitrogen from septic systems and lawn fertilizer cause nitrate-nitrogen to increase in the ground water beneath the downgradient side of the subdivisions. In three of the five subdivisions the highest nitrate-nitrogen value exceeds the drinking water standard of 10 mg/L. 相似文献
17.
The behavior of the herbicides isoproturon (IPU) and chlortoluron (CTU) in ground water and shallow unsaturated zone sediments were evaluated at a site situated on the Chalk in southern England. Concentrations of IPU in ground water samples varied from < 0.05 to 0.23 microgram/L over a five-year period of monitoring, and were found to correlate with application of the pesticide. Concentrations of pesticides in ground water samples collected during periods of rising water table were significantly higher than pumped samples and suggest that rapidly infiltrating recharge water contains higher herbicide concentrations than the native ground water. Significant variations in herbicide concentrations were observed over a three-month period in ground water samples collected by an automated system, with concentrations of IPU ranging from 0.1 to 0.5 microgram/L, and concentrations of a recent application of CTU ranging from 0.2 to 0.8 microgram/L. Different extraction methods were used to assess pore water concentrations of herbicides in the unsaturated zone, and samples were analyzed by standard HPLC analysis and immunoassay (ELISA) methods. These data indicated highly variable concentrations of herbicide ranging from 4 to 200 g/ha for HPLC and 0.01 to 0.04 g/ha for ELISA, but indicate a general pattern of decreasing concentrations with depth. The results of this study indicate that transport of IPU and CTU through the unsaturated zone to shallow ground water occurs and that this transport increases immediately following herbicide application. Measured concentrations of herbicides are generally lower than specified by the European Union Drinking Water Directive, but are observed to spike above this limit. These results imply that, while delivery of pesticides to ground water can occur as a result of normal agricultural practices, the impact on potable supplies is likely to be negligible due to the potential for degradation during the relatively long travel time through the unsaturated zone and high degree of dilution that occurs within the aquifer. As a result of the wide variation in concentrations detected by different techniques, it is suggested that for future site investigations more than one sampling strategy be employed to characterize the occurrence of pesticide residues and elucidate the transport mechanisms. 相似文献
18.
Jean. M. Dasch Abdul S. Abdul Devi N. Rai Thomas L. Gibson Noel Grosvenor 《Ground Water Monitoring & Remediation》1997,17(3):194-209
The soil and ground water at a General Motors plant site were contaminated with petroleum products from leaking underground storage tanks. Based on the initial assessment, the site was complex from the standpoint of geology (clay layers), hydrology (a recharge zone with a perched water table), and contaminant (approximately 4800 gallons of mixed gasoline and oil). After a thorough study of remedial alternatives, a synergistic remedial approach was adopted including pump and treat, product removal, vapor extraction, and bioventing. The system was designed and implemented at the site through 22 dual-extraction wells. Over a 21-month period, 4400 gallons of gasoline and oil were removed from the system, including 59 percent by vapor extraction, 28 percent by bioventing, and 13 percent by pump and treat. Synergism between the various remedial methods was demonstrated clearly. Ground water pump and treat lowered the water table, allowing air to flow for vapor extraction. The vacuum applied for vapor extraction increased the ground water removal rate and the efficiency of pump and treat. The vapor extraction system also added oxygen to the soil to stimulate aerobic biodegradation. 相似文献
19.
Mary E. Exner 《Ground Water Monitoring & Remediation》1990,10(1):147-159
Atrazine, cyanazine, alachlor, and metolachlor in the surface water of a recharge structure, which impounds runoff from row-cropped farmland in Nebraska, are transported with seepage to the shallow ground water flow system and to the locally confined regional aquifer. All wells in the shallow flow system and all those in the regional flow system impacted by seepage from the structure had detectable concentrations of at least one of the four pesticides.
The detectable concentrations of cyanzine, alachlor, and metolachlor in the two flow systems ranged from 0.1 to 0.9 ppb. These concentrations were an order of magnitude lower than those in the surface water. Concentrations in the regional aquifer clustered at the lower end of this concentration range. These three pesticides were not detected in the baseline study of the regional aquifer.
Unlike alachlor, cyanzine, and metolachlor, atrazine was always present in the wells impacted by seepage from the recharge structure. In the shallow flow system, concentrations ranged from 0.3 to 8.8 ppb and from 0.1 to 2.5 ppb in the regional aquifer. The average of the detectable atrazine concentrations in the baseline study was 0.04 ± 0.05 ppb. 相似文献
The detectable concentrations of cyanzine, alachlor, and metolachlor in the two flow systems ranged from 0.1 to 0.9 ppb. These concentrations were an order of magnitude lower than those in the surface water. Concentrations in the regional aquifer clustered at the lower end of this concentration range. These three pesticides were not detected in the baseline study of the regional aquifer.
Unlike alachlor, cyanzine, and metolachlor, atrazine was always present in the wells impacted by seepage from the recharge structure. In the shallow flow system, concentrations ranged from 0.3 to 8.8 ppb and from 0.1 to 2.5 ppb in the regional aquifer. The average of the detectable atrazine concentrations in the baseline study was 0.04 ± 0.05 ppb. 相似文献
20.
An abandoned creosote facility in Conroe, Texas, has become a field site for the National Center for Ground Water Research (NCGWR) at Rice University. Ground-water contamination in the shallow aquifer beneath the site was characterized by sampling soils and water quality at 14 monitoring wells and 35 boreholes. Results from six sampling trips over two years for inorganic and organic chemical concentrations in the ground water show wells around the site were contaminated to levels above 800 μg/l for naphthalene, 400 μg/1 for methyl naphthalene, and 150 μg/1 for dibenzofuran. Conservative constituents, traced by chloride concentrations up to 75 mg/l, have migrated 300 ft (90 m) downgradient of the site. Organic contaminants have been adsorbed and microbially degraded in their migration from the waste source as evidenced by their attenuated concentrations. Detailed field pump tests have been performed to evaluate hydraulic conductivity at several of the shallow wells. The U.S. Geological Survey (USGS) Solute Transport Model (Konikow and Bredehoeft, 1978) has been used to predict chloride plume patterns and evaluate parameters which govern transport processes at the Conroe waste site. 相似文献