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1.
By PVT fractionation experiments to model phase-controlled and gaw-washing fractionations during the formation of petroleum reservoirs,the authors measured the physical and chemical properties of products formed in different fractionation staes and made a correlative analysis of the influence of depressurization and gas washing on oil/gas molecular composition and the rule of fractionation.The analytical results showed that gas washing is an important factor affecting the physical properties of crude oils.and also can be regarded as a good genetic interpretation of marine wax-high oils in the Tarim region,Xinjiang,China.Phase-controlled and gaw-washing fractionations can lead to the formation of condensates and their differences in chemical composition from crude oils are a direct reflection of evaporating fractionation.Phasecontrolled and gaw-washing fractionations have a great influence on the composition of molecular compounds and relevant parameters.So phase-controlled and gas-washing fractionations during the formation of petroleum reservoirs are not only favorable to identifying different processes of formation of petroleum reservoirs,but also to the scientific application of routine geochemical parameters.  相似文献   

2.
Based on the analysis of the hydrocarbon geochemical characteristics in the Kuqa petroleum system of the Tarim Basin, this study discusses the causes and controlling factors of the phase diversities and their differences in geochemical features. According to the characteristics and differences in oil and gas phase, the petroleum system can be divided into five categories: oil reservoir, wet gas reservoir, condensate gas-rich reservoir, condensate gas-poor reservoir and dry gas reservoir. The causes for the diversities in oil and gas phases include diversities of the sources of parent material, maturity of natural gas and the process of hydrocarbon accumulation of different hydrocarbon phases. On the whole, the Jurassic and Triassic terrestrial source rocks are the main sources for the hydrocarbon in the Kuqa Depression. The small differences in parent material may cause diversities in oil and gas amount, but the impact is small. The differences in oil and gas phase are mainly affected by maturity and the accumulation process, which closely relates with each other. Oil and gas at different thermal evolution stage can be captured in different accumulation process.  相似文献   

3.
The spectral characters of hydrocarbons in some oil-bearing strata and soil layers ouer oil and gas reservoirs in the Junggar Basin and northern Tarim Basin in Xinjng are compared with those of chemically pure hydrocarbons.The hydrocarbons are characterized by the bi-absorption at 2310nm and 2350nm.Hydrocarbon and radioactive anomalies in oil and gas terrains are found much more widespread than carbonate alterations.Based on the spectra of heavy hydrocarbons related to oil between 2270nm and 2460nm and refined data treatme nt, remote sensing may hold encouraging promise as a directly prospecting technique for oil and gas resources.  相似文献   

4.
Natural gas exploration in Nanpu sag, Bohai Bay Basin, has achieved breakthroughs in recent years, and a number of natural gas and condensate wells with high yield have been found in several structures in the beach area. Daily gas production of single wells is up to 170,000 m3, and high-yield wells are mainly distributed in?the Nanpu No. 1 structural belt.?Studies have shown that these natural gases are mainly hydrocarbon gases, with methane content about 80% to 90% and ethane 6%-9%, so they are mainly wet gas; and non-hydrocarbons are at a low level.?Carbon isotopes of methane range from -42‰ to -36‰, and ethane from -28‰ to -26‰. Calculated maturity based on the relationship between δ13C and Ro of natural gas, the gases are equivalent to those generated from organic matter when Ro is 1.0%-1.7% (mainly 1.25%-1.32%). The natural gas is oil-type gas generated from the source rocks at mature to high mature stage, associated with condensate, so carbon isotopes of the gases are heavier. Natural gas in the Nanpu No.1 structural belt is mainly associated gas with condensate. The analysis of the origin and source of natural gas and condensate, combined with the monomer hydrocarbon carbon isotopes and biomarker, indicated that the main source rocks in the Nanpu No.1 structural belt were Es3 (the lower member of the Shahejie Formation), followed by Es1 (the upper member of the Shahejie Formation).?The high-mature hydrocarbons from source rocks in the deep sag mainly migrated through deep inherited faults into shallow traps and accumulated to form oil and gas pools. Therefore, there is a great potential for exploring gas in deep layers.  相似文献   

5.
The successful exploration and production of shale-gas resources in the United States and Canada sets a new possible solution towards the energy crisis presently affecting most countries of Asia. This study focuses on the use of well log and 2D seismic data for the characterization of the shale oil/gas potential of a Paleocene–Eocene succession — the Meyal area in the Potwar Basin of Pakistan. Two shaly plays are identified in Paleocene–Eocene strata in well logs using ΔLogR and modified ΔLogR cross-plot techniques. The results indicate that Paleocene shale(the Patala Formation) and the lower shaly part of Eocene limestone(Sakesar Formation) can be potentially mature source rocks. However, the thermal maturity modelling proves that only the Paleocene shale is mature. Our results also suggest that the maturity responses on ΔLogR models for the lower shaly part of the Eocene limestone are due to trapped hydrocarbons in the intra-formational fractures. Petroelastic/petrophysical analysis of the Patala Formation reveals two potential shale oil/gas zones on the basis of Young's modulus, Poisson's ratio, Brittleness index and Total Organic Content at an exploitation depth of 3980–3988 m. This work can provide valuable insight for estimating shale oil/gas potential in highly deformed basins not only in Asia but in other parts of the world.  相似文献   

6.
Some Ordovician and Triassic oils in Block 9 are characterized by light oils,which have distinctly differentiated from heavy oils in other blocks in the Tahe Oilfield,Tarim Basin.Based on the whole oil gas chroma- tograms,this paper estimates the effect of oil migration and fractionation and the amount of depletion(Q)in terms of the n-alkanes depletion model.The results showed that the amount of depletion in the Ordovician reservoir is highest in the east of this block,e.g.the depletion is 97% in Well T904.The amount of Q gets lower to the west,e.g.the depletion is 53.4%in Well T115 and there is no sign of depletion in Well S69.It is suggested that the direction of gas washing is from the east to the west.The compositions and isotopic characteristics of associated gas in Ordovician oils indicated that the gas might be derived from Cambrian source rocks of the Caohu Depression which lies to the east of Block 9.In contrast,no obvious depletion of n-alkanes in Triassic oils was found,suggesting that the migration pathway of natural gas has been limited to the Ordovician karst fracture system formed in the Early Hercynian Orogeny.Different depletions of the Ordovician and Triassic oils can reveal fault activities in this region.  相似文献   

7.
This article reports the main formation models and distribution of the oil and gas pools in Tarim basin,China,including (I) occurrence of the found oil and gas pools,(2) main formation models of oil and gas pools,and (3) distribution law of oil/gas pools.Petroleum is distributed widely in the strata of Tarim basin from the Sinian at the bottom to the Neogene at the top.However,the found oil and gas fields are mainly distributed in Shaya (沙雅) uplift,Tazhong (塔中) uplift,and Kuche (库车)depression.This article presents 4 main formation models,namely,early formation and long-term preservation,early formation and late reformation,middle-late multiphase-multisource formation,late single-stage formation.Tarim basin is very rich in petroleum resources.Long-term inherited intrabasinal paleohighs and slope zones are the most favorable areas for accumulation of hydrocarbons,but the types of oil and gas pools are different from area to area.The control of unconformities and faults on hydrocarbon accumulating is prominent in Tarim basin.Preservation conditions are of utmost importance.Formation of some oil and gas pools is the result of reforming and re-accumulating of early accumulated hydrocarbons.  相似文献   

8.
The C and H isotopic compositions of the methane in more than 160 gas samples from 10 basins in China are presented in this paper.The natural gases are classified as four types: biogenic gas ,bio-thermocatalytic transitional gas, gas associated with condensate oil ,and coal-type gas. The isotopic compositions of these gases closely related to the depositional basins, the types of organic matter,the stages of thermal evolution and the genetic characteristics of different gas reservoirs.Studies of the C and H isotopic compositions of terrigenous natural gases will provide valua-ble information on the prospecting and development of natural gases of different genetic types.  相似文献   

9.
This paper is mainly concentrated on the geochemical characteristics and origin of gas of Kekeya field in the Tarim basin, NW China. This study shows that Permian mudstone is the main source rock of oil and gas. Based on the carbon isotopes of C1--C4, the carbon isotope of gas in Kekeya field is a little heavier than that in the typical marine-derived gas. The relationship between carbon isotopes of methane and ethane is coincident with Faber equation of gas derived from organic matter Ⅰ/Ⅱ. The majority of gas maturity is estimated, based on the formula, at 1.8%-2.2% besides K2 and K18 wells. In addition, the gas derived from 0.9%-1.2% Ro source rocks may also bemixture. ^40Ar/^36Ar and ^3He/^4He ratios from the gas samples also support the mixing process. Moreover, the gas in this region is mainly generated from more mature source rocks although the low mature gas exists.  相似文献   

10.
Gross compositions and distribution of saturated and aromatic hydrocarbons in Carboniferous sandstone reservoire rocks in oil and water zones for Tzhong-10 well of the Zhongyang Uplift in the Tarim Basin were studied in dteail by means of Rock-Eval Pyrolysis,thin-chromatograph-flame ionization detection(TLC-FID),gas chromatography,gas chromatography-mass spectrometry.The results suggest that the gross composition of reservoir hydrocarbons between the oil zone and the water zone show significant differences,Water wahing has a dramatic effect on saturated hydrocarbon blomarkers,especially drimane series compounds,Drimane series compounds in the water zone have been depleted completely.However,the contents of tricyclic iterpanes and pentacyclic triterpanes tend to decrease slightly,but the water-zone reservoir hydrocarbons contian a large amount of gammacerane.This suggests that gammacerane be more resistant to water washing than diterpanes and homohopanes.The contents of pregnane,homopregrane,diasteranes relastively decrease as a result of water washing.Water washing has a noticeable effect on polycyclic aromatic hydrocarbon compounds,especially aromatic sulfur compounds,and the contents of dibenzothiophene series compounds and benzonaplyiothipophene decrease significantly as a result of water washing.However,the conterts of bicyclic and tricyclic aromatic hydrocarbons decrase slightly and those of tetracyclic and pentacyclic aromatic hydrocarbons,especially benzofluoranthene and benzopyrenes,increase markedly owing to adecrease in light aromatie hydrocarbons as a result of water washing.  相似文献   

11.
高蜡凝析油或轻质油的分布特征与成因机理   总被引:2,自引:2,他引:2  
介绍了中国部分含油气盆地中的高蜡凝析油或轻质油的地球化学特征及其在地域上和层位上的分布规律,并以大港千米桥古潜山高蜡凝析油气藏、吐哈盆地西部凹陷部分高蜡凝析油田或轻质油田、塔里木盆地柯克亚凝析油气田、盐城凹陷的高蜡凝析油藏为例,总结了几种高蜡凝析油或轻质油的成因模式,即煤系腐殖型烃源岩热演化生烃、运移分馏作用、混合作用或"气洗作用"等.  相似文献   

12.
李威  李友川  兰蕾  傅宁  王柯 《地质学报》2021,95(3):913-923
2018年中国东部最大整装凝析气田——渤中19-6气田的发现,一举打开了渤海湾盆地深层天然气勘探的新领域,展现了油型盆地天然气勘探的巨大潜力。渤中凹陷发育多套不同成熟度的烃源岩,位于渤中凹陷西南部的渤中19-6气田凝析油与天然气并存,近年来于该地区的天然气成因及形成条件多有研究,但是对于凝析油的形成则少有研究。本文以渤中19-6气田为例,探讨多套烃源岩发育的复杂油气区凝析油的成因及与天然气的关系。渤中19-6气田6个凝析油样品化学组成及其变化特征精细分析对比表明:该区凝析油以低碳数正构烷烃为主,含有较丰富的环己烷、甲基环己烷等环烷烃和苯、甲苯等低碳数芳烃,金刚烷类化合物较发育,高碳数生物标志化合物含量较低,综合判断凝析油属于混合偏腐殖型高熟原油。结合该区凝析油与天然气对比结果认为,该区凝析油和天然气属于同一套烃源岩在同一阶段所生成的烃类化合物,两者相伴而生,均属于烃源岩原生产物。  相似文献   

13.
塔里木盆地叶城凹陷拥有多套烃源岩层,主要为石炭系卡拉乌依组、二叠系棋盘组与普司格组2-3段、侏罗系煤系地层与叶尔羌群等,这些烃源岩都可能是柯东1井凝析油和柯克亚第三系原油的母源。在这一地区,油源一直是一个很具争议性的问题。选取了叶城凹陷克里阳构造带柯东1井2个凝析油、柯克亚构造带7个第三系原油,以及叶城凹陷各烃源岩层具有代表性的17个烃源岩样品,对其生物标志物及正构烷烃单体烃稳定碳同位素比值等参数进行了详细的测试分析。油油对比揭示,柯东1井原油与柯克亚第三系原油在正构烷烃组分、成熟度与稳定碳同位素组成等特征上具有明显的相似性,显示同源的特征。油源对比显示,普司格组2-3段下部是这些原油的源岩。这一烃源岩层具有与柯克亚地区原油一致的成熟度和相似的特征性生物标志物,即高含量的重排藿烷、Ts和 C27-C29重排甾烷等,而其他烃源岩层则不具备这类特征。较高成熟阶段形成的原油,解释了普司格组2-3段烃源岩可溶有机质与柯东1井等原油在单体烃稳定碳同位素比值上具有2‰~3‰的差别。  相似文献   

14.
The geochemical characteristics of 16 oils/condensates/seep oil/oil shows (collectively called oils) from the Eastern Papuan Basin (EPB) and one seep oil from the Western Papuan Basin (WPB) are integrated with data from previous studies of oils, fluid inclusion oils and solid bitumens from the EPB and WPB, Papua New Guinea. The combined set of samples can be divided in two major families of hydrocarbons. The Family A oils, mostly occurring in the WPB region, were generated from clay rich marine source rocks, containing predominantly terrigenous higher plant derived organic matter (OM) deposited in a sub-oxic to oxic environment. Source rock(s) for Family A oils are likely to be of Middle to Upper Jurassic, e.g., the Upper Jurassic Imburu Formation. The Family B oils, distributed mainly in the EPB region, were generated from Cretaceous or younger marine carbonate source rock(s) deposited under anoxic to sub-oxic conditions, and containing predominantly prokaryotic OM with some terrigenous higher plant inputs. The EPB natural gases analyzed in this study may be co-genetic to the co-occurring Family B oils in the EPB. Both Family A and B oils were generated at similar thermal maturities of 1.0–1.3% vitrinite reflectance equivalent. Although no source interval to date has been firmly identified in the EPB, post-Jurassic strata are a viable option, because (1) Late Cretaceous and Paleogene carbonate and clastic marine sediments including possible source lithologies are present, and (2) this section of the Papuan Basin sustained rapid sedimentation and tectonic loading, particularly in the Cenozoic.  相似文献   

15.
塔北地区普遍存在气顶型凝析气藏和带油环的凝析气藏。与传统烃类热演化理论相矛盾的是:1)天然气的成熟度远高于油环原油或凝析油;2)高-过成熟天然气与同藏的原油间存在明显的物性不匹配。结合地质背景,认为这种矛盾是由后期形成的干气进入已形成的油藏并溶解原油轻烃这一过程所致,凝析气中的轻烃是气-液溶解平衡的产物。地质历史时期凝析气与油环分离或产生凝析油气藏或混入其它油藏的蒸发分馏作用过程导致了轻烃的油藏再分配,形成了塔北地区纵向上原油轻烃的“反序”分布趋势及某些参数的异常分布。认为烃类的气-液相溶解平衡作用是原始原油轻烃分布特征后期演变的主要控制机制之一。其实质是不同性质轻烃气液两相差异性分配基础上的物理化学分异过程。  相似文献   

16.
马柯阳  周永红 《沉积学报》1995,13(4):100-108
塔北地区普遍存在气顶型凝析气藏和带油环的凝析气藏。与传统烃类热演化理论相矛盾的是:1)天然气的成熟度远高于油环原油或凝析油;2)高-过成熟天然气与同藏的原油间存在明显的物性不匹配。结合地质背景,认为这种矛盾是由后期形成的干气进入已形成的油藏并溶解原油轻烃这一过程所致,凝析气中的轻烃是气-液溶解平衡的产物。地质历史时期凝析气与油环分离或产生凝析油气藏或混入其它油藏的蒸发分馏作用过程导致了轻烃的油藏再分配,形成了塔北地区纵向上原油轻烃的“反序”分布趋势及某些参数的异常分布。认为烃类的气-液相溶解平衡作用是原始原油轻烃分布特征后期演变的主要控制机制之一。其实质是不同性质轻烃气液两相差异性分配基础上的物理化学分异过程。  相似文献   

17.
我国凝析油的成因类型及其地球化学特征和意义   总被引:5,自引:1,他引:5  
陈践发  沈平 《沉积学报》1995,13(1):32-40
近十几年的勘探实际表明,在我国一些含油气盆地中,许多天然气藏均伴生一定量的凝析油(或轻质油)。按母质类型可将凝析油分为海相腐泥型有机质生成的凝析油、煤系地层腐殖质有机质生成的凝析油、陆相混合型有机质生成的凝析油。本文较详细地从成因机理上讨论了这三种不同成因凝析油的形成特点。海相腐泥型有机质一般在有机质热演化达到高成熟-过成熟阶段,由干酪根或早期形成的高分子液态烃热裂解才形成凝析油。煤系地层中腐殖型有机质从低成熟到过成熟各个阶段所生成的一定量的液态烃一般主要以凝析油的状态与天然气相伴生。陆相混合型有机质从低成熟到过成熟阶段也都可能形成凝析油。利用凝析油单体烃的组份特征,石蜡指数和庚烷值对我国主要含油气盆地凝析油的成熟度进行了计算,所得结果,大都与地质实际相吻合。研究表明我国凝析油成熟度的分布范围从低成熟到过成熟均有。三种不同成因的凝析油其地球化学特征具有一定差异,煤系地层腐殖型有机质形成的凝析油从组份来讲相对富含芳烃,其芳烃含量一般为16.2~23.5%,饱和烃/芳烃值为3.2~5.2,同时其姥鲛烷/植烷值相对较高,通常均大于3;而海相腐泥型有机质生成的凝析油则相对富含饱和烃,其饱/芳比值为11.8~18.2,同时姥蛟烷/植烷值较低,一般小于1。陆相混合型有机质生成的凝析油则介于二者之间。三类不同成因的凝析油它们的芳烃组份(蔡系、联苯系和药系)和低分子生物标记物(菇类化合物)以及烷烃和芳烃组份的碳同位素组成都具有明显的差异。利用凝析油的这些地球化学特征可以有效地判识凝析油的成熟度和成因类型,从而确定与之相伴生的天然气的成因或来源。  相似文献   

18.
This work extensively investigated global tight sandstone gas, and geologically and geochemically analyzed the tight sandstone gas in China's Ordos, Sichuan, and Tarim basins. We compared typical tight sandstone gas in China with that in North America. We proposed six conditions for the formation of China's tight sandstone gas, and illustrated the geological characteristics of tight sandstone gas. In China, gas-bearing tight sandstones were mainly deposited in continental lake deltas and marine-terrigenous facies basin environments, associated with coal-measure strata, and were mostly buried deeper than 2000 m under a formation pressure of 20–30 MPa, with pressure coefficients varying from overpressure to negative pressure. In other countries, tight gas bearing sandstones were dominantly deposited in marine to marine-terrigenous facies environments, occurred in coal-measure strata, and were mostly buried shallower than 2000 m in low-pressure systems. We systematically analyzed tight sandstone gas in the Ordos, Sichuan, and Tarim basins in terms of chemical compositions, geochemical characteristics of carbon isotopes, origins, and sources. Tight sandstone gas in China usually has a hydrocarbon content of 95%, with CH4 content 90%, and a generally higher dry coefficient. In the three above-mentioned large tight sandstone gas regions, δ13 C1 and δ13 C2 mainly ranges from-42‰ to-28‰ and from-28‰ to-21‰, respectively. Type III coal-measure source rocks that closely coexist with tight reservoirs are developed extensively in these gas regions. The organic petrology of source rocks and the carbon isotope compositions of gas indicate that tight sandstone gas in China is dominantly coal-derived gas generated by coal-measure strata. Our analysis of carbon isotope series shows that local isotope reversals are mainly caused by the mixing of gases of different maturities and that were generated at different stages. With increasing maturity, the reversal tendency becomes more apparent. Moreover, natural gas with medium-low maturity(e.g., Xujiahe Formation natural gas in the Sichuan Basin) presents an apparent reversal at a low-maturity stage, a normal series at a medium-maturity stage, and a reversal tendency again at a high-maturity stage. Finally, we proposed four conditions for preferred tight sandstone gas "sweep spots," and illustrated the recoverable reserves, proven reserves, production, and exploration prospects of tight sandstone gas. The geological and geochemical characteristics, origins, sources, and exploration potential of tight sandstone gas in China from our research will be instructive for the future evaluation, prediction, and exploration of tight sandstone gas in China and abroad.  相似文献   

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