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1.
Cadmium,zinc, copper,and barium in foraminifera tests 总被引：1，自引：0，他引：1
Edward A. Boyle 《Earth and Planetary Science Letters》1981,53(1):11-35
The concentrations of cadmium, zinc, copper and barium have been determined on 2-mg samples of single-species foraminifera populations. Cleaning techniques were tested using North Atlantic core tops, and followed by a detailed downcore study for the last 30,000 years in South Atlantic core V22-174. Raw foram tests cleaned by crushing followed by ultrasonic removal of fine-grained material, and dissolved in a pH 5.5 acetate buffer, contain appreciable amounts of trace elements associated with ferromanganese and alumino-silicate contaminants. A reductive/complexing cleaning treatment reduces ferromanganese contamination by 1–2 orders of magnitude. Acetate buffers at pH 5.5 complex iron and raise the solubility of ferromanganese oxides; these buffers are unsuitable for separating carbonate lattice-bound trace elements from the fraction associated with ferromanganese phases. Improved mechanical and ultrasonic reductive cleaning combined with a mild dissolution in distilled water under 1 atm.PCO2 reduces contaminant levels another order of magnitude. The Cd and Zn concentrations (order 10?8 mole Cd/mole Ca and 10?5 mole Zn/mole Ca) of species with low surface area show an increase with decreasing isotopic temperatures. This increase is consistent with the increasing concentrations of these metals from low values in surface waters to higher values at depth. The variance of Cd and Zn over the last 30,000 years in the central South Atlantic is consistent with the probable variability of the dissolved trace elements at the calcification levels of the species analyzed. Cu and Ba are irreproducible and probably sensitive to residual contaminant phases. The trace element content of the tests differs from levels observed in a recent coprecipitation study. Foraminifera may be a significant vector in zinc cycling in the ocean. 相似文献
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Evidence for a signal near 19 years is found in 51 out of 65 rain gauge records in the tri-state region of Arkansas, Louisiana, and Mississippi, While another term with period 10 to 11 years is found in 39 instances. These are identified as the 18.6-year luni-solarM
n
and solar cycleS
c
signals in climate variability. In terms of both amplitude and phase the luni-solar wave trains are highly nonstationary; in particular, the waves commonly change phase by 180°. Examples of theM
n
andS
c
terms in corn yield for Arkansas and Missouri are presented, and the implications for economic science briefly discussed. 相似文献
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Gautam Sen Michael Bizimis Reshmi Das Dalim K. Paul Arijit Ray Sanjib Biswas 《Earth and Planetary Science Letters》2009,277(1-2):101-111
Kutch (northwest India) experienced lithospheric thinning due to rifting and tholeiitic and alkalic volcanism related to the Deccan Traps K/T boundary event. Alkalic lavas, containing mantle xenoliths, form plug-like bodies that are aligned along broadly east–west rift faults. The mantle xenoliths are dominantly spinel wehrlite with fewer spinel lherzolite. Wehrlites are inferred to have formed by reaction between transient carbonatite melts and lherzolite forming the lithosphere. The alkalic lavas are primitive (Mg# = 64–72) relative to the tholeiites (Mg# = 38–54), and are enriched in incompatible trace elements. Isotope and trace element compositions of the tholeiites are similar to what are believed to be the crustally contaminated Deccan tholeiites from elsewhere in India. In terms of Hf, Nd, Sr, and Pb isotope ratios, all except two alkalic basalts plot in a tight cluster that largely overlap the Indian Ridge basalts and only slightly overlap the field of Reunion lavas. This suggests that the alkalic magmas came largely from the asthenosphere mixed with Reunion-like source that welled up beneath the rifted lithosphere. The two alkalic outliers have an affinity toward Group I kimberlites and may have come from an old enriched (metasomatized) asthenosphere. We present a new model for the metasomatism and rifting of the Kutch lithosphere, and magma generation from a CO2-rich lherzolite mantle. In this model the earliest melts are carbonatite, which locally metasomatized the lithosphere. Further partial melting of CO2-rich lherzolite at about 2–2.5 GPa from a mixed source of asthenosphere and Reunion-like plume material produced the alkalic melts. Such melts ascended along deep lithospheric rift faults, while devolatilizing and exploding their way up through the lithosphere. Tholeiites may have been generated from the main plume head further south of Kutch. 相似文献
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通过对福建华安县汰内井2005年以来的水氡测值进行分析,提取了中期及短期异常,认为这些异常与2006年12月26日台湾屏东海外7.2级地震有关。 相似文献
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Streamflow generation was investigated using isotopic and geochemical tracers in semiarid, glacier-covered, montane catchments in the upper Shule River, northeastern Tibetan Plateau. Samples from stream water, precipitation, glacier meltwater, and groundwater were collected at the Suli and Gahe catchments along the Shule River, with an area of 1908 and 4210 km2, respectively. The samples were analysed for stable isotopes of water and major ions. Results of diagnostic tools of mixing models showed that Ca2+, Mg2+ and Cl−, along with δ18O and δ2H, behaved conservatively as a result of mixing of three endmembers. The three endmembers identified by the mixing analysis were surface runoff directly from precipitation, groundwater, and glacier meltwater. Streamflow was dominated by groundwater, accounting for 59% and 60% of streamflow on average in the Suli and Gahe catchments, respectively, with minimum groundwater contribution in July (47% and 50%) and maximum contribution in October (69% and 70%). The contributions of surface runoff were slightly higher in the Suli catchment (25%) than in the Gahe catchment (19%). However, the contributions of glacier meltwater were higher in the Gahe catchment (21%) compared to the Suli catchment (17%), as a result of a higher percentage of glacier covered area in the Gahe catchment. This difference followed well the non-linear power–law trend of many glacier-covered catchments around the world. As glacier retreat continues in the future, the reduction of streamflow in glacier-covered upper Shule catchment likely will be accelerated and possibly elsewhere in the Tibetan Plateau. This study suggests that it is critical to define the turning point of an accelerated reduction in glacier meltwater for glacier-covered catchments around the world in order to better assess and manage water resources. 相似文献
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Shiber JG 《Marine pollution bulletin》2011,62(1):66-72
Seventeen samples of canned sardines, originating from six countries and sold in eastern Kentucky, USA, were analyzed in composites of 3-4 fish each for total arsenic (As), cadmium (Cd) and lead (Pb) by graphite furnace atomic absorption spectrophotometry (AAS) and for mercury (Hg) by thermal decomposition amalgamation and AAS. Results in μg/g wet: As 0.49-1.87 (mean: 1.06), Cd < 0.01-0.07 (0.03), Pb < 0.06-0.27 (0.11), Hg ND < 0.09. Values fall generally within readings reported by others, but no internationally agreed upon guidelines have yet been set for As or Cd in canned or fresh fish. The incidence of cancers and cardiovascular diseases associated with As ingestion is extraordinarily high here. With the role of food-borne As in human illness presently under scrutiny and its maximum allowable limits in fish being reviewed, more studies of this nature are recommended, especially considering the potential importance of small pelagic fishes as future seafood of choice. 相似文献
8.
《Journal of Atmospheric and Solar》2002,64(5-6):541-549
Recently, it has been shown that certain features of magnetotail dynamics in response to solar wind changes may resemble the behavior of a complex system near a dynamical critical state (Chang, Phys. Plasmas 6 (1999) 4137; Consolini and Chang, Space Sci. Rev. 95 (2001) 309), and of topological phase transitions (Chang, Phys. Scr. (2001), 80). Moreover, the impulsive part of the magnetotail response seems to be well described by cellular automata and other simulation models displaying criticality.Here, the relevance of the magnetic field topological disorder will be discussed in connection with observed complexity and near-criticality, showing how the impulsive character of the magnetotail response could be viewed as fluctuation-induced topological transitions among metastable configurations of magnetic field topology. 相似文献
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Dev K. Niyogi Janet M. Bandeff Cem Selman Drew E. Menke 《Aquatic Sciences - Research Across Boundaries》2010,72(2):203-212
We examined nutrient flux, uptake, and transformation along a spring-fed stream in the Ozark region of Missouri, USA, over
the year 2006. Water in Mill Creek originates from several springs, with a single spring contributing over 90% of the stream
discharge during much of the year of study. Soluble reactive phosphate concentrations were usually low (<10 μg L−1) along Mill Creek, but peaked during high discharge. Concentrations of dissolved inorganic nitrogen (DIN) were relatively
high in the spring water, mainly as nitrate, but usually declined across a small pond and the 10-km length of Mill Creek.
During low flows in summer and early autumn, the stream removed over 300 μg L−1 of DIN over its 10-km length, or about 80% of the initial amount. DIN retention along the stream, as a percentage of the
DIN upstream, was related mainly to discharge, with higher flows having much higher DIN concentrations. The net uptake rate
of DIN uptake was 0.91 μg m−2 s−1 in the stream during summer baseflow. The uptake rate declined downstream for different reaches and was closely related to
DIN concentration. In experimental channels, uptake by epilithic algae was one significant sink for nitrate-N in Mill Creek.
In 2006, inorganic nutrient export during a single day after a spring storm was similar to export during 40–100 days of low
flow conditions in summer and early autumn. Our results suggest that significant nutrient retention can occur during baseflow
periods via biological uptake, whereas substantial export occurs during high flow conditions. 相似文献
10.
Microbial carbonates in Holocene beachrocks,Shuiweiling, Luhuitou Peninsula,Hainan Island 总被引：2，自引：0，他引：2
Two research methods, geomicrobiology and carbonate sedimentology, were adopted to study the microbial carbonates in the beachrocks, Shuiweiling, Luhuitou, Sanya City, Hainan Island. The results indicate that microbial carbonates occur in Shuiweiling beachrocks and cements related to microbial activitives are common. Microbial carbonates were mainly developed on the surfaces of coral skeletons and within the coral (fragments and shivers) skeletal cavities,and rarely grew in interspaces formed by coral and other biological detritus. The growth morphologies of microbial carbonates are various, including stromatolitic lamination, thin crusts, dome-like, and microbialites. Microbial carbonates commonly trap fine-sized bioclasts, contain tubular filaments, and show laminated growth striation. Microbial carbonates within the coral skeletal cavities are generally stromatolitic cone-shaped, with a random growth direction along the bearing of trend of cavities, showing distinct growth laminae and recognizable growth phases. It is a special growth pattern of crypt microbial carbonates. Microbial cements occur mainly in shape of needle cement, calcified filaments, microborings, and calcified framboidal spheres. The needle cement is the most common type. These microbial cements indicate that microbial activities and microbial carbonates played an important role in beachrock formation in which carbonates were dominant components and the climate of tropical ocean monsoon was influential. Such microbial carbonates and microbial cementation have not been reported here from beachrocks along the northern shorelines of the South China Sea. The results support a clear microbial origin for certain carbonate cements in beachrocks, confirm that microbial carbonates are a significant contributor to carbonate sedimentation, and widen the knowledge of beachrocks from a new field. 相似文献
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The spread of green algae over mudflats in Langstone Harbour has been caused by increased discharges of both treated and untreated sewage effluent. The decline in some species of estuarine birds may be a secondary effect of the blanketing of the muds by algae, but Soulsby et al. concluded that the evidence for a causal link was inconclusive. This note examines the points they put forward in support of this. 相似文献
12.
A compact, spheroidal Type B inclusion in Allende contains melilite laths that project radially inward from the inclusion edge which show interference growth textures. The combined textural and chemical features of this object cannot be explained by independent vapor-solid condensation of grains in space, followed by random aggregation of these grains into an inclusion. Rather, it probably formed from a once-molten droplet that crystallized in response to radiative cooling from its outer surface. The crystallization sequence in this and another similar inclusion in which oxygen isotopes have been measured is: melilite-spinel-anorthite-fassaite. This sequence supports the idea that oxygen isotopic heterogeneities in coarse-grained inclusions were formed after complete solidification of these objects by partial exchange with a less16O-rich gas, and not during or before a melting event. 相似文献
13.
Roberto E. Galindo Domínguez William L. Bandy Carlos A. Mortera Gutiérrez José Ortega Ramírez 《Geofísica Internacional》2013,52(3):261-275
In August 2009, a marine geophysical survey was conducted in Lake Tequesquitengo (located in the state of Morelos, Mexico) to delineate the extent of the remains of a small town that has been submerged since the mid 19th century. The survey consists of the acquisition and mapping of magnetic, single beam bathymetric and side-scan sonar data. A dual receiver marine GPS navigation system was used to position the boat during the survey. Except for the larger structural remains that are visible on the side scan sonar images, the magnetic anomaly map proved to be most useful in delineating the extent of the town. These anomalies exhibit short wavelength components in the area surrounding a submerged church, with the shortest wavelength components being confined to the area immediately east of the church. These short wavelength components are only observed near the church; therefore, we propose that they delineate the buried remnants of the submerged town. 相似文献
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S.A. Morse 《Earth and Planetary Science Letters》1975,26(3):331-336
Abundant lamellae of plagioclase are present in the (100) planes of hypersthene megacrysts in andesine anorthosite along Tikkoatokhakh Bay, northwest of Nain, Labrador. Spongy intergrowths of plagioclase in hypersthene also occur. Plagioclase lamellae have mean compositions ranging from An43 to An92, with extreme compositions from An39 to An97; the calcic compositions are the more abundant. Such lamellae are always accompanied in the hypersthene by grains or lamellar segments of magnetite, and rarely by lamellae of olivine, augite, magnetite, or ilmenite. Some calcic plagioclase lamellae contain antiperthitic spindles of orthoclase. The host rocks of the hypersthene megacrysts are layered leuconorites and anorthosites with mean plagioclase compositions ranging from An41 to An55. The plagioclase lamellae in hypersthene are characteristically much more calcic than the host-rock plagioclase. There is little doubt that the lamellae exsolved from a pyroxene host, dominantly by a coupled redox reaction which generated magnetite, thereby releasing silica to combine with the Ca-Tschermak and jadeite components of the precursor pyroxene. Rapid growth of megacrysts may account for their aluminous nature. 相似文献
16.
36Ar, 84Kr, and 132Xe abundances along with Kr and Xe isotopic compositions are reported for two African shales and samples of chert from the Gunflint Formation in Canada. It is observed that these data and similar abundance data from other terrestrial materials show correlations between 36Ar-84Kr and between 84Kr-132Xe. The elemental ratios defined by all the above data differ significantly from and show greater variations than those measured in carbonaceous chondrites, a well-investigated class of extraterrestrial material. Physical absorption and equilibrium solubility acting on the atmosphere are investigated as explanations for the observations. The Kr and Xe isotopic spectra are also consistent with a mass-dependent incorporation process acting on a reservoir of atmospheric composition. 相似文献
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Kaersutites from Kakanui, New Zealand and from three localities in the southwestern United States have been analyzed for rare gases, water and carbon to investigate the volatile signature of the sub-continental mantle. This study does not confirm the high 3He/4He and 21Ne/22Ne ratios reported by Saito et al. [1] for the Kakanui kaersutite. Instead, a 3He/4He ratio of 6 RA and atmospheric 21Ne/22Ne ratios were measured which are consistent with our current knowledge of the earth's mantle. A low 40Ar/36Ar of 320 and more than 10?8 cm3/g of 36Ar confirms the argon results of Saito et al. and indicates that significant quantities of 36Ar reside in this portion of the mantle. Kaersutites from the southwestern United States (Arizona) have a heterogeneous helium isotope signature, ranging from 8.8 RA at San Carlos to 0.46 at Hoover Dam. All D/H ratios for the water in kaersutites (?56‰ to ?78‰) represent typical mantle values with no apparent correlation with 3He/4He. The correlation of increasing carbon content (140–400 ppm) with increasing δ13C (?24.5‰ to ?16.7‰) may reflect differences in the proportions of oxidized and reduced carbon in these samples. 相似文献
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James W. Telford 《Pure and Applied Geophysics》1975,113(1):1067-1084
The various models that have been proposed for describing the dynamical development of small cumuli are discussed in terms of how well they predict the observed distribution of liquid water. The entrainment concept is examined and shown to involve contradictions when applied to growing blobs. An alternative process is offered in which the dominating factor in the cloud dynamics is the mixing in of drier overlying air down through the cloud until temporary static equilibrium is established. Consideration of the mixing process and calculations of the required dilution show this process can lead to the observed liquid water distributions. 相似文献