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1.
Limited information is available in the literature on the levels of brominated flame retardants in the southern hemisphere. This study presents concentrations of polybrominated diphenyl ethers (PBDEs) in the blubber of small cetaceans from the coast of São Paulo (Brazil), southwestern Atlantic. PBDE levels were highest in Stenellafrontalis (770 ng g−1 lipid) followed by Stenobredanensis (475 ng g−1 lipid), Sotaliaguianensis (65.6 ng g−1 lipid), Tursiopstruncatus (64.2 ng g−1 lipid) and Pontoporiablainvillei (60.3 ng g−1 lipid). In general, continental shelf individuals exhibited higher contamination than inshore animals. This might be related to larger prey items consumed by continental shelf dolphins. The pattern of contamination indicates that Penta-BDE commercial mixtures are a major source of PBDEs to top predators in the southwestern Atlantic. Congeners found in Octa-BDE formulations were not detected in the investigated animals.  相似文献   

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This article characterizes the spatial and temporal current variations, in the subtidal and tidal ranges, during the rainy and dry seasons, at the continental shelf off the Jaguaribe River, through measurements of continuous current field data from an acoustic Doppler current profiler (ADCP) mooring during 124 days, from June 12 to October 14, 2009. To support this dataset, we collected corresponding data from a meteorological station located at the estuary. The spatial variation showed that highest current speeds occur near the coast, with an offset of a NNW coastal jet, decreasing intensity, monotonically, towards offshore up to 0.1 ms?1. In the rainy season, small inversions of the wind field were observed, lasting 2 to 3 days on average and were accompanied by the direction of surface currents only. In the dry season, the period of reversal of wind fields and currents lasted 14 and 35 h, respectively. The analysis of empirical orthogonal functions in rainy and dry seasons showed that the continental shelf is predominantly barotropic, where the second and third modes explained only 7% of the total variance, during the dry season. The tidal currents are more intense in the direction normal to the coast, showing a semidiurnal tidal regime. Energy distribution between tidal currents and currents of longer periods showed that for the component parallel to bathymetry, subtidal frequency currents are dominant, contributing to more than 70% of the variance. For the normal component to the coastline bathymetry, there is a significant increase of power concerning tidal currents, at all depths, so they contribute with about 55% of the total variance.  相似文献   

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Ten sediment core samples with lengths ranging from 35 to 100 cm were collected in the Baixada Santista region and analyzed to determine As, Br, Co, Cr, Cs, Fe, Rb, Sb, Ta, Th, U, Zn and rare earths (Sc, Ce, Eu, La, Lu, Nd, Sm, Tb and Yb) level concentrations using instrumental neutron activation analysis (INAA). The studied region is located in the southeastern coast of São Paulo State and is comprised of a densely urbanized area, the largest industrial complex of the country, with a predominance of petrochemical and fertilizer plants. It is also home to Brazil’s most important and busiest port. The conclusions found that the As, La, Sm, Ne, Ce, Eu, Hf, Ta, Th, and U elements have a high background level in the region and that Fe and Zn were the main indicators of anthropogenic contribution in the sediments.  相似文献   

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We sampled different substrates (sand, gravel, leaf litter and stones) in the rainy and dry season to study the distribution and composition of benthic macroinvertebrates in tropical streams (northeastern Brazil). Benthic macroinvertebrates were distributed according to the substrates, with stones showing a higher richness and abundance of species and abundance of collector-gatherers and filter-collectors. The results of the PCoA showed a separation of stones from the other substrates and similarities between sand and gravel.  相似文献   

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The statistics of pre-midnight 5-m irregularities in the equatorial F region over São Luís is presented. The data set ranges from October 2001 to December 2008 and covers maximum solar-flux-to-minimum solar flux epoch. The variabilities in irregularity parameters, namely, height and time of their appearance in the radar echoes, with solar-flux variation are presented. The seasonal variations (combined over all years, irrespective of solar-flux) of occurrence of irregularities, occurrence of bottom-type layer (or bottom-side irregularities without plume) and bottom-side/topside plume (or bottom-side irregularities with plume) are presented. The largest occurrences of bottom-side irregularities without plume and with plume are found on April (equinox) and December (summer) months respectively. The ambient ionospheric conditions namely prereversal evening vertical drift, bottom-side density gradient and off-equatorial E region conductivity are inferred using digisonde measurements during April 2002 and December 2002. Based on these conditions and recent studies on gravity wave climatology over Brazil, it is suggested that shear in zonal plasma drift and low gravity wave activity may account for less occurrence of plume during April as compared to December months. This suggestion is quantified using numerical simulation model of collisional-interchange instability (CII) and plasma bubble.  相似文献   

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Coherent scatter radar observations conducted right before twilight by the 30 MHz radar in São Luís (Brazil) during both quiet (December 10, 2001) and disturbed (December 12, 2001) conditions detected type I echoes on the shoulders of broad type II spectra (near zero Doppler velocity). Zonal electric fields inferred from the São Luís ionosonde have a larger magnitude during the period where these spectral observations were made than on December 18, 2001 when type I echoes were not observed during late afternoon. The IMF Bz and AE index indicate that the extended geomagnetic disturbance in the afternoon of December 12, 2001 has allowed the interaction between disturbance dynamo and prompt penetration electric fields. The latter electric field component could have exceeded the former to give rise to the observed electric fields, and make possible observation of type I echoes.  相似文献   

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《水文科学杂志》2013,58(4):857-867
Abstract

Water abstraction for irrigation upstream of a reservoir and its impact on reservoir yield and reliability are studied. Water demand and availability are strongly related in semi-arid environments where the irrigation sector is responsible for a large part of consumptive water use. Variations in water abstractions for irrigation depend on irrigation requirements per hectare and the size of the irrigated area. The Orós Reservoir in semi-arid Northeast Brazil has been taken as a case study. The results show that water abstracttion for irrigation is of significant importance for reservoir yield and reliability. Yield—reliability simulations for the study area show that taking into account upstream water abstraction for a reservoir yield of 20.0 m3/s results in a water-scarcity probability of 10% on an annual basis (90% reliability). This is only 5% if up-stream abstraction for irrigation is ignored. This study shows that observed land-use changes in the study area do have a significant impact on reservoir yield reliability. The variability of upstream water abstraction was found to be of low importance for reservoir yield and reliability.  相似文献   

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Tree ring studies are usually used to determine or verify climatic factors prevailing at a given place or region that may cause tree-ring width variations. Few studies are dedicated to the solar phenomena which may underlie these tree-ring width variations. Furthermore, it is known that some terrestrial phenomena are influenced by short- and long-time scale solar variability. An optical and computational method was set up and applied to tree samples (Araucaria angustifolia from Santa Catarina State in Southern Brazil) in order to obtain a growth ring width mean chronology. Spectral analysis is used for the search of periodicities, by maximum entropy and iterative regression methods. The results evidenced several embedded signals at periods which may be related to solar activity variations. Cross-correlation analysis between sunspot number and tree-ring data was performed and a lag of zero year was obtained. From our work, it seems that the tropical conifer species Araucaria angustifolia may be a good choice for studies on Sun-Earth relationships and their regional effects.  相似文献   

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The accumulation of synthetic debris in marine and coastal environments is a consequence of the intensive and continuous release of these highly persistent materials. This study investigates the current status of marine debris ingestion by sea turtles and seabirds found along the southern Brazilian coast. All green turtles (n = 34) and 40% of the seabirds (14 of 35) were found to have ingested debris. No correlation was found between the number of ingested items and turtle’s size or weight. Most items were found in the intestine. Plastic was the main ingested material. Twelve Procellariiformes (66%), two Sphenisciformes (22%), but none of the eight Charadriiformes were found to be contaminated. Procellariiformes ingested the majority of items. Plastic was also the main ingested material. The ingestion of debris by turtles is probably an increasing problem on southern Brazilian coast. Seabirds feeding by diverse methods are contaminated, highlighting plastic hazard to these biota.  相似文献   

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Abstract

The definition of rainfall behaviour at the regional level is of great importance in planning policy for the rational use of water resources for both agricultural and urban uses. It allows the delimitation of areas of homogeneous rainfall features and shows the system dynamics in the area, so providing more comprehensive knowledge about the rainfall. Precipitation zones were identified within the São Francisco River basin, Northeast Brazil, by analysing the rainfall frequencies by means of global wavelet power spectra. Data from 200 raingauges were analysed and the results of the overall power spectra showed a high annual frequency throughout the basin; however, other frequencies are present with minor significance that represent changes in the rainfall regime. Although, the computed global wavelet power spectra presented an annual frequency, they showed peculiar patterns (denoted A and B) that could be used to characterize the region. Thus, three sub-regions with homogeneous rainfall patterns were identified as: Region A (south part of the basin) and Region B (north part of the basin), with frequency patterns A and B, respectively, and a Transition Zone in the central part that shows both frequency patterns.

Citation Santos, C.A.G. and Morais, B.S., 2013. Identification of precipitation zones within São Francisco River basin (Brazil) by global wavelet power spectra. Hydrological Sciences Journal, 58 (4), 789–796.  相似文献   

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Introduction Located between Qingzang (Qinghai-Xizang) Plateau that highly uplifts due to compression and North China plain that badly subsides due to crustal extension, the Ordos massif has both the basic attributes of stretching tectonic region of North China marginal basin and the features of marginal shear-compression zone of Qingzang Plateau. It has a length of about 600 km in the N-S direction and a width of about 400 km in the W-E direction. Its geological structure is very simple…  相似文献   

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S coda wave of seventy-four local earthquakes recorded in a network of ten seismic stations were used to calculate coda Q attenuation (Qc) in the João Câmara area (northeastern Brazil). The estimates show Qc as a strong function of frequency in the range from 6.0 to 20.0 Hz. We found out that Qc in João Câmara has a functional form given by Qc= Q0 f, where Q0= 151 ± 99 and = 0.98 ± 0.05. If the standard deviations are taken into account,we conclude that there are no relevant changes in both Q0 and values from one station to another. The estimated Q0 values at the different stations suggest that the Samambaia fault is a boundary between two different seismic attenuation zones. In one side of the fault (left), where stations were installed in Pre-Cambrian terrain and thick sedimentary layer, the seismic attenuation is stronger than in the other side (stations installed in thin sedimentary layer and limestone outcrop).The anomalous Q0 values in the left side of the Samambaia fault can be explained due to the presence of a shallow conductive layer in the upper crust( 10 km), such as proposed by Padilha et al. (1992). According to our results, if there is a conductive layer in the area, it probably spreads over João Câmara city and surrounding regions.However, more detailed investigation either with seismic methods (seismic attenuation,3D tomography with P and/or S wave velocities) or with other geophysical methods is needed to interpret the observed differences in Q0 values between the two sides of the Samambaia fault.  相似文献   

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This study reports the analysis of polycyclic aromatic compound (PAC) metabolites, as biomarkers of exposure to PACs in marine environment. PAC metabolites were measured in bile samples from 14 species of demersal fish caught in the São Sebastião Channel (SSC), SE Brazilian coastline. Naphthalene (NPH) equivalents, phenanthrene (PHN) equivalents, and benzo[a]pyrene (BaP) equivalents were quantified using a reverse-phase high-performance liquid chromatography coupled with fluorescence detection method. For all samples, the means (±standard deviation, n = 37) of concentrations obtained for NPH, PHN, and BaP equivalents were, respectively, 290,000 ± 200,000 ng/g, 18,000 ± 14,000 ng/g, and 970 ± 1900 ng/g. These results indicate recent exposure of these fish to PACs in their environment. In addition, two species (Cyclichthys spinosus and Prionotus nudigula) of fish were analyzed in order to investigate local sources of PAC contamination in the SSC and the influence of the petroleum terminal in fish caught in remote areas. The results showed that these fish species potentially migrate along the channel, especially P. nudigula. Correlations among groups of PAC metabolites indicate the same petrogenic source for NPH and PHN equivalents and a combustion source (e.g., automobile, ships) for BaP equivalents. The ratio BaP/PHN equivalents (0.05 ± 0.07, n = 37) confirms the predominance of petrogenic PACs for contamination by these chemicals in this region.  相似文献   

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Karst aquifers consist of complex networks of conduits in which groundwater flows and recharge/discharge processes are generally more dynamic than in other types of aquifers. Due to their intrinsic heterogeneity and anisotropy, monitoring, quantifying, and analysing natural responses of karst springs is an efficient tool. Unlike Cenozoic and Mesozoic rocks, in Neoproterozoic karst systems, groundwater circulates and stores generally in dissolution features known as tertiary porosity, as the rock's primary porosity is recrystallized, considered negligible. This article studies the hydrodynamics of a karst portion of the São Miguel River basin, southwest of the state of Minas Gerais, Brazil. The region is predominantly composed of Neoproterozoic carbonate rocks, dating from about 570 to 540 million years ago. During a hydrological year (2019–2020), three karst springs (S1, S2, and S3) were daily monitored through their natural responses (variations of electrical conductivity, EC, temperature, T, and discharge, Q) to rainfall episodes. The data were interpreted based on the analysis of spring hydrographs, time series, recession curves (seasonal and intra-annual), and statistics of EC, T, and Q variations. The results show the three springs generally exhibit quick flow, typically karstic, in the case of hydrosystems with a well-structured and functional underground drainage network. The time series indicate the hydrosystem drained by S1 presents slower circulation and a lower degree of linearity, resulting from the higher sinuosity of the system, while the hydrosystems of S2 and S3 have similar behaviours, of quick water circulations immediately after a rainy episode. The degrees of karstification classify S1 and S2 as complex and extensive karst systems consisting of several subsystems, and S3 as a system in which the conduit network is more developed at the upper epiphreatic zone than near the outlet.  相似文献   

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