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1.
A regional-scale groundwater study was conducted over a 2-year period to assess the extent of nitrate contamination and source identification for southern Baldwin County, AL. Groundwater wells were sampled and analyzed for nitrate and a host of other geochemical parameters which revealed that extensive areas within aquifer zone A2 exhibited nitrate concentrations exceeding regulatory limits. Spatial iso-concentration maps of nitrate were constructed using ArcGIS software to determine the extent and severity of contamination for the aquifers underlying southern Baldwin County with the primary interest focused on the heavily utilized aquifer zone A2. Nitrate levels in the central and northeastern portion of the study area were most extensive with maximum concentrations of 63 mg/L likely resulting from agricultural inputs. Several other small regions throughout the study area exhibited elevated levels of nitrate and chloride as high as 112 and 51.1 mg/L, respectively, and sources likely vary (i.e., residential septic systems, animal waste to agriculture). With the exception of a few groundwater samples, there was no obvious correlative relationship between chloride and nitrate concentration for data collected during the 2-year period. Collectively, a general inverse relationship between nitrate concentrations and well depth was observed for the aquifer system under investigation. The study provides an initial current data set of areas impacted or most vulnerable to nitrate contamination and initial assessment of likely sources of nitrate in the region.  相似文献   

2.
It is necessary to understand the presence, movement, and persistence of contaminants in aquifers to develop adequate groundwater protection plans. Fractured bedrock aquifers with thin overburden cover are very sensitive to contamination, and little is known about transport processes from the ground surface to depth in this setting. This study was undertaken to investigate the potential of groundwater contamination by polybrominated diphenyl ethers (PBDEs), which are flame retardants, in a natural fractured bedrock aquifer in Canada proven to be sensitive to contamination. PBDEs, which had not been previously measured in groundwater in detail, were detected in the study aquifer at concentrations greater than those observed in surface-water bodies. Potential sources include manure, septic tanks, and the atmosphere. From this scoping study, it is evident that additional surveys of PBDE concentrations in groundwater are warranted, especially in settings with high potential source concentrations coupled with sensitive aquifers.  相似文献   

3.
Groundwater in karstic aquifers can be dangerously sensitive to contamination. In this paper, DRASTIC assessment was modified and applied, for the first time, to address the intrinsic vulnerability for karst aquifers. The theoretical weights of two of DRASTIC’s parameters (aquifer media and hydraulic conductivity) were modified through sensitivity analysis. Two tests of sensitivity analyses were carried out: the map removal and the single parameter sensitivity analyses. The modified assessment was applied for the karst aquifers underlying Ramallah District (Palestine) as a case study. The aquifer vulnerability map indicated that the case study area is under low, moderate and high vulnerability of groundwater to contamination. The vulnerability index can assist in the implementation of groundwater management strategies to prevent degradation of groundwater quality. The modified DRASTIC assessment has proven to be effective because it is relatively straightforward, use data that are commonly available or estimated and produces an end product that is easily interpreted.  相似文献   

4.
High arsenic levels in groundwater of the aquifers, belonging to the Pliocene terrestrial layers and Quaternary alluvial sediments, have become a significant problem for the inhabitants living in Sarkisla (Turkey). The main objective of this study was to determine the origin and arsenic contamination mechanisms of the Sarkisla drinking water aquifer systems. The highest arsenic concentrations were found in Pliocene layers and alluvial sediments with concentrations ranging from 2.1 to 155 mg/kg. These rocks are the main aquifers in the study area, and most of the drinking groundwater demand is met by these aquifers. Groundwater from the Pliocene aquifer is mainly Ca-HCO3 and Ca-SO4 water type with high EC values reaching up to 3,270 μS/cm, which is due to the sulfate dissolution in some parts of the alluvial aquifer. Stable isotope values showed that the groundwater was of meteoric origin. Tritium values for the groundwater were between 8.31 and 14.06 TU, representing a fast circulation in the aquifer. Arsenic concentrations in the aquifers were between 0.5 and 345 μg/L. The highest arsenic concentrations detected in the Pliocene aquifer system reached up to 345 μg/L with an average value of 60.38 μg/L. The arsenic concentrations of the wells were high, while the springs had lower arsenic concentrations. These springs are located in the upper parts of the study area where the rocks are less weathered. The hydrogeochemical properties demonstrated that the water–rock interaction processes in sulfide-bearing rocks were responsible for the remarkably high groundwater arsenic contamination in the study area. In the study area, the arsenic levels determined in groundwater exceeded the levels recommended by the WHO. Therefore, it is suggested that this water should not be used for drinking purposes and new water sources should be investigated.  相似文献   

5.
A study was conducted to evaluate production strategies for a well field system near a source of groundwater contamination. Numerical modeling of groundwater flow was employed to generate hydraulic head configurations for different production scenarios. For a given scenario, an evaluation of contamination susceptibility was made by comparing head distributions in two aquifer units to the positions of the contaminant source and discharging water supply wells. The results of this study suggest that groundwater flow modeling can be a useful technique for planning the production of water supply wells in aquifers at risk of contamination from anthropogenic pollution sources.  相似文献   

6.
扬-泰-靖地区地下水系统水力联系与硫酸盐污染特征   总被引：2，自引：0，他引：2  
本文对长江三角洲扬-泰-靖地区第四系松散层地下水中环境同位素(D、18O、34S)的分布特征进行了分析,旨在揭示大气降水、长江水、潜水及承压水之间的水力联系,辨别地下水中硫酸盐的来源及其污染状况。研究结果表明潜水含水层接受大气降水及长江水的补给,硫酸盐主要为农业污染来源或与海源硫酸盐的混合。承压含水层主要接受大气降水的补给,与潜水含水层及长江之间的水力联系较差,硫酸盐来源不同。在研究区顶部和沿江地段的浅层孔隙承压水中,硫酸盐来源于硫化物的氧化;在东部的深层孔隙承压水中,硫酸盐主要来源于硫酸盐岩的溶解或海源硫酸盐的滞留,基本未受到潜水或地表水中硫酸盐的污染。  相似文献   

7.
The texture and three-dimensional framework of geologic materials should be considered in assessments of groundwater's vulnerability to contamination because geology controls the movement of contaminants and groundwater and influences groundwater quality. Contaminants are introduced into, transmitted through, and stored by geologic materials. We present a model that identifies aquifers and ranks sequences of geologic materials by their relative potential for transmitting water and contaminants from land surface. With this basis, the model can be used to assess the potential for contamination of aquifers by surface activities such as landfitling of wastes or application of agricultural chemicals. A regional map of aquifer contamination potential can be generated from the model; it retains the geologic map information intact and available for reinterpretation or other uses.The model was developed using broad, regional map information and is intended to be a general tool for assessing the regional vulnerability of aquifers to contamination. It is not intended for local, site-specific use, but for prioritizing local areas where contamination potential and/or land-use history warrant more detailed assessment or monitoring. Because it provides a regional view of contamination potential, regional patterns or trends of map units should be evaluated, rather than using the map information literally to assess local areas. Methods of applying this model and contamination potential map to groundwater protection and management are currently being studied; research includes an attempt to statistically validate the model with water-quality data, and to identify natural groupings of the ranked contamination potential map units.  相似文献   

8.
Groundwater resources are vulnerable to contamination especially in shallow aquifers. The aquifer hydrogeological parameters and the Land Uses category combinations lead to subdivide areas according to their contamination likelihood. In arid and semi-arid regions, shallow aquifers are more exposed to groundwater contamination due to high population densities (extensive uses) and agricultural activities (nitrate contamination). Moreover, these regions are characterized by low rainfall and high evaporation. Furthermore, the spread of farmland, industrial and domestic sectors, is the principal contaminant producer which threats the groundwater quality. To protect these limited resources, the groundwater vulnerability assessment was developed in Maritime Djeffara shallow aquifer (Southeastern Tunisia). The study area is essentially occupied by agricultural areas (intensive use of chemical fertilizers) in addition to the discharge of industrial zones. The main objective of this study is to assess the aquifer vulnerability using the Susceptibility Index (SI) method as a specific vulnerability model. The results show that the study area is classified into five classes of vulnerability: very low, low, medium, high, and very high (1.54, 20, 41.54, 35.9, and 1.02%, respectively) with an uneven spatial distribution. The risk results exhibit three degrees: low, moderate, and high. The validation of the vulnerability model was performed by using salinity values and nitrate concentrations with a correlation coefficient of about 57 and 55%, respectively. This study could serve as a scientific basis for sustainable land use planning and groundwater management in the study area.  相似文献   

9.
跨边界含水层作为地下水资源系统的一部分，涉及国家或地区之间的利益关系。文章分析了跨边界含水层问题，针对亚洲东部、中部和南部地下水系统，圈定了具有重要意义的跨国界含水层9处。对这些含水层，特别是我国边界上的黑龙江一阿穆尔河平原和伊犁河谷含水层进行了评价；对我国跨省界含水层进行了初步分析。研究跨边界含水层问题，对管理国家或地区之间共有的珍贵地下水资源，建设持久和平、共同繁荣的和谐社会具有重要的意义。  相似文献   

10.
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11.
以贵州省安龙县1∶50 000水文地质图幅为例,采用含水层探采井的水质、水量监测数据,分析不同含水层水资源赋存特征及其与水化学的相关性。研究结果表明:（1）研究区含水层可分为纯碳酸盐岩管道含水层、非纯碳酸盐岩裂隙含水层、碎屑岩裂隙含水层、松散岩类孔隙含水层4种类型,各含水层中地下水水化学类型均以HCO-Ca?Mg型为主;（2）除非纯碳酸盐岩含水层探采井的降深与水体中Mg2+、HCO-3浓度呈现出显著的负相关性（R2=-0.77/-0.74）外,其余离子浓度与钻井单位涌水量、降深的相关性均不显著,相关系数(R2)均小于0.3;（3）非纯碳酸盐岩含水层和松散岩类含水层的总矿化度（TDS）、总硬度（TH）含量均比纯碳酸盐岩含水层低5 mg?L-1以上,TDS、TH的高值区均集中于纯碳酸盐岩含水层中,而低值区则分布于松散岩类含水层。   相似文献   

12.
 Anthropogenic activities create various contaminated leachate, which can migrate downward from the vadose zone to groundwater, transferring contaminants, including some hazardous ones. When these various sources of contamination influence the groundwater aquifer simultaneously, the effects of contamination are enhanced. The major concern of this study has been to determine whether the shape of a groundwater chlorograph might be the result of such deterministic effects as accumulation of one or more particular processes of groundwater contamination, and how this might relate to specific hydrological situations. This study proposes a classification of groundwater contamination on the basis of properties of the main components of groundwater quality graphs and the corresponding hydrogeological/environmental situation. The study further suggests that contamination of groundwater in any hydrogeological situation (e.g. sea water) may be graphically expressed. A variety of chlorographs and nitrographs, representative of various groundwater aquifers sampled from a number of wells throughout Israel attest to this. The study thus indicates that groundwater quality graphs may be considered as a complementary tool for groundwater quality control and better understanding aquifer situations.  相似文献   

13.
The Zagros Mountain Ranges (ZMR) in southern and southwestern Iran consisting mainly of limestone are a large and very valuable catchment area, which recharges the aquifers in vast areas of Iran and of the Gulf States beyond the Persian Gulf. The collision resulting from the opening of the Red Sea and the convergence of Arabia towards Iran increases the rock porosity and thus the internal drainages. This helps to recharge the aquifers, but the ground water becomes more vulnerable to the growing landfill. Another source of ground water contamination is the Lower Paleozoic salt which crops out in the form of numerous salt plugs.The Makran Mountain Ranges (MMR) in southern and southeastern Iran are also a large catchment area and subjected to subduction. They have therefore different lithology and are less exposed to contamination.Because of the ongoing tectonic activities in different stages of plate convergence from subduction to incipient and advanced collision, the migration of ground water under the Persian Gulf to the Gulf States, the contamination of ground water by salt plugs and growing landfill, and the degree of rock exposure, a study of the relation of morphotectonics to ground water and its contamination in southern Iran seems to be required and promising.  相似文献   

14.
KARSTIC: a sensitivity method for carbonate aquifers in karst terrain   总被引：5，自引：2，他引：5  
. Groundwater in karstic aquifers can be dangerously sensitive to contamination. Many cities in the western USA rely on karstic carbonate aquifers for municipal water supplies. For example, Rapid City, South Dakota, pumps more than half of its drinking water from wells in the Madison Limestone. This work examined the sensitivity of karstic aquifers to surface contamination in mountainous terrain. Where karstic carbonate aquifers are exposed at their outcrop areas, they are particularly susceptible to the introduction of contamination through diffuse recharge or through point recharge at swallow holes along streams. Residential developments in mountainous regions of the western USA are encroaching on the recharge areas of karstic aquifers. Many of these residential developments are served by onsite wastewater disposal systems such as septic tanks and drain fields, with the attendant danger of introduction of pathogens from malfunctioning treatment systems above fractured limestone which offers little filtering. Where streams disappear into karstic aquifers at swallow holes, microbial contaminants such as Giardia or Cryptosporidium are a concern, as well as potential spills, leaks, or accidents along roads near these streams. The KARSTIC method developed and modified in this work puts greater emphasis on karst features than previous sensitivity procedures such as the US Environmental Protection Agency's DRASTIC method. The modified method gives increased attention to highly sensitive areas of karstic carbonate aquifers by weighting the synergistic effects of fracturing, karst development, and swallow holes of recharging streams. In a field application, hydrogeologic maps of a watershed in the Black Hills, USA, were digitized into a geographic information system. The resulting sensitivity map and report can be used by planners, managers, and the public as a screening tool for assessing groundwater sensitivity in regions which include karstic aquifers.  相似文献   

15.
Monitored natural attenuation can be a viable option for remediation of groundwater contamination by BTEX compounds. Under the field conditions, the rate of contaminant mass attenuation through natural processes, such as biodegradation, to a large extent affected by the groundwater flow regime, which is primarily controlled by the aquifer heterogeneity. Numerical simulation techniques were used to describe quantitatively the relationship between biodegradation rate of BTEX and aquifer heterogeneity. Different levels of aquifer heterogeneity were described by random hydraulic conductivity fields (K) having different statistical parameters, the coefficient of variation (CV) and the correlation length (h). The Turning Bands Algorithm was used to generate such K fields. Visual MODFLOW/RT3D was used to simulate the fate and transport of dissolved BTEX plume within heterogeneous aquifers. The multispecies reactive transport approach described BTEX degradation using multiple terminal electron-accepting processes. First-order biodegradation rate constants were calculated from simulated BTEX plumes in heterogeneous flow fields. The results showed that aquifer heterogeneity significantly affected biodegradation rate; it decreased with increasing CV when h was in the range of up to 12 m, whereas it increased with increasing CV when h was greater than about 12 m. For well characterized aquifers, this finding could be of great value in assessing the effectiveness of natural attenuation during feasibility studies at BTEX contaminated sites.  相似文献   

16.
Many cities in developing countries are dependent upon groundwater for water supply. Frequently this groundwater is pumped from semi-confined aquifers in alluvial deposits. These deeper aquifers are often considered to be protected from polluted shallow water by intervening less-permeable layers. However, where groundwater is pumped from a semi-confined aquifer immediately beneath a city, significant induced leakage of contaminated shallow water can occur. This may lead to a serious deterioration of water quality in deeper aquifers in the longer-term. A simple model has been developed which provides insight into the hydraulic controls on water quality in such semi-confined aquifers. The model provides a tool for the initial assessment and prediction of the impact of urbanization on groundwater quality. Also, the model characterizes the key hydrogeological behaviour through a single parameter, here termed the ‘city leakage factor’, which can be used to assess the vulnerability to contamination by leakage. A case study of a city in Thailand illustrates the use of this model.
Résumé Beaucoup de villes des pays en développement dépendent de l’eau souterraine pour leur alimentation en eau. Cette eau souterraine est souvent pompée dans des aquifères alluviaux semi-captifs. Ces aquifères plus profonds sont souvent considérés comme protégés des eaux peu profondes et polluées, grace à des couches intercalaires moins perméables. Cependant, dans le cas où l’eau souterraine est pompée à partir d’un aquifère semi-captif situé directement sous une ville, une drainance importante des eaux peu profondes et polluées peut être induite. Ceci peut entra?ner, à long terme, une détérioration significative de la qualité de l’eau dans les aquifères plus profonds. Un modèle simple a été construit fournissant un aper?u des contr?les hydrauliques agissant sur la qualité de l’eau dans des aquifères semi-captifs. Ce modèle est un outil permettant d’évaluer l’état initial et de prédire l’impact de l’urbanisation sur la qualité de l’eau souterraine. Le modèle caractérise également les comportements hydrogéologiques majeurs à travers un unique paramètre, nommé dans cette étude facteur de drainance de la ville“, et qui peut être utilisé pour évaluer la vulnérabilité de l’aquifère face à une contamination par drainance. L’étude de cas d’une ville en Tha?lande illustre l’utilisation de ce modèle.
Resumen Muchas ciudades de paises en desarrollo dependen del agua subterránea para el abastecimiento de agua. Frecuentemente el agua subterránea se bombea de acuíferos semi-confinados en depósitos aluviales. Estos acuíferos más profundos se protegen frecuentemente de agua somera contaminada mediante la intervencción de capas menos permeables. Sin embargo, donde el agua subterránea se bombea de un acuífero semi-confinado inmediatamente debajo de una ciudad, pueden ocurrir fugas significativas inducidas de agua somera contaminada. Esto puede conducir a un serio deterioro de calidad de agua en acuíferos más profundos en el largo plazo. Se ha desarrollado un modelo simple el cual aporta idea acerca de los controles hidráulicos en la calidad del agua en tales acuíferos semi-confinados. El modelo aporta una herramienta para la evaluación inicial y predicción del impacto de urbanización en la calidad del agua subterránea. El modelo también caracteriza el comportamiento hidrogeológico clave a traves de un solo parámetro, que aquí se denomina ′factor de fuga de la ciudad′el cual puede usarse para evaluar la vulnerabilidad a la contaminación por fuga. El uso de este modelo se ilustra con un estudio de caso de una ciudad en Tailandia.
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17.
This study investigated the relationship between near-surface lithology and the spatial variability of As concentrations using sediment grain-size analysis and electromagnetic induction survey in the southeast Bangladesh. It has been observed that the aquifers overlain by finer sediments have higher concentrations of As in groundwater, whereas As concentrations are remarkably low in aquifers having permeable sandy materials or thinner silt/clay layer at the surface. The near-surface lithology acts as a controlling factor for spatial distributions of groundwater As within the very shallow depths (<15 m). Shallow alluvial aquifers can provide low-As drinking water in many areas of the country when tube wells are properly installed after investigation of the overlying near-surface sediment attributes and hydraulic properties.  相似文献   

18.
In lagoonal and marine environments, both historic monuments and recent buildings suffer from severe salt damage caused by sea flooding, sea-level rise and frequent storm events. Salt-water contamination of groundwater systems, a widespread phenomenon typical of coastal areas, can lead to a deterioration not only of the quality of fresh groundwater resources, but also of building materials in urban settlements. A general overview is given of the hydrogeological configuration of the subsoil of Venice (Italy), with particular reference to the shallow groundwater circulation. The relationship between the seawater in the subsoil and salt decay processes, due to salt crystallization, is highlighted. These processes affect civil constructions in Venice??s historic center. Perched aquifers, influenced by tide variations and characterized by salt-water intrusion, favor the transport of salts within masonry walls through the action of rising damp. In fact, foundations, in direct contact with the aquifers, may become a preferential vehicle for the transportation of salt within buildings. Decay patterns of different building materials can be detected through non-destructive techniques, which can identify sea-salt damage and therefore assist in the preservation of cultural heritage in coastal areas.  相似文献   

19.
某油田地下水污染特征及其机理分析   总被引：1，自引：0，他引：1  
在对某油田石油类污染物分布特征研究的基础上,对其进入地下水的途径进行分析。研究表明,除石油类外,CODMn、Cl-、NO3-N和TDS具异常变化,这些异常变化已成为石油类污染的参考指标。含水层污染程度主要以严重污染和中度污染为主,下段含水层中的石油类污染物的浓度明显高于上段含水层。地下水遭受污染的途径类型分为地表渗透型和优势通道渗漏型,但地表渗透型污染对研究区地下水的威胁性相对来说较小。由构造活动、地下水开采引发的地裂缝形成的优势通道渗漏型污染是地下水污染的主要途径。  相似文献   

20.
This study used optical brighteners (OB) released from septic systems to show that groundwater flow direction is largely controlled by the structural framework in a faulted karst groundwater system. Effective protection of groundwater resources requires that groundwater systems are adequately characterized and source water protection areas (SWPA) are developed for drinking water wells. Karst aquifers are among the most sensitive to contamination due to high recharge rates, and among the most difficult aquifers to characterize due to heterogeneity, and anisotropy. Because septic systems may be used to treat wastewater within SWPAs for karst aquifers there is a need to characterize these groundwater systems using tracers. The objective of this study was to characterize groundwater flow in a faulted portion of the Edwards aquifer in Bexar County, Texas using OB that are released as incidental tracers from septic systems. This study included measurement of water levels, sampling of groundwater and surface water, analysis for OB, and spatial analysis in a GIS. Results show that OB intensities were highest to the southwest of the septic area, a direction that is sub-parallel to the fault and fracture orientation and nearly perpendicular to the hydraulic gradient. This indicates that movement of OB, solutes, or non-aqueous liquids/solids in a faulted karst system can be largely controlled by fault/fracture orientation and structural relay ramps.  相似文献   

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