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1.
Spatial distribution, source apportionment, and potential ecological risks of sixteen polycyclic aromatic hydrocarbons (PAHs) and seven endocrine disrupting compounds (EDCs) in the intertidal sediment at the Shuangtaizi Estuary, Bohai Sea of China were analyzed. Results showed that the total PAH concentrations ranged from 28.79 ng g? 1 dw to 281.97 ng g? 1 dw (mean: 115.92 ng g? 1 dw) and the total EDC concentrations from 0.52 ng g? 1 dw to 126.73 ng g? 1 dw (mean: 37.49 ng g? 1 dw). The distribution pattern for the PAHs was generally different from that of the EDCs possibly due to their distinct sources and n-octanol-/water partition coefficients (KOW). Qualitative and quantitative analytical results showed that PAH sources were mainly from a mixture of pyrogenic and petrogenic contributions. The higher levels at the southeast of Geligang indicated that the EDC pollutants may have mainly originated from the plastic industry and other chemical plants located along the Liao River. Ecological risk assessment revealed that PAHs exhibited low ecotoxicological effects, whereas EDCs, especially 4-tert-octylphenol and bisphenol A, had high ecological hazard to the estuarine biota.  相似文献   

2.
Surface sediments (n = 17) were collected from 6 sites located in the coasts of the Bushehr Peninsula. ∑16PAH concentrations were in the range of 285.9–1288 ng g? 1 dw and the sediments were moderately polluted. Py, Ph, B(a)A and Flu showed > 70% of the detected values in order of the mentioned rank. 4-ring PAHs were the dominant compounds and the molecular ratios presented the dominant pyrolytic source. The toxicity of PAHs for sediment dwelling life was averagely equivalent to occurrence of 0.08 ng g? 1 of Dioxin in dw of the examined sediments. The evaluated narcotic potential (confidence level of 99%) was 0.027–3.04 and upper part of the Bushehr Peninsula, where the human population is more concentrated, showed more narcotic potential. ∑ n-alkane concentrations (n-C15 ? n-C32) were in the range of 3.10–35.6 μg g? 1 dw. The dominant distribution of even carbon number n-alkanes was traced back to a possibly autochthonous source.  相似文献   

3.
The objective of this study was to explore the slope position and land use change effects on the variability in magnetic susceptibility and 137Cs inventory as the soil redistribution indicators in a hilly semiarid calcareous area in Iran. The selected study area is located in a hilly region with pasture and cultivation land use of Fereydunshahr, Isfahan Province in west-central Iran. In the two mentioned dominant ecosystems, four slope positions including summit, shoulder, backslope and footslope were identified and in each land use and slope position, three cores were selected to collect 72 soil samples from three depths (0–10, 10–20, 20–30 cm) in an area of 15 × 15 cm. Additional 28 soil samples were collected from the reference site for soil loss and deposition calculations by using the Cs-137 measurement. The results of the study with the use of the Cs-137 technique showed that the average soil loss in the pasture land (46.4 t ha− 1 yr− 1) was significantly (p < 0.05) lower than the average soil loss in the cultivated land (80.4 t ha− 1 yr− 1). The highest soil loss in both land uses was obtained in the shoulder position, 60.1 and 84.4 t ha− 1 yr− 1, respectively, for the pasture and cultivated lands. Moreover, the highest rates of soil deposition was observed in a footslope position in both land uses and they were 34 and 32.4 t ha− 1 yr− 1 for the pasture and cultivated lands, respectively. Magnetic susceptibility was significantly (p < 0.05) greater in pasture (χlf = 41.51 × 10− 8 m3/kg) than in the cultivated land (χlf = 34.90 × 10− 8 m3/kg). The pasture land with a lower soil loss rate, indicated significantly higher magnetic susceptibility in all landform positions as compared to that in the cultivated land. The results of the correlation analysis showed that among the studied soil physico-chemical properties, χlf (r = 0.83, p < 0.01) in the pasture land had the highest correlation with the Cs-137 inventory. Throughout the non-linear regression analysis, χlf was introduced for relating soil parameters and the cesium inventory explained 68% and 79% of the total variability of 137Cs in the pasture and cultivated lands, respectively. The results implied that the variability in the magnetic susceptibility within the hillslope is consistent with the variation of the Cs-inventory; and the results thus demonstrate the slope and land use effects on soil redistribution.  相似文献   

4.
《Journal of Hydrology》2006,316(1-4):213-232
The Magdalena River, a major fluvial system draining most of the Colombian Andes, has the highest sediment yield of any medium-sized or large river in South America. We examined sediment yield and its response to control variables in the Magdalena drainage basin based on a multi-year dataset of sediment loads from 32 tributary catchments. Various morphometric, hydrologic, and climatic variables were estimated in order to understand and predict the variation in sediment yield. Sediment yield varies from 128 to 2200 t km−2 yr−1 for catchments ranging from 320 to 59,600 km2. The mean sediment yield for 32 sub-basins within the Magdalena basin is ∼690 t km−2 yr−1. Mean annual runoff is the dominant control and explains 51% of the observed variance in sediment yield. A multiple regression model, including two control variables, runoff and maximum water discharge, explains 58% of the variance. This model is efficient (ME=0.89) and is a valuable tool for predicting total sediment yield from tributary catchments in the Magdalena basin. Multiple correlations for those basins corresponding to the upper Magdalena, middle basin, Eastern Cordillera, and catchment areas greater than 2000 km2, explain 75, 77, 89, and 78% of the variance in sediment yield, respectively. Although more variance is explained when dataset are grouped into categories, the models are less efficient (ME<0.72). Within the spatially distributed models, six catchment variables predict sediment yield, including runoff, precipitation, precipitation peakedness, mean elevation, mean water discharge, and relief. These estimators are related to the relative importance of climate and weathering, hillslope erosion, and fluvial transport processes. Time series analysis indicates that significant increases in sediment load have occurred over 68% of the catchment area, while 31% have experienced a decreasing trend in sediment load and thus yield. Land use analysis and increasing sediment load trends indicate that erosion within the catchment has increased over the last 10–20 years.  相似文献   

5.
In the last decade, sediment replenishment forming cohesionless sandy banks below dams has become an increasingly common practice in Japan to compensate for sediment deficits downstream. The erosion process of the placed cohesionless sediment is a combination of lateral toe-erosion and the following mass failure. To explore cohesionless bank failure mechanisms, a series of experiments was done in a soil tank using a compacted sandy soil mass exposed to an increasing water level. Two types of uniform sand(D_(50) = 0.40 mm and 0.17 mm) and two bank heights(50 cm and 25 cm) were used under the condition of a constant bank slope of 75°. The three dimensional(3D) geometry of the bank after failure was measured using a handheld 3D scanner. The motion of bank failure was captured using the particle image velocimetry(PIV) technique, and the matric suction was measured by tensiometers. The compacted sandy soil was eroded by loss of matric suction accompanying the rise in water level which subsequently caused rotational slide and cantilever toppling failure due to destabilization of the bank. The effect of erosion protection resulting from the slumped blocks after these failures is discussed in the light of different failure mechanisms. Tensile strength is analyzed by inverse calculation of cantilever toppling failure events. The tensile strength had non-linear relation with degree of saturation and showed a peak.The findings of the study show that it is important to incorporate the non-linear relation of tensile strength into stability analysis of cantilever toppling failure and prediction of tension crack depth within unsaturated cohesionless banks.  相似文献   

6.
The incidence and severity of extraordinary macroalgae blooms (green tides) are increasing. Here, climate change (ocean warming and acidification) impacts on life history and biochemical responses of a causative green tide species, Ulva rigida, were investigated under combinations of pH (7.95, 7.55, corresponding to lower and higher pCO2), temperature (14, 18 °C) and nitrate availability (6 and 150 μmol L? 1). The higher temperature accelerated the onset and magnitude of gamete settlement. Any two factor combination promoted germination and accelerated growth in young plants. The higher temperature increased reproduction, which increased further in combination with elevated pCO2 or nitrate. Reproductive success was highest (64.4 ± 5.1%) when the upper limits of all three variables were combined. Biochemically, more protein and lipid but less carbohydrate were synthesized under higher temperature and nitrate conditions. These results suggest that climate change may cause more severe green tides, particularly when eutrophication cannot be effectively controlled.  相似文献   

7.
In a mountain environment, the transport of coarse material is a key factor for many fields such as geomorphology, ecology, hazard assessment, and reservoir management. Despite this, there have been only a few field investigations of bedload, in particular using multiple monitoring methods. In this sense, attention has frequently focused on the effects of “high magnitude/low frequency floods” rather than on “ordinary events”. This study aims to analyze the sediment dynamics triggered by three high-frequency floods (recurrence interval “RI” between 1.1 and 1.7 yr) that occurred in the Rio Cordon basin during 2014. The flood events were investigated in terms of both sediment mobility and bedload magnitude. The Rio Cordon is an Alpine basin located in northeastern Italy. The catchment has a surface area of 5 km2, ranging between 1763 and 2763 m above sea level. The Rio Cordon flows on an armored streambed layer, with a stable step-pool configuration and large boulders. Since 1986, the basin has been equipped with a permanent station to continuously monitor water discharge and sediment flux. To investigate sediment mobility, 250 PIT-tags were installed in the streambed in 2012. The 2014 floods showed a clear difference in terms of tracer displacement. The near-bankfull events showed equal mobility conditions, with mean travel distance one order of magnitude higher than the below-bankfull event. Furthermore, only the near-bankfull events transported coarse material to the monitoring station. Both events had a peak discharge up to 2.06 m3 s-1, but the bedload transport rates differed by more than one order of magnitude, proving that under the current supply-limited condition, the bedload appears more related to the sediment supply than to the magnitude of the hydrological features. In this sense, the results demonstrated that near-bankfull events can mobilize large amounts of material for long distances, and that floods of apparently similar magnitude may lead to different sediment dynamics, depending on the type and amount of sediment supply.  相似文献   

8.
The lateral and vertical extents of Macondo oil in deep-sea sediments resulting from the 2010 Deepwater Horizon oil spill were determined using chemical forensics and geostatistical kriging of data from 2397 sediment samples from 875 cores collected in 2010/2011 and 2014. The total mass of Macondo-derived hopane on the seafloor in 2010/2011 was conservatively estimated between 2.00 and 2.26 metric tons, derived from 219,000 to 247,000 barrels of oil; or 6.9 to 7.7% of the 3.19 million barrels spilled. Macondo-derived hopane was deposited over 1030 to 1910 km2 of the seafloor, mostly (> 97%) in surface (0–1 cm) and near-surface (1–3 cm) sediments, which is consistent with short-term oil deposition. Although Macondo oil was still present in surface sediments in 2014, the total mass of Macondo-derived hopane was significantly lower (~ 80 to 90%) than in 2010/2011, affirming an acute impact from the spill and not long-term deposition from natural seeps.  相似文献   

9.
The levels and distribution of tris-(2,3-dibromopropyl) isocyanurate (TBC) and hexabromocyclododecanes (HBCDs) of surface sediments in the Yellow River Delta wetland had been investigated. The concentrations of TBC and ∑ HBCDs ranged from 0.20 to 29.03 ng·g? 1 dw and below limits of detections (LODs) to 20.25 ng·g? 1 dw. The average composition profile of three HBCDs isomers were 10.1%, 6.1% and 83.8% for α-, β- and γ-HBCD, respectively. Moreover, correlation analysis indicated there are similar sources among three isomers and positive correlations between total organic carbon (TOC) content and concentrations of TBC and HBCDs. The mass inventory of TBC,α-, β-, γ-HBCD, ΣHBCDs in surface sediments of Yellow River Delta wetland were estimated about 725.50, 72.76, 44.29, 548.34, 665.39 kg. Therefore, further investigations on potential human health and environmental risk assessments of TBC and HBCDs were needed.  相似文献   

10.
The spectral attenuation of solar irradiation was measured during summer in two types of coastal waters in southern Chile, a north Patagonian fjord (Seno Reloncaví) and open coast (Valdivia). In order to relate the light availability with the light requirements of upper subtidal seaweeds, the saturating irradiance for photosynthesis (Ek) from P–I curves was measured. In addition the UV risk was assessed. Based on the z1% of PAR, the lower limit of the euphotic zone in the studied systems averaged 21 m (Kd 0.24 m?1) in Seno Reloncaví and 18 m (Kd 0.27 m?1) in the coast of Valdivia. Photosynthesis of the studied seaweeds was saturated at markedly lower irradiances than found in their natural depths at the time of the study. Solar radiation penetrating into these depths at both locations largely supports the light requirements for the photosynthesis of subtidal species: 50–160 μmol m?2 s?1 for seaweeds from Seno Reloncaví (7 m tidal range) and 20–115 μmol m?2 s?1 for Valdivia assemblages (2 m tidal range). Optimal light conditions to saturate photosynthesis (Ek) were present at 10–16 m water depth. The attenuation of solar irradiation did not vary significantly between the fjord and coastal sites of this study. However, the underwater light climates to which seaweeds are exposed in these sites vary significantly because of the stronger influence of tidal range affecting the fjord system as compared with the open coastal site. The patterns of UV-B penetration in these water bodies suggest that seaweeds living in upper littoral zones such as the intertidal and shallow subtidal (<3 m) may be at risk.  相似文献   

11.
Volume measurements for magnesiowüstite (Mg0.6Fe0.4)O, were carried out up to pressures of 10.1 GPa in the temperature range 300–1273 K, using energy-dispersive synchrotron X-ray diffraction. These data allow reliable determination of the temperature dependence of the bulk modulus and good constraint on the thermal expansitivity at ambient pressure which was previously not known for magnesiowüstite. From these data, thermal and elastic parameters were derived from various approaches based on the Birch–Murnaghan equation of state (EOS) and on the relevant thermodynamic relations. The results from three different equations of state are remarkably consistent. With (∂KT/∂P)T fixed at 4, we obtained K0=158(2) GPa, (∂KT/∂T)P=−0.029(3) GPa K−1, (∂KT/∂T)V=−3.9(±2.3)×10−3 GPa K−1, and αT=3.45(18)×10−5+1.14(28)×10−8T. The K0, (∂KT/∂T)P, and (∂KT/∂T)V values are in agreement with those of Fei et al. (1992) and are similar to previously determined values for MgO. The zero pressure thermal expansitivity of (Mg0.6Fe0.4)O is found to be similar to that for MgO (Suzuki, 1975). These results indicate that, for the compositional range x=0–0.4 in (Mg1−xFex)O, the thermal and elastic properties of magnesiowüstite exhibit a dependence on the iron content that is negligibly small, within uncertainties of the experiments. They are consequently insensitive to the Fe–Mg partitioning between (Mg, Fe)SiO3 perovskite and magnesiowüstite when applied to compositional models of the lower mantle. With the assumption that (Mg0.6Fe0.4)O is a Debye-like solid, a modified equation of heat capacity at constant pressure is proposed and thermodynamic properties of geophysically importance are calculated and tabulated at high temperatures.  相似文献   

12.
The aim of the present study is to optimize the slow release biostimulant ball (BSB) for bioremediation of contaminated coastal sediment using response surface methodology (RSM). Metals contamination and stabilization of metals in coastal sediments using BSB were investigated. The effects of BSB size (1–5 cm), distance (1–10 cm), and time (1–4 months) on the stabilization of metals including Fe, Cd, Cu, and Pb were determined. The maximum stabilization percentages of Fe, Cd, Cu, and Pb, of 64.5%, 54.9%, 63.8%, and 47.6%, respectively, were observed at a 3 cm ball size, 5.5 cm distance, and a period of 4 months; these values are the optimum conditions for effective treatment of contaminated coastal sediment. The determination coefficient of the R2 value suggests that > 91.55%, 89.97%, 96.10%, and 86.40% of the variance is attributable to the variables of Fe, Cd, Cu, and Pb, respectively.  相似文献   

13.
The activities of the natural radionuclides (238U, 232Th, 226Ra and 40K) of the surface sediments in the Yangtze Estuary were determined and used to evaluate radiation hazards in the study area. The of activities of 238U, 232Th, 226Ra and 40K ranges from 14.1 to 62.3, 26.1 to 71.9, 13.7 to 52.3, and 392 to 898 Bq kg? 1, respectively, which were comparable to values of other regions in China. The activities of 232Th, 40K and 226Ra were clearly different from the global recommended values. The radium equivalent activity was less than the recommended limit of 370 Bq kg? 1; therefore, the sediment in this area can be safely used for reclamation. The external hazard index values were less than one. The average absorbed gamma dose rate and annual effective dose equivalent values were slightly greater than the world average value. 226Ra/238U and 232Th/238U ratios could potentially be applied for tracing sediment source.  相似文献   

14.
Wildfire is a natural component of sagebrush (Artemisia spp.) steppe rangelands that induces temporal shifts in plant community physiognomy, ground surface conditions, and erosion rates. Fire alteration of the vegetation structure and ground cover in these ecosystems commonly amplifies soil losses by wind- and water-driven erosion. Much of the fire-related erosion research for sagebrush steppe has focused on either erosion by wind over gentle terrain or water-driven erosion under high-intensity rainfall on complex topography. However, many sagebrush rangelands are geographically positioned in snow-dominated uplands with complex terrain in which runoff and sediment delivery occur primarily in winter months associated with cold-season hydrology. Current understanding is limited regarding fire effects on the interaction of wind- and cold-season hydrologic-driven erosion processes for these ecosystems. In this study, we evaluated fire impacts on vegetation, ground cover, soils, and erosion across spatial scales at a snow-dominated mountainous sagebrush site over a 2-year period post-fire. Vegetation, ground cover, and soil conditions were assessed at various plot scales (8 m2 to 3.42 ha) through standard field measures. Erosion was quantified through a network of silt fences (n = 24) spanning hillslope and side channel or swale areas, ranging from 0.003 to 3.42 ha in size. Sediment delivery at the watershed scale (129 ha) was assessed by suspended sediment samples of streamflow through a drop-box v-notch weir. Wildfire consumed nearly all above-ground live vegetation at the site and resulted in more than 60% bare ground (bare soil, ash, and rock) in the immediate post-fire period. Widespread wind-driven sediment loading of swales was observed over the first month post-fire and extensive snow drifts were formed in these swales each winter season during the study. In the first year, sediment yields from north- and south-facing aspects averaged 0.99–8.62 t ha−1 at the short-hillslope scale (~0.004 ha), 0.02–1.65 t ha−1 at the long-hillslope scale (0.02–0.46 ha), and 0.24–0.71 t ha−1 at the swale scale (0.65–3.42 ha), and watershed scale sediment yield was 2.47 t ha−1. By the second year post fire, foliar cover exceeded 120% across the site, but bare ground remained more than 60%. Sediment yield in the second year was greatly reduced across short- to long-hillslope scales (0.02–0.04 t ha−1), but was similar to first-year measures for swale plots (0.24–0.61 t ha−1) and at the watershed scale (3.05 t ha−1). Nearly all the sediment collected across all spatial scales was delivered during runoff events associated with cold-season hydrologic processes, including rain-on-snow, rain-on-frozen soils, and snowmelt runoff. Approximately 85–99% of annual sediment collected across all silt fence plots each year was from swales. The high levels of sediment delivered across hillslope to watershed scales in this study are attributed to observed preferential loading of fine sediments into swale channels by aeolian processes in the immediate post-fire period and subsequent flushing of these sediments by runoff from cold-season hydrologic processes. Our results suggest that the interaction of aeolian and cold-season hydrologic-driven erosion processes is an important component for consideration in post-fire erosion assessment and prediction and can have profound implications for soil loss from these ecosystems. © 2019 John Wiley & Sons, Ltd.  相似文献   

15.
Mercury (Hg) can reach the environment through natural and human-related sources, threatening ecosystems all over the planet due to its well known deleterious effects. Therefore, Antarctic trophic webs, despite being relatively isolated, are not exempt of its influence. To evaluate Hg concentrations in an Antarctic ecosystem, different tissues from 2 species of invertebrates, 2 of fish, 8 of birds, 4 of pinnipeds and at least 5 of vegetation were investigated (n = 176). For animals, values ranged from 0.018 to 48.7 μg g? 1 dw (whole Antarctic krill and Antarctic Fur Seal liver). They were generally correlated to trophic position (assessed by δ15N and δ13C) but also to cephalopods and myctophids consumption. For vegetation, values ranged from 0.014 to 0.227 μg g? 1 dw (Colobanthus quitensis and an unidentified lichen), with lichens presenting significantly higher values than mosses, likely due to year-round exposure and absorption of animal derived organic matter, as hypothesized by literature.  相似文献   

16.
《Continental Shelf Research》2007,27(10-11):1477-1500
Constraining the exchange of water from the shoreline to the mid-shelf is necessary for the development of accurate and predictive models of nearshore circulation. Ra isotopes, which emanate from sediments and have a variety of half-lives, may be useful in measuring cross-shelf mixing rates. The distributions of Ra isotopes were measured in transects extending perpendicular from the shoreline at Sunset Beach and Huntington Beach, CA. The average inventory at Sunset Beach was four times greater than at Huntington Beach. Building on previous research on Ra inputs and circulation in San Pedro Bay, a two-dimensional model for surface water Ra was developed to identify the importance of onshore flow and cross-shelf mixing near Huntington Beach. For the mean summertime conditions, the eddy diffusivity (Kh) was 1.4±0.4 m2 s−1, with 8% of the water from Sunset Beach moving down the coast. The remaining water must be low-Ra water that has moved onshore. At time scales greater than a week, the short-lived Ra inventory at Huntington Beach varied by 50%, which reflects changes in the fractions of water moving down-coast and/or in the longshore advection rate. The shoreline Ra concentration varied on time scales of hours, which may be generated by tidal changes in the Ra input at the shoreline and short-period fluctuations in the mixing rate. The low Kh observed in this study in comparison to higher values measured further offshore is evidence that Kh increases with distance offshore. When scale-dependent mixing beyond 455 m offshore is incorporated into the model, the results are consistent with the observed data for 223Ra, 224Ra, and 228Ra. Using the model, the 228Ra input flux to the summertime mixed layer was between 3.4×106 and 4.0×106 atoms s−1 (m shoreline)−1.  相似文献   

17.
The feasibility of a potential bioindicator based on functional groups of microzooplankton tintinnids for bioassessments of water quality status was studied during southwest monsoon (June to September) along the coastal waters of Kalpakkam, India during 2012–2015. The work highlights the following features (1) tintinnid community composed of 28 species belonging to 11 genera and 9 families, revealed significant differences among the four study sites (2) maximum numerical abundance (2224 ± 90 ind. l? 1) and species diversity (H′ = 2.66) of tintinnid were recorded towards Bay of Bengal whereas minimum abundance (720 ± 35 ind. l? 1) and diversity (H′ = 1.74) were encountered in the backwater sites, (3) multivariate analyses [RELATE, Biota-environment (BIOENV) and canonical analysis of principal coordinates (CAP)] reveal that chl a, nitrate and phosphate were the potential causative factors for tintinnid distribution. Based on the results, we suggest that tintinnids may be used as a potential bioindicator of water quality status in marine ecosystem.  相似文献   

18.
Electromagnetic induction (EMI) instruments provide rapid, noninvasive, and spatially dense data for characterization of soil and groundwater properties. Data from multi-frequency EMI tools can be inverted to provide quantitative electrical conductivity estimates as a function of depth. In this study, multi-frequency EMI data collected across an abandoned uranium mill site near Naturita, Colorado, USA, are inverted to produce vertical distribution of electrical conductivity (EC) across the site. The relation between measured apparent electrical conductivity (ECa) and hydraulic conductivity (K) is weak (correlation coefficient of 0.20), whereas the correlation between the depth dependent EC obtained from the inversions, and K is sufficiently strong to be used for hydrologic estimation (correlation coefficient of ? 0.62). Depth-specific EC values were correlated with co-located K measurements to develop a site-specific ln(EC)–ln(K) relation. This petrophysical relation was applied to produce a spatially detailed map of K across the study area. A synthetic example based on ECa values at the site was used to assess model resolution and correlation loss given variations in depth and/or measurement error. Results from synthetic modeling indicate that optimum correlation with K occurs at ~ 0.5 m followed by a gradual correlation loss of 90% at 2.3 m. These results are consistent with an analysis of depth of investigation (DOI) given the range of frequencies, transmitter–receiver separation, and measurement errors for the field data. DOIs were estimated at 2.0 ± 0.5 m depending on the soil conductivities. A 4-layer model, with varying thicknesses, was used to invert the ECa to maximize available information within the aquifer region for improved correlations with K. Results show improved correlation between K and the corresponding inverted EC at similar depths, underscoring the importance of inversion in using multi-frequency EMI data for hydrologic estimation.  相似文献   

19.
Digital Soil Mapping (DSM) is widely used in the environmental sciences because of its accuracy and efficiency in producing soil maps compared to the traditional soil mapping. Numerous studies have investigated how the sampling density and the interpolation process of data points affect the prediction quality. While, the interpolation process is straight forward for primary attributes such as soil gravimetric water content (θg) and soil bulk density (ρb), the DSM of volumetric water content (θv), the product of θg by ρb, may either involve direct interpolations of θv (approach 1) or independent interpolation of ρb and θg data points and subsequent multiplication of ρb and θg maps (approach 2). The main objective of this study was to compare the accuracy of these two mapping approaches for θv. A 23 ha grassland catchment in KwaZulu-Natal, South Africa was selected for this study. A total of 317 data points were randomly selected and sampled during the dry season in the topsoil (0–0.05 m) for θg by ρb estimation. Data points were interpolated following approaches 1 and 2, and using inverse distance weighting with 3 or 12 neighboring points (IDW3; IDW12), regular spline with tension (RST) and ordinary kriging (OK). Based on an independent validation set of 70 data points, OK was the best interpolator for ρb (mean absolute error, MAE of 0.081 g cm−3), while θg was best estimated using IDW12 (MAE = 1.697%) and θv by IDW3 (MAE = 1.814%). It was found that approach 1 underestimated θv. Approach 2 tended to overestimate θv, but reduced the prediction bias by an average of 37% and only improved the prediction accuracy by 1.3% compared to approach 1. Such a great benefit of approach 2 (i.e., the subsequent multiplication of interpolated maps of primary variables) was unexpected considering that a higher sampling density (∼14 data point ha−1 in the present study) tends to minimize the differences between interpolations techniques and approaches. In the context of much lower sampling densities, as generally encountered in environmental studies, one can thus expect approach 2 to yield significantly greater accuracy than approach 1. This approach 2 seems promising and can be further tested for DSM of other secondary variables.  相似文献   

20.
This work aimed to evaluate the use of Mugil curema as a biomonitor for polycyclic aromatic hydrocarbon (PAH) bioavailability. Fish biliary metabolites from low-contaminated (Cananéia) and contaminated (Santos) Brazilian estuaries were analysed using a high-performance liquid chromatography apparatus coupled to fluorescence detectors connected in a series. In the Cananéia and Santos estuaries, total metabolite levels ranged from 0.85 to 34.4 μg g? 1 of bile and from 4.06 to 528 μg g? 1 of bile, respectively. Metabolite levels were not influenced by feeding status or sexual hormones (p < 0.05), thus suggesting that M. curema is a good biomonitor for PAH bioavailability. In estuarine regions, it is possible to sample both the male and female genders of this species in any reproductive period.  相似文献   

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