共查询到20条相似文献，搜索用时 62 毫秒
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G. G. Pavlova A. G. Vladimirov V. I. Gvozdev P. G. Korostelev B. I. Semenyak V. G. Gonevchuk P. A. Tishin 《Doklady Earth Sciences》2016,471(1):1118-1122
The increased demand for indium has made it necessary to revise prospects of In-bearing tin ore deposits in the Russian Far East on the basis of geological data and results of recent analytical methods (X-ray fluorescence with synchrotron radiation, atomic absorption, and ICP-MS). The average In contents in ores of the Tigrinoe and Pravourmiiskoe deposits vary from 55 to 70 ppm, which allows tin ore deposits with Sn?sulfide mineralization to be considered as quite promising with respect to In production from ores of Russian deposits. By their estimated In reserves, the Tigrinoe and Pravourmiiskoe deposits may be attributed to large ore objects. 相似文献
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Sonja Aulbach Steven B. Shirey Thomas Stachel Steven Creighton Karlis Muehlenbachs Jeff W. Harris 《Contributions to Mineralogy and Petrology》2009,157(4):525-540
Sulfide inclusions in diamonds from the 90-Ma Jagersfontein kimberlite, intruded into the southern margin of the Kaapvaal
Craton, were analyzed for their Re–Os isotope systematics to constrain the ages and petrogenesis of their host diamonds. The
latter have δ13C ranging between −3.5 and −9.8‰ and nitrogen aggregation states (from pure Type IaA up to 51% total N as B centers) corresponding
to time/temperature history deep within the subcontinental lithospheric mantle. Most sulfides are Ni-poor ([Ni + Co]/Fe = 0.05–0.25
for 15 of 17 inclusions), have elevated Cu/[Fe + Ni + Co] ratios (0.02–0.36) and elemental Re–Os ratios between 0.5 and 46
(12 of 14 inclusions) typical of eclogitic to more pyroxenitic mantle sources. Re–Os isotope systematics indicate two generations
of diamonds: (1) those on a 1.7 Ga age array with initial 187Os/188Os (187Os/188Osi) of 0.46 ± 0.07 and (2) those on a 1.1 Ga array with 187Os/188Osi of 0.30 ± 0.11. The radiogenic initial Os isotopic composition for both generations of diamond suggests that components with
high time-integrated Re–Os are involved, potentially by remobilization of ancient subducted oceanic crust and hybridization
of peridotite. A single sulfide with higher Os and Ni content but significantly lower 187Os/188Os hosted in a diamond with less aggregated N may represent part of a late generation of peridotitic diamonds. The paucity
of peridotitic sulfide inclusions in diamonds from Jagersfontein and other kimberlites from the Kaapvaal craton contrasts
with an overall high relative abundance of diamonds with peridotitic silicate inclusions. This may relate to extreme depletion
and sulfur exhaustion during formation of the Kaapvaal cratonic root, with the consequence that in peridotites, sulfide-included
diamonds could only form during later re-introduction of sulfur. 相似文献
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V. V. Maslennikov N. R. Ayupova S. P. Maslennikova A. Yu. Lein A. S. Tseluiko L. V. Danyushevsky R. R. Large V. A. Simonov 《Lithology and Mineral Resources》2017,52(4):334-334
The ore-formational, ore-facies, lithological, and mineralogical-geochemical criteria are defined for the detection of hydrothermal ecosystem fauna in ores of the volcanic-hosted massive sulfide deposits in the Urals. Abundant mineralized microfauna is found mainly in massive sulfide mounds formed in the jasperous basalt (Buribai, Priorsk, Yubileinoe, Sultanov), rhyolite—basalt (Yaman-Kasy, Blyava, Komosomol’sk, Sibai, Molodezhnoe, Valentorsk), and the less common serpentinite (Dergamysh) formations of the Urals (O—D2). In the ore-formational series of the massive sulfide deposits, probability of the detection of mineralized fauna correlates inversely with the relative abundance of felsic volcanic rocks underlying the ores. This series is also marked by a gradual disappearance of colloform pyrite, marcasite, isocubanite, pyrrhotite, and pyrite pseudomorphoses after pyrrhotite; increase of the amount of bornite, fahlores, and barite; decrease of contents of Se, Te, Co, and Sn in chalcopyrite and sphalerite; and inсrease of Tl, As, Sb, and Pb in the colloform pyrite. Probability of the detection of mineralized fauna in the morphogenetic series of massive sulfide deposits decreases from the weakly degraded sulfide mounds to the clastic stratiform deposits. The degradation degree of sulfide mounds and fauna preservation correlates with the attenuation of volcanic intensity, which is reflected in the abundance of sedimentary and volcanosedimentary rocks and the depletion of effusive rocks in the geological sections. 相似文献
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It has been shown from petrologic,geochemical,trace element and REE evidence that the gran-ite intrusions at Sikongshan,Anhui Province,can be assigned to two distinct types which are radically different in age and origin.The Precambrian gneissic granited resulted from remelting of old continental crust while the Mesozoic granites were derived ,also through remelting,from low-Rb/Sr rocks at greater depths.Granite masses at Tiantangzhai and Zhoujiawan in the Dabieshan Mountains are also dicussed. 相似文献
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N. R. Ayupova V. V. Maslennikov V. A. Kotlyarov S. P. Maslennikova L. V. Danyushevsky R. Large 《Doklady Earth Sciences》2017,473(1):318-322
For the first time, extremely high Se and In contents were determined for the pinches of massive sulfide orebodies that are composed of small-clastic layered sulfide sediments transformed during submarine supergenesis. Se (clausthalite and naumannite) and In (roquesite) minerals were found. Hydrothermal chalcopyrite, a significant amount of which is present in the clasts of paleohydrothermal black smoker chimneys, was the source of Se. Most of the amount of In was contributed during dissolution of clasts of hydrothermal sphalerite, which is unstable in the submarine oxidation zone in the presence of oxidized pyrite. 相似文献
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Mineralogy and Petrology - Contemporary mineralogy and geochemistry are concerned with understanding and deciphering processes that occur near the surface of the Earth. These processes are... 相似文献
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K. R. Kovalev O. N. Kuzmina B. A. Dyachkov A. G. Vladimirov Yu. A. Kalinin E. A. Naumov M. V. Kirillov I. Yu. Annikova 《Geology of Ore Deposits》2016,58(2):116-133
The Zhaima gold–sulfide deposit is located in the northwestern part of the West Kalba gold belt in eastern Kazakhstan. The mineralization is hosted in Lower Carboniferous volcanic and carbonate rocks formed under conditions of marginal-sea and island-arc volcanic activity. The paper considers the mineralogy and geochemistry of primary gold–sulfide ore and Au-bearing weathering crusts. Au-bearing arsenopyrite–pyrite mineralization formed during only one productive stage. Disseminated, stringer–disseminated, and massive rocks are enriched in Ti, Cr, V, Cu, and Ni, which correspond to the mafic profile of basement. The main ores minerals are represented by finely acicular arsenopyrite containing Au (up to few tens of ppm) and cubic and pentagonal dodecahedral pyrite with sporadic submicroscopic inclusions of native gold. The sulfur isotopic composition of sulfides is close to that of the meteoritic standard (δ34S =–0.2 to +0.2). The 40Ar/39Ar age of three sericite samples from ore veinlets corresponds to the Early Permian: 279 ± 3.3, 275.6 ± 2.9, and 272.2 ± 2.9 Ma. The mantle source of sulfur, ore geochemistry, and spatial compatibility of mineralization with basic dikes allow us to speak about the existence of deep fluid–magmatic systems apparently conjugate with the Tarim plume. 相似文献
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Doklady Earth Sciences - An attempt to provide a new explanation for the change in the geodynamic regime in the Early Cretaceous is presented below. It accounts for data on a number of global... 相似文献
10.
Victor Kress 《Contributions to Mineralogy and Petrology》2007,154(2):191-204
Experiments were performed in the system O–S–Fe–Ni designed to extend our understanding of the chemistry of sulfide liquids.
Results indicate that adding nickel to Fe-rich sulfide liquids in equilibrium with silicate liquids extends their stability
field to much higher oxygen fugacities and lower sulfur fugacities. Increasing Ni/Fe at a given temperature and sulfur and
oxygen fugacity is accompanied by a significant decrease in the oxygen content of the sulfide liquid. Results of these experiments
are combined with data from the literature to calibrate an associated regular solution model for O–S–Fe–Ni liquids. This model
represents a complete refit of the associated regular solution model of Kress (Contrib Mineral Petrol 139:316–325, 2000). The resulting model is combined with the olivine solution model of Hirschmann (Am Mineral 76:1232–1248, 1991) to explore the effect of variations in oxygen and sulfur fugacities on the distribution of Fe and Ni between olivine and
sulfide liquid. Predicted olivine–sulfide distribution trends parallel those observed by Gaetani and Grove (Geochim Cosmochim
Acta 61:1829–1846, 1997), Gaetani and Grove (Earth Planet Sci Lett 169:147–163, 1999), Brenan and Caciagli (Geochim Cosmochim Acta 64:307–320, 2000) and Brenan (Geochim Cosmochim Acta 67:2663–2681, 2003), but are systematically offset toward lower predicted Ni in the sulfide. Nevertheless our results are consistent with the
assertion that low K
D
os
values in magmatic ore deposits such as the J-M Reef reflect high iron contents in the sulfides combined with relatively
high oxygen fugacities.
相似文献
| Victor KressEmail: |
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The Kalatongke (also spelt as Karatungk) Ni–Cu–(platinum-group element, PGE) sulfide deposit, containing 33 Mt sulfide ore
with a grade of 0.8 wt.% Ni and 1.3 wt.% Cu, is located in the Eastern Junggar terrane, Northern Xinjiang, NW China. The largest
sulfide ore body, which occupies more than 50 vol.% of the intrusion Y1, is dominantly comprised of disseminated sulfide with
a massive sulfide inner zone. Economic disseminated sulfides also occur at the base of the intrusions Y2 and Y3. The main
host rock types are norite in the lower part and diorite in the upper part of each intrusion. Enrichment in large ion lithophile
elements and depletion in heavy rare earth elements relative to mid-ocean ridge basalt indicate that the mafic intrusions
were produced from magmas derived from a metasomatized garnet lherzolite mantle. The average grades of the disseminated ores
are 0.6 wt.% Ni and 1.1 wt.% Cu, whereas those of the massive ores are 2 wt.% Ni and 8 wt.% Cu. The PGE contents of the disseminated
ores (14–69 ppb Pt and 78–162 ppb Pd) are lower than those of the massive ores (120–505 ppb Pt and 30–827 ppb Pd). However,
on the basis of 100% sulfide, PGE contents of the massive sulfides are lower than those of the disseminated sulfides. Very
high Cu/Pd ratios (>4.5 × 104) indicate that the Kalatongke sulfides segregated from PGE-depleted magma produced by prior sulfide saturation and separation.
A negative correlation between the Cu/Pd ratio and the Pd content in 100% sulfide indicates that the PGE content of the sulfide
is controlled by both the PGE concentrations in the parental silicate magma and the ratio of the amount of silicate to sulfide
magma. The negative correlations between Ir and Pd indicate that the massive sulfides experienced fractionation. 相似文献
12.
H. M. Helmy C. Ballhaus R. O. C. Fonseca T. J. Nagel 《Contributions to Mineralogy and Petrology》2013,166(6):1725-1737
Experimentally derived phase relations of arsenide in sulfide melt are presented to quantify the fractionation paths of As-bearing sulfide melts. When a natural sulfide melt reaches arsenide saturation, a separate Ni–PGE-rich arsenide melt exsolves. The arsenic saturation concentration in an Fe–Ni–Cu sulfide melt is between 0.5 and 1.5 wt%. The affinities of the chalcophile metals for an immiscible arsenide melt follow the order Pt > Pd > Ni ? Fe ≈ Cu. In natural systems, arsenide exsolution will be triggered by the activity of the nickel arsenide components dissolved in sulfide melt, Ni being the most common base metal with strong affinity to the Asn? anionic species. Arsenic may have a major effect on the fractionation paths of sulfide melts even if no separate arsenide phase forms. Arsenic, and probably many other chalcogens and metalloids in magmatic melts, may undergo associations with Pt and Pd well before discrete PGE minerals become stable phases. 相似文献
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The bedded clastic ore widespread on the slopes and flanks of the deeply eroded sulfide mound at the Saf’yanovka volcanic-hosted
copper massive sulfide deposit consists of products of destruction of the Paleozoic black smoker along with diverse newly
formed sulfides. The size of ore clasts gradually decreases with distance from the massive ore mound, from more than tens
of centimeters to a few millimeters. The clastic sediments are characterized by good preservation of sulfide material composed
of hydrothermal sedimentary colloform pyrite, chalcopyrite with lamellae of relict isocubanite, and concentrically zoned sphalerite.
Numerous pyrite framboids, nodules, and euhedral crystals; chalcopyrite segregations; and twinned sphalerite are typical of
sulfide-bearing black shale. Enargite, tennantite, and galena were formed after pyrite, filling interstices between nodules
or partially replacing and corroding the previously formed minerals. The interrelations between minerals show that the fine-clastic
sulfide-bearing black shale underwent diagenesis in the presence of organic matter. 相似文献
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M. V. Charykova V. G. Krivovichev O. S. Yakovenko V. V. Semenova K. N. Semenov W. Depmeier 《Geology of Ore Deposits》2012,54(8):638-646
The understanding of the mechanisms of the selenium behavior under near-surface conditions is an urgent problem of modern mineralogy and geochemistry, and is very important for solving environmental problems. The objective of this study is to synthesize analogs of ahlfeldite and cobaltomenite and to estimate their solubility in water. These analogs have been synthesized by mixing aqueous solutions of cobalt and nickel nitrates, respectively, and sodium selenite acidified with a solution of nitric acid. The obtained samples have been identified by X-ray diffraction and IR spectroscopy. The solubility has been determined by the isothermal saturation method in ampoules at 25°C, while the solubility products have been calculated using the Geochemist’s Workbench (GMB 7.0) software package. The solubility products of ahlfeldite and cobaltomenite are 10?9.20 and 10?9.44, respectively. The Eh-pH diagrams were calculated and plotted with the GMB 7.0 software package. The Eh-pH diagrams of the Ni-Se-H2O and Co-Se-H2O systems have been calculated for the average contents of these elements in underground water and their contents in acidic water of the oxidation zone of sulfide deposits. The formation of ahlfeldite and cobaltomenite under near-surface conditions is discussed. 相似文献
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Saburo Sakai Masaru Nakaya Yoshikazu Sampei David L. Dettman Katsumi Takayasu 《Environmental Earth Sciences》2013,68(7):1999-2006
The relationship among H2S, total organic carbon (TOC), total sulfur (TS) and total nitrogen contents of surface sediments (0–1 cm) was examined to quantify the relationship between H2S concentrations and TOC content at the sediment water interface in a coastal brackish lake, Nakaumi, southwest Japan. In this lake, bottom water becomes anoxic during summer due to a strong halocline. Lake water has ample dissolved SO4 2? and the surface sediments are rich in planktic organic matter (C/N 7–9), which is highly reactive in terms of sulfate reduction. In this setting the amount of TOC should be a critical factor regulating the activity of sulfate reduction and H2S production. In portions of the lake where sediment TOC content is less than 3.5 %, H2S was very low or absent in both bottom and pore waters. However, in areas with TOC >3.5 %, H2S was correlated with TOC content (pore water H2S (ppm) = 13.9 × TOC (%) ? 52.1, correlation coefficient: 0.72). H2S was also present in areas with sediment TS above 1.2 % (present as iron sulfide), which suggests that iron sulfide formation is tied to the amount of TOC. Based on this relationship, H2S production has progressively increased after the initiation of land reclamation projects in Lake Nakaumi, as the area of sapropel sediments has significantly increased. This TOC–H2S relationship at sediment–water interface might be used to infer H2S production in brackish–lagoonal systems similar to Lake Nakaumi, with readily available SO4 2? and reactive organic matter. 相似文献
17.
I. V. Gaskov A. G. Vladimirov A. I. Khanchuk G. A. Pavlova V. I. Gvozdev 《Geology of Ore Deposits》2017,59(1):56-67
The study of base-metal massive sulfide and tin–sulfide deposits in Siberia and the Russian Far East has revealed that the indium content in ores exceeding the average statistical value at similar deposits worldwide could be economically important. Sphalerite and chalcopyrite and chalcopyrite, bornite, and sphalerite are the major indium carriers in the base-metal massive sulfide and tin–sulfide ores, respectively. In addition, base-metal massive sulfide ores have high Cd, Ag, and Te contents, whereas tin–sulfide ores have elevated Ge, Ga, and Nb contents. This has stimulated the investment attractiveness of these deposits. 相似文献
18.
The paper presents concentrations of the platinum-group and chalcophile elements in the base metal sulfides (BMS) from the Jinchuan Ni–Cu sulfide deposit determined by laser ablation-inductively coupled plasma-mass spectrometry. Mass balance calculations reveal that pentlandite hosts a large proportion of Co, Ni and Pd (> 65%), and that pentlandite and pyrrhotite accommodate significant proportions of Re, Os, Ru, Rh, and Ag (~ 35–90%), whereas chalcopyrite contains a small amount of Ag (~ 10%) but negligible platinum-group elements. Iridium and Pt are not concentrated in the BMS and mostly occur in As-rich platinum-group minerals. The enrichments of Co, Ni, Re, Os, Ru, and Rh in pentlandite and pyrrhotite, and Cu in chalcopyrite are consistent with the fractionation of sulfide liquid and exsolution of pentlandite and pyrrhotite from the mono-sulfide solid solution (MSS). The Ir-bearing minerals exsolved from the MSS, depleting pentlandite and pyrrhotite in Ir, whereas sperrylite exsolved from the residual sulfide liquid on cooling. Diffusion of Pd from residual sulfide liquid into pentlandite during its exsolution from the MSS and crystallization of Pt-bearing minerals in the residual sulfide liquid resulted in the enrichment of Pd in pentlandite and decoupling between Pd and Pt in the Jinchuan net-textured and massive ores. 相似文献
19.
M. V. Charykova V. G. Krivovichev O. S. Yakovenko V. V. Semenova K. N. Semenov W. Depmeier 《Geology of Ore Deposits》2013,55(7):525-531
Understanding the mechanisms of arsenic’s behavior under near-surface conditions is one of the actual problems of contemporary mineralogy and geochemistry and is important for solving environmental problems. The aim of this study is to synthesize analogs of erythrite and annabergite and to investigate their solubility in water. These phases have been synthesized by the boiling-dry of aqueous solutions of cobalt and nickel nitrates mixed with sodium hydroarsenate alkalized with NaOH. The samples obtained have been identified with electron microprobe, X-ray diffraction, and IR spectroscopy. Solubility has been determined by the isothermal saturation method in ampoules at 25°C. The solubility has been calculated using the Geochemist’s Workbench (GMB 7.0) software package. The measured solubilities of erythrite and annabergite are 10?35.76 and 10?36.43, respectively. Eh-pH diagrams were calculated and plotted using the GMB 7.0 software package. The database comprises the thermodynamic parameters of 46 elements, 47 main particles, 48 redox pairs, 552 particles in solution, 624 solid phases, and 10 gases. The Eh-pH diagrams of the Ni-As-H2O and Co-As-H2O systems were plotted for the average contents of these elements in the acidic waters in the oxidation zones of sulfide deposits. The formation of erythrite and annabergite under near-surface conditions is discussed. 相似文献
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Based on the analytical results for 101 samples from 50 survey spots,this paper describes the changes in rations of various components in calcium carbonate from the sea area at the Pearl River mouth with pH.Relations of ∑CO2 with salinity,and Ca concentration with salinity in different parts of the river mouth have been established.The annual throughput of Ca from the Pearl River and the saturation degrees of calcite and aragonite have been calculated. 相似文献