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1.
The reduction of shallow-water platform seas favorable for dolomite formation was one of the factors responsible for the decrease and shift of this process to the coastal zones. The carbonate accumulation was influenced by several factors, such as climatic, tectonic (subsidence rates and lithospheric plate position, which determined the shelf occurrence in favorable climatic zones), and global sealevel fluctuations, which controlled the shelf bathymetry and dimensions. The interrelation of these factors, as well as their influence on carbonate accumulation is very intricate and ambiguous. Therefore, none of them can be discriminated as preponderant. Differences in the Paleozoic and Mesozoic-Cenozoic carbonate accumulation and dolomite formation are outlined according to climatic environments, relationship with sealevel fluctuations, atmosphere composition, and other features.  相似文献   

2.
Kuh-e Mond Field is a conventional heavy oil resource in the Zagros foreland Basin, Iran, produced from the fractured carbonates partially filled by dolomite, calcite, and anhydrite cement. Vitrinite reflectance data from carbonate reservoir suggest low-maturation levels corresponding to paleotemperatures as low as 50 °C. The observed maturation level (< 0.5% Rmax) does not exceed values for simple burial maturation based on the estimated burial history. Oil inclusions within fracture-filled calcite and dolomite cement indicate the key role of these fractures in oil migration.The fluid inclusion temperature profiles constructed from the available data revealed the occurrence of petroleum in dolomite, calcite, and anhydrite and characterize the distinct variations in the homogenization temperatures (Th). Fluid inclusions in syntectonic calcite veins homogenize between 22 °C and 90 °C, showing a salinity decrease from 22 to 18 eq. wt.% NaCl. Fluid inclusions in anhydrite homogenize at < 50 °C, showing that the pore fluids became warmer and more saline during burial. The Th range in the calcite-dolomite cement depicts a change in water composition; therefore, we infer these cements precipitated from petroleum-derived fluids. The microthermometry data on the petroleum fluid inclusions suggest that the reservoir was filled with heavy black oils and high-salinity waters and indicate that undersaturated oil was present in a hydrostatically pressured reservoir.The Th data do not support vertical migration of hot fluids througout the section, but extensive lateral fluid migration, most likely, drove tectonically dewatering in the south or west of the pool.  相似文献   

3.
Carbonatites are often of economic importance, which raises the problem of distinguishing carbonatites from limestones when either are metamorphosed to high-grade marbles. They can be of similar appearance, particularly those from the Proterozoic and Archaean of the Indian Subcontinent. This study also contributes to solving the problem of determining the frequency of alkaline and carbonatitic magmatism during the early history of the Earth.The mineral assemblage of apatite–magnetite–phlogopite–calcite is common to marbles of both carbonatite and limestone origin. If pyrochlore is present that identifies the rock as carbonatite; if anorthite, fassaite, scapolite or spinel then it was formerly a limestone. If these minerals are absent, then trace element analysis can supply the critical Sr and REE data, which are both normally high in carbonatitic rocks and low in former limestones. These distinguishing factors are applied to the metamorphic carbonate, pyroxenite, calcite–apatite rock complex at Borra, Eastern Ghats, India, which has been variously interpreted as formerly a carbonatite and as a limestone. The evidence shows that the Borra rocks are meta-sedimentary.  相似文献   

4.
Molecular biomarkers are the important maturity parameters for sedimentary organic matter.They have also been widely used for determining the maturity of organic matter in ore deposits. However,during the study of organic matter in the Kupferschiefer from the Lubin mine, it had been found that the biomarkers were influenced by sulfide formation. In order to probe into the degree of influence on biomarkers, seven samples collected from a Kupferschiefer section from the Lubin mine were analyzed by various geochemical methods. The results indicated that in the samples with higher copper contents, the values of biomarkers are lower than in the samples with lower copper contents. In highly mineralized samples, hydrogen donation for thermochemical sulfate reduction (TSR) occurred in alkylated phenanthrenes and naphthalenes, leading to the decrease of 12 biomarker parameters during the Kupferschiefer mineralization.  相似文献   

5.
Based on materials obtained in Cruises 33 and 34 of the R/V Professor Logachev, the paper addresses formation conditions, morphology, structures, mineral composition of the present-day oceanic sulfide ores, and their relationships with the host (biogenic carbonate) bottom sediments in the 19°–20° N MAR (Zenith-Victoria and Petersburg hydrothermal fields) region. The grain size distribution, mineral composition of the carbonate (background) and ore-hosting sediments, as well as physicochemical parameters of their interstitial waters, are examined. The results suggest a significant role of hydrothermal-metasomatic processes in the formation of ores and ore-bearing sediments. A model is proposed for the formation of sulfide mineralization in oceanic sediments at the geochemical barrier in the zone of their interaction with the acid hydrothermal (diffuse-type) ore-bearing solutions delivered from rocks of the ocean floor.  相似文献   

6.
The carbonate sediments from the Vendian–Cambrian shelf of the Tuva-Mongolian microcontinent were dated by Sr and C isotope chemostratigraphy. Analysis of the Sr-isotopic characteristics (0.70725–0.70873) and δ13C variations (+ 10.5 to –3.5‰), as well as their comparison with the data on the key sections of Siberia, Africa, Central Asia, Australia, South America, and Spitsbergen, showed that the carbonate sedimentary cover of the Tuva-Mongolian microcontinent accumulated at 600–520 Ma and the carbonate sediments of the Muren Formation and the basal beds of the Bokson Group near the Ukha-Gol River are the oldest. Their sedimentation followed the Marinoan global glaciation.  相似文献   

7.
The Jurassic successions represent a wide distribution in North of the Kerman province. These successions include Ab-Haji, Badamu, and Hojedk formations. The Hojedk Formation contains the plant fossils. The Lenjan section is one of the suitable areas for paleontological studies on the Hojedk Formation. The study section is mostly composed of green sandstone and shale with several interbedded coal veins with different thicknesses. The thickness of the Hojedk Formation is about 200 m in the Lenjan section. In this study, seven genera and 13 species of macro plant fossils were identified and described, including Nilssonia undulata, Nilssonia bozorga, Nilssonia berriesi, Nilssonia sp., Klukia cf. exilis, Klukia exilis, Cladophlebis antarctica, Coniopteris lobata, Coniopteris murrayana, Elatocladus confertus, Podozamites sp., Equisetites sp., and Coniopteris sp. The Bajocian–Bathonian can be attributed to the Lenjan section based on the recognized flora.  相似文献   

8.
We carried out a comprehensive facies/microfacies, micropalaeontological and biostratigraphical analysis of several carbonate olistoliths incorporated within a widely developed Albian conglomeratic sequence from the Eastern Carpathians of Romania. The majority of the sampled olistoliths contain a rich assemblage of benthic foraminifera and calcareous green algae. All of the described microfossils represent common lowermost Cretaceous taxa not previously reported from these carbonate elements or from this region. Based on benthic foraminifera assemblages the age of the studied olistoliths is upper Berriasian–lower Valanginian, contrary to the general belief that they are Barremian–Aptian in age. The dominant microfacies types mainly reflect deposition in shallow-water environments and show similarities with synchronous platform carbonates of the central-western Neotethys Ocean. The micropalaeontological and sedimentological data support new interpretations concerning the source area of these carbonate elements and provide new information concerning the evolution of the lowermost Cretaceous carbonate platforms of the Carpathians.  相似文献   

9.
The Hassi R’Mel field, which is the largest gas field in Algeria, produces principally gas condensate. The produced gas and oil comes from four reservoirs of Triassic age (reservoir A, reservoir B, reservoir C, and the Lower Series). All the previous studies in this field focused only on the upper reservoirs (A, B, and C), which have shown an excellent petrophysical properties. However, due to the presence of shale facies as well as volcanic intrusions, the Lower Series reservoir has been less explored. Thus, our study is mainly focused on this Lower Series in order to find the best sandy levels. The aim of this paper was to determine the facies types in the area, their distribution in the southern area of the Hassi R’Mel gas field, and their depositional environment. The Triassic rocks in this field are divided into four formations. From the youngest to oldest, these are S4, Lower Shale, Horizon A, and the Lower Series. The Lower Series formation can be further divided into three members (shaly sandstone, andesite, and lower shale). The shaly sandstone member within the Lower Series is composed of four units that are present all over the study area with an important pinch-out toward the northern part. The depositional environment within the defined units is a braided fluvial system in the southern part that evolves into a meandering fluvial system toward the north. Thus, the study area is considered to be a transitional zone between two depositional systems.  相似文献   

10.
The sorption of aqueous cadmium on carbonate-hydroxyapatite （CHap） is a complicated non-homogeneous solid/water reaction, From kinetic point of view, it can be described by two stages： at the earlier stage, reaction rate is so fast that its kinetic course is intricate, and at the later stage, the rate of reaction becomes slow and the process of reaction accords with one order reaction kinetic equation. Experimental results show that the relationship between reaction rate constant kl and temperature T accords to Arrhenius Equation, and the activation energy of sorption （Ea） is 6.075 J/mol and frequency factor （A） is 220 s^-1. At the same time, reaction rate constant kl increases with decreasing Cd^2＋ initial concentration, on the contrary, with increasing pH and CHap dosage.  相似文献   

11.
The Brno Massif in Moravia, Czech Republic, is an important exposure of Precambrian basement in central Europe. It includes large volumes of Cadomian granitoids and a narrow fault-bounded zone with metagabbros, metadiorites, and metabasalts. This so-called Central Basic Belt also contains some metarhyolites; one of these was dated by means of the zircon evaporation method at 725 ±15 Ma. Chemical and isotope data show that the dated rock represents a mantle-derived magma which is cosanguinous with surrounding MORB-type metabasites. The data suggest that the Brno Massif hosts the oldest metabasite complex currently known in central Europe. Its formation apparently coincides with the main period of ocean-floor spreading and island-arc formation in the Panafrican orogens. This lends further support to the theory that the Brno Massif is a Gondwana-derived element. Received: 9 December 1999 / Accepted: 9 February 2000  相似文献   

12.
E. V. Bibikova 《Petrology》2010,18(5):482-488
Analysis of isotope-geochemical data obtained for the early crustal complexes of the Earth provided constraints on the formation time, scales of development, and geochemical features of protocrust. Most informative were isotope-geochemical and geochemical data on the oldest zircons with ages up to 4.4 Ga, short-lived 146Sm/142Nd isotope system, and lead isotope composition of the oldest rocks of Greenland. The presence of positive 142Nd anomaly in the rocks of West Greenland and negative anomaly in the amphibolites of the oldest Nuvvuagittuq greenstone belt of the Superior province (O’Neil et al., 2008) indicates the early differentiation of the Earth material into depleted mantle and enriched (basaltic) crust (Caro et al., 2006; Benett et al., 2007a, b; O’Neil et al., 2008). Pb-Pb isotopic systematics of the oldest crustal rocks from West Greenland and Labrador testifies that high μ enriched crust (238U/204Pb = 10.9) of basaltic composition already existed 3.9 Ga ago (Kamber et al., 2003). Based on isotope-geochemical and geochemical features of the oldest zircons in the Late Archean greenstone belts of the Yilgarn block (Western Australia), the crust of intermediate-felsic composition and water on the Earth’s surface already existed 4.4 Ga ago (Wilde et al., 2001).  相似文献   

13.
A new chelid species (Prochelidella cerrobarcinae nov. sp.) are described from the Aptian-Albian? Puesto La Paloma Member, Cerro Barcino Formation, northern of Chubut Province, Argentina. The basal section of this member, which bears the turtle remains, is composed of tuffaceous mudstones with plane parallel lamination, asymmetrical ripples and a chert intercalation suggesting sub-aqueous deposition in a relatively shallow lacustrine environment. Pr. cerrobarcinae nov. sp. is represented by post-cranial remains of several specimens that not only represents the oldest pleurodiran chelid record in the world but, together with the chelid remains of Albian Lightning Ridge, New South Wales, Australia, indicates that chelid diversification began well before the final fragmentation of southern Gondwana.  相似文献   

14.
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15.
The Upper Cretaceous succession outcropping in the Anamas–Akseki Autochton, consists of approximately 500 m thick purely platform carbonate sediments. It begins with Cenomanian limestones intercalated with limestone breccias (Unit-1) containing mainly Pseudorhapydionina dubia, Pseudonummoloculina heimi, Spiroloculina cretacea (Assemblage I) and unconformably overlies the Lower Cretaceous (Barremian–Aptian) limestones with Vercorsella laurentii, Praechrysalidina infracretacea and Salpingoporella hasi. The Cenomanian limestones include foraminiferal packstone–wackestone, peloidal packstone–wackestone and mudstone microfacies deposited in restricted platform conditions. The Cenomanian succession is truncated by an unconformity characterised by locale bauxite deposits. Immediately above the unconformable surface, dolomitic limestones and rudistid limestones (Unit-2) are assigned to the upper Campanian based on the benthic foraminiferal assemblage (Assemblage II) comprising mainly Murciella gr. cuvillieri, Pseudocyclammina sphaeroidea, Accordiella conica, Scandonea samnitica and Fleuryana adriatica (smaller-sized populations). The upper Campanian limestones composed of dominantly foraminiferal-microbial packstone–wackestone microfacies deposited in shallow water environment with low energy, restricted circulation. The following limestones of the Unit-2 is characterised by sporadic intercalation of “open shelf” Orbitoides, Omphalocyclus, Siderolites assemblage (Assemblage III), assigned to the Maastrichtian, in addition to pre-existing “restricted platform” species. In the upper part of this biozone, the Rhapydionina liburnica/Fleuryana adriatica concurrent range subzone (Assemblage IIIb) is distinguished by the presence of Valvulina aff. triangularis, Loftusia minor as well as the nominal species. The Maastrichtian limestones with sporadically open marine influence consist of bioclastic (rudist-bearing) packstone–floatstone, foraminiferal packstone–wackestone with rudist fragments and peloidal/intraclastic packstone–wackestone microfacies deposited in shallow subtidal–subtidal (lagoonal) environments. The Upper Cretaceous succession passes upwardly into 70 m thick limestones and clayey limestones (Unit-3) which do not contain rudists and pre-existing foraminiferal assemblage with one exception Valvulina aff. triangularis. Variable amounts of ostracoda, discorbids, miliolids, dasycladacean algae and Stomatorbina sp. (Assemblage IV) occur into mud-rich microfacies suggesting restricted conditions with low water energy. A probable Danian age is proposed for the Unit-3 based on the occurrence of Valvulina aff. triangularis and Stomatorbina sp. which were previously recorded from Danian of peri-Tethyan platforms.  相似文献   

16.
Carbonate, largely in the form of dolomite, is found throughout the host rocks and ores of the Nchanga mine of the Zambian Copperbelt. Dolomite samples from the hanging wall of the mineralization show low concentrations of rare-earth elements (REE) and roof-shaped, upward convex, shale-normalized REE patterns, with positive Eu*SN anomalies (1.54 and 1.39) and marginally negative Ce anomalies (Ce*SN 0.98,0.93). In contrast, dolomite samples associated with copper and cobalt mineralization show a significant rotation of the REE profile, with HREE enrichment, and La/LuSN ratios <1 (0.06–0.42). These samples also tend to show variable but predominantly negative Eu*SN and positive cerium anomalies and an upwardly concave MREE distribution (Gd-Er). Malachite samples from the Lower Orebody show roof-tile-normalized REE patterns with negative europium anomalies (Eu*SN 0.65–0.80) and negative cerium anomalies (Ce*SN 0.86–0.9). The carbonate 87Sr/86Sr signature correlates with the associated REE values. The uppermost dolomite samples show Neoproterozoic seawater-like 87Sr/86Sr ratios ranging from 0.7111 to 0.7116, whereas carbonate from Cu–Co mineralized samples show relatively low concentrations of strontium and more radiogenic 87Sr/86Sr, ranging between 0.7136–0.7469. The malachite samples show low concentrations of strontium, but give a highly radiogenic 87Sr/86Sr of 0.7735, the most radiogenic 87Sr/86Sr ratio. These new data suggest that the origin and timing of carbonate precipitation at Nchanga is reflected in the REE and Sr isotope chemistry. The upper dolomite samples show a modified, but essentially seawater-like signature, whereas the rotation of the REE profile, the MREE enrichment, the development of a negative Eu*SN anomaly and more radiogenic 87Sr/86Sr suggests the dolomite in the Cu–Co mineralized samples precipitated from basinal brines which had undergone significant fluid–rock interaction. Petrographic, REE, and 87Sr/86Sr data for malachite are consistent with the original sulfide Lower Orebody being subject to a later oxidizing event.  相似文献   

17.
Taiyangshan is a poorly studied copper–molybdenum deposit located in the Triassic Western Qinling collisional belt of northwest China. The intrusions exposed in the vicinity of the Taiyangshan deposit record episodic magmatism over 20–30 million years. Pre-mineralization quartz diorite porphyries, which host some of the deposit, were emplaced at 226.6 ± 6.2 Ma. Syn-collisional monzonite and quartz monzonite porphyries, which also host mineralization, were emplaced at 218.0 ± 6.1 Ma and 215.0 ± 5.8 Ma, respectively. Mineralization occurred during the transition from a syn-collisional to a post-collisional setting at ca. 208 Ma. A barren post-mineralization granite porphyry marked the end of post-collisional magmatism at 200.7 ± 5.1 Ma. The ore-bearing monzonite and quartz monzonite porphyries have a εHf(t) range from − 2.0 to + 12.5, which is much more variable than that of the slightly older quartz diorite porphyries, with TDM2 of 1.15–1.23 Ga corresponding to the positive εHf(t) values and TDM1 of 0.62–0.90 Ga corresponding to the negative εHf(t) values. Molybdenite in the Taiyangshan deposit with 27.70 to 38.43 ppm Re suggests metal sourced from a mantle–crust mixture or from mafic and ultramafic rocks in the lower crust. The δ34S values obtained for pyrite, chalcopyrite, and molybdenite from the deposit range from + 1.3‰ to + 4.0‰, + 0.2‰ to + 1.1‰, and + 5.3‰ to + 5.9‰, respectively, suggesting a magmatic source for the sulfur. Calculated δ18Ofluid values for magmatic K-feldspar from porphyries (+ 13.3‰), hydrothermal K-feldspar from stockwork veins related to potassic alteration (+ 11.6‰), and hydrothermal sericite from quartz–pyrite veins (+ 8.6 to + 10.6‰) indicate the Taiyangshan deposit formed dominantly from magmatic water. Hydrogen isotope values for hydrothermal sericite ranging from − 85 to − 50‰ may indicate that magma degassing progressively depleted residual liquid in deuterium during the life of the magmatic–hydrothermal system. Alternatively, δD variability may have been caused by a minor amount of mixing with meteoric waters. We propose that the ore-related magma was derived from partial melting of the ancient Mesoproterozoic to Neoproterozoic middle to lower continental crust. This crust was likely metasomatized during earlier subduction, and the crustal magmas may have been contaminated with lithospheric mantle derived magma triggered by MASH (e.g., melting, assimilation, storage, and homogenization) processes during collisional orogeny. In addition, a significant proportion of the metals and sulfur supplied from mafic magma were simultaneously incorporated into the resultant hybrid magmas.  相似文献   

18.
Late Devonian (Famennian) marine successions globally are typified by organic-rich black shales deposited in anoxic and euxinic waters and the cessation of shelf carbonate sedimentation. This global ‘carbonate crisis’, known as the Hangenberg Event, coincides with a major extinction of reef-building metazoans and perturbations to the global carbon cycle, evidenced by positive carbon-isotope excursions of up to 4‰. It has been suggested that authigenic carbonate, formed as cements in sedimentary pore spaces during early burial diagenesis, is a significant mass fraction of the total global carbon burial flux, particularly during periods of low oxygen concentration. Because some authigenic carbonate could have originated from remineralization of organic carbon in sediments, it is possible for this reservoir to be isotopically depleted and thereby drive changes in the carbon isotopic composition of seawater. This study presents bulk isotopic and elemental analyses from fine-grained siliciclastics of the Late Devonian–Early Mississippian Bakken Formation (Williston Basin, USA) to assess the volume and isotopic composition of carbonates in these sediments. Carbonate in the Bakken black shales occurs primarily as microscopic disseminated dolomite rhombs and calcite cements that, together, comprise a significant mass-fraction (ca 9%). The elemental composition of the shales is indicative of a dynamic anoxic to sulphidic palaeoenvironment, likely supported by a fluctuating chemocline. Despite forming in an environment favourable to remineralization of organic matter and the precipitation of isotopically depleted authigenic carbonates, the majority of carbon isotope measurements of disseminated carbonate fall between −3‰ and +3‰, with systematically more depleted carbonates in the deeper-water portions of the basin. Thus, although there is evidence for a significant total mass-fraction of carbonate with contribution from remineralized organic matter, Bakken authigenic carbonates suggest that Famennian black shales are unlikely to be sufficiently 13C-depleted relative to water column dissolved inorganic carbon to serve as a major lever on seawater isotopic composition.  相似文献   

19.
The complex study of the river water and pore solutions from the bottom sediments in the lower reaches of the Razdol’naya River was conducted in February 2010. The major ion composition of the waters indicates the submarine origin of the near-bottom and pore waters in the lower reaches of the Razdol’naya River in the winter. The river estuary extends upstream for more than 20 km. It was established that the studied sediments are reduced oozes containing pyrite, hydrotroilite, and iron monosulfide, which is direct evidence for sulfate-reduction in the sediments. The diagenesis of organic matter is the main reason for the considerable decrease in the amount of sulfates and the increase in the alkalinity of the sediment pore water. The sedimentary pore water sampled from the deep river pits is characterized by excess alkalinity that cannot be explained by sulfate-reduction and methane genesis. It was suggested that the chemical weathering of silicate minerals and the bacterial mineralization of salts of organic acids could result in the excess alkalinity of the sediment pore water.  相似文献   

20.
It is shown that the formation of borosilicate skarn in the Taukha metallogenic zone completes a series of successive stages of the formation and transformation of the folded sequences of the Taukha accretionary wedge. The Early Cretaceous sedimentary stage, including accumulation of detrital tourmaline-rich sedimentary rocks, was implemented in the marginal sea of the Paleopacific Sino-Korean segment. In the Turonian–Campanian, the boron-bearing folded sequences of the accretionary wedge were involved in anatexis to generate siliceous S-type boron-bearing melts. The thus-formed magmatic chambers were emptied during catastrophic volcanic eruptions. At the final Middle Campanian volcanic stage, fluid-magmatic differentiation of the melt in the residual chambers generated fluid flow. The infiltration interaction of the fluids, which inherited enrichment in boron, with limestones of the olistostrome sequence resulted in the formation of a giant zone of grossular–wollastonite skarns and danburite lodes. The boron potential of the Taukha boron–lead–zinc metallogenic zone may be considered as a reproduction of the Precambrian boron metallogeny of the eastern Eurasian margin, which was implemented in the Late Mesozoic during recycling of the continental crust.  相似文献   

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