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1.
Previous work on the fauna and flora of the Cambay shale underlying as well as inter-bedded within the lignite seams of Vastan lignite mine, Gujarat allows the shale to be assigned a Lower Eocene age. However, there is no record of occurrence of any fossil from the sedimentary beds succeeding the shale-lignite sequence that might fix upper age limit of the Cambay shale. We record a characteristic Middle Eocene ostracod assemblage from the Nummulitic marl/limestone, immediately overlying the shale-lignite sequence from the Tadkeshwar lignite mine close to the Vastan lignite mine. The assemblage comprises 22 species, many of which widely occur in the Middle Eocene beds of Kachchh, Rajasthan and adjacent areas of Pakistan.  相似文献   

2.
The Neogene Beypazari basin is one of the important coal districts of Central Anatolia with approximately 600 million short tons lignite reserves. The coal-bearing Neogene sediments occurring in the Beypazari basin are divided into seven formations, in ascending order; Çoraklar, Hirka, Akpinar, Çayirhan, Bozbelen and Kirmir Formations with Sariyar Limestone and Teke volcanics.The Çoraklar Formation consists of cross-bedded sandstones, channel-fill conglomerates, mudstones, carbonaceous shales and volcanoclastic pebblestones, which are fluvial in origin. The lower lignite seam occurs in the lower part of the Çoraklar Formation.The upper lignite seam occurs in the uppermost part of the Çoraklar Formation and is overlain by the Hirka Formation with a sharp contact. The Hirka Formation consists mainly of alternating shale, mudstone, bituminous shale, claystone, tuffite and silicified limestone, and they all are apparently of lacustrine origin.The lignite deposite occur in the Çayirhan and Koyunaǧili parts of the Beypazari Neogene basin. The Çayirhan coal field consists of lower and upper lignite seams, but the Koyunaǧili field contains only an upper lignite seam.The lower lignite seam, which does not crop out at the surface, indicates a fluvial origin of the lignite deposits, based on the lateral discontinuity and the lower sulphur content of the lower lignite seam, and the sedimentologic and stratigraphic features of the associated sediments. But the uniform stratigraphic and sedimentologic features, high sulphur content and wide-spread distribution of the upper lignite seam indicate that the upper lignites were deposited probably in a mud-flat facies of playa-lake environment. The lower and upper lignites are completely different in relation to the depositional environment, the geometry and degree of rank in lateral directions.The lateral spreading and geometry of the lower lignite deposits were controlled by channel, floodplain and well-drained marshes of a fluvial system. On the basis of recent drillings and field investigations, the lower lignite deposit has been demonstrated to be a linear spreading parallel to the axis of the channel fills and throughcross beds in clastic sediments of fluvial facies. Therefore, the lower lignite deposits trend along a northeastern direction and is not expected to be as widely spread as the upper lignites.  相似文献   

3.
The Tertiary basins of Gujarat have always been a potential target for their hydrocarbon resources. The lignite resources of the region have also been an important field of research. The present paper presents the results of the petrological study carried out on the lignites of the Saurashtra basin. For this purpose samples were collected from lower and upper lignite seams from the Surkha lignite mine of Bhavnagar, Saurashtra. These samples were subjected to detailed petrographic analysis (both maceral and microlithotype). The study reveals that these lignites are dominantly composed of huminite group macerals while liptinite and inertinite group macerals occur in subordinate amounts. These lignites have attained a thermal maturity up to 0.28-0.30 percent vitrinite reflectance (VRr) which classifies them as ‘low rank C’ coals. Moreover, Bhavnagar lower lignite seam shows relatively less gelification as compared to the upper seam which suffered relatively more biochemical degradation. These lignites are characterized by high gelification index (GI) and low tissue preservation index (TPI).With the help of petrography based facies models an attempt has been made to reconstruct the environment of the paleomire of these lignites.  相似文献   

4.
河北省辖区内赋存、分布的褐煤资源形成于早白垩世和第三纪，但由于煤层顶底板岩石固结程度差，建井开采时井巷变形严重，维护困难，致使大量褐煤资源未得以开发利用。根据已有资料分析，褐煤含煤区地质构造条件简单、水文地质条件简单、主要呵采煤层顶板以泥岩或炭质泥岩为主，岩石致密，透气性差。褐煤本身透气性好，燃点低，没有粘结性，挥发分高．受热容易膨胀破裂，诸多因素都表明适合采用煤炭地下气化的开采方式进行开发利用，因此有必要加强我省褐煤资源的地质勘查工作和煤炭地下气化工艺的研究，为今后褐煤开发利用奠定基础。  相似文献   

5.
乌兰图嘎超大型锗矿床含锗煤的矿物学   总被引：2，自引：0，他引：2  
内蒙古乌兰图嘎锗矿是我国近年来发现的产在煤层中的超大型锗矿床,锗金属储量达1600 t。以乌兰图嘎超大型锗矿床的含锗煤为研究对象,利用X射线衍射(XRD)、带能谱的扫描电镜(SEM-EDX)和电子探针(EPMA)详细研究了乌兰图嘎含锗煤及其同时代的红旗煤矿无矿煤的矿物学特征。分析结果表明,乌兰图嘎含锗煤中的主要矿物包括石英、蒙脱石;次要矿物包括长石、高岭石、伊利石;另含少量三水铝石、角闪石、叶蜡石、石膏、绿泥石、锐钛矿、黄铁矿、方解石、白云石和草酸钙石;微量的锆石、闪锌矿、白钨矿、重晶石、黄铜矿、卤化物、磷酸盐以及含Pb、Bi、Cr、As和Sb矿物。未发现含锗矿物。推测含锗煤中的锗可能主要呈有机结合,而Ba、Zn、Ti、W、Pb、Bi、Cr、Fe、As、Zr、Sb、Cu和REE可能主要与矿物相结合。此外,首次在乌兰图嘎含锗煤及红旗煤矿无矿煤中发现含银颗粒或自然银,推测胜利煤田的褐煤可能有相当规模的Ag矿化。  相似文献   

6.
Tadkeshwar lignite deposits are one of the important Lower Tertiary lignite deposits of Cambay Basin, Gujarat. These lignites are rich in huminite macerals followed by liptinite and inertinite with moderate to high proportions of associated mineral matter. Under fluorescence mode these are found to be rich in liptinite macerals, in particular the liptodetrinite and resinite. The type of huminite suggests that the lignite is formed from mixed vegetal source, i.e. woody forest vegetation and herbs, shrubs. The composition of macerals indicates the deposition of lignite in sub-aqueous condition in wet-reducing environment with intermittent exposure and subsidence of the peat surface. The rank of the Main and the Leader seams, determined through reflectance measurement, indicate that the lignite is less mature. The considerable amount of perhydrous huminite may have contributed to the lower reflectance values in some of the samples. Low rank and appreciable amount of mineral matter make the lignite suitable for its utilization in thermal power plants, however when upgraded or mixed with better quality coals it can be used for other industries.  相似文献   

7.
The Kalol oilfield in the Cambay graben, Gujarat. western India, is known to contain thick seams of lignite in the Kalol Formation (Middle Eocene), overlying the oil-bearing Cambay Black Shale (Lower Eocene), at depths between 1110 m and 1500 m. The Kalol Formation occurs in the northern portion of the Cambay Basin as a wedge-shaped sequence of regressive and transgressive marine environments, the lignite being confined to the former phase.Chemically, the Kalol lignite is characteristically low in moisture (4.45–4.64%), quite low in ash (1.67-10.82%) and high in volatiles (43.56–55.25%). C is 72.39–77.18%, H is 4.47–5.93%, N is 1.16–1.58%, O is 15.73–18.62%, and S is 0.32–0.86%. According to Seyler's classification, the Kalol lignite can be classified as belonging to rank (a) lower than lignitous, (b) perlignitous, (c) ortholignitous, (d) metalignitous, and (e) bituminous. According to North American (ASTM) classification, utilising data on volatiles and Rm oil, the lignite belongs to lignite, sub-bituminous C and low volatile bituminous rank.Petrographically, the Kalol lignite is composed of huminite (50–81%), liptinite (1–16%), and inertinite (6–32%). Inertinite comprises mainly sclerotinite as plectenchyma, fusinite being absent. Exsudatinite is quite common. On the basis of microlithotype, the lignite comprises textile (1–13%), detrite (19–69%), liptitextite (1–10%), liptidetrite (4–16%), inertidetrite (1–25%), detrinertite (3–21%), and inertite (5–26%), with shale (5–12%). Rm oil varies from 0.30 to 0.40. The bituminous coal sample is high in shaly matter (53%) and composed of vitrinite (16%) and sclerotinite (29%), the former showing Rm 1.80.These studies indicate that the chemical and petrographic constitution of the lignite is favourable for underground gasification.  相似文献   

8.
The Barmer Basin of Rajasthan is significant for its Paleogene lignite sequences. The lignite seam occurs in Akli Formation of Barmer Basin at the depth of 06–241 m. A total of 57 lignite samples were collected from the working faces of lignite mine and were subjected to proximate analysis (moisture, ash yield, volatile matter, and fixed carbon), ultimate analysis (carbon, hydrogen, nitrogen, oxygen and sulfur), elemental analysis (Fe, Ca, Mg, Cd, Mn, K, Na, Cu, Co, Ni, Cr, Zn, and Pb) and rock-eval pyrolysis for mineral carbon (MINC). Some elements like Cu, Cd, Co, Ni, Zn, Pb, Na, and K occur in high concentration, while Mg and Ca have their concentrations lower than World Clarke average. In addition, various minerals and functional groups present in the lignite samples were analyzed through X-ray diffraction and Fourier transform infrared (FTIR) spectroscopy. The mineral (weight and atomic) percentage has also been analyzed through scanning electron microscopy–energy dispersive spectroscopy (SEM–EDS).  相似文献   

9.
褐煤煤层气储集特征及气含量确定方法   总被引：5，自引：3，他引：2  
褐煤基质中的孔隙以中孔、大孔为主。实验表明,褐煤对甲烷的吸附能力很低;褐煤基质中的游离气含量通常占总气含量的50%以上。因此,传统的煤层气含量确定方法不适用于褐煤。本文建立了褐煤煤层气含量的确定方法,将吸附气含量与相应储层压力及温度条件下的游离气含量相加,即得到褐煤总的气含量等温线。利用这条等温线,即可获得该温度下不同储层压力时的气含量值。   相似文献   

10.
The Ilgin lignite field can be subdivided into the Haramiköy and Kurugöl areas which are separated by an area of basement and a fault. The lignite-bearing sequence consists mainly of fluvial and lacustrine Neogene deposits. The Ilgin lignite, averaging 8 m (up to 25 m) thick, is blackish brown and dark brown in colour. The lignite contains abundant brown wood, plant remains and white gastropod shells. Samples have an average of 38.9% moisture on an as-received basis and a mean of 3.9% total sulphur on an air-dried basis. Geochemical analysis, using an ICP-MS, was undertaken. Thirteen lignite core samples from three boreholes drilled in the Kurugöl area were ashed at 750°C. The average trace element contents of the lignite show a higher concentration of U (average 43 ppm) when compared to the range for most coals in the world, while the others (Ti, P, Sc, Be, Mn, Co, Cu, Zn, Ga, As, Rb, Sr, Zr, Nb, Mo, Cs, Ba, Y, Ta, W, Tl, Pb, Bi, Th, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, Lu) agree with the global ranges. The Ilgin lignite is identified as of Middle Miocene (Middle Serravallian) age and occurs within lacustrine sediments deposited under subtropical climatic conditions.  相似文献   

11.
Summary The paper describes an investigation of the geotechnical properties of the Ptolemais lignite (brown coal) and shows that the soil mechanics principles used in the study of natural and cemented soils are applicable. The material has a high and variable void ratio incompatible with its preconsolidation pressure, which may be attributed to the existence of structure (chemical bonding). Bond strength and degradation have been studied and are found to be isotropic, while the stress-strain response in the prevield domain is intensely cross-anisotropic. The shear strength determined from triaxial CU and CD tests is variable but strongly dependent on the in situ moisture content. Tests on high quality intact specimens having a wide range of moisture contents (100–150%) verify a hypothesis that the magnitude of bond strength (expressed by the peak shear strength) is inversely proportional to the moisture content. A Hvorslev-type normalization process shows that the peak shear strength of the material can be estimated from the in situ moisture content with reasonable accuracy, thus facilitating preliminary stability calculations of production cuts in lignite mines. The properties of the Ptolemais lignite are compared with the properties of a lignite from another location in Greece (Megalopolis) and an Australian lignite (Morwell). It is shown that the shear strength characteristics of the lignite types studied are similar and strongly dependent on the in situ moisture content, which seems to be a measure of the magnitude of inter-particle bonding.  相似文献   

12.
The Cenozoic Krabi Basin in the southern part of peninsular Thailand contains about 112 million tons proven coal reserves. At present, coal is only produced from the Bang Mark mine located in the southern part of the basin, where the main lignite bed is 7-20 m thick. The lignite bed occurs in an overall paralic succession. The present paper investigates the depositional conditions of an approximately 8 m thick lignite bed (main seam) in the Bang Mark mine using organic petrography, including maceral ratios, and geochemistry. The results are further interpreted in a sequence stratigraphic context. The lignite is of low rank and is completely dominated by huminite indicating generally oxygen-deficient conditions in the precursor mire. Very low inertinite contents suggest rare occurrences of wildfires. The lower part of the lignite bed represents a topogenous fresh water peat mire with open water areas that in few cases may have experienced influx of saline water. The peat mire was subjected to periodic inundations and deposition of siliciclastics. Tissue preservation was relatively poor. The upper part of the lignite bed represents a slightly domed fresh water ombrogenous peat mire with a stable watertable and a balance between peat accumulation and accommodation space creation that favoured preservation of plant tissues. In general, the mire vegetation changed from less woody in the topogenous mire to more arborescent in the ombrogenous mire, where plants with suberinised wood cell walls also were more frequent. Decompacted, the lignite bed corresponds to a minimum ~ 11 m thick peat deposit that records from ~ 22,000 to 55,000 years of peat accumulation. Watertable rise in the peat mire was controlled overall by relative sea-level rise. In a sequence stratigraphic context, the lignite bed overlies a terrestrialisation surface (TeS; sensu Diessel, 2007) and the lowermost part records peat formation during a falling watertable and a decreasing accommodation/peat accumulation ratio (terrestrialisation). An accommodation reversal surface (ARS; sensu Diessel, 2007) indicates a change to paludification style of peat formation characterised by rising watertable and a high accommodation/peat accumulation ratio. Another ARS marks a gradual change to a situation with a balanced accommodation/peat accumulation ratio. The overall watertable rise throughout peat formation, but at a gradually slower rate from base to top, suggests that the lignite bed could be located in the late transgressive systems tract (TST).  相似文献   

13.
In the present investigation all the working lignite seams of Cambay basin of Gujarat have been studied to see the distribution and geochemistry of selected major/minor elements like Fe, Ca, Na, K, Mg, and Mn and trace elements like Cu, Co, Cr, Cd, Ni, Pb and Zn. The vertical variation of these elements along the seam profiles has been studied to see the pattern of distribution of these elements and also to know the horizons of their enrichment and the probable cause. Further, these elements have been correlated among themselves and also with organic and inorganic matter of lignite. The correlation study indicates that in Tadkeshwar upper seam Fe has its affinity with huminite while Mg and Na have their affinity with liptinite and in Tadkeshwar lower seam Na has an affinity with liptinite. In Vastan upper seam Mn and Cu are associated with inertinite and Na with huminite while in Vastan lower seam Cu relates to huminite and Cd to liptinite and huminite. In Rajpardi seam Ca and Co are associated with huminite. The study provides information on the mode of occurrence of elements of less studied lignites of western India.  相似文献   

14.
Summary Removal of inherent moisture from run-of-mine lignite was tested by lock-feeding the lignite, which was previously sized by screening into 25 kg autoclaves. High pressure, up to 4.053 MPa (588 psi), saturated steam was then introduced into the pressure reactor. Reaction time, pressure, temperature and depressurization rates were strictly controlled for each reactor test run. Results indicate that about 80% of lignite total moisture was removed, including some of the inherent moisture, yielding a nonoxidized, and thus stable, lignite product. Some reduction of noncombustible portions of the lignite also took place. The conclusion reached as a result of the tests is that the steam-drying process can be successfully applied to reducing moisture in lignite, and may be considered for additional studies on acceleration of the coalification process.  相似文献   

15.
The petrological studies on Khadsaliya lignites from Bhavnagar district have been carried out for their microconstituent’s characterization. Quantitative estimation of macerals reveal, due to high amount of macerals of huminite group, that this lignite deposits has formed from forest dominated vegetation in a fast subsiding basin, experiencing almost uniform environmental conditions, with slight intermittent fluctuations. The rank based on Ro max % values indicates that lignites are less mature and have not reached the sub-bituminous stage of coalification as those of the lignites from Panandhro (Gujarat) and Neyveli (Tamil Nadu) fields. High pyrite content in the Khadsaliya lignite makes it not much suitable for combustion purpose.  相似文献   

16.
In the present study an attempt has been made to characterize the Gurha lignites employing petrographic and geochemical techniques on a large number of lignite samples. The data generated has been discussed to understand the hydrocarbon generation potential as well as the evolution of the paleomires of these lignites. The present investigation indicates that these lignites are mainly dominated by the huminite followed by inertinite and liptinites occurs in meager concentration. The huminite reflectance values rank the Gurha lignite as a low-rank B lignite.Petrographic result indicates these lignites are thermally immature in nature and comprised of Type-III kerogen and may generate only gas on maturation which is further supported by the rock-eval pyrolysis. The plots of rock eval data also indicates the same. The GI and TPI as well as GWI and VI values and the petrography-based facies critical models indicate that these lignites originated mostly under wet forest swamp condition. The microscopic constituents have also shown that these lignites are from herbaceous plants in wet forest swamp environment and ombrotrophic hydrological condition. The presences of framboidal pyrite in the study area infer the marine influence which also supported by the presence of high sulphur content.  相似文献   

17.
Two samples of Pliocene lignites from the Ptolemais basin of Greece, one from the upper and one from the lower lignite seams, were heated and dried in air at 50°C intervals from 50 to 1200°C. The two lignite samples initially contained the same minerals, namely calcite, dolomite, quartz, kaolinite, illite, pyrite and gypsum, but in different proportions. The lignite sample from the upper lignite seam is rich in Fe2O3, CaO and SO3, while that from the lower lignite seam is rich in SiO2 and Al2O3.Hematite, periclase, melilites, calcium ferrite and brownmillerite are constituents of the 1200°C lignite ash from both samples. The heating conditions and the chemistry of the samples lowered the formation temperatures of brownmillerite, which appeared in both samples at 950°C. In the Fe2O3, CaO- and SO3-rich sample, magnesioferrite is present from 850 to 1100°C and hematite appears at 300°C. In the SiO2- and Al2O3-rich sample, magnesioferrite was not detected at any temperature and hematite appeared at 600°C.Anhydrite, which normally decomposes in air at 1638°C, is the main constituent at 1150°C, on heating the lignite sample that was rich in Fe2O3, CaO and SO3. Anhydrite diminishes at 1200°C. In the SiO2- and Al2O3-rich lignite sample, anhydrite is main constituent at 1100°C, but diminishes considerably at 1150°C and decomposes at 1200°C.  相似文献   

18.
煤层气原地资源量和技术可采资源量的计算结果,可为国家制定煤层气开发战略提供决策依据,也可为煤层气开发的相关部门或单位提供参考依据,对推动我国煤层气产业发展具有重要意义。通过对我国褐煤分布区的煤层气资源量的计算,弥补了我国长期缺少褐煤煤层气资源量的缺陷,使我国煤层气资源量数据更加完整,我国陆上煤层埋深2 000 m以浅的煤层气原地资源量为32.86×1012m3,其中,褐煤主要分布区为1.40×1012m3,非褐煤地区为31.46×1012m3。利用已建立的煤层气技术可采资源量评价方法体系,并基于目前的开发技术,对我国煤层气技术可采资源量进行计算,结果为13.90×1012m3,占原地资源量的42%。   相似文献   

19.
The Cr and Ni contents are high in the Eocene lignite of the Shenbei coalfield, which is a small intracontinental basin located in Liaoning Province, China. In this paper, we studied the distribution, origin and occurrence of Cr, Ni and other hazardous trace elements in the Shenbei lignite on the basis of coal petrology, and geochemistry of the lignite and combustion products. The following conclusions on the Shenbei lignite can be drawn: (1) The dominant maceral group in the Shenbei coal is huminite (humodetrinite), accounting for 96%–99% of the total maceral. Inertinite content is less than 1%. Liptinite content (sporinite and cutinite) is 0.2–1.6%. Common minerals in the Shenbei lignite include clay minerals (kaolinite), pyrite and quartz, and calcite and siderite. Chromite is not present in the lignite. (2) Potentially hazardous trace elements such as Co (22 μg/g), Cr (79 μg/g), Cu (63 μg/g), Zn (93 μg/g), V (88 μg/g) and Ni (75 μg/g) are strongly enriched in the Shenbei lignite compared with average concentration of trace elements in the Chinese coal and worldwide lignite. These elements are mainly associated with fulvic acid (FA) and/or coal organic macromolecular compounds in most of the studied lignite samples, indicating an organic association and enrichment of these elements in the Shenbei lignite. (3) Unusually high trace elements contents in the Shenbei lignite are derived mainly from the olivine basalt (country rock of coal basin) that consists of 52.7% plagioclase, 17.8% pyroxene, 14% olivine and 15.5% Ti–Fe oxide minerals. These olivine basalts have higher Cr, Ni, Pb and Zn contents than other types of rock and worldwide basalts do. (4) Fly ash of the Shenbei lignite, with 90% 1–50 μm amorphous particles and 8% 1–10 μm cenosphere, has high contents of Zn (23,707 μg/g), Be (12 μg/g), Sr (1574 μg/g), Pb (486 μg/g) and Cr (349 μg/g). In particular, the ferruginous micro-cenoshperes contain 1–12.79% Zn. Fine bottom ash (<0.031mm) of the Shenbei lignite has higher contents for most of the elements with the exception of Mo, Sn and Zn. Therefore, the potentially environmental and health impact of the fly ash and fine bottom ash should constitute a major concern.  相似文献   

20.
A coal mine panel claimed to infringe on a permit boundary, or to create an hazard after subsidence has been the subject of lawsuits. We study at the Soma–Darkale coalfield (Manisa, Turkey), the footprint of a lignite coal mine panel at a depth of about 150–200 m by mapping all of the surface fractures we could observe, and by developing a post-subsidence density model that we verified through gravity measurements with positive Bouguer anomaly. With the analysis of the fracture map and the gravity data, we were able to identify the footprint of a mine panel from the effect of the anomalous mass due to denser overburden material filling up the space after the extraction of less-dense lignite. Whereas, using empirical methods like the so-called “limit line approach” to evaluate the extent of the area where mining can have subsidence-induced surface fracturing, one could not recognize for certain infringement of permit boundaries. The orientations of the fractures we mapped at the ground surface, the Bouguer gravity map, and a test borehole indicated the presence and dimensions of a coal panel in dispute. The presented approach based on gravity method and fracture observations may be an example to help settle conflicts related to the position of the longwall mine panel.  相似文献   

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