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硅灰石表面改性实验研究 总被引:18,自引:0,他引:18
实验以湖北大冶硅灰石为原料,初步探讨了硅灰石表达改性的工艺条件。经沉降体积法、表面接触角、红外光谱等方法检测和填充橡胶试验证实,硅灰石得到了改性且其填充性能有明显的提高。 相似文献
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选用气流磨超音速气流作为机械力,对硅灰石、硬脂酸进行超细粉碎-表面改性。应用透射电子显微镜分析、观察硅石灰/硬脂酸复合粉体界面微观形貌及成分(Ca、Si、C)的变化规律。TEM能谱分析结果表明:从硅灰石到硬脂酸,Ca、Si含量逐渐降低,C含量则逐渐升高。 相似文献
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硅灰石的表面改性与特性研究 总被引:2,自引:0,他引:2
利用湖北某矿生产的硅灰石粉,探讨了以兼价的表面活性剂AS对硅灰石进行表面改性的条件流程,改性后的硅灰石转变为生硅灰石,并对其特性进行了研究,已用于管带橡胶,PVC电缆填料和涂料颜料的试验。 相似文献
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膨润土提纯后的尾矿主要含石英、斜绿泥石和白云母等矿物,以尾矿为主原料制备了复合陶瓷颗粒,采用XRD,IR和SEM探讨了烧结工艺对结构变化的影响,研究了复合陶瓷颗粒的组分变化、烧结温度、pH、初始浓度、吸附时间和温度对Cr(Ⅵ)离子吸附效果的影响,探讨了动力学和热力学变化。结果表明,烧结温度对吸附影响不大,烧结适宜温度为1000℃,陶瓷颗粒的主晶相为石英和硅灰石,表面为不均匀多孔结构。吸附的最佳吸附条件是pH值1、陶瓷颗粒用量1 g、吸附时间12 h及铬离子初始浓度100 mg/L,吸附率达96.33%。吸附行为符合准二级动力学方程,属于单分子层化学吸附;热力学数据说明,吸附反应为自发吸热反应。 相似文献
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针对自然降尘、工业区降尘及人工粉尘进行的物相、成分、表面形貌、元素含量和粒度分析表明降尘均以石英和方解石为主要物相成分,SiO2、CaO含量较高,K2O、Na2O含量低。自然降尘为无规则颗粒,大颗粒表面上带有微小颗粒团聚;工业区降尘形貌呈球形、团状;人工粉尘呈柱状或纤维状。降尘粒度在0.3~5μm内集中分布,小于5μm的粉尘比例均超过99%。在模拟人体温度37℃条件下,进行了32 h内粉尘在谷氨酸水溶液中的溶出行为和电化学作用的对比研究。各粉尘样品的pH值和电导率变化趋势相似,8 h前各粉尘样品的pH值电导率随时间增加缓慢上升,8 h到32 h间pH值上升速度明显加快。元素K、Ca、Na、Mg的溶出离子总量为35.4~429 mg/L,其中Ca元素的溶出量最大为20~334 mg/L,重金属离子Fe、Zn、Mn、Pb、Ba的离子溶出总量为0.18~5.59 mg/L,Al、Si离子溶出总量为3.0~21.7 mg/L。粉尘中各元素主要在前16 h溶出较快。各粉尘在酸性谷氨酸水溶液中的溶解程度由大到小为:硅灰石蛇纹石海泡石;水泥厂降尘自然降尘电厂降尘。CaO含量高的水泥厂降尘和硅灰石人工粉尘溶解程度最大,表明其在酸性谷氨酸环境中耐腐蚀性较差,表现出较低的生物持久性。SiO2含量高的电厂降尘和海泡石人工粉尘溶解程度最小,具有较强耐蚀能力和较高生物持久性。 相似文献
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硅灰石质白色颜料的研制 总被引:4,自引:0,他引:4
针对硅灰石作为白色颜料的主要不利因素,对其进行超细粉碎和表面化学改性处理,改进硅灰石粉体粒度、粉体表面组成和表面结构,提高粉体的白度和折射率,进而提高遮盖力。改性后的硅灰石超细粉体具有良好的高级白色颜料性能。 相似文献
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为了使酸性含镍氯化铁蚀刻废液资源化制备的铁黄达到颜料性能指标,通过考察改性剂的种类、改性剂用量、改性p H、改性温度和改性时间对铁黄粉体亲油化度的影响,并通过红外光谱、热分析解析了改性剂在粉体表面作用机理。研究结果表明:在最佳工艺条件下,当改性剂为十二烷基苯磺酸钠、改性剂用量为7%、p H为3.5、温度为30℃和改性时间为30 min时,其亲油化度高达54.7%。红外光谱和热分析显示,十二烷基苯磺酸钠以化学键合的方式结合在纳米铁黄的表面,其包覆量大约为5.4%,使纳米铁黄粉体具有亲油疏水性能。 相似文献
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Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引:4,自引:0,他引:4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
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Emmanuel Skourtsos Daniel Vachard Alexandra Zambetakis-Lekkas Rossana Martini Louisette Zaninetti 《Comptes Rendus Geoscience》2002,334(12):925-931
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931. 相似文献
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正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.) 相似文献
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正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.) 相似文献
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正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.) 相似文献
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正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus., 相似文献
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正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an 相似文献
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正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of 相似文献