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1.
In 1995–1998, Han 11 km terrestrial surge of Kuannersuit Glacier, an outlet glacier of the largest ice cap on Disko Island, West Greenland, affected the catchment dramatically. In order to estimate solute fluxes and provenances, bulk meltwaters were sampled at the main subglacial outlet during the initial part of the quiescent phase. The hydrochemistry is significantly influenced by a subglacial basaltic weathering regime with absence of carbonate minerals. The results show that marine and aerosol derived solutes have minimal contribution to the total ion content, whereas sequestration of atmospheric CO2 associated with carbonation of Ca-rich feldspar and reactive volcanic glass is more dominant than previously reported from glacierized catchments. Application of a sampling strategy dividing water samples into four groups to determine the content of dissolved HCO3− and CO32− shows that the cationic equivalent weathering rate range is 683–860 Σmeq+ m−2 a−1 and solute flux ranges between 76 and 98 t km−2 a−1. The crustal denudation rate is estimated to 26 t km−2 a−1, and the transient CO2 drawdown amounts to 8500–13700 kg C km−2 a−1.  相似文献   

2.
238U, 232Th, 230Th and 226Ra abundances have been measured in six samples of recent Hawaiian basalt by high precision mass spectrometry, in an attempt to compare the melting process in plumes and at spreading ridges. The data reveal a very small range in (230Th/238U) activity ratio up to a maximum value of 1.02 ± 0.01, and (226Ra/230Th) activity ratios which lie between 1.10 ± 0.015 and 1.19 ± 0.02. UTh and RaTh abundances are linearly correlated demonstrating that the disequilibria predate crystallisation and differentiation. Using recently published estimates for the bulk partition coefficients of U and Th, the results are consistent with melting rates > 10−3 kg m−3 a−1 at porosities < 10−3 for dynamic fractional melting in the garnet stability field.  相似文献   

3.
In this study, we explored the spatial and temporal relations between boulders and their original in-situ locations on sandstone bedrock cliffs. This was accomplished by combining field observations with dating methods using cosmogenic isotopes (10Be and 14C) and optically stimulated luminescence (OSL). Our conclusions bear both on the landscape evolution and cliff retreat process in the hyperarid region of Timna and on the methodology of estimating exposure ages using cosmogenic isotopes.

We recognize three discrete rock fall events, at 31 ka, 15 ka, and 4 ka. In this hyperarid region, the most plausible triggering mechanism for rock fall events is strong ground acceleration caused by earthquakes generated by the nearby Dead Sea fault (DSF). Our record, however, under represents the regional earthquake record implying that ongoing development of detachment cracks prior to the triggering event might be slower than the earthquake cycle.

Cliff retreat rates calculated using the timing of rock fall events and estimated thickness of rock removed in each event range between 0.14 m ky− 1 and 2 m ky− 1. When only full cycles are considered, we derive a more realistic range of 0.4 m ky− 1 to 0.7 m ky− 1. These rates are an order of magnitude faster than the calculated rate of surface lowering in the area. We conclude that sandstone cliffs at Timna retreat through episodic rock fall events that preserve the sharp, imposing, landscape characteristic to this region and that ongoing weathering of the cliff faces is minor.

A 10%–20% difference in the 10Be concentrations in samples from matching boulder and cliff faces that have identical exposure histories and are located only a few meters apart indicates that cosmogenic nuclide production rates are sensitive to shielding and vary spatially over short distances. However, uncertainties associated with age calculations yielded boulder and matching cliff face ages that are similar within 1 σ . The use of external constraints in the form of field relations and OSL dating helped to establish each pair's age. The agreement between calculated 14C and 10Be ages indicates that the accumulation of 10Be at depth by the capture of slow deep-penetrating muons was properly accounted for in the study.  相似文献   


4.
Chemical and isotopic ratio (He, C, H and O) analysis of hydrothermal manifestations on Pantelleria island, the southernmost active volcano in Italy, provides us with the first data upon mantle degassing through the Sicily Channel rift zone, south of the African–European collision plate boundary. We find that Pantelleria fluids contain a CO2–He-rich gas component of mantle magmatic derivation which, at shallow depth, variably interacts with a main thermal (100°C) aquifer of mixed marine–meteoric water. The measured 3He/4He ratios and δ13C of both the free gases (4.5–7.3 Ra and −5.8 to −4.2‰, respectively) and dissolved helium and carbon in waters (1.0–6.3 Ra and −7.1 to −0.9‰), together with their covariation with the He/CO2 ratio, constrain a 3He/4He ratio of 7.3±0.1 Ra and a δ13C of ca. −4‰ for the magmatic end-member. These latter are best preserved in fluids emanating inside the active caldera of Pantelleria, in agreement with a higher heat flow across this structure and other indications of an underlying crustal magma reservoir. Outside the caldera, the magmatic component is more affected by air dilution and, at a few sites, by mixing with either organic carbon and/or radiogenic 4He leached from the U–Th-rich trachytic host rocks of the aquifer. Pantelleria magmatic end-member is richer in 3He and has a lower (closer to MORB) δ13C than all fluids yet analyzed in volcanic regions of Italy and southern Europe, including Mt. Etna in Sicily (6.9±0.2 Ra, δ13C=−3±1‰). This observation is consistent with a south to north increasing imprint of subducted crustal material in the products of Italian volcanoes, whose He and C (but also O and Sr) isotopic ratios gradually evolve towards crustal values northward of the African–Eurasian plate collision boundary. Our results for Pantelleria extend this regional isotopic pattern further south and suggest the presence of a slightly most pristine or ‘less contaminated’, 3He-richer mantle source beneath the Sicily Channel rift zone. The lower than MORB 3He/4He ratio but higher than MORB CO2/3He ratio of Pantelleria volatile end-member are compatible with petro-geochemical evidence that this mantle source includes an upwelling HIMU–EM1-type asthenospheric plume component whose origin, according to recent seismic data, may be in the lower mantle.  相似文献   

5.
Groundwater recharge and palaeoclimate in the Sirte and Kufra basins, Libya   总被引：1，自引：0，他引：1  
Stable and radio-isotope results (C, H, O) for groundwaters from the Sirte and northern Kufra basins are used to determine the recharge history during the Holocene and late Pleistocene. Radiocarbon ages have been corrected on the basis of their stable carbon isotope ratios and on environmental samples from the areas, and two groups may be recognised: (1) low 14C activity groundwaters (13000–34000 yr. BP) with δ 13C-5.6 to −11.7‰; and (2) higher 14C activity groundwaters (5000–7800 yr. BP) enriched in 13C up to δ 13C = −3.2‰. There is a general correlation of age with depth.

A well defined freshwater (< 50 mg/l Cl−) channel can be traced within the aquifer for some 130 km through the region, which is considered to represent recharge from a former wadi. This water with an age of ± 7800 yr. BP is chemically and isotopically distinct from the regional groundwaters and provides direct evidence of a significant recharge event during the Holocene.

The stable isotope (O and H) composition of groundwater from the Kufra and Sirte basins are all related by an evaporative line with slope δ D = 4.5δ 13O − 35 with an intercept on the meteoric line of -11‰. This suggests a recharge source continuing into the Holocene from air masses, analogous to current heavy monsoon rain derived from south of the Sahara. The spatial and temporal distribution of groundwaters in relation to the evaporative line suggests a progressive change in character of the recharge which is controlled by a shift towards strongly convective rainfall during the Holocene.

The direct hydrogeological and geochemical evidence supports climatic models proposed by several workers in which discrete humid episodes during the Holocene are inferred.  相似文献   


6.
This study proposes an efficient new cleaning procedure for measuring in situ cosmogenic 10Be in olivines and pyroxenes. This chemical routine is specially designed to decontaminate the abundant meteoric 10Be from these minerals. The method was tested on mafic minerals from basaltic flows of Mt. Etna volcano and from Hawaiian flows and moraines. A sequential dissolution test shows that 10Be concentrations decrease with the number of cleaning steps until reaching a constant value. This is a necessary condition to demonstrate the efficiency of the method in properly decontaminating samples of meteoric 10Be. Moreover, cross-calibration with cosmogenic 3He measured within the same samples yielded a sea level high-latitude production rate of 4.5±0.4 at g−1 a−1 for cosmogenic 10Be in mafic minerals. This rate is within 1σ uncertainty of empirically or model-derived rates for 10Be on the same targets. Such concordance supports the consistency of the new method.  相似文献   

7.
Xiao-Yan Li   《Journal of Hydrology》2002,260(1-4):151-160
Information regarding dew deposition on the stone-covered surface is scarce. The effects of gravel and sand mulches on dew condensation were studied during the late summer and fall of 1999 in the semiarid loess region of China. The results indicated that there were significant difference in daily dew amount between gravel mulch, sand mulch and dry loess soil (control). The average dew amount for gravel mulch was 0.071 mm d−1 with extreme 0.022 and 0.20 mm d−1. The average values for sand mulch and dry loess soil was 0.12 and 0.15 mm d−1, respectively. The minimum dew amount was 0.048 mm d−1 for sand mulch and 0.071 mm d−1 for dry loess soil, and the maximum dew amount was approximate 0.25 mm d−1 for both treatments. The results suggest that surface stone mulch can reduce dew deposition as compared to sand and dry loess soil.  相似文献   

8.
This study aimed to determine whether the δ13C levels in the foliage and twigs of four Eucalyptus grandis clones were related to their water use efficiency (WUE). This relationship has previously been demonstrated in a number of herbaceous species but not in mature trees. The study involved accurate measurements of tree trunk growth and water use over a period of 4 months, with subsequent isotopic analysis of mature foliage from the north and south side of the canopy, and young leaves from the top of the canopy.

The water use efficiencies were found to vary from 5.97 × 10−3 to 12.3 × 10−3 m3 m−3. Significant differences were observed between clonal-mean water use efficiencies averaged over six sampling periods. The average δ13C of the mature and young foliage was found to be significantly correlated with WUE. However, the correlation was weak, suggesting that the relationship between δ13C and WUE is more complex in trees than suggested in the literature on crop plants. It is suggested that differences between sample trees in carbon allocation and leaf-to-air vapour pressure deficits may account for the poor correlation between δ13C and WUE in the four E. grandis clones studied.  相似文献   


9.
In an attempt to constrain the origin of polycrystalline diamond, combined analyses of rare gases and carbon and nitrogen isotopes were performed on six such diamonds from Orapa (Botswana). Helium shows radiogenic isotopic ratios of R/Ra = 0.14–1.29, while the neon ratios (21Ne/22Ne of up to 0.0534) reflect a component from mantle, nucleogenic and atmospheric sources. 40Ar/36Ar ratios of between 477 and 6056 are consistent with this interpretation. The (129Xe/130Xe) isotopic ratios range between 6.54 and 6.91 and the lower values indicate an atmospheric component. The He, Ne, Ar and Xe isotopic compositions and the Xe isotopic pattern are clear evidence for a mantle component rather than a crustal one in the source of the polycrystalline diamonds from Orapa. The δ13C and δ15N isotopic values of − 1.04 to − 9.79‰ and + 4.5 to + 15.5‰ respectively, lie within the range of values obtained from the monocrystalline diamonds at that mine. Additionally, this work reveals that polycrystalline diamonds may not be the most appropriate samples to study if the aim is to consider the compositional evolution of rare gases through time. Our data shows that after crystallization, the polycrystalline diamonds undergo both gas loss (that is more significant for the lighter rare gases such as He and Ne) and secondary processes (such as radiogenic, nucleogenic and fissiogenic, as well as atmospheric contamination). Finally, if polycrystalline diamonds sampled an old mantle (1–3.2 Ga), the determined Xe isotopic signatures, which are similar to present MORB mantle – no fissiogenic Xe from fission of 238U being detectable – imply either that Xe isotopic ratios have not evolved within the convective mantle since diamond crystallization, or that these diamonds are actually much younger.  相似文献   

10.
A nomogram is developed to show that pH, redox potentials (EhNHE) and measures of dissolved sulfides (H2S + HS− + S2−)(total free S2−) can be used to classify organic enrichment impacts in marine sediments. The biogeochemical cycle of sulfur in marine sediments is described to show that changes in macrobenthic infauna community structure associated with high levels of organic matter supply result from stress due to oxygen deficiency (hypoxia and anoxia) and toxic effects of S2−. The changes reflect enhancement of microbial sulfate reduction under conditions of high organic matter sedimentation and the progressive formation of hypoxic–anoxic conditions measured by decreased EhNHE and increased concentrations of S2−. The nomogram provides a basis for classification of the oxic status of marine sediments based on changes in inter-related biological and biogeochemical variables along an organic enrichment gradient.  相似文献   

11.
Four distinct approaches, that vary markedly in the spatial and temporal resolution of their measurement and process-level outputs, are used to investigate the daily and seasonal water vapour exchange in a 70-year-old Belgian Scots pine forest. Transpiration, canopy interception, soil evaporation and evapotranspiration are simulated, using a stand-level process model (SECRETS) and a soil water balance model (WAVE). Simulated transpiration was compared with up-scaled sap flow measurements and simulated evapotranspiration to eddy covariance measurements.

Reasonable agreement in the temporal trends and in the annual water balance between the two models was observed, however daily and weekly predictions often diverged. Most notably, WAVE estimated very low, to no transpiration during late autumn, winter and early spring when incident radiation fell below 50 W m−2 while SECRETS simulated low (0.1–0.4 mm day−1) fluxes during the same period. Both models exhibited similar daily trends in simulated transpiration when compared with sap flow estimates, although simulations from SECRETS were more closely aligned. In contrast, WAVE over-estimated transpiration during periods of no rainfall and under-estimated transpiration during rainfall. Yearly, total evapotranspiration simulated by the models were similar, i.e. 658 mm (1997) and 632 mm (1998) for WAVE and 567 mm (1997) and 619 mm (1998) for SECRETS.

Maximum weekly-average evapotranspiration for WAVE exceeded 5 mm day−1, while SECRETS never exceeded 4 mm day−1. Both models, in general, simulated higher evapotranspiration than that measured with the eddy covariance technique. An impact of the soil water content in the direct relationship between the models and the eddy covariance measurements was found.

The results suggest that: (1) different model formulations can reproduce similar results depending on the scale at which outputs are resolved, (2) SECRETS estimates of transpiration were well correlated with the empirical measurements, and (3) neither model fitted favourably to the eddy covariance technique.  相似文献   


12.
Gas is extracted from large (6–31 kg) Antarctic ice samples to obtain sufficient CO2 for14C measurements with small low-level proportional counters. The14C ages of Byrd core ice are in accord with glaciological estimates ranging from (2.2−1.1+1.4)×103 yr at 271 m depth to more than 8 × 103 yr at 1071 m depth. The CO2 abundances in gas extracted from Byrd core ice range from 0.0216 to 0.051%, with below present-day atmosphere CO2 abundances for ice from 1068 and 1469 m depths. The CO2 abundance in gas from Allan Hills surface ice samples ranges between four and six times the atmospheric value and the CO2 had a specific activity three times that of contemporary carbon. A possible explanation for the anomalously high specific activity is surface melting with the incorporation into CO2 of14C produced by cosmic ray spallation of oxygen in ice. The CO2 abundance in gas extracted from subsurface Allan Hills ice ranged from 0.030 to 0.065%, and the specific activities are below contemporary carbon, indicating ages greater than 5×103 yr. The18O/16O ratio of oxygen in the trapped gas is the same as that of atmospheric oxygen and differs markedly from the18O/16O ratio in the ice. The O2, N2, and Ar abundances and isotopic compositions are similar to those in contemporary air, except for positive15N/14N ratios in a few samples.  相似文献   

13.
Isotope and hydrochemical data of the thermal water system in Cieplice laskie Zdrój (Spa) indicate the existence of two subsystems that greatly differ in volume and which meet at the fault zones of a granitic horst, where they discharge at an altitude of about 340m. One of the subsystems is very small (about 4 × 103 m3) as indicated by the tritium age of the order of 10 years and a low outflow rate. Its recharge area found from the δ18O and δD values, is about 200m above the springs, most probably on the slopes of the foothills of the Karkonosze Mountains south-southwest of the spa. The large subsystem contains water which is free of tritium and whose 14C content is from 1 to 8 pmc with δ13C = −8.0 to −9.2‰. The isotopic composition of this water reflects either the climatic effect (low-altitude recharge during a cooler pre-Holocene climate) or the altitude effect (recharge in the early Holocene period at about 1000m at the heights of the Karkonosze assuming that the 14C concentration is strongly reduced by exchange with calcite in veins). For the former hypothesis, the recharge area of this water is probably either at the foot of the southeastern slopes of the Kaczawa Mountains or/and at the foot of the Rudawy Janowickie Mountains, to the east of Cieplice. The noble gas temperatures are more consistent with the pre-Holocene recharge. Similarly, the 4He excess and 40Ar/36Ar ratio support the hypothesis of a pre-Holecene age. The constant 3He/4He ratio of 26 × 10−8 for highly different helium contents indicates crustal origin of helium. For the pre-Holocene age of water its volume is calculated at >- 109m3 (stagnant water in micropores and mobile water in fractures) and the hydraulic conductivity of the host granite massif is estimated at about 7 × 10−8 ms−1. Two outflows from this subsystem have different and variable fractions of a modern water component (bomb age), most probably originating from the bank infiltration of a nearby stream.  相似文献   

14.
Variations in some physical, chemical, and nutrient conditions were investigated at Turkwel Gorge Reservoir and its inflowing river, Suam between 1994 and 1995. Seasonal changes in inflow volume had the greatest impact on the reservoir and river conditions investigated. A wide fluctuation in inflow volume combined with a regulated outflow independent of season resulted in a draw down of over 10 m in each year. Flood inflows during the wet season resulted in the lowest values of Secchi depth (range, 0.09–2.16 m), electrical conductivity (EC, range = 140–200 mS cm−1) and total alkalinity (TA, range = 75–111 mg l−1) while the highest values were measured during the dry season. A functional relation between EC and TA (TA = 0.529 mg l−1, EC: R2 = 0.876) suggests a predominance of carbonates among the anions. Vertical profiles of temperature and dissolved oxygen (DO) revealed that the reservoir is monomictic with a wide variation in the depth of the daily mixed layer. High values of pH (range = 6.7–8.9) and DO (range = 4.9–9.2 mg l−1) were associated with periods of peak phytoplankton photosynthesis while the lowest values followed reservoir mixing. Peak total nitrogen (TN, range = 119–526 μg l−1) and total phosphorus (TP, range = 8.9–71.6 μg l−1) levels during the wet season resulted from increased river loading. Values of dissolved reactive silica (DRS, range = 0.41–9.77 mg l−1) showed a wet season decline which was related to diatom depletion during the wet season. Annual reservoir areal loading rates of 27.38, 10.90 and 408.5 mg m−2 were computed for TN, TP and DRS respectively based on estimates of inflowing river loads in 1994.

At the inflowing river Suam, low levels of EC (range = 107–210 μS cm−1) and TA (range = 62–125 mg l−1) occurred during the wet season while the highest levels occurred shortly before the river dried up. The first flood water at the resumption of river inflow in March was characterized by very low levels of DO (range = 1.8–8.2 mg l−1) and high levels of TN (range = 205–3354 μg l−1) and TP (102–1259 μg l−1). River pII (6.9–7.7) and DRs (range = 9.01–19.93 mg l−1) varied irregularly throughout the year.  相似文献   


15.
We report the first measurements of hydrodynamic dispersion in a microfractured granite using a combination of novel techniques. A fracture network was induced in a cylindrical plug of Ailsa Craig micro-granite by thermal stressing, to produce an isotropic network of fractures with an average aperture of  0.3 μm, a density of approximately 4 × 104 fractures/mm3 and a permeability of 5.5 × 10− 17 m2. After saturating the cores with 0.01 M NaCl solution a step in the concentration profile to 1 M was advected into the plug at flow rates of 0.07 to 2.13 cm3 h− 1. The longitudinal electrical impedance of the plug was measured continuously as the solute front advected through its length until the plug was saturated with the concentrated electrolyte. Analysis of the impedance versus time relationships allows the derivation of the longitudinal dispersion coefficient, DL, and hydrodynamic retardation, RH. The Peclet number–dispersion relationship for the micro-fracture network is very similar to that predicted for other, radically different, fracture networks. Thus dispersion may be more dependent on fracture connectivity and length than fracture density and display a relationship similar to that shown by particle beds and clastic sandstones. The high retardation values observed (2.2–4.9) reflect flow behaviour within a fracture network with a proportion of ‘blind’ sections, and demonstrates how such networks can slow the advance of conservative solute components.  相似文献   

16.
The water balance of a small lake using stable isotopes and tritium   总被引：2，自引：0，他引：2  
A small maar lake, known as the Blue Lake, set in a karstic region of southeastern Australia, provides the municipal water supply for a population of 20,000. The lake has a volume of 3.6·107m3, of which 10–15% is pumped from it each year. The lake is recharged almost entirely from groundwater and the main objective of this study was to estimate the total groundwater inflow and outflow rates. Estimation of groundwater throughflow in a lake is difficult to assess using classical hydrological techniques and an alternative method involving measurement of the concentrations of the environmental isotopes 3H, 18O, 2H and 14C in the lake water and in the recharging groundwater was used to establish the lake-water balance. The water-balance calculations indicated a total groundwater inflow to Blue Lake of between 5.0·106 and 6.5·106m3yr.−1, corresponding to a residence time of water in the lake of 6 yr. It was not possible to derive the relative proportions of inflow to the lake from the two possible source aquifers, using these isotopes, because their concentrations did not show a sufficiently large contrast to distinguish the two water sources.  相似文献   

17.
Playa systems are driven by evaporation processes, yet the mechanisms by which evaporation occurs through playa salt crusts are still poorly understood. In this study we examine playa evaporation as it relates to land surface energy fluxes, salt crust characteristics, groundwater and climate at the Salar de Atacama, a 3000 km2 playa in northern Chile containing a uniquely broad range of salt crust types. Land surface energy budget measurements were taken at eight representative sites on this playa during winter (August 2001) and summer (January 2002) seasons. Measured values of net all-wave radiation were highest at vegetated and rough halite crust sites and lowest over smooth, highly reflective salt crusts. Over most of the Salar de Atacama, net radiation was dissipated by means of soil and sensible heat fluxes. Dry salt crusts tended to heat and cool very quickly, whereas soil heating and cooling occurred more gradually at wetter vegetated sites. Sensible heating was strongly linked to wind patterns, with highest sensible heat fluxes occurring on summer days with strong afternoon winds. Very little energy available at the land surface was used to evaporate water. Eddy covariance measurements could only constrain evaporation rates to within 0.1 mm d−1, and some measured evaporation rates were less than this margin of uncertainty. Evaporation rates ranged from 0.1 to 1.1 mm d−1 in smooth salt crusts around the margin of the salar and from 0.4 to 2.8 mm d−1 in vegetated areas. No evaporation was detected from the rugged halite salt crust that covers the interior of the salar, though the depth to groundwater is less than 1 m in this area. These crusts therefore represent a previously unrecorded end member condition in which the salt crusts form a practically impermeable barrier to evaporation.  相似文献   

18.
We have determined the production yields for radionuclides in Al2O3, SiO2, S, Ar, K2SO4, CaCO3, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides 10Be, 14C and 26Al produced in quartz targets, 26Al in Al2O3 and S targets, 36Cl in K2SO4 and CaCO3 targets, and 53Mn in Fe2O3 targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ− capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ− capture, by fast muons and by neutron capture.  相似文献   

19.
Water sampling during the 1993 IV Russian–US Joint Expedition to the Bering and Chukchi Seas (BERPAC) indicates that Pacific Ocean burdens of the long-lived radionuclide 129I are relatively low in the Pacific-influenced Arctic, particularly compared to high latitude waters influenced by the North Atlantic. These low concentrations occur despite the presence of potential submerged anthropogenic sources in the East Sea (Sea of Japan), and in the northwest Pacific Ocean, east of the Kamchatka Peninsula. The concentration of 129I entering the Arctic Ocean through Bering Strait, 0.7×108 atoms kg−1, is only slightly higher than observed in deep Pacific waters. Similar concentrations (0.44–0.76×108 atoms kg−1) measured in Long Strait indicate no significant transfer of 129I eastward into the Chukchi Sea in the Siberian Coastal Current from the Siberian marginal seas to the west. However, the concentrations reported here are more than an order of magnitude higher than the Bering Strait input concentration estimated (1.0×106 atoms kg−1) from bomb fallout mass balances, which supports other existing evidence for a significant atmospheric deposition term for this radionuclide in surface ocean waters. Near-bottom water samples collected in productive waters of the Bering and Chukchi Seas also suggest that sediment regeneration may locally elevate 129I concentrations, and impact its utility as a water mass tracer. As part of this study, two deep 129I profiles were also measured in the East Sea in 1993–1994. The near-surface concentration of 129I ranged from 0.12 to 0.31×108 atoms kg−1. The 129I concentration showed a steady decrease with depth, although because of active deep water ventilation, the entire 3000 m water column exceeded natural concentrations of the radionuclide. Atom ratios of 129I/137Cs in the East Sea also suggest an excess of 129I above bomb fallout estimates, also possibly resulting from atmospheric deposition ultimately originating from nuclear facilities.  相似文献   

20.
Chemical heterogeneities in the Martian mantle are believed to result from the crystallization of a magma ocean in the first 100 million years of its history. Shergottite meteorites from Mars are thought to retain a compositional record of such early differentiation and the resulting mineralogy at different depths. The coupled 176Lu–176Hf and 147Sm–143Nd isotope systematics in 9 shergottites are used here to investigate these issues. Three compositional groups in the shergottites display distinct isotope systematics. One group, commonly termed as depleted, is characterized by positive 176Hfi from + 46.2 to + 50.4 and 143Ndi from + 36.2 to + 39.1. Another, termed as enriched, has negative 176Hfi = − 16.5 to − 13.2 and 143Ndi = − 7.0 to − 6.5. The third group is intermediate between the depleted and enriched groups with positive 176Hfi = + 30.0 to + 33.4 and 143Ndi = + 16.9. Together, they describe mixing curves between 176Hf/177Hf, 143Nd/144Nd, Lu/Hf, and Sm/Nd, implying that they sample two distinct sources in the Martian mantle. All shergottites are characterized by (Sm/Nd)source < (Sm/Nd)sample, but (Lu/Hf)source > (Lu/Hf)sample. This decoupling can be explained by two successive partial melting episodes in the depleted shergottite source and localized in the Martian upper mantle. The genesis of shergottites can be modeled using non-modal equilibrium partial melting in a source initially composed of 60% olivine, 21% clinopyroxene, 9% orthopyroxene, and 10% garnet, with degrees of partial melting of 8.8% and 3.9%, respectively, for the two successive events. The enriched end-member of the shergottite mixing curve is best modeled by late-stage quenched residual melt resulting from the crystallization of a magma ocean. The depleted shergottite source may be modeled as a mixture of cumulates and residual melt, as convection in the Martian magma ocean is expected to reduce the incompatible trace element heterogeneity in the final solidified layers. Consequently, equilibrium crystallization is preferred to model the crystallization of the Martian magma ocean. The models that best explain the shergottite data are those where the magma ocean is at a depth of at least 1350 km in Mars.  相似文献   

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