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1.
The commonly reported temperature coefficient of P. the equilibrium partial pressure of CO2, is (P/T) A,C ,which is about 15 ppm/°C, or 5% of the atmospheric partial pressure of CO2. This coefficient, however, applies only to deep water, not to surface water which can exchange CO2 with the atmosphere. The coefficient (P/T) A,C ,, where designates constancy of the sum of atmospheric and surface-ocean CO2, is the appropriate value for air-sea exchange. Numerical values are mass-dependent because the depth of the exchanging ocean layer must be specified. For a 100-m surface layer, the value is ca. 1.5 ppm/°C, or 0.5% of ambient CO2. Editor's Note:In view of the interdisciplinary importance of the carbon dioxide-climate problem, this note on seawater chemistry should be of interest to specialists beyond the discipline of ocean chemistry.  相似文献   

2.
Summary During an expedition to the high Andes of Southern Peru in June–July 1977, measurements of direct solar radiation in four spectral bands (0.270–0.530–0.630–0.695–2.900 ) were conducted at six sites in elevations ranging from sea level to 5645 m. These measurements were evaluated in Langley plots to determine total optical depths () and irradiances at the top of the atmosphere. In addition, water vapor optical depths (wv) were calculated from the mean radiosounding over Lima during the expedition, and Rayleigh (ray) and ozone (oz) optical depths were obtained from published tabulations. Subtracting ray, oz, and wv from yielded estimates of aerosol optical depth aer. The components ray and oz decrease from the shorter towards the longer wavelength bands and from the lower towards the higher elevation sites; aer also decreases towards the higher elevations. Particularly pronounced is the decrease of aer and from the lowlands of the Pacific coast to the highlands of the interior, reflecting the effect of a persistent lower-tropospheric inversion and the contrast from the marine boundary layer to the clear atmosphere of the high Andes.With 4 Figures  相似文献   

3.
Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both SO and AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m3. In the case of aerosol carbon, we obtained a more gradual increase of AC up to an LWC of 0.5 g/m3. At higher LWCs, _ remained relatively constant at 0.60. As the differences between SO and A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.  相似文献   

4.
This paper describes the similarity between atmospheric fluctuations of carbon dioxide, water vapor and temperature using data which cover a wide range of instability (0.02 < < 10). The is the Monin-Obukhov stability parameter including the humidity effect.The spectral analysis shows that the coherency between fluctuations of carbon dioxide and water vapor or temperature is very close to unity, and the phase difference is basically out of phase for whole frequency ranges analyzed. The stability dependence of the normalized standard deviation of carbon dioxide is very similar to those of water vapor and temperature. The normalized standard deviation is about 2.5 under near neutral conditions, and it decreases with increasing instability following the -1/3; power law as (-)-1/3. The skewness factors of carbon dioxide, water vapor and temperature show a systematic departure with increasing instabilities for 0.02 < s- < 1, and level off at high instabilities for 1 < -\s < 10. The stability dependence of the flatness factors is not so clear as that noted in the standrard deviation and skewness factors. Dissipation rates of carbon dioxide, water vapor and temperature variance are well related to the spectral peak wavelength. This seems to be real since the local production and local dissipation rates are the main terms, almost balancing one another in the variance budget equations for scalar entities.  相似文献   

5.
The yields of products have been calculated for the reactions of hydroxyl radicals and ozone with 19 of the two-through-six carbon anthropogenic alkenes. Based on their rate of reaction, mechanisms of reactions and the ambient air distribution for these alkenes their seasonal ambient air yields have been estimated.Aldehydes predominate as products irrespective of season, with smaller yields of several ketones. Other minor products include carboxylic acids, carbon monoxide, carbon dioxide, and alkenes. About a two-fold increase is estimated in the yields of hot biradicals and their products from summer to winter.One sensitivity analysis was made by recomputing yields at a different OH radical to O3 concentration than assumed most likely in the calculations discussed above. In addition, the sensitivity of product yields to an estimated range of seasonally averaged sunset-to-sunrise NO3 radical concentrations was calculated. The effects of free radical reactions are discussed, but these are believed to make a relatively minor contribution within the NO x -rich atmospheres that contain anthropogenic alkenes.The uncertainties in product yields associated with the range of NO3 radical concentrations assumed present is relatively small for aldehydes, as is the decrease in yield of the one carbon hot biradical. Larger uncertainties occur for ketones. Significant decreases in yields occur for larger hot biradicals, especially the branched-chain hot radicals in the presence of NO3 radicals.  相似文献   

6.
Atmospheric oxidation of monoterpenes contributes to formation of tropospheric ozone and secondary organic aerosol, but their products are poorly characterized. In this work, we report a series of outdoor smog chamber experiments to investigate both gaseous and particulate products in the ozone oxidation of four monoterpenes: -pinene, -pinene, 3-carene, and sabinene. More than ten oxygenated products are detected and identified in each monoterpene/O3 reaction by coupling derivatization techniques and GC/MS detection. A denuder/filter pack sampling system is used to separate and simultaneously collect gas and aerosol samples. The identified products, consisting of compounds containing carbonyl, hydroxyl, and carboxyl functional groups, are estimated to account for about 34–50%, 57%, 29–67%, and 24% of the reacted carbon mass for -pinene, sabinene, -pinene, and 3-carene, respectively. The identified individual products account for >83%, 100%, >90%, and 61% of the aerosol mass produced in the ozone reaction of -pinene, sabinene, -pinene, and 3-carene. The uncertainty in the yield data is estimated to be ±50%. Many of the products partition between gas and aerosol phases, and their gas-aerosol partitioning coefficients are determined and reported here. Reaction schemes are suggested to account for the products observed.  相似文献   

7.
The variations of and in the drainage flow in the Brush Creek valley of western Colorado are investigated using data from Doppler acoustic sodars and instrumented towers. The data were obtained on two experimental nights during the 1984 ASCOT field study. There is good agreement between the variations derived from low-level observations of the sodars and those derived from the towers located throughout the valley. The observed hourly average and in the nocturnal drainage flow are about 20 ° to 25 ° and 5 °, respectively; these values are much larger than those generally observed over flat terrain during nighttime stable conditions. After sunrise (about 0600 MST), as the valley warms and the flow direction changes to up-valley, these parameters increase sharply to their peak values at about 0800 MST and then decrease to their normal daytime values after about two hours.In the drainage flow, the hourly average varies inversely with wind speed according to the relation u 0.7ms-1. The vertical standard deviation is much less enhanced by complex terrain than the horizontal standard deviation. The observed values are predicted fairly well by the local similarity theory.Oak Ridge Associated Universities (ORAU) Summer Research Participant at ATDD in 1987 andOak Ridge Associated Universities (ORAU) Summer Research Participant at ATDD in 1987 and  相似文献   

8.
E- turbulence model predictions of the neutralatmospheric boundary layer (NABL) are reinvestigated to determine thecause for turbulence overpredictions found in previous applications. Analytical solutions to the coupled E and equations for the case of steady balance between transport and dissipation terms, the dominant balance just below the NABL top, are derived. It is found that analytical turbulence profiles laminarizeat a finite height only for values of closure parameter ratio c 2 /e equal toor slightly greater than one, with laminarization as z for greater . The point = 2 is additionally foundthat where analytical turbulent length scale (l) profilesmade a transition from ones ofdecreasing ( < 2) to increasing ( > 2)values with height. Numerically predicted profiles near the NABL topare consistent with analytical findings. The height-increasingvalues of l predicted throughout the NABL with standard values ofclosure parameters thus appear a consequence of 2.5(> 2), implied by these values (c 2 = 1.92, = 1.3, e = 1). Comparison of numericalpredictions with DNS data shows that turbulence overpredictions obtained with standard-valued parameters are rectifiedby resetting and e to 1.1 and 1.6, respectively, giving, with c 2 = 1.92, 1.3, and laminarization of the NABL's cappingtransport-dissipation region at a finite height.  相似文献   

9.
The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O2 of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O2 versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(Hdecomposition–HO 2 reaction), between these two reactions pathways. For (H)[22–0.5(HO 2 reaction)], alkoxy radical decomposition dominates over the reaction with O2 at room temperature and atmospheric pressure of air, while for (H)[25-0.5(HO 2 reaction)], the O2 reaction dominates over decomposition (where the units of H are in kcal mol–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.  相似文献   

10.
Flux densities of carbon dioxide were measured over an arid, vegetation-free surface by eddy covariance techniques and by a heat budget-profile method, in which CO2 concentration gradients were specified in terms of mixing ratios. This method showed negligible fluxes of CO2, consistent with the bareness of the experimental site, whereas the eddy covariance measurements indicated large downward fluxes of CO2. These apparently conflicting observations are in quantitative agreement with the results of a recent theory which predicts that whenever there are vertical fluxes of sensible or latent heat, a mean vertical velocity is developed. This velocity causes a mean vertical convective mass flux (= cw for CO2, in standard notation). The eddy covariance technique neglects this mean convective flux and measures only the turbulent flux c w. Thus, when the net flux of CO2 is zero, the eddy covariance method indicates an apparent flux which is equal and opposite to the mean convective flux, i.e., c w = – c w. Corrections for the mean convective flux are particularly significant for CO2 because cw and c w are often of similar magnitude. The correct measurement of the net CO2 flux by eddy covariance techniques requires that the fluxes of sensible and latent heat be measured as well.  相似文献   

11.
A pair of parallel cold wires separated in either the vertical or lateral direction was used to obtain the three components x, y, z of the temperature derivative in the streamwise, lateral and vertical directions, respectively. The average absolute skewness values of x and z are nonzero and approximately equal, while the skewness of y is approximately zero. These results appear to be consistent with the presence of a large, three-dimensional organised structure in the surface layer. There is an apparent low-frequency contamination in the spectral density of y and z due mainly to small errors in estimating the sensitivity of the cold wires. The temperature derivatives were high-pass filtered, the filter being set to remove possible contributions from the large structure and to minimise low-frequency sensitivity contamination. The filtered rms ratios \~x/\~y and \~x/\~z were in the range 0.7 to 0.9, a result in qualitative agreement with that obtained in the laboratory boundary layer by Sreenivasan et al. (1977). The skewness of filtered x or z is negligible, consistent with local isotropy of small-scale temperature fluctuations and in support of the high wavenumber spectral isotropy discussed in Antonia and Chambers (1978).  相似文献   

12.
Summary The first GCM climate change projections to include dynamic vegetation and an interactive carbon cycle produced a very significant amplification of global warming over the 21st century. Under the IS92a business as usual emissions scenario CO2 concentrations reached about 980ppmv by 2100, which is about 280ppmv higher than when these feedbacks were ignored. The major contribution to the increased CO2 arose from reductions in soil carbon because global warming is assumed to accelerate respiration. However, there was also a lesser contribution from an alarming loss of the Amazonian rainforest. This paper describes the phenomenon of Amazonian forest dieback under elevated CO2 in the Hadley Centre climate-carbon cycle model.  相似文献   

13.
Refuge has patchy vegetation in sandy soil. During midday and at night, the surface sources and sinks for heat and moisture may thus be different. Although the Sevilleta is broad and level, its metre-scale heterogeneity could therefore violate an assumption on which Monin-Obukhov similarity theory (MOST) relies. To test the applicability of MOST in such a setting, we measured the standard deviations of vertical (w) and longitudinal velocity (u), temperature (t), and humidity (q), the temperature-humidity covariance (¯tq), and the temperature skewness (St). Dividing the former five quantities by the appropriate flux scales (u*, *, and q*) yielded the nondimensional statistics w/u*, u/u*, t/|t*|, q/|q*|, and ¯tq/t*q*. w/u*, t/|t*|, and St have magnitudes and variations with stability similar to those reported in the literature and, thus, seem to obey MOST. Though u/u* is often presumed not to obey MOST, our u/u* data also agree with MOST scaling arguments. While q/|q*| has the same dependence on stability as t/|t*|, its magnitude is 28% larger. When we ignore ¯tq/t*q* values measured during sunrise and sunset transitions – when MOST is not expected to apply – this statistic has essentially the same magnitude and stability dependence as (t/t*)2. In a flow that truly obeys MOST, (t/t*)2, (q/q*)2, and ¯tq/t*q* should all have the same functional form. That (q/q*)2 differs from the other two suggests that the Sevilleta has an interesting surface not compatible with MOST. The sources of humidity reflect the patchiness while, despite the patchiness, the sources of heat seem uniformly distributed.  相似文献   

14.
Summary ¶In order to better understand land-atmosphere interactions and increase the predictability of climate models, it is important to investigate the role of forest representation in climate modeling. Corresponding to the big-leaf model commonly employed in land surface schemes to represent the effects of a forest, a so called big-tree model, which uses multi-layer vegetation to represent the vertical canopy heterogeneity, was introduced and incorporated into the National Center for Atmospheric Research (NCAR) regional climate model RegCM2, to make the vegetation model more physically based. Using this augmented RegCM2 and station data for China during 1991 Meiyu season, we performed 10 experiments to investigate the effects of the application of the big-tree model on the summer monsoon climate.With the big-tree model incorporated into the regional climate model, some climate characteristics, e.g. the 3-month-mean surface temperature, circulation, and precipitation, are significantly and systematically changed over the model domain, and the change of the characteristics differs depending on the area. Due to the better representation of the shading effect in the big-tree model, the temperature of the lower layer atmosphere above the plant canopy is increased, which further influences the 850hPa temperature. In addition, there are significant decreases in the mean latent heat fluxes (within 20–30W/m2) in the three areas of the model domain.The application of the big-tree model influences not only the simulated climate of the forested area, but also that of the whole model domain, and its impact is greater on the lower atmosphere than on the upper atmosphere. The simulated rainfall and surface temperature deviate from the originally simulated result and are (or seem to be) closer to the observations, which implies that an appropriate representation of the big-tree model may improve the simulation of the summer monsoon climate.We also find that the simulated climate is sensitive to some big-tree parameter values and schemes, such as the shape, height, zero-plane displacement height and mixing-length scheme. The simulated local/grid differences may be very large although the simulated areal-average differences may be much lower. The area-average differences in the monthly-mean surface temperature and heat fluxes can amount to 0.5°C and 4W/m2, respectively, which correspond to maximum local/grid differences of 3.0°C and 40W/m2 respectively. It seems that the simulated climate is most sensitive to the parameter of the zero-plane displacement among the parameters studied.  相似文献   

15.
Recent studies suggest that the destruction of methane by Cl in the marine boundary layer could be accounted for as another major sink besides the methane destruction by OH. High level ab initio molecular orbital calculations have been carried out to study the CH4+Cl reaction, the carbon Kinetic Isotope Effect (KIE) is calculated using Conventional Transition-State Theory (CTST) plus Wigner and Eckart semiclassical tunneling corrections. The calculated KIE is around 1.026 at 300 K and has a small temperature variation. This is by far the largest KIE among different processes involving atmospheric methane destruction (e.g., OH, soil). A calculated mass balance of atmospheric methane including the KIE for the CH4+Cl reaction is found to favor those methane budgets with enhanced biological methane sources, which have relatively lighter carbon isotope composition.  相似文献   

16.
Experimental evidence indicates that the diurnal behaviour of the fluxes of heat into the ground and into the atmosphere versus the net flux of radiation can be modelled by closed curves, the hourly values folowing one another in either a clockwise or counter clockfashion. A general formulation to express the different heat fluxes as a function of net radiation is proposed. This relationship between the different heat fluxes and can be expressed as a sum of three terms: the first indicates a direct proportionality to , the second gives the deviation from linearity and depends on /t, and the third gives the value of the flux when = 0. The formulae are then expressed as a function of time and the ratios between the heat fluxes and are evaluated. A comparison with the approximations generally used shows that the latter may be considered as particular cases of the more general equations proposed here.  相似文献   

17.
The gas and particle phase reaction products of a mixture of the atmospherically important terpenes -pinene and -pinene with the atmospheric oxidants O3 and OH/NOx were investigated using both gas chromatography-mass spectrometry (GC-MS) and high performance liquid chromatography (HPLC) for identification and quantification of reaction products. The nighttime oxidation of a mixture of -pinene and -pinene in the presence of O3/air, and the daytime oxidation of a mixture of -pinene + -pinene with NOx air in the presence of natural sunlight were carried out in the University of North Carolina's large outdoor smog chamber (190 m3) located in Chatham County, North Carolina. Mass balances for gaseous and aerosol reaction products are reported over the course of the reaction. More than twenty-nine products were identified and/or quantified in this study. On average, measured gas and particle phase products accounted for 74 to 80% of the reacted -pinen/-pinene mixture carbon. Measurements show that a number of reaction products were found in both O3 and NOx system [pinonaldehyde, pinic acid, pinonic acid, pinalic-3-acid, 4-hydroxypinalic-3-acid, 4-oxonopinone, 1-hydroxy-nopinone, 3-hydroxy-nopinone, and nopinone]. Pinonic acid, pinic acid, pinalic-3-acid, 4-hydroxypinalic-3-acid, and 10-hydroxypinonic acid were observed in the early stage in the aerosol phase and may play an important role in the early formation of secondary aerosols.  相似文献   

18.
Analytical solutions for the Ekman layer   总被引：1，自引：0，他引：1  
The PBL equation that governs the transition from the constant-stress surface layer to the geostrophic wind in a neutrally stratified atmosphere for which the eddy viscosityK(z) is assumed to vary smoothly from the surface-layer value U *z (0.4,U *=friction velocity,z=elevation) to the geostrophic asymptoteK GU *d forzd is solved through an expansion in fd/U *1 (f=Coriolis parameter). The resulting solution is separated into Ekman's constant-K solution an inner component that reduces to the classical logarithmic form forzd and isO() relative to the Ekman component forzd. The approximationKU *d is supported by the solution of Nee and Kovasznay's phenomenological transport equation forK(z), which yieldsK–U *d exp(–z/d), where is an empirical constant for which observation implies, 1. The parametersA andB in Kazanskii and Monin's similarity relation forG/U * (G=geostrophic velocity) are determined as functions of . The predicted values ofG/U * and the turning angle are in agreement with the observed values for the Leipzig wind profile. The predicted value ofB based on the assumption of asymptotically constantK is 4.5, while that based on the Nee-Kovasznay model is 5.1; these compare with the observed value of 4.7 for the Leipzig profile. A thermal wind correction, an asymptotic solution for arbitraryK(z) and 1, and an exact (unrestricted ) solution forK(z)=U *d[1–exp(–z/d)] are developed in appendices.  相似文献   

19.
TheConvectiveDiffusionObserved byRemoteSensors (CONDORS) field experiment conducted at the Boulder Atmospheric Observatory used innovative techniques to obtain three-dimensional mappings of plume concentration fields, /Q, of oil fog detected by lidar and chaff detected by Doppler radar. It included extensive meteorological measurements and, in 1983, tracer gases measured at a single sampling arc. Final results from ten hours of elevated and surface release data are summarized here. Many intercomparisons were made. Oil fog /Q measured 40m above the arc are mostly in good agreement withSF 6 values, except in a few instances with large spacial inhomogeneities over short distances. After a correction scheme was applied to compensate for the effect of its settling speed, chaff dy/Q agreed well with those of oil except in two cases of oil fog hot spots. Mass or frequency distribution vs. azimuth or elevation angle comparisons were made for chaff, oil, and wind, with mostly good agreements. Spacial standard deviations, y and z, of chaff and oil agree overall and are consistent at short range with velocity standard deviations vand w 0.6w* (the convective scale velocity), as measured atz>100m. Surface release y is enhanced up to 60% at smallx, consistent with the Prairie Grass measurements and with larger v and reduced wind speed measured near the surface. Decreased y at small dimensionless average times is also noted. Finally, convectively scaled dy, C y, were plotted versus dimensionlessx andz for oil, chaff, and corrected chaff for each 30–60 min period. Aggregated CONDORSC y fields compare well with laboratory tank and LES numerical simulations; surface-released oil fog compares expecially well with the tank experiments. However, large deviations from the norm occurred in individual averaging periods; these deviations correlated strongly with anomalies in measured distributions.On assignment to the US Environmental Protection Agency, Atmospheric Research and Exposure Assessment Laboratory, RTP, NC.  相似文献   

20.
Equilibrium evaporation beneath a growing convective boundary layer   总被引：1，自引：1，他引：0  
Expressions for the equilibrium surface Bowen ratio ( s ) and equilibrium evaporation are derived for a growing convective boundary layer (CBL) in terms of the Bowen ratio at the top of the mixed layer i and the entrainment parameter A R . If AR is put equal to zero, the solution for s becomes-that previously obtained for the zero entrainment or closed box model. The Priestley-Taylor parameter is also calculated and plotted in terms ofA R and i . Realistic combinations of the atmospheric parameters give values of in the range 1.1 to 1.4.  相似文献   

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