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1.
Marine Isotope Stage 11 has been proposed as an analogue for the present interglacial interval; yet, terrestrial climate records from both this region and time interval are rare. The sediments deposited at Lake El'gygytgyn (67°30′N, 172°5′E) in Far East Russia contain a 3·56 Ma record of climate variability. This study presents a high‐resolution record of sediment colour change from Marine Isotope Stage 8 to 12 (ca 275 to 475 ka) and demonstrates the link between lake catchment processes and climate variability. The hue colour parameter, calculated from data collected via colour reflectance spectroscopy in the visible spectrum (380 to 720 nm), exhibits correspondence with global climate records. Determining the source of sediment colour changes was achieved through detailed mineralogical and sedimentological methods, and linked to colour changes through a series of colour sensitivity tests. Mineralogical data, measured by X‐ray diffraction, reveal fluctuations in concentrations of clay minerals corresponding to colour changes. Further analyses of the clay mineral assemblages show no change in relative clay mineral abundances, yet demonstrate a lake catchment dominated by physical weathering processes. Using measured mineral abundances, reconstructions of sediment colour based on colour reflectance mineral standards link mineral and clay mineral content to overall sediment colour. Colour sensitivity tests demonstrate the ability of iron oxide minerals to stain sediments red. Additionally, colour sensitivity to organic matter content was tested, suggesting that organic content drives variability in the red portion of the spectrum and darkens the overall colour signal. Sediment colour is then ultimately linked to physical weathering of bedrock minerals, with small amounts of chemical weathering producing iron oxides during wet intervals. Fluctuations in the sediment colour reveal a high‐resolution record of wet/dry cycles, and provide new information about wet periods for the Russian Arctic region not yet understood from other lake proxy records.  相似文献   

2.
Soils (n=250) were collected from ten salt and brackish-water marshes of North Carolina and analyzed for organic matter content by loss on ignition (LOI) and Kjeldahl nitrogen (KN). Total organic carbon and total nitrogen were determined on the same samples using an elemental CHN analyzer. Regression analyses indicated that LOI and KN were excellent estimators of organic C (R2=0.990) and total N(R2=0.986), respectively, in low clay content (0–11%) marsh soils containing a wide range of soil organic C (0.1–28%) and total N (0–1.6%). A quadratic equation best described the relationship between organic C and organic matter (Organic C=0.40 [LOI] +0.0025 [LOI]2) while a linear model accurately described the relationship between total N and Kjeldahl N (Total N=1.048 [KN]?0.010). The proportion of organic C in organic matter (C/OM) increased with increasing soil organic matter content, probably as a result of aging. Young marshes, which are characterized by low soil organic content contain C/OM ratios similar to emergent vegetation (40–45%). In old organic soils (70–80% organic matter), C/OM increased to 57–60% due to accumulation of reduced organic materials.  相似文献   

3.
古海洋研究中的地球化学新指标   总被引：30，自引：4，他引：30  
有机地球化学与微量元素地球化学古环境指标及其相关的同位素指标已成为追溯古全球变化与古海洋生物地球化学演化的有力工具。从古环境替代指标的示踪原理和应用的角度，综述了有孔虫碳同位素、有机地球化学整体指标、生物标志化合物、单体有机分子同位素、微量元素等在古海洋古环境研究中的应用及相关的研究动态与进展。指出古海洋研究正从以恢复古海洋的物理参数（温度、盐度、古洋流等）为主，向着揭示古水团演化、古生产力、古营养状况、碳贮库及碳循环等古生物地球化学演化过程方向纵深发展。  相似文献   

4.
Lake Bosumtwi is one of the most widely studied palaeoclimate archives in West Africa. Results from numerous AMS 14C dates of samples from four piston cores from Lake Bosumtwi show that an abrupt sedimentary transition from a mid-Holocene sapropel to calcareous laminated muds occurred at about 3200 cal yr B.P. High-resolution analyses of the nitrogen isotopic composition of organic matter across this transition confirm its abrupt nature, and suggest that the change may signal a step toward increased aridity and intensified surface winds that affected western equatorial Africa from Ghana to the Congo basin. Northern and Eastern Africa experienced a similar abrupt shift toward aridity during the late Holocene, but at about 5000 cal yr B.P., a difference in timing that illustrates the regional nature of climate changes during the Holocene and the importance of feedback mechanisms in regulating Holocene climate variability. Furthermore, an abrupt change at about 3000 cal yr B.P. occurs at several sites adjacent to the tropical and subtropical Atlantic, which may hint at major changes in the surface temperatures of the tropical Atlantic and/or Pacific at this time.  相似文献   

5.
The results of a theoretical isotope mass balance model are presented for the time dependence of burial and weathering-plus-degassing fluxes within the combined long-term carbon and sulfur cycles. Averaged data for oceanic δ13C and δ34S were entered for every million years from 270 to 240 Ma (middle Permian to middle Triassic) to study general trends across the Permian-Triassic boundary. Results show a drop in the rate of global organic matter burial during the late Permian and a predominance of low values during the early-to-middle Triassic. This overall decrease with time is ascribed mainly to epochs of conversion of high biomass forests to low biomass herbaceous vegetation resulting in a decrease in the production of terrestrially derived organic debris. Additional contributions to lessened terrestrial carbon burial were increased aridity and a drop in sea level during the late Permian which led to smaller areas of low-lying coastal wetlands suitable for coal and peat deposition.Mirroring the drop in organic matter deposition was an increase in the burial of sedimentary pyrite, and a dramatic increase in the calculated global mean ratio of pyrite-S to organic-C. High S/C values resulted from an increase of deposition in marine euxinic basins combined with a decrease in the burial of low-pyrite associated terrestrial organic matter. The prediction of increased oceanic anoxia during the late Permian and early Triassic agrees with independent studies of the composition of sedimentary rocks.Weathering plus burial fluxes for organic carbon and pyrite sulfur were used to calculate changes in atmospheric oxygen. The striking result is a continuous drop in O2 concentration from ∼30% to ∼13% over a twenty million year period. This drop was brought about mainly by a decrease in the burial of terrestrially derived organic matter. but with a possible contribution from the weathering of older organic matter on land. It must have exerted a considerable influence on animal evolution because of the role of O2 in respiration. Some examples are the extinction of many vertebrates, loss of giant insects and amphibians, and the restriction of animals to low elevations. It is concluded that the extinction of plants may have contributed to the extinction of animals.  相似文献   

6.
The most drastic changes of the organic geochemical parameters examined (organic carbon, soluble organic matter content and composition, δC13 insoluble organic matter) occur over the near-surface 3 m intervals of two shallow core holes drilled into outcrops of the Upper Cretaceous Mancos Shale in Utah. This observation is believed to reflect the effects of weathering under the semi-arid climate of the study area. Therefore, organic geochemical data obtained from analysis of surface samples should be interpreted with caution.  相似文献   

7.
This paper provides an incisive review of paleoclimate science and its relevance to natural-resource management within the Murray-Darling Basin (MDB). The drought of 1997–2010 focussed scientific, public and media attention on intrinsic climate variability and the confounding effect of human activity, especially in terms of water-resource management. Many policy and research reviews make statements about future planning with little consideration of climate change and without useful actionable knowledge. In order to understand future climate changes, modellers need, and demand, better paleoclimate data to constrain their model projections. Here, we present an insight into a number of existing long-term paleoclimate studies relevant to the MDB. Past records of climate, in response to orbital forcing (glacial–interglacial cycles) are found within, and immediately outside, the MDB. High-resolution temperature records, spanning the last 105 years, exist from floodplains and cave speleothems, as well as evidence from lakes and their associated lunettes. More recently, historical climate records show major changes in relation to El Niño–Southern Oscillation cycles and decadal shifts in rainfall regimes. A considerable body of research currently exists on the past climates of southeastern Australia but, this has not been collated and validated over large spatial scales. It is clear that a number of knowledge gaps still exist, and there is a pressing need for the establishment of new paleoclimatic research within the MDB catchment and within adjacent, sensitive catchments if past climate science is to fulfil its potential to provide policy-relevant information to natural-resource management into the future.  相似文献   

8.
Defining the control that hydrology exerts on organic carbon (OC) export at the watershed scale is important for understanding how the source and quantity of OC in streams and rivers is influenced by climate change or by landscape drainage. To this end, molecular (lignin phenol), stable carbon isotope, and dissolved organic carbon (DOC) data were collected over a range of flow conditions to examine the influence of hydrology on annual OC export from an 850 km2 Midwestern United States agricultural watershed located in west central Indiana. In years 2002 and 2003, modeled annual DOC loads were 19.5 and 14.1 kg ha−1yr−1, while 71% and 85%, respectively, of the total annual OC was exported in flow events occurring during less than 20% of that time. These results highlight the importance of short-duration, high-discharge events (common in smaller watersheds) in controlling annual OC export. Based on reported increases in annual stream discharge coupled with current estimates of DOC export, annual DOC loads in this watershed may have increased by up to 40% over the past 50 years. Molecular (lignin phenol) characterization of quantity and relative degradation state of terrestrial OC shows as much temporal variability of lignin parameters (in high molecular weight dissolved organic carbon) in this one watershed as that demonstrated in previously published studies of dissolved organic matter in the Mississippi and Amazon Rivers. These results suggest that hydrologic variability is at least as important in determining the nature and extent of OC export as geographic variability. Moreover, molecular and bulk stable carbon isotope data from high molecular weight dissolved organic carbon and colloidal organic carbon showed that increased stream flow from the study watershed was responsible for increased export of agriculturally derived OC. When considered in the context of results from other studies that show the importance of flood events and in-stream processing of terrestrial organic carbon, our results show how hydrologic variability in smaller watersheds can reflect landscape-scale carbon dynamics in ways that cannot necessarily be measured at the outlets of large rivers due to multiple source signals and attenuated hydrology.  相似文献   

9.
In this study, a ca. 4000 cal. yr ancient lacustrine (or wetland) sediment record at the southern margin of Tarim Basin is used to reconstruct the history of climate change. Six radiocarbon dates on organic matter were obtained. δ18O and δ13C of carbonate, pollen and sediment particle size were analysed for climate proxies. The proxies indicate that a drier climate prevailed in the area before ca. 1010 BC and during period 1010 BC–AD 500 climate then changed rapidly and continuously from dry to moist, but after about AD 500 climate generally shows dry condition. Several centennial‐scale climatic events were revealed, with the wettest spell during AD 450–550, and a relatively wetter interval between AD 930–1030. Pollen results show that regional climate may influence human agricultural activities. Spectral analysis of mean grain size (MGS) proxy reveals statistically pronounced cyclic signals, such as ca. 200 yr, ca. 120 yr, ca. 90 yr, ca. 45 yr and ca. 33 or 30 yr, which may be associated with solar activities, implying that solar variability plays an important role in the decadal‐ and centennial‐scale climate variations in the study area. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

10.
冻土区甲烷排放研究进展   总被引：6，自引：0，他引：6  
冻土区土牡表面和活动层土的ＣＨ４排放和吸收表现出强烈的时空变化性。根据多年冻土中ＣＨ４含量的模拟结果表明，全球尺度上，平均每米厚度多年冻土含有ＣＨ４６５Ｔｇ。在未来的２００年间，多年冻土融化所导致的大气ＣＨ４附加年源强变化于２～２５Ｔｇ。  相似文献   

11.
《Quaternary Science Reviews》2007,26(13-14):1713-1724
Continuous high-resolution pollen data for the past 225 ka from sediments in Bear Lake, Utah–Idaho reflect changes in vegetation and climate that correlate well with variations in summer insolation and global ice-volume during MIS 1 through 7. Spectral analysis of the pollen data identified peaks at 21–22 and 100 ka corresponding to periodicities in Earth's precession and eccentricity orbital cycles. Suborbital climatic fluctuations recorded in the pollen data, denoted by 6 and 5 ka cyclicities, are similar to Greenland atmospheric temperatures and North Atlantic ice-rafting Heinrich events. Our results show that millennial-scale climate variability is also evident during MIS 5, 6 and 7, including the occurrence of Heinrich-like events in MIS 6, showing the long-term feature of such climate variability. This study provides clear evidence of a highly interconnected ocean–atmosphere system during the last two glacial/interglacial cycles that extended its influence as far as continental western North America. Our study also contributes to a greater understanding of the impact of long-term climate change on vegetation of western North America. Such high-resolution studies are particularly important in efforts of the scientific community to predict the consequences of future climate change.  相似文献   

12.
Here we present Holocene organic carbon, nitrogen, sulphur, carbon isotope ratio and macrofossil data from a small freshwater lake near Sisimiut in south‐west Greenland. The lake was formed c. 11 cal ka BP following retreat of the ice sheet margin and is located above the marine limit in this area. The elemental and isotope data suggest a complex deglaciation history of interactions between the lake and its catchment, reflecting glacial retreat and post‐glacial hydrological flushing probably due to periodic melting of local remnant glacial ice and firn areas between 11 and 8.5 cal ka BP. After 8.5 cal ka BP, soil development and associated vegetation processes began to exert a greater control on terrestrial–aquatic carbon cycling. By 5.5 cal ka BP, in the early Neoglacial cooling, the sediment record indicates a change in catchment–lake interactions with consistent δ13C while C/N exhibits greater variability. The period after 5.5 cal ka BP is also characterized by higher organic C accumulation in the lake. These changes (total organic carbon, C/N, δ13C) are most likely the result of increasing contribution (and burial) of terrestrial organic matter as a result of enhanced soil instability, as indicated by an increase in Cenococcum remains, but also Sphagnum and Empetrum. The impact of glacial retreat and relatively subdued mid‐ to late Holocene climate variation at the coast is in marked contrast to the greater environmental variability seen in inland lakes closer to the present‐day ice sheet margin. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

13.
Small diameter core samples were taken from outcrops of the Permian Phosphoria Formation and the Cretaceous Pierre Shale of the Western United States to determine the effects of weathering on organic matter in shale outcrops. While the Pierre Shale core showed no evidence of weathering, the Phosphoria Formation showed significant reduction of overall organic content and pronounced changes in organic composition over the near-surface interval of the core. Total organic carbon is lower by as much as 60% over the upper 2 ft of the core. Chloroform-soluble organic matter and total hydrocarbon (C15+) concentrations are 50% lower over this same interval. The ratio of saturated to aromatic hydrocarbons decreases steadily with core depth over the upper 2.6 ft of the core. Aromatic hydrocarbons are enriched in the stable carbon-13 isotope by an average of 1.7%. over this same interval. Shallow core samples also show a loss of n-paraffins relative to branched/cyclic compounds in the saturated C15+ fraction.Although the extent of weathering is variable, certain characteristic effects are recognizable and can be applied to the interpretation of outcrop data in organic geochemical studies.  相似文献   

14.
With this study, I suggest that changes in biogeochemical processes in northern Norwegian fjords during the last glacial/interglacial transition (14.3 to 6.3 ka B.P.) are predominantly climate induced. Variable strength in Atlantic water inflow, intrusion of Arctic waters and sea-ice coverage, various nutrient supply, as well as several re-advances of continental ice-sheets are recorded by both bulk organic and selected biomarkers in sediments of the Andfjord. Stable isotope (δ13Corg, δ15N) and Rock-Eval pyrolysis data indicate a strong supply of terrestrial organic matter during stadials (e.g., Younger Dryas, Older Dryas) whereas enhanced input of marine organic matter prevailed during the interstadials (Bølling/Allerød). Profiles of selected biomarkers of marine origin show a characteristic climate-induced variation during the whole time interval, where relatively low concentrations of dinosterols and C37 alkenones may indicate—similar to today—a minor contribution of their respective plankton groups (coccolithophorids, dinoflagellates). The prevalence of Arctic waters and seasonal sea-ice coverage during the Younger Dryas is indicated by a single maximum of 24-methylenecholesterol probably indicating the dominance of sea-ice diatoms and/or the prevalence of diatoms of Thalassiosiraceae in surface waters. The sediments of the Allerød, in contrast, show a pronounced maximum in dinosterols, indicating a better adaptation of dinoflagellates to an oceanic regime that is characterized by incipient intrusion of Atlantic water, highly variable sea surface temperatures, and well stratified water masses. The concentration of higher-molecular-weight n-alkanes, however, follows the deglacial-early Holocene trend of climate amelioration from the last deglaciation to the middle Holocene, with maxima during ice advances (stadials) and minima during the middle Holocene warm period.These new results significantly improve the understanding of climate-induced response on organic matter supply in fjords and provide a better knowledge of past variations of biogeochemical processes in high-latitude coastal environments.  相似文献   

15.
max vs the present depth of the Kupferschiefer, soluble organic matter (SOM) yields, and relative proportions of saturated and aromatic hydrocarbons of the SOM provide evidence for an oxidative alteration of organic matter in highly mineralized Kupferschiefer samples near the Rote F?ule zones. This is confirmed by differences in the composition of the saturated and aromatic hydrocarbon fractions of the soluble organic matter: Saturated hydrocarbons from Rote F?ule samples are dominated by short-chain n-alkanes and higher abundances of pristane and phytane relative to heptadecane (n-C17) and octadecane (n-C18), respectively, compared with samples more distant to the Rote F?ule zone. Compositional changes of the aromatic hydrocarbon fractions with decreasing distance to that zone are characterized by the occurrence of polycyclic aromatic hydrocarbons and elevated ratios of phenanthrene to methylphenanthrenes that are attributed to demethylation reactions and resulted in a decrease of the methylphenanthrene index (MPI 1). Kupferschiefer samples from the barren zone of the Polish Basin do not show these alteration patterns. The observed variations in organic matter composition with burial depth are consistent with changes due to increasing thermal maturation. Maturity assessment is achieved from MPI 1 and the methyldibenzothiophene ratio (MDR). From the relationship between the maturity of organic matter in terms of vitrinite reflectance values and depth of the Kupferschiefer strata, a continuous increase in reflectance of vitrinite is obtained within the Polish Basin. The alteration pattern of organic matter related to base metal mineralization of the Kupferschiefer corresponds to changes in the isotopic composition of organic carbon and calcite. Kerogen within, or close to, Rote F?ule zone is enriched in 13C caused by the preferential release of isotopically light organic compounds through progressive degradation of organic matter. The opposite tendency towards lower δ 13C and δ 18O values of calcite provides evidence for isotopic exchange between carbonate and the oxidizing, ore-bearing solutions and for organic matter remineralization. In contrast, organic matter and calcite from the Kupferschiefer do not show regular trends in δ 13C with increasing thermal maturation. Received: 25 June 1999 / Accepted: 1 December 1999  相似文献   

16.
与古气候和古环境息息相关的有机质发育特征的高精度预测,是油气地质研究的核心和难点,对中—低勘探程度沉积盆地常规油气或中高勘探程度沉积盆地中非常规油气的高效评价部署具有重要意义。本研究利用旋回地层学、地球化学技术,通过东营凹陷FY1井古近系沙河街组三段下亚段的高频旋回地层划分和古环境、古气候、有机质地球化学、矿物学分析,探索陆相泥页岩有机质在不同尺度旋回地层中的富集规律。结果表明: (1)在东营凹陷古近系沙三下亚段中识别出2个1.2 Ma超长斜率旋回、5个400 ka长偏心率旋回、21个96 ka短偏心率旋回、42个51 ka斜率旋回、103个19 ka岁差旋回。结合前期研究成果,以1.2 Ma、400 ka、96 ka波形曲线为依据,识别出2个长期、6个中期、21个短期基准面旋回; (2)东营凹陷沙三下亚段沉积时期古环境恢复与TOC数据对比分析证明,古气候演化与有机质富集之间基本同步,均受控于天文旋回,即超长斜率增大或长偏心率增大时期,气候温暖湿润,基准面升高,地层还原性增强,有利于有机质富集; (3)有机质的富集主要取决于古气候温暖湿润程度控制的古生产力和湖盆水体深度控制的有机质保存环境,长期与中期尺度旋回对有机质富集的控制程度高于短期旋回,因此在长期、中期尺度上,可以旋回波形曲线为依据进行古环境恢复和富有机质层的厘定。  相似文献   

17.
The purpose of this study was to determine peat formation processes throughout the millennia in four tidal marshes in the Sacramento–San Joaquin Delta. Peat cores collected at each site were analyzed for bulk density, loss on ignition, and percent organic carbon. Core data and spline fit age–depth models were used to estimate inorganic sedimentation, organic accumulation, and carbon sequestration rates in the marshes. Bulk density and percent organic matter content of peat fluctuated through time at all sites, suggesting that peat formation processes are dynamic and responsive to watershed conditions. The balance between inorganic sedimentation and organic accumulation at the sites also varied through time, indicating that marshes may rely more strongly on either inorganic or organic matter for peat formation at particular times in their existence. Mean carbon sequestration rates found in this study (0.38–0.79 Mg C ha−1 year−1) were similar to other long-term estimates for temperate peatlands.  相似文献   

18.
Radiocarbon Dating of Soil Organic Matter   总被引：2，自引：0，他引：2  
Radiocarbon ages of soil organic matter are evaluated with a model which incorporates the dynamics of the14C content of soil organic matter. Measured14C ages of soil organic matter or its fractions are always younger than the true ages of soils due to continuous input of organic matter into soils. Differences in soil C dynamics due to climate or soil depth will result in significantly different14C signatures of soil organic matter for soils of the same age. As a result, the deviation of the measured14C age from the true age of soil formation could differ significantly among different soils or soil horizons. Our model calculations also suggest that14C ages of soil organic matter will eventually reach a steady state provided that no climatic or ecological perturbations occur. Once a soil or a soil horizon has reached a steady state,14C dating of soil organic matter will provide no useful information regarding the age of the soil. However, for soils in which steady state has not been reached, it is possible to estimate the age of soil formation by modeling the measured14C contents of soil organic matter. Radiocarbon dating of buried soils could, in general, overestimate the true age of the burial by as much as the steady-state age of the soil or soil horizon.  相似文献   

19.
The Chemical Nature of Phosphorus in Subtropical Lake Sediments   总被引：1，自引：0，他引：1  
The phosphorus (P) composition of sediment profiles in three subtropical lakes of contrasting trophic state in Florida, USA, was determined by sequential fractionation and solution 31P NMR spectroscopy. Sediment from Lake Annie, an oligo-mesotrophic sinkhole with moderately acidic sediment (pH 5.4; loss on ignition 58 %), contained higher total P concentrations than sediment from eutrophic Lake Okeechobee (pH 7.7, loss on ignition 36 %) and hyper-eutrophic Lake Apopka (pH 7.5, loss on ignition 69 %). The chemical nature of sediment P varied markedly among the three lakes, suggesting the predominance of different diagenetic processes. Lake Okeechobee sediment was dominated by inorganic P, indicating the dominance of abiotic reactions; Lake Annie sediment contained abundant organic P throughout the sediment profile, indicating the importance of organic P stabilization at acidic pH; Lake Apopka contained almost half of its sediment P in microbial biomass, indicating the importance of biotic processes in regulating P dynamics. Solution 31P NMR spectroscopy of NaOH–EDTA extracts revealed that organic P occurred mainly as phosphomonoesters in all lakes. However, sediment from Lake Apopka also contained abundant phosphodiesters and was the only lake to contain detectable concentrations of polyphosphate, perhaps due to a combination of alternating redox conditions and high concentrations of inorganic phosphate and organic carbon. Organic P concentrations determined by sequential fractionation and solution 31P NMR spectroscopy were similar for all lakes when microbial P was included in values for sequential fractionation. We conclude that the chemical nature of sediment P varies markedly depending on trophic state and can provide important information on the dominant processes controlling P cycling in subtropical lakes.  相似文献   

20.
An exploratory study was carried out at 22 sampling stations along the Langat River, Selangor in order to investigate on the vitality of cation exchange capacity (CEC) in sediment (0–5 cm). Parameters such as pH, Eh, salinity, and electrical conductivity (EC) were determined. The CEC in sediment has been calculated by the determination of Ca2+, Na+, Mg2+, and K+ using the flame atomic absorption spectrophotometer, while the organic matter content in sediment was ascertained using the loss on ignition method. The characteristic of the sediment shows that pH (3.09–7.46), salinity (0.02–10.71 ppt), EC (3.39–517 μS/cm) and Eh (?16.20–253.10 mV) were substantially high in variation. This study also revealed that exchangeable Ca2+ and Mg2+ were controlled by organic matter contents, while exchangeable Na+ and K+ were influenced by salinity. Salinity was observed to play a major part in controlling all the exchangeable cations, as it gives strong significant correlations with Na+, K+, Mg2+, CEC, and organic matter at p?<?0.01. The presence of seawater, clay mineralogy, and organic matter proves that it does play an important role in determining the CEC and soon relates to the pollution magnitude in the sediment.  相似文献   

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