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1.
The Fe/Mg+Fe) ratios (XFe) of the Quaternary basalts (SiO2 < 53 wt.%) in the Japanese arcs were examined. The XXFe of relatively magnesian basalts decreases from the volcanic front toward the Japan Sea across the arcs. Based on the partition coefficient of Mg-Fe2+ between olivine and liquid, it is suggested that all the basalts near the volcanic front, which are mostly tholeiitic basalts, are significantly fractionated, whereas many basalts near the Japan Sea, which are mostly alkali basalts, are little fractionated. The K2 O content in the primary basalt magmas increases toward the Japan Sea. Combining the XFe and K2 O data, it is suggested that relatively large amounts of tholeiitic magmas are produced near the volcanic front, but they fractionate during their ascent, whereas smaller amounts of alkali basalt magmas are formed near the Japan Sea, but they can ascend with less fractionation. The density of primary tholeiite magma is significantly larger than that of primary alkali basalt magmas. It is most likely that primary tholeiite magmas cannot ascend beyond the upper crust and would fractionate to produce less dense tholeiitic magmas near the volcanic front, whereas primary alkali basalt magmas can ascend through the upper crust without fractionation, as far as buoyancy is the principal ascending force. In the Japanese arcs, the stress field may be less compressional near the Japan Sea than near the volcanic front, so that magmas can ascend more rapidly in the latter region than in the former. These two factors may be responsible for the above mentioned chemical variations of basalt magmas across the arcs. The variation in volume of the Quaternary volcanic rocks across the arcs can be explained by the presence of a melt-rich zone above but nearly parallel to the subducted slab.  相似文献   

2.
Multibeam bathymetry and bottom imaging (Simrad EM12D) studies on an area of about 9500 km2 were conducted over the Pitcairn hotspot near 25°10′S, 129° 20′W. In addition, 15 dives with the Nautile submersible enabled us to obtain ground-true observations and to sample volcanic structures on the ancient ocean crust of the Farallon Plate at 3500–4300 m depths. More than 100 submarine volcanoes overprint the ancient crust and are divided according to their size into large (>2000 m in height), intermediate (500–2000 m high) and small (<500 m high) edifices. The interpretation of seafloor backscatter imagery accompanied by submersible observations and sampling enabled us to infer that the total volume of submarine lava erupted during hotspot activity is about 5900 km3 within a radius of about 110 km. The most recent volcanic activities occur on both small and large edifices composed of a great variety of lava flows. These flows vary in composition, following a succession from picritic basalt to alkali basalt, trachybasalt, trachy-andesite and to trachyte. Their large range of SiO2 (48–62%), Na2O+K2O (2–11%), Ba (300–1300 ppm), MgO (1–11%), Nb (19–130 ppm), Ni (4–400 ppm) and rare earth elements suggests that crystal–liquid fractionation from basanite and/or picritic melt sources was a major process. The variation in composition between the least evolved basaltic rocks and the other more evolved silicic lava is marked by a difference in their flow morphology (pillow, giant tubes, tabular to blocky flows). The lava composition and field observation indicate that several magmatic pulses giving rise to cyclic eruptions are responsible for the construction of the edifices. The two larger edifices (>2000 m high) show more extensive eruptive events and a wider range in compositional variability than the smaller (<500 m high) ones. Several (five) submersible transects made along the slope of one of the largest edifices (Bounty) enabled us to observe at least nine successive eruptive cycles progressing from pillow and giant tubular basalt to tabular/blocky trachy-andesite and trachyte flows. Pyroclasts and hyaloclastites are often found with these eruptive sequences. The smaller edifices, forming individualized cones, are built mainly of evolved silicic (SiO2>53%) flows consisting essentially of alternating sequences of trachy-andesite and trachyte. The distribution and composition of the small edifices suggest that they are the result of sub-crustal forceful magma injection and channeling supplied from reservoirs associated with the large volcanoes.  相似文献   

3.
The influence of volcanic processes on magmatic differentiation can be evidenced by the study of some of the most typical volcanoes of post-orogenic magmatism of Central Italy. It has been recognized that a close relationship exists between degree and type of differentiation on one hand, and structure and evolution of volcanic edifices as well as shape of their magmatic chambers on the other. The effect of the structural features of volcanic apparata on the magmatic differentiation is often so strong as to obliterate the original genetic characters of the magma. It was seen that, in Central Italy, magmas of «atlantic» affinities differentiating from basalt to trachyte, can turn to magmas of strong « mediterranean » affinities in the more superficial volcanic environments.  相似文献   

4.
3He/4He ratios in lavas erupted during the last 360 years at Mt. Vesuvius are between 2.2 and 2.7 RA (RA = atmospheric ratio of 1.39 × 10−6), and are among the lowest values measured in young volcanic rocks. They are also identical to values measured in summit crater fumaroles sampled during 1987–1991. This agreement indicates that the 3He/4He ratio in the crater fumaroles faithfully tracks the magmatic value. The relatively low and uniform 3He/4He ratio in the lavas reflects either a mantle source enriched in (U + Th)/3He, or a mixture of magmatic and crustal components.  相似文献   

5.
Minor centres in the Central Volcanic Zone (CVZ) of the Andes occur in different places and are essential indicators of magmatic processes leading to formation of composite volcano. The Andahua–Orcopampa and Huambo monogenetic fields are located in a unique tectonic setting, in and along the margins of a deep valley. This valley, oblique to the NW–SE-trend of the CVZ, is located between two composite volcanoes (Nevado Coropuna to the east and Nevado Sabancaya to the west). Structural analysis of these volcanic fields, based on SPOT satellite images, indicates four main groups of faults. These faults may have controlled magma ascent and the distribution of most centres in this deep valley shaped by en-echelon faulting. Morphometric criteria and 14C age dating attest to four main periods of activity: Late Pleistocene, Early to Middle Holocene, Late Holocene and Historic. The two most interesting features of the cones are the wide compositional range of their lavas (52.1 to 68.1 wt.% SiO2) and the unusual occurrence of mafic lavas (olivine-rich basaltic andesites and basaltic andesites). Occurrence of such minor volcanic centres and mafic magmas in the CVZ may provide clues about the magma source in southern Peru. Such information is otherwise difficult to obtain because lavas produced by composite volcanoes are affected by shallow processes that strongly mask source signatures. Major, trace, and rare earth elements, as well as Sr-, Nd-, Pb- and O-isotope data obtained on high-K calc-alkaline lavas of the Andahua–Orcopampa and Huambo volcanic province characterise their source and their evolution. These lavas display a range comparable to those of the CVZ composite volcanoes for radiogenic and stable isotopes (87Sr/86Sr: 0.70591–0.70694, 143Nd/144Nd: 0.512317–0.512509, 206Pb/204Pb: 18.30–18.63, 207Pb/204Pb: 15.57–15.60, 208Pb/204Pb: 38.49–38.64, and δ 18O: 7.1–10.0‰ SMOW), attesting to involvement of a crustal component. Sediment is absent from the Peru–Chile trench, and hence cannot be the source of such enrichment. Partial melts of the lowermost part of the thick Andean continental crust with a granulitic garnet-bearing residue added to mantle-derived arc magmas in a high-pressure MASH [melting, assimilation, storage and homogenisation] zone may play a major role in magma genesis. This may also explain the chemical characteristics of the Andahua–Orcopampa and Huambo magmas. Fractional crystallisation processes are the main governors of magma evolution for the Andahua–Orcopampa and Huambo volcanic province. An open-system evolution is, however, required to explain some O-isotopes and some major and trace elements values. Modelling of AFC processes suggests the Charcani gneisses and the local Andahua–Orcopampa and Huambo basement may be plausible contaminants.  相似文献   

6.
7.
The extinct Pleistocene volcano Muriah, situated behind the main Pleistocene—Recent Sunda magmatic arc in north-central Java, has erupted at least two contrasted groups of lavas. One group forms a well-defined compositional series (Anhydrous Series) from leucite basanite to tephritic phonolite, with olivine and tschermakitic clinopyroxene the main phenocrysts. The other group, the “Hydrous Series”, includes compositionally variable tephrites and high-K andesites with common plagioclase, biotite and amphibole. Lavas of the Anhydrous Series are much richer in LIL trace elements than the most potassic lavas of neighbouring active volcanoes, but relative HFS element enrichment is less pronounced. REE patterns have almost constant slopes from La (250–600 times chondrites) to Yb (5–10 times chondrites), while those of lavas of active centres are less light-enriched, and show flattening in the heavy REE. Anhydrous Series initial 87Sr/86Sr ratios (0.7043–0.7046) are lower than those of active centres (0.7047–0.7053). Hydrous Series lavas are intermediate in all these geochemical characteristics.The most mafic A-series leucite basanite, with Mg/(Mg + Fe2+) 0.69, 140 ppm Ni and 620 ppm Cr was probably derived from the primary magma for the series by fractionation of only 5 wt.% olivine. Its REE pattern suggests derivation from a garnet-bearing source. Experiments on this basanite, with up to 10% olivine and 20% orthopyroxene added, and in the presence of H2O and H2O/CO2 mixtures, have shown that for all but very high magma water contents, the olivine and garnet liquidus fields are widely separated by fields of phlogopite and clinopyroxene. There is no liquidus field of orthopyroxene. Hence, if magma production involved an equilibrium melting process alone, the most probable sources are of garnet-bearing phlogopite clinopyroxenite type. Alternatively, this magma may represent the end-product of interaction between a low-K basanite magma from a garnet lherzolite source in the asthenosphere and a phlogopite-bearing lherzolite zone in the lower lithosphere. Its production was probably related to crustal doming and extension superimposed on the dominant subduction regime. Hydrous Series magmas may have resulted from mixing between Anhydrous Series magmas and high-K calc-alkaline basaltic to andesitic magmas more directly related to subduction processes.  相似文献   

8.
During 1979–1989, variations were observed in the oxygen composition of the water contained in the geothermal reservoir at Vulcano Island, Italy.The reservoir water, that has a magmatic origin, showed an oxygen composition of +1.0±0.5‰ δ18O during periods without local tectonic earthquakes, and an oxygen composition of +3.4±0.5‰ δ18O after the highest-energy seismic activity that occurred recently near the island. A slight increase of the δ18O value in the reservoir water was also observed after a low-energy sequence of tectonic earthquakes that occurred at very shallow depth just beneath Vulcano Island. These 18O variations in the reservoir water are consistent with earthquake-induced increases in the contribution from high-temperature δ18O-rich magmatic condensate to the geothermal reservoir, and with subsequent decreases in the δ18O value due to 18O exchanges at the temporarily increased reservoir temperature during reactions between the highly reactive magmatic condensate and the local rocks.Only minor changes in the deuterium composition of the reservoir water occurred with time, as the δD value in the magmatic condensate released from the magma after major local earthquakes quickly approached the δD value of the water contained in the geothermal reservoir.Also the chloride concentration in the reservoir water appears to be linked to the contribution from the magmatic fluid. This chloride content seems not to have undergone major changes with time, as it may be buffered by temporary increases in the reservoir temperature up to values >300°C induced by major local earthquakes. This mechanism may possibly occur also in other magmatic–hydrothermal systems.  相似文献   

9.
The times of activity at Fuego (one of the most active volcanoes in the world) since 1800 correlate with the activity of other Central American volcanoes. Approximately 0.7 km3 of olivine-bearing, high-Al2O3 basalt has been erupted since 1932, and about 1.7 km3 has been produced during 450 years of historic records. A minimum of 13,000 years and a maximum of 100,000 years were required to build Fuego's cone of 50 km3. Within the recent cluster of activity since 1932, rates of magma production have increased to 0.5 m3/s and the trend has been toward more eruptions (shorter reposes) of progressively more mafic basalt. 47% of the eruptions occurred within 2 days of the fortnightly tidal maximum and 56% occurred within 2 hours of the semi-diurnal minimum of the vertical tidal gravity acceleration. Thus the maximum compressional component of the tidal cycles can trigger an eruption at Fuego. Eruptions with higher effusion rates produce larger volumes of materials, although they only last a few hours. The 20–70 year clusters of activity beginning at 80–170-year intervals are interpreted as reflecting the ascent of primary batches of magma. A deeper (8–16 km), larger (> 1 km3) primary chamber and a shallower (2–5 km), smaller (0.1 km3), dike-like secondary chamber best explain Fuego's behavioral pattern.  相似文献   

10.
18O/16O and 87Sr/86Sr ratios were determined for Quaternary calc-alkalic volcanic rocks from six volcanic rock suites in the central and western Japan arcs. The δ18O values relative to SMOW and 87Sr/86Sr ratios range from +6.3 to +9.90/00 and 0.70357 to 0.70684, respectively. Both the O- and Sr-isotopic compositions are higher than those for island-arc primitive magmas and their differentiates. The isotopic compositions of the calc-alkalic rocks cannot be derived by a simple fractional crystallization of the primitive magmas. On the other hand, the 18O- and 87Sr-enrichment is confined to the rock suites located in well-developed island arcs having thick continental-type crust with low or negative Bouguer anomalies. Involvement of 18O- and 87Sr-rich crustal material in the magma formation is suggested.The isotopic compositions vary remarkably within individual rock suites as well as from volcano to volcano. The data points in δ18O vs. 87Sr/86Sr plot accord with a mixing model between primitive magmas and crustal material of dioritic composition on an average, assuming their comparative Sr contents. The primitive magmas involved could not be low-Sr tholeiites, but magmas more or less enriched in incompatible elements including Sr, which correspond to high-alkali tholeiites or alkali basalts and their evolved magmas. The nature of the primitive magmas seems to change from tholeiitic to more alkalic with progressing island-arc evolution.Mixing of crust-derived melts is more plausible than assimilation of solid-rocks for involving 20 to 30% crustal material in the magmas along simple mixing curves. Isotopic variations between the rock suites are ascribed to variable Sr concentration radio of the end-members, variable isotopic compositions of crustal material or variable mixing ratio of the end-members. Extremely high-δ 18O rocks with moderate increase in 87Sr/86Sr ratio suggest another mixing process in shallower magma chambers between andesite magmas and metasedimentary rocks having high δ 18O and 87Sr/86Sr values but low Sr content. Subsequent fractional crystallization of once-derived magmas would be the prominent process for the rock suites showing gradual increase in 18O up to 10/00 with uniform 87Sr/86Sr ratios.  相似文献   

11.
For any given volcanic field the compositions of primary melts provide important constraints on models of magmatic processes and volcanic eruptions. In this paper, based on petrography, olivine and bulk rock compositions, two tholeiitic picrites (samples C122 and C123) from Haleakala Volcano, east Maui are evaluated as possible primary melts. Sample C122 (bulk rock MgO = 16.6%) has a high apparent Mg-Fe exchange coefficient, KD, between olivine phenocrysts and bulk rock (0.6). However, major-elements and Ni mass-balance calculations show that the olivines in C122 are in equilibrium with the residual melt (matrix) after closed-system equilibrium fractionation of 25 wt.% olivine. Therefore, the Mg/Fe ratio, Ca content, and Ni content of C122 are consistent with the hypothesis that the bulk composition of C122 is close to a primary melt formed by partial melting of a mantle containing olivine with composition around Fo89 to Fo91. The uniform composition and small size (mostly 0.2–0.3 mm) of the olivine, and the glass patches in the matrix suggest fast ascent, and rapid cooling at shallow depth for C122. On the contrary, sample C123, which has an apparent KD (between the most mafic olivine megacrysts and the bulk rock) close to the equilibrium value (0.27), the multiple planar subgrain boundaries in most of the olivine crystals indicate that it may not be a primary melt unless the deformed olivines are generated at magmatic condition as phenocrysts. If the deformed subgrain boundary texture in olivine could indeed be generated at magmatic condition, then the wide compositional range of olivine crystals in C123 (Fo74 to Fo91) suggests multi-stage crystallization over a wide range of cooling temperatures.The compositions of the two picrites, and a differentiated basalt which does not contain xenocrysts suggest that the Haleakala tholeiites are derived from primary melts with at least 16–17 wt.% MgO. Lavas with such high MgO content are rare in Haleakala and other Hawaiian volcanoes; therefore, most Hawaiian tholeiites must have undergone extensive fractionation histories.  相似文献   

12.
The chemical composition and D/H, and ratios have been determined for the acid hot waters and volcanic gases discharging from Zaō volcano in Japan. The thermal springs in Zaō volcano issue acid sulfate-chloride type waters (Zaō) and acid sulfate type waters (Kamoshika). Gases emitted at Kamoshika fumaroles are rich in CO2, SO2 and N2, exclusive of H2O. Chloride concentrations and oxygen isotope data indicate that the Zaō thermal waters issue a fluid mixture from an acid thermal reservoir and meteoric waters from shallow aquifers. The waters in the Zaō volcanic system have slight isotopic shifts from the respective local meteoric values. The isotopic evidence indicates that most of the water in the system is meteoric in origin. Sulfates in Zaō acid sulfate-chloride waters with δ34S values of around +15‰, are enriched in 34S compared to Zaō H2S, while the acid sulfate waters at Kamoshika contain supergene light sulfate (δ34S = + 4‰) derived from volcanic sulfur dioxide from the volcanic exhalations. The sulfur species in Zaō acid waters are lighter in δ34S than those of other volcanic areas, reflecting the difference in total pressure.  相似文献   

13.
Rhyolites occur as a subordinate component of the basalt-dominated Eastern Snake River Plain volcanic field. The basalt-dominated volcanic field spatially overlaps and post-dates voluminous late Miocene to Pliocene rhyolites of the Yellowstone–Snake River Plain hotspot track. In some areas the basalt lavas are intruded, interlayered or overlain by ~15 km3 of cryptodomes, domes and flows of high-silica rhyolite. These post-hotspot rhyolites have distinctive A-type geochemical signatures including high whole-rock FeOtot/(FeOtot+MgO), high Rb/Sr, low Sr (0.5–10 ppm) and are either aphyric, or contain an anhydrous phenocryst assemblage of sodic sanidine ± plagioclase + quartz > fayalite + ferroaugite > magnetite > ilmenite + accessory zircon + apatite + chevkinite. Nd- and Sr-isotopic compositions overlap with coeval olivine tholeiites (ɛNd = −4 to −6; 87Sr/86Sri = 0.7080–0.7102) and contrast markedly with isotopically evolved Archean country rocks. In at least two cases, the rhyolite lavas occur as cogenetic parts of compositionally zoned (~55–75% SiO2) shield volcanoes. Both consist dominantly of intermediate composition lavas and have cumulative volumes of several 10’s of km3 each. They exhibit two distinct, systematic and continuous types of compositional trends: (1) At Cedar Butte (0.4 Ma) the volcanic rocks are characterized by prominent curvilinear patterns of whole-rock chemical covariation. Whole-rock compositions correlate systematically with changes in phenocryst compositions and assemblages. (2) At Unnamed Butte (1.4 Ma) the lavas are dominated by linear patterns of whole-rock chemical covariation, disequilibrium phenocryst assemblages, and magmatic enclaves. Intermediate compositions in this group resulted from variable amounts of mixing and hybridization of olivine tholeiite and rhyolite parent magmas. Interestingly, models of rhyolite genesis that involve large degrees of melting of Archean crust or previously consolidated mafic or silicic Tertiary intrusions do not produce observed ranges of Nd- and Sr-isotopes, extreme depletions in Sr-concentration, and cogenetic spectra of intermediate rock compositions for both groups. Instead, least-squares mass-balance, energy-constrained assimilation and fractional crystallization modeling, and mineral thermobarometry can explain rhyolite production by 77% low-pressure fractional crystallization of a basaltic trachyandesite parent magma (~55% SiO2), accompanied by minor (0.03–7%) assimilation of Archean upper crust. We present a physical model that links the rhyolites and parental intermediate magmas to primitive olivine tholeiite by fractional crystallization. Assimilation, recharge, mixing and fractional melting occur to limited degrees, but are not essential parts of the rhyolite formation process. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. This paper constitutes part of a special issue dedicated to Bill Bonnichsen on the petrogenesis and volcanology of anorogenic rhyolites.  相似文献   

14.
Following the collision along the Bitlis–Zagros suture, a north–south convergence between the Arabian Platform and Laurasia has continued uninterrupted until the present. As a result, the continental crust has been shortened, thickened and consequently elevated to form the Turkish–Iranian high plateau. On the high plateau volcanic activity began during the Neogene, intensified during the late Miocene–Pliocene and continued until historical times. Large volcanic centres have been developed during the Quaternary which form significant peaks above the Turkish–Iranian high plateau. Among the Quaternary volcanoes, the major volcanic centres are Ararat, Tendürek, Suphan and Nemrut. Ararat (Ağri Daği) is the largest volcanic center and is a compound stratovolcano, consisting of Greater Ararat and lesser Ararat. The former represents the highest elevation of Anatolia reaching over 5000 m in height. Tendürek is a double-peaked shield volcano, which produced a voluminous amount of basalt lava as extensive pahoehoe, and aa flows. It has an ill-defined semi-caldera. Suphan is an isolated stratovolcano, capped by silicic dome. It represents the second highest topographic elevation in Anatolia, with a height of over 4000 m. A cluster of subsidiary cones and small domes surrounds the volcano. Nemrut is the largest member of a group of volcanoes, which trend north–south. It is a stratovolcano, having a well-defined collapse caldera and a caldera lake. Various volcanic ejecta have been extruded from these volcanic centres over the last 1 to 2 million years. The Quaternary volcanic centres, although temporally and spatially closely associated, display a wide range of lavas from basalt to rhyolite. The volcanoes have diverse compositional trends; Ararat is distinctly subalkaline, Suphan is mildly subalkaline, Nemrut is mildly alkaline and Tendürek is strongly alkaline. The major and trace element compositions together with the isotope ratios indicate that their magmas were generated from a heterogeneous mantle source. Each of the volcanic centres has undergone a partly different magmatic evolution.  相似文献   

15.
Fumarole discharges (95–560°C) collected from the dacite dome inside Mount St. Helens crater show temporal changes in their isotopic and chemical compositions. A δD vs. δ18O plot shows that condensed waters from the gases are mixtures of meteoric and magmatic components, but that the apparent magmatic end-member in 1994 was depleted by about 7‰ in δD relative to the apparent end-member in 1980. Based on δD modeling, approximately 63% of shallow, post-1980 magma has yet to degas. Surprisingly, Cl and F contents in the 1994 samples were only 0.47 and 3.8%, respectively, of the concentrations determined for end-member magmatic fluid in 1980. The data indicate that Cl (and F and B) is degassed from magma relatively quickly compared to water and/or that most of the Cl degassed in later years is dissolved into the shallow Mount St. Helens hydrothermal system. Because metals are often transported in magmatic and hydrothermal fluids as Cl complexes, rapid changes in surface volatile compositions may have implications for the timing and location of metals transport and deposition in some volcanoes.  相似文献   

16.
The Hasan Dagi volcano is one of the two large Plio-Quaternary volcanoes in Cappadocia (Central Anatolia, Turkey). Three stages of edifice construction have been identified for this volcano: Paleovolcano, Mesovolcano and Neovolcano. Most samples from Hasan Dagi volcano are calc-alkaline and define an almost complete trend from basaltic andesite to rhyolite. However, the more recent (Neovolcano) mafic samples are alkaline basalts. The mineralogical and geochemical characteristics of the oldest lavas (Keçikalesi (13 Ma) and Paleo-Hasan Dagi (7 Ma)) are significantly different from those of the younger lavas (Meso- and Neo-Hasan Dagi (<1 Ma)). Calcic plagioclase and pigeonite are typically observed in these older lavas. The Paleovolcano basalts are depleted in alkalis and display a tholeiitic tendency whereas the differentiated lavas are depleted in Na2O but enriched in K2O compared to younger lavas. There is an evolution through time towards higher TiO2, Fe2O3*, MgO, Na2O and K2O and lower Al2O3 and SiO2 which is reflected in the basalt compositions. All the basalts display multi-element patterns typical of continental margin magmas with a significant enrichment in LILE (K, Rb, Ba and Th) and LREE and strong (Paleovolcano) to moderate (Meso- and Neovolcano) negative Nb, Zr and Ti anomalies. However, the younger basalts are the most enriched in incompatible elements, in agreement with their alkaline affinities and do not systematically display negative HFSE anomalies. REE data suggest an hydrous amphibole-bearing crystallization history for both Meso- and Neovolcano lavas. The distinction between the older and younger lavas is also apparent in trace element ratios such as Nb/Y, Ti/Y and Th/Y. These ratios indicate the role of a subducted component±crustal contamination in the genesis of the Hasan Dagi lavas, particularly for the oldest lavas (Keçikalesi and Paleo-Hasan Dagi). The decreasing influence of this component through time, over the last 6–7 m.y., has been accompanied by an increasing contribution of melt-enriched lithosphere. Although the range of variation of Sr, Nd and Pb isotopic ratios is small (0.70457–0.70515; 0.51262–0.51273; 18.80–18.94; 15.64–15.69; 38.87–39.10), it also reflects the evolution of the magma sources through time. Indeed, the youngest (Neovolcano) and most primitive basalts display significantly lower 87Sr/86Sr than the Paleo- and Mesovolcano basalts, whereas the Mesovolcano basalts display more radiogenic Pb than Paleovolcano samples. Magma mixing processes between initially heterogeneous and/or variably contaminated magmas may account for the genesis of the less differentiated and intermediate lavas (48–57% SiO2). Meso- and Neovolcano differentiated lavas (60–68% SiO2) are either derived from the analyzed basalts or from more primitive and more depleted magmas by fractional crystallization±some crustal contamination (AFC). Furthermore, the highly differentiated samples (72–75% SiO2) are not strongly contaminated. The strong calc-alkaline character of Hasan Dagi lavas, in the absence of contemporaneous subduction, must reflect the heritage of the early subduction of the Afro–Arabian plate under the Eurasian plate. The evolution towards alkaline compositions through time is clearly related to the development of extensional tectonics in Central Anatolia in the Late Miocene.  相似文献   

17.
Two groups of rhyolites have been recognized at San Vincenzo (Tuscany, Italy). Group A rhyolites are characterized by plagioclase, quartz, biotite, sanidine and cordierite mineral assemblages. They show constant MgO and variable CaO and Na2O contents. Initial87Sr/86Sr ratios in group A samples range between 0.71950 and 0.72535, whereas the Nd isotopic compositions are relatively constant (0.51215–0.51222). Group B rhyolites are characterized by orthopyroxene and clinopyroxene as additional minerals, and show textural, mineralogical and chemical evidence of interaction with more mafic magmas. The Sr and Nd isotopic ratios range between 0.71283–0.71542 and 0.51224–0.51227 respectively. Magmatic inclusions of variable size (1 mm to 10 cm) were found in groups B rhyolites. These inclusions consist mainly of diopsidic clinopyroxene and minor olivine and biotite. They are latitic in composition and represent blobs of hybrid intermediate magmas entrained in the rhyolitic melts. These magmatic inclusions have relatively high Sr contents (996–1529 ppm) and Sr and Nd isotope-ratios of 0.70807–0.70830 and 0.51245–0.51252 respectively.87Sr/87Sr data on minerals separated from both group A and B rhyolites and magmatic inclusions reveal strong isotopic disequilibria due to the presence of both restitic and newly crystallized phases in group A rhyolites and due to interaction of rhyolites with a mantle-de-rived magma in group B rhyolites. Isotopic data on whole rocks and minerals allow us to interpret the group A rhyolites as representative of different degrees of melting of an isotopically fairly homogeneous pelitic source; conversely, group B rhyolites underwent interactions with a mantle-derived magma. The crustal source as inferred from isotopic systematics would be characterized by87Sr/86Sr and143Nd/144Nd ratios close to 0.7194 and 0.51216 respectively. The sub-crustal magma would have Sr isotopic composition close to 0.7077 and a143Nd/144Nd ratio greater than or equal to 0.51252. These isotopic features are different from those reported for the parental magmas postulated for Vulsini and Alban Hills in the nearby Roman Magmatic Province, and are similar to those of the Vesuvius and Ischia magmas.  相似文献   

18.
The magmatic system feeding the last eruption of the volcano La Fossa, Vulcano Island, Italy was studied. The petrogenetic mechanisms controlling the differentiation of erupted rocks were investigated through petrography, mineral chemistry, major, trace and rare earth element and Sr, Nd and Pb isotopic geochemistry. In addition, melt inclusion and fluid inclusion data were collected on both juvenile material and xenolithic partially melted metamorphic clasts to quantify the P-T conditions of the magma chamber feeding the eruption. A regular and continuous chemical zoning has been highlighted: rhyolites are the first erupted products, followed by trachytes and latites, whereas rhyolitic compositions were also found in the upper part of the sequence. The chemical and isotopic composition of the rhyolites indicates that they originated by fractional crystallization from latitic magmas plus the assimilation of crustal material; the trachytes represent hybrid magmas resulting from the mixing of latites and rhyolites, contaminated in the shallow magmatic system. The erupted products, primarily compositionally zoned from latites to rhyolites, are heterogeneous due to syn-eruptive mingling. The occurrence of magmacrust interaction processes, evidenced by isotopic variations (87Sr/86Sr=0.70474±3 to 0.70511±3; 143Nd/144Nd=0.512550±6 to 0.512614±8; 206Pb/204Pb=19.318–19.489; 207Pb/204Pb=15.642–15.782; 208Pb/204Pb=39.175–39.613), is confirmed by the presence of partially melted metamorphic xenoliths, with 87Sr/86Sr=0.71633±6 to 0.72505±2 and 143Nd/144Nd=0.51229±7, in rhyolites and trachytes. AFC calculations indicate a few percentage contribution of crustal material to the differentiating magmas. Thermometric measurements on melt inclusions indicate that the crystallization temperatures of the latites and trachytes were in the range of 1050–1100° C, whereas the temperature of the rhyolites appears to have been around 1000°C at the time of the eruption. Compositional data on melt inclusions reveal that the magmas involved in the eruption contained about 1–1.5 wt.% dissolved H2O in pre-eruptive conditions. Secondary fluid inclusions found in metamorphic xenoliths give low equilibration pressure data (30–60 MPa), giving the location of the higher portions of the chamber at around 1500–2000 m of depth.  相似文献   

19.
Igneous rocks from the Philippine tectonic plate recovered on Deep Sea Drilling Project Legs 31, 58 and 59 have been analyzed for Sr, Nd and Pb isotope ratios. Samples include rocks from the West Philippine Basin, Daito Basin and Benham Rise (40–60 m.y.), the Palau-Kyushu Ridge (29–44 m.y.) and the Parece Vela and Shikoku basins (17–30 m.y.). Samples from the West Philippine, Parece Vela and Shikoku basins are MORB (mid-ocean ridge basalt)-like with 87Sr/86Sr= 0.7026−0.7032, 143Nd/144Nd= 0.51300−0.51315, and 206Pb/204Pb= 17.8−18.1. Samples from the Daito Basin and Benham Rise are OIB (oceanic island basalt)-like with 87Sr/86Sr= 0.7038−0.7040, 143Nd/144Nd= 0.51285−0.51291 and 206Pb/204Pb= 18.8−19.2. All of these rocks have elevated 207Pb/204Pb and 208Pb/204Pb compared to the Northern Hemisphere Regression Line (NHRL) and have δ207Pb values of 0 to +6 and δ208Pb values of +32 to +65. Lavas from the Palau-Kyushu Ridge, a remnant island arc, have 87Sr/86Sr= 7032−0.7035, 143Nd/144Nd= 0.51308−0.51310 and 206Pb/204Pb= 18.4−18.5. Unlike the basin magmas erupted before and after them, these lavas plot along the NHRL and have Pb-isotope ratios similar to modern Pacific plate MORB's. This characteristic is shared by other Palau-Kyushu Arc volcanic rocks that have been sampled from submerged and subaerial portions of the Mariana fore-arc.At least four geochemically distinct magma sources are required for these Philippine plate magmas. The basin magmas tap Source 1, a MORB-mantle source that was contaminated by EMI (enriched mantle component 1 [31]) and Source 2, an OIB-like mantle source with some characteristics of EMII (enriched mantle component 2 [31]). The arc lavas are derived from Source 3, a MORB-source or residue mantle including Sr and Pb from the subducted oceanic crust, and Source 4, MORB-source or residue mantle including a component with characteristics of HIMU (mantle component with high U/Pb [31]). These same sources can account for many of the isotopic characteristics of recent Philippine plate arc and basin lavas. The enriched components in these sources which are associated with the DUPAL anomaly were probably introduced into the asthenosphere from the deep mantle when the Philippine plate was located in the Southern Hemisphere 60 m.y.b.p.  相似文献   

20.
Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ18O = +5.7 to +6.6 (‰ SMOW) andδ34S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ18O = +6.3 ± 0.2 are slightly enriched in18O with respect to unfractionated basalts of<53%SiO2 with meanδ18O = +6.0 ± 0.1. This18O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ18O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ18OSiO2 trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO2; therefore, the meanδ34S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of18O and34S in Mariana Arc parental magmas relative to ocean floor basalts withδ18O ca. + 5.7‰ andδ34S = ca.0.3‰ is attributed to the recycling of18O- and34S-rich crustal components (sediment withδ18O = ca. + 25‰ and seawater sulfate withδ34S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments.  相似文献   

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