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1.
Ideally, the correction of the measured CO2 fugacity (fCO2) at temperature Tm to fCO2 at the in-situ temperature Tin should be made by using at least 2 known parameters (pH-AT, CT-AT,…) and the reliable constants for carbonic acid. In practice however, a measured CO2 property pair is not always available. When fCO2 is measured alone, one must make an estimate of the effect of temperature on seawater fCO2 from the accurate knowledge of seawater salinity and temperature and the approximate knowledge of the carbonate parameters. In this paper we present an empirical relationship that can be used to estimate the effect of temperature on fCO2. The equation is of the form: where fCO2[t] and fCO2[20] represent fCO2 at temperatures t°C and 20°C, respectively; the parameters A, B, etc. are functions of the ratio X = CT/AT: where the parameters ai, bi, etc. are functions of salinity.The 25-parameter equation is fitted by the values of fCO2 calculated using the constants of Goyet and Poisson (1989), when X varies from 0.8 to 1.0, t varies from −1dgC to 40°C, and S varies from 30 to 40. For Tm - Tin within ± 10°C, direct measurements of fCO2 as a function of the temperature (from −I to 30°C verify this equation within less than ±5 μatm. 相似文献
ƒCO2[t] − ƒCO2[20]=A + Bt + Ct2 + Dt3 + Et4
E = e0 + e1X + e2X2ln(X) + e3exp(X) + e4/ln(X)
2.
Norihisa Imasato 《Journal of Oceanography》1976,32(6):253-266
The mechanism of the development of wind-waves will be proposed on the basis of the observed wave spectra in the wind tunnels and at Lake Biwa (Imasato, 1976). It consists of two aspects: One is that the air flow over the wind-waves transfers momentum concentratively to the steepest component waves and the other is that the upper limit of the growth of a wave spectral density is given by the ultimate value in the slope spectral density. The first aspect means that the wave field has the momentum transfer filter on receiving the momentum from the air flow. Wind-waves in the stage of sea-waves receive the necessary amount of momentum by the form drag,e.g. according to the Miles' (1960) inviscid mechanism, through a very narrow frequency region around a dominant spectral peak. On the other hand, wind-waves in the stage of initial-wavelets receive it according to the Miles' (1962a) viscous model through a fairly broad frequency region around the peak. The upper limit ofS
max
developing according to viscous mechanism is given byS
max
=6.40×10–4
k
max
–2cm2s andS
max
=2.03C(f
max
)–2cm2s(S
max
is the power density of the wave spectral peak with the frequencyf
max
,k
max
is the wave number corresponding to the frequencyf
max
andC is the phase velocity).From the second aspect, the upper limit of the growth of wave spectral density is given by 33.3f
–4cm2s in the frequency region of late stage of sea-waves. Therefore, the spectral peak, which has the largest value in the slope spectral density in the component waves of the wave spectrum, rises high over the line 4.15f
–5cm2s. The energy is transported from the spectral peak to the high frequency part and to the forward face of a wave spectrum by nonlinear wave-wave interaction. This nonlinearity is confirmed by the bispectra calculated from the observed wind-wave data. In the stage of sea-waves, nonlinear rearrangement of the wave energy comes from a narrow momentum transfer filter, and, in the stage of initial-wavelets, it comes mainly from small corrugations and small steepness of the wave field. 相似文献
3.
Hisashi Mitsuyasu 《Journal of Oceanography》2017,73(2):169-180
Wind and wind-generated waves were measured in a wind-wave tank. A clear transition was found in the relation between the wind speed U 10 and the wind friction velocity u * near u * = 0.2 m/s, where U 10 is the wind speed at 10 m height extrapolated from the measured wind profile in a logarithmic layer, and u * = 0.2 m/s corresponds roughly to U 10 = 8 m/s in the present measurement. Quite a similar transition was found in the relation between the spectral density of high frequency wind waves and u *. These results suggest the existence of the critical wind speed for air–sea boundary processes, which was proposed by Munk (J Marine Res 6:203–218, 1947) more than half a century ago. His original idea of the critical wind speed was based on the discontinuities in such phenomena as white caps, wind stress, and evaporation, which commonly appear at a wind speed near 7 m/s. On the basis of the results of our present study and those of earlier studies, we discuss the phenomena which are relevant to the critical wind speed for the air–sea boundary processes. The conclusion is that the critical wind speed exists and it is attributed to the start of wave breaking rather than the Kelvin–Helmholtz instability, but the air–sea boundary processes are not discontinuous at a particular wind speed; because of the stochastic nature of breaking waves, the changes occur over a range of wind speeds. Detailed discussions are presented on the dynamical processes associated with the critical wind speed such as wind-induced change of sea surface roughness and high frequency wave spectrum. Future studies are required, however, to clarify the dynamical processes quantitatively. In particular, there is a need to further examine the gradual change of breaking patterns of wind waves with the increase of wind speed, and the associated change of the structure of the wind over wind waves, such as separation of the airflow at the crest of wind waves, the turbulent stress, and wave-induced stress. Studies on the dynamical structure of the high frequency wave spectrum are also needed. 相似文献
4.
Wave dissipation characteristics in SWAN (Simulating Waves Nearshore) model are investigated through numerical experiments. It is found that neither the fully developed integral parameters of wind waves (significant wave height and peak frequency) nor the high frequency spectral tail can be well reproduced by the default wave dissipation source terms. A new spectral dissipation source term is proposed, which comprises saturation based dissipation above two times of peak frequency and improved whitecapping dissipation at lower frequency spectrum. The reciprocal wave age (u /c p ) is involved into the whitecapping model to adjust dissipation rate at different wind speed. The Phillips higher frequency saturation parameter in the saturation-based dissipation is no longer taken as a constant, but varies with wave age. Numerical validations demonstrate that both the wind wave generation process and higher frequency spectrum of wind waves can be well simulated by the new wave dissipation term. 相似文献
5.
在试验水池中，开展了波浪在岛礁地形上演化问题的研究。首先在实验水池中建立了西太平洋某岛礁地形的模型，然后采用改进的JONSWAP谱，由造波机产生不同周期、波高的随机波浪。试验中观察到了不同类型畸形波生成的过程及不同波面形态的畸形波。对偏度、峰度及水深与畸形波要素Hm/Hs（Hm表示波列中的最大波高， Hs为有效波高）的关系进行了详细的分析，同时，对畸形波波高Hfr与偏度的关也进行了分析。通过对试验结果分析，发现峰度与畸形波要素i>Hm/Hs呈正相关， Hfr增大时相应的偏度也会呈现增大的趋势。此外，水深的变化剧烈时（如斜坡、海山位置）有助于畸形波的发生。 相似文献
6.
X-波段雷达近海海浪频谱反演的神经网络模型 总被引：2，自引：1，他引：1
X-波段雷达作为国内海浪观测的一种新工具,在海浪频谱获取和有效波高反演方面仍存在较多问题.本文利用非线性回归方法,将现场实测浮标数据频谱和雷达一维图像谱分别与标准频谱模型进行拟合,发现浮标频谱和一维图像谱具有标准频谱的特征,能够较准确地获取相应的谱参数.提出了建立由雷达一维图像谱参数反演海浪频谱参数的神经网络模型,同时在模型中加入影像序列信噪比,进而反演有效波高,并将反演结果与现场实测数据和传统算法(建立影像序列信噪比与有效波高之间的线性回归方程)进行了对比,结果表明,获取谱参数的误差和反演有效波高的平均误差在20％以内,而传统算法计算有效波高平均误差在20％以上. 相似文献
8.
Abstract
Whilst much attention has been given to models that describe wave, tide and sediment transport processes in sufficient detail to determine the local changes in bed level over a relatively detailed representation of the bathymetry, far less attention has been given to models that consider the problem at a much larger scale (e.g. that of geomorphological elements such as a tidal flat and tidal channel). Such aggregated or lumped models tend not to represent the processes in detail but rather capture the behaviour at the scale of interest. One such model developed using the concept of an equilibrium concentration is the Aggregated Scale Morphological Interaction between Tidal basin and Adjacent coast (ASMITA). In a companion paper (Part 1), we detail the original model and provide some new insights into the concepts of equilibrium, and horizontal and vertical exchange that are key components of this modelling approach. In this paper, we summarise a range of developments that have been undertaken to extend the original model concept, to illustrate the flexibility and power of the conceptual framework. However, adding detail progressively moves the model in the direction of the more detailed process-based models and we give some consideration to the boundary between the two.Highlights
- A range of extensions to the original ASMITA model are presented that allow additional processes or features to be represented in the model.
- The merits of ever increasing complexity within an aggregated model, versus the use of a suitable local-scale and more detailed process-based model are discussed.
9.
The deviations of the marine surface slope spectra (measured using an array of wave gauge sensors) from the theoretical estimates obtained using the linear spectral model of the wave field are analyzed. It has been indicated that the average measured full slope spectra (the sum of the slope component spectra in the orthogonal directions) is higher than the theoretical estimates by 6% at frequencies from the surface wave spectral peak (f m ) to 4.5 f m . The difference between the measured and theoretical estimates of the full slope spectrum rapidly increases at frequencies of f < f m . At f m ≈ 0.75 f m , the average measured full slope spectrum is higher than the theoretical estimate by a factor of more than 5. 相似文献
10.
The conditional acid dissociation constants (pKa′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pKa′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln−1):The estimated accuracy of pH measurements using these calculated pKa′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities. 相似文献
11.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2