共查询到20条相似文献，搜索用时 312 毫秒
1.
The mobility of the rare-earth elements(REE)during hydrothermal activities is increasingly documented.Geological and experimental evidence suggests that REE may be mobile in solutions rich in F^-,Cl^-,HCO3^-,CO^2- 3,HPO4^2-,PO4^3-,or in combinations of the above ligands,even though little has been known about which ligand or which combination is most effective in mobilizing REE. The fractionation of REE resulting from hydrothermal activities is inconsistent.One set of field data implies the prererential mobility of the light rare-earth elements(LREE).whereas another set of field observations indicates the dominant mobilization of the heavy rare earth elements(HREE),and some theoretical prediction is comtradictory to the field evidence.The Eu anomalies due to hydrothermal activities are complex and plausible explanation is not available.The existing experimental approaches dealing with REE are not adequate for explanation ofREE behaviour in aqueous solutions.Systematic experimental approaches are suggested. 相似文献
2.
FAN Honghai CHEN Jinyong WANG Shengyun ZHAO Jingyang GU Dazhao MENG Yanning 《《地质学报》英文版》2017,91(6):2126-2137
This paper presents a systematic study of major and trace elements and Sm-Nd isotopes in leucogranites closely related to uranium mineralization in the Gaudeanmus area, Namibia. The results illustrate that the uraniferous leucogranites possess high Si_O_2(68.8 wt%–76.0 wt%, average 73.1 wt%) and K(4.05 wt%–7.78 wt%, average 5.94 wt%) contents, and are sub-alkaline and metaluminous to weakly peraluminous, as reflected by A/CNK values of 0.96–1.07 with an average of 1.01. The leucogranites are rich in light rare earth elements(LREE/HREE = 2.53–7.71;(La/Yb)N = 2.14–10.40), have moderate Eu depletion and high Rb/Sr ratios(2.03–5.50 with an average of 4.36); meanwhile, they are enriched in Rb, K, Th, U and Pb, and depleted in Ba, Nb, Ta, and Sr. The ε_(Nd)(t) values of uraninites range from -14.8 to -16.5, and the two-stage Nd model ages are 2.43–2.56 Ga. Detailed elemental and Sm-Nd isotopic geochemical characteristics suggest that the leucogranites were formed in a postorogenic extensional environment. The U-rich pre-Damara basement was the main source of uranium during the primary mineralization event, which is disseminated in leucogranites, whereas the uranium mineralization in veins possibly resulted from remobilization of the primary uranium minerals. 相似文献
3.
The Banqi gold deposit is one of the important Carlin-type gold deposits in the southwestern Guizhou Carlin-type gold district, and it is the first deposit of the type found in China. As the major gangue mineral in this deposit, calcite can be divided into four types based on their formation time: pre-mineralization, main metallogenic epoch, late stage of mineralization, and post-mineralization. All types of calcites have distinct features such as field occurrence, physical typomorphic characteristics and trace elements characteristics. The pre-mineralization calcites have the highest REE contents (∑REE=29.70-40.10 μg/g), which are characterized by the most enriched LREE (LREE/ HREE=1.96-3.03), a distinct positive Eu anomalies (δEu=3.83-5.02), and almost no Ce anomalies (δCe=1.02-1.05). The calcites of the main metallogenic epoch have relatively low REE contents (∑REE=10.76-15.53 μg/g), and are characterized by the most enriched HREE (LREE/HREE=0.11-0.23), almost no Eu (δEu=0.73-1.20) and Ce anomalies (δCe=0.88-1.25). The calcites of the late stage of mineralization have the lowest REE contents (∑REE=2.82-4.34 μg/g), and are characterized by enriched HREE (LREE/HREE=0.26-0.86), weakly negative Eu (δEu=0.67-0.83) and Ce anomalies (δCe=0.55-0.81), which are similar to those of the calcites of the main metallogenic epoch. The post-minera¬lization calcites have relatively low REE contents (∑REE=6.92-10.91 μg/g), characterized by enriched LREE (LREE/HREE=1.83-2.34), weakly negative Eu anomalies (δEu=0.72-0.74) and moderately negative Ce anomalies (δCe=0.41-0.50). In addition, the Fe and Mn contents of ore-forming stage calcites are obviously higher than that of the calcites unrelated to mineralization, and negatively correlated with LREE/HREE ratio, which illustrates that the HREE concentrations of calcites are controlled by the incorporation of Fe and Mn. Thus, it will provide an important exploration indicator for the Yunnan-Guizhou-Guangxi Carlin-type gold deposits through the study of typomorphic characteristics of calcite. © 2018, Science Press. All right reserved. 相似文献
4.
LI Ruibao PEI Xianzhi LI Zhuochen SUN Yu PEI Lei CHEN Guochao CHEN Youxin LIU Chengjun WEI Fanghui 《《地质学报》英文版》2013,87(2):333-345
The Helegangnaren feldspar granite exposed in the eastern part of East Kunlun, is characterized by high concentrations of SiO2 and alkaline, low abundances of Fe, Mg and Ca, metaluminous-weak peraluminous. Trace elements analysis shows that the granite is depleted extremely in Ba, Sr and Eu, and rich in some large-ion lithophile elements and high field strength elements. Besides, the granite has high Ga contents, the values of 104(Ga/Al) vary from 2.50 to 2.77, which is mainly greater than the lower limit of A-type granites (2.6), and is higher than the I- and S-type granites’ average (2.1 and 2.28, respectively). Rare earth element (REE) is characterized by relatively high fractionations of light REE (LREE) and heavy REE (HREE) (LREE/HREE=9.3–13.60, (La/Yb)N=10.92–18.02), pronounced negative Eu anomalies (δEu=0.08–0.13), and exhibits right-dipping gull pattern. Major elements, rare elements and trace elements features show the granite is ascribed to A-type granite and A2 subtype in tectonic genetic type. They are plotted into post-collision or within-plate area in a variety of tectonic discriminations. Geological and geochemical data comprehensively suggest that the granite is formed in a post-collision extensive tectonic setting. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U-Pb dating yields a weighted mean age of 425?Ma, belonging to Middle Silurian, which is similar to the age of the post-collision geological events in the region. The differences of magmatic rocks in formation age, rocks assemblage and rocks series systematically indicate that the regional tectonic stress regime in the East Kunlun orogenic belt experienced a major transformation from compress to extension in Middle Silurianin, and the Helegangnaren feldspar granite intruded in the early stage of tectonic transformation. 相似文献
5.
The behaviour of the rare-earth elements(REE)during the weathering of granites was studied in southern Guangxi,China.Based on the study of the weathering profiles,the soil,weathered and sub-weatereb zones are identified with different REE geochemical behaviours throug the weathering profiles of granite.The Ce anomalies of the weathering profiles cover a large range of values with most falling between 1.02 and 1.43in the soil zone and 0.16and 0.40in the weathered and sub-weathered zones.Light rare-earth elements(LREE) and heavy rare-earth elements(HREE)are enriched to varying degree in the weathering profiles as compared to host granites.In the soil zone,more HREEs are leached than LREEs,and HREEs are more enriched than LREE in the weathered and sub-weathered zones.It is considered that infiltration and adsorption on clays are two processes controlling the enrichment and formation of REE deposits in the weathering profiles of granite. 相似文献
6.
LIU Hong LI Guangming HUANG Hanxiao CAO Huawen YUAN Qian LI Yingxu OUYANG Yuan LAN Shuangshuang Lü Menghong YAN Guoqiang 《《地质学报》英文版》2018,92(4):1396-1414
The Jiangla'angzong granite in the northern part of the Central Lhasa Terrane is composed of syenogranite and adamellite. LA-ICP-MS zircon U-Pb analyses suggest that syenogranite has a weighted mean ~(206) Pb/~(238) U age of 86±1 Ma(mean square weighted deviation=0.37), which is in accordance with the muscovite Ar-Ar age(85±1 Ma) of Cu-Au ore-bearing skarns and the zircon U-Pb age(84±1 Ma) of adamellite. This suggests that the Jiangla'angzong magmatism and Cu–Au mineralization events took place during the Late Cretaceous. The granite contains hornblende, biotite, and pyroxene, and does not contain Al-bearing minerals, such as muscovite, cordierite, and garnet. It has high contents of SiO_2(65.10–70.91 wt%), K_2O(3.44–5.17 wt%), and total K_2O+Na_2O(7.13–8.15 wt%), and moderate contents of A_(12)O_3(14.14–16.45 wt%) and CaO(2.33–4.11 wt%), with a Reitman index(σ43) of 2.18 to 2.33, and A/CNK values of 0.88 to 1.02. The P_2O_5 contents show a negative correlation with SiO_2, whereas Pb contents show a positive correlation with SiO_2. Th and Y contents are relatively low and show a negative correlation with the Rb contents. These characteristics suggest that the Jiangla'angzong granite is a high K calc–alkaline metaluminous I–type granite. It is enriched in light rare earth elements(LREE) and large ion lithofile elements(LILE), and depleted in heavy rare earth elements(HREE) and high field strength elements(HFSE), with LREE/HREE ratios of 11.7 to 18.1. The granite has negative Eu anomalies of 0.58 to 0.94 without obvious Ce anomalies(δCe=1.00–1.04). The relatively low initial 87 Sr/86 Sr ratios of 0.7106 to 0.7179, positive εHf(t) values of 1.0 to 4.1, and two-stage Hf model ages(TDM2) ranging from 889 Ma to 1082 Ma, These geochemical features indicate that the granite derived from a juvenile crust. The(~(143) Nd/~(144) Nd)_t values from the Jiangla'angzong granite range from 0.5121 to 0.5123, its εNd(t) values range from-10.17 to-6.10, its(~(206) Pb/~(204) Pb)_t values range from 18.683 to 18.746, its(~(207) Pb/~(204) Pb)_t values range from 15.695 to 15.700, and its(~(208) Pb/~(204) Pb)_t values range from 39.012 to 39.071. These data indicate that the granite was formed by melting of the upper crust with the addition of some mantle materials. We propose that the Jiangla'angzong granite was formed during the postcollision extension of the Qiangtang and Lhasa terranes. 相似文献
7.
王剑锋 《中国地球化学学报》1991,10(3):277-287
Based on the data of 64 samples ,the REE geochemical characteristics of volcanic rocks in northern Zhejiang and eastern Jiangxi provinces are discussed in this paper.The REE distribution patterns in acid and intermediate-acid volcanic rocks in these areas display some similarities,as indicated by rightward-inclined V-shaped curves with negative Eu anomalies,which are parallel to earch other.In addi-tion,their REE parameters(ΣREE,ΣLREE/ΣHREE,δEu,Ce/Yb,La/Sm,La/Yb,etc)also va-ry over a narrow range with small deviations.HREE are particularly concentrated in the volcanic rocks as-sociated with uranium mineralization.The initial ^87Sr/^86Sr ratio in the volcanic rocks is about 0.7056-0.7139.All these features in conjunction with strontium isotopic data indicate that the rock-forming materials come from the sialic crust.The REE distribution patterns and REE geochemical parameters of the volcanic rocks ,as well as La/Sm-La and Ce/Yb-Eu/Yb diagrams may be applied to the sources of rock-forming and ore-forming materials. 相似文献
8.
XIEGuiqing HURuizhong MAOJingwen LIRuiling CAOJinjian JIANGGuohao QILiang 《《地质学报》英文版》2005,79(2):201-210
The development of Early Cretaceous mafic dikes in northern and southern Jiangxi allows an understanding of the geodynamic setting and characteristics of the mantle in southeast China in the Cretaceous. Geological and geochemical characteristics for the mafic dikes from the Wushan copper deposit and No. 640 uranium deposit are given in order to constrain the nature of source mantle, genesis and tectonic implications. According to the mineral composition,the mafic dikes in northern Jiangxi can be divided into spessartite and olive odinite types, which belong to slightly potassium-rich calc-alkaline lamprophyre characterized by enrichment in large ion lithophile elements (LILE) and light rare earth elements (LREE), large depletion in high strength field elements (HSFE) and with negative Nb, Ta and Ti anomalies, as well as 87Sr/86Sr ratios varying from 0.7055 to 0.7095 and 143Nd/r44Nd ratios varying from 0.5119 to 0.5122.All features indicate that the magma responsible for the mafic dikes was derived mainly from metasomatic lithosphere mantle related to dehydration and/or upper crust melting during subduction. Differences in geochemical characteristics between the mafic dikes in northern Jiangxi and the Dajishan area, southern Jiangxi were also studied and they are attributed to differences in regional lithospheric mantle components and/or magma emplacement depth. Combining geological and geochemical characteristics with regional geological history, we argue that southeast China was dominated by an extensional tectonic setting in the Early Cretaceous, and the nature of the mantle source area was related to enrichment induced by asthenosphere upwelling and infiltration of upper crust-derived fluids responding to Pacific Plate subduction. 相似文献
9.
LI Zuochen PEI Xianzhi LI Ruibao PEI Lei LIU Chengjun CHEN Youxin LIU Zhanqing CHEN Guochao XU Tong YANG Jie WEI Bo 《《地质学报》英文版》2014,88(2):584-597
This study focuses on the zircon U–Pb geochronology and geochemistry of the Bairiqiete granodiorite intrusion(rock mass) from the Buqingshan tectonic mélange belt in the southern margin of East Kunlun. The results show that the zircons are characterized by internal oscillatory zoning and high Th/U(0.14–0.80), indicative of an igneous origin. LA–ICP–MS U–Pb dating of zircons from the Bairiqiete granodiorite yielded an age of 439.0 ± 1.9 Ma(MSWD = 0.34), implying that the Bairiqiete granodiorite formed in the early Silurian. Geochemical analyses show that the rocks are medium-K calc-alkaline, relatively high in Al2O3(14.57–18.34 wt%) and metaluminous to weakly peraluminous. Rare-earth elements have low concentrations(45.49–168.31 ppm) and incline rightward with weak negative to weak positive Eu anomalies(δEu = 0.64–1.34). Trace-element geochemistry is characterized by negative anomalies of Nb, Ta, Zr, Hf and Ti and positive anomalies of Rb, Th and Ba. Moreover, the rocks have similar geochemical features with adakites. The Bairiqiete granodiorite appears to have a continental crust source and formed in a subduction-related island-arc setting. The Bairiqiete granodiorite was formed due to partial melting of the lower crust and suggests subduction in the Buqingshan area of the Proto-Tethys Ocean. 相似文献
10.
LING Qicong LIU CongqiangLaboratory for Study of the Earth''s Interior Geofluids Institute of Geochemistry Chinese Academy of Sciences Guiyang Guizhou E-mail: lingqicong@hotmail.com China University of Geosciences Wuhan Hubei 《《地质学报》英文版》2003,77(2):246-257
REE and other trace elements in the altered marbles, massive skarns and ores, as well as garnet and quartz were determined in order to examine the behaviors of trace elements during hydrothermal alteration. It is demonstrated that the high-field-strength (HFS) elements Zr, Hf, Th and Nb were immobile while other trace elements were mobile during the formation of skarns and related deposits. REE and ore-forming elements such as Cu and Ag in hydrothermally-altered marbles and skarns were provided primarily by hydrothermal fluids. In the direction transverse of the strata, the more deeply the marbles were altered, the higher the total REE abundance and the larger the negative Eu anomalies would be. The chondrite-normalized REE patterns of skarns are similar to those of the marbles, but the former are distinguished by much higher REE contents and more remarkable negative Eu anomalies. Those patterns were apparently not inherited from the marble protolith, but were controlled by garnets, which were determine 相似文献
11.
The black shales of the Lower Cambrian Niutitang Formation in Weng'an.on the Yangtze platform of south China,contain voluminous polymetallic sulfide deposits.A comprehensive geochemical investigation of trace,rare earth,and platinum group elements(PGE)has been undertaken in order to discuss its ore genesis and correlation with the tectono.depositional setting.The ore-bearing layers enrich molybdenum(Mo),nickeI(Ni),vanadium(V),lead(Pb),strontium(Sr), bariam(Ba),uranium(U),arsenic(As),and rare earth elements(REE)in abundance.High uranium/thorium(U/Th)ratios(U/Th>1)indicated that mineralization was mainly influenced by the hydrothermal process.The δU value Was above 1.9.showing a reducing sedimentary condition.The REE patterns showed high enrichment in Iight rare earth elements (LREE)(heavy rare earth elements (HREE)(LREE/HREE=5-17),slightly negative europium(EU)and cerium(Ce)anomalies(δEu=0.81-0.93).and positive Ce anomalies(δCe=0.76-1.12).PGE abundance was characterized by the PGE-type distribution patterns,enriching platinum(Pt),palladium(Pd),ruthenium(RuJ and osmium(Os).The Pt,Pd ratio was 0.8.which is close to the ratios of seawater and ultramafic rocks.AII of these geochemical features suggest that the mineralization was triggered by hydrothermal activity in an extensionai setting in the context of break-up of the Rodinian supercontinent. 相似文献
12.
洒西白钨矿床位于滇东南老君山矿集区内,呈层状、似层状产出。矿区围岩为一套中深变质岩,其稀土元素组成特征为:矿区围岩LREE/HREE比值为4.37~6.87,δEu为0.67~1.49,δCe值为0.62~0.98;外围混合片麻岩LREE/HREE比值为4.51~5.58,δEu平均为0.14。矿石Eu正异常与Ce负异常同时存在说明矿石沉淀时相对高温的热水流体和较低温的海水在海底发生了对流混合,部分样品中Eu负异常的形成可能与后期岩浆热液叠加改造作用有关。结合矿床地质特征,洒西白钨矿床成因为喷流沉积-后期岩浆热液改造型。 相似文献
13.
总结了内蒙古大石寨地区1∶25万区域地球化学调查获得的1点/4km2的水系沉积物组合样品中的La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Y等15种稀土元素的区域地球化学分布特征。稀土元素分布与研究区中部的黑云母花岗岩密切相关,轻稀土主要分布在该岩体外围的二叠系地层中,重稀土主要分布在该岩体上方。该岩体上方和外围地层的稀土元素分布、稀土元素总量、轻重稀土比及δCe、δEu、(La/Sm)N、(La/Tb)N、(La/Lu)N、(Ce/Yb)N、(Gd/Lu)N等稀土元素分馏特征的差异明显。利用区域地球化学调查水系沉积物样品中的稀土元素含量,可获得研究区可靠的稀土元素区域地球化学分布特征,也可反映研究区地质特点,并为区域地球化学异常解译提供参考资料。 相似文献
14.
内蒙古东胜地区中侏罗统砂岩沉积物源的地球化学证据 总被引：3，自引：0，他引：3
基于显微薄片观察、稀土和微量元素分析探讨了鄂尔多斯盆地北部东胜地区中侏罗统直罗组砂岩的物源和铀矿化的地球化学特征。砂岩样品含有多种的变质岩岩屑应来自盆地北部的变质岩,那里的花岗片麻岩和斜长角闪岩分析显示:花岗片麻岩LREE/HREE为19.02,斜长角闪岩LREE/HREE为4.47。这两类母岩LREE/HREE比值分别接近于砂岩最高和最低LREE/HREE比值,其稀土配分曲线模式与砂岩LREE/HREE比值端元岩样可以对比,说明砂岩的母岩主要来自这两类变质岩。花岗片麻岩Th/U高,表明发生铀丢失,可作为本区铀成矿的重要铀源。有意义的是,铀含量高的样品,其LREE/HREE比值高,铀含量与亲硫的微量元素Pb、Zn和Mo具有相关关系,这些特征可作为铀矿化的重要标志。 相似文献
15.
那茶淌北铅锌矿床位于西藏冈底斯成矿带东段北部,主要由矽卡岩铅锌矿体组成,是一个典型的矽卡岩型矿床。笔者通过对矿床内的矽卡岩、大理岩(灰岩)、黑云母花岗岩的地球化学对比分析表明:在主量元素方面,显示Si、Al、Fe、Ti、Mg、Ca、Mn等元素在矽卡岩、大理岩、黑云母花岗岩之间发生明显的交换;在稀土元素方面,矽卡岩、大理岩和黑云母花岗岩均具有LREE富集,HREE亏损,并且发育Eu和Ce负异常和相似的REE配分模式,说明矽卡岩的成因与大理岩、黑云母花岗岩具有一定关系。结合三种不同岩性的地球化学特征,强烈的轻、重稀土分异,Eu、Ce负异常,推测矽卡岩由中高温还原热液交代碳酸盐而成,矽卡岩成岩过程中可能有少量海水加入。 相似文献
16.
四川甲基卡新三号(X03) 超大型锂矿脉是近年发现且价值巨大的锂矿化伟晶岩脉,但相对缺少地球化学的研究,利用ICP-MS测试手段对该矿脉ZK1101钻孔中44件样品进行分析测试,发现该矿脉稀土总量很低(∑REE为0.180×10-6~8.613×10-6,平均值为2.543×10-6),配分曲线呈右倾斜型,相对富集轻稀土,总体表现铕负异常.围岩的稀土含量与一般片岩相近(∑REE为160.134×10-6~265.881×10-6,平均值为230.718×10-6),稀土配分曲线总体呈右倾平滑趋势,富集轻稀土,铕为负异常.铕的分布具有特殊性,表现为铕在伟晶岩脉的边部具有显著的正异常.∑REE与Li呈负相关性,δCe与Li则表现为弱正相关性.这一首次发现的低稀土总量和矿脉边部Eu显著正异常的特殊性,对于甲基卡伟晶岩的含矿性评价可能具有重要意义. 相似文献
17.
研究了邹家山铀矿床原始矿石中的稀土元素含量特征及其在酸浸过程中的行为。结果表明:(1)该矿床矿石中伴生的稀土元素总含量很高,∑REE平均含量达3231.55×10-6,其中HREE达2933.39×10-6,属珍贵的重稀土元素富集型,具有负Eu异常、Ce无异常的特征。(2)在强酸及氧化剂浸泡条件下,轻、重稀土元素的浸出行为明显不同。重稀土元素更易被浸出,其浸出率是轻稀土元素的2倍左右。在强酸或强酸加氧化剂浸泡下,随原子序数的增加,轻稀土元素(La~Eu)的浸出率较明显增加,而重稀土元素(Gd~Lu-Y)的浸出率则小幅度递减;15种稀土元素中Gd的浸出率最高,La的浸出率最低。(3)初步获得邹家山铀矿床伴生稀土元素酸法浸出的最佳硫酸浓度和氧化剂用量,即在硫酸浓度为30g/L的条件下,100mL的浸泡液中含有2mL30%的过氧化氢时,稀土元素浸出率可达到最高值。 相似文献
18.
稀土的开发和广泛应用使得人们倍加关注其在环境中的分布及其环境地球化学行为。赣江作为鄱阳湖流域五大入湖河之一,发源于稀土资源富集的赣南地区,而其下游水体及周边地下水中稀土元素的含量和分异特征目前尚不完全清楚。以赣江北支水体及沉积物为研究对象,开展了稀土元素地球化学研究。结果表明,赣江北支水体中稀土元素总量在地表水中为230~1 146 ng/L(均值458.85 ng/L),地下水中为284~1 498 ng/L(均值634.94 ng/L),沉积物中稀土元素总量为177.9~270.7 mg/kg(均值226.99 mg/kg)。PHREEQC模拟计算表明,水体中的稀土元素主要以碳酸根络合物(REEC03+)的形式存在。地表水和地下水总体上均表现为重稀土元素相较于轻、中稀土元素富集,沉积物未表现出明显的富集特性;水体具有Ce、Eu负异常特点,而沉积物表现为Ce正异常和Eu负异常,指示氧化还原环境和水岩相互作用对稀土元素在水-沉积物系统中迁移转化的影响。地下水中稀土元素的含量沿流向具有上升趋势,而水体中重稀土元素的富集程度不断减弱,同时碳酸根络合物(REEC03+)的占比不断降低,反映水体中稀土元素的含量受到pH、胶体吸附、络合作用以及地下水-地表水相互作用的影响。水体中重稀土元素的富集受到碳酸根络合反应的影响,Ce、Eu负异常与Ce氧化沉淀和母岩特性相关。Gd异常值表明,研究区中下游水体中的Gd元素受到人为输入的影响。 相似文献
19.
N. Shikazono Y. Ogawa M. Utada D. Ishiyama T. Mizuta N. Ishikawa Y. Kubota 《Journal of Geochemical Exploration》2008
In this study we analyzed the chemical composition of hydrothermally altered dacite and basalt from the Kuroko mining area, northeastern Honshu, Japan, by REE (rare earth element). Features of rare earth element analyses include: (1) altered footwall dacite exhibits a negative Eu anomaly compared with fresh dacite, suggesting preferential removal of Eu2+ from the altered dacite via hydrothermal solutions, (2) altered hangingwall dacite and basalt and dacite and basalt adjacent to ore deposits exhibit positive Eu anomalies compared with fresh dacite and basalt, suggesting addition of Eu2+ from hydrothermal solutions, (3) LREE ratio (∑LREE/∑REE) from altered dacite of chlorite–sericite zone and K-feldspar zone show a negative relationship with δ18O, and La/Sm ratios show a positive correlation with the K2O index. These trends indicate the addition of light rare earth elements such as La to the altered dacite from hydrothermal solution and/or leaching of heavy rare earth elements such as Sm and Yb, (4) Principal component analysis (PCA) indicates that light rare earth elements enrichment is related to the formation of sericite zone near the Kuroko deposits but not to the formations of chlorite and K-feldspar zones, and (5) The correlations among REE features (LREE ratio, MREE ratio, HREE ratio, Eu/Eu?), δ18O and K2O index are not found for montmorillonite zone, mixed layer clay mineral zone and mordenite zone. Therefore, it is inferred that sericite, chlorite and K-feldspar alterations are related to the Kuroko and vein-type mineralization, but montmorillonite and mordenite alterations are not related to the mineralizations, and probably they formed at the post-mineralization stage. 相似文献
20.
对长白山第四系玄武岩覆盖区零星出露的花岗质岩石和片麻岩进行LA-ICPMS锆石U-Pb年龄测定及地球化学分析,结果显示花岗质岩石的年龄为2 509~2 558 Ma;斜长角闪片麻岩的年龄为2 475~2 553 Ma。地球化学特征上,这些岩石均属奥长花岗岩-英云闪长岩-石英闪长岩系列(TTG),稀土元素配分模式图呈右倾型,轻重稀土元素分馏明显(LREE/HREE=3.85~34.48),白云母二长花岗岩具有铕的负异常(δEu=0.41~0.54),富集Rb、K、Th等元素,亏损Nb、Sr、P、Ti等元素;黑云斜长角闪石片麻岩具有铕负异常(δEu=0.67~0.76),富集Rb、K、La、Nd等元素,亏损Th、Nb、Sr、P、Yb等元素;花岗质片麻岩和黑云斜长片麻岩具有铕的弱负-正异常(δEu=0.87~3.3),富集Rb、K、Sr等元素,亏损Nb、Th、P等元素。年代学和地球化学特征与白山地块和和龙地块中的同类岩石基本一致,表明白山地块与和龙地块在晚太古代是同一个陆块(龙岗陆块),二者目前的分布格局是后期北东向左行断裂构造改造的结果。 相似文献