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1.
《Applied Geochemistry》1997,12(4):483-496
The34S-to-32S ratio in dissolved SO4 has been studied in the Kalix River, Northern Sweden, and its catchment. Weekly sampling over 17 months revealed temporal variations from +5.3‰ up to +7.4‰ in the δ34S values in the river. Snow and rain samples showed lower δ34S values (average +5.6‰ and +5.0‰, respectively). The atmosphere is the major source for S in surface waters in the catchment, and the heavier δ34S values in the river are a result of SO4 reduction within the catchment.Most of the temporal variations in the δ34S value in the river are caused by a mixing of water from the mountain areas (relatively light δ34S) and the woodland. The δ34S value is relatively heavy in the woodland tributaries because of bacterial SO4 reduction in peatland areas influenced by groundwater.The highest δ34S values were measured during the spring flood, in June and in November. These heavy δ34S values are related to different types of water with diverse origins.The heavy δ34S values coinciding with the early spring flood originate from peatland areas in the woodland. Relatively heavy δ34S values (up to +14.4‰) were registered in mire water. Smaller variations of the δ34S value during summer and early autumn most likely were caused by the input of ground-mire water during heavy rains. A correlation between increased TOC concentrations and increased δ34S values was observed.The heavy δ34S values in June and November probably originate from SO4 reduction in bottom water and sediments in lakes within the catchment. Bottom water, enriched in34SSO4, was transported in the river during the spring and autumn overturn. 相似文献
2.
Dmytro Siergieiev Anders Widerlund Angela Lundberg Lisbeth Almqvist Magali Collomp Johan Ingri Björn Öhlander 《Aquatic Geochemistry》2014,20(1):59-80
Using hydrogeochemical analysis of two large boreal rivers (pristine Kalix and hydropower regulated Lule) discharging into the Gulf of Bothnia, the major impacts of regulation on water discharge, element transport and their seasonal redistribution have been assessed. The pre-regulation hydrogeochemical features were assumed to be similar for the two rivers. For the Lule River, the average maximum runoff was almost halved, while the average minimum was tripled as a result of the regulation. The fraction of winter transport of total organic carbon (TOC), Fe, Si, suspended Mn and P in the Lule River was, according to a conservative estimate, two to three times higher than in the pristine river. Longer residence time in the Lule River delayed arrival of the suspended Mn peak and dissolved Si decline to the river mouth. During summer, the suspended C/N ratio in the regulated river was 10–20 compared to <10 for the pristine, suggesting presence of predominantly old organic material. This was supported by a virtually constant suspended P/Fe ratio throughout the year in the Lule River, indicating low abundance of phytoplankton. TOC varied irregularly in the Lule River suggesting temporal disconnection between the river and the upper riparian zone. The disappearance of the spring flow maximum, a shift of element transport from spring to winter and supply of mainly old organic material during the vegetation growth season may have a pronounced impact on the ecosystem of the Gulf of Bothnia and the river itself. 相似文献
3.
Larisa Pekka Johan Ingri Anders Widerlund Olga Mokrotovarova Margarita Riabtseva Bjrn
hlander 《Applied Geochemistry》2004,19(12):62
The Kola River in the northern part of the Kola Peninsula, northwestern Russia, flows into the Barents Sea via the Kola Bay. The river is a unique place for reproduction of salmon and an important source of drinking water for more than 500,000 people in Murmansk and the surrounding municipalities. To evaluate the environmental status of the Kola River water, sampling of the dissolved (<0.22 μm) and suspended (>0.22 μm) phases was performed at 12 sites along the Kola River and its tributaries during 2001 and 2002. Major (Ca, K, Mg, Na, S, Si, HCO3 and Cl) and trace (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sr, Ti, and Zn) elements, total and particulate organic C (TOC and POC), N and P were analysed. Comparison with the boreal pristine Kalix River, Northern Sweden, shows that, except for Na, Cl, Al, Cu and Ni, which exceed the concentrations in the Kalix River by as much as 2–3 times, the levels of other major and trace elements are close to or even below the levels in the Kalix River. However, the results also demonstrate that pollutants from the three major sources: (1) the Cu–Ni smelter in Monchegorsk, (2) the open-pit Fe mine and ore concentration plant in Olenegorsk, and (3) the Varlamov, the Medveziy and the Zemlanoy creeks, draining the area of the large agricultural enterprises in the lower part of the watershed, have a major influence on the water quality of the Kola River. 相似文献
4.
Frequent sampling during an annual cycle of dissolved(<0.45 m) and suspended (>0.45 m) elementshas been conducted in the Kafue River at Raglan'sFarm, upstream from the mining activities within theCopperbelt Province, Zambia. Additional sampling ofsediment and interstitial pore water was conductedduring low water discharge. The presence of carbonateswithin the drainage basin naturally gives rise to highelement concentrations in the dissolved phase(Ca = 626, Mg = 494, Na = 360 and K = 24 mmol l-1).During the rainy season the relative composition ofthe dissolved elements indicated a wash out ofaccumulated weathering products and mineralisedorganic material from the unsaturated zone of the soilprofile. High concentrations of dissolved Al, Fe andMn were measured during high water discharge. At lowwater discharge the sediment was a major source of Fe,Mn and associated Co and Cu to the water column.Enhanced concentrations of dissolved and suspended S,Co and Cu during the rainy season indicated thatatmospheric deposited particles from the mining areawere washed out into the river. Autochthonousformation of particles rich in Si indicated diatomproduction during low water discharge. 相似文献
5.
贵州喀斯特地区河流的研究--碳酸盐岩溶解控制的水文地球化学特征 总被引：41，自引：1，他引：40
测量了喀斯特地区乌江、沅江两大水系的河流枯水期的主元素、Sr2+离子浓度和Sr同位素比值。这些河流的化学组成代表了流经碳酸盐岩地层的河水的化学组成。这些河流及其支流有高的溶解盐,TZ+变化范围为：2.1～6.3 meq/L,高于全球河流的平均值(TZ+=0.725 meq/L)。河水含有较高的溶质浓度,河水水化学组成以Ca2+和HCO-3为主,其次为Mg2+和SO2-4,Na++K+和Cl-+Si分别只占阳离子和阴离子组成的5%～10%。
这些河流的化学和同位素组成主要受其自流盆地的地质特征控制。流经碳酸盐岩地层的乌江水系河流具有较高的Sr浓度（1.1～9.70 mol/L）和较低的87Sr/86Sr比值（0.7077～0.7110）,与流经碎屑岩地层的沅江水系的清水江河流中较高的87Sr/86Sr比值（0.7090～0.7145）及较低的Sr浓度（0.28～1.32 mol/L）形成鲜明的对比。
流域盆地的地理岩性控制了河水的化学组成和同位素组成。对河水的化学计量分析表明河水化学组成受碳酸盐岩溶解控制,而碳酸盐岩主要受碳酸和硫酸作用而溶解。乌江流域受硫酸作用特别明显,表明硫酸主要来源于燃煤或流域盆地硫化物矿物氧化而形成的大气输入。化学元素和同位素比值之间的相互关系表明3个主要来源为：石灰岩、白云岩和硅酸盐岩的风化。同时估计了碳酸盐岩和硅酸盐岩的化学风化速率,结果表明流域盆地的碳酸盐岩风化速率远远高于许多世界大河。岩石风化过程中硫酸的出现或土地的过度使用或土壤植被的退化等都可能是导致流域的碳酸盐岩风化速率如此高的原因。 相似文献
6.
Abstract: The aim of this study undertaken at Lake Muhazi in Rwanda was to determine and analyze the major elements present in water. ?The presence of many major elements (Al, As, Ba, C, Ca, Cu, Fe, H+, K, Mg, Mn, N, P, S, Si, and Zn) was determined by spectroscopic technique. The concentrations of the elements were measured in water samples taken from three different locations of the lake from May to August 2008. The lake is polluted by water flow from mountain sides surrounding the lake. Other causes of pollution could be the use of agrochemicals in the sugar land, which surrounds the lake, and human activities near the lake. Finally, we proposed the strategies that can be applied in order to ensure good conservation of the environment and to prevent augmentation of heavy materials into the lake. 相似文献
7.
Reidar G. Trnnes 《Lithos》2000,53(3-4):233-245
Melting experiments were performed on an FeO-rich bulk Earth model composition in the CMFAS system in order to investigate the partitioning of major elements between coexisting minerals and melts. The starting material (34.2% SiO2, 3.86% Al2O3, 35.2% FeO, 25.0% MgO and 1.88% CaO), contained in Re-capsules, was a mixture of crystalline forsterite and fayalite, and a glass containing SiO2, Al2O3, and CaO. Olivine is the first liquidus phase at 10 GPa but is replaced by majoritic garnet (ga) in the 15–26 GPa range. Magnesiowüstite (mw) crystallizes close to the liquidus and is joined by perovskite (pv) at 26 GPa.
The quenched melt compositions are homogeneous throughout the melt region of the charges and are only slightly enriched in Si, Ca and Fe, and depleted in Mg, relative to the starting composition. The Fe/Mg and Ca/Al ratios in all of the minerals increase rapidly below the liquidus to become compatible with the bulk composition at the solidus. At 26 GPa, a relative density sequence of mw>pv>melt>ga is observed. This indicates that majorite floating, combined with the sinking of magnesiowüstite and perovskite can be expected during the solidification of a Hadean magma ocean and in hot mantle plumes early in the Earth's history. The mineral–melt partitioning relations indicate that fractional crystallization or partial melting in the transition zone and the upper part of the lower mantle would increase the Fe/Mg and Ca/Al ratios of the melt, even if magnesiowüstite was predominant in the solid fraction. A significant contribution of accumulated mw to the segregation of the protocore is therefore unlikely. The suggested process of perovskite fractionation to the lower mantle is not capable of increasing the Mg/Si ratio in the residual melt, and the combined fractionation of perovskite and magnesiowüstite produces a melt with elevated ratios of Si/Mg, Ca/Al and Fe/Mg. 相似文献
8.
Geochemistry,dissolved elemental flux rates,and dissolution kinetics of lithologies of Alaknanda and Bhagirathi rivers in Himalayas,India 总被引：1，自引：1，他引：0
Alaknanda and Bhagirathi (AB) river basins in the Himalayan region in India expose lithologies comprising mainly of granites,
low–high-grade metamorphics, shales and carbonates which, in conjunction with the monsoon rains and glacial melt, control
water chemistry and dissolved elemental flux rates. In the present study, we monitored two locations: (a) Srinagar on the
Alaknanda river and (b) Maneri on the Bhagirathi river for daily variations in total suspended sediments, major ions and dissolved
silica over one complete year (July 2004–June 2005). Based on long-term discharge data, discharge-weighted composition and
dissolved elemental flux rates (with respect to Ca, Mg, HCO3, Si) of the river were estimated. The information thus obtained has substantially added up to the existing chemical data
of these rivers and has refined the flux rates. Our high-frequency samples provide informations such as (a) water chemical
compositions that show a large temporal and spatial variation and (b) carbonate lithology that controls water chemistry predominantly.
The dissolution kinetics of various lithologies namely leucogranite, gneiss, quartzite, phyllite and shale of the AB river
basins were studied through batch experiments at controlled temperature (25 and 5°C) and pH (8.4) condition. In laboratory,
these lithologies undergo slow rates of dissolution (10−13 to 10−15 mol/m2 s), while field weathering rates based on dissolved elemental flux rates in the AB rivers are much higher (10−8 to 10−9 mol/m2 s). Extremely high physical weathering rates in AB rivers, which enhance chemical weathering significantly, mainly attribute
this wide discrepancy in laboratory-derived rates of representative basin rocks and dissolved elemental fluxes in the field.
However, laboratory-simulated experiments facilitate to quantify elemental release rates, understand the kinetics of the dissolution
reactions, and compare their roles at individual level. 相似文献
9.
雅鲁藏布江丰水期河水离子组成特征及其控制因素 总被引：1，自引：0，他引：1
为了解雅鲁藏布江丰水期河水离子组成特征及其控制因素,利用2015年采集的8个河水水样,运用数理统计、聚类分析、Piper三线图、Gibbs模型以及离子比值等方法,分析了雅鲁藏布江丰水期河水水化学特征,并探讨了其主要控制因素。结果表明：河水中阳离子以Ca2+、Mg2+为主,阴离子则以HCO3-和SO42-为主,阴、阳离子分别约占其总量的96%和85%。河水水化学类型均为HCO3·SO4-Ca·Mg型。TDS含量介于202.46~371.27 mg·L-1,均值为299.30 mg·L-1,较世界河流平均值高。自上至下,河水水化学特征表现出一定的差异性,河水中主要离子以及TDS、TH、EC的含量沿程表现出下降的趋势,其原因主要有支流河水汇入和降水增加的稀释作用。河水水样均落在Gibbs模型图中部偏左,表明河水中主要离子化学组分主要受水岩作用控制。离子比值法分析表明研究区碳酸盐岩以及蒸发岩的风化溶解是河水水化学的主要控制因素,且存在硅酸盐类矿物的风化。 相似文献
10.
Philippe Négrel 《Aquatic Geochemistry》1999,5(2):125-165
A small watershed (89 km2) underlain by granite or granite-gneiss in the Margeride mountains, southern Massif Central (France),
has been studied using the chemical and isotopic composition of its dissolved load, bed sediments and soils. Dissolved concentrations
of major ions (Cl, SO4, NO3, HCO3, Ca, Na, Mg, K, Al and Si), trace elements (Rb and Sr) and strontium isotopes have been
determined for three different hydrologic periods in the main stream of the Desges river and its tributaries.
The aim was to characterize the chemical and isotopic signatures of each reservoir in the watershed; signature changes are
interpreted as fluctuations in the different influencing components: rainwater, weathering products and anthropogenic addition.
In the study area, as in other watersheds in granite environments, the only source for input of chemical species into the
dissolved load at high altitude is chemical weathering and atmospheric deposition, whereas at lower altitude, human influence
plays a non-negligible role.
As precipitation is a major vehicle for the addition of dissolved chemical species into the hydrosystem, a systematic rainwater
study using an automatic collector was carried out over one year in order to better constrain rain elemental input. Corrections
for rainwater addition, using chloride as an atmospheric-input reference, were computed for selected elements and for 87Sr/86Sr
ratios. After these correction, the geochemical budget of the watershed was determined and the role of anthropogenic addition
was evaluated based on strontium isotope relationships.
For particulate matter, we used the normalization of chemical species relative to parent rocks and the element ratios which
reflect the depletion or enrichment in soils and sediments. Both the immobile- and mobile-element approaches have been tested,
using Ti/Zr and La/Ce ratios for the former and Ca/Sr, K/Rb, and K/Fe ratios for the latter.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
11.
High-pressure melting experiments were performed at ~26 GPa and ~2,200–2,400°C on synthetic peridotite compositions with varying FeO and Al2O3 contents and on a synthetic CI chondrite analogue composition. Peridotite liquids show a crystallisation sequence of ferropericlase (Fp) followed down temperature by Mg-silicate perovskite (MgPv) + Fp, which contrasts a sequence of MgPv followed by MgPv + Fp observed in the chondritic composition. The difference in crystallisation sequence is a consequence of the different bulk Mg/Si ratios. MgPv/melt partition coefficients for major, minor and trace elements were determined by electron microprobe and secondary ion mass spectrometry. Partition coefficients of tri- and tetravalent elements increase with increasing Al concentration in MgPv. A lattice strain model indicates that Al3+ substitutes predominantly onto the Si-site in MgPv, whereas most elements substitute onto the Mg-site, which is consistent with a charge-compensating coupled substitution mechanism. MgPv/melt partition coefficients for Mg (DMg) and Si (DSi) are related to the melt Mg/Si ratio such that DSi becomes lower than DMg at low Mg/Si melt ratios. We use a crystal fractionation model, based on upper mantle refractory lithophile element ratios, to constrain the amount of MgPv and Ca-silicate perovskite (CaPv) that could have fractionated during a Hadean magma ocean event and could still be present as a chemically distinct heterogeneity in the lower mantle today. We show that a fractionated crystal pile composed of 96% MgPv and 4% CaPv could comprise up to 13 wt% of the entire mantle. 相似文献
12.
13.
The lower reaches of the Coatzacoalcos River in southeast Mexico is an area of intense industrial development. The physico-chemical characteristics of the area have exhibited differences over the years. Apparently from the associated outcroppings of limestone in the Uxpanapa River Basin, the major elements that are dissolved show higher concentrations of Ca, Mg and HCO3– in the waters supplied by this river. The water in the Calzadas River contains high concentrations of Ca, SO4 and HCO3– that are associated with the saline domes crossed by this river. Due to industrial discharges, the sulfate concentration is very high in the water and air during April. Nitrate concentration diminishes with salinity. Higher nitrate as well as nitrite and ammonia levels are present during flood season. Phosphate concentration, associated with high oxygen levels, is higher in January. Zn, Cu and Cr are higher during the dry season (April) when dilution is minimal and low levels of TOC are present. The smaller concentrations of Zn and Cu observed in January are associated with high TOC values in water. The lower levels of Cr present in August are associated with high amounts of suspended matter. Pajaritos Lagoon and Teapa-L, with large industrial discharges, have the highest nutrient and dissolved metal concentrations in the area. Air particles smaller than 2.5 m contain Fe, V, Ti, Cu, Zn, and high amounts of S. These anomalous concentrations of sulfates and metals are attributed to anthropogenic sources. 相似文献
14.
Uraniferous waters of the Arkansas River valley,Colorado, U.S.A.: a function of geology and land use
《Applied Geochemistry》1995,10(2):133-144
The effect of local geology and land-use practices on dissolved U was investigated by analysis of surface water and some springs in the Arkansas River valley of southeastern Colorado. Water samples were collected during a 2 week period in April, 1991. The rate of increase of U concentration with distance downriver increased markedly as the river flowed from predominantly undeveloped lands underlain by igneous and metamorphic rocks to agriculturally developed lands underlain by marine shale and limestone. An additional abrupt increase in dissolved U was observed along the section of river where discharge is often greatly reduced because of extensive diversions for irrigation and where remaining flow is largely composed of irrigation return water. Dissolved U in this last section of river and in most of its tributaries exceeded the proposed U.S. drinking water standard of 20 μ/L In water samples collected from agricultural areas dissolved U showed strong positive correlation with major dissolved constituents Na, Ca, Mg, and SO4 that increase as a result of sulfate mineral dissolution and clay mineral ion-exchange reactions in weathered shale bedrock and shaley soils. Highly soluble minor and trace elements Cl, Li, B, Sr, and Se that are not subject to strong sorptive uptake or precipitation in this setting also correlated positively with U. These combined observations indicate that natural leaching of U-bearing shale bedrock and derivative soils, additional leaching of rock and soil by irrigation water, and evaporative concentration in a semi-arid climate can produce concentrations of dissolved U in surface water and shallow ground water that may threaten nearby drinking water supplies. Other agriculturally developed areas of the semi-arid Western U.S. with similar geology are likely to contain high concentrations of U in irrigation drain water. 相似文献
15.
格尔木河222Rn同位素变化及其对地表水-地下水交互关系的指示意义 总被引：2，自引：0，他引：2
我国西北内陆干旱区水资源匮乏,生态环境脆弱,在全球气候变化和人类活动干扰背景下,采用同位素方法进行精细尺度地表水-地下水交互作用研究是探求当地水循环变化和水资源管理的基本要求。通过测量格尔木河流域河水、地下水样品2019年5月和8月的222Rn浓度和典型断面流量,结果发现：山区河段河水222Rn浓度最高,平均值为948.72 Bq·m-3,指示基岩裂隙水是山区河段重要补给来源;山前冲洪积扇河水222Rn浓度最低,平均值为76.71 Bq·m-3,地下水补给较少;溢出带地区河水222Rn浓度上升至平均676 Bq·m-3,地下水溢出补给河水,向下至细土平原,河水222Rn浓度呈下降趋势。时间变化上,8月与5月相比,河水222Rn浓度下降,表明地下水补给减少。溢出带S1~S2河段河水与地下水交互关系以双向转化为主,基于质量守恒原理计算河水与地下水交互通量,5月和8月累积河水渗漏通量分别为3.87 m3?s-1和0.9 m3?s-1,地下水补给通量分别为0.51 m3?s-1和0.47 m3?s-1,河水渗漏强度大于地下水补给,二者交互通量存在时空差异。 相似文献
16.
Patrick Ollivier Olivier Radakovitch Bruno Hamelin 《Journal of Geochemical Exploration》2006,88(1-3):394
Dissolved major and trace element concentrations were determined from November 2000 to December 2003 in the lower Rhône River (France). Subsurface water samples were collected about twice a month and more regularly during flood events. An unusual trend was observed for As, Sb, Ni and Ba concentrations which increased with river discharge at the beginning of the floods, in contrast with other elements. Variations of Sb/Na and As/Na molar ratios show that it is related to higher contributions of waters from western tributaries of the Rhône River enriched in As, Sb, Ni and Ba due to ancient mining activities. These unusual variations of dissolved element concentrations are thus interpreted as mark of a water mass origin within the watershed. 相似文献
17.
Wei Xu Xiaosi Su Zhenxue Dai Fengtian Yang Pucheng Zhu Yong Huang 《Hydrogeology Journal》2017,25(7):2015-2029
Environmental tracers (such as major ions, stable and radiogenic isotopes, and heat) monitored in natural waters provide valuable information for understanding the processes of river–groundwater interactions in arid areas. An integrated framework is presented for interpreting multi-tracer data (major ions, stable isotopes (2H, 18O), the radioactive isotope 222Rn, and heat) for delineating the river–groundwater interactions in Nalenggele River basin, northwest China. Qualitative and quantitative analyses were undertaken to estimate the bidirectional water exchange associated with small-scale interactions between groundwater and surface water. Along the river stretch, groundwater and river water exchange readily. From the high mountain zone to the alluvial fan, groundwater discharge to the river is detected by tracer methods and end-member mixing models, but the river has also been identified as a losing river using discharge measurements, i.e. discharge is bidirectional. On the delta-front of the alluvial fan and in the alluvial plain, in the downstream area, the characteristics of total dissolved solids values, 222Rn concentrations and δ18O values in the surface water, and patterns derived from a heat-tracing method, indicate that groundwater discharges into the river. With the environmental tracers, the processes of river–groundwater interaction have been identified in detail for better understanding of overall hydrogeological processes and of the impacts on water allocation policies. 相似文献
18.
Hydrogeochemistry and environmental tracers (2H, 18O, 87Sr/86Sr) in precipitation, river and reservoir water, and groundwater have been used to determine groundwater recharge sources, and to identify mixing characteristics and mineralization processes in the Manas River Basin (MRB), which is a typical mountain–oasis–desert ecosystem in arid northwest China. The oasis component is artificial (irrigation). Groundwater with enriched stable isotope content originates from local precipitation and surface-water leakage in the piedmont alluvial–oasis plain. Groundwater with more depleted isotopes in the north oasis plain and desert is recharged by lateral flow from the adjacent mountains, for which recharge is associated with high altitude and/or paleo-water infiltrating during a period of much colder climate. Little evaporation and isotope exchange between groundwater and rock and soil minerals occurred in the mountain, piedmont and oasis plain. Groundwater δ2H and δ18O values show more homogeneous values along the groundwater flow direction and with well depths, indicating inter-aquifer mixing processes. A regional contrast of groundwater allows the 87Sr/86Sr ratios and δ18O values to be useful in a combination with Cl, Na, Mg, Ca and Sr concentrations to distinguish the groundwater mixing characteristics. Two main processes are identified: groundwater lateral-flow mixing and river leakage in the piedmont alluvial–oasis plain, and vertical mixing in the north oasis plain and the desert. The 87Sr/86Sr ratios and selected ion ratios reveal that carbonate dissolution and mixing with silicate from the southern mountain area are primarily controlling the strontium isotope hydrogeochemistry. 相似文献
19.
The concentration of dissolved Ba in a number of rivers having their drainage almost entirely in Deccan Trap basalts has been
measured. These results along with available data on the abundances of major elements in these waters, and on Ba and major
elements in bed sediments of these rivers provide a measure of (i) the relative mobility of Ba during chemical weathering
and erosion of basalts, particularly with respect to alkaline earths, Mg, Ca and Sr, and (ii) the flux of Ba out of the Deccan
and its global significance. The concentration of dissolved Ba ranges from 8 to 105 nM. The average Ba/Mg*, Ba/Ca* and Ba/Sr
(* is concentration corrected for atmospheric contribution) in waters is lower than the corresponding mean ratios in Deccan
basalts, though they overlap within errors. Majority of the water samples, however, have ratios less than that in basalts.
These findings can be interpreted as a cumulative effect of limited release/mobility of Ba during chemical weathering and
erosion of basalts and its reactive behaviour in waters which promote its association with clays and oxy-hydroxides of Fe.
These results also indicate that during chemical erosion of Deccan basalts, Ba is the least mobile among the alkaline earth
elements. The abundance of Ba in sediments and their Ba/Al ratios relative to basalts are consistent with the above conclusion.
Ba/Mg and Ba/Ca ratios in water and in sediments from the same location are strongly correlated; however, the mean ratios
in waters are far less than those in sediments. This is a result of limited Ba mobility, effectively 5–6 times lower than
that of Mg. The annual flux of dissolved Ba out of the Deccan Traps is ~1 × 107 moles, ~ 0.2% of its global riverine transport to oceans. The contribution of dissolved Ba from Deccan Traps, seem lower
than its aerial coverage, ~ 0.5% of the global drainage area; the potential causes for this could be the lower abundance of
Ba in basalts relative to “average continental crust”, and its behaviour during chemical weathering and erosion. 相似文献
20.
《Applied Geochemistry》2004,19(11):1745-1758
In order to reveal the intra-annual variability of the major ion composition of the Pilcomayo river, a dryland river, and its relationship to discharge, water samples were taken at regular time intervals from May 1998 until February 1999 at the town of Villa Montes (Bolivia). Water chemistry of the Pilcomayo river was highly variable during the year and strongly influenced by differences in discharge between the wet and the dry season. Halite dissolution appeared to play an important role and both Cl and Na concentrations became very high (±10 mmol L−1) during the dry season. Pyrite weathering and dissolution of gypsum, dolomite and calcite determined Ca, Mg, CO3 and SO4 chemistry. At the onset of the rainy season `rinse out' effects occurred, resulting in marked concentration peaks especially for the least soluble ions. Possible effects on biota, such as consequences for trace metal toxicity, are discussed briefly. 相似文献