共查询到20条相似文献，搜索用时 777 毫秒
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Astronomy Reports - Improvement of the prediction accuracy of the Earth’s rotation parameters (ERP) is one of the main problems of applied astrometry. In order to solve this problem, various... 相似文献
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Turchanina Oksana Satin Vladimir Derevyanko Aleksey 《中国地球化学学报》2006,25(B08):51-52
As is well known, a high content of sulphur in coals is an effect of the post-depositional history of coal seams and one of the most important criteria of its use as a fuel. Sulphur in coals can cause a serious environmental and technological problem during their utilization. This problem is very actual for the Donetsk Basin because 734 mined seams out of the total of 1009 （73%） are comprised of coals with sulphur content -2%. The chemical pre-treatment as a first stage in their processing is widely used in order to effectively obtain the thermal destruction products of coals （such as semi-coke, coke, adsorbents, etc.） and to simultaneously utilize coal wastes. Development in pre-treatment methods for high-sulphur, low-rank coals is especially desirable for reducing the sulphur contents of the solid products. The aim of the present work is to investigate the influence of coal pre-treatment on the yield and composition of thermal destruction products, and the sulphur distribution among different components of the coals of different genetic types by reductivity （low-reduced LRC and reduced RC coals）. The thermal behavior of the coals was studied by means of the Fisher method （heated to 520℃, at a rate of 7℃/min）. The composition of the semi-coking gas was investigated by means of a VTI gas analyzer. The coal samples were chemically treated directly before thermal destruction by the introduction of 1-% solutions of radical polymerization initiator AAD （acrylic acid dinitrile C8H12N4） and products of coal-tar distillation （absorber oil）. Coal pre-treatment increases the semi-coke yield and its coking ability, and changes the liquid/gaseous product ratio. 相似文献
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Yoko Shimamoto Yoshio Takahashi 《中国地球化学学报》2006,25(B08):114-114
Although inorganic species are predominant in natural systems, but there are many kinds of organoarsenic species such as methylated and phenylated arsenic compounds. Phenylarsonic acid （PA） is a degradation product of organoarsenics used for chemical warfare agents, which has been detected in well water at the disposal site of the agents in Japan. There are few reports studying behavior of PA in soil. In this study, PA was adsorbed onto ferrihydrite and its chemical forms were determined using high performance liquid chromatography connected to inductivity-coupled plasma mass spectrometry （HPLC-ICP-MS）. 100 mg/kg of PA was mixed with 0.03 g of 2-line ferrihydrite. For each suspension, pH was adjusted by HNO3 or NaOH. Each sample was incubated for more than 19 hours and the final pH was measured. After filtration, the chemical form of arsenic in the filtrate was measured using HPLC-ICP-MS. In addition, ferrihydrite separated by filtration was dissolved by 3 ml of 0.5 M HCI and the arsenic species in the solution was detected by HPLC-ICP-MS （column： Tosoh TSKgel SuperlC-AP, eluent： 0.01 M HNO3）. It was verified that PA is not degraded by heating in 0.5 M HCl solution. At pH 3.1, any arsenic compounds were not detected from the solution, because almost all arsenic species were adsorbed onto ferrihydrite at lower pH. At pH= 12, however, 7%-10% of inorganic arsenic was detected in the solution. In solid phase, there are some problems to determine the precise ratio of inorganic and organic species. When the solution includes Fe ion at 0.01 M level, the retention time of arsenic species drifted compared to those in standard solution, which makes it difficult to determine precisely the arsenic species adsorbed on ferrihydrite. Therefore, more study is needed to determine the ratio of inorganic and organic species in the system. 相似文献
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Zeng Zuoxun Faculty of Earth Sciences China University of Geosciences Wuhan Li Sitian Yang Shigong Faculty of Earth Resources China University of Geosciences Wuhan Liu Lilin Fu Yongtao Faculty of Earth Sciences China Univers 《中国地质大学学报(英文版)》1997,(1)
ＴｈｒｅＤｉｍｅｎｓｉｏｎａｌＭｏｄｅｌｉｎｇｏｆＥｆｅｃｔｏｆＩｎｄｉａ┐ＥｕｒａｓｉａＣｏｌｉｓｉｏｎ＊ＺｅｎｇＺｕｏｘｕｎＦａｃｕｌｔｙｏｆＥａｒｔｈＳｃｉｅｎｃｅｓ，ＣｈｉｎａＵｎｉｖｅｒｓｉｔｙｏｆＧｅｏｓｃｉｅｎｃｅｓ，Ｗｕｈａｎ４３００... 相似文献
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Zonal distribution of seepage hydrocarbon-induced altereb carbonates over oil/gas reservoirs is a common phenomenon observed in the field.The authors considered that the continuous production of CO2 within the “alteration chimney ”gives rise to a significant difference in physical and chemical properties between its interior and the surrounding country rocks.And it is this difference that has promoted the erosion and precipitation of carbonates,thus leading to the zonal distribution of seepage hydrocarbon-induced altered carbonates over oil/gas reservoirs.This may be a reasonable interpretation of the phenomenon described above. 相似文献
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Doklady Earth Sciences - The influence of variations in fo-, fa-, en-, fs-, di-, an-, and ab-components in a high-Mg basaltic melt on the topology of the spinellide liquidus was analyzed using the... 相似文献
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Vesignieite, Cu_3Ba(VO_4)_2(OH)_2, crystallizes in space group C_2 / m with a°=1.0270(2), b°=0.5911(1),c°=0.7711(2)nm and β=116.42(3)°. The intensity data were collected with the RIGAKU RASA-IISsingle-crystal four-circle diffractometer. The structure was determined by Patterson and Fourier methods andrefined by the least-square technique to a final R index of 0.051 for 614 independent diffraction points with|F? |>3σ|F?|. The crystal structure analysis shows that vesignieite has a layer structure parallel to (001). The powder diffraction lines were reindexed. 相似文献
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Abstract A new selected area electron diffraction (SAED) pattern was found from Fe‐illite. The lattice of the ED pattern can be described as a compound tessellation of (3,6)[79{3,6}], which is based on a large coincidence‐site lattice (CSL) with oriented crystal associations rotated by a non‐crystallographic angle 26°. This phenomenon corresponds to the plesiotwinning of Fe‐illite and has been never reported in the nature so far. 相似文献
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This paper deals with a simulated test of biogenic mineralization made with a blue-green alga species,Spirulina platensix. The data in the experiment were recorded by a computerized surveying system. The influ-ence of algae on the accumulation of phosphorus by changing their microenvironment to promote the forma-tion and deposition of phosphate was studied. The results show that the pH value of cultural liquor rose up to 10 and the redox potential (Eh) may dropby 100-200 mV during the algal logarithmic growth stage, and the cultrual liquor was changed into a mediumwith a weakly reducing condition. At the end of the logarithmic growth stage white deposits of Na_2Ca(CO_3)_2·5H_2O and Ca_2Mg (PO_4)_2·2H_2O were formed on the floor of cultural containers. The test presented a wduableevidence for the theory of biogenic mineralization. 相似文献
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Wang Ende Shenyang Institute of Gold Technology Shenyang Liaoningand Guan Guangyue Northeast U niversity of Technology Shenyang Liaoniny 《《地质学报》英文版》1994,68(1):31-42
The bacteria used in the experiment are Thiobacillus Ferrooxidans separated from acidic mine water in sulphide deposits. The chemoautotrophic bacteria can act directly on sulphides and accelerate the oxidation of sulphides. The experiment shows that the bacteria, as an important microbial factor of gold's supergenous enrichment within the oxidized zones of sulphide deposits, are helpful to dissolve gold and silver in ferric sulphate. In the bacterial oxidation process, the precipitation of goethite is concerned both with the lower activity of ferric ions and with the existence of carbonates in solution. Meanwhile, the acid-resisting and oxidizing ability of the bacteria will certainly lead up to a microbial way of treating the acidic mine water. 相似文献
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Yang Wunian Zhu Zhangsen Institute of Remote Sensing GIS Chengdu University of Technology Chengdu Sichuan Liu Xinzhu Yang Wencai 《《地质学报》英文版》1997,71(3):344-354
The structural feature shown on a remote sensing image is a synthetic result ofcombination of the deformations produced during the entire geological history of an area.Therefore, the respective tectonic stress field of each of the different stages in the complexdeformation of an area can be reconstructed in three steps: (1) geological structures formed atdifferent times are distinguished in remote sensing image interpretation; (2) structuraldeformation fields at different stages are determined by analyzing relationships betweenmicrostructures (joints and fractures) and the related structures (folds and faults); and (3)tectonic stress fields at different stages are respectively recovered through a study of the featuresof structural deformation fields in different periods. Circular structures and related circlular and radial joints are correlated in space to con-cealed structural rises. The authors propose a new method for establishing a natural model ofthe concealed structural rises and calculating the tectonic stress field by using quantitative dataof the remote sensing information of circular structures and related linear structures. 相似文献
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G. Makharadze G. Supatashvili T. Makharadze 《International Journal of Environmental Science and Technology》2018,15(10):2165-2168
Natural macromolecular organic substances—fulvic acids—take an active part in complex formation processes and stipulate migration forms of heavy metals in natural waters. In spite of researches, experimental data on stability constants of complex compounds of fulvic acids with heavy metals (among them zinc) are heterogenous and they differ in several lines from each other. One of the reasons of such condition is ignoring an average molecular weight of the associates of fulvic acids, which finally causes the wrong results. Complex formation process between zinc (II) and fulvic acids was studied by the solubility method at pH = 8.0. ZnO suspension was used as a solid phase. Fulvic acids were isolated from Paravani lake by the adsorption chromatographic method. This article shows that during the complex formation process, every 1/5 part of an associate of fulvic acids inculcates into zinc’s (II) inner coordination sphere, as an integral ligand. So it may assume that the average molecular weight of the associate of fulvic acids which takes part in complex formation process equals to 1252. This part of the associate of fulvic acids was conventionally called an “active associate.” The average molecular weight of the “active associate” was used for determining the composition of zinc fulvate complex, the concentration of free ligand and stability constant, which equals to \(1.6 \times 10^{4}\). 相似文献
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Martin J.S. Rudwick 《《幕》》2008,31(3):363-366
Bursting the Limits of Time by the distin- guished historian of geology Martin Rudwick is a massive, two-part book. The first part contains what he calls a synchronous history of what eventually became historical geology in western Europe between the time of de Sans- sure＇s epoch-making ascent of Mont Blanc in 1787 and the discovery of the Kirkdale hyaena cave by Buckland in the winter of 1821-1822, 相似文献
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XU Lin LIN Yangting WANG Shijie OUYANG Ziyuan Key Laboratory of the Study of Earth’s Deep Interior Institute of Geology Geophysics Chinese Academy of Sciences Beijing China National Astronomical Observatories Beijing China Institute of Geochemistry Guiyang China 《中国地球化学学报》2009,28(3):271-278
Bulk compositions of metallic Fe-Ni from two equilibrated ordinary chondrites, Jilin (H5) and Anlong (H5), and two unequilibrated
ones, GRV 9919 (L3) and GRV 021603 (H3), were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). The CI-,
Co-normalized abundances of siderophile and chalcophile elements of metallic Fe-Ni from the unequilibrated ordinary chondrites
correlate with 50% condensation temperatures (i.e., volatility) of the elements. The refractory siderophile elements (i.e.,
platinum group elements, Re), Au, Ni and Co show a flat pattern (1.01×CI Co-normalized), while moderate elements (As, Cu,
Ag, Ga, Ge, Zn) decrease with volatility from 0.63×CI (Co-normalized, As) to 0.05×CI (Co-normalized, Zn). Cr and Mn show deficit
relative to the trend, probably due to their main partition in silicates and sulfides (nonmagnetic). Metallic Fe-Ni from the
equilibrated ordinary chondrites shows similar patterns, except for strong deficit of Cr, Mn, Ag and Zn. It is indicated that
these elements were almost all partitioned into silicates and/or sulfides during thermal metamorphism. The similar deficit
of Cr, Mn, Ag and Zn was also found in iron meteorites.
Our analyses demonstrate similar behaviors of W and Mo as refractory siderophile elements during condensation of the solar
nebula, except for slight depletion of Mo in the L3 and H5 chondrites. The Mo-depletion of metallic Fe-Ni from GRV 9919 (L3)
relative to GRV 021603 (H3) could be due to a more oxidizing condition of the former than the latter in the solar nebula.
In contrast, the Mo-depletion of the metallic Fe-Ni from the H5 chondrites may reflect partition of Mo from metal to silicates
and/or sulfides during thermal metamorphism in the asteroidal body. 相似文献