共查询到20条相似文献，搜索用时 31 毫秒
1.
Patrick A. Carr Emeline Moreira Leonid Neymark Marc D. Norman Julien Mercadier 《Geostandards and Geoanalytical Research》2023,47(1):67-87
Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is used to compare the suitability of four cassiterite (SnO2) materials (SPG, Yankee, AY-4 and Jian-1), and three matrix-mismatched reference materials (NIST SRM 612, NIST SRM 614 and 91500 zircon) for normalisation of U-Pb and Pb-Pb isotope ratios in cassiterite. The excess variance of ages determined by LA-ICP-MS is estimated to be ±0.33% for 207Pb/206Pb vs. 208Pb/206Pb isochron ages and ± 1.8% and for U-Pb ages. Incorporation of this excess variance in cassiterite ages is necessary for realistic uncertainties. 207Pb-206Pb ages are advantageous for dating Precambrian cassiterite such as SPG compared with U-Pb ages as matrix effect on instrumental mass fractionation of Pb isotopes are generally considered to be minor. We note minor bias in 207Pb/206Pb vs. 208Pb/206Pb isochron ages (~ 0.6%) when using either the NIST SRM 614 or 91500 zircon reference materials and emphasise the requirement for uncertainty propagation of all sources of error and reference materials with comparable U and Pb mass fraction to the cassiterite. The 238U/206Pb isotopic ratios from normalisation to matrix-mismatched reference materials show varied results, which emphasises the need to use matrix-matched reference materials for calculating U-Pb ages. When cross-calibrated against each other, LA-ICP-MS U-Pb ages of the ca. 1535 Ma SPG, ca. 245 Ma Yankee and ca. 155 Ma Jian-1 cassiterites are all consistent with their ID-TIMS values. 相似文献
2.
Lu Xiang Rucheng Wang Rolf L. Romer Xudong Che Huan Hu Zhimin Tang 《Geostandards and Geoanalytical Research》2023,47(3):609-628
Columbite-tantalite LA-ICP-MS U-Pb dating is a fast and useful method to determine the age of rare-metal deposits and fingerprint the provenance of columbite-tantalite ore concentrates. Accurate LA-ICP-MS U-Pb dating requires matrix-matched reference materials. We analysed three columbite-tantalite samples (SN3, HND and RL2) from China using ID-TIMS and LA-ICP-MS to assess their potential as reference materials for in situ U-Pb dating. Coltan 139 and these three columbite-tantalite samples with variable compositions yielded internally consistent LA-ICP-MS U-Pb ages when using each other for calibration and the weighted mean 206Pb/238U ages are comparable to respective ID-TIMS ages. Composition-dependent U-Pb fractionation seems to be insignificant under the LA-ICP-MS conditions used. Sample SN3 has a low percentage of heterogeneity for 206Pb/238U ages (4%) with low common Pb contributions (f206 < 1%) and shows a good potential in calibrating unknown samples as primary reference material for LA-ICP-MS analysis. Samples RL2 and HND have altered sections characterised by high LREE contents, flat LREE patterns and old 206Pb/238U apparent ages, and are not suited as reference materials. The low 207Pb/206Pb intercepts for samples RL2 and HND lack geological meaning but provide strong evidence that the disturbed U-Pb systematics with anomalous apparent 206Pb/238U ages is a secondary feature. 相似文献
3.
内蒙古道伦达坝铜钨锡矿床LA-ICP-MS锆石和锡石U-Pb年龄及其地质意义 总被引：6，自引：1，他引：5
道伦达坝矿床位于大兴安岭南段,是一个铜钨锡矿床,其铜、钨、锡储量均达中型。矿体呈脉状,主要产于二叠系砂板岩中的断裂破碎带中,华力西期黑云母花岗岩中的断裂破碎带中亦赋存有矿体。文章选取2件石英-萤石-白云母-电气石-锡石-黑钨矿阶段的矿石样品对其中的进行了LA-ICP-MS U-Pb定年,获得2件样品的~(207)Pb/~(206)Pb-~(238)U/~(206)Pb谐和年龄分别为(134.7±6.6)Ma(MSWD=1.4)和(136.8±7.4)Ma(MSWD=1.7),~(206)Pb/~(207)Pb-~(238)U/~(207)Pb等时线年龄分别为(132±12)Ma(MSWD=0.76)和(135±13)Ma(MSWD=0.9)。锡石定年结果表明,道伦达坝矿床形成于早白垩世。对矿区外围张家营子岩体中的斑状细粒花岗岩进行了LA-ICP-MS锆石U-Pb测年,获得的~(206)Pb/~(238)U加权平均年龄为(135±1)Ma(MSWD=1.3),该岩体的形成年龄与道伦达坝矿床的成矿年龄在误差范围内一致。本次定年结果表明道伦达坝矿床形成于早白垩世,与同期的花岗质岩浆活动有密切的成因联系,该矿床属于与花岗岩有关的岩浆热液脉型矿床。 相似文献
4.
W. Siebel C. K. Shang E. Thern M. Dani?ík J. Rohrmüller 《International Journal of Earth Sciences》2012,101(8):2105-2123
Correct interpretation of zircon ages from high-grade metamorphic terrains poses a major challenge because of the differential response of the U–Pb system to metamorphism, and many aspects like pressure–temperature conditions, metamorphic mineral transformations and textural properties of the zircon crystals have to be explored. A large (c. 450?km2) coherent migmatite complex was recently discovered in the Bohemian Massif, Central European Variscides. Rocks from this complex are characterized by granulite- and amphibolite-facies mineral assemblages and, based on compositional and isotopic trends, are identified as the remnants of a magma body derived from mixing between tonalite and supracrustal rocks. Zircon crystals from the migmatites are exclusively large (200–400?μm) and yield 207Pb/206Pb evaporation ages between 342–328?Ma and single-grain zircon fractions analysed by U–Pb ID-TIMS method plot along the concordia curve between 342 and 325?Ma. High-resolution U–Pb SHRIMP analyses substantiate the existence of a resolvable age variability and yield older 206Pb/238U ages (342–330?Ma, weighted mean age?=?333.6?±?3.1?Ma) for inner zone domains without relict cores and younger 206Pb/238U ages (333–320?Ma, weighted mean age?=?326.0?±?2.8?Ma) for rim domains. Pre-metamorphic cores were identified only in one sample (206Pb/238U ages at 375.0?±?3.9, 420.3?±?4.4 and 426.2?±?4.4?Ma). Most zircon ages bracket the time span between granulite-facies metamorphism in the Bohemian Massif (~345?Ma) and the late-Variscan anatectic overprint (Bavarian phase, ~325?Ma). It is argued that pre-existing zircon was variously affected by these metamorphic events and that primary magmatic growth zones were replaced by secondary textures as a result of diffusion reaction processes and replacement of zircon by dissolution and recrystallization followed by new zircon rim growth. Collectively, the results show that the zircons equilibrated during high-grade metamorphism and record partial loss of radiogenic Pb during post-peak granulite events and new growth under subsequent anatectic conditions. 相似文献
5.
HU Huabin MAO Jingwen LIU Dunyi NIU Shuyin WANG Yanbin LI Yongfeng SHI Ruruo Shijiazhuang University of Economics Shijiazhuang Hebei China University of Geosciences Beijing Email: huhb@.com Institute of Geology Chinese Academy of Geological Science Beijing 《《地质学报》英文版》2005,79(4):491-496
1 Introduction Since the Guilaizhuang gold deposit was discovered in the 1980s, the Tongshi magmatic complex has attracted attention since it exhibits a spatial-temporal relationship to gold mineralization. In the past ten years, a number of detailed fundamental researches have been carried out on the complex, Guilaizhuang gold deposit and their relationships (Qiu et al., 1994; Lin et al., 1996; Yan et al., 1996; Xu et al., 1999; Kong et al., 2001; Shun et al., 2001). Up to date, some res… 相似文献
6.
扬子地块西南缘大红山群老厂河组变质火山岩的锆石U-Pb定年及其地质意义 总被引：15，自引：8，他引：7
大红山群是扬子地台西缘相对较老的地层单元,普遍经历了绿片岩相-低角闪岩相变质作用。其中部的曼岗河组、红山组已获得古元古代晚期～1.68Ga的成岩年龄,其底部的老厂河组却未有相关年龄的报道。大红山群的变质时代目前也无精确的年龄结果。本文以老厂河组厚层变质沉积岩中的薄层变质火山岩样品为研究对象,在岩相学研究的基础上,运用LA-ICP-MS方法对变质火山岩锆石进行原位U-Pb同位素定年及相关的微量、稀土元素测试,获得变质火山岩的原岩年龄和变质年龄:(1)老厂河组变质中酸性岩和变质基性岩中岩浆锆石微区的207Pb/206Pb加权平均年龄分别为1711±4Ma和1686±4Ma,限定老厂河组的形成年龄范围为1711～1686Ma;(2)变质基性岩(石榴斜长角闪岩)中变质锆石的206Pb/238U年龄为849±12Ma。本文结果表明,大红山群的形成时代可提早至1711±4Ma,又一次证明了扬子地台西缘古老结晶基底的存在;大红山群在～850Ma经历了一期新元古代变质事件,这期变质可能是与扬子地台西缘新元古代岩浆事件有关的区域变质事件。 相似文献
7.
Yamuna Singh D. V. L. N. Sastry Sanjay Bagora P. S. C. Pandit S. D. Rai M. B. Verma 《Journal of the Geological Society of India》2018,92(1):7-10
The results of geochronological studies on columbite-tantalite and monazite from the rare metal pegmatites of the Kawadgaon–Challanpara area in Bastar craton, central India are presented. Columbite-tantalite yielded U-Pb concordia upper intercept age of 1978±16 Ma (MSWD = 0.18). Radiogenic 207Pb*/206Pb* (T7/6) ages on 4 out of 5 columbite-tantalite vary in a narrow range of 1903 to 2077 Ma and are similar to U-Pb age, whereas, one sample shows younger 207Pb*/206Pb*(T7/6) age of 1728 Ma. Younger Pb-Pb age of 1744 ± 250 Ma (MSWD = 150) has also been indicated by these columbite-tantalite samples. Four out of five monazite samples define Pb-Pb errorchron age of 2050±370 Ma (MSWD = 165) and radiogenic 207Pb*/206Pb* (T7/6) ages on 3 out of 5 monazites show a narrow range of 1983 to 2083 Ma. Other two samples show younger 207Pb*/206Pb*(T7/6) ages as 1254 Ma and 1592Ma. Both monazite and columbite-tantalite indicate disturbance in Pb and U isotopic systematics as revealed by high MSWD. However, selected samples from both monazite and columbite-tantalite indicate age of their formation as c. 2000 Ma. Younger ages, i.e., 1254 to 1744 Ma are indicative of later geological disturbances. Reported age of c. 2000 Ma is comparable to Rb-Sr date of pegmatitic muscovite (1850-2330 Ma) from this area and is younger to intrusive granites of c. 2500 Ma. By analogy, therefore, it may be inferred that the age of the rare element mineralization may be ~2000 Ma old, and linked with younger granitic activity that spanned over the period from 2300 to 2100 Ma in the Bastar craton. 相似文献
8.
Garnets from different migmatites and granites from the Damara orogen (Namibia) were dated with the U-Pb technique after bulk dissolution of the material. Measured 206Pb/204Pb ratios are highly variable and range from ca. 21 to 613. Variations in isotope (208Pb/204Pb, 206Pb/204Pb) and trace element (Th/U, U/Nd, Sm/Nd) ratios of the different garnets show that some garnets contain significant amounts of monazite and zircon inclusions. Due to their very low 206Pb/204Pb ratios, garnets from pelitic migmatites from the Khan area yield Pb-Pb ages with large errors precluding a detailed evaluation. However, the 207Pb/206Pb ages (ca. 550–500 Ma) appear to be similar to or older than U-Pb monazite ages (530±1–517±1 Ma) and Sm-Nd garnet ages (523±4–512±3 Ma) from the same sample. It is reasonable to assume that the Pb-Pb garnet ages define growth ages because previous studies are consistent with a higher closure temperature for the U-Pb system in garnet relative to the U-Pb system in monazite and the Sm-Nd system in garnet. For igneous migmatites from Oetmoed, Pb-Pb garnet ages (483±15–492±16 Ma) and one Sm-Nd garnet whole rock age (487±8 Ma) are similar whereas the monazite from the same sample is ca. 30–40 Ma older (528±1 Ma). These monazite ages are, however, similar to monazite ages from nearby unmigmatized granite samples and constrain precisely the intrusion of the precursor granite in this area. Although there is a notable difference in closure temperature for the U-Pb and Sm-Nd system in garnet, the similarity of both ages indicate that both garnet ages record garnet growth in a migmatitic environment. Restitic garnet from an unmigmatized granite from Omaruru yields similar U-Pb (493±30–506±30 Ma) and Sm-Nd (493±6–488±7 Ma) garnet ages whereas the monazite from this rock is ca. 15–25 Ma older (516±1–514±1 Ma). Whereas the monazite ages define probably the peak of regional metamorphism in the source of the granite, the garnet ages may indicate the time of melt extraction. For igneous garnets from granites at Oetmoed, the similarity between Pb-Pb (483±34–474±17 Ma) and Sm-Nd (492±5–484±13 Ma) garnet ages is consistent with fast cooling rates of granitic dykes in the lower crust. Differences between garnet and monazite U-Pb ages can be explained by different reactions that produced these minerals at different times and by the empirical observation that monazite seems resistant to later thermal re-equilibration in the temperature range between 750 and 900 °C (e.g. Braun et al. 1998). For garnet analyses that have low 206Pb/204Pb ratios, the influence of high- inclusions is small. However, the relatively large errors preclude a detailed evaluation of the relationship between the different chronometers. For garnet with higher 206Pb/204Pb ratios, the overall similarity between the Pb-Pb and Sm-Nd garnet ages implies that the inclusions are not significantly older than the garnet and therefore do not induce a premetamorphic Pb signature upon the garnet. The results presented here show that garnet with low 238U/204Pb ratios together with Sm-Nd garnet data and U-Pb monazite ages from the same rock can be used to extract geologically meaningful ages that can help to better understand tectonometamorphic processes in high-grade terranes.Editorial responsibility: J. Hoefs 相似文献
9.
This study considers the potential of using the U-Pb dating of garnet for determining quantitative P-T-t paths for the late Archean metamorphism in the Pikwitonei granulite domain. Garnets for U-Pb dating were selected mainly
from samples that also provide information on pressure and temperature. The garnets used for dating were clear and free of
any visible inclusions. Pb concentrations range from 63 ppb to 966 ppb and U from 136 ppb to 1143 ppb. The measured 206Pb/204Pb ratios range from 52.8 to 529.4. The ages are generally discordant with U/Pb ages that may lie above or below concordia.
The discordance is caused by a recent disturbance of the U/Pb ratio in the garnets as indicated by replicate analyses on the
same garnet separates that reproduce 207Pb/206Pb ages well within analytical uncertainty and in most cases within ±1.5 Ma at 2600–2750 Ma. High grade metamorphism continued
over a period of at least one hundred million years, but the garnet-K-feldspar Pb-Pb ages suggest that, during this time,
garnet growth has been favored during three distinct periods in the Cauchon Lake area: 2700–2687 Ma 2660–2637 Ma 2605–2591
Ma The ca. 2695 Ma garnet ages from Cauchon Lake date the time of melting and staurolite breakdown during prograde metamorphism,
the ca. 2640 Ma ages date the time of extensive migmatization and the last period of metamorphic garnet growth, the ca. 2600
Ma ages date the time of crystallization of igneous garnet in late granitic intrusions. Peak metamorphism occurred around
2640 Ma followed by the intrusions of pegmatites starting at 2629 Ma. The Pb-Pb ages for garnet are similar to the U-Pb ages
for zircon that date a leucocratic mobilizate (2695 Ma), a plagioclaseamphibole mobilizate (2637 Ma) and pegmatite (2598 Ma)
(Heaman et al. 1986 a; Krogh et al. 1986; this study). Xenocrysts of garnet from 2600 Ma old graphic granites give minimum
ages of 2984 Ma and 2741 Ma which are minima for the times of garnet growth in the source of the granites. The agreement of
the zircon and garnet ages suggests that the metamorphism may have been punctuated by events that led to the development of
melts or encouraged mineral growth at specific times. If so, the prograde and retrograde paths of metamorphism in the area
may have contained minor excursions in pressure, temperature or fluid fugacities. In the Natawahunan Lake area some 50 km
northwest of Cauchon Lake, garnet growth associated with the prograde breakdown of staurolite occurred at ca. 2744–2734 Ma.
This suggests that a similar style of metamorphism may have occurred earlier in the Natawahunan Lake area than at Cauchon
Lake area, or higher grades of metamorphism were reached earlier and were of longer duration associated with the somewhat
greater depths in the Natawahunan Lake area. These results indicate the these garnets, which are 0.1–1 cm in diameter, have
maintained closed system behavior for U and Pb at peak metamorphic conditions, i.e. temperatures up to 800° C and pressures
of 7.5 kb. 相似文献
10.
We present the results of a comparative study of several geochronometer minerals (baddeleyite, zircon, apatite, phlogopite and tetraferriphlogopite) and isotopic systems (U-Pb, Th-Pb and Rb-Sr) from phoscorites (magnetite-forsterite-apatite-calcite rocks) and carbonatites of the Kovdor ultramafic-alkaline-carbonatite massif, Kola Peninsula, Russia. Uranium, thorium and their decay products are extremely fractionated by minerals that crystallise from carbonatite and phoscorite magma. We obtain high-precision ages from different chronometers, compare their accuracy, and evaluate the role of geochronological pitfalls of initial radioactive disequilibrium, differential migration of radiogenic isotopes, and inaccurate decay constants.Apatite yielded concordant U-Th-Pb ages between 376 and 380 Ma. The accuracy of the apatite 238U-206Pb ages is, however, compromised by uncertainty in the amount of radiogenic 206Pb produced from initial excess 230Th. The 235U-207Pb ages are relatively imprecise due to large common Pb correction and the uncertainty in the initial Pb isotopic composition. The Th-Pb system yields a more precise age of 376.4 ± 0.6 Ma.Zircon from two carbonatite samples is characterised by moderate to low U contents, high Th contents, and very high Th/U ratios up to 9000. The 206Pb*/238U systems in the zircon are strongly affected by the presence of excess 206Pb*, produced by decay of initial 230Th. The 208Pb*/232Th ages of zircon from both carbonatite samples are uniform and yield a weighted average of 377.52 ± 0.94 Ma.Baddeleyite U-Pb analyses are 3 to 6% normally discordant and have variable 207Pb*/206Pb* apparent ages. Eleven alteration-free baddeleyite fractions from three samples with no evidence for Pb loss yield uniform 206Pb*/238U ages with a weighted average of 378.54±0.23 Ma (378.64 Ma after correction for initial 230Th deficiency), which we consider the best estimate for age of the phoscorite-carbonatite body of the Kovdor massif. The 206Pb*/238U ages of baddeleyite fractions from five other samples spread between 378.5 and 373 Ma, indicating a variable lead loss up to 1.5%. The anomalously old 207Pb/235U and 207Pb/206Pb ages are consistent with the presence of excess radiogenic 207Pb* in the baddeleyite. We interpret this as a result of preferential partitioning of 231Pa to baddeleyite.Fifteen phlogopite and tetraferriphlogopite fractions from five carbonatite and phoscorite samples yielded precise Rb-Sr isochron age of 372.2 ± 1.5 Ma, which is 5 to 7 m.y. younger than our best estimate based on U-Th-Pb age values. This difference is unlikely to be a result of the disturbance or late closure of Rb-Sr system in phlogopite, but rather suggests that the accepted decay constant of 87Rb is too high.Comparative study of multiple geochronometer minerals from the Kovdor massif has revealed an exceptional complexity of isotopic systems. Reliable ages can be understood through systematic analysis of possible sources of distortion. No single geochronometer is sufficiently reliable in these rocks. Th-Pb and Rb-Sr can be a very useful supplement to U-Pb geochronometry, but the routine use of these geochronometers together will require more precise and accurate determination of decay constants for 232Th and 87Rb. 相似文献
11.
《International Geology Review》2012,54(9):1064-1075
ABSTRACTThe Neoproterozoic Kaijianqiao Formation is one of the most important pre-Sturtian rift successions in South China and there has long been a lack of reliable geochronological constraints for its minimum depositional age. In this study, new zircon U-Pb ages of volcaniclastic rocks from the topmost Kaijianqiao Formation are presented. The youngest SHRIMP and LA-ICP-MS zircon 206Pb/238U weighted mean ages of the tuff sample are 715.0 ± 9.8 and 718.8 ± 9.4 Ma, respectively. The youngest LA-ICP-MS zircon 206Pb/238U weighted mean age of the tuffaceous siltstone sample is 720.8 ± 7.4 Ma and represents the maximum depositional age of the topmost Kaijianqiao Formation. The results show that the minimum depositional age of the Kaijianqiao Formation in the western Yangtze Block should be ca. 715 Ma, consistent with other pre-Sturtian rift successions in South China, such as the Banxi Group, Chengjiang, and Liantuo formations. Together with the published zircon U-Pb ages, it is demonstrated that the Sturtian glaciation in South China (Jiangkou glaciation) most likely initiated around 715 Ma. In other Rodinia blocks, like Laurentia and Arabia, the Sturtian glaciation probably started between 712 and 717 Ma, thus our new results further support that the Sturtian glaciation was a rapid and globally synchronous event. Other 206Pb/238U zircon ages display five distinct peaks at ca. 751, 780, 799, 819, and 848 Ma, which corresponded to the tectonic-magmatic events related to the break-up of Rodinia. 相似文献
12.
桐柏造山带深熔作用:混合岩LA-ICPMS锆石U-Pb年代学证据 总被引：2，自引：1，他引：1
桐柏造山带是研究秦岭-桐柏-大别-苏鲁变质带演化的关键地区。由于桐柏高级变质杂岩深熔作用发生时间还缺乏准确的限定,这一区域的构造演化仍存在较大的争议。本文对桐柏杂岩中的一个混合岩的中色体和两个混合岩浅色体样品中的锆石进行了LA-ICPMS年代学测定。中色体中锆石分析点获得的上下交点分别为859±73Ma和135±250Ma。接近上交点的6个谐和分析点给出的206Pb/238U加权平均结果为828±7Ma (MSWD=0.57)。这一年龄结果同上交点在误差范围内一致,代表混合岩原岩结晶年龄,对应扬子板块北缘出现的中-新元古代的岩浆事件。另一方面,混合岩浅色体中的新生锆石具有面状分带或是弱的振荡环带,低的Th/U比值,锆石形态学和内部结构也表明新生锆石结晶于与深熔作用有关的熔体中,它们的206Pb/238U加权平均值分别为135±4Ma和131±3Ma。这一年龄范围代表桐柏高级变质地体发生深熔作用时间,区域上与桐柏-大别变质带广泛出现的碰撞后岩浆事件的时代相同。桐柏造山带出现造山后伸展的时间应不晚于135Ma。 相似文献
13.
U/Pb and Pb/Pb zircon ages for arc-related intrusions of the Bolu Massif (W Pontides, NW Turkey): evidence for Late Precambrian (Cadomian) age 总被引：2，自引：0，他引：2
We present new U/Pb and Pb/Pb radiometric age data from two tectono-stratigraphic units of the regionally extensive Bolu Massif, in the W Pontides (İstanbul Fragment), N Turkey. A structurally lower unit (Sünnice Group) is cut by small meta-granitic intrusions, whereas the structurally higher unit comprises meta-volcanic rocks (Çaşurtepe Fm) cut by meta-granitic plutons (Tüllükiriş and Kapıkaya plutons). U/Pb single-crystal dating of zircons from the Kapıkaya Pluton yielded a concordant cluster, with a mean 238U/206Pb age of 565.3 ± 1.9 Ma. Zircons from the Tüllükiriş Pluton (affected by Pb loss) gave a 207Pb/206Pb age of 576 ± 6 Ma age (Late Precambrian). Small meta-granitic intrusions cutting the Sünnice Group yielded a less precise 207Pb/206Pb age of 262 ± 19 Ma (Early Permian). The older ages from the Bolu Massif confirm the existence of latest Precambrian arc magmatism related to subduction of a Cadomian ocean. We infer that the Bolu Massif represents a fragment of a Cadomian active margin. Cadomian orogenic units were dispersed as exotic terranes throughout the Variscan and Tethyan orogens, and the Bolu Massif probably reached its present position prior to latest Palaeozoic time. Our dating results also confirm that NW Turkey was affected by Hercynian magmatism related to subduction of Palaeotethys, as inferred for other areas of the Pontides. 相似文献
14.
都龙锡锌多金属矿床LA-MC-ICPMS锡石U-Pb测年及其意义 总被引：12，自引：9，他引：3
云南都龙锡锌多金属矿床是我国最大的锡石硫化物矿床之一。缺乏精确可靠的成矿年代学判据,是该矿床成因认识存在较大分歧的重要原因之一,严重制约了地质勘探工作的深入。本文应用LA-MC-ICP-MS微区原位U-Pb同位素测年技术,对都龙矿区曼家寨矿段的锡石样品进行了研究,获得DL12-716、DL12-722、DL12-740等三件样品的206Pb/207Pb-238U/207Pb等时线年龄分别为89.2±4.1Ma(N=22,MSWD=4.5)、88.0±1.6Ma(N=24,MSWD=2.3)和87.2±3.9Ma(N=31,MSWD=14),207Pb/206Pb-238U/206Pb谐和年龄分别为96.6±3.5Ma(MSWD=8.1)、93.6±1.6Ma(MSWD=5.8)和82.0±2.5Ma(MSWD=11)。结合矿床地质特征和前人成岩-成矿年代学成果,表明都龙矿区锡成矿作用主要发生在晚白垩纪,与燕山晚期岩浆热液活动关系密切,结合地质事实,表明燕山晚期岩浆热液活动是老君山矿集区锡钨多金属成矿的关键。通过区域地质及年代学对比,表明滇东南地区晚白垩世存在大规模花岗岩成岩-锡成矿事件。 相似文献
15.
Xiao-Feng Cao Xin-Biao Lü Jian-Hua Lei Chao Chen Yu-Qi Wang Bao-Feng Du Wei Mei Xiang Gao An-Dao Du 《Resource Geology》2010,60(4):397-403
The Dapingliang Cu deposit is located at the eastern part of the Kuruketage block in NW China. Igneous rocks are widely distributed in the district and skarn are formed at the contact zone between igneous rocks and the carbonates of Beiyixi Formation. The ore is distributed in the skarn. Zircon U-Pb isotopic ages of the plagiogranite, which is related to the Cu deposit, indicate that the lower and upper intercept ages are 826 ± 23 Ma and 1886 ± 61 Ma, respectively. The lower intercept age corresponds to a weighted mean 206Pb/238U age of 826 ± 13 Ma, yielded by ten analysis points. The upper intercept age may represent the age of the source rock, from which the plagiogranite originated. Re-Os isotopic analysis of six molybdenite samples from L7 orebody in the Dapingliang deposit shows an isochron age of 830 ± 26 Ma, which corresponds to the weighted mean model age of 829.4 ± 9.5 Ma. The concordant ages obtained by zircon U-Pb dating and molybdenite Re-Os dating are compatible with the skarn-type mineralization at Dapingling and confirm that the deposit formed during the Tarim orogeny. 相似文献
16.
Dr. Claudia Carl Dr. Harald Dill Hans Kreuzer Prof. Dr. Immo Wendt 《International Journal of Earth Sciences》1985,74(3):483-504
K/Ar dating of micas from rocks of Fichtelgebirge and the northern Oberpfalz (NE-Bavaria) covers the rather wide range from 330 to 300 Ma. In combination with Rb/Sr wholerock isochron ages of post-tektonic granites four Variscian events can be traced:
- Regional metamorphism ～ 330 Ma,
- Intrusion of the older post-deformative granite G1 about 320 Ma (Falkenberger Granit) followed by rapid cooling.
- About 300 Ma ago the older mineral ages were more or less reset by the intrusion of younger granites (G2 to G4, Flossenbürger Granit) again followed by a rapid cooling.
- Local influences later than 290 Ma are recorded by some white micas in fault gauges at least up to the middle Jurassic (< 150 Ma).
17.
为了精确厘定莲花山铜矿的成矿时代,在前人研究的基础上,开展了与成矿关系密切的花岗闪长斑岩锆石U-Pb定年测定。实验结果共获得4组年龄数据,第1组有1个锆石,206Pb/238U年龄为343Ma±2Ma;第2组1个锆石,206Pb/238U年龄为264Ma±2Ma;第3组有1个锆石,206Pb/238U年龄为256Ma±2Ma;第4组有17个锆石,206Pb/238U年龄在240~249Ma之间,206Pb/238U年龄加权平均值为246.4Ma±1.2Ma(N=17)。结合所测锆石的CL图像特征,确定花岗闪长斑岩就位发生在晚二叠世—早三叠世。 相似文献
18.
Allen K. Kennedy Jörn-Frederik Wotzlaw James L. Crowley Mark Schmitz Urs Schaltegger Benjamin Wade Laure Martin Cristina Talavera Bryant Ware Thi Hao Bui 《Geostandards and Geoanalytical Research》2023,47(2):373-402
Twelve apatite samples have been tested as secondary ion mass spectrometry (SIMS) reference materials. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis shows that the SLAP, NUAN and GR40 apatite gems are internally homogeneous, with most trace element mass fractions having 2 standard deviations (2s) ≤ 2.0%. BR2, BR5, OL2, AFG2 and AFB1, which have U > 63 μg g-1, 206Pb/204Pb > 283, and homogeneous SIMS U-Pb data, have respective isotope dilution thermal ionisation mass spectrometry (ID-TIMS) ages of 2053.83 ± 0.21 Ma, 2040.34 ± 0.09 Ma, 868.87 ± 0.25 Ma, 478.71 ± 0.22 Ma and 473.25 ± 0.09 Ma. Minor U-Pb heterogeneity exists and accurate SIMS results require correction with the 3D Concordia-constrained common Pb composition. Among the studied samples, AFG2 and BR5 are the most homogeneous U-Pb reference materials. The SIMS sulfur isotopic compositions of eight of the apatites shows they are homogeneous, with 2s for both 103δ34S and 103δ33S < 0.55‰. One apatite, BR96, has Δ33S = -0.36 ± 0.2‰. The apatite samples have ID-TIMS 87Sr/86Sr between 0.704214 ± 0.000030 and 0.723134 ± 0.000035. 相似文献
19.
This paper evaluates the analytical precision, accuracy and long‐term reliability of the U‐Pb age data obtained using inductively coupled plasma–mass spectrometry (ICP‐MS) with a frequency quintupled Nd‐YAG (λ = 213nm) laser ablation system. The U‐Pb age data for seven standard zircons of various ages, from 28 Ma to 2400 Ma (FCT, SL13, 91500, AS3, FC1, QGNG and PMA7) were obtained with an ablation pit size of 30 μm diameter. For 207Pb/206Pb ratio measurement, the mean isotopic ratio obtained on National Institute of Standards and Technology (NIST) SRM610 over 4 months was 0.9105 ± 0.0014 (n = 280, 95% confidence), which agrees well with the published value of 0.9096. The time‐profile of Pb/U ratios during single spot ablation showed no significant difference in shape from NIST SRM610 and 91500 zircon standards. These results encouraged the use of the glass standard as a calibration standard for the Pb/U ratio determination for zircons with shorter wavelength (λ = 213 nm) laser ablation. But 206Pb/238U and 207Pb/235U ages obtained by this method for seven zircon standards are systematically younger than the published U‐Pb ages obtained by both isotope dilution–thermal ionization mass spectrometry (ID‐TIMS) and sensitive high‐resolution ion‐microprobe (SHRIMP). Greater discrepancies (3–4% younger ages) were found for the 206Pb/238U ages for SL13, AS3 and 91500 zircons. The origin of the differences could be heterogeneity in Pb/U ratio on SRM610 between the different disks, but a matrix effect accuracy either in the ICP ion source or in the ablation‐transport processes of the sample aerosols cannot be neglected. When the 206Pb/238U (= 0.2302) newly defined in the present study is used, the measured 206Pb/238U and 207Pb/235U ages for the seven zircon standards are in good agreement with those from ID‐TIMS and SHRIMP within ±2%. This suggests that SRM610 glass standard is suitable for ICP‐MS with laser ablation sampling (LA‐ICP‐MS) zircon analysis, but it is necessary to determine the correction factor for 206Pb/238U by measuring several zircon standards in individual laboratories. 相似文献
20.
苏鲁仰口超高压岩石SHRIMP锆石U/Pb定年与部分熔融时限 总被引：5，自引：4，他引：1
在大型碰撞造山带中,在陆壳物质深俯冲或快速折返早期,在超高压-高压条件下,易熔组分可能发生水致或脱水部分熔融,形成花岗质熔体。在超高压-高压条件下,苏鲁超高压岩石发生过部分熔融作用,形成长英质多晶体包裹体和不同尺度的花岗质岩石, 导致可观的地球化学效应。为确定苏鲁超高压岩石部分熔融的时限,对山东仰口超高压副片麻岩和其中平行片麻理的同构造钾质花岗岩脉进行了SHRIMP锆石U/Pb地质年代学、全岩地球化学和锆石内矿物包裹体的研究。副片麻岩的锆石具有典型的核-幔-边结构。核部锆石为碎屑锆石,206Pb/238U年龄大于282Ma,可能反映了副片麻岩的原岩包含不同成因的物质;幔部和边部的Th/U比都小于0.1,分别给出233±3Ma和214±4Ma的206Pb/238U 年龄,分别对应于超高压变质和角闪岩相退变质年龄。同构造花岗岩脉是富钾过铝质花岗岩(A/CNK=1.2),锆石也具有核-幔-边结构;核部锆石年龄与副片麻岩的核部锆石年龄相当,反映了该花岗岩脉的源区可能是变沉积岩;除幔部锆石的一个点具有206Pb/238U年龄为234.6±3.9Ma之外,其它幔部锆石位于谐和线附近,给出206Pb/238U年龄为220.8±2.9Ma, 该年龄代表着该花岗岩脉的形成年龄。上述数据表明,在仰口地区,超高压岩石的部分熔融作用早于角闪岩相退变质作用。 相似文献