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1.
Results of the study of noble metal specialization of Lower and Middle Riphean terrigenous rocks in the Bashkir Anticlinorium (South Urals) are reported. The study revealed their genetic differences in the relatively unaltered, i.e., “background” terrigenous rocks in type sections of the Burzyan and Yurmatau groups and in sedimentary rocks of the same stratigraphic levels from tectonic zones subjected to local dynamothermal metamorphism of the greenschist facies and intruded by mafic rocks. It has been established that Ru serves as a geochemical marker of the impact of magmatic processes on sedimentary rocks and the redistribution of noble metals during metamorphism and local metasomatism. A generalized model is proposed for the formation of noble metal geochemical specialization of Lower and Middle Riphean terrigenous rocks in the South Urals.  相似文献   

2.
The Grenvillian orogeny (～1250 to 980 Ma) was one of the most significant Riphean events. It determined the formation of many structures observable now in North and South America, northwestern Europe, South Africa, Western Australia, Antarctica, and other regions. Nevertheless, its reflections in the most complete and relatively well investigated Upper Precambrian sedimentary sections of northern Eurasia such as the Riphean stratotype (Bashkir meganticlinorium) and hypostratotype (Uchur-Maya region) still remain unknown. This is primarily true of the petrographic and chemical compositions of terrigenous rocks. This work is dedicated to the analysis of peculiar features in variations of the whole-rock chemical composition of sandstones and fine-grained clastic rocks (shales, mudstones, fine-grained clayey siltstones) that constitute Middle-Upper Riphean boundary layers of the Bashkir meganticlinorium, Kama-Belaya aulacogen, and Uchur-Maya region. The analysis reveals no tendency for the decrease in the degree of the chemical and, consequently, mineralogical maturity in the upward direction through the Middle-Upper Riphean sections in the above-mentioned regions. The whole-rock compositions of fine-grained clastic rocks associated with sandstones correspond mostly to that of “common” Upper Precambrian clayey rocks. The formation of practically the entire Yurmatinian-Karatavian succession in the Bashkir meganticlinorium proceeded under relatively stable TDM and ?Nd(T) values. The period of 1250 to 980 Ma in the central and eastern parts of the Siberian Platform was marked by repeated rifting episodes alternating with accumulation of mature platformal sediments, although repercussions of Grenvillian collisional processes are missing from this region as well. The performed analysis provides grounds for the conclusion that contribution of the Grenvillian events to the formation of most complete Riphean successions in northern Eurasia was insignificant.  相似文献   

3.
贵金属配分模式及地质应用   总被引：2，自引：0，他引：2  
张生  李统锦 《世界地质》1996,15(2):39-45
通过与ＲＥＥ模式对比，介绍了贵金属配分模式的构筑方法和组成参数；并对包括地幔岩石、科马提岩和玄武岩在内的各种基性、超基性岩石的特性ＰＧＥ＋Ａｕ配分模式和贵金属分馏机制进行了综述。  相似文献   

4.
ＩＮＴＲＯＤＵＣＴＩＯＮＬｏｗｅｒＣａｍｂｒｉａｎｂｌａｃｋｒｏｃｋｓｅｒｉｅｓｅｘｉｓｔｓｂｒｏａｄｌｙｉｎｍｏｒｅｔｈａｎ１０ｐｒｏｖｉｎｃｅｓｉｎＳｏｕｔｈＣｈｉｎａ（Ｃｈｅｎｅｔａｌ．,１９９０）．Ｔｈｅｂｏｔｏｍｏｆｔｈｅｓｅｒｉｅｓｓｐｏ...  相似文献   

5.
The materials on the geology and geochemical specialization of Riphean terrigenous rocks of the Bashkirian meganticlinorium, including carbonaceous shale and conglomerate, are reported. Conglomerate is characterized by a high concentration of Au and PGEs mostly related to intensely dislocated zones. It is concluded that potentially ore-bearing zones in terrigenous deposits of the Bashkirian meganticlinorium were formed as a result of multistage polygene processes controlled by the Riphean–Vendian geodynamic evolution of the region.  相似文献   

6.
Geologic and paleogeographic settings of the Upper Jurassic, Cretaceous, and Paleogene phosphorite-bearing rocks in the Kaliningrad and southeastern Baltic regions are considered. The paper discusses structures of the phosphorite-bearing sections, outlines phosphorite types, and compares them with the adjacent regions and phosphorite-bearing basins of the East European Platform. It is noted that the age of Meso-Cenozoic phosphorite-bearing horizons in the Kaliningrad and southeastern Baltic regions are similar or akin to the age of phosphorite-bearing horizons in other regions of the East European Platform. The age also matches that of ancient weathering crusts in provenances. Data on the composition of rare and rare earth elements in phosphorites from the northwestern basins of the East European Platform are used to estimate the role of igneous rocks, in particular, alkaline mafic-ultramafic rocks of Karelia that delivered phosphorus to sedimentation basins.  相似文献   

7.
The mineral assemblage and the sedimentological characteristics of the “Donauplatin” (Danubian fluvial placer containing platinum-group elements (PGE) and gold (Au)) are described for the first time in connection with upstream reference placer deposits near the potential source area in tributaries of the River Danube/Donau. Granulometric and morphometric data have been obtained using the CCD-based CAMSIZER technique. The platinum-group minerals (PGM; iridium, osmium, unknown iridium-osmium-sulfide, ruthenium-osmium-iridium alloys, platinum-iron alloys, iridium-bearing platinum, sperrylite) have been derived from ultramafic magmatic rocks, probably belonging to the ophiolitic series in the Tepla Barrandian unit of the Bohemian Massif. The Au-Pd-Cu compounds in the placer originated from dynamo-metamorphogenic processes in a sulfur-deficient environment at the SW edge of the Bavarian Basement. Gold in the “Donauplatin” has been reworked from a “secondary” or intermediate repository of lateritic gold (Boddington-type). Its primary source is supposed to be of orogenic origin. Provenance analyses of the associated non-heavy minerals point to high-pressure metamorphic rocks, igneous rocks (monazite) and high-temperature metamorphic rocks (750° to 850°C, zircon morphology). Garnet compositions indicate that meta(ultra)basic igneous rocks, calc-silicate rocks and skarns prevailed over paragneisses in the provenance area. Extraterrestrial processes creating the well-known Ries impact crater in the environs of Nördlingen during the Miocene have a minor share in the PGE budget by delivering molybdenum-ruthenium-osmium-iridium alloys and iridium solid-solution series (s.s.s.) minerals. Judging by the heavy mineral suites, Saxothuringian source rocks of the NE Bavarian Basement connected with the Donau River via the Naab River drainage system have not contributed to the element budget of the “Donauplatin” under study. Stream sediments which have been derived from this provenance area are characterized by low-temperature (LT) crystalline rocks and a considerable proportion of pegmatitic and metabauxitic material lacking in the Holocene sediments of the “Donauplatin”.  相似文献   

8.
The U–Pb isotope data and corresponding ages of detrital zircons from rocks of the basal complexes of the Uralides of different segments of the Ural Fold Belt are considered. It was established that complexes of ancient domains of the East European Platform (Volga-Uralia, Sarmatia, Kola, etc.) seem to have been the main provenance areas of the clastic material for the Southern, Middle, and Northern Urals. This means that there were relatively remote and local (igneous formations of the pre-Uralides) provenance areas. Rift rock associations of the Uralides of the Subpolar and Polar Urals were formed mainly through erosion of local provenance areas (predominantly, Late Riphean–Vendian island-arc and orogenic magmatic complexes of the Proto-Uralides–Timanides). Detrital zircons of Riphean age dominate in rocks of the basal complexes of the Uralides. A source for them could have been rock complexes of Svecofennian-Norwegian Orogen and Cadomides of the Scythian-Turan Plate, intraplate magmatic formations, and metamorphic complexes, as well as blocks accreted to the margin of the East European Platform in the Late Precambrian–Cambrian and later detached and displaced during the Ordovician rifting and spreading. In general, the basal complexes of Uralides were formed owing to supply of clastic material from both remote and local sources. Despite the appearance of information of a totally new level (U–Pb isotope ages of detrital zircons, their Lu–Hf systematics, and the distribution features of rare earth and trace elements), the contribution of these sources to the formation of the Late Cambrian–Early Ordovician clastic strata is hardly possible at present to evaluate.  相似文献   

9.
The mantle metasomatites (fluidized magmatic rocks) of the Pamir-Tien Shan region show extremely high contents of lithophile and chalcophile trace elements, which often exceeds the regional average abundances of the Earth’s crust. Geochemical relations were established between mantle and crustal rocks, and it was shown that the compositions of magmatic rocks of different age and formation depth and polychronous mineralization are relatively stable. These data and some other facts indicate the possible influence of mantle fluids (melts) on the crustal rocks and processes. An alternative model implies the geochemical influence of crustal rocks on the geochemical characteristics of the regional mantle. The ore material of alkali basic rocks and some hydrothermal and rare metal deposits shows a geochemical affinity to the supposed mantle (mantle-crustal) sources. The ore-bearing fluids (melts) were presumably related to the evolution of ultradeep “hot” material of mantle plumes and “daughter” diapirs carrying alkaline, trace, and ore elements.  相似文献   

10.
Association of titanium-zirconium placers and phosphate mineralization in Upper Cretaceous rocks of the East European Platform is shown with the Tsentral’noe (Central) and Unecha deposits as example. This paragenesis is caused by interaction between the multicomponent placer ore (phosphate-rare metal) concentrations and mechanical-chemical differentiation that shows up periodically during the sub-aerial migration of sedimentary material. Clastic ore components were mainly derived from intermediate collectors, while the phosphate material was delivered by the phosphate-containing solutions and particulates in the chemical weathering crust. Such phosphorite-titanium-zirconium occurrences can also be detected in other regions, including areas with rare metal placers.  相似文献   

11.
Analyses of stream sediment and soil samples from the Bushveld Complex, South Africa have revealed enhanced precious metal concentrations, which can be related both to mining activities and the presence of hidden concentrations of platinum-group elements (PGEs) and gold. The economically important PGE deposits hosted by the Upper Critical Zone of the Rustenburg Layered Suite are revealed by a high PGE and Au content in the overlying soils. A second zone of elevated precious metal concentrations straddles the boundary between the Main and Upper Zones and has to date been traced for more than 100 km. This zone follows the igneous layering of the Rustenburg Layered Suite and is offset by the Brits Graben. It is therefore thought to be the reflection of a magmatic PGE-Au mineralisation. Received: 31 May 1996 / Accepted: 7 January 1997  相似文献   

12.
This paper is devoted to detailed study of picritic rocks (olivine melanogabbronorites) and comagmatic gabbrodolerites from sills and dikes in the central part of the Bashkirian meganticlinorium. These rocks are ascribed to the Kama-Belsk magmatic province (KBP) that was formed in the eastern East European Platform (EEP) in the Mesoproterozoic time. The study of minerals (EMPA, SIMS), rocks, and their oxygen isotope compositions showed the contribution of crustal contamination, fractional crystallization and cumulus processes in their formation. The geochemical indicators of crustal contamination (Nb/Nb*, (Nb/La) n , δ18O, and others) show strong variations, which indicates uneven crustal contribution in the parental melts during rock formation (10–25%). The study of weakly contaminated (δ18O = 5.3‰) olivine melanogabbronorites (MgO = 22.55 wt %) from the small Ishlya-1 subvolcanic body, which contain subordinate amount of cumulus (24%), high-magnesian olivine (Fo91.3), and high-Cr spinel (cr# 0.67), as well as HREE depleted clinopyroxenes, allowed us to retrieve the composition of parental melt. The latter contained about 20 wt % MgO and was formed by 19–26% melting of mantle source (potential mantle temperature T m of 1530–1545°C). Geochemical characteristics of KBP reflect the formation of primary melts by melting of mantle column at different depths, mixing of the melts, and significant contamination by crustal material. The dominant role in the formation of the rocks of the Ishlya area and Mashak Complex was played by derivatives of spinel peridotites, while the rocks of the Bakal-Satka area were derived from garnet peridotites.  相似文献   

13.
According to the neutron activation analysis (NAA) data, the average Au content makes up 0.004 μg/g in sabelliditid tubes, 0.08 μg/g in vendotaenid ribbon remains, and 0.28 μg/g (the maximal value) in sapropelic films. Sorption of soluble compounds at the epigenesis stage is the most probable mechanism of Au concentration in Vendian-Cambrian rocks from the East European Platform.  相似文献   

14.
The distribution of gold in rocks from some igneous complexes of the central and southwestern areas of eastern Transbaikalia (Daurian, Aga, and Argun structure-formational zones) was studied by quantitative extraction–atomic-absorption analysis and mass spectrometry with inductively coupled plasma (Element-2 mass spectrometer). High gold concentrations (on average, 0.0043 ppm) are typical of the most widespread hornblende-biotite granodiorites and granites of the main phases of batholith intrusions in the Upper Paleozoic Unda complex in the east of the study area and in the Triassic–Middle Jurassic Kyra complex in the west. The rocks of the Early–Middle Jurassic (Sokhondo) and Middle–Upper Jurassic (Shakhtama, Kharalga, and Kukul’bei) complexes have much lower Au concentrations (mainly 0.0014–0.0030 ppm), with the minimum ones established in the Shakhtama complex. During the magmatic differentiation of granitoid intrusions, the concentrations of gold in the late leucogranite differentiates decreased.The Au concentrations in the studied complexes do not depend on the composition of the host terrigenous rocks of different ages, which evidences the endogenous nature of the revealed differences in Au concentrations in the regional granitoids. Abnormally high concentrations of gold in some studied samples are observed mainly in the regional hydrothermal mineralization occurrences.The classification R-type cluster analysis showed that all variables of the studied igneous rocks are subdivided into three groups by the degree of correlation. Gold shows a distinct tendency to the correlation with siderophile oxy- and sulfurophile groups of metals. The Q-type analysis generally confirmed the correctness of the known formational classification of the regional granitoids.  相似文献   

15.
华南地区三叠系广泛分布蚀变火山灰(俗称“绿豆岩”)。对渝北温泉镇地区平洪村剖面与谢家槽剖面的“绿豆岩”进行矿物学、全岩地球化学和锆石U-Pb测年及地球化学分析。X射线衍射分析表明,矿物组成均以石英和碱性长石为主,此外还含有伊利石、蒙脱石等黏土矿物。锆石岩相学、Th/U比值及锆石REE配分模式都显示典型的岩浆成因锆石特征,但样品和锆石的地球化学特征明显不同。锆石U-Pb测年结果揭示平洪村样品的形成年龄为(247.2±0.59) Ma(MSWD=2.3,n=30),与早、中三叠世的界线年龄(247.2 Ma)高度吻合,其锆石地球化学特征显示板内成因,推测是在峨眉山大火成岩省主要活动期之后板内火山活动过程中形成的。谢家槽剖面样品年龄为(225.9±1.4) Ma(MSWD=1.6,n=29),锆石地球化学特征显示岩浆弧成因,结合区域地质演化特征分析,特别是研究区北部(华北南缘)同时期火山灰的发现,认为谢家槽剖面“绿豆岩”很可能是勉略洋闭合过程中的产物。  相似文献   

16.
This work presents new data on the conditions of formation of igneous rocks on the western slope of the Southern Urals and the adjacent part of the East European Platform. Based on the calculated P–T melting parameters of the mantle substrate, it is shown that plume magmatism leads to the formation of similar rocks (picrites and picrite-dolerites), while the genesis of them is quite different. The first type of rocks is a product of crystallization of the undifferentiated mantle-derived melt in the upper horizons of the crust; the rocks of the second type are formed as a result of magma differentiation in large intracrustal magma chambers.  相似文献   

17.
On the basis of the geological and geochemical studies, including chemical analysis of bulk rocks, rare-earth and trace element studies, fluid inclusion, and S and O isotopic analyses, the authors described the geo-logical background of the deposit in detail and presented significant proofs for the conditions of formation of the Shaxi porphyry copper-gold deposit. Compared with other large and supper-large porphyry copper deposits in China and the adjacent Cu-Au mineralized areas, the ore-forming processes and conditions were analyzed; and the possibil-ity of forming large porphyry copper deposits in the Shaxi area was discussed. The present study indicated that the ore-forming fluid and material were mainly of magmatic origin, while meteoric water played a certain role in the ore-forming processes. Interactions between subducting and overriding plates provided a major driving force for the formation of igneous rocks and the deposition of metal elements in East China since Jurassic. Based on the geo-chemical data of the Shaxi intrusive, it is found that the copper (gold) mineralization is closely related to the genesis of adakite-like intrusive in the Shaxi area. This adakite-like intrusive was formed in the subduction environment as a result of the subduction of the West Pacific plate toward the East China continent, where there is a great potential-ity to form a large porphyry copper deposit.  相似文献   

18.
Devonian, spessartite dykes, known as the Weekend dykes, onthe Eastern Shore of Nova Scotia contain panidiomorphic texturesand mineral (amphibole, clinopyroxene, and biotite) compositionstypical of shoshonitic lamprophyres. The major element and traceelement geochemistry of the Weekend dykes is also representativeof shoshonitic lamprophyres with high large ion lithophile elementconcentrations (LILE, e.g., Rb, K, and Ba) relative to the lightrare earth elements (LREE, e.g., La) and very low Nb and Ti.Only Ta concentrations are uncharacteristically high relativeto Nb and Ti. The dykes are variably evolved but many samplesshow primitive compositions with high mgnumber [>0.70, wheremg-number=Mg/(Mg+09total Fe) atomic] high MgO and Ni concentrations(>10 wt.% and 150 ppm, respectively), and low heavy REE concentrations.All noble metal concentrations (Au, Pd, Pt, Rh, Ru, and Ir)tend to be lower in evolved samples than in primitive rocks,suggesting that evolved magmas were efficiently scavenged byimmiscible sulphide globules and that shoshonitic lamprophyreplutons may hold economic promise for the platinum-group elements(PGE). Noble metal abundances in even the most primitive rocksare low compared with many basaltic rocks excepting mid-oceanridge basalt (MORB). This makes doubtful the idea that Megumagroup mesothermal gold deposits, which are spatially and temporallyassociated with the dykes, derived their gold from the lamprophyres.Models that explain PGE concentrations and Pd/Ir ratios in awide variety of mafic rocks suggest that the low noble metalabundances probably reflect metal retention in mantle sulphides,olivine, and PGE alloys at low percentages of melting. However,noble metal abundances are higher than expected if the oceanicslab was involved in the melting process or if the source regionresembled that for most MORB, which appears to have low PGE.Mantle metasomatism represents an unlikely explanation for thePGE abundances, which are equivalent to those expected in alkalinehot-spot magmas. The high PGE abundances of hot-spot magmas(compared with MORB) may be related to the incorporation ofcore materials in deep mantle plumes. Presumably the hot-spotlikemantle became part of the subcontinental lithospheric mantlebefore the subduction and transpressional event that producedthe shoshonitic magmas.  相似文献   

19.
The first results of U–Pb dating of detrital zircons from Upper Ordovician sandstones of the Bashkir uplift in the Southern Urals and U–Pb isotopic ages available for detrital zircons from six stratigraphic levels of the Riphean–Paleozoic section of this region are discussed. It is established that the long (approximately 1.5 Ga) depositional history of sedimentary sequences of the Bashkir uplift includes a peculiar period lasting from the Late Vendian to the Emsian Age of the Early Devonian (0.55–0.41 Ga). This period is characterized by the following features: (1) prevalence of material from eroded Mesoproterozoic and Early Neoproterozoic crystalline complexes among clastics with ages atypical of the Volga–Urals segment of the East European Platform basement; (2) similarity of age spectra obtained for detrital zircons from different rocks of the period: Upper Vendian–Lower Cambrian lithic sandstones and Middle Ordovician substantially quartzose sandstones.  相似文献   

20.
Northeastern China is suited in the eastern part of the Central Asian Orogenic Belt, and it is mainly composed of Erguna Massif, Xing'an Massif, Songnen-Zhangguangcai Range Massif, Jiamusi Massif, and Nadanhada Terrane. The Late Paleozoic magmatism was relatively intense accompanied with multiple stages of amalgamation in several microcontinents, therefore these magmatic products are an important media in recording the Late Paleozoic tectonic evolution history of the northeastern China. According to the petrological, geochronological, and geochemical characteristics of Late Paleozoic igneous rocks in the northeastern China, we found that the Late Paleozoic magmatism was based on Carboniferous -Permian igneous rocks. The Early Carboniferous magmatic products are gabbro, diorite and granite, the Late Carboniferous magmatic products are mainly composed of granitoids with minor gabbro, and the Permian magmatic products are mainly granitoids. Meanwhile, these Late Paleozoic igneous rocks mostly exhibit typical arc characteristics. In addition, the Late Paleozoic igneous rocks in eastern Jilin and Heilongjiang provinces are mainly Permian granitoids with minor gabbro, and these Permian igneous rocks show typical arc characteristics. Combined with petrological, geochronological, geochemical and isotopic characteristics, we suggest that the Late Paleozoic igneous rocks in the Great Xing'an Range and eastern Jilin and Heilongjiang provinces underwent different magmatic evolution history, and the microcontinents in NE China had different crustal growth history.  相似文献   

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