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1.
There is determined the LC50 for 24 … 96 h of phenol, 2,4-dinitrophenol and pentachlorophenol as sodium salt by static assay at water temperatures of 16, 23 and 36°C. In addition, the combinations of the three substances were tested in the same way. With decreasing temperature, the toxicity of the individual substances decreased by 6.5 … 22%, that of the mixtures by 10 … 87%; with rising temperature, the toxicity increased by 38 … 747% and 75 … 744%, respectively. The safety limits at 23°C lie between 0.3 μg/l for a synergistically acting mixture and 0.9 mg/l for an antagonistically acting one; for the individual substances this range is 3.5 μg/l to 0.5 mg/l. 相似文献
2.
The toxicity of phenol, pentachlorophenol and Na-pentachlorophenate to Cypris subglobosa is determined in the batch experiment for 96. h. In the sequence mentioned, the LC50,96h of the three substances are 71.8, 6.56 and 4.41 mg/l, respectively. In the range of 6 … 95 h the mean survival time shows a negative regression to the toxicant concentration, which, however, is not significant statistically for Na-pentachlorophenate. In agreement with this, the LC50 for 12, 24, 48, 72 and 96 h of exposure shows a significant decrease. Due to the comparatively high LC50,96h for pentachlorophenol and Na-pentachlorophenate for C. subglobosa about in comparison with fish, the species is little suited to the toxicological investigation of wastewater. 相似文献
3.
B. S. Khangarot 《洁净——土壤、空气、水》1981,9(6):639-649
Static bioassay acute toxicity tests of Zinc, Copper and Mercury were conducted to determine the median lethal concentrations (LC50s) of a freshwater teleost Channa marulius (HAM .) The 96 h LC50 and 95% confidence limits for Zn2+ were 25.61 (24.13 … 27.12) mg/l; 0.90 (0.80 … 1.038) mg/l; for Cu2+ and 0.314 (0.257 … 0.371) mg/l for Hg2+. However, these values decreased at 240 h of exposure and were: 21.09 (18.29 … 24.60) mg Zn2+/l; 0.66 (0.568 … 0.841) mg Cu2+/l; and 0.131 (0.103 … 0.158) mg Hg2+/l. The relative potency ratio of Zn/Hg, Zn/Cu and Cu/Hg suggests that fish were most sensitive to Hg, followed by Cu and Zn ions. The acute toxicities of mixtures of Zn2+?Cu2+; Zn2+?Hg2+, Cu2+?Hg2+ and Zn2+?Cu2+?Hg2+ up to 48 h of exposure were also investigated. The additive index and ranges for Zn2+?Cu2+ were ?0.241 (-0.577 … 0.054); 0.056 (-0.269 … 0.475) for Zn-Hg; 0.285 (-0.043 … 0.718) for Cu-Hg; and -0.542 (-1.215 … 0.005) for Zn-Cu-Hg. All the mixtures tested showed a greater than additive toxicity because index ranges overlapped zero. 相似文献
4.
B. S. Khangarot 《洁净——土壤、空气、水》1981,9(5):505-509
The acute toxicity of copper and copper plus complexing agents to common guppy Lebistes reticulatus was studied for 96 h by a static bioassay technique. The addition of complexing agents viz. disodium salt of EDTA, citric acid, sodium thiosulphate and glycine in Cu2+ solutions caused a great decrease in the per-cent mortality as compared to that of Cu2+ test solutions alone. 10 mg/l of complexing agent was added in each copper concentration in all the test series. The 96 h LC50 values and 95% confidence limits in mg/l of Cu2+ plus were 1.23 (0.95…1.65) for Cu2+ alone; 4.30 (4.04 … 4.55) for Cu2+ plus EDTA; 1.94 (1.69 … 2.18) for Cu2+ plus citric acid; 3.44 (2.96 … 3.74) for Cu2+ sodium thiosulphate and 2.29 (2.22 … 3.02) for Cu2+ plus glycine. 相似文献
5.
To prevent infection with Dracunculus medinensis, a carrier host, the copepod Cyclops, has to be controlled. After preceding laboratory investigations a field trial with well water and different additions of chlorine and sodium permanganate is carried out. The exposure is performed at an ambient temperature of 25… 40 °C and in bright and dark samples (5… 11 h of sunshine/d) as well as in the well. The residual concentrations of the two chemicals are an exponential function of the time of exposure with half-times between 6 and 23 h for chlorine and 11… 30 h for sodium permanganate. The depletion of the two oxidizing agents under light is faster than in darkness. Dosage should be done in such a way that the LC90,24h after 24 h of exposure will not be fallen below; in a specific case, this guarantees at the same time that the permissible concentrations for drinking water will not be reached 96 h after addition. For this, initial concentrations of 30 mg 1 Cl2 or 50 mg/l KMnOr are necessary. Under these conditions, the Cyclops population had died on the seventh day after the application of chemicals, but after seven weeks it reached the original density again. With one application of chloride or sodium permanganate a week Dracunculiasis can be completely controlled. 相似文献
6.
By way of introduction the general fundamentals and kinetic setups of the competitive and non-competitive as well as substrate inhibition of cultures of microorganisms are stated. Investigated on a laboratory scale is the degradation of liquid pig slurry in a 600-1 stirring fermenter with discontinuous addition (pO2≧=30 = saturation) of methanol as external substrate by a yeast mixed culture of Metschnikowia and Pichia membranifaceans to utilize the steam-volatile fatty acids (12 g/l) and of Acetobacter methanolicus to utilize methanol. A stable fermentation with stable residual concentrations of 235 mg/l fatty acids, 142 mg/l mH4-N an 100 … 300 mg/l methanol for aperiod of 2400 h can be achieved. 相似文献
7.
The freshwater pondsnail Viviparus bengalensis (LINNAEUS) was exposed to sublethal concentrations of pentachlorophenol (1.561 mg/l) and sodium pentachlorophenate (0.991 mg/l). Both the chemicals caused considerable damage in the mantle of the snail. Their toxic effects included shrinkage and elongation of epithelial cells, the cells losing contact with each other, resulting in the formation of intercellular spaces, enlargement of nuclei, shrinkage of the basement layer and loss of shape of polygonal cells of connective tissue. 相似文献
8.
By diluting a boggy water there is produced water with a COD-Mn of 3.4 … 10.6 mg/l O2 which is due only to humic substances. The water is mixed with 2.5 … 12.9 mg/l Cl2 at pH-values of 5.2 … 8.5 and incubated for 24 h at 20°C. CHCl3 concentrations of 38 … 480 μg/l were found by the subsequent gas-chromatographic determination. The production of chloroform can be calculated by means of a quadratic polynomial in dependence on COD-Mn, chlorine concentration and pH-value. 相似文献
9.
The method is based on the determination of the number of the nonmotile sperms and/or the lethally damaged sperms with the aid of the fluorescent dye primuline. Incubation takes place at a suspension density of 10.000/mm3… 38.000/mm3, at 40°C or 46 °C for 15… 60 min. During the test with sublimate the loss of motility amounts to 55% at 4 mg/l Hg2+, the LC50 is 7.3 mg/l Hg2+. Phenyl-mercuric acetate causes the total loss of motility with 20 mg/l, the LC50 is above 168 mg/l (equivalent to 100 mg/l Hg2+). The LC50 of sodiumpentadecylmonosulphonate and dodecylpyridinchloride are 11.6 and 15.8 mg/l, resp. Filtrates of blooming of cyanophyceae on Baltic, having been digested by repeated freezing and thawing, with 1.5… 6.4 g/l dry matter showed motility losses of 30… 100 % for Nodularia spumigena, whereas no significant effect was produced by a filtrate of Microcystis aeruginosa with 28.2 g/l dry matter as well as water-blooming of Nodularia spumigena from the Small Jasmund Bodden. 相似文献
10.
The LC50 of Malathion for Channu punctatus is determined for 24… 96 h of exposure as 10.95… 3.22 mg/l. At exposure to 2.5 mg./l Malathion, growth–measured by increase in weight–is significantly reduced from the 19th day and reduced by 10 % till the 31st day. During the same period of time, the RNA and protein contents of the muscle is lowered by 10 and 15 %, respectively, as compared with the control. In addition to an acute toxic effect, in sublethal concentrations Malathion has also pronounced effects on growth and metabolism. 相似文献
11.
The Actinomycetes strain of the genus Rhodococcus having been isolated from the river Saale is able to use phenol as the sole carbon source up to concentrations of 2 g/l and metabolizes phenol via the β-ketoadipic acid path (ortho-cleavage). The synthesis of the inducable enzyme system can be inhibited by chloramphenicol. In detailed experiments in discontinuous and continuous cultures the growth rate and the yield coefficient attain their maxima of 0.256 h?1 and 0.62, resp., at phenol concentrations of 0.5 … 0.8 g/l. At higher substrate concentrations there occurs a substrate inhibition. In the range between 20 and 40°C growth and phenol utilization are highly dependent on temperature. 相似文献
12.
As investigations on model solutions and real wastewaters with 30 … 33 g/l phenol and 5 … 10 g/l formaldehyde as well as pH = 2 … 3 have shown, the following technique of sewage purification proves to be optimal: condensation with addition of 7 g/l sulphuric acid at 98 °C, settling of the condensation products formed for 8 h, centrifugation of the supernatant and adsorption on activated carbon or a polymer sorbent (XAD 4). Preference should be given to activated carbon. The residual concentrations amount to 0.1 mg/l for both phenol and formaldehyde. The adsorbents are largely fully regenerated with methanol, the regeneration solution containing 11 … 20 g/l phenol. 相似文献
13.
P. Loth 《洁净——土壤、空气、水》1989,17(2):153-158
A mass development of Uroglena americana with cellular densities of up to 13.5 · 106 and 86.106 cells/l, was observed in two drinking-water reservoirs. In the first case the development remained confined to the upper 20 m, in the second case there occurred a gradual shift of the maximum to deeper zones from May to July with decreasing cellular densities down to a depth of 35 m. Laboratory experiments for the control of the algae development were performed in order to protect the drinking-water resources from potential impairments of odour and taste. Samples of the storage-reservoir water with 20.106 cells/l of Uroglena were concentrated up to 1.25 … 12.5 mg/l Ca(OH)2 (pH-values of 7.2 … 9.6) by addition of calcium hydroxide and observed for 39 h. First impairment of the cells of Uroglena is detectable at 5 mg/l Ca(OH)2 after 15 h, an immediate effect can be observed at 7.5 mg/l Ca(OH)2 together with increased sedimentation, also Gymnodinium and Cryptomonas having been damaged. Thereupon a successful control of Uroglena by liming up to pH-values above 8.0 is possible. The application of lime to outdoor areas was not necessary, in the final analysis, since the drinking-water quality could be secured by the optimum choice of the intake depth of raw water with a maximum of 4.103 to 77.103 cells/l. 相似文献
14.
D. J. Stom S. S. Timofeeva N. F. Kashina L. J. Bielykh S. N. Souslov V. V. Boutoeov M. S. Apartzin 《洁净——土壤、空气、水》1980,8(3):223-230
In two test series, for which 10 and 2 … 4 g/1 wet matter of higher and lower aquatic plants from the lake Baikal and from the waters in the surroundings of Irkutsk were used, phenol solutions having concentrations of 10?3 … 10?5 M (1 … 5 mg/1) were applied. During the investigations the possible error clue to the presence of microorganisms was eliminated. The phenol decomposition by aquatic plants proceeds as a first-order reaction. The results of analyses are summarized in several tables and graphical representations. 相似文献
15.
— The 96 h TL50 values, the maximum acceptable toxicant concentration (MATC) and the safe concentrations were determined for various aquatic pollutants, viz. thiotox, chlordane, metasystox, dichlorvos, sevin and carbofuran (pesticides), phenol, pentachlorophenol and dinitrophenol (phenolic compounds), cadmium chloride and copper sulphate (heavy metal), swascofix P14, swanic 6 L and swascol 1P (synthetic detergent) using the larvae (the most sensitive stage of the life cycle) of Cyprinus carpio, a fresh water exotic carp. — The estimated MATC ranged between 0.009 and 400 μg/1 for all the pollutants; — the calculated value of the application factor (AF) ranged between 0.0096 and 0.0978. — The safe concentrations were determined for each pollutant by the lowest value of application factor worked out in the present investigation; — safe concentrations were also worked out by different formulae given by different workers. The values obtained were compared with the safe concentrations value worked out by the authors of the present study. 相似文献
16.
- The present investigation was undertaken to evaluate the effects of three sublethal concentrations (1/10th, 1/15th and 1/20th fractions of 96 h LC50) of phenol (P), dinitrophenol (DNP), pentachlorophenol (PCP) and their antagonistic [(PCP + DNP)/P], additive [(DNP + P)/PCP] and synergistic [(P + DNP)/PCP] combinations, on several organic and inorganic components of haemopoetic systems of Notopterus notopterus after 30 d of exposure.
- Glucose, lactate, total phosphorus, non-protein nitrogen, sodium, potassium, magnesium, calcium, iron and chloride were found to be increased in most cases while protein and cholesterol were found to be decreased.
- It has been concluded that these alterations in blood parameters might be due to a damage or hyperactivity of liver, kidney and endocrine glands, the main centres for controlling the tissue metabolism.
17.
Hydrobiological Investigations of the Water Quality of the Water Supply Reservoirs Husinec and Římov
P. Porcalov 《洁净——土壤、空气、水》1985,13(2):149-153
The two eutrophicated reservoirs Husinec (2.6 km3, 35 ha, zmax 18 m, MQ 1.87 m3/s) and ?ímov (34.5 hm3, 216 ha, zmax 44 m, MQ 4.14 m3/s) show concentrations of total phosphorus of 10… 50 mg/m3 and chlorophyll contents of 7… 36 mg/m3 in the summer season. For both reservoirs a good correlation exists between the chlorophyll concentration and the density of the phytoplankton (20 · 103… 13 · 106 ind./l). With average concentrations of 10… 20 mg/m3 chlorophyll a in summer, the water can be treated for producing drinking water only at a higher expenditure. The water quality will be improved by a reduction of the phosphorus load. 相似文献
18.
Ultraviolet derivative spectroscopy was used as an analytical tool for the direct and simultaneous determination of aniline and phenol in water. It is shown that the diA/dλi values are proportional to aniline (i = 2, 4) and phenol (i = 2, 4 and 5) concentrations at 205.3 or 271.6 … 282.8 nm. The performance characteristics are discussed in detail. Thus the best precision resulted in both aniline and phenol for the second derivatives. The accuracy of the methods applied is independent on the derivative order and concentration levels within the dynamic range of 1 to 10 mg · 1?1 aniline or phenol respectively. 相似文献
19.
After extensive experiments aimed at determining the free volatile fatty acids (C2 to C6) in organically highly polluted percolation water of household refuse dumping places there proved optimum a column packed with 10% Carbowax 20 M on Chromatron N-AW-DMCS after having been conditioned for five days at 270°C and subsequently covered with 10% hard wax. On short retention times the investigated isomeric column pairs are completely separated. Equally favourable results were obtained also for liquid manure and silage extracts. The detection limits lie between 10 and 20 mg/l, the relative standard deviation is 20 … 30% in the range of the lower detection limit and 2 … 3% at 200 mg/l in the upper range. In the investigation of percolation waters with concentrations between 235 and 4300 mg/l reproducibility lies at a mean relative standard deviation of 0.5 … 2.8%. The technique is well suited for routine checking. 相似文献
20.
G. Hanschmann 《洁净——土壤、空气、水》1991,19(3):265-266
Humic substances (HS) can be extracted from water into chloroform in one step by means of cetyl-pyridinium chloride and sodium chloride. The absorbance (at 450 nm) of the extract is proportional to the HS content. Two procedures are presented for HS concentrations of 2 … 20 mg/l and 20 … 200 mg/l water, respectively. 相似文献