首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 500 毫秒
1.
The EH and EL enstatite chondrites are the most reduced chondrite groups, having formed in nebular regions where the gas may have had high C/O and/or pH2/pH2O ratios. Enstatite chondrites (particularly EH) have higher CI- and Mg-normalized abundances of halogens (especially F and Cl) and nitrogen than ordinary chondrites and most groups of carbonaceous chondrites. Even relative to CI chondrites, EH and EL chondrites are enriched in F. We have found that literature values for the halogen abundance ratios in EH and EL chondrites are strongly correlated with the electronegativities of the individual halogens. We suggest that the most reactive halogens were the most efficient at forming compounds (e.g., halides) that were incorporated into EH-chondrite precursor materials. It seems plausible that, under the more-oxidizing conditions pertaining to the other chondrite groups, a larger fraction of the halogens remained in the gas. Nitrogen may have been incorporated into the enstatite chondrites as simple nitrides that did not condense under the more-oxidizing conditions in the regions where other chondrite groups formed. Literature data show that unequilibrated enstatite chondrites have light bulk N (δ 15N ≈ −20‰) compared to most ordinary (−5 to +20‰) and carbonaceous (+20 to +190‰) chondrites; this may reflect the contribution in enstatite chondrites of nitride condensates with δ15 N values close to the proposed nebular mean (~−400‰). In contrast, N in carbonaceous chondrites is mainly contained within 15N-rich organic matter. The major carrier of N in ordinary chondrites is unknown.  相似文献   

2.
Abstract– Six chondritic clasts in the Cumberland Falls polymict breccia were examined: four texturally resemble ordinary chondrites (OCs) and two are impact melt breccias containing shocked OC clasts adjacent to a melt matrix. The six chondritic clasts are probably remnants of a single OC projectile that was heterogeneously shocked when it collided with the Cumberland Falls host. Mayo Belwa is the first known aubrite impact melt breccia. It contains coarse enstatite grains exhibiting mosaic extinction; the enstatite grains are surrounded by a melt matrix composed of 3–16 μm‐size euhedral and subhedral enstatite grains embedded in sodic plagioclase. Numerous vugs, ranging from a few micrometers to a few millimeters in size, constitute ～5 vol% of the meteorite. They occur nearly exclusively within the Mayo Belwa matrix; literature data show that some vugs are lined with bundles of acicular grains of the amphibole fluor‐richterite. This phase has been reported previously in only two other enstatite meteorites (Abee and St. Sauveur), both of which are EH‐chondrite impact melt breccias. It seems likely that in Mayo Belwa, volatiles were vaporized during an impact event and formed bubbles in the melt. As the melt solidified, the bubbles became cavities; plagioclase and fluor‐richterite crystallized at the margins of these cavities via reaction of the melt with the vapor.  相似文献   

3.
Abstract— The enstatite chondrite reckling peak (rkp) a80259 contains feldspathic glass, kamacite, troilite, and unusual sets of parallel fine‐grained enstatite prisms that formed by rapid cooling of shock melts. Metallic Fe,Ni and troilite occur as spherical inclusions in feldspathic glass, reflecting the immiscible Fe‐Ni‐S and feldspathic melts generated during the impact. The Fe‐Ni‐S and feldspathic liquids were injected into fractures in coarse‐grained enstatite and cooled rapidly, resulting in thin (≤ 10 μm) semicontinuous to discontinuous veins and inclusion trails in host enstatite. Whole‐rock melt veins characteristic of heavily shocked ordinary chondrites are conspicuously absent. Raman spectroscopy shows that the feldspathic material is a glass. Elevated MgO and SiO2 contents of the glass indicate that some enstatite and silica were incorporated in the feldspathic melt. Metallic Fe,Ni globules are enclosed by sulfide and exhibit Nienrichment along their margins characteristic of rapid crystallization from a Fe‐Ni‐S liquid. Metal enclosed by sulfide is higher in Si and P than metal in feldspathic glass and enstatite, possibly indicating lower O fugacities in metal/sulfide than in silicate domains. Fine‐grained, elongate enstatite prisms in troilite or feldspathic glass crystallized from local pyroxene melts that formed along precursor grain boundaries, but most of the enstatite in the target rock remained solid during the impact and occurs as deformed, coarsegrained crystals with lower CaO, Al2O3, and FeO than the fine‐grained enstatite. Reckling Peak A80259 represents an intermediate stage of shock melting between unmelted E chondrites and whole‐rock shock melts and melt breccias documented by previous workers. The shock petrogenesis of RKPA80259 reflects the extensive impact processing of the enstatite chondrite parent bodies relative to those of other chondrite types.  相似文献   

4.
Our survey of type 4–6 ordinary chondrites indicates that gas-poor, melt-rock and/or exotic clast-bearing fragmental breccias constitute 5%, 22% and 23%, respectively, of H, L and LL chondrites. These abundances contrast with the percentages of solar-gas-rich regolith breccias among ordinary chondrites: H (14%), L (3%) and LL (8%) (Crabb and Schultz, 1981). Petrologic study of several melt-rock-clast-bearing fragmental breccias indicates that some acquired their clasts prior to breccia metamorphism and others acquired them after metamorphism of host material. In general, the melt-rock clasts in gas-poor H chondrite fragmental breccias were acquired after breccia metamorphism and were probably formed by impacts into boulders or exposed outcrops of H4-6 material in the H chondrite parent body regolith. In contrast, most of the melt-rock clasts in gas-poor L and LL fragmental breccias were acquired prior to breccia metamorphism. The low abundance of regolith breccias among L chondrites and evidence that at least two-thirds of the L chondrites suffered a major shock event 0.5 Gyr ago, suggest that the L parent body may have been disrupted by a major collision at that time and that the remaining parent body fragments were too small to develop substantial regoliths (e.g., Heymann, 1967; Crabb and Schultz, 1981). Such a disruption would have exposed a large amount of L chondrite bedrock, some of which would consist of fragmental breccias that acquired melt-rock clasts very early in solar system history, prior to metamorphism. The exposed bedrock would serve as a potential target for sporadic meteoroid impacts to produce a few fragmental breccias with unmetamorphosed melt-rock clasts. The high proportion of genomict brecciated LL chondrites reflects a complex collisional history, probably including several episodes of parent body disruption and gravitational reassembly. Differences in the abundances of different kinds of breccias among the ordinary chondrite groups are probably due to the stochastic nature of major asteroidal collisions.  相似文献   

5.
Abstract– Metamorphosed clasts in the CV carbonaceous chondrite breccias Mokoia and Yamato‐86009 (Y‐86009) are coarse‐grained, granular, polymineralic rocks composed of Ca‐bearing (up to 0.6 wt% CaO) ferroan olivine (Fa34–39), ferroan Al‐diopside (Fs9–13Wo47–50, approximately 2–7 wt% Al2O3), plagioclase (An37–84Ab63–17), Cr‐spinel (Cr/(Cr + Al) = 0.19–0.45, Fe/(Fe + Mg) = 0.60–0.79), nepheline, pyrrhotite, pentlandite, Ca‐phosphate, and rare grains of Ni‐rich taenite; low‐Ca pyroxene is absent. Most clasts have triple junctions between silicate grains, indicative of prolonged thermal annealing. Based on the olivine‐spinel and pyroxene thermometry, the estimated metamorphic temperature recorded by the clasts is approximately 1100 K. Few clasts experienced thermal metamorphism to a lower degree and preserved chondrule‐like textures. The Mokoia and Y‐86009 clasts are mineralogically unique and different from metamorphosed chondrites of known groups (H, L, LL, R, EH, EL, CO, CK) and primitive achondrites (acapulcoites, brachinites, lodranites). On a three‐isotope oxygen diagram, compositions of olivine in the clasts plot along carbonaceous chondrite anhydrous mineral line and the Allende mass‐fractionation line, and overlap with those of the CV chondrule olivines; the Δ17O values of the clasts range from about ?4.3‰ to ?3.0‰. We suggest that the clasts represent fragments of the CV‐like material that experienced metasomatic alteration, high‐temperature metamorphism, and possibly melting in the interior of the CV parent asteroid. The lack of low‐Ca pyroxene in the clasts could be due to its replacement by ferroan olivine during iron‐alkali metasomatic alteration or by high‐Ca ferroan pyroxene during melting under oxidizing conditions.  相似文献   

6.
Abstract— Bencubbin is an unclassified meteorite breccia which consists mainly of host silicate (～40 vol.%) and host metal (～60%) components. Rare (< 1%) ordinary chondrite clasts and a dark xenolith (formerly called a carbonaceous chondrite clast) are also found. A petrologic study of the host silicates shows that they have textures, modes, mineralogy and bulk compositions that are essentially the same as that of barred olivine (BO) chondrules, and they are considered to be BO chondritic material. Bulk compositions of individual host silicate clasts are identical and differ only in their textures which are a continuum from coarsely barred, to finely barred, to feathery microcrystalline; these result from differing cooling rates. The host silicates differ from average BO chondrules only in being angular clasts rather than fluid droplet-shaped objects, and in being larger in size (up to 1 cm) than most chondrules; but large angular to droplet-shaped chondrules occur in many chondrites. Bencubbin host metallic FeNi clasts have a positive Ni-Co trend, which coincides with that of a calculated equilibrium nebular condensation path. This appears to indicate a chondritic, rather than impact, origin for this component as well. The rare ordinary chondrite clast and dark xenolith also contain FeNi metal with compositions similar to that of the host metal. Two scenarios are offered for the origin of the Bencubbin breccia. One is that the Bencubbin components are chondritic and were produced in the solar nebula. Later brecciation, reaggregation and minor melting of the chondritic material resulted in it becoming a monomict chondritic breccia. The alternative scenario is that the Bencubbin components formed as a result of major impact melting on a chondritic parent body; the silicate fragments were formed from an impact-induced lava flow and are analogous to the spinifex-textured rocks characteristic of terrestrial komatiites. Both scenarios have difficulties, but the petrologic, chemical and isotopic data are more consistent with Bencubbin being a brecciated chondrite. Bencubbin has a number of important chemical and isotopic characteristics in common with the major components in the CR (Renazzo-type) chondrites and the unique ALH85085 chondrite, which suggests that their major components may be related. These include: (1) Mafic silicates that are similarly Mg-rich and formed in similar reducing environments. (2) Similarly low volatiles; TiO2, Al2O3 and Cr2O3 contents are also similar. (3) Similar metallic FeNi compositions that sharply differ from those in other chondrites. (4) Remarkable enrichments in 15N. (5) Similar oxygen isotopic compositions that lie on the same mixing line. Thus, the major components of the Bencubbin breccia are highly similar to those of the ALH85085 and CR chondrites and they may have all formed in the same isotopic reservoir, under similar conditions, in the CR region of the solar nebula.  相似文献   

7.
Abstract— Six ordinary chondrite breccias from the Museo Nacional de Ciencias Naturales, Madrid (Spain), are described and classified as follows: the solar gas-rich regolith breccia Oviedo (H5); the pre-metamorphic fragmental breccias Cabezo de Mayo (type 6, L-LL), and Sevilla (LL4); the fragmental breccias Cañellas (H4) and Gerona (H5); and the impact melt breccia, Madrid (L6). We confirm that chondrites with typical light-dark structures and petrographic properties typical of regolith breccias may (Oviedo) or may not (Cañellas) be solar gas-rich. Cabezo de Mayo and Sevilla show convincing evidence that they were assembled prior to peak metamorphism and were equilibrated during subsequent reheating. These meteorites contain small melt rock clasts that were incorporated into the host chondrite while still molten and/or plastic and cooled rapidly and, yet, are totally equilibrated with their hosts. Compositions of olivine and low-Ca pyroxene in host chondrite and breccia clasts in Cabezo de Mayo are transitional between groups L and LL. It is suggested, based on mineralogic and oxygen isotopic compositions of host and clasts, that the rock formed on the L parent body by mixing, prior to peak metamorphism. This was followed by partial equilibration of two different materials: the indigenous L chondrite host and exotic LL melt rock clasts.  相似文献   

8.
Abstract— We review the meteoritical and astronomical literature to answer the question: What is the evidence for the importance of ordinary chondritic material to the composition of the asteroid belt? From the meteoritical literature, we find that currently (1) our meteorite collections sample at least 135 different asteroids; (2) out of 25+ chondritic meteorite parent bodies, 3 are (by definition) ordinary chondritic; (3) out of 14 chondritic grouplets and unique chondrites, 11 are affiliated with a carbonaceous group/clan of chondrites; (4) out of 24 differentiated groups of meteorites, only the HE iron meteorites clearly formed from ordinary chondritic precursor material; (5) out of 12 differentiated grouplets and unique differentiated meteorites, 8 seem to have had carbonaceous chondritic precursors; (6) a high frequency of carbonaceous clasts in ordinary chondritic breccias suggests that ordinary chondrites have been embedded in a swarm of carbonaceous material. The rare occurrence (only one example) of ordinary chondritic clasts in carbonaceous chondritic breccias indicates that ordinary chondritic material has not been widespread in the asteroid belt; (7) cosmic spherules, micrometeorites, and stratospheric interplanetary dust particles—believed to represent a less biased sampling of asteroidal material—show that only a very small fraction (less than ～1%) of asteroidal dust has an ordinary chondritic composition. From the astronomical literature, we find that currently (8) spectroscopic surveys of the main asteroid belt are finding more and more nonordinary chondritic primitive material in the inner main belt; (9) the increase in spectroscopic data has increased the inferred mineralogical diversity of main belt asteroids; and (10) no ordinary chondritic asteroids have been directly observed in the main belt. These lines of evidence strongly suggest a scenario in which ordinary chondritic asteroids were never abundant in the main belt. The S-type asteroids may currently be primarily differentiated, but the precursor material is more likely to have been carbonaceous chondritic, not ordinary chondritic. Historically, carbonaceous material could have dominated the entire main belt. This could explain the presence in the inner main belt of asteroids linked to the primitive carbonaceous chondrites, and the absence of asteroids linked to the ordinary chondrites. The implications of this scenario for the asteroid heating mechanism(s) are briefly discussed.  相似文献   

9.
Abstract— The Kaidun meteorite contains carbonaceous chondrite (CM1) clasts that have been highly altered by reactions with hydrothermal fluids. Pyrrhotite in these clasts occurs as unusual needles wrapped by sheaths of phyllosilicate, and pentlandite forms veins that crosscut aggregates of phyllosilicate and garnet but not pyrrhotite. The isotopic compositions of S (δ34SCDT) in individual sulfide grains, measured by ion micro-probe, are fractionated compared to troilite in ordinary chondrites. The S in Kaidun sulfides is isotopically light (as much as ?4.2% for pyrrhotite and ?5.7%0 for pentlandite), unlike sulfides in other carbonaceous chondrites, which are enriched in 34S. The unusual S-isotopic composition of these texturally unique sulfides supports the hypothesis that Kaidun CM1 clasts were pervasively altered under extreme thermal conditions, possibly by fluids that had lost isotopically heavy SO2.  相似文献   

10.
Abstract— Rumuruti (R) chondrites constitute a new, well‐established chondrite group different from the carbonaceous, ordinary, and enstatite chondrites. Many of these samples are gas‐rich regolith breccias showing the typical light‐dark structure and consist of abundant fragments of various parent‐body lithologies embedded in a fine‐grained olivine‐rich matrix. Unequilibrated type‐3 lithologies among these fragments have frequently been mentioned in various publications. In this study, detailed mineralogical data on seven primitive fragments from the R‐chondrites Dar al Gani 013 and Hughes 030 are presented. The fragments range from ～300 μ in size up to several millimeters. Generally, the main characteristics can be summarized as follows: (1) Unequilibrated type‐3 fragments have a well‐preserved chondritic texture with a chondrule‐to‐matrix ratio of ～1:1. Chondrules and chondrule fragments are embedded in a fine‐grained olivine‐rich matrix. Thus, the texture is quite similar to that of type‐3 carbonaceous chondrites. (2) In all cases, matrix olivines in type‐3 fragments have a significantly higher Fa content (44–57 mol%) than olivines in other (equilibrated) lithologies (38–40 mol% Fa). (3) Olivines and pyroxenes occurring within chondrules or as fragments are highly variable in composition (Fa0–65 and Fs0–33, respectively) and, generally, more magnesian than those found in equilibrated R chondrites. Agglomerated material of the R‐chondrite parent body (or bodies) was highly unequilibrated. It is suggested that the material that accreted to form the parent body consisted of chondrules and chondrule fragments, mainly having Mg‐rich silicate constituents, and Fe‐rich highly oxidized fine‐grained materials. The dominating phase of this fine‐grained material may have been Fa‐rich olivine from the beginning. The brecciated whole rocks, the R‐chondrite regolith breccias, were not significantly reheated subsequent to brecciation or during lithification, as indicated by negligible degree of equilibration between matrix components and Mg‐rich olivines and pyroxenes in primitive type‐3 fragments.  相似文献   

11.
We used chemical equilibrium and chemical kinetic calculations to model chemistry of the volatiles released by heating different types of carbonaceous, ordinary and enstatite chondritic material as a function of temperature and pressure. Our results predict the composition of atmospheres formed by outgassing during accretion of the Earth and other terrestrial planets. Outgassing of CI and CM carbonaceous chondritic material produces H2O-rich (steam) atmospheres in agreement with the results of impact experiments. However, outgassing of other types of chondritic material produces atmospheres dominated by other gases. Outgassing of ordinary (H, L, LL) and high iron enstatite (EH) chondritic material yields H2-rich atmospheres with CO and H2O being the second and third most abundant gases. Outgassing of low iron enstatite (EL) chondritic material gives a CO-rich atmosphere with H2, CO2, and H2O being the next most abundant gases. Outgassing of CV carbonaceous chondritic material gives a CO2-rich atmosphere with H2O being the second most abundant gas. Our results predict that the atmospheres formed during accretion of the Earth and Mars were probably H2-rich unless the accreted material was dominantly CI and CM carbonaceous chondritic material. We also predict significant amounts of S, P, Cl, F, Na, and K in accretionary atmospheres at high temperatures (1500-2500 K). Finally, our results may be useful for interpreting spectroscopic observations of accreting extrasolar terrestrial planets.  相似文献   

12.
Abstract— In situ io n microprobe analyses of spinel in refractory calcium‐aluminium‐rich inclusions (CAIs) from type 3 EH chondrites yield 16O‐rich compositions (δ 18O and δ 17O about‐40‰). Spinel and feldspar in a CAI from an EL3 chondrite have significantly heavier isotopic compositions (δ 18O and δ 17O about ?5‰). A regression through the data results in a line with slope 1.0 on a three‐isotope plot, similar to isotopic results from unaltered minerals in CAIs from carbonaceous chondrites. The existence of CAIs with 16O‐rich and 16O‐poor compositions in carbonaceous as well as enstatite chondrites indicates that CAIs formed in at least two temporally or spatially distinct oxygen reservoirs. General similarities in oxygen isotopic compositions of CAIs from enstatite, carbonaceous, and ordinary chondrites indicate a common nebular mechanism or locale for the production of most CAIs.  相似文献   

13.
Abstract— Like calcium‐aluminum‐rich inclusions (CAIs) from carbonaceous and ordinary chondrites, enstatite chondrite CAIs are composed of refractory minerals such as spinel, perovskite, Al, Ti‐diopside, melilite, hibonite, and anorthitic plagioclase, which may be partially to completely surrounded by halos of Na‐(±Cl)‐rich minerals. Porous, aggregate, and compact textures of the refractory cores in enstatite chondrite CAIs and rare Wark—Lovering rims are also similar to CAIs from other chondrite groups. However, the small size (<100μm), low abundance (<1% by mode in thin section), occurrence of only spinel or hibonite‐rich types, and presence of primary Ti‐(±V)‐oxides, and secondary geikelite and Ti, Fe‐sulfides distinguish the assemblage of enstatite chondrite CAIs from other groups. The primary mineral assemblage in enstatite chondrite CAIs is devoid of indicators (e.g., oldhamite, osbornite) of low O fugacities. Thus, high‐temperature processing of the CAIs did not occur under the reducing conditions characteristic of enstatite chondrites, implying that either (1) the CAIs are foreign to enstatite‐chondrite‐forming regions or (2) O fugacities fluctuated within the enstatite‐chondrite‐forming region. In contrast, secondary geikelite and Ti‐Fe‐sulfide, which replace perovskite, indicate that alteration of perovskite occurred under reducing conditions distinct from CAIs in the other chondrite groups. We have not ascertained whether the reduced alteration of enstatite chondrite CAIs occurred in a nebular or parent‐body setting. We conclude that each chondrite group is correlated with a unique assemblage of CAIs, indicating spatial or temporal variations in physical conditions during production or dispersal of CAIs.  相似文献   

14.
Abstract— The Rumuruti meteorite shower fell in Rumuruti, Kenya, on 1934 January 28 at 10:43 p.m. Rumuruti is an olivine-rich chondritic breccia with light-dark structure. Based on the coexistence of highly recrystallized fragments and unequilibrated components, Rumuruti is classified as a type 3–6 chondrite breccia. The most abundant phase of Rumuruti is olivine (mostly Fa～39) with about 70 vol%. Feldspar (～14 vol%; mainly plagioclase), Ca-pyroxene (5 vol%), pyrrhotite (4.4 vol%), and pentlandite (3.6 vol%) are major constituents. All other phases have abundances below 1 vol%, including low-Ca pyroxene, chrome spinels, phosphates (chlorapatite and whitlockite), chalcopyrite, ilmenite, tridymite, Ni-rich and Ge-containing metals, kamacite, and various particles enriched in noble metals like Pt, Ir, arid Au. The chemical composition of Rumuruti is chondritic. The depletion in refractory elements (Sc, REE, etc.) and the comparatively high Mn, Na, and K contents are characteristic of ordinary chondrites and distinguish Rumuruti from carbonaceous chondrites. However, S, Se, and Zn contents in Rumuruti are significantly above the level expected for ordinary chondrites. The oxygen isotope composition of Rumuruti is high in δ17O (5.52 ‰) and δ18O (5.07 ‰). Previously, a small number of chondritic meteorites with strong similarities to Rumuruti were described. They were called Carlisle Lakes-type chondrites and they comprise: Carlisle Lakes, ALH85151, Y-75302, Y-793575, Y-82002, Acfer 217, PCA91002, and PCA91241, as well as clasts in the Weatherford chondrite. All these meteorites are finds from hot and cold deserts having experienced various degrees of weathering. With Rumuruti, the first meteorite fall has been recognized that preserves the primary mineralogical and chemical characteristics of a new group of meteorites. Comparing all chondrites, the characteristic features can be summarized as follows: (a) basically chondritic chemistry with ordinary chondrite element patterns of refractory and moderately volatile lithophiles but higher abundances of S, Se, and Zn; (b) high degree of oxidation (37–41 mol% Fa in olivine, only traces of Fe, Ni-metals, occurrence of chalcopyrite); (c) exceptionally high Δ17O values of about 2.7 for bulk samples; (d) high modal abundance of olivine (～70 vol%); (e) Ti-Fe3+?rich chromite (～5.5 wt% TiO2); (f) occurrence of various noble metal-rich particles; (g) abundant chondritic breccias consisting of equilibrated clasts and unequilibrated lithologies. With Rumuruti, nine meteorite samples exist that are chemically and mineralogically very similar. These meteorites are attributed to at least eight different fall events. It is proposed in this paper to call this group R chondrites (rumurutiites) after the first and only fall among these meteorites. These meteorites have a close relationship to ordinary chondrites. However, they are more oxidized than any of the existing groups of ordinary chondrites. Small, but significant differences in chemical composition and in oxygen isotopes between R chondrites and ordinary chondrites exclude formation of R chondrites from ordinary chondrites by oxidation. This implies a separate, independent R chondrite parent body.  相似文献   

15.
Scott A. Sandford 《Icarus》1984,60(1):115-126
Infrared transmission spectra from 53 meteorites in the spectral range from 2.5 to 25 μm were measured to permit comparisons with data of astronomical objects that are potential meteorite sources. Data were taken for 14 carbonaceous chondrites, 5 LL ordinary chondrites, 6 L ordinary chondrites, 10 H ordinary chondrites, 1 enstatite chondrite, 4 aubrites, 3 eucrites, 4 howardites, 1 diogenite, 1 mesosiderite, 2 nakhlites, 1 shergottite, and the anomalous achondrite Angra dos Reis. The CO and CV carbonaceous chondrites have spectra similar to each other, with 10-μm features characteristic of olivine. The CM carbonaceous chondrites have distinctive 10-μm features that are attributed to layer lattice silicates. Members of both the CI and CR classes have spectra distinct from those of other carbonaceous chondrites. The LL, L, and H ordinary chondrites have spectra that match those of olivine and pyroxene mixtures. The enstatite chondrites and enstatite achondrites (aubrites) all exhibit spectra diagnostic of the pyroxene enstatite. The angrite, howardites, aucrites, nakhlites, shergottite, and diogenite all have similar spectra also dominated by pyroxene. The single mesosiderite examined had a spectrum distinct from all the other meteorites.  相似文献   

16.
Abstract— We studied the elemental and isotopic abundances of noble gases (He, Ne, Ar in most cases, and Kr, Xe also in some cases) in individual chondrules separated from six ordinary, two enstatite, and two carbonaceous chondrites. Most chondrules show detectable amounts of trapped 20Ne and 36Ar, and the ratio (36Ar/20Ne)t (from ordinary and carbonaceous chondrites) suggests that HL and Q are the two major trapped components. A different trend between (36Ar/20Ne)t and trapped 36Ar is observed for chondrules in enstatite chondrites indicating a different environment and/or mechanism for their formation compared to chondrules in ordinary and carbonaceous chondrites. We found that a chondrule from Dhajala chondrite (DH‐11) shows the presence of solar‐type noble gases, as suggested by the (36Ar/20Ne)t ratio, Ne‐isotopic composition, and excess of 4He. Cosmic‐ray exposure (CRE) ages of most chondrules are similar to their host chondrites. A few chondrules show higher CRE age compared to their host, suggesting that some chondrules and/or precursors of chondrules have received cosmic ray irradiation before accreting to their parent body. Among these chondrules, DH‐11 (with solar trapped gases) and a chondrule from Murray chondrite (MRY‐1) also have lower values of (21Ne/22Ne)c, indicative of SCR contribution. However, such evidences are sporadic and indicate that chondrule formation event may have erased such excess irradiation records by solar wind and SCR in most chondrules. These results support the nebular environment for chondrule formation.  相似文献   

17.
Abstract— The N and C abundances and isotopic compositions of acid-insoluble carbonaceous material in thirteen primitive chondrites (five unequilibrated ordinary chondrites, three CM chondrites, three enstatite chondrites, a CI chondrite and a CR chondrite) have been measured by stepped combustion. While the range of C isotopic compositions observed is only ～δ13C = 30%, the N isotopes range from δ15N ' -40 to 260%. After correction for metamorphism, presolar nanodiamonds appear to have made up a fairly constant 3–4 wt% of the insoluble C in all the chondrites studied. The apparently similar initial presolar nanodiamond to organic C ratios, and the correlations of elemental and isotopic compositions with metamorphic indicators in the ordinary and enstatite chondrites, suggest that the chondrites all accreted similar organic material. This original material probably most closely resembles that now found in Renazzo and Semarkona. These two meteorites have almost M-shaped N isotope release profiles that can be explained most simply by the superposition of two components, one with a composition between δ15N = -20 and -40% and a narrow combustion interval, the other having a broader release profile and a composition of δ15N ～ 260%. Although isotopically more subdued, the CI and the three CM chondrites all appear to show vestiges of this M-shaped profile. How and where the components in the acid-insoluble organics formed remains poorly constrained. The small variation in nanodiamond to organic C ratio between the chondrite groups limits the local synthesis of organic matter in the various chondrite formation regions to at most 30%. The most 15N-rich material probably formed in the interstellar medium, and the fraction of organic N in Renazzo in this material ranges from 40 to 70%. The isotopically light component may have formed in the solar system, but the limited range in nanodiamond to total organic C ratios in the chondrite groups is consistent with most of the organic material being presolar.  相似文献   

18.
CM chondrites are complex impact (mostly regolith) breccias, in which lithic clasts show various degrees of aqueous alteration. Here, we investigated the degree of alteration of individual clasts within 19 different CM chondrites and CM‐like clasts in three achondrites by chemical analysis of the tochilinite‐cronstedtite‐intergrowths (TCIs; formerly named “poorly characterized phases”). To identify TCIs in various chondritic lithologies, we used backscattered electron (BSE) overview images of polished thin sections, after which appropriate samples underwent electron microprobe measurements. Thus, 75 lithic clasts were classified. In general, the excellent work and specific criteria of Rubin et al. (2007) were used and considered to classify CM breccias in a similar way as ordinary chondrite breccias (e.g., CM2.2‐2.7). In BSE images, TCIs in strongly altered fragments in CM chondrites (CM2.0‐CM2.2) appear dark grayish and show a low contrast to the surrounding material (typically clastic matrix), and can be distinguished from TCIs in moderately (CM2.4‐CM2.6) or less altered fragments (CM2.7‐CM2.9); the latter are bright and have high contrast to the surroundings. We found that an accurate subclassification can be obtained by considering only the “FeO”/SiO2 ratio of the TCI chemistry. One could also consider the TCIs’ S/SiO2 ratio and the metal abundance, but these were not used for classification due to several disadvantages. Most of the CM chondrites are finds that have suffered terrestrial weathering in hot and cold deserts. Thus, the observed abundance of metal is susceptible to weathering and may not be a reliable indicator of subtype classification. This study proposes an extended classification scheme based on Rubin’s scale from subtypes CM2.0‐CM2.9 that takes the brecciation into account and includes the minimum to maximum degree of alteration of individual clasts. The range of aqueous alteration in CM chondrites and small spatial scale of mixing of clasts with different alteration histories will be important for interpreting returned samples from the OSIRIS‐REx and Hayabusa 2 missions in the future.  相似文献   

19.
Abstract— Approximately 275 mineral species have been identified in meteorites, reflecting diverse redox environments, and, in some cases, unusual nebular formation conditions. Anhydrous ordinary, carbonaceous and R chondrites contain major olivine, pyroxene and plagioclase; major opaque phases include metallic Fe-Ni, troilite and chromite. Primitive achondrites are mineralogically similar. The highly reduced enstatite chondrites and achondrites contain major enstatite, plagioclase, free silica and kamacite as well as nitrides, a silicide and Ca-, Mg-, Mn-, Na-, Cr-, K- and Ti-rich sulfides. Aqueously altered carbonaceous chondrites contain major amounts of hydrous phyllosilicates, complex organic compounds, magnetite, various sulfates and sulfides, and carbonates. In addition to kamacite and taenite, iron meteorites contain carbides, elemental C, nitrides, phosphates, phosphides, chromite and sulfides. Silicate inclusions in IAB/IIICD and IIE iron meteorites consist of mafic silicates, plagioclase and various sulfides, oxides and phosphates. Eucrites, howardites and diogenites have basaltic to orthopyroxenitic compositions and consist of major pyroxene and calcic plagioclase and several accessory oxides. Ureilites are made up mainly of calcic, chromian olivine and low-Ca clinopyroxene embedded in a carbonaceous matrix; accessory phases include the C polymorphs graphite, diamond, lonsdaleite and chaoite as well as metallic Fe-Ni, troilite and halides. Angrites are achondrites rich in fassaitic pyroxene (i.e., Al-Ti diopside); minor olivine with included magnesian kirschsteinite is also present. Martian meteorites comprise basalts, lherzolites, a dunite and an orthopyroxenite. Major phases include various pyroxenes and olivine; minor to accessory phases include various sulfides, magnetite, chromite and Ca-phosphates. Lunar meteorites comprise mare basalts with major augite and calcic plagioclase and anorthositic breccias with major calcic plagioclase. Several meteoritic phases were formed by shock metamorphism. Martensite (α2-Fe,Ni) has a distorted body-centered-cubic structure and formed by a shear transformation from taenite during shock reheating and rapid cooling. The C polymorphs diamond, lonsdaleite and chaoite formed by shock from graphite. Suessite formed in the North Haig ureilite by reduction of Fe and Si (possibly from olivine) via reaction with carbonaceous matrix material. Ringwoodite, the spinel form of (Mg,Fe)2SiO4, and majorite, a polymorph of (Mg,Fe)SiO3 with the garnet structure, formed inside shock veins in highly shocked ordinary chondrites. Secondary minerals in meteorite finds that formed during terrestrial weathering include oxides and hydroxides formed directly from metallic Fe-Ni by oxidation, phosphates formed by the alteration of schreibersite, and sulfates formed by alteration of troilite.  相似文献   

20.
Abstract— We studied numerous specimens of the Norton County enstatite achondrite (aubrite) by optical microscopy, electron microprobe, and neutron-activation analysis. Our main conclusions are the following: 1. Norton County is a fragmental impact breccia, consisting of a clastic matrix made mostly of crushed enstatite, into which are embedded a variety of mineral and lithic clasts of both igneous and impact melt origin. 2. The Norton County precursor materials were igneous rocks, mostly plutonic orthopyroxenites, not grains formed by condensation from the solar nebula. 3. The Mg-silicate-rich aubrite parent body experienced extensive melting and igneous differentiation, causing formation of diverse lithologies, some of which have not been described previously. These lithologies include dunites (represented by forsterite crystals), plutonic orthopyroxenites (represented by most enstatite crystals in the matrix), plutonic pyroxenites (the pyroxenitic clasts), and plagioclase-silica rocks (like the feldspathic clasts). Presence of impact melt breccias (the microporphyritic clasts and the diopside-plagioclase-silica clast) of still different compositions further attest to the lithologic diversity of the aubrite parent body.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号