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1.
This study presents the potential of multi-frequency electromagnetic induction (EMI) in archaeology. EMI is currently less employed for archaeological prospection with respect to other geophysical techniques. It is capable of identifying shallow subsurface relics by simultaneously measuring the apparent electrical conductivity (ECa) and apparent magnetic susceptibility (MSa). Moreover, frequency sounding is able to quantify the depths and vertical shapes of buried structures. In this study, EMI surveys with five frequencies were performed at two heritage sites with different geological conditions: Han Hangu Pass characterized by cinnamon soil and Xishan Yang by sandy loams. In the first site, high ECa values were observed with variations in depth correlated to archaeological remains. Moreover, electromagnetic anomalies related to an ancient road and five kiln caves were identified. In the second site, an ancient tomb, indicating extremely low ECa and high MSa, was discovered. Its electromagnetic properties are attributed to the cavity and ferroferric oxides.  相似文献   

2.
It is important to understand the link between land surface/soil properties and shallow groundwater quality. To that end, soil properties and near‐water‐table groundwater chemistry of a shallow, unconfined aquifer were measured on a 100‐m grid on a 64‐ha irrigated field in southeastern North Dakota. Soil properties and hydrochemistry were compared via multivariate analysis that included product‐moment correlations and factor analysis/principal component analysis. Topographic low areas where the water table was in close proximity to the soil surface generally had higher apparent electrical conductivity (ECa) and higher percent silt and clay than higher positions on the landscape. The majority of the groundwater was characterized by Ca‐ and Mg‐HCO3 type water and was associated with topographic high areas with lower ECa and net groundwater recharge. Small topographic depressions were areas of higher ECa (net groundwater discharge) where salts that precipitated via evapotranspiration and evaporative discharge dissolved and leached to the groundwater during short‐term depression‐focused recharge events. At this site, groundwater quality and soil ECa were related to surface topography. High‐resolution topography and ECa measurements are necessary to characterize the land surface/soil properties and surficial groundwater quality at the field‐scale and to delineate areas where the shallow groundwater is most susceptible to contamination.  相似文献   

3.
Electromagnetic induction (EMI) instruments provide rapid, noninvasive, and spatially dense data for characterization of soil and groundwater properties. Data from multi-frequency EMI tools can be inverted to provide quantitative electrical conductivity estimates as a function of depth. In this study, multi-frequency EMI data collected across an abandoned uranium mill site near Naturita, Colorado, USA, are inverted to produce vertical distribution of electrical conductivity (EC) across the site. The relation between measured apparent electrical conductivity (ECa) and hydraulic conductivity (K) is weak (correlation coefficient of 0.20), whereas the correlation between the depth dependent EC obtained from the inversions, and K is sufficiently strong to be used for hydrologic estimation (correlation coefficient of ? 0.62). Depth-specific EC values were correlated with co-located K measurements to develop a site-specific ln(EC)–ln(K) relation. This petrophysical relation was applied to produce a spatially detailed map of K across the study area. A synthetic example based on ECa values at the site was used to assess model resolution and correlation loss given variations in depth and/or measurement error. Results from synthetic modeling indicate that optimum correlation with K occurs at ~ 0.5 m followed by a gradual correlation loss of 90% at 2.3 m. These results are consistent with an analysis of depth of investigation (DOI) given the range of frequencies, transmitter–receiver separation, and measurement errors for the field data. DOIs were estimated at 2.0 ± 0.5 m depending on the soil conductivities. A 4-layer model, with varying thicknesses, was used to invert the ECa to maximize available information within the aquifer region for improved correlations with K. Results show improved correlation between K and the corresponding inverted EC at similar depths, underscoring the importance of inversion in using multi-frequency EMI data for hydrologic estimation.  相似文献   

4.
Acute toxicity bioassays were conducted on mine tailings produced by pilot plant testing for the proposed Quartz Hill molybdenum mine, which will be situated near Ketchikan, Alaska. Tailings bioassays were conducted in seawater with juvenile coho salmon (Oncorhynchus kisutch), mussel larvae (Mytilus edulis), infaunal amphipods (Rhepoxynius abronius), and euphausiids (Euphausia pacifica). The same general range of mine tailings concentrations was acutely toxic to all four test species with acute effects observed between 61 000 to 277 000 mg l?1 (wet wt) tailings solids (range of 95% confidence limits for LC50 and EC50 values). Chemical analyses of bioassay test solutions and leaching test solutions were conducted for metals (including Cd, Cu, Pb, Zn, Mn and Mo), EPA Priority Pollutant base/neutral organics, and more general parameters such as sulphate, nitrate/nitrite, cyanides, phosphate and ammonia. Parameters possibly contributing to the observed toxicity were complex contaminant mixtures including total suspended solids and heavy metals. The present study provides information related to the marine disposal of mine tailings and shows that these mine tailings present a relatively low level of acutely toxic effects.  相似文献   

5.
《水文科学杂志》2013,58(1):253-265
Abstract

Measurements of dielectric permittivity and electrical conductivity were taken in a saline gypsiferous soil collected from southern Tunisia. Both time domain reflectometry (TDR) and the new WET sensor based on frequency domain reflectometry (FDR) were used. Seven different moistening solutions were used with electrical conductivities of 0.0053–14 dS m?1. Different models for describing the observed relationships between dielectric permittivity (K a ) and water content (θ), and bulk electrical conductivity (EC a ) and pore water electrical conductivity (EC p ) were tested and evaluated. The commonly used K a –θ models by Topp et al. (1980) and Ledieu et al. (1986) cannot be recommended for the WET sensor. With these models, the RMSE and the mean relative error of the predicted θ were about 0.04 m3 m?3 and 19% for TDR and 0.08 m3 m?3 and 54% for WET sensor measurements, respectively. Using the Hilhorst (2000) model for EC p predictions, the RMSE was 1.16 dS m?1 and 4.15 dS m?1 using TDR and the WET sensor, respectively. The WET sensor could give similar accuracy to TDR if calibrated values of the soil parameter were used instead of standard values.  相似文献   

6.
Ground-water monitoring to delineate a contaminant plume in fluvial hydrostratigraphic units often is uncertain. Fluvial deposits consist typically of interbedded layers of sands, silts and clays, with buried stream channel deposits of sands or gravels. The channel deposits are often interpreted erroneously to be discontinuous between test holes and in cross section due to their sinuosity. Erroneous conclusions pertaining to the areal continuity of these geometrically complex deposits are inevitable unless the investigator thoroughly understands the depositional environment(s). The hydraulic conductivity of buried stream channel deposits may be several orders of magnitude higher than the matrix materials in which they are enclosed. The higher hydraulic conductivity of buried stream channel deposits has potentially significant ramifications with respect to ground-water monitoring to delineate the geometry of a contaminant plume migrating through these deposits. Ground-water monitoring at uranium mill waste disposal sites located in fluvial environments began on a significant scale in about 1977. A uranium mill tailing disposal site located in such an environment in central Wyoming is among the first sites monitored. Thirty-seven monitor wells were constructed at the site to delineate a seepage plume originating from one of the tailing ponds. This case history illustrates the need for a detailed under—standing of the hydrostratigraphy at a waste disposal site in order to interpret the meaning of ground-water quality data effectively. Water quality data from monitor wells located on a hit or miss basis often are misleading. The hydrostratigraphic horizon from which a water quality sample is collected must be well defined before the sample analyses can be interpreted quantitatively.  相似文献   

7.
Offsite movement of waterborne agrochemicals is increasingly targeted as a non-point source of water quality degradation. Our research has indicated that subsurface water movement is variable and site-specific, and that a small soil volume frequently conducts a large volume of flow. This concentrated flow is usually caused by soil morphology, and it often results in water moving rapidly offsite from certain areas of fields; little or no lateral subsurface flow may occur in other areas. Identifying these subsurface regions is difficult using conventional soil survey and vadose zone sampling techniques. In this study, traditional surveying is combined with electromagnetic induction (EMI) and ground-penetrating radar (GPR) mapping to identify areas with high potential for subsurface offsite movement of agrochemicals, optimizing these identification techniques, and expanding the mapping procedures to make them useful at the field-scale for agricultural production practices. Conclusions from this research are: (1) EMI mapping provides rapid identification of areas of soil with a high electrical conductivity and presumably high potential for offsite movement of subsurface water, (2) GPR mapping of areas identified by EMI mapping provides a means to identify features that are known to conduct concentrated lateral flow of water, and (3) combining the capabilities of EMI and GPR instrumentation makes possible the surveys of large areas that would otherwise be impossible or unfeasible to characterize.  相似文献   

8.
Copper production is an essential component of the Chilean economy. During the extraction process of copper, large quantities of waste materials (tailings) are produced, which are typically stored in large tailing ponds. Thickened Tailings Disposal (TTD) is an alternative to conventional tailings ponds. In TTD, a considerable amount of water is extracted from the tailings before their deposition. Once a thickened tailings layer is deposited, it loses water and it shrinks, forming a relatively regular structure of tailings blocks with vertical cracks in between, which are then filled up with “fresh” tailings once the new upper layer is deposited. The dynamic response of a representative column of this complex structure made out of tailings blocks with softer material in between was analyzed using a periodic half-space finite element model. The tailings’ behavior was modeled using an elasto-plastic multi-yielding constitutive model, and Chilean earthquake records were used for the seismic analyses. Special attention was given to the liquefaction potential evaluation of TTD.  相似文献   

9.
The mapping of saline soils is the first task before any reclamation effort. Reclamation is based on the knowledge of soil salinity in space and how it evolves with time. Soil salinity is traditionally determined by soil sampling and laboratory analysis. Recently, it became possible to complement these hard data with soft secondary data made available using field sensors like electrode probes. In this study, we had two data sets. The first includes measurements of field salinity (ECa) at 413 locations and 19 time instants. The second, which is a subset of the first (13 to 20 locations), contains, in addition to ECa, salinity determined in the laboratory (EC2.5). Based on a procedure of cross-validation, we compared the prediction performance in the space-time domain of 3 methods: kriging using either only hard data (HK) or hard and mid interval soft data (HMIK), and Bayesian maximum entropy (BME) using probabilistic soft data. We found that BME was less biased, more accurate and giving estimates, which were better correlated with the observed values than the two kriging techniques. In addition, BME allowed one to delineate with better detail saline from non-saline areas.  相似文献   

10.
Estimates of soil hydraulic properties using pedotransfer functions (PTF) are useful in many studies such as hydrochemical modelling and soil mapping. The objective of this study was to calibrate and test parametric PTFs that predict soil water retention and unsaturated hydraulic conductivity parameters. The PTFs are based on neural networks and the Bootstrap method using different sets of predictors and predict the van Genuchten/Mualem parameters. A Danish soil data set (152 horizons) dominated by sandy and sandy loamy soils was used in the development of PTFs to predict the Mualem hydraulic conductivity parameters. A larger data set (1618 horizons) with a broader textural range was used in the development of PTFs to predict the van Genuchten parameters. The PTFs using either three or seven textural classes combined with soil organic mater and bulk density gave the most reliable predictions of the hydraulic properties of the studied soils. We found that introducing measured water content as a predictor generally gave lower errors for water retention predictions and higher errors for conductivity predictions. The best of the developed PTFs for predicting hydraulic conductivity was tested against PTFs from the literature using a subdata set of the data used in the calibration. The test showed that the developed PTFs gave better predictions (lower errors) than the PTFs from the literature. This is not surprising since the developed PTFs are based mainly on hydraulic conductivity data near saturation and sandier soils than the PTFs from the literature. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

11.
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12.
Spatial sampling design based on the variability and distribution of soil properties is an important issue with the progress in precision agriculture and soil ecology. Electromagnetic induction (type EM38) and variance quad‐tree (VQT) method were both applied to optimize the sampling scheme of soil salinity in a coastal reclamation field in north Jiangsu Province, China. Apparent soil electrical conductivity (ECa) measured with EM38 was used as an ancillary variable and the spatial distribution of ECa was used as priori information. The process and result of VQT algorithm analysis was illustrated and the obtained sampling strategy was validated using observed soil salinity. Then the spatial precision and sampling efficiency were evaluated. The result indicated that the spatial distribution of soil salinity produced with the VQT scheme was quite similar to that produced with total sampling sites, while sampling quantity of the former was reduced to approximately 1/2 of the latter. The spatial precision of VQT scheme was considerably higher than that of traditional grid method with respect to the same sampling number, and fewer samples were required for VQT scheme to obtain the same precision level. A 17.3% increase in sampling efficiency was achieved by VQT over grid method at the precision level of 90%. The VQT method was proved to be more efficient and economical because it can sample intensively or sparsely according to variation status in local areas. The associated application of EM38 and VQT method provides efficient tools and theoretical basis for saving sampling cost and improving sampling efficiency in coastal saline region and enriching soil ecology.  相似文献   

13.
Simultaneous measurement of coupled water, heat, and solute transport in unsaturated porous media is made possible with the multi-functional heat pulse probe (MFHPP). The probe combines a heat pulse technique for estimating soil heat properties, water flux, and water content with a Wenner array measurement of bulk soil electrical conductivity (ECbulk). To evaluate the MFHPP, we conducted controlled steady-state flow experiments in a sand column for a wide range of water saturations, flow velocities, and solute concentrations. Flow and transport processes were monitored continuously using the MFHPP. Experimental data were analyzed by inverse modeling of simultaneous water, heat, and solute transport using an adapted HYDRUS-2D model. Various optimization scenarios yielded simultaneous estimation of thermal, solute, and hydraulic parameters and variables, including thermal conductivity, volumetric water content, water flux, and thermal and solute dispersivities. We conclude that the MFHPP holds great promise as an excellent instrument for the continuous monitoring and characterization of the vadose zone.  相似文献   

14.
江苏太湖地区水污染物及其向水体的排放量   总被引：95，自引：9，他引：86  
１９９７年各污染累计向江苏太湖地区水体排放ＴＮ６４８２４ｔ,各污染源中ＴＮ所占份额的高低顺序为：农田２４％、工业２２％、人粪尿１８％、畜禽粪尿１６％,生活污水１４％,精养鱼塘６％。种植业、畜牧业,渔业累计占４６％,农业生产对水体的氮素污染较重。ＣＯＤｃｒ排放量的高低顺序为生活污水８９３８５ｔ、人粪尿７４５５１ｔ、畜禽粪尿１６８２０ｔ、精养鱼塘４０７．３ｔ。等标污染负荷分析结果表明,畜禽粪尿,生活污  相似文献   

15.
Arsenic-contaminated mine tailings that were discharged into Whitewood Creek at Lead, South Dakota, from 1876 to 1978, were deposited along the floodplains of Whitewood Creek and the Belle Fourche River. The resulting arsenic-contaminated floodplain deposit consists mostly of overbank sediments and filled abandoned meanders along White-wood Creek, and overbank and point-bar sediments along the Belle Fourche River. Arsenic concentrations of the contaminated sediments indicate the degree of dilution of mine tailings by uncontaminated alluvium. About 13 per cent of the 110 × 106 Mg of mine tailings that were discharged at Lead were deposited along the Whitewood Creek floodplain. Deposition of mine tailings near the mouth of Whitewood Creek was augmented by an engineered structure. About 29 per cent of the mine tailings delivered by Whitewood Creek were deposited along the Belle Fourche River floodplain. About 60 per cent of that sediment is contained in overbank deposits. Deposition along a segment of the Belle Fourche River was augmented by rapid channel migration. The proportions of contaminated sediment stored along Whitewood Creek and the Belle Fourche River are consistent with sediment storage along the floodplains of perennial streams in other, similar sized watersheds.  相似文献   

16.
Application of the BME approach to soil texture mapping   总被引：3，自引：1，他引：3  
In order to derive accurate space/time maps of soil properties, soil scientists need tools that combine the usually scarce hard data sets with the more easily accessible soft data sets. In the field of modern geostatistics, the Bayesian maximum entropy (BME) approach provides new and powerful means for incorporating various forms of physical knowledge (including hard and soft data, soil classification charts, land cover data from satellite pictures, and digital elevation models) into the space/time mapping process. BME produces the complete probability distribution at each estimation point, thus allowing the calculation of elaborate statistics (even when the distribution is not Gaussian). It also offers a more rigorous and systematic method than kriging for integrating uncertain information into space/time mapping. In this work, BME is used to estimate the three textural fractions involved in a texture map. The first case study focuses on the estimation of the clay fraction, whereas the second one considers the three textural fractions (sand, silt and clay) simultaneously. The BME maps obtained are informative (important soil characteristics are identified, natural variations are well reproduced, etc.). Furthermore, in both case studies, the estimates obtained by BME were more accurate than the simple kriging (SK) estimates, thus offering a better picture of soil reality. In the multivariate case, classification error rate analysis in terms of BME performs considerably better than in terms of kriging. Analysis in terms of BME can offer valuable information to be used in sampling design, in optimizing the hard to soft data ratio, etc.  相似文献   

17.
Electrolytic model tank experiments to study resistivity and time domain induced polarization (IP) response over layered earth models were initiated primarily to facilitate the understanding of field results. Alternate layers of clay and sand (or clay-coated sand) with, in some cases, a surficial layer of water were assembled in the tank and resistivity and IP measurements made for a range of electrode spacings using the Wenner configuration. Graphite and silver-silver chloride electrodes were used as current and potential electrodes respectively. Clay-coated (3% by weight) sand was found to generate stronger polarization than either clay or sand alone. Apparent chargeability ma was observed to be positive for a nonpolarizable surface layer. For a polarizable surface layer, the sign of IP was controlled by the polarizability, the thickness of the second layer, and the spacing of the electrode spreads. The apparent chargeability ma can theoretically change sign from positive to negative and vice versa with a gradual increase in electrode spacing, and such negative IP effects were obtained in a few observations. A simultaneous decrease in IP and an increase in resistivity, which is a qualitative diagnostic feature for the occurrence of clean freshwater sand aquifers, could also be generated in the model tank experiment. Combined resistivity and IP soundings were carried out near Fredericton Junction and Tracy, New Brunswick, Canada. Field curves are presented along with the model curves for qualitative comparison and understanding of IP behaviour over a layered earth. Twenty-five out of twenty-seven soundings show only positive apparent chargeabilities, whereas two show chargeability sign changes (positive/negative/positive). The model study gives reason to believe that surface soils and Quaternary gravel boulder deposits near Fredericton Junction are relatively non-polarizable. As an auxiliary experiment, sand and clay were taken in different proportions by weight and mixed thoroughly with water in a cement mixer. The mixtures were then compressed with a suitable die and plunger under 3.6 Pa pressure to prepare cylindrical samples of height 18 cm and diameter 15.5 cm. IP measurements were done on the flat faces using the Wenner configuration with a= 2 cm. Chargeability was found to be negative for 100 and 90% clay mixtures. It reached a positive maximum for an 80% clay-20% sand mixture and then decreased gradually with increasing sand and decreasing clay content.  相似文献   

18.
Abstract

Time-domain reflectometry (TDR) is an electromagnetic technique for measurements of water and solute transport in soils. The relationship between the TDR-measured dielectric constant (Ka ) and bulk soil electrical conductivity ([sgrave]a) to water content (θW) and solute concentration is difficult to describe physically due to the complex dielectric response of wet soil. This has led to the development of mostly empirical calibration models. In the present study, artificial neural networks (ANNs) are utilized for calculations of θw and soil solution electrical conductivity ([sgrave]w) from TDR-measured Ka and [sgrave]a in sand. The ANN model performance is compared to other existing models. The results show that the ANN performs consistently better than all other models, suggesting the suitability of ANNs for accurate TDR calibrations.  相似文献   

19.
The swelling properties of buffer material for high level radioactive waste repository in a near-field environment are of particular importance for achieving the low permeability sealing function. In this study, the free swelling behavior of a potential buffer material Zhisin clay is evaluated under simulated groundwater conditions such as immersion in NaCl, CaCl2, and Na2SO4 solutions at various concentrations. Experimental results indicate that Zhisin clay, being a Ca-bentonite, exhibits reduced swelling strain in salt solutions. The amount of decrease in swelling strain upon saline water intrusion is affected by both the type and concentration of electrolyte. At the same concentration, the swelling strains in CaCl2 solution are lower than those in NaCl solution due to the quasi-crystals formed in the presence of calcium ions. Also, the swells in Na2SO4 solution are found to be lower than those in NaCl solution. This is attributed to the precipitation of CaSO4, which acts as binding agent and results in aggregation of clay particles.  相似文献   

20.
The influence of large‐scale mining operations on groundwater quality was investigated in this study. Trace element concentrations in groundwater samples from the North Mara mining area of northern Tanzania were analyzed. Statistical analyses for relationships between elemental concentrations in the samples and distance of a sampling site from the mine tailings dam were also conducted. Eleven trace elements (Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) were determined, and averages of Fe and Al concentrations were higher than levels accepted by the Tanzanian drinking water guideline. Levels of Pb in three samples were higher than the World Health Organization (WHO) and United States Environmental Protection Agency (USEPA) drinking water guidelines of 10 and 15 µg/L, respectively. One sample contained a higher As level than the WHO and USEPA guideline of 10 µg/L. The correlation between element concentrations and distance from the mine tailings dam was examined using the hierarchical agglomeration cluster analysis method. A significant difference in the elemental concentration existed depending on the distance from the mine tailings dam. Mann–Whitney U‐test post hoc analysis confirmed a relationship between element concentration and distance of a sampling site from the mine tailings dam. This relationship raises concerns about the increased risks of trace elements to people and ecosystem health. A metal pollution index also suggested a relationship between elemental concentrations in the groundwater and the sampling sites’ proximity from the mine tailings dam.  相似文献   

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