首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 46 毫秒
1.
The results of study of rutile inclusions in pyrope from the Internatsionalnaya kimberlite pipe are presented. Rutile is characterized by unusually high contents of impurities (up to 25 wt %). The presence of Cr2O3 (up to 9.75 wt %) and Nb2O5 (up to 15.57 wt %) are most typical. Rutile inclusions often occur in assemblage with Ti-rich oxides: picroilmenite and crichtonite group minerals. The Cr-pyropes with inclusions of rutile, picroilmenite, and crichtonite group minerals were formed in the lithospheric mantle beneath the Mirnyi field during their joint crystallization from melts enriched in Fe, Ti, and other incompatible elements as a result of metasomatic enrichment of the depleted lithospheric mantle.  相似文献   

2.
PT parameters of crystallization have been determined for pyropes and Cr-diopsides from loose sediments of the Kola region, taking into account the chemical compositions of these minerals. Being either deep-seated xenocrysts or constituents of mantle xenoliths in kimberlites, pyropes and Cr-diopsides bear information on composition of the lithospheric mantle and its diamond resource potential. It was established that pyropes belong to the lherzolitic (45%), harzburgitic (30%), and eclogitic (25%) mineral assemblages. The Ni thermometry of pyropes yielded their formation temperature at 650–1250°C, which corresponds to a depth interval of 75–190 km. The distribution of different pyrope-bearing assemblages and their trace element composition allowed us to suggest a layered structure of the Kola lithospheric mantle. Its shallow unit (75–110 km) is mainly composed of depleted lherzolite; the medium-deep unit (110–170 km) consists of harzburgite, and the deep unit (170–190 km), of both lherzolite and harzburgite. About 16% of lherzolitic-harzburgitic pyropes were derived from the diamond mantle facies, i.e., from a depth of 140–190 km. Cr-diopsides are subdivided into two genetic groups: eclogitic (high Al2O3 and Na2O, low MgO and CaO) and ultramafic (high MgO, CaO, and Cr2O3; low Al2O3 and Na2O). The crystallization parameters of Cr-diopside from deep-seated ultramafic group were determined using the Cr-in-Cpx barometer and En-in-Cpx thermometer. Most samples fall into the graphite stability field (20–45 kbar and 700–1150°C). If these minerals were derived from kimberlites, this implies that the latter were constituents of carbonatite-ultramafic intrusions. Cr-diopsides may also be derived from diamond-free ultramafic xenoliths contained in alkaline ultramafic dikes. Nevertheless, 15% of Cr-diopside compositions fall in the field of diamond stability (55–60 kbar and 1000–1100°C). These conditions fit the geotherm characterizing a low heat flow. The results support the high resource potential of the Kola region for diamonds.  相似文献   

3.
New members of the crichtonite mineral series are described in which K, Ba, Ca and REE are in significant concentrations (5 wt% oxides) filling the A formula position in AM21O38. These phases are chromium (16 wt% Cr2O3) titanates (58 wt% TiO2) enriched in ZrO2 (5 wt%) and constitute a mineral repository for refractory and large ion lithophile elements in the upper mantle. The mineral senes coexists with Mg-Cr-ilmenite, Nb-Cr-rutile, and Ca-Cr (NbZr) armalcolite that have equally unusual chemistries. Kimberlitic crichtonites are depleted in the intermediate lanthanides but highly enriched in LREE and HREE with chondrite normalized abundances of 103 to 105. Crichtonite, armalcolite, and Nb-Cr-rutile occupy a compositional range in TiO2 contents bridging the gap between ilmenite and rutile, two minerals having a widespread distribution in kimberlites and mantle-derived nodule suites.In common with other associations, and based on similarities in mineral chemistry, it is concluded that these minerals formed at P = 20–30 kb, 900–1100°C by reaction of peridotite with metasomatizing fluids. Kimberlitic crichtonite may be expressed as spinel + Cr-ferropseudobrookite, and armalcolite is equivalent to Cr-geikielite + rutile in the system (FeMg)-TiO2-Cr2O3. This system contains a number of Cr-Ti compounds not found as minerals but it is proposed that the ubiquitous occurrence of ilmenite intergrowths in kimberlitic rutile results from decomposition of high pressure αPbO2-type crystallographic shear structures. The new minerals have exotic chemistries and the high K-affinities broaden the scope for the origin of alkalic rocks, the generation of highly potassic magmas in the upper mantle, and suggest that alkali metasomatism may be pervasive.  相似文献   

4.
We report the first data on the contents of main oxides and REE in rocks and the compositions of pyropes and almandines from the Maiskoe kimberlite body recently discovered in the Nakyn field of the Yakutian kimberlite province.The kimberlites are characterized by low contents of Ti, a slight domination of Mg over Ca, and high contents of K2O in some samples. The pyropes have high contents of Cr2O3 (up to 14.5 wt.%); many of them (～16%) are poor in Ca. In petrochemical and mineralogical features the kimberlites of the Maiskoe body are complementary to the highly diamondiferous kimberlites of the nearby Botuobinskaya and Nyurbinskaya pipes. At the same time, they are not the final link in the evolution of kimberlite magmatism in the Nakyn field, which makes the latter still more promising for diamonds.  相似文献   

5.
Samples of afghanite, (Na,Ca,K)8 (Al6Si6O24)(SO4,Cl,CO3)3 · H2O, from the Malaya Bystraya and Tultui lazurite deposits in the Baikal region have been studied with X-ray diffraction and an electron microprobe. The unit-cell dimensions a and c of the examined afghanite samples range from 12.729 to 12.762 &0A and from 21.385 to 21.415 &0A. Isomorphic substitution is exhibited between Na and K; Ca content is about 2.5 apfu; the Cl/SO4 ratio is close to 1.0 with slight variations. Parameter a was plotted versus K content. The correlation between Na and K is established. Comparative analysis has shown that afghanite from the Baikal region is characterized by a lower K content than that from volcanic complexes in Italy. In the studied samples, K2O ranges from 0.51 to 2.28 wt %, whereas in comparable samples from volcanic complexes of Italy, it varies from 3.44 to 8.26 wt %. Sodalite-group minerals display a similar behavior of potassium. In lazurite from the Baikal region, the K2O content ranges from 0 to 0.95 wt %; the K2O content in hauyne from Italy varies from 0.88 to 5.75 wt %. The wider isomorphic miscibility in the feldspar minerals from volcanic-hosted assemblages in Italy as compared with the same minerals from lazurite deposits of the Baikal region reflects the difference in the geological and physicochemical conditions under which the minerals have been formed. In addition to the X-ray procedure, the Cl/SO4 ratio determined from microprobe data may be used to identify cancrinite-group minerals found at the Baikal lazurite deposits. It is near 1.0 in afghanite; 0.8 in tounkite; and more than 2 in davyne.  相似文献   

6.
The study area Mettur forms an important industrial town situated NW of Salem district. The geology of the area is mainly composed of Archean crystalline metamorphic complexes. To identify the major process activated for controlling the groundwater chemistry an attempt has been made by collecting a total of 46 groundwater samples for two different seasons, viz., pre-monsoon and post-monsoon. The groundwater chemistry is dominated by silicate weathering and (Na + Mg) and (Cl + SO4) accounts of about 90% of cations and anions. The contribution of (Ca + Mg) and (Na + K) to total cations and HCO3 indicates the domination of silicate weathering as major sources for cations. The plot for Na to Cl indicates higher Cl in both seasons, derived from Anthropogenic (human) sources from fertilizer, road salt, human and animal waste, and industrial applications, minor representations of Na also indicates source from weathering of silicate-bearing minerals. The plot for Na/Cl to EC indicates Na released from silicate weathering process which is also supported by higher HCO3 values in both the seasons. Ion exchange process is also activated in the study area which is indicated by shifting to right in plot for Ca + Mg to SO4 + HCO3. The plot of Na-Cl to Ca + Mg-HCO3-SO4 confirms that Ca, Mg and Na concentrations in groundwater are derived from aquifer materials. Thermodynamic plot indicates that groundwater is in equilibrium with kaolinite, muscovite and chlorite minerals. Saturation index of silicate and carbonate minerals indicate oversaturation during pre-monsoon and undersaturation during post-monsoon, conforming dissolution and dilution process. In general, water chemistry is guided by complex weathering process, ion exchange along with influence of Cl ions from anthropogenic impact.  相似文献   

7.
The problem of heterogeneity of the mantle lithosphere of the southwestern portion of the Siberian Platform has been considered, and the diamond content in potential mother lodes within this area has been estimated based on original geochemical data on the rare-element composition of pyropes from diamondiferous lamproites of the Ingashin field within the Prisayan region and ancient dispersion haloes of minerals accompanying diamonds in the area between the Angara and Uda rivers. Pyropes from lamproites are characterized by low concentrations of Zr (0.18–9.05 ppm), Hf (0.03–0.37 ppm), and rare earth elements (Sm 0.04–0.49, Eu 0.02–0.16, and Dy 0.05–0.96 ppm). Pyropes from the Lower Carboniferous Baeron Formation within the Tangui-Chuksha area are significantly different from pyropes of the Ingashin lamproites in high contents of Zr (30.36–139.23 ppm) and Hf (0.4–2.22 ppm). These pyropes are characterized by elevated concentrations of rare earth elements (Sm 1.34–3.68, Eu 0.53–1.17, and Dy 1.0–2.05 ppm). The distribution patterns of rare incompatible elements in pyropes of the Lower Carboniferous Mura massif within the Mura area manifest even stronger differences with pyropes of the Ingashin lamproites and in many respects with pyropes from Lower Carboniferous sediments of the Baeron Formation within the Tangui-Chuksha area. The results obtained indicate that there is no large-scale regional spreading of pyropes from Mid-Riphean lamproite bodies in the course of washout of these bodies and that the mantle lithosphere in the southwestern portion of the Siberian Platform is laterally heterogeneous in mineralogical-geochemical terms. The chemical composition and the peculiar distribution pattern of rare elements in pyropes from lamproites of the Prisayan region indicate a depleted, primarily lherzolite composition of the upper mantle that was transformed through low-temperature potassium metasomatosis. In terms of the chemical and rare-element compositions, pyropes from Lower Carboniferous sediments of the Tangui-Chuksha and Mura areas belong to a wider range of mantle rocks: depleted peridotites, metasomatic peridotites under low (900–1000°C) and high (>1000°C) temperature conditions, and megacrysts. This suggests that the composition of the lithospheric mantle in this area of the southern portion of the Siberian Platform is characterized by a considerably differentiated stratification of mantle rocks, some of which were credibly formed in the diamond stability field.  相似文献   

8.
Based on the measurements of refractive index,specific gravity,unit cell parameter,and mineral chemistry and infrared absorption spectrum analyses of pyropes in kimberlites from China,systematic studies of the Physical properties and compositional variations of pyropes of different colors and diverse paragenetic types,within and between kimberlite provinces have been undertaken,The origin of pyropes in the Kimberlites and the depth of their formation have been discussed.Pyropes of the purple series are different from those of the orange series in physical and chemical properties,for exaple,pyropes of the puple series are higher in α0,RI,SG,Cr2O3,MgO,Cr/(Cr Al),Mg/(Mg Fe),and Mg/(Mg Ca),and lower in Al2O3,Fe2O3 FeO than those of the orange series.The classification of garnets in kimberlites from china by the Dawson and Stephens‘ method(1975) has been undertaken and clearly demonstrates that pyropes of diamond-rich kimberlites contain much more groups than those of diamond-poor,especially diamond-free kimberlites.The higher in α0,RI,SG,Cr2O(3.Cr/(Cr Al),knorringite and Cr-component the pyropes are ,the richer in diamond the kimberlites will be.The infrared absorption spectrum patterns of pyropes change with their chemical composition regularly,as reflected in the shape and position of infrared absorption peaks.Two absortpion bands at 862-901 cm^-1 will grade into degeneration from splitting and the absorption band positions of pyropes shift toward lower frequency with increasing Cr2O3 content and Cr/(Cr Al) ratio of pyropes,LREE contents of orange pyrope megacrysts are similar to those of porple pyrope macrocrysts,but the former is higher in HREE than the latter,showing their different chondrite-normalized patterns.The formation pressures of pyropes calculated by Cr-component,Ca-component,knorringite molecules of pyropes show that some pyropes of the purple series in diamondiferous kimberlites fall into the diamond stability field.but all pyropes of diamond-free kimberlites lie outside the diamond stability field.The megacrysts were formed through early crystallization of kimberlites magma at high pressure condition,the majority of the purple pyrope macrocrysts have been derived from disaggregated xenoliths but the minoirty of them appear to be fragments of the discrete megacryst pyropes,or phenocrysts.  相似文献   

9.
Representative sampling of a diamond-bearing basal horizon in the Carnian Stage (Upper Triassic) on the northeastern margin of the Siberian Platform revealed a wide spectrum of indicator minerals, first of all, garnets, whose compositions are the same as in the inclusions in the regional diamonds. Of special interest are garnets of potential eclogite paragenesis with an abnormally high impurity of MnO (0.5–3.2 wt.%), which was earlier detected in more than 20% of garnets present as inclusions in diamonds of northern Quaternary placers and recommended as a new mineralogical criterion for diamond presence. Subcalcic Cr-pyropes of dunite–harzburgite paragenesis were also found in variable amounts, from 0.7 to 3.9 rel.%, in the sample of 973 grains of pyropes of lherzolite and websterite parageneses. Three grains contain 11.9, 12.6, and 16 wt.% Cr2O3, which corresponds to the presence of 30–34% of Mg–Cr-knorringite component. Such pyropes have been revealed for the first time in the study region. Cr-spinels are a mixture of compositions typical of kimberlites and the regional alkali-ultrabasic rocks. All studied samples contain picroilmenites with a variable content of Cr2O3 impurity. Since Mg–Fe–Ca-garnets with Mg# < 35 can be partly hosted in metamorphic rocks of the Anabar Shield, the elevated content of Na2O impurity (> 0.09 wt.%) was also taken into account. The different contents of indicator minerals in the samples might be due to the variable composition of the diamond orebodies. The Carnian placers call for new systematic sampling. Special attention should be given to estimation of the composition of garnets of presumably eclogite paragenesis with elevated contents of TiO2, MnO, CaO, and Na2O and to search for perovskite and Nb-containing rutile. These minerals, together with zircons, are of interest for determining the U–Pb isotopic age of probable diamond orebodies—kimberlites.  相似文献   

10.
Environmental geochemistry of Damodar River basin, east coast of India   总被引：1，自引：0，他引：1  
 Water and bed sediment samples collected from the Damodar River and its tributaries were analysed to study elemental chemistry and suspended load characteristics of the river basin. Na and Ca are the dominant cations and HCO3 is the dominant anion. The water chemistry of the Damodar River basin strongly reflects the dominance of continental weathering aided by atmospheric and anthropogenic activities in the catchment area. High concentrations of SO4 and PO4 at some sites indicate the mining and anthropogenic impact on water quality. The high concentration of dissolved silica, relatively high (Na+K)/TZ+ ratio (0.2–0.4) and low equivalent ratio of (Ca+Mg)/(Na+K) indicate that dissolved ions contribute significantly to the weathering of aluminosilicate minerals of crystalline rocks. The seasonal data show a minimum ionic concentration in the monsoon season, reflecting the influence of atmospheric precipitation on total dissolved solids contents. The suspended sediments show a positive correlation with discharge and both discharge and suspended load reach their maximum value during the monsoon season. Kaolinite is the mineral that is possibly in equilibrium with the water. This implies that the chemistry of the Damodar River water favours kaolinite formation. The concentration of heavy metals in the finer size fraction (<37 μ m) is significantly higher than the bulk composition. The geoaccumulation index values calculated for Fe, Mn, Zn, Ni and Cr are well below zero, suggesting that there is no pollution from these metals in Damodar River sediments. Received: 21 January 1998 · Accepted: 4 May 1998  相似文献   

11.
Fresh mid-ocean ridge basalt of varying crystallinity has been powdered and reacted with seawater and an artificial Na-K-Ca-Cl solution at 200–500°C and 500–1000 bar in sealed gold capsules. Water/rock mass ratios of 1–3 were used and durations ranged from 2 to 20 months.These time periods were sufficient for most elements to approach a steady-state concentration in solution which was determined by equilibrium with alteration minerals (Mg, SiO2, SO4), by rate of formation of these minerals (Na, Ca), or by depletion from the rock (K, B, Ba). The resulting solutions closely resemble the brines from the basalt-seawater geothermal system at Reykjanes, Iceland. Mg was almost completely removed from seawater into the alteration products smectite, tremolite-actinolite, or talc. Sulfate also was removed to low concentrations, both by precipitation of anyhydrite and by reduction to sulfide. Net transfer of Na from seawater into solids occurred in most experiments by formation of sodic feldspar and possibly analcime. Sr was removed from seawater in some experiments but showed no change or a small gain in others. SiO2, Ca, K, Ba, B and CO2 were leached from basalt and enriched in solution. SiO2 concentrations were controlled by saturation with quartz at 300°C and above. The principal Ca-bearing phases which formed were anhydrite, the hydrated Ca-silicate truscottite, tremolite-actinolite, and possibly wairakite. No K-rich phases formed. For some minerals the crystallinity of the starting basalt affected the amount which formed.Removal of Mg from seawater into solid alteration products occurred rapidly and was balanced largely by leaching of Ca from basalt. Net transfer of Na from seawater into solids occurred more slowly and was balanced mainly by leaching of additional Ca from basalt. Thus, reaction between seawater and basalt at low water/rock ratios can be considered to consist of two exchanges: Mg for Ca, and Na for Ca.  相似文献   

12.
Teboursouk region, Northwestern Tunisia, is characterized by the diversity of its natural resources (petroleum, groundwater and minerals). It constitutes a particular site widely studied, especially from a tectonic stand point as it exhibits a complex architecture dominated by multi-scale synclinals and Triassic extrusions. It has typical karst landform that constitutes important water resources devoted for human consumption and agriculture activities, besides to the exploitation of the Mio-Plio-Quaternary aquifer (MPQ). Thus, hydrogeological investigations play a significant role in the assessment of groundwater mineralization and the evaluation of the used water quality for different purposes. Hence, the current study based on a combined geochemical–statistical investigation of 50 groundwater samples from the multilayered aquifer system in the study area give crucial information about the principal factors and processes influencing groundwater chemistry. The chemical analysis of the water samples showed that Teboursouk groundwater is dominantly of Ca–Mg–Cl–SO4 water type with little contribution of Ca–Mg–HCO3, Na–K–Cl–SO4 and Na–K–HCO3. The total dissolved solids (TDS) values range from 0.37 to 3.58 g/l. The highest values are located near the Triassic outcrops. Furthermore, the hydrogeochemistry of the studied system was linked with various processes such as carbonates weathering, evaporites dissolution of Triassic outcrops and anthropogenic activities (nitrate contamination). Additionally, the main processes controlling Teboursouk water system were examined by means of multivariate statistical analysis (PCA and HCA) applied in this study based on 10 physicochemical parameters (TDS, pH, SO4, HCO3, pCO2, Ca, Mg, Na, K, Cl and NO3). Two principal components were extracted from PCA accounting 61% of total variance and revealing that the chemical characteristics of groundwater in the region were acquired through carbonates and evaporite dissolution besides to nitrate contamination. Similarly, according to Cluster analysis using Ward’s method and squared Euclidean distance, groundwater from the studied basin belongs to five different groups suggesting that the geochemical evolution of Teboursouk groundwater is controlled by dissolution of carbonates minerals, chemical weathering of Triassic evaporite outcrops, cation exchange and anthropogenic activities (nitrate contamination).  相似文献   

13.
This paper reports new petrographic and mineralogical data on the Manchary kimberlite pipe, which was discovered south of Yakutsk (Central Yakutia) in 2007–2008, 100 km. The pipe breaks through the Upper Cambrian carbonate deposits and is overlain by Jurassic terrigenous rock masses about 100 m thick. It is composed of greenish-gray kimberlite breccia with a serpentine-micaceous cement of massive structure. The porphyry texture of kimberlite is due to the presence of olivine, phlogopite, and picroilmenite phenocrysts. The SiO2 and Al2O3 contents of the groundmass are indicative of typical noncontaminated kimberlites. The groundmass has a significant content of ore minerals: Fe- and Cr-spinels, perovskite, magnetite, and, less commonly, magnesian Cr-magnetite. Pyropes occur in kimberlites as sharp-edged fragments and show uneven distribution. Chemically, they belong to lherzolite, wehrlite, or nondiamondiferous dunite–harzburgite parageneses. Garnets corresponding to lherzolites of anomalous composition make up 8%; this is close to the garnet content of Middle Paleozoic kimberlites from the Yakutian kimberlite province. The pyropes from the new pipe are compositionally similar to those from diamond-poor Middle Paleozoic kimberlites in the north of the Yakutian diamondiferous province. Chemically, pyropes from the Manchary pipe and those from the modern alluvium of the Kengkeme and Chakyya Rivers differ substantially. Consequently, the rocks of the pipe could not be a source of pyropes for this alluvium. They probably occured from other sources. This fact along with numerous “pipelike” geophysical anomalies, suggest the existence of a new kimberlite field in Central Yakutia.  相似文献   

14.
Water samples for chemical analyses were collected in January 2012. A total of 72 samples of groundwater were collected from 72 boreholes in the Midyan Basin, northwestern Saudi Arabia. Samples were collected in polyethylene bottles and preserved and the used analytical techniques were in accordance with the standard methods from American public health association. Geochemical analyses of the groundwater samples from Midyan Basin reveal the concentration of fluoride (F) between 0.98 and 2.1 mg/l. Other parameters, e.g, pH, EC, TDS, HCO3, SO4, NO3, Cl, K, Na, Mg, and Ca have been found in a variable proportion. Among them, the concentration of EC, HCO3, K, Na and Mg is higher than the permissible limits. According to thermodynamical considerations, most of the analysed samples are graded under-saturated with respect to calcite and fluoride, while saturation has been observed in some samples. The under-saturation could probably be attributed to low concentration of calcite and fluoride in the studied wells. Fluoride concentration shows weak positive correlation with EC, TDS, Na, Cl, and SO4. Factors controlling the concentration of fluoride (F) in the studied samples are the area climate, water chemistry and the presence of accessory minerals in the rocks through which groundwater is circulating, besides the anthropogenic activities in the area.  相似文献   

15.
In the light of progressive depletion of groundwater reservoir and water quality deterioration of the Neyveli basin, an investigation on dissolved major constituents in 25 groundwater samples was performed. The main objective was detection of processes for the geochemical assessment throughout the area. Neyveli aquifer is intensively inhabited during the last decenniums, leading to expansion of the residential and agricultural area. Besides semi-aridity, rapid social and economic development stimulates greater demand for water, which is gradually fulfilled by groundwater extraction. Groundwaters of the study area are characterized by the dominance of Na?+?K over Ca?+?Mg. HCO3 was found to be the dominant anion followed by Cl and SO4. High positive correlation was obtained among the following ions: Ca–Mg, Cl–Ca,Mg, Na–K, HCO3–H4SiO4, and F–K. The hydrochemical types in the area can be divided into two major groups: the first group includes mixed Ca–Mg–Cl and Ca–Cl types. The second group comprises mixed Ca–Na–HCO3 and Ca–HCO3 types. Most of the groundwater samples are within the permissible limit of WHO standard. Interpretation of data suggests that weathering, ion exchange reactions, and evaporation to some extent are the dominant factors that determine the major ionic composition in the study area.  相似文献   

16.
The Parnell Quartz Monzonite in the Pilbara Block of Western Australia is a Proterozoic (1731 ± 14 Ma) pluton characterized by high modal K‐feldspar and a greater abundance of hornblende relative to biotite, as is typical of Phanerozoic monzonitic rocks in eastern Australia. The only geochemical features reflecting its setting in an Archaean terrain are high Na2O, Ni and Cr. The pluton is zoned, with an increase in K‐feldspar, quartz and biotite and a decrease in plagioclase and hornblende from margin to core. Chemically, this zoning is reflected by systematic variation of CaO, K2O, Na2O, Sr and Rb, but ferromagnesian elements have irregular trends, implying preferential extraction of feldspars relative to mafic minerals during differentiation of the magma. The unusual geochemical trends are explained by a model involving ‘in situ’ feldspar fractionation of a K‐rich residual liquid from a mafic crystalline mush.

A parent magma similar to the average rock composition of the pluton is deduced because high ferromagnesian trace element abundances preclude extensive fractionation of mafic minerals. Geochemical and isotopic constraints suggest that the ultimate source was chemically similar to a shoshonitic basaltic andesite, that must have been emplaced beneath the eastern margin of the Pilbara Block in the Early Proterozoic. Subsequent partial melting of this postulated underplated source at ～ 1700 Ma to produce the Parnell Quartz Monzonite was probably associated with tectonism in the Gregory Range Complex.  相似文献   

17.
Air particulate matter (PM) samples were collected from June 2006 to May 2007 for determination of chemical elements. PM samples were taken in two size fractions (PM2.5 and PM10) with MiniVolume air samplers on rooftops of various buildings (15–25 m above ground) in the city of Riyadh. The samples were subjected to X-ray fluorescence analysis to measure major (Na, Mg, Al, K, Ca, Si, P, S, and Fe) and trace elements (Mn, Ni, Cu, Zn, and Ba). The results showed that the PM concentrations were higher for PM10 compared to PM2.5, indicating that the major PM source was local dust. Also the spatial distribution with high PM concentrations was observed in the south and southeast of the city and the lowest levels were in the center and northeast of the city. This spatial distribution was attributed to different factors such as wind direction and velocity, emission from cement factories, and the presence of buildings, trees, and paved streets that reduce the amount of dust resuspended into the atmosphere. The air quality of the city was found to range from good to hazardous based on PM2.5, and from good to very hazardous based on PM10. The element-enrichment factors revealed two element groups according to their changing spatial behavior. The first group showed no significant spatial changes indicating they have the same common source. The second group (mainly S and Ni) exhibited significant changes as expected from anthropogenic inputs. The origin of S is possibly a combination of minerals (CaSO4) and fossil fuel combustion. The source of Ni is probably from fossil fuel combustion.  相似文献   

18.
Hydrochemistry of groundwater is important for inrush water source identification in coal mines. For determining the source of inrush water from the 8101 working face in the Wolonghu coal mine, Northern Anhui Province, China, a total of 22 groundwater samples from three aquifer systems (loose layer—LA, coal bearing sandstone—CA, and the underlying limestone—TA), and eight samples from the 8101 working face were collected for analyzing major ion concentrations. The results suggest that major ion concentrations of the aquifer systems were different from each other, and they can be subdivided into Na–HCO3, Na–SO4, and Ca–SO4 types. Factor analysis indicates that their chemical compositions are mainly originated from two kinds of contributions: dissolution of soluble minerals (e.g., calcite, dolomite, and gypsum) and weathering of silicate minerals (e.g., plagioclase). Plots of factor scores and cluster analysis imply that LA was connected with CA, whereas TA was an isolated aquifer system. Moreover, the source of 8101 working face water was finally determined to be LA by using discriminant analysis.  相似文献   

19.
The Lovozero pluton (Kola Peninsula, Russia) is an unique object from the standpoint of the abundance, diversity, and originality of Th mineralization. In contrast to other igneous rocks and to such chemical elements as Ca, REE, U, and Na, Th in the hyperalkaline pegmatites and hydrothermalites of the Lovozero pluton commonly occurs as its own mineral phases. Umbozerite Na3Sr4Th(Mn,Zn,Fe,Mg)[Si8O24](OH) (7 samples), Ti-Th silicate Na0–7Sr0–1ThTi1–2Si8O22–23(OH) · nH2O (8 samples), Na-Th silicate (Na,K)4Th3[Si8(O,OH)24] · nH2O (6 samples), thorite (2 samples), steenstrupine-(Ce)-thorosteenstrupine series minerals (5 samples), and Th phosphate (Th,Na,K,Ca,Mg,U,Sr,Ba)[(P,Si, Al)1O4] · nH2O (1 sample) were investigated in this study. Ti-Th silicates and Th phosphate have been described for the first time. All of the above-mentioned minerals have been examined with electron microprobe, IR spectroscopy, powder diffraction, thermogravimetric and optical methods. High-Th minerals such as steenstrupine, umbozerite, Th phosphate, and Na-Th silicates crystallized mainly during the ussingite stage of the pegmatite-forming process. At the early hydrothermal high-alkaline stage, steenstrupine was replaced with REE and Th aggregates (belovite, vitusite, seidite, Na-Th silicates, Ti-Th silicates, etc.). Thorite, Ti-Th silicates, and minerals of the rhabdophane and monazite groups were formed at the late hydrothermal low-alkaline stage. Despite the metamict features of almost all samples, stoichiometric ratios of cations in umbozerites and Ti-Th silicates remain stable. Clear relationships have been revealed between umbozerites and Ti-Th silicates, on the one hand, and seidite-(Ce), a Ti-silicate that has a zeolite-like structure, on the other. This implies that, under certain conditions, these minerals may be regarded as potential suppliers of Th to the environment due to the leaching of Th from zeolite channels.  相似文献   

20.
The Mount Morgan Au-Cu pyritic massive sulphide deposit occurs in a north-trending belt of Middle Paleozoic volcanic rocks located in south-central Queensland. The host rocks for the deposit are a normal sequence of rhyolitic tuff that have a north-northwest regional strike and easterly dips of 20° to 30°. The tuff contains thin units of chert, jasperoid and carbonate.The Mount Morgan deposit was represented by a zone of sulphide mineralization 600 m long, 100–200 m wide and 300 m deep that transects stratigraphy and can be divided into: (1) an oxidized zone, characterized by a hematitic, Au-enriched gossan with minor stratiform sphalerite-argillite; and (2) a primary zone which can be subdivided into an upper zone of greater than 50% sulphide minerals (Main Pipe orebody), and a lower siliceous stockwork zone with approximately 20% sulphide minerals (Sugarloaf orebody). Pyrite is the most abundant sulphide mineral in both the upper and lower primary zones with lesser pyrrhotite and accessory chalcopyrite, sphalerite and gold. A zone of silicification forms an envelope around the orebody and extends stratigraphically downwards in a pipe-like zone for greater than 750 m. The orebody contained 67 Mt of 4.87 g/t Au and 0.70% Cu.The distribution and variation of between 7 and 29 elements and specific conductance were examined in 1252 samples of the host rocks taken from diamond drill core and surface outcrop. The host rocks in the immediate vicinity of the deposit are marked by the development of three distinct but overlapping chemical and mineralogical zones representing an outward progression from the most intensive to a less intensive alteration. A 50-m-thick siliceous inner zone of intensely altered rocks, depleted in all investigated elements except Si, surrounds the orebody. This zone passes outward into a 100-m-thick middle zone of dominantly sericite-pyrite characterized by high concentrations of K, Fe, Cu and Co. The sericite-pyrite zone, in turn, passes into an outer 100-m-thick chlorite zone with high Fe, Mg, Mn and Zn concentrations. High concentrations of H2O+ are associated with the sericite-pyrite zone and the chlorite zone. The alteration pipe underlying the Mount Morgan orebody is characterized by depletions in Na, Ca and K and enrichments in Fe and Mg. A non-economic pyrite body contained within the alteration pipe has spatially restricted enrichment halos of Fe, Mg, Zn, Cu and Co.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号