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1.
The dissociation of N2 by electron impact and by e.u.v. photo-absorption is studied, and it is shown that the forbidden predissociation of the numerous 1Πu and 1Σu+ valence and Rydberg states of N2 in the 11–24eV energy range is the dominant mechanism for N atom production. By measuring the absolute emission cross sections for the e.u.v. singlet bands of N2 and by using the generalized oscillator strength data of Lassettre (1974), it has been possible to construct a detailed model of the total N2 dissociation cross section which is in good agreement with the measurements of Winters (1966) and Niehaus (1967) and provides some insights into the maximum possible N(2D) yield from dissociative excitation. The total cross section for exciting N2 e.u.v. radiation in the 800Å–1100Å wavelength range has been measured and found to have a value of 3.4 ×10?17 cm2 at 100 eV under optically thin conditions. Although this result implies that large fluxes of e.u.v. photons should be excited in auroral substorms and in the airglow, they are not observed, and we show that this development is a consequence of radiation entrapment and predissociation. The total cross section for dissociating N2 by electron impact is given for optically thin and thick media. And some questions concerning the energy budget of a magnetospheric storm which are raised by these results, are discussed.  相似文献   

2.
The absolute cross-sections for the excitation of the 989 Å, 1027 Å, 7990 Å, 8446 Å, 1.1287 μm and 1.3164 μm multiplets of atomic oxygen by electron impact dissociation of O2 are reported. The radiative branching ratios for these transitions are calculated from these results and compared with the NBS compilation of Wiese et al. (1966) and the recent theoretical calculations of Pradhan and Saraph (1977). The cascade models of O+ radiative recombination and of electron-impact excitation of the OI(3S) state in the terrestrial airglow are discussed in the light of the laboratory measurements, and the effects of the resonant absorption of components of the λ 989 Å and λ. 1027 Å multiplets by the Birge-Hopfield band system of N2 are investigated. This process is shown to depend sensitively on the N2 vibrational temperature and to cause characteristic changes in the OI e.u.v. emission spectrum in auroras and in the sunlit F-region at high exospheric temperatures. It is also suggested that the λ 1027 Å radiation observed in auroral spectra is actually due to molecular nitrogen band emission that has been enhanced by entrapment effects and not to the excitation of the 2p 3P-3d 3D0 transition of atomic oxygen as believed previously.  相似文献   

3.
From estimates of drying effect in the cloud layer, data of the Venera 14 X-ray fluorescent spectroscopy, and evaluation of photochemical production of sulfuric acid, it follows that sulfuric acid and/or products of its further conversion should constitute not only the Mode 2 particles but most of the Mode 3 particles as well. The eddy mixing coefficient equals 2 × 104 cm2 s?1 in the cloud layer. The presence of ferric chloride in the cloud layer is indicated by the Venus u.v. absorption spectrum in the range of 3200–5000 Å, by the Venera 12 X-ray fluorescent spectrum, by the coincidence of the calculated FeCl3 condensate density profile and that of the Mode 1 in the middle and lower cloud layer, as well as by the upward flux of FeCl3 from the middle cloud layer which provides the necessary concentration of FeCl3 in H2SO4 solution. FeCl3 as the second absorber explains the localization of absorption in the upper cloud layer due to the FeCl3 conversion to ferric sulfate near the boundary between the upper and middle cloud layers. Other possible absorbers such as sulfur, ammonium pyrosulfite, nitrosylsulfuric acid, etc. are discussed.  相似文献   

4.
Recent far ultraviolet spectra of four nightside auroras observed with the extreme ultraviolet (e.u.v.) spectrometer abroad the STP 78?1 satellite (Bowyer et al., 1981) are discussed in terms of two secondary electron flux distribution models. One of these is based on calculations published by Rees and Maeda (1973) and the other on electron flux observations. Using the 1084 Å NII line as the norm, the relative intensities of several lines in the range 900–1400 Å could be fitted equally well by either model, indicating that some of these emission ratios are somewhat independent of the energy dependence of the secondary electron flux. The ratio of the NI 1243 Å to 1084 Å emission is seen to yield an effective correlation for the other observed emissions and a reasonably consistent estimate of the penetration depth of the aurora.  相似文献   

5.
Shailendra Kumar 《Icarus》1985,61(1):101-123
Models of Io's ionosphere at the time of the Pioneer 10 encounter are constructed in the presence of an SO2Na atmosphere on Io. The formation of the observed ionosphere on the downstream side requires precipitation of electrons; solar EUV alone is inadequate. Electron impact in the range 500–800 eV on an SO2 atmosphere with a surface density of 14 × 1010 cm?3 provides the best fit to the Pioneer 10 radio occultation entry data. The SO2+, the major ion produced, is converted rapidly to SO+ and in turn to S+ by reactions with the dissociation products of SO2. Ion chemistry leads to the formation of S+ as the dominant ion at and above the ionospheric peak. Na+ would dominate the ion composition near the surface, and it provides important constraints on the amount of Na allowed in the atmosphere. The relatively narrow energy range and flux required for incident electrons suggests that a fraction of torus plasma is accelerated in the wake region and penetrates deep into the atmosphere. On the upstream side the torus plasma compresses the ionosphere. These characteristics support the possible presence of a weak magnetic field associated with Io. S+ ions would escape from Io in the wake region at a rate of up to 1026 sec?1.  相似文献   

6.
《Icarus》1987,70(1):1-12
An array spectrometer was used on the nights of 1985 May 30–June 1 to observe the disks of Uranus and Neptune in the spectral regions 7–14 and 17–23 μm with effective resolution elements ranging from 0.23 to 0.87 μm. In the long-wavelength region, the spectra are relatively smooth with the broad S(1) H2 collision-induced rotation line showing strong emission for Neptune. In the short-wavelength spectrum of Uranus, an emission feature attributable to C2H2 with a maximum stratospheric mixing ratio of 9 × 10−9 is apparent. An upper limit of 2 × 10−8 is placed on the maximum stratospheric mixing ratio of C2H6. The spectrum of Uranus is otherwise smooth and quantitatively consistent with the opacity provided by H2 collision-induced absorption and spectrally continuous stratospheric emission, as would be produced by aerosols. Upper limits to detecting the planet near 8 μm indicate a CH4 stratospheric mixing ratio of 1 × 10−5 or less, below a value consistent with saturation equilibrium at the temperature minimum. In the short-wavelength spectrum of Neptune, strong emission features of CH4 and C2H6 are evident and are consistent with local saturation equilibrium with maximum stratospheric mixing ratios of 0.02 and 6 × 10−6, respectively. Emission at 8–10 μm is most consistent with a [CH3D]/[CH4] volume abundance ratio of 5 × 10−5. The spectrum of Neptune near 13.5 μm is consistent with emission by stratospheric C2H2 in local saturation equilibrium and a maximum mixing ratio of 9 × 10−7. Radiance detected near 10.5 μm could be attributed to stratospheric C2H4 emission for a maximum mixing ratio of approximately 3 × 10−9. Quantitative results are considered preliminary, as some absolute radiance differences are noted with respect to earlier observations with discrete filters.  相似文献   

7.
Ground-based observations of Venus were made with a 5-cm drive Michelson interferometer during December 1970 and December 1973. The thermal emission spectrum of the central portion of the apparent disk was recorded from 450–1250 cm?1 with an apodized spectral resolution of 0.25 cm?1. All statistically significant sharp line absorption features in the spectrum have been identified with gaseous CO2. Comparison between the observed spectrum and a synthetic spectrum computed from a model atmosphere, assuming gaseous CO2 and a sulfuric acid haze as opacity sources, indicates good agreement. A broad diffuse absorption feature associated with the sulfuric acid haze is evident in the 870- to 930 cm?1 region. With the exception of the rotational lines of the 927-cm?1 CO2 band, the above feature appears as a continuum down to 0.25 cm?1 resolution. In the 750- to 1250-cm?1 range, the spectrum exhibits moderate thermal contrast with maximum brightness temperatures of 234–238°K occurring near 825 cm?1. These temperatures are in general agreement with previous measurements.  相似文献   

8.
Soft X-ray emission from the X-ray source Per X-1 was observed in the 0.4–2 keV energy interval from a rocket borne X-ray detector. Spectral analysis of the data indicates that in the 0.4–2 keV band the X-ray emission from Per X-1 can be fitted either with a power law of slope-(4.8±1.2) or a thermal bremsstrahlung spectrum with akT value of (0.26 ?0.08 +0.12 ) keV. Such a steep spectrum is inconsistent with the spectrum measured above 2 keV. The measured flux in 0.4–2 keV band corresponds to X-ray luminosity of 3×1045 ergs s?1 for Per X-1.  相似文献   

9.
During the evening of 9 April and the morning of 10 April 1969, the twilight zenith intensity of the atomic oxygen red line OI(3P-1D) at 6300 Å was measured at the Blue Hill Observatory (42°N, 17°W). At the same time incoherent scatter radar data were being obtained at the Millstone Hill radar site 50 km distant. We have used a diurnal model of the mid-latitude F-region to calculate the ionospheric structure over Millstone Hill conditions similar to 9–10 April 1969. The measured electron temperature, ion temperature, and electron density at 800 km are used as boundary conditions for the model calculations. The diurnal variation of neutral composition and temperature were obtained from the OGO-6 empirical model and the neutral winds were derived from a semiempirical three-dimensional dynamic model of the neutral thermosphere. The solar EUV flux was adjusted to yield reasonable agreement between the calculated and observed ionospheric properties.This paper presents the results of these model computations and calculations of the red line intensity. The 6300 Å emission includes contributions from photoelectron excitation, dissociative recombination, Schumann-Runge photodissociation and thermal electron impact. The variations of these four components for morning and evening twilight between 90–120° solar zenith angles, and their relative contributions to the total 6300 Å emission line intensity, are presented and the total is compared to the observations. For this particular day the Schumann-Runge photodissociation component, calculated using the solar fluxes tabulated by Ackermann (1970), is the dominant component of the morning twilight 6300 Å emission. During evening twilight it is necessary to utilize a lower O2 density than for the morning twilight in order to bring the calculated and observed 6300 Å emission rates into agreement. The implication that there may be a diurnal variation in the O2 density at the base of the thermosphere is discussed in the light of available experimental data and current theoretical ideas.  相似文献   

10.
Marla H. Moore 《Icarus》1984,59(1):114-128
The infrared absorption spectrum from 3.3 to 27 μm (3030-370 cm?) of SO2 ice films has been measured at 20 and 88°K before and after 1-MeV proton irradiation. The radiation flux was chosen to simulate the estimated flux of Jovian magnetospheric 1-MeV protons incident on Io. After irradiation, SO3 is identified as the dominant molecule synthesized in the SO2 ice. This is also the case after irradiation of composite samples of SO2 with sulfur, or disulfites. Darkening was observed in irradiated SO2 ice and in irradiated S8 pellets. Photometric and spectral measurements of the thermoluminescence of irradiated SO2 have been made during warming. The spectrum appears as a broad band with a maximum at 4450 Å. Analysis of the luminescence data suggests that, at Ionian temperatures, irradiated SO2 ice would not be a dominant contributor to posteclipse brightening phenomena. After warming to room temperature, a form of SO3 remains along with a sulfate and S8. Based on these experiments, it is reasonable to propose that small amounts of SO3 may exist on the surface of Io as a result of irradiation synthesis in SO2 frosts.  相似文献   

11.
12.
We have obtained the spectrum of a middle-aged PSR B0656+14 in the 4300–9000 Å range with the ESO/VLT/FORS2. Preliminary results show that at 4600–7000 Å the spectrum is almost featureless and flat with a spectral index α ν ??0.2 that undergoes a change to a positive value at longer wavelengths. Combining with available multiwavelength data suggests two wide, red and blue, flux depressions whose frequency ratio is about 2 and which could be the 1st and 2nd harmonics of electron/positron cyclotron absorption formed at magnetic fields ~108 G in upper magnetosphere of the pulsar.  相似文献   

13.
A review is given of the stratospheric budgets of odd oxygen, odd nitrogen, nitrous oxide, methane and carbonyl sulfide. The stratospheric column production rate of NO by the reaction N2O + O(1D) → 2 NO is 1.1–1.9 × 108 molecules cm?2 s?1. The stratospheric loss rates for N2O, CH4 and COS are equal to 0.9–1.4 × 109, 1 × 1010 and 0.5 × 107 molecules cm?2 s?1, respectively. From currently available information on the global distributions of N2O and CH4 there are some indications of about two times smaller OH concentrations below 35 km than those which are calculated based on the latest compilation of kinetic data.Most significantly, however, it is shown that photochemical models and available ozone observations cannot be reconciled and that there may be particularly severe problems in the 25–35 km region. This issue is thoroughly discussed.Volcanic emissions of SO2 to the stratosphere may locally lead to much enhanced ozone concentrations and heating rates. These may influence the dynamic behaviour of volcanic plumes before their dispersion over large volumes of the stratosphere.  相似文献   

14.
A theory of the i.r. radiation (2–20 μ) of the upper atmosphere (90–250 km height) has been developed. It includes the calculation of concentrations and temperatures as well as the analysis of atomic and molecular level population kinetics. Various excitation and quenching processes are analysed. Results are given for the following bands: NO (5.3μ), NO+(4.3μ.), CO (4.7 μ), N14N15 (4.4 μ), CO2(4.3 and 15 μ), H2O(2.7 and 6.3 μ), N2O(4.5; 7.8 and 17μ), O3(9.6 and 14.4 μ). The energy aspect of the problem is discussed. It is found that at a height of 120 km intensity in the region of 2 to 20 μ 3 to 10 is that of the 63 μ line of atomic oxygen. The comparison of theory with the experiment was carried out and satisfactory agreement obtained. The correlations of intensities in i.r. bands and emissions in visible and u.v. spectra were considered.  相似文献   

15.
The paper presents the results of the spectral observations of comet C/2001 Q4 (NEAT) acquired with the Zeiss-600 telescope of the Andrushevka astronomical observatory in May 2004. The spectrum of the comet was obtained in the range of 3600–8200 Å. We identified a number of emission features in the spectrum of comet C/2001 Q4 (NEAT). The emission bands of C2, C3, CN, CH, NH2, H2O+ were detected in the spectrum of the comet, and their intensities were determined. The ratios of gas-production rates Q(C2)/Q(CN) = 0.23, Q(C3)/Q(CN) = ?0.79, and Q(NH2)/Q(CN) = ?0.029 were determined with the Haser model.  相似文献   

16.
Measurements were made of the time-averaged gamma ray energy loss spectrum in the energy range 360 keV to 7 MeV by the gamma ray detector on the OSO-7 satellite during the 3B flare on August 4, 1972. The differential photon spectrum unfolded from this spectrum after subtracting the background spectrum and contributions from gamma ray lines is best described by a power law with spectral index of 3.4±0.3 between 360–700 keV and by an exponential law of the form exp (-E/E 0) with E 0 = 1.0±0.1 MeV above 700 keV. It is suggested that this spectrum is due to nonthermal electron bremsstrahlung from a population of electrons, with a strong break in the spectrum at 2 MeV. Since the observational data indicates that the matter number density must be n H ? 5 × 1010 cm-3 in the production region, the number of electrons above 100 keV required to explain the results is ?2 × 1034.  相似文献   

17.
The Mariner 9 infrared spectrometer obtained data over a large part of Mars for almost a year beginning late in 1971. Mars' infrared emission spectrum was measured from 200 to 2000 cm?1 with an apodized resolution of 2.4 cm?1. No significant deviation from terrestrial ratios of carbon (12C/13C) or oxygen (16O/18O; 16O/17O) isotopes was observed on Mars. The 12C/13C isotopic ratio was found to be terrestrial with an uncertainty of 15%. Upper limits have been calculated for several minor constituents. With an effective noise equivalent radiance of 1.2 × 10?9 W cm?2 sr?1/cm?1, new upper limits in centimeter-atmospheres of 2 × 10?5 for C2H2, 4 × 10?3 for C2H4, 3 × 10?3 for C2H6, 2 × 10?4 for CH4, 1 × 10?3 for N2O, 1 × 10?4 for NO2, 4 × 10?5 for NH3, 1 × 10?3 for PH3, 7 × 10?4 for SO2, and 1 × 10?4 for OCS have been derived.  相似文献   

18.
The aim of this paper has been to study the neutral helium triplet emission lines identified in the spectrum of the envelope of Nova Delphini. By comparing the observed flux of the neutral helium lines with that calculated theoretically by Robbins, we find that the optical thickness in the center of the line 3889 is of the order of 21.50 for summer 1969. The optical thickness obtained by this method is here denoted tran(3889).On the other hand, we obtain the number of neutral helium atoms in the 23S state [N(23S)] by considering the equilibrium between the mechanisms that populate and depopulate this state. We then find that the depopulation by photoionization due to the radiation of Ly (Hi), transitions to the 21S, 21p and 23p states by electron collision, photoionization due to the continuum radiation of the central star, are 82.70%, 13.20%, 2.40%, 0.90% and 0.80% respectively. We find that the mechanism of the photoionization by Ly is the dominant mechanism of depopulation of 23S state. We calculated ( 3889) of the order of 82.37, fromN(23S), obtained in the preceding paragraph. The optical thickness obtained by this method is here denoted bal(3889).The difference between tran(3889) and bal(3889) is very large and it cannot be attributed to calculation errors. We have considered all the mechanisms that can depopulate the 23S state, so we then conclude that the difference between tran(3889) and bal(3889) is due to the heterogeneity of the envelope of the Nova, already found by us in our previous study of the profiles of the permitted and forbidden lines. Finally, we find from this study a filling factor of the order of 0.30.  相似文献   

19.
Observations of the dwarf Irr galaxy IC 10 have been performed at the 6-m Special Astrophysical Observatory telescope with the SCORPIO focal reducer in the mode of a slit spectrograph. The ionized-gas emission spectrum in the region of intense current star formation has been investigated. The relative oxygen, N+, and S+ abundances in about twenty H II regions and the synchrotron superbubble have been estimated. The galaxy-averaged oxygen abundance is 12 + log(O/H) = 8.17 ± 0.35 and the metallicity is Z = 0.18 ± 0.14Z . The metallicity found by comparing diagnostic diagrams with photoionization models is shown to be less reliable than its estimate based on strong oxygen lines.  相似文献   

20.
Hubble Space Telescope/Wide Field and Planetary Camera 2 (HST/WFPC2) images of Io obtained between 1995 and 2007 between 0.24 and 0.42 μm led to the detection of the Pele plume in reflected sunlight in 1995 and 1999; imaging of the Pele plume via absorption of jovian light in 1996 and 1999; detection of the Prometheus-type Pillan plume in reflected sunlight in 1997; and detection of the 2007 Pele-type Tvashtar plume eruption in reflected sunlight and via absorption of jovian light. Based on a detailed analysis of these observations we characterize and compare the gas and dust properties of each of the detected plumes. In each case, the brightness of the plumes in reflected sunlight is less at 0.26 μm than at 0.33 μm. Mie scattering analysis of the wavelength dependence of each plume’s reflectance signature suggests that range of particle sizes within the plumes is quite narrow. Assuming a normal distribution of particle sizes, the range of mean particle sizes is ~0.035–0.12 μm for the 1997 Pillan eruption, ~0.05–0.08 μm for the 1999 Pele and 2007 Tvasthar plumes, and ~0.05–0.11 μm for the 1995 Pele plume, and in each case the standard deviation in the particle size distribution is <15%. The Mie analysis also suggests that the 2007 Tvashtar eruption released ~109 g of sulfur dust, the 1999 Pele eruption released ~109 g of SO2 dust, the 1997 Pillan eruption released ~1010 g of SO2 dust, and the 1995 Pele plume may have released ~1010 g of SO2 dust. Analysis of the plume absorption signatures recorded in the F255W filter bandpass (0.24–0.28 μm) indicates that the opacity of the 2007 Tvashtar plume was 2× that of the 1996 and 1999 Pele plume eruptions. While the sulfur dust density estimated for the Tvashtar from the reflected sunlight data could have produced 61% of the observed plume opacity, <10% of the 1999 Pele F255W plume opacity could have resulted from the SO2 dust detected in the eruption. Accounting for the remaining F255W opacity level of the Pele and Tvasthar plumes based on SO2 and S2 gas absorption, the SO2 and S2 gas density inferred for each plume is almost equivalent corresponding to ~2–6 × 1016 cm?2 and 3–5 × 1015 cm?2, respectively, producing SO2 and S2 gas resurfacing rates ~0.04–0.2 cm yr?1 and 0.007–0.01 cm yr?1; and SO2 and S2 gas masses ~1–4 × 1010 g and ~2–3 × 109 g; for a total dust to gas ratio in the plumes ~10?1–10?2. The 2007 Tvashtar plume was detected by HST at ~380 ± 40 km in both reflected sunlight and absorbed jovian light; in 1999, the detected Pele plume altitude was 500 km in absorbed jovian light, but in reflected sunlight the detected height was ~2× lower. Thus, for the 1999 Pele plume, similar to the 1979 Voyager Pele plume observations, the most efficient dust reflections occurred in the region closest to the plume vent. The 0.33–0.42 μm brightness of the 1997 Pillan plume was 10–20× greater than the Pele or Tvashtar plumes, exceeding by a factor of 3 the average brightness levels observed within 200 km of 1979 Loki eruption vent. But, the 0.26 μm brightness of the 1997 Pillan plume in reflected sunlight was significantly lower than would be predicted by the dust scattering model. Presuming that the 0.26 μm brightness of the 1997 Pillan plume was attenuated by the eruption plume’s gas component, then an SO2 gas density ~3–6 × 1018 cm?2 is inferred from the data (for S2/SO2 ratios ?4%), comparable to the 0.3–2 × 1018 cm?2 SO2 density detected at Loki in 1979 (Pearl, J.C. et al. [1979]. Nature 280, 755; Lellouch et al., 1992), and producing an SO2 gas mass ~3–8 × 1011 g and an SO2 resurfacing rate ~8–23 cm yr?1. These results confirm the connection between high (?1017 cm?2) SO2 gas content and plumes that scatter strongly at nearly blue wavelengths, and it validates the occurrence of high density SO2 gas eruptions on Io. Noting that the SO2 gas content inferred from a spectrum of the 2003 Pillan plume was significantly lower ~2 × 1016 cm?2 (Jessup, K.L., Spencer, J., Yelle, R. [2007]. Icarus 192, 24–40); and that the Pillan caldera was flooded with fresh SO2 frost/slush just prior to the 1997 Pillan plume eruption (Geissler, P., McEwen, A., Phillips, C., Keszthelyi, L., Spencer, J. [2004a]. Icarus 169, 29–64; Phillips, C.B. [2000]. Voyager and Galileo SSI Views of Volcanic Resurfacing on Io and the Search for Geologic Activity at Europa. Ph.D. Thesis, Univ. of Ariz., Tucson); we propose that the density of SO2 gas released by this volcano is directly linked to the local SO2 frost abundance at the time of eruption.  相似文献   

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