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A chamber was constructed to simulate the boundary between the ice table, regolith and atmosphere of Mars and to examine fractionation between H2O and HDO during sublimation under realistic martian conditions of temperature and pressure. Thirteen experimental runs were conducted with regolith overlying the ice. The thickness and characteristic grain size of the regolith layer as well as the temperature of the underlying ice was varied. From these runs, values for the effective diffusivity, taking into account the effects of adsorption, of the regolith were derived. These effective diffusivities ranged from 1.8 × 10−4 m2 s−1 to 2.2 × 10−3 m2 s−1 for bare ice and from 2.4 × 10−11 m2 s−1 to 2.0 × 10−9 m2 s−1 with an adsorptive layer present. From these, latent heats of adsorption of 8.6 ± 2.6 kJ mol−1 and 9.3 ± 2.8 kJ mol−1 were derived at ice-surface temperatures above 223 ± 8 K and 96 ± 28 kJ mol−1 and 104 ± 31 kJ mol−1 respectively for H2O and HDO were derived at colder temperatures. For temperatures below 223 K, the effective diffusivity of HDO was found to be lower than the diffusivity of H2O by 40% on average, suggesting that the regolith was adsorptively fractionating the sublimating gas with a fractionation factor of 1.96 ± 0.74. Applying these values to Mars predicts that adsorbed water on the regolith is enriched in HDO compared to the atmosphere, particularly where the regolith is colder. Based on current observations, the D/H ratio of the regolith may be as high as 21 ± 8 times VSMOW at 12°S and LS = 357° if the regolith is hydrated primarily by the atmosphere, neglecting any hydration from subsurface ice. 相似文献
3.
Greenhouse warming due to carbon dioxide atmospheres may be responsible for maintaining the early Earth's surface temperature above freezing and may even have allowed for liquid water on early Mars. However, the high levels of CO2 required for such warming should have also resulted in the formation of CO2 clouds. These clouds, depending on their particle size, could lead to either warming or cooling. The particle size in turn is determined by the nucleation and growth conditions. Here we present laboratory studies of the nucleation and growth of carbon dioxide on water ice under martian atmospheric conditions. We find that a critical saturation, S=1.34, is required for nucleation, corresponding to a contact parameter between solid water and solid carbon dioxide of m=0.95. We also find that after nucleation occurs, growth of CO2 is very rapid, and we report the growth rates at a number of supersaturations. Because growth would be expected to continue until the CO2 pressure is lowered to its vapor pressure, we expect particles larger than those being currently suggested for the present and past martian atmospheres. Using this information in a microphysical model described in a companion paper, we find that CO2 clouds are best described as “snow,” having a relatively small number of large particles. 相似文献
4.
It has been suggested that inclusions of CO2 or CO2 clathrate hydrates may comprise a portion of the polar deposits on Mars. Here we present results from an experimental study in which CO2 molecules were trapped in water ice deposited from CO2/H2O atmospheres at temperatures relevant for the polar regions of Mars. Fourier-Transform Infrared spectroscopy was used to monitor the phase of the condensed ice, and temperature programmed desorption was used to quantify the ratio of species in the generated ice films. Our results show that when H2O ice is deposited at 140-165 K, CO2 is trapped in large quantities, greater than expected based on lower temperature studies in amorphous ice. The trapping occurs at pressures well below the condensation point for pure CO2 ice, and therefore this mechanism may allow for CO2 deposition at the poles during warmer periods. The amount of trapped CO2 varied from 3% to 16% by mass at 160 K, depending on the substrate studied. Substrates studied were a tetrahydrofuran (C4H8O) base clathrate and Fe-montmorillonite clay, an analog for Mars soil. Experimental evidence indicates that the ice structures are likely CO2 clathrate hydrates. These results have implications for the CO2 content, overall composition, and density of the polar deposits on Mars. 相似文献
5.
Franck Montmessin Jean-Loup Bertaux Oleg Korablev François Forget Didier Fussen Aurélie Rébérac 《Icarus》2006,183(2):403-410
The formation of CO2 ice clouds in the upper atmosphere of Mars has been suggested in the past on the basis of a few temperature profiles exhibiting portions colder than CO2 frost point. However, the corresponding clouds were never observed. In this paper, we discuss the detection of the highest clouds ever observed on Mars by the SPICAM ultraviolet spectrometer on board Mars Express spacecraft. Analyzing stellar occultations, we detected several mesospheric detached layers at about 100 km in the southern winter subtropical latitudes, and found that clouds formed where simultaneous temperature measurements indicated that CO2 was highly supersaturated and probably condensing. Further analysis of the spectra reveals a cloud opacity in the subvisible range and ice crystals smaller than 100 nm in radius. These layers are therefore similar in nature as the noctilucent clouds which appear on Earth in the polar mesosphere. We interpret these phenomena as CO2 ice clouds forming inside supersaturated pockets of air created by upward propagating thermal waves. This detection of clouds in such an ultrararefied and supercold atmosphere raises important questions about the martian middle-atmosphere dynamics and microphysics. In particular, the presence of condensates at such high altitudes begs the question of the origin of the condensation nuclei. 相似文献
6.
Using Mars Global Surveyor Mars Orbiter Camera daily global maps, cloud areas have been measured daily for water ice clouds associated with the topography of the major volcanoes Olympus Mons, Ascraeus Mons, Pavonis Mons, Arsia Mons, Elysium Mons, and Alba Patera. This study expands on that of Benson et al. [Benson, J.L., Bonev, B.P., James, P.B., Shan, K.J., Cantor, B.A., Caplinger, M.A., 2003. Icarus 165, 34-52] by continuing their cloud area measurements of the Tharsis volcanoes, Olympus Mons and Alba Patera for an additional martian year (August 2001-May 2003) and by also including Elysium Mons measurements from March 1999 through May 2003. The seasonal trends in cloud activity established by Benson et al. [Benson, J.L., Bonev, B.P., James, P.B., Shan, K.J., Cantor, B.A., Caplinger, M.A., 2003. Icarus 165, 34-52] for the five volcanoes studied earlier are corroborated here with an additional year of coverage. For volcanoes other than Arsia Mons, interannual variations that could be associated with the large 2001 planet encircling dust storm are minimal. At Arsia Mons, where cloud activity was continuous in the first two years, clouds disappeared totally for ∼85° of LS (LS=188°-275°) due to the dust storm. Elysium Mons cloud activity is similar to that of Olympus Mons, however the peak in cloud area is near LS=130° rather than near LS=100°. 相似文献
7.
Steven W. Ruff 《Icarus》2004,168(1):131-143
Spectral features observed in Mars Global Surveyor Thermal Emission Spectrometer data (∼1670-220 cm−1) of martian surface dust provide clues to its mineralogy. An emissivity peak at ∼1630 cm−1 is consistent with the presence of an H2O-bearing mineral. This spectral feature can be mapped globally and shows a distribution related to the classical bright regions on Mars that are known to be dust covered. An important spectral feature at ∼830 cm−1 present in a newly derived average spectrum of surface dust likely is a transparency feature arising from the fine particulate nature of the dust. Its shape and location are consistent with plagioclase feldspars and also zeolites, which essentially are the hydrous form of feldspar. The generally favored visible/near-infrared spectral analog for martian dust, JSC Mars-1 altered tephra, does not display the ∼830 cm−1 feature. Zeolites commonly form from the interaction of low temperature aqueous fluids and volcanic glass in a variety of geologic settings. The combination of spectral features that are consistent with zeolites and the likelihood that Mars has (or had) geologic conditions necessary to produce them makes a strong case for recognizing zeolite minerals as likely components of the martian regolith. 相似文献
8.
The Mars Global Surveyor Mars Orbiter Camera was used to obtain global maps of the martian surface with equatorial resolution of 7.5 km/pixel in two wavelength ranges: blue (400-450 nm) and red (575-625 nm). The maps used were acquired between March 15, 1999 (Ls=110°) and July 31, 2001 (Ls=205°), corresponding to approximately one and a quarter martian years. Using the global maps, cloud area (in km2) has been measured daily for water ice clouds topographically corresponding to Olympus Mons, Ascraeus Mons, Pavonis Mons, Arsia Mons, Alba Patera, the western Valles Marineris canyon system, and for other small surface features in the region. Seasonal trends in cloud activity have been established for the three Tharsis volcanoes, Olympus Mons, and Alba Patera. Olympus, Ascraeus, and Pavonis Mons show cloud activity from about Ls=0°-220° with a peak in cloud area near Ls=100°. One of our most interesting observational results is that Alba Patera shows a double peaked feature in the cloud area with peaks at Ls=60° and 140° and a minimum near Ls=100°. Arsia Mons shows nearly continuous cloud activity. The altitudes of several of these clouds have been determined from the locations of the visual cloud tops, and optical depths were measured for a number of them using the DISORT code of Stamnes et al. (1988, Appl. Opt. 27, 2502-2509). Several aspects of the observations (e.g., cloud heights, effects of increased dust on cloud activity) are similar to simulations in Richardson et al. (2002, J. Geophys. Res. 107, 5064). A search for short period variations in the cloud areas revealed only indirect evidence for the diurnal cloud variability in the afternoon hours; unambiguous evidence for other periodicities was not found. 相似文献
9.
Aaron Zent 《Icarus》2008,196(2):385-408
A time-resolved energy balance model in the latitude range targeted by Phoenix, and extending back in time over the past 10 Ma, has been developed and used to predict the time-varying temperature field in ground ice over scales ranging from minutes to millions of years. The temperature history is compared to the population doubling times of terrestrial psychrophiles as a function of temperature, and the lifetime of analog microbe spores against de-activation by galactic cosmic rays (GCR), in order to assess the habitability of ground ice and surrounding materials that may be sampled by Phoenix. Metrics are derived to quantify “habitability” and compare different model configurations, including total and maximum continuous time, per year, that ground ice temperatures exceed various thresholds, maximum and average dormancy periods, and maximum and average consecutive growing seasons. The key unknowns in assessing the position, and hence the temperature, of the ground ice table at high northern latitude is the fate of the perennial north polar cap at high obliquity. If enough H2O ice can persist at polar latitudes to buffer at least the high-latitude atmosphere at all orbital configurations, ground ice is found to be relatively shallow over much of the past 10 Ma, and regularly achieves temperatures in excess of those required for the growth of terrestrial psychrophiles. The dry overburden expected at the landing site can easily be sampled by Phoenix, and includes the “sweet spot” that is characterized by the optimal habitability metrics over the past 10 Ma. If the atmosphere is buffered only by low-latitude ice deposits at obliquities greater than about 30°, the frequency and duration of habitable ice is considerably diminished, and the intervening dormancy periods, during which cosmic ray damage accumulates, are correspondingly longer. In all cases, the maximum dormancy period that must be survived by putative martian psychrophiles is at least an order of magnitude greater than the amount of time required to reduce terrestrial psychrophile spore viability by 10−6 (∼7×104 years). Depending on the fate of high-obliquity polar ice, the maximum dormancy period can exceed 4×106 years, a factor of 60 longer than terrestrial psychrophile spore lifetimes. Habitability of martian ground ice is therefore dependent on putative martian psychrophiles developing robustness against GCR deactivation at least an order of magnitude greater than their terrestrial counterparts. Simulations of ground ice throughout the 65° N-72° N latitude range accessible to Phoenix suggest that higher-latitude ground ice has better habitability metrics, although the discrepancy is less than an order of magnitude for all metrics and across the entire latitude range. 相似文献
10.
We report on laboratory experiments in which we allowed an SNC-derived mineral mix to react with pure water under a simulated Mars atmosphere for 7 months. These experiments were performed at one bar and at three different temperatures in order to simulate the subsurface conditions that most likely exist where liquid water and rock interact on Mars today. The dominant cations dissolved in the solutions we produced, which may be characterized as dilute brines, are Ca2+, Mg2+, Al3+, and Na+, while the major anions are dissolved C, F−, SO2−4 and Cl−. Typical solution pH was in the range of 4.2-6.0. Abundance patterns of elements in our synthetic sulfate-chloride brines are distinctly unlike those of terrestrial ocean water or continental waters, however, they are quite similar to those measured in the martian fines at the Mars Pathfinder and Viking 1 and 2 Landing sites. This suggests that salts present in the martian regolith may have formed over time as a result of the interaction of surface or subsurface liquid water with basalts in the presence of a martian atmosphere similar in composition to that of today. If most of the mobile surface layer was formed during the Noachian when erosion rates were much higher than at present, and if this layer is homogeneous in salt composition, the total amount of salt in the martian fines is approximately the same as in the Earth's oceans. The minimum quantity of circulating water necessary to deposit this amount of salt is approximately equivalent to a global layer 625 m deep. 相似文献
11.
Encouraged by recent results of the Mars Odyssey spacecraft mission and the OMEGA team (Mars Express) concerning water in equatorial latitudes between ±45° on Mars and the possible existence of hydrated minerals, we have investigated the water sorption properties of natural zeolites and clay minerals close to martian atmospheric surface conditions as well as the properties of Mg-sulfates and gypsum. To quantify the stability of hydrous minerals on the martian surface and their interaction with the martian atmosphere, the water adsorption and desorption properties of nontronite, montmorillonite, chabazite and clinoptilolite have been investigated using adsorption isotherms at low equilibrium water vapor pressures and temperatures, modeling of the adsorption equilibrium data, thermogravimetry (TG), differential scanning calorimetry (DSC), and proton magic angle spinning nuclear magnetic resonance measurements (1H MAS NMR). Mg-sulfate hydrates were also analyzed using TG/DSC methods to compare with clay mineral and zeolites. Our data show that these microporous minerals can remain hydrated under present martian atmospheric conditions and hold up to 2.5-25 wt% of water in their void volumes at a partial water vapor pressure of 0.001 mbar in a temperature range of 333-193 K. Results of the 1H MAS NMR measurements suggest that parts of the adsorbed water are liquid-like water and that the mobility of the adsorbed water might be of importance for adsorption-water-triggered chemistry and hypothetical exobiological activity on Mars. 相似文献
12.
Hydrogen peroxide (H2O2) has been suggested as a possible oxidizer of the martian surface. Photochemical models predict a mean column density in the range of 1015-1016 cm−2. However, a stringent upper limit of the H2O2 abundance on Mars (9×1014 cm−2) was derived in February 2001 from ground-based infrared spectroscopy, at a time corresponding to a maximum water vapor abundance in the northern summer (30 pr. μm, Ls=112°). Here we report the detection of H2O2 on Mars in June 2003, and its mapping over the martian disk using the same technique, during the southern spring (Ls=206°) when the global water vapor abundance was ∼10 pr. μm. The spatial distribution of H2O2 shows a maximum in the morning around the sub-solar latitude. The mean H2O2 column density (6×1015 cm−2) is significantly greater than our previous upper limit, pointing to seasonal variations. Our new result is globally consistent with the predictions of photochemical models, and also with submillimeter ground-based measurements obtained in September 2003 (Ls=254°), averaged over the martian disk (Clancy et al., 2004, Icarus 168, 116-121). 相似文献
13.
Mars General Circulation Model (GCM) simulations are presented to illustrate the importance of the ice emissivity of the seasonal CO2 polar caps in regulating the effects of airborne dust on the martian CO2 cycle. Simulated results show that atmospheric dust suppresses CO2 condensation when the CO2 ice emissivity is high but enhances it when the CO2 ice emissivity is low. This raises the possibility that the reason for the repeatable nature of the CO2 cycle in the presence of a highly variable dust cycle is that the CO2 ice emissivity is “neutral” - the value that leads to no change in CO2 condensation with changing atmospheric dust. For this GCM, the “neutral” emissivity is approximately 0.55, which is low compared to observed cap emissivities. This inconsistency poses a problem for this hypothesis. However, it is clear that the CO2 ice emissivity is a critical physical parameter in determining how atmospheric dust affects the CO2 cycle on Mars. 相似文献
14.
Kelly Fast Theodor Kostiuk Tilak Hewagama Timothy A. Livengood Sebastien Lebonnois 《Icarus》2006,183(2):396-402
Ozone is an important observable tracer of martian photochemistry, including odd hydrogen (HOx) species important to the chemistry and stability of the martian atmosphere. Infrared heterodyne spectroscopy with spectral resolution ?106 provides the only ground-based direct access to ozone absorption features in the martian atmosphere. Ozone abundances were measured with the Goddard Infrared Heterodyne Spectrometer and the Heterodyne Instrument for Planetary Wind and Composition at the NASA Infrared Telescope Facility on Mauna Kea, Hawai'i. Retrieved total ozone column abundances from various latitudes and orbital positions (LS=40°, 74°, 102°, 115°, 202°, 208°, 291°) are compared to those predicted by the first three-dimensional gas phase photochemical model of the martian atmosphere [Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F., 2004. J. Geophys. Res. 109, doi:10.1029/2004JE002268. E07004]. Observed and modeled ozone abundances show good agreement at all latitudes at perihelion orbital positions (LS=202°, 208°, 291°). Observed low-latitude ozone abundances are significantly higher than those predicted by the model at aphelion orbital positions (LS=40°, 74°, 115°). Heterogeneous loss of odd hydrogen onto water ice cloud particles would explain the discrepancy, as clouds are observed at low latitudes around aphelion on Mars. 相似文献
15.
In order to advance our understanding of the long-term stability of subsurface ice, the diurnal martian water cycle, and implications for liquid water, we determined diffusion coefficients and adsorption kinetics for the water vapor produced by the sublimation of ice buried beneath various layers of fine-grained (<63, 63-125, and 125-250 μm) basaltic powder under simulated martian conditions. Sublimation rates at shallower depths, <10 mm, were determined to be affected by mass transfer through the atmosphere in addition to the basalt layer. For greater depths, the measured diffusion coefficients for water vapor moving through basalt grains were 1.56±0.53×10−4, 2.05±0.82×10−4, and for the <63, 63-125, and 125-250 μm basaltic layers, respectively. Through the Brunauer, Emmett and Teller (BET) isotherm, which assumes multiple molecular layers of adsorbed water, we determined the adsorption constants of 52.6±8.3 at 270 K for <63 μm, 39.0±6.4 at 267 K for 63-125 μm, and 54.3±9.3 at 266 K for 125-250 μm, resulting in surface areas of 2.6±0.1×104, 1.7±0.3×104, , respectively. These results suggest that while diffusion is too rapid to explain the purported diurnal cycle in water content of the atmosphere, adsorption is efficient and rapid, and does provide an effective mechanism to explain such a cycle. The present diffusion data suggest that very thin, <50 pr μm, shallow, 10 mm, ice deposits would last for >10 h at ∼224 K, just above the freezing point of saturated CaCl2. Temperatures can remain above ∼224 K over most of the planet, which means that water, even as saturated brine, will sublimate before the freezing point is reached and liquid could be formed. On the other hand, 1 m ice layers below 1 m of fine-grained basaltic regolith at 235 K and 10 Pa of atmospheric water could last 600 to 1300 years. At deeper depths and lower temperatures, ice could last since the last major obliquity change 400,000 years ago. 相似文献
16.
Vladimir A. Krasnopolsky 《Icarus》2006,185(1):153-170
There is a significant progress in the observational data relevant to Mars photochemistry in the current decade. These data are not covered by and sometimes disagree with the published models. Therefore we consider three types of models for Mars photochemistry. A steady-state model for global-mean conditions is currently the only way to calculate the abundances of long living species (H2, O2, and CO). However, our model does not fit the observed CO abundance using gas-phase chemistry and reasonable values of heterogeneous loss of odd hydrogen on the water ice aerosol. The second type of the calculated models is steady-state models for local conditions. The MGS/TES data on temperature profiles, H2O, and dust are input parameters for these models. The calculations have been made for nine seasonal points spread over the martian year and for twelve latitudes with a step of 10° for each season. The only adopted heterogeneous reaction is a weak loss of H2O2 on water ice with probability of 5×10−4. The results are in good agreement with the recent observations of the O2 dayglow at 1.27 μm and the O3 and H2O2 abundances. Global maps of the seasonal and latitudinal behavior of these species have been made. The third type of models is a time-dependent model for local conditions. These models show that odd hydrogen quickly converts to H2O2 at the nighttime and the chemistry is switched off while the association of O, the heterogeneous loss of H2O2, and eddy diffusion continue. This requires significant changes in the global-mean and local steady-state models discussed above, and these changes have been properly done. The calculated diurnal variations of Mars photochemistry are discussed. The martian photochemistry at low and middle latitudes is significantly different in the aphelion period at LS=10°-130° from that in the remaining part of the year. 相似文献
17.
Michael D Smith 《Icarus》2004,167(1):148-165
We use infrared spectra returned by the Mars Global Surveyor Thermal Emission Spectrometer (TES) to retrieve atmospheric and surface temperature, dust and water ice aerosol optical depth, and water vapor column abundance. The data presented here span more than two martian years (Mars Year 24, Ls=104°, 1 March 1999 to Mars Year 26, Ls=180°, 4 May 2003). We present an overview of the seasonal (Ls), latitudinal, and longitudinal dependence of atmospheric quantities during this period, as well as an initial assessment of the interannual variability in the current martian climate. We find that the perihelion season (Ls=180°-360°) is relatively warm, dusty, free of water ice clouds, and shows a relatively high degree of interannual variability in dust optical depth and atmospheric temperature. On the other hand, the aphelion season (Ls=0°-180°) is relatively cool, cloudy, free of dust, and shows a low degree of interannual variability. Water vapor abundance shows a moderate amount of interannual variability at all seasons, but the most in the perihelion season. Much of the small amount of interannual variability that is observed in the aphelion season appears to be caused by perihelion-season planet-encircling dust storms. These dust storms increase albedo through deposition of bright dust on the surface causing cooler daytime surface and atmospheric temperatures well after dust optical depth returns to prestorm values. 相似文献
18.
The surface heat flux of a planet is an important parameter to characterize its internal activity and to determine its thermal evolution. Here we report on a new method to constrain the surface heat flux of Mars during the Hesperian. For this, we explore the consequences for the martian surface heat flux from a recently presented new hypothesis for the formation of Aram Chaos (Zegers, T.E., Oosthoek, J.H.P., Rossi, A.P., Blom, J.K., Schumacher, S. [2010]. Earth Planet. Sci. Lett. 297, 496-504. doi:10.1016/j.epsl.2010.06.049.). In this hypothesis the chaotic terrain is thought to have formed by melting of a buried ice sheet. The slow sedimentation and burial of the ice sheet led to an increased thermal insulation of the ice and subsequently to a temperature increase high enough to trigger melting and the formation of the subsurface lake. As these processes highly depend on the thermal properties of the subsurface and especially on the surface heat flux, it is possible to constrain the latter by using numerical simulations. Based on the hypothesis for the formation of Aram Chaos, we conducted an extensive parameter study to determine the parameter settings leading to sufficient melting of the buried ice sheet. We find that the surface heat flux in the Aram Chaos region during the Hesperian was most likely between 20 and 45 mW m−2 with a possible maximum value of up to 60 mW m−2. 相似文献
19.
Mark A. Wieczorek 《Icarus》2008,196(2):506-517
The polar caps of Mars have long been acknowledged to be composed of unknown proportions of water ice, solid CO2 (dry ice), and dust. Gravity and topography data are here analyzed over the southern cap to place constraints on its density, and hence composition. Using a localized spectral analysis combined with a lithospheric flexure model of ice cap loading, the best fit density of the volatile-rich south polar layered deposits is found to be 1271 kg m−3 with 1-σ limits of 1166 and 1391 kg m−3. The best fit elastic thickness of this geologically young deposit is 140 km, though any value greater than 102 km can fit the observations. The best fit density implies that about 55% dry ice by volume could be sequestered in these deposits if they were completely dust free. Alternatively, if these deposits were completely free of solid CO2, the dust content would be constrained to lie between about 14 and 28% by volume. The bulk thermal conductivity of the polar cap is not significantly affected by these maximum allowable concentrations of dust. However, even if a moderate quantity of solid CO2 were present as horizontal layers, the bulk thermal conductivity of the polar cap would be significantly reduced. Reasonable estimates of the present day heat flow of Mars predict that dry ice beneath the thicker portions of the south polar cap would have melted. Depending on the quantity of solid CO2 in these deposits today, it is even possible that water ice could melt where the cap is thickest. If independent estimates for either the dust or CO2 content of the south polar cap could be obtained, and if radar sounding data could determine whether this polar cap is presently experiencing basal melting or not, it would be possible to use these observations to place tight constraints on the present day heat flow of Mars. 相似文献
20.
Fifteen organic and three inorganic compounds were tested for methane (CH4) evolution under simulated martian conditions of 6.9 mbar; UVC (200-280 nm) flux of 4 W m−2; 20 °C; simulated optical depth of 0.1; and a Mars gas composition of CO2 (95.3%), N2 (2.7%), Ar (1.7%), O2 (0.13%), and water vapor (0.03%). All three inorganic compounds (i.e., NaCl, CaCO3, graphite) failed to evolve methane at the minimum detection level 0.5 ppm, or above. In contrast, all organic compounds evolved methane when exposed to UV irradiation under simulated martian conditions. The polycyclic aromatic hydrocarbon, pyrene, released the most methane per unit of time at 0.175 nmol CH4 g−1 h−1, and a spectral reflectance target material used for the MER rovers and Phoenix lander released the least methane at 0.00065 nmol CH4 cm−2 h−1. Methane was also released from UV-killed bacterial endospores of Bacillus subtilis. Although all organic compounds evolved methane when irradiated with UV photons under martian conditions, the concentrations of residual organics, biogenic signature molecules, and dead microbial cells should be relatively low on the exterior surfaces of the MSL rover, and, thus, not significant sources of methane contamination. In contrast, kapton tape was found to evolve methane at the rate of 0.00165 nmol CH4 cm−2 h−1 (16.5 nmol m−2 h−1) under the UV and martian conditions tested. Although the evolution of methane from kapton tape was found to decline over time, the large amount of kapton tape used on the MSL rover (lower bound estimated at 3 m2) is likely to create a significant source of terrestrial methane contamination during the early part of the mission. 相似文献