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1.
J.-H. Yu S. Y. O’Reilly L. Zhao W. L. Griffin M. Zhang X. Zhou S.-Y. Jiang L.-J. Wang R.-C. Wang 《Mineralogy and Petrology》2007,90(3-4):271-300
Summary The F-rich Hongshan pluton in the eastern Nanling Range, southern China, is a topaz-bearing albite leucogranite. It is distinctive
from other topaz-bearing felsic rocks in South China with respect to age, size, geochemical evolution and topaz mode and morphology.
The Hongshan granites are highly peraluminous and characterized by high K2O/Na2O, Si, Rb, Cs, Nb, Ta and F, and low Ca, Ba, Sr, Zr, Hf, P, K/Rb, Zr/Hf and Eu/Eu*. The granites show significant trace-element variations with magma evolution, with increasing Rb, Cs, Nb, Ta, Sn, W and decreasing
Sr, Ba, Zr, Hf, Y, REE, Pb, Th, K/Rb, Zr/Hf, Th/U and Eu/Eu*. These changes dominantly reflect fractional crystallization of plagioclase, biotite and accessory minerals such as zircon
and monazite. The granites also exhibit a decrease in ɛNd(t = 225 Ma) from −7.9 to −11.7 with magma evolution. Modeling shows
that the Nd isotopic variation could result from assimilation of the Taoxi Group wall rocks during fractional crystallization.
The Hongshan pluton also shows spatial geochemical variations; the most evolved parts are located in the southeastern part
of the pluton, which would be the most likely target area for rare-metal mineralization commonly associated with other topaz-bearing
granites.
Zircon grains from two rock types in the Hongshan body were analyzed in situ for U–Pb ages and Hf isotopic values. The concordant zircon grains mostly range from 218 to 230 Ma with an average of 224.6
± 2.3 Ma (Indosinian). Some zircons with different internal structures and Hf isotope compositions, as well as monazite fragments,
yield U–Pb ages of ca. 280 to 240 Ma, suggesting older thermal events in the studied area. The ɛHf(t) of these older zircons
is strongly negative (−12.3), implying a crustal source with a Paleoproterozoic model age, similar to that for the Proterozoic
Zhoutan Group. The main (∼225 Ma) zircon population exhibits less negative ɛHf(t) (−3.0 to −7.6) and Mesoproterozoic model
ages, suggesting that the original magma of the Hongshan granite was generated from deeper Mesoproterozoic crust. 相似文献
2.
Simultaneously in-situ analyses of U–Pb isotopes and trace elements were carried out for zircons, in combination with the in-situ analyses of trace elements in coexisting minerals, from low-T/UHP metagranite in the Dabie orogen. The results provide geochemical evidence for the existence of supercritical fluid during continental subduction-zone metamorphism. The zircons are categorized into three types based on their patterns of REE distribution. Type I zircons show increasing enrichment from La to Lu, with prominent positive Ce anomalies and negative Eu anomalies, which are typical of magmatic zircon. Some of them display regular or blurred oscillatory-zoned texture and apparent 206Pb/238U ages of 341 to 780 Ma, suggesting metamorphic modification by solid-state recrystallization with no significant involvement of metamorphic fluid. Type II zircons share similar Th, U and HFSE contents and REE patterns to Type I zircons. However, they exhibit blurred oscillatory-zoned texture or are unzoned, have apparent 206Pb/238U ages of 348 to 709 Ma, and are LREE-enriched relative to Type I zircons. This suggests that they underwent metamorphic reworking by replacement recrystallization in the presence of metamorphic fluid. The LREE enrichment is due to the presence of microscale LREE-bearing mineral inclusions (such as apatite, monazite or epidote) in the zircons. Type III zircons, representing the majority of the present analyses, are characterized by spongy texture and consistent enrichment of LREE, HREE, Th, U and HFSE relative to Type I zircons. They yield nearly concordant U–Pb ages close to the discordia lower-intercept. The consistent enrichment of trace elements relative to the magmatic zircon indicates involvement of a special UHP metamorphic fluid that has a strong capacity to extract significant amounts of LREE, HREE, Th, U and HFSE from such accessory minerals as allanite, garnet, rutile and zircon. Because these minerals are stable in the field of hydrous melt in granite–water systems, they are not able to be decomposed during the exhumation of deeply subducted continental crust. Thus, a supercritical fluid is suggested to transport the LREE, HREE, Th, U and HFSE in the accessory minerals to recrystallized zircons. The mechanism of dissolution recrystallization is responsible for the spongy texture and the very high concentration of trace elements in this type of metamorphic zircons. Therefore, the action of supercritical fluid is evident under the low-T/UHP metamorphic conditions. 相似文献
3.
南辽河群盖县组的重新厘定:来自辽南地区黄花甸-苏子沟一带变质砂岩碎屑锆石U-Pb年代学证据 总被引：4，自引：2，他引：2
传统认为辽河群顶部的盖县组广泛分布于辽南地区。本文对岫岩县黄花甸-苏子沟一带的南辽河群盖县组变质长石石英砂岩和变质石英砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学研究。其中变质长石石英砂岩中碎屑锆石普遍发育核-边结构,核部具有清晰的振荡环带;变质石英砂岩中碎屑锆石基本无核-边结构,具有清晰或者略模糊的振荡环带。锆石微量元素分析结果显示,具有振荡环带锆石微区具有轻稀土元素(LREE)亏损、重稀土元素(HREE)相对富集的配分曲线特征,Ce正异常和Eu负异常明显,Th/U和Zr/Hf比值较高,表明其岩浆成因。变质长石石英砂岩岩浆成因锆石微区~(207)Pb/~(206)Pb谐和年龄集中于2506～1748Ma之间,且呈现～2178Ma和～1863Ma两个年龄主峰,表明主要物质来源为同时期花岗质岩石(条痕状花岗岩和斑状花岗岩);变质石英砂岩岩浆成因锆石微区~(207)Pb/~(206)Pb谐和年龄集中于3546～1950Ma之间,呈现～2149Ma年龄主峰值,表明主要物质来源为条痕状花岗岩,另有少量太古宙基底物质的加入。研究区变质长石石英砂岩～1.86Ga的年龄峰值与辽河群其它变沉积岩明显不同,表明沉积时代一定晚于～1.86Ga,即形成于辽河群古元古代变质作用之后。综合研究区盖县组变质长石石英砂岩与辽河群其它变沉积岩碎屑锆石U-Pb年龄的差异,我们建议将盖县组部分变沉积岩从辽河群中解体出来。 相似文献
4.
北秦岭蟒岭岩体的锆石U-Pb年龄、地球化学及其演化 总被引：2，自引：1，他引：1
蟒岭岩体位于北秦岭构造带北部,岩石类型主要为似斑状黑云母二长花岗岩、中粗粒黑云母二长花岗岩、中细粒二长花岗岩、含辉石黑云角闪闪长岩和黑云母钾长花岗岩。依据LA-ICPMS锆石U-Pb定年结果,结合前人测试的年龄,将蟒岭岩体的岩浆演化划分为晚侏罗世早期、晚侏罗世晚期—早白垩世早期和早白垩世中期3期。第一期为含辉石黑云角闪闪长岩,其LA-ICPMS锆石U-Pb年龄为（157±1） Ma,该期岩石SiO2质量分数较低,富碱,属于准铝质,钾玄岩-高钾钙碱性系列;第二期二长花岗岩,侵位年龄为（148±1） Ma~（144±1） Ma,具有高硅、富碱的特征,属于准铝质-弱过铝质,钾玄岩-高钾钙碱性I-A过渡型花岗岩;第三期黑云母钾长花岗岩,侵位年龄为（124±2） Ma,具高硅、富碱、低镁、铝饱和指数偏高的特征,属过铝质,高钾钙碱性I-A过渡型花岗岩。组成蟒岭岩体的花岗岩从早到晚,SiO2质量分数逐渐升高,而Al2O3、TiO2、MgO、CaO、P2O5、TFe2O3质量分数逐渐降低;稀土元素总量具有由高到低的变化趋势,第一期和第二期岩石的稀土元素配分曲线为轻稀土元素相对富集的右倾型,而第三期的稀土元素配分曲线呈两边高中间低的不对称弧形,整体上负铕异常不明显或呈微弱正铕异常;微量元素上,这3期岩石均富集K、Rb、Ba、Sr等大离子亲石元素,而相对亏损P、Nb、Ta、Ti等高场强元素。与区域上同时代成矿花岗岩体对比,两者均具有高硅、富碱的特征,稀土元素球粒陨石标准化曲线呈轻稀土元素富集的右倾斜型,但蟒岭岩体中二长花岗岩没有明显的Eu异常,且Ba、P、Ti亏损及Ta、Nb富集没有含矿花岗岩明显。 相似文献
5.
点苍山-哀牢山杂岩带多期变质作用:嘎洒地区变沉积岩锆石微量元素与U-Pb年代学制约 总被引：2，自引：2，他引：0
点苍山-哀牢山杂岩带位于青藏高原东南缘,为云南三江地区一条重要的造山带,由扬子板块和印支板块于晚二叠世-中晚三叠世碰撞拼合而成。杂岩带主要由各类副片麻岩、片岩、石英岩、大理岩和斜长角闪岩构成,岩石发育强烈糜棱岩化和深熔作用。本文选取哀牢山北段新平嘎洒地区变沉积岩为研究对象,通过对变沉积岩锆石的阴极发光图像、微量元素、矿物包裹体组合、表面形态和U-Pb年龄的综合研究,揭示出嘎洒地区哀牢山杂岩经历了两期变质事件:其中,含石榴子石斜长二云母片岩中30颗变质锆石获得了较为一致的206Pb/238U年龄215±6Ma~227±5Ma,加权平均年龄为222.3±1.2Ma(n=30,MSWD=0.27),这些锆石具有浑圆状或椭圆状形态、较为均匀的阴极发光图像、平坦的HREE配分模式((Lu/Gd)N=0.73~4.08)和弱的负Eu异常,这些特征与典型的高级变质岩中变质锆石相似,而锆石的Th/U比值较为分散为0.06~0.84,平均值为0.45,可能与变质过程中富Th矿物独居石分解有关。变质年龄与杂岩带中点苍山和元阳地区变质岩中、晚三叠世变质年龄极为吻合,指示这期变质事件与中-晚三叠世古特提斯洋闭合-造山有关,标志着点苍山-哀牢山杂岩带为三江地区一条重要的古缝合线。此外,嘎洒地区夕线石榴黑云二长片麻岩的岩相学特征显示,岩石经历了石榴子石的转熔作用,除两颗锆石年龄为35.4Ma外,28颗锆石(增生边)给出了误差范围内较为一致的206Pb/238U年龄(27.3±0.5Ma~31.9±0.5Ma),加权平均年龄为29.4±0.53Ma(n=28,MSWD=2.0)。这些锆石的增生边中的矿物包裹体组合为夕线石+钾长石+黑云母+石英+独居石,且具有较低的Th/U比值(0.01~0.1),平坦的重稀土(HREE)配分模式((Lu/Gd)N=0.45~7.59)和中等程度的负Eu异常,这些特征指示该类锆石为典型的变质锆石。变质年龄与新生代红河-哀牢山剪切带内大量发现的同剪切岩浆岩、变质岩的年龄较为一致,指示这期年轻的变质事件与岩石圈尺度大规模剪切运动有关。此外,两类变沉积岩中6颗继承性碎屑锆石的年龄分布范围为528~783Ma,这些锆石具有锥形的锆石形态,清晰的振荡环带,表面发育蚀痕和凹坑,较高的Th/U比(0.1),陡倾的HREE配分曲线,表明这些锆石为经过剥蚀-搬运-沉积的岩浆锆石,具有继承性碎屑锆石的特征,说明哀牢山杂岩变沉积岩中至少应包含新元古代和早古生代的沉积物源,指示研究区哀牢山杂岩带部分岩石并不属于真正意义上的扬子结晶基底。 相似文献
6.
Fluid-assisted zircon and monazite growth within a shear zone: a case study from Finnmark,Arctic Norway 总被引：1，自引：0，他引：1
Christopher L. Kirkland Martin J. Whitehouse Trond Slagstad 《Contributions to Mineralogy and Petrology》2009,158(5):637-657
The U–Pb ages, REE content, and oxygen isotopic composition of zircon rims developed within a major shear zone in the Kalak
Nappe Complex (KNC), Arctic Norway have been determined along with the age of monazite crystals. Different generations of
granitic veins have been distinguished based on both field criteria and monazite ages of 446 ± 3 and 424 ± 3 Ma. Within each
of these veins, inherited zircon cores are mantled by homogeneous low CL-response zircon rims which yield a range of concordant
U–Pb dates of ca. 470–360 Ma. Significant numbers of zircon rims coincide with the timing of monazite crystallization. The
zircon rims have moderate light REE enrichment compared to cores, distinctive (Sm/La)
n
values of less than 12, and La between 0.3 and 10 ppm. This indicates free elemental exchange between newly formed zircon
rims and the surrounding matrix. The rims have calculated accumulated alpha-radiation dosages corresponding with a crystalline
structure and δ18O values of 1‰. This implies rim crystallization directly from a zirconium-saturated hydrothermal fluid which was modified
by some silicate melt. Growth of the zircon rims was prolonged and locally variable due to preferential fluid flow. A third
type of zircon can be recognized, forming both rims and cores, with high alpha-radiation doses, and significant enrichment
in La, Pr, and Eu. These are interpreted as low-temperature hydrothermally altered metamict zircons. The high volatile input
and partial melting in the shear zone favoured prolonged zircon rim growth due to its ability to easily nucleate on inherited
seeds. On the other hand, monazite, susceptible to dissolution and re-growth, crystallized in brief episodes, as has been
predicted from theoretical phase diagrams. From a regional perspective, these results elucidate cryptic Ar–Ar cooling ages,
providing the first record of a Late Ordovician heating and cooling phase within the KNC prior to the climactic Scandian collision. 相似文献
7.
Songbai Peng T.M. Kusky X.F. Jiang L. Wang J.P. Wang H. Deng 《Gondwana Research》2012,21(2-3):577-594
We report the presence of a Grenvillian ophiolite on the northern margin of the Yangtze craton, drastically changing current ideas about South China's role in plate reconstructions of the Rodinia supercontinent. Strongly deformed amphibolites that locally show relict pillow lavas, isotropic and layered metagabbro, diabase dikes, serpentinized dunite and harzburgite with podiform chromite are dated at circa 1100–985 Ma (U–Pb zircon). The ophiolite is structurally dismembered and thrust over the Proterozoic shelf sequence that covers the north margin of the Yangtze craton, and overrode a flysch to conglomerate-wildflysch unit shed from the ophiolite and a magmatic arc terrane and deposited on the older Yangtze carbonate platform. The youngest clasts in the conglomerate are circa 861–813 Ma (U–Pb zircon), giving a maximum age for ophiolite emplacement. Fine-grained layered amphibolites exhibit slightly depleted-flat type REE curves with no obvious Eu anomalies, and are N-MORB type tholeiites. Metagabbro has typical cumulate textures, flat REE distributions and obvious positive Eu anomalies. The REE characteristics of serpentinized dunites show a U-shape of slight loss of middle REE, representing cumulates metasomatized by LREE slightly enriched mantle. All these features indicate that the metamafic–ultramafic rocks from the Proterozoic Miaowan Formation form a structurally dismembered ophiolite resting above an ophiolitic wildflysch, sitting on top of the Proterozoic shelf sequence on the Yangtze craton. The ophiolite is contemporaneous with an arc sequence preserved to the north on the edge of the Yangtze craton, suggesting that the entire ophiolitic forearc–arc was accreted to the Yangtze craton between 1000 and 850 Ma. Xenocrystic zircons in granite clasts in the basal wildflysch unit have ages consistent with Australian affinity, and detrital zircons in the arc sequence also show derivation from Australia, suggesting that the arc formed on the Australian segment of Rodinia before collision with the Yangtze craton. The discovery of the Proterozoic Miaowan ophiolite supplies important evidence for the existence of a Neoproterozoic oceanic basin on the north margin of the Yangtze craton, and demonstrates that the Yangtze craton first collided with Rodinia on its northern margin, with subsequent accretion of the Cathaysian block on the southern margin of the craton. 相似文献
8.
为了理清北山南部晚古生代构造演化过程,对野马井地区的二长花岗岩与流纹岩进行了岩石学、全岩主微量元素地球化学、锆石U-Pb年代学及Hf同位素等研究.LA-ICP-MS锆石U-Pb定年结果表明二长花岗岩与流纹岩的就位年龄分别为402.7±2.4 Ma与392.9±2.5 Ma.二者均为富钾钾质岩浆岩,呈现过铝质-强过铝质,轻重稀土弱到中等分馏且相对富集轻稀土,二长花岗岩呈现无或弱的负Eu异常,流纹岩呈现较明显的负Eu异常,二者均富集Rb、Th、U、Pb等,亏损Nb、Ta、Ba、Sr、Ti等,为I型酸性岩浆岩.二长花岗岩与流纹岩的锆石εHf（t）值介于-2.2~+6.8,对应Hf模式年龄（tDM2）为962~1 533 Ma;指示二者主要由中元古代陆壳物质熔融所形成.依据野马井地区泥盆纪富钾酸性岩浆岩的地球化学特征,结合该区域其他地质资料,可推测其为后碰撞构造环境的产物. 相似文献
9.
不同成因锆石阴极发光及微量元素特征:以新疆阿尔泰地区花岗岩和伟晶岩为例 总被引：2，自引：0，他引：2
新疆阿勒泰可可托海地区出露大量花岗岩和伟晶岩脉,利用阴极发光显微照相(CL)、电子探针背散射(BSE)和激光剥蚀电感耦合等离子质谱技术(LA-ICP-MS),观察和分析岩石中锆石的内部结构、稀土元素及Th,U含量后结果表明:该区花岗岩锆石具振荡环带和强烈的阴极发光特征,Th/U比值较高(Th/U=0.16～0.99),轻稀土亏损、重稀土富集,具较大的Ce正异常,为典型岩浆成因锆石。伟晶岩(KP-08-11)锆石为热液锆石,不具振荡环带和阴极发光,具低的Th/U比值(0.01～0.13),强烈富集稀土元素,尤其是轻稀土元素较花岗岩锆石高一个数量级,Ce的正异常相对较低。伟晶岩(KP3-08-1)锆石为变质重结晶锆石,Th/U比值分布范围较广(0.01～0.78),强烈亏损稀土元素,稀土元素配分模式存在显著的"REE四分组效应"。微量元素特征表明,伟晶岩(KP-08-11)锆石可能结晶自富U贫Th的残余岩浆流体,而伟晶岩(KP3-08-1)的锆石经历了蜕晶质化和变质重结晶作用,但依然保持了共存伟晶岩熔体的微量元素特征。 相似文献
10.
滇西三江地区临沧花岗岩的岩石成因:地球化学、锆石U-Pb年代学及Hf同位素约束 总被引：21，自引：12，他引：9
位于滇西三江地区南澜沧江带的临沧花岗岩,其岩石类型主要为黑云母二长花岗岩,研究结果表明,该花岗岩的SiO2含量为66.84%～73.99%,平均为69.72%,K2O/Na2O值高,为1.42～30.1,平均为8.66,Al2O3含量为12.94%～15.23%,平均为14.44%,铝饱和指数A/CNK为1.06～8.59,平均为2.61,大部分大于1.1,为高钾钙碱性过铝-强过铝花岗岩。岩石总体上富集大离子亲石元素和Pb,明显亏损高场强元素。稀土总量198.2×10-6～359.2×10-6,平均为252.5×10-6,具有明显的轻稀土富集,重稀土亏损的特征,(La/Yb)N为7.87～17.62,平均11.19,δEu为0.34～0.57,平均0.48,球粒陨石标准化配分模式显示明显的负Eu异常。两件样品的锆石U-Pb年龄分别为219.19±0.99Ma和219.69±0.67Ma,属晚三叠世。SiO2-P2O5、SiO2-Zr判别图、K2O-Na2O判别图、ACF图解等花岗岩成因类型判别图指示临沧花岗岩为S型花岗岩,其物质来源为贫粘土的砂屑岩。微量元素Rb-Y+Nd判别图中,临沧花岗岩体投影点全部落入后碰撞花岗岩区。在Sr-Yb判别图中,投影点大部分落入低Sr高Yb型花岗岩区,与我国东南沿海花岗岩特征一致,应形成于挤压向伸展转换的后碰撞阶段。锆石Hf同位素组成比较均一,εHf(t)均为负值(集中于-14～-11之间),Hf地壳模式年龄集中于1.95～2.15Ga,推断其为古老地壳部分熔融的产物。结合锆石定年结果及岩体产出的区域地质背景,我们认为临沧花岗岩形成于缅泰马陆块与思茅地块大陆碰撞造山过程的后碰撞阶段,应形成于晚三叠世。 相似文献
11.
The U-Pb (SHRIMP-II) age of zircons from garnet-spinel peridotite nodules in Cenozoic alkali basalts of the Vitim Plateau,
Transbaikal region were determined. Most of the zircons are euhedral and subhedral prismatic crystals with an elongation of
1.5–2.0. Fragments of crystals and nearly equant crystals with rounded edges are present as well. Rounded or irregular cores
are observed in some grains. None of the zircons yielded an age that would correspond to the time of basalt eruption (21–2.35
Ma or younger). The youngest dates range from 135.2 ± 2.7 Ma to 141 ± 3 Ma (Early Cretaceous). Both concordant values and
the lower intersection of discordia with concordia (138.8 ± 5.7 Ma) are within this age interval. The upper intersection corresponds
to 1891 ± 26 Ma. A considerable part of the concordant values are grouped within the intervals (164.6 ± 1.6)–(183.4 ± 2.0)
and (264.0 ± 7.3)–(295.7 ± 0.76) Ma (Early-Middle Jurassic and Early Permian, respectively). The older concordant values fall
in the interval 1462 ± 19 to 1506 ± 4 Ma (Mesoproterozoic). Proterozoic age was obtained for cores of composite zircon grains.
Zircons pertaining to all age intervals are enriched in REE relative to chondrite (except La). The chondrite-normalized REE
patterns are positively sloped with an increase in contents from LREE to HREE. The LREE and HREE contents and the depth of
the Eu minimum tend to increase with age. In composite zircons of Proterozoic age, cores are somewhat enriched in REE. It
has been suggested that crystallization of zircon as a separate phase in peridotites extremely depleted in Zr was related
to a low degree of partial melting. The melt that formed in the intergranular space and that was repeatedly enriched in Zr
was not extracted from the solid framework of rock and crystallized in situ under the changed thermodynamic conditions in
the upper mantle. The occurrence of zircons of several age intervals in peridotites testifies to the multistage evolution
of the upper mantle and recurrent partial melting under various physicochemical conditions. 相似文献
12.
内蒙古敖汉旗克力代岩体锆石U-Pb年代及地球化学 总被引：1，自引：0，他引：1
通过LA-ICP-MS锆石U-Pb测年对内蒙古敖汉旗克力代岩体进行研究。结果表明,岩浆锆石的加权平均年龄为263±1 Ma,表明其结晶年龄为中二叠世。岩石地球化学分析表明,岩体具有高Si(SiO2=69.94%～72.56%),富ALK(Na2O+K2O=8.04%～9.23%),贫Fe(FeOT=1.50%～1.82%)、Mg(MgO=0.65%～0.86%)、Ti(TiO2=0.32%～0.35%)的特点;A/CNK值为0.87～0.93,为准铝质;A/NKC1.1,显示出I型花岗岩特征。固结指数(SI)为6.06～7.36,分异指数(DI)为88.82～91.82,说明岩体经历了较强的分异演化作用。稀土元素总量较低(ΣREE=91.76×10-6～143.16×10-6),轻稀土明显富集,重稀土相对亏损,LREE/HREE值平均为9.14,(La/Yb)N平均值为8.36,δEu平均值为0.58,为Eu亏损型。大离子亲石元素(LILE)Rb、K较富集,强烈亏损高场强元素(HFSE)Nb、Ti、Ta。因此,判定克力代岩体为高钾钙碱性I型花岗岩。结合测年结果和地球化学特征,判定该岩体为晚海西期华北板块和西伯利亚板块碰撞作用形成的同碰撞型花岗岩。 相似文献
13.
Residence of REE, Y, Th and U in Granites and Crustal Protoliths; Implications for the Chemistry of Crustal Melts 总被引：36，自引：8，他引：28
A systematic study with laser ablation—ICP-MS, scanningelectron microscopy and electron microprobe revealed that 70–95wt% of REE (except Eu), Y, Th and U in granite rocks and crustalprotoliths reside within REEYThU-rich accessories whose nature,composition and associations change with the rock aluminosity.The accessory assemblage of peraluminous granites, migmatitesand high-grade rocks is composed of monazite, xenotime (in low-Cavarieties), apatite, zircon, Thorthosilicate, uraninite andbetafite-pyrochlore. Metaluminous granites have allanite, sphene,apatite, zircon, monazite and Thorthosilicaie. Peralkaline graniteshave aeschinite, fergusonite, samarskite, bastnaesite, fluocerite,allanite, sphene, zircon, monazite, xenotime and Th-orthosilicate.Granulite-grade garnets are enriched in Nd and Sm by no lessthan one order of magnitude with respect to amphibolite-gradegarnets. Granulitegrade feldspars are also enriched in LREEwith respect to amphibolite-grade feldspars. Accessories causenon-Henrian behaviour of REE, Y, Th and U during melt—solidpartitioning. Because elevated fractions of monazite, xenotimeand zircon in common migmatites are included within major minerals,their behaviour during anatexis is controlled by that of theirhost. Settling curves calculated for a convecting magma showthat accessories are too small to settle appreciably, beingseparated from the melt as inclusions within larger minerals.Biotite has the greatest tendency to include accessories, therebyindirectly controlling the geochemistry of REE, Y, Th and U.We conclude that REE, Y, Th and U are unsuitable for petrogeneticalmodelling of granitoids through equilibrium-based trace-elementfractionation equations. KEY WORDS: accessory minerals; geochemical modelling; granitoids; REE, Y, Th, U 相似文献
14.
P. B. Tomascak Eirik J. Krogstad Richard J. Walker 《Contributions to Mineralogy and Petrology》1996,125(1):45-59
Neodymium and lead isotope and elemental data are presented for the Sebago batholith (293±2 Ma), the largest exposed granite
in New England. The batholith is lithologically homogeneous, yet internally heterogeneous with respect to rare earth elements
(REE) and Nd isotopic composition. Two-mica granites in the southern/central portion of the batholith (group 1) are characterized
by REE patterns with uniform shapes [CeN/YbN (chondrite normalized) = 9.4–19 and Eu/Eu* (Eu anomaly) = 0.27–0.42] and ɛ
Nd(t) = −3.1 to −2.1. Peripheral two-mica granites (group 2), spatially associated with stromatic and schlieric migmatites,
have a wider range of total REE contents and patterns with variable shapes (CeN/YbN = 6.1–67, Eu/Eu* = 0.20–0.46) and ɛ
Nd(t) = −5.6 to −2.8. The heterogeneous REE character of the group 2 granites records the effects of magmatic differentiation
that involved monazite. Coarse-grained leucogranites and aplites have kinked REE patterns and low total REE, but have Nd isotope
systematics similar to group 2 granites with ɛ
Nd(t) = −5.5 to −4.7. Rare biotite granites have steep REE patterns (CeN/YbN = 51–61, Eu/Eu* = 0.32–0.84) and ɛ
Nd(t) = −4.6 to −3.8. The two-mica granites have a restricted range in initial Pb isotopic composition (206Pb/204Pb = 18.41–18.75; 207Pb/204Pb = 15.60–15.68; 208Pb/204Pb = 38.21–38.55), requiring and old, high U/Pb (but not Th/U) source component. The Nd isotope data are consistent with magma
derivation from two sources: Avalon-like crust (ɛ
Nd>−3), and Central Maine Belt metasedimentary rocks (ɛ
Nd<−4), without material input from the mantle. The variations in isotope systematics and REE patterns are inconsistent with
models of disequilibrium melting which involved monazite.
Received: 8 December 1995 / Accepted: 29 April 1996 相似文献
15.
16.
Magmatic and hydrothermal zircon growth during multiple orogenic cycles in an evolving mantle wedge 总被引：1，自引：1，他引：0
The Hongseong area of the Hongseong-Imjingang Belt in the central-western Korean Peninsula forms part of a subduction-collision system that is correlated with the Qinling-Dabie-Sulu Belt in China. Several serpentinized ultramafic bodies carrying blocks of metamorphosed mafic rocks occur in this area. Here we investigate zircon grains in serpentinites from Bibong(BB) and Wonnojeon(WNJ), and high-pressure(HP) mafic granulite from Baekdong(BD) localities based on U-Pb, REE and Lu-Hf analyses. The zircons from BD HP mafic granulite show distinct age peaks at 838 Ma, 617 Ma and 410 Ma, with minor peaks at1867 Ma, 1326 Ma and 167 Ma. The Neoproterozoic age peaks in these rocks as well as in the serpentinites suggest subduction-related melt-fluid interaction in the mantle wedge at this time. The older zircon grains ranging in age from the Early to Middle Paleoproterozoic might represent detrital grains from the basement rocks transferred to the wedge mantle through sediment subduction. The BD HP mafic granulite shows a Middle Paleozoic age peak(Devonian; 410 Ma). The 242-245 Ma age peaks in the compiled age data of zircon grains serpentinites from BB and WNJ correspond to a major Triassic event that further added melts and fluids into the ancient mantle wedge to crystallize new zircons. In the chondrite normalized rare earth element diagram, the magmatic zircon grains from the studied rocks show LREE depletion and HREE enrichment with sharply negative Eu and Pr anomalies and positive Ce and Sm anomalies. The REE patterns of hydrothermal zircons show LREE enrichment, and relatively flat patterns with negative Eu anomaly. Zircon Hf signature from the WNJ serpentinite show negative εHf(t)(-18.5 and-23.5) values indicating an enriched mantle source with TDM in the range of 1614 Ma and1862 Ma. Zircons from the BD HP mafic granulite also show slightly negative εHf(t)(average-4.3) and TDM in the range of 1365-1935 Ma. Our study provides evidence for multiple zircon growth in an evolving mantle wedge that witnessed melt and fluid interaction during different orogenic cycles. 相似文献
17.
Kun Zhou Yi‐Xiang Chen Yong‐Fei Zheng Li‐Juan Xu 《Journal of Metamorphic Geology》2019,37(8):1099-1127
Partial melting of ultrahigh‐pressure (UHP) metamorphic rocks is common during collisional orogenesis and post‐collisional reworking, indicating that determining the timing and processes involved in this partial melting can provide insights into the tectonic evolution of collisional orogens. This study presents the results of a combined whole‐rock geochemical and zirconological study of migmatites from the Sulu orogen in eastern China. These data provide evidence of multiple episodes of crustal anatexis and geochemical differentiation within the UHP metamorphic rocks. The leucosomes contain higher concentrations of Ba and K and lower concentrations of the rare earth elements (REE), Th and Y, than associated melanosomes and granitic gneisses. The leucosomes also have homogenous Sr–Nd–O isotopic compositions that are similar to proximal (i.e. within the same outcrop) melanosomes, suggesting that the anatectic melts were generated by the partial melting of source rocks that are located within individual outcrops. The migmatites contain zircons with six different types of domains that can be categorized using differences in structures, trace element compositions, and U–Pb ages. Group I domains are relict magmatic zircons that yield middle Neoproterozoic U–Pb ages and contain high REE concentrations. Group II domains represent newly grown metamorphic zircons that formed at 230 ± 1 Ma during the collisional orogenesis. Groups III, IV, V, and VI zircons are newly grown anatectic zircons that formed at 222 ± 2 Ma, 215 ± 1 Ma, 177 ± 2 Ma, and 152 ± 2 Ma, respectively. The metamorphic zircons have higher Th/U and lower (Yb/Gd)N values, flat heavy REE (HREE) patterns with no significantly negative Eu anomalies relative to the anatectic zircons, which are characterized by low Th/U ratios, steep HREE patterns, and negative Eu anomalies. The first two episodes of crustal anatexis occurred during the Late Triassic at c. 222 Ma and c. 215 Ma as a result of phengite breakdown. The other two episodes of anatexis occurred during the Jurassic period at c. 177 Ma and c. 152 Ma and were associated with extensional collapse of the collision‐thickened orogen. The majority of Triassic anatectic zircons and all of the Jurassic zircons are located within the leucosomes, whereas the melanosomes are dominated by Triassic metamorphic zircons, suggesting that the leucosomes within the migmatites record more episodes of crustal anatexis. Both metamorphic and anatectic zircons have elevated εHf(t) values compared with relict magmatic zircon cores, suggesting that these zircons contain non‐zircon Hf derived from material with more radiogenic Hf isotope compositions. Therefore, the Sulu and Dabie orogens experienced different episodes of reworking during the exhumation and post‐collisional stages. 相似文献
18.
《International Geology Review》2012,54(6):548-564
Field study of granitic rocks in the Gebel Abu Brush-Dahis (ABD) area, Southeastern Desert, Egypt, shows that they comprise two granitic groups, namely A- and I-type suites. The A type is distinguished mineralogically by abundant orthoclase and sodic plagioclase, ferrohornblende, monazite, and allanite. In contrast, the I type has more hornblende and biotite, which are more magnesian in composition, and less feldspar. The parental magmas of both suites have many similar geochemical characteristics, although the A type has slightly higher alkalis, Zr, Hf, Zn, and LREE, and lower CaO, MgO, Sr, Ni, and Fe+2. The geochemical properties characteristic of leucocratic A-type granites-such as high Ga/Al ratios, Nb, Y, HREE, and F contents-are only manifest in the more felsic members of the A-type suite. These features were produced by 70% fractional crystallization of feldspar, hornblende, quartz, and biotite. Geotectonically, the study revealed that the A-and I-type granites are typical of an arc setting, but the more felsic members of the A-type suite plot in a within-plate regime. Geochemically, the granites are subalkaline and peraluminous to metaluminous. The granodiorites/adamellites (I-type suite) have fractionated LREE and slightly fractionated or nearly flat HREE, with small or no Eu anomalies. The alkali-feldspar granites (A-type suite) have flat REE with large Eu anomalies, except for one sample, which shows increasing LREE and decreasing HREE with large Eu anomalies; the quartz-monzonites have fractionated LREE and nearly flat HREE with no Eu anomaly. The flat HREE and/or HREE enrichment is attributed to involvement of garnet and/or zircon in melt generation at the source. The uranium and thorium contents in the granitic rocks are present in the accessory minerals—particulary in monazite, titanite, zircon, allanite, fluorite, apatite, and opaques. Anomalous high radioactivity in the bostonite (alkaline) dike as well as uranium mineralization are largely confined to contacts and fracture zones. Uranophane is the characteristic uranium mineral in the oxidation zone. An XRD study of the high anomalies in pegmatite and bostonite reveals that the uranium mineralizations produced uranophane (Usilicate), thorianite, soddyite, zippeite, and becquerelite. 相似文献
19.
The Archean Mkhondo suite in southern Swaziland is a multiply deformed succession of metasediments intruded with amphibolite dykes and sills and granitoid gneisses. Mineral and textural relationships indicate an early period of granulite facies metamorphism, followed later by amphibolite facies metamorphism. Geothermobarometry indicates maximum temperatures of 700–900°C and burial depths of 25–3 km. Paragneisses and biotite quartzites have LREE enriched patterns with small negative Eu anomalies, whereas white quartzites show variable REE patterns and low REE concentrations. BIF has slight LREE enrichment and Eu anomalies. Amphibolites have moderate LREE enrichment and depletions in Ta---Nb and P. Unlike many Archean granitoids, the Mkhondo granitoid gneisses are high in K and other LILE, have large negative Eu anomalies and are not depleted in HREE.SHRIMP
isotopic analyses of detrital zircons from a biotite quartzite define a source age of 3600–3460 Ma. A deformed granitoid in tectonic contact with the Mkhondo suite yields a zircon evaporation
mean age of 3192±5 Ma, which is interpreted as the age of emplacement. A zircon evaporation age of a granitic melt patch in paragneiss, as well as whole-rock and garnet Sm---Nd isotopic ages, suggest that the peak of high-grade metamorphism in the Mkhondo suite occurred at about 2750 Ma. This is the first evidence for Late Archean high-grade metamorphism in the southeastern Kaapvaal craton. The age data of this study restrict deposition of the Mkhondo suite to between 3.2 and 2.75 Ga.Mkhondo paragneisses are interpreted as shales with biotite quartzites as iron- and quartz-rich detrital sediments. Geochemical mixing calculations indicate that the sediment sources were composed of basalt (±komatiite), TTG and Eu-depleted granitoids. The Mkhondo assemblage may have been deposited along a passive continental margin or in a continental interior basin. The presence of minor BIF with positive Eu anomalies suggests minor hydrothermal input into the sedimentary basin. Intense chemical weathering was probably most important in production of the relatively pure quartz sands. 相似文献
20.
Field relations, mineralogy, major- and trace-element contents (including REE analyses of whole-rock samples and minerals) of three Proterozoic granites and their associated molybdenite mineralized aplites have been studied at Allebuoda, Munka and Kåtaberget in northern Sweden. The granites crystallized from melts that were not saturated with water. The mineralized potassic aplites formed by quenching of residual melts caused by sudden pressure drop, H2O saturation and vapour escape during tectonic rupturing. Leucogranites with higher Na2O/K2O ratios from Allebuoda and Munka crystallized during H2O-saturated equilibrium conditions in which the exsolved vapour could continuously migrate away. The pressure was probably 3 kbar at Munka, and somewhat lower at Allebuoda.
The granites have REE patterns characterized by LREE enrichments and negative Eu anomalies. In comparison, the potassic aplites and the more sodic leucogranites are depleted in LREE, enriched in HREE and have larger negative Eu anomalies. Allanite and monazite are the most important REE carriers in the granites. These minerals are strongly enriched in LREE, whereas fluorite and xenotime, which are more abundant in the aplites, are most enriched in HREE. Due to the strong control of accessory minerals on the REE balance, REE are of limited use in petrogenetic modelling of highly evolved granitic systems. 相似文献