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1.
State-of-the-art analytical techniques are capable of detecting contamination In the part per billion (ppb) range or lower. At these levels, a truly representative ground water sample Is essential to precisely evaluate ground water quality. The design specifications of a ground water monitoring system are critical in ensuring the collection of representative samples, particularly throughout the long-term monitoring period.
The potential interfaces from commonly used synthetic well casings require a thorough assessment of site, hydrogeology and the geochemical properties of ground water. Once designed, the monitoring system must be installed following guidelines that ensure adequate seals to prevent contaminant migration during the installation process or at some time in the future. Additionally, maintaining the system so the wells are in hydraulic connection with the monitored zone as well as periodically Inspecting the physical integrity of the system can prolong the usefulness of the wells for ground water quality. When ground water quality data become suspect due to potential interferences from existing monitoring wells, an appropriate abandonment technique must be employed to adequately remove or destroy the well while completely sealing the borehole.
The results of an inspection of a monitoring system comprised of six 4-inch diameter PVC monitoring wells at a hazardous well facility Indicated that the wells were improperly installed and in some cases provided a pathway for contamination. Subsequent down hole television inspections confirmed inaccuracies between construction logs and the existing system as well as identified defects in casing materials. An abandonment program was designed which destroyed the well casings in place while simultaneously providing a competent seal of the re-drilled borehole.  相似文献   

2.
When fugitive methane migrates upward along boreholes of oil and gas wells, it may migrate into shallow ground water or pass through overlying soil to the atmosphere. Prior to this study, there was little information on the fate of fugitive methane that migrates into ground water. In a field study near Lloydminster, Alberta, Canada, we found hydrogeochemical evidence that fugitive methane from an oil well migrated into a shallow aquifer but has been attenuated by dissimilatory bacterial sulfate reduction at low temperature ( approximately 5 degrees C) under anaerobic conditions. Evidence includes spatial and temporal trends in concentrations of methane and sulfate in ground water and associated trends in concentrations of bicarbonate and sulfide. Within 10 m of the oil well, sulfate concentrations were low, and sulfate was enriched in both 34S and 18O. Sulfate concentrations had a strong positive correlation with delta13C values of bicarbonate, and sulfide was depleted in 34S compared to sulfate. These data indicate that bacterial sulfate reduction occurred near the production well. Near the oil well, elevated concentrations of bicarbonate were observed, and the bicarbonate was depleted in 13C. Modeling indicates that the main source of this excess 13C-depleted bicarbonate is oxidized methane. In concert with the sulfate concentration and isotope data, these results support an interpretation that in situ bacterial oxidation of methane has occurred, linked to bacterial sulfate reduction. Bacterial sulfate reduction may play a major role in bioattenuation of fugitive natural gas in ground water in western Canada.  相似文献   

3.
Volatile organic compounds delected in ground water from wells at Test Area North (TAN) at the Idaho National Engineering Laboratory (INEL) prompted RCRA facility investigations in 1989 and 1990 and a CERCLA-driven RI/FS in 1992. In order to address ground water treatment feasibility, one of the main objectives, of the 1992 remedial investigation was to determine the vertical extent of ground water contamination, where the principle contaminant, of concern is trichloroethylene (TCE). It was hypothesized that a sedimentary interbed at depth in the fractured basalt aquifer could be inhibiting vertical migration of contaminants to lower aquifers. Due to the high cost of drilling and installation of ground water monitoring wells at this facility (greater than $100,000 per well), a real time method was proposed for obtaining and analyzing ground water samples during drilling to allow accurate placement of well screens in zones of predicted VOC contamination. This method utilized an inflatable pump packer pressure transducer system interfaced with a datalogger and PC at land surface. This arrangement allowed for real lime monitoring of hydraulic head above and below the packer to detect leakage around the packer during pumping and enabled collection of head data during pumping for estimating hydrologic properties. Analytical results were obtained in about an hour from an on-site mobile laboratory equipped with a gas chromalograplvmass spectrometer (GC/MS). With the hydrologic and analytical results in hand, a decision was made to either complete the well or continue drilling to the next test zone. In almost every case, analytical results of ground water samples taken from the newly installed wells closely replicated the water quality of ground water samples obtained through the pump packer system.  相似文献   

4.
A large number of oil wells in Kuwait were damaged and ignited by the retreating Iraqi troops during the 1991 Gulf War. The resulting spillage of huge volumes of crude oil on the surface gave rise to oil lakes and crude oil–impregnated soil. Moreover, products of crude oil combustion had spread over a large tract of the ground surface, causing widespread contamination of soil. Hydrocarbon contamination of ground water by the infiltrating runoff water carrying the contaminants from the surface soil to the water table and/or through direct contact with the crude oil leaking through the damaged casing in the subsurface was feared. This preliminary study was carried out to investigate the extent and nature of this possible contamination of ground water. The results indicate that the shallow fresh water lenses present under the Umm Al-Aish water field and in the southeastern parts of the Raudhatain water field in North Kuwait were affected by hydrocarbon pollution. Standard methods like the determination of the contents of the total petroleum hydrocarbon by the Fourier transform infrared method and 16 polyaromatic hydrocarbons using the gas chromatography-mass spectrometry method did not work well, possibly due to the environmental degradation of the crude oil over time. The fluorescence methods and the total organic carbon and total organic matter gave better indications of the intensity and the extent of ground water pollution. The brackish water fields of South and Central Kuwait were, however, free of any indications of hydrocarbon contamination.  相似文献   

5.
The New Jersey Department of Environmental Protection's Technical Regulations require the horizontal and vertical delineation of contamination. Monitor wells screened at increasingly deeper intervals are used to delineate vertical contamination. In New Jersey, the open interval in a bedrock well cannot exceed 7.6 m. Since contamination has been found at depths as great as 91.4 m in a production well in the study area, it would be prohibitively expensive to install monitor wells with 7.6 m open holes at ever-increasing depths until no contamination was found. Isolation of discrete zones in boreholes using pneumatic packers was implemented at a site in north central New Jersey. Ground water samples were collected from selected 6.1 m sections of boreholes drilled into fractured bedrock at three locations on the property and one offsite location. The ground water samples were analyzed in a field laboratory. The analytical results were used to determine the vertical extent of gasoline-related compounds dissolved in the ground water on the property and offsite. These compounds include benzene, ethylbenzene, methyl tertiary butyl ether, toluene, and xylenes. The four boreholes were converted into bedrock monitor wells. The intake interval for each of the wells was selected through evaluation of the vertical distribution of contaminants as determined from analytical results obtained from a field laboratory located onsite. Three wells are used for the recovery of contaminated ground water. The recovered water will be treated at the onsite air-stripping unit. The fourth well is used to chemically and hydraulically monitor the progress of the ground water recovery program.  相似文献   

6.
The water-soluble fractions of unleaded gasoline, kerosene and diesel fuel were evaluated by U.S. EPA Methods 602, 610, and 625.
Several chemical indicator compounds useful in assessing petroleum contamination of ground water, including benzene, substituted benzenes, n-alkanes, and polynuclear aromatic hydrocarbons, were identified. These were applied to the interpretation of data collected from monitoring wells at gasoline service stations that were undergoing ground water remediation. The chemical indicators are used to identify the likely type(s) of petroleum contamination. Certain hydrocarbons may be unique to specific fuel types.
Gas chromatograms of field sample extracts were compared with chromatograms of laboratory water-soluble fractions (WSFs) and neat fuels (unleaded gasoline, kerosene, and diesel). In some situations, field samples represented water-soluble fractions of the contaminating fuel. In others, a fuel-water agglomeration was indicated, with the chromatograms showing peaks that represented components of both the WSFs and the neat fuels.
The use of both gas chromatography pattern identification and chemical indicators appears to be a viable approach to assessing ground water contamination caused by petroleum products.  相似文献   

7.
In the past 30 to 40 years, floodplain areas of large rivers, such as the Missouri River, have been extensively used for large industrial and municipal landfills. Many of these sites are now causing varying degrees of ground water contamination. Rapid geophysical characterization techniques have proven useful for delineation of anomalous areas indicative of potential contaminant plumes. These methods have also resulted in a cost effective approach to the location and number of monitoring wells.
An effective technique to initially characterize ground water contamination at such landfills along the Missouri River in northwestern Missouri involved a combination of electrical resistivity and electromagnetic conductivity methods. Resistivity was used to obtain soundings of the alluvium by using a modified Wenner array and to corroborate shallow electromagnetic conductivity measurements by using short Wenner array electrode spacings.
Upon confirmation of similar measurements of the upper soils for the two methods, numerous electromagnetic conductivity traverses were made at each landfill site. The data generated from these surveys were graphed and contoured to delineate anomalous areas. Based on the geophysical study, a ground water monitoring well network was then designed for each landfill.
As a result, a minimal number of wells were required to initially characterize the ground water quality at these two sites. In general, analysis of water samples from these wells displayed good correlation with the geophysical results.  相似文献   

8.
Detection of free-phase gas (FPG) in groundwater wells is critical for accurate assessment of dissolved gas concentrations and the occurrence of FPG in the subsurface, with consequent implications for understanding groundwater contamination and greenhouse gas emissions. However, identifying FPG is challenging during routine groundwater monitoring and there is poor agreement on the best approach to detect the occurrence of FPG in groundwater. In this study, laboratory experiments in a water column were designed to mimic nonflowing and flowing conditions in a groundwater well to evaluate how the presence of FPG affects water pressure and commonly used continuous field parameters. The laboratory results were extrapolated to interpret field data at an abandoned exploration well with episodic release of free-gas CO2. The FPG effect on water pressure varied between flowing and nonflowing wells, and depending on whether the FPG was above or below the sensor. Electrical conductivity values were decreased and/or behaved erratically when FPG was present in the water column. Findings from this study have shown that the combined measurement of water pressure, electrical conductivity, and total dissolved gas pressure can provide information about the occurrence of FPG in groundwater wells. Measurement of these parameters at different depths can also provide information about relative depths and amounts of FPG within the well water column. This approach can be used for long-term monitoring of groundwater gases, managing gas-locking in production wells with gassy groundwater, and measuring fugitive greenhouse gas emissions from groundwater wells.  相似文献   

9.
The reliability of filter pack and annular seal emplacements, and the degree of integrity of installed seals, are two of the most important factors to be considered when both installing and later utilizing ground water monitoring wells.
Numerous, and often costly, problems of using existing methods of installing filter packs and annular seals during the construction of ground water monitoring wells have led to the development of a technique of installing these monitoring well components using a dry injection system.
The dry injection system has been used to construct monitoring wells in extremely complex overburden/bedrock environments with a variety of drilling techniques. The system has shown that a high degree of reliability in the, construction of monitoring wells and greater confidence in obtaining representative ground water samples can be achieved over existing methods of filter pack and annular seal emplacement. The system has also been more cost effective than existing methods, especially for deep boreholes and multilevel monitoring system installations.  相似文献   

10.
The objective of this study was to assess the possible impact of deep well disposal operations, conducted between 1958 and 1974, on the ground water quality in a shallow fresh water aquifer beneath Sarnia, Ontario, Canada. Because of the breakout of formation fluids in Sarnia and Port Huron, Michigan, in the early 1970s, it had been hypothesized that liquid waste from the disposal zone in bedrock had leaked through numerous abandoned oil, gas, and salt wells in the area up to the shallow fresh water aquifer and from there to the surface.
A monitoring well network of 29 5cm (2 inch) diameter piezometers was established in the thin sand and shale aquifer system, which exists between 30 and 70m (100 and 230 feet) below ground surface. In addition, a 300m (1000 foot) deep borehole was drilled and instrumented with a Westbay multilevel casing, which permitted sampling of the disposal zone.
Ground water samples from the shallow monitoring wells and the Westbay multilevel casing were analyzed for volatiles by GC/MS. Those volatile aromatics that were conspicuously present in the deep disposal zone, e.g., ethyl toluenes and trimethyl benzene, were not detected in the shallow monitoring wells. Thus, if contaminants from the disposal zone did indeed migrate to the shallow aquifer, contamination was not widespread and probably consisted mostly of displaced chloride-rich formation waters.  相似文献   

11.
Horizontal drilling and hydraulic fracturing have enabled hydrocarbon recovery from unconventional reservoirs, but led to natural gas contamination of shallow groundwaters. We describe and apply numerical models of gas‐phase migration associated with leaking natural gas wells. Three leakage scenarios are simulated: (1) high‐pressure natural gas pulse released into a fractured aquifer; (2) continuous slow leakage into a tilted fractured formation; and (3) continuous slow leakage into an unfractured aquifer with fluvial channels, to facilitate a generalized evaluation of natural gas transport from faulty natural gas wells. High‐pressure pulses of gas leakage into sparsely fractured media are needed to produce the extensive and rapid lateral spreading of free gas previously observed in field studies. Transport in fractures explains how methane can travel vastly different distances and directions laterally away from a leaking well, which leads to variable levels of methane contamination in nearby groundwater wells. Lower rates of methane leakage (≤1 Mcf/day) produce shorter length scales of gas transport than determined by the high‐pressure scenario or field studies, unless aquifers have low vertical permeabilities (≤1 millidarcy) and fractures and bedding planes have sufficient tilt (~10°) to allow a lateral buoyancy component. Similarly, in fractured rock aquifers or where permeability is controlled by channelized fluvial deposits, lateral flow is not sufficiently developed to explain fast‐developing gas contamination (0‐3 months) or large length scales (~1 km) documented in field studies. Thus, current efforts to evaluate the frequency, mechanism, and impacts of natural gas leakage from faulty natural gas wells likely underestimate contributions from small‐volume, low‐pressure leakage events.  相似文献   

12.
Clusters of elevated methane concentrations in aquifers overlying the Barnett Shale play have been the focus of recent national attention as they relate to impacts of hydraulic fracturing. The objective of this study was to assess the spatial extent of high dissolved methane previously observed on the western edge of the play (Parker County) and to evaluate its most likely source. A total of 509 well water samples from 12 counties (14,500 km2) were analyzed for methane, major ions, and carbon isotopes. Most samples were collected from the regional Trinity Aquifer and show only low levels of dissolved methane (85% of 457 unique locations <0.1 mg/L). Methane, when present is primarily thermogenic (δ13C 10th and 90th percentiles of ?57.54 and ?39.00‰ and C1/C2+C3 ratio 10th, 50th, and 90th percentiles of 5, 15, and 42). High methane concentrations (>20 mg/L) are limited to a few spatial clusters. The Parker County cluster area includes historical vertical oil and gas wells producing from relatively shallow formations and recent horizontal wells producing from the Barnett Shale (depth of ~1500 m). Lack of correlation with distance to Barnett Shale horizontal wells, with distance to conventional wells, and with well density suggests a natural origin of the dissolved methane. Known commercial very shallow gas accumulations (<200 m in places) and historical instances of water wells reaching gas pockets point to the underlying Strawn Group of Paleozoic age as the main natural source of the dissolved gas.  相似文献   

13.
Public health authorities generally recommend annual water-quality monitoring of rural water wells and shock chlorination if coliforms are detected. It is implicitly assumed that shock chlorination is effective in ridding most wells of bacteriological pathogens for months to years. Neither annual monitoring nor shock chlorination was effective in addressing coliform contamination of selected water wells in a small town developed on an alluvial aquifer where septic system effluents are impacting well water quality. Considerable temporal variation in total and fecal coliforms was observed in water wells monitored for a six-month period. Individual wells intermittently met and exceeded the drinking water criteria, indicating annual sampling was insufficient. Shock chlorination of three contaminated wells and their associated distribution systems proved ineffective because colonies apparently originated from outside the wells and reappeared over relatively short time periods (ranging from less than one week up to 21 weeks). The relatively fast and similar rate of recovery of total heterotrophic bacteria suggested they are related to biofilm formation in the wells and not to ground water contamination.  相似文献   

14.
The Effect of Three Drilling Fluids on Ground Water Sample Chemistry   总被引:1,自引:0,他引:1  
Three monitoring wells were installed in borings that were constructed using water-based drilling fluids containing either (1) guar bean, (2) guar bean with breakdown additive, or (3) bentonite. These fluids were selected to observe their effect on the chemistry of subsequent water samples collected from the wells. The wells were installed to depths of 66 feet, 100.5 feet and 103 feet, respectively, in fine-to-medium sand and gravel outwash deposits near Antigo, Wisconsin. Drilling fluids were necessary to maintain an open borehole during well construction through strata containing cobbles and boulders.
The bentonite and guar drilling fluids caused temporarily elevated concentrations of chemical oxygen demand (COD) in ground water samples collected from the monitoring wells. Using standard development, purging and sampling procedures, elevated COD concentrations persisted for about 50 days for the well bored with the guar-with-additive fluid, 140 days for the bentonite well and 320 days for the guar well. Unfiltered ground water samples for all wells had greater concentrations of COD than samples filtered through a 0.45 micron filter. Sulfate concentrations also decreased with time in the guar-with-additive well and bentonite well, but not in the guar well.
The elevated COD concentrations are attributed to the large concentrations of oxidizable carbon present in the guar bean drilling fluid and in the organic polymers present in the bentonite drilling fluid. Well development and purging procedures, including borehole flushing, surging, bailing and/or chemically induced viscosity breakdown of the guar mud decreased the time before background conditions were achieved. Future research should evaluate the physical and geochemical interaction of different drilling fluid compositions with a variety of geologic matrices and drilling, well development and well purging techniques.  相似文献   

15.
油田采油和注水对油井动态的影响   总被引:1,自引:0,他引:1       下载免费PDF全文
采用弹性理论和地下流体力学理论,通过理想的水以状含油层模型,分析讨论了油田采油和注水对油井动态的影响。认为异层采油和注水引起的含油层应力应变的变化,使含油层孔隙压力发生变化,进而对油井的动态产生影响。  相似文献   

16.
The objective of most ground water quality monitoring programs is to obtain samples that are "representative" or that retain the physical and chemical properties of the ground water in an aquifer. Many factors can influence whether or not a particular sample is representative, but perhaps the most critical factor is the method or type of sampling device used to retrieve the sample.
The sampling equipment available today ranges from simple to highly sophisticated, and includes bailers, syringe devices, suction-lift pumps, gas-drive devices, bladder (Middelburg-type) pumps, gear-drive and helical rotor electric submersible pumps and gas-driven piston pumps. New devices are continually being developed for use in small-diameter wells in order to meet the needs of professionals engaged in implementing elaborate ground water monitoring programs.
In selecting a sampling device for a monitoring program, the professional must consider a number of details. Among the considerations are: the outside diameter of the device, the overall impact of the device on ground water sample integrity (including the materials from which the sampling device and associated equipment are made and the method by which the device delivers the sample), the capability of the device to purge the well of stagnant water, the rate and the ability to control the rate at which the sample is delivered, the depth limitations of the device, the ease of operating, cleaning and maintaining the device, the portability of the device and required accessory equipment, the reliability and durability of the device, and the initial and operational cost of the device and accessory equipment. Based on these considerations, each of the devices available for sampling ground water from small-diameter wells has its own unique set of advantages and disadvantages that make it suitable for sampling under specific sets of conditions. No one sampling device is applicable to all sampling situations.  相似文献   

17.
A tracer test was used to evaluate whether cross contamination exists along a monitoring well completed through a shallow ground water system in fractured clay and screened in a sand and gravel aquifer. The fractured clay is separated from the sand and gravel deposit by a layer of highly plastic unfractured clay. A natural vertical downward hydraulic gradient of approximately 0.5 exists between the shallow system and the sand and gravel aquifer. Ground water contamination was detected in an adjacent monitoring well screened in the fractured clay and in the monitoring well screened in the sand and gravel deposit. No ground water contamination was apparent in an intermediate well screened in the unfractured clay layer. A tracer of sodium bromide was injected into a shallow boring near the monitoring wells. The tracer was detected in the monitoring well in the sand and gravel aquifer after three to seven days. The bromide concentration continued to increase in this well with time while the concentration in the shallow boring declined. This trend of tracer concentration indicates the tracer has in fact migrated downward and possibly traveled along the well column.  相似文献   

18.
The impacts of unconventional oil and gas production via high-volume hydraulic fracturing (HVHF) on water resources, such as water use, groundwater and surface water contamination, and disposal of produced waters, have received a great deal of attention over the past decade. Conventional oil and gas production (e.g., enhanced oil recovery [EOR]), which has been occurring for more than a century in some areas of North America, shares the same environmental concerns, but has received comparatively little attention. Here, we compare the amount of produced water versus saltwater disposal (SWD) and injection for EOR in several prolific hydrocarbon producing regions in the United States and Canada. The total volume of saline and fresh to brackish water injected into depleted oil fields and nonproductive formations is greater than the total volume of produced waters in most regions. The addition of fresh to brackish “makeup” water for EOR may account for the net gain of subsurface water. The total amount of water injected and produced for conventional oil and gas production is greater than that associated with HVHF and unconventional oil and gas production by well over a factor of 10. Reservoir pressure increases from EOR and SWD wells are low compared to injection of fluids for HVHF, however, the longer duration of injections could allow for greater solute transport distances and potential for contamination. Attention should be refocused from the subsurface environmental impacts of HVHF to the oil and gas industry as a whole.  相似文献   

19.
Theoretical analysis and laboratory column experiments were carried out to investigate the conditions required for petroleum products (oil) to flow into a well installed through a sandy porous medium contaminated with the oil. The results indicated that oil would flow into a well only after a layer of "free oil" is formed in the adjacent porous medium. Because significant quantities of oil could be stored in the porous medium under the influence of capillary suction prior to the formation of the zone of free oil, the presence of oil in a well would indicate an advanced stage of oil contamination of the subsurface. While monitoring wells could be used to delineate the extent of the free-oil plume and the plume of dissolved petroleum constituents, they are not useful for delineating the extent of capillary held oil.
The experimental results also indicated that the ratio of the oil-layer thickness in the well to that in the porous medium is not a constant as is sometimes assumed in practice. Further, estimates of the oil thickness in the medium based on the oil thickness in wells and on capillary properties measured in the laboratory were sensitive to the values of the parameters used in these estimates. The measured thickness of the oil layer in a monitoring well alone may not yield reliable estimates of the amount of oil in the subsurface, and assuming that the oil-thickness ratio is a constant can lead to inadequate site assessments and inappropriate remedial plans.  相似文献   

20.
Waste disposal sites with volatile organic compounds (VOCs) frequently contain contaminants that are present in both the ground water and vadose zone. Vertical sampling is useful where transport of VOCs in the vadose zone may effect ground water and where steep vertical gradients in chemical concentrations are anticipated. Designs for combination ground water and gas sampling wells place the tubing inside the casing with the sample port penetrating the casing for sampling. This physically interferes with pump or sampler placement. This paper describes a well design that combines a ground water well with gas sampling ports by attaching the gas sampling tubing and ports to the exterior of the casing. Placement of the tubing on the exterior of the casing allows exact definition of gas port depth, reduces physical interference between the various monitoring equipment, and allows simultaneous remediation and monitoring in a single well. The usefulness and versatility of this design was demonstrated at the Idaho National Engineering and Environmental Laboratory (INEEL) with the installation of seven wells with 53 gas ports, in a geologic formation consisting of deep basalt with sedimentary interbeds at depths from 7.2 to 178 m below land surface. The INEEL combination well design is easy to construct, install, and operate.  相似文献   

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