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1.
Aquatic humic substances, which account for 30 to 50% of the organic carbon in water, are a principal component of aquatic organic matter. The molecular size of aquatic humic substances, determined by small-angle X-ray scattering, varies from 4.7 to 33 Å in their radius of gyration, corresponding to a molecular weight range of 500 to greater than 10,000. The aquatic fulvic acid fraction contains substances with molecular weights ranging from 500 to 2000 and is monodisperse, whereas the aquatic humic acid fraction contains substances with molecular weights ranging from 1000 to greater than 10,000 and is generally polydisperse. 相似文献
2.
Thermogravimetric technique was used for the characterization of natural (humic) and synthetic (melanoidins) substances. The influence of pH on the thermal stability of humic substances was studied. A similarity in thermal behaviour of natural humic substances and of melanoidins (prepared from an excess of sugar) and the unique thermal properties of melanoidins (prepared from basic amino acids) was observed. Thermal behavior of natural and synthetic substances was compared with model compounds of sugar, peptide and kerogen types. 相似文献
3.
内蒙古西胡里吐盆地有机质特征及其与铀矿化的关系 总被引：7，自引：2，他引：7
在砂岩型铀矿床中 ,有机质与铀矿化之间有着较为密切的关系。西胡里吐盆地的有机质主要是以松柏类和蕨类等高等植物残体为母质的腐殖型有机质。通过镜质体反射率、有机质碎屑的颜色、粘土矿物X 衍射和古地温恢复等分析测试发现 ,有机质的成熟度较低 ,处于未成熟—低成熟早期阶段。有机质的类型和成熟度决定了其在热演化中产生了大量腐殖酸并保存在地层中。褐煤、腐殖酸、残余植物碎屑和地沥青等是现存有机质的主要类型。除大量产出的煤层外 ,有机质主要呈碎屑状和细分散状分布于地层之中。 70 %的岩石中有机质的丰度在 0 1 %～ 3 % ,对铀矿化的形成较为有利。铀与有机质的紧密共生以及二者之间的正相关性 ,表明了有机质在西胡里吐盆地铀矿化形成中所起的重要作用。有机质中的腐殖酸与铀矿化的关系最为密切 ,有机粘土复合体、蚀变岩屑、植物碎屑和地沥青等吸附剂对铀的吸附均与腐殖酸有关。腐殖酸吸附铀后可以将铀还原 ,还可以与铀酰离子等进行络 (鳌 )合形成铀酰腐殖酸盐 ,并最终引起铀的沉淀富集。 相似文献
4.
《Applied Geochemistry》2000,15(1):97-116
A total of 35 groundwaters from 4 different aquifer systems in Germany are investigated for their physico-chemical properties, dissolved organic C (DOC) and humic and fulvic acids. Humic substances are isolated and characterized for their elemental composition, UV/Vis and fluorescence spectroscopic properties, size distribution by gel permeation chromatography (GPC) and 14C content. For isolation of sufficient quantities of humic substances a mobile sampling system is developed based on a combination of reverse osmosis (RO) and XAD–8 adsorption chromatography. One of the aquifer systems (Gorleben) covers a wide range of hydrogeochemical conditions, whereas the other 3 aquifer systems (Munich, Franconian Albvorland and Fuhrberg) have less diverse properties. One specific feature of the Gorleben aquifer system is the presence of a very high DOC, which, in contrast to other aquifer systems, contains considerable amounts of aquatic humic acid. This is attributed to the release of aquatic humic substances originating from sedimentary organic C (SOC) that is abundant in Gorleben sediments. The results show that aquatic humic substances from different aquifer systems have dissimilar properties which differ from one another. Systematic differences are found among humic substances from different regions of the Gorleben aquifer system. Such differences are considered to be caused by the mixing of humic substances from the SOC. However, exact quantification of such mixing appears difficult because overlapping effects of different geochemical processes feigning a dissolution of SOC cannot be excluded. 相似文献
5.
13C NMR spectra of solid humic substances in Holocene sediments have been obtained using cross polarization with magic-angle sample spinning techniques. The results demonstrate that this technique holds great promise for structural characterizations of complex macromolecular substances such as humin and humic acids. Quantifiable distinctions can be made between structural features of aquatic and terrestrial humic substances. The aliphatic carbons of the humic substances are dominant components suggestive of input from lipid-like materials. An interesting resemblance is also noted between terrestrial humic acid and humin spectra. 相似文献
6.
Effect of extracellular polymeric substances on sludge reduction potential of Bacillus licheniformis 总被引：1，自引：0，他引：1
J. Merrylin S. Kaliappan S. Adish Kumar I. T. Yeom Banu J. Rajesh 《International Journal of Environmental Science and Technology》2013,10(1):85-92
The disposal of wastewater sludge generated during the treatment of the various municipal and industrial wastewaters is a major environmental problem. In this study the thermophilic bacterium Bacillus licheniformis, which enhances the efficiency of sludge reduction, was isolated from waste activated sludge acclimated to 55 °C. The resulting suspended solids’ degradation was 12 % and chemical oxygen demand solubilization was 18 %. To further enhance the sludge reduction potential, extra polymeric substances, which play a major role in the formation of flocs, were removed. A chemical extractant, ethylenediaminetetraacetate that is also a cation binding agent, was used to remove the extra polymeric substances. After the removal of extra polymeric substances, the suspended solids’ degradation increased from 12 to 23 % and the chemical oxygen demand solubilization increased from 18 to 25 %. These observations confirm that Bacillus licheniformis enhanced sludge reduction in non-flocculated sludge (with the removal of extra polymeric substances) as compared to flocculated sludge (without the removal of extra polymeric substances). 相似文献
7.
区域地层岩石中元素丰度及其演化资料说明,早古生代末期的火山作用与放牛沟多金属矿床的形成并无明显的直接联系。从时空关系、物质组分以及矿化和元素在多种介质中的分带规律都表明矿床、原生晕和华力西早期后庙岭花岗岩具有共同的物质来源。矿床同位素研究结果,成矿成晕物质主要来自上地幔或下地壳,但有部分来自上地壳。后庙岭花岗岩以Ⅰ型为主,并兼有S型特征。其成岩物质主要来自深部地壳同熔岩浆,但也有部分火山-沉积岩系同化重熔物质加入。根据初始~(87)Sr/~(86)Sr比值为0.705成岩物质也应以深源为主。后庙岭花岗岩物质来源的双重性一定程度上反映了放牛沟多金属矿床成矿成晕物质来源的双重性——以下地壳为主并兼有上地壳物质来源。 相似文献
8.
土壤腐殖质提取和分组综述 总被引：4，自引：0，他引：4
土壤腐殖质的定量提取、分离与纯化是深入研究土壤腐殖质的重要前提。本文详细综述了国内外腐殖质提取和分组的实验手段和研究进展;以国际腐殖质协会提供的标准方法为参考,对比论述了提取剂种类,提取次数、提取剂用量等的选择;对比讨论了两种主要的土壤腐殖质的分组方法。超滤分离和体积排阻色谱是腐殖质物理化学表征研究中的两种新兴技术,笔者认为组合使用两种实验手段对土壤腐殖质进行细致的分离与分组研究有助于深化理解土壤腐殖质的化学性质和分子结构。 相似文献
9.
Abstract The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late times; in the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian. 相似文献
10.
Chen Yuchuan Mao Jinwen Wang Ping''an Chinese Academy of Geological Sciences Beijing Fei Zhenbi 《《地质学报》英文版》1995,69(2)
The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian. 相似文献
11.
Amino acids comprise from 15 to 36% by weight of humic substances from carbonate and non-carbonate sediments. Humic and fulvic acids extracted from carbonate sediments are characterized by an amino acid composition consisting primarily of the acidic amino acids, aspartic and glutamic acid. Humic substances from non-carbonate sediments have a distinctly different amino acid composition consisting primarily of glycine and alanine. Amino acid analyses of various molecular weight fractions of fulvic acids extracted from carbonates show that lower molecular weight fractions have appreciably higher relative abundances of the acidic amino acids compared to higher molecular weight fractions. Based on typical values for carboxyl group content in humic substances, acidic amino acids may be a significant contributor of these functional groups. Carbonate surfaces appear to selectively adsorb aspartic acid-enriched organic matter while non-carbonates do not have this property. 相似文献
12.
Comparative characterization of humic substances from the open ocean, estuarine water and fresh water 总被引：2，自引：0，他引：2
Humic substances were isolated from ocean, estuarine water and fresh water using a two column array of XAD-8 and XAD-4 resins in series. The extracted fulvic acids and XAD-4 fraction from different origins were characterized using UV–vis., molecular fluorescence, Fourier transform infrared (FTIR) spectroscopy and cross polarization magic angle spinning (CPMAS)-13C nuclear magnetic resonance (NMR) spectroscopy. The isolation procedure allowed us to obtain the necessary amount of sample for characterization, even in the case of open ocean water, which has a very low amount of dissolved organic carbon (DOC). Humic substances from the open ocean showed the lowest chromophore and fluorophore contents and showed relatively greater fluorescence at lower wavelengths than those from fresh water. FTIR and 13C NMR spectra highlighted the idea that humic substances from a marine environment have a more branched aliphatic structure and less aromatic structure than those highly influenced by terrestrial sources. The spectra also suggest that the open ocean humic substances have a higher content of olefinic carbons than aromatic- or alkyl-substituted carbons. 相似文献
13.
In laboratory experiments, two fungi that commonly colonize leaves of Spartina aZterniJEoru(L oisel.) were studied to determine if they contribute to the formation of humic substances, which have been isolated earlier from salt marsh estuaries. In incubations of up to one year in duration, Phaeosphaeria spartinicola and Phaeosphaeria halima did not form dark pigments when grown in an artificial, full-nutrient medium. However, if the nutrient solution was enriched with a water extract of S. alterniJEoro, appreciable amounts of dark brown substances were produced. Elemental (C, H, N, 0) and spectral (ultraviolet, visible, and Fourier Transform Infrared) analyses of these dark brown substances show them to be similar to salt marsh humic substances. 相似文献
14.
城市饮用水源地水环境健康风险评价及风险管理 总被引：36，自引：1，他引：35
环境健康风险评价是环境科学的一个新兴研究领域,在简要介绍水环境健康风险评价基本方法的基础上,建立了健康风险评价模式,并根据深圳市主要饮用水源地水质监测资料,进行分析与评价。研究结果表明:(1)深圳市7个主要水库由基因毒物质所产生的健康风险的数量级为1 0-5~1 0-4,而由躯体毒物质所产生的健康风险的数量级为1 0-11~1 0-10,因此,基因毒物质为优先控制污染物;(2)对于Cr、As、Cd这三种基因毒物质,这7个水库的优先控制污染物是Cr;(3)对于躯体毒物质,所有水库的优先控制污染物是氨;(4)饮用水源各类污染物所致健康危害的个人年总风险小于国际辐射防护委员会(ICRP)推荐的最大可接受值,但超过瑞典环保局、荷兰建设和环境部推荐的最大可接受水平。目前环境健康风险评价还没有包括在常规环境评价工作中,建议在今后的评价工作中应该逐步开展这方面的工作,以提高供水安全。 相似文献
15.
黑潮化学物质输入东海的途径与通量 总被引：3，自引：0，他引：3
Liu Wei Song Jinming Yuan Huamao Li Xuegang Li Ning Duan Liqin Zuo Jiulong 《地球科学进展》2015,30(8):904-914
在对黑潮水文特征分析的基础上,探讨了黑潮对中国近海化学物质输入途径,归纳总结了黑潮对东海生源要素、痕量元素、同位素及其他化学物质的输入特征,提出了黑潮对中国近海化学物质输入研究应着重关注的问题。主要的结论包括:吕宋海峡、中国台湾东北部及日本九州西南海域是黑潮向中国近海输送化学物质的3个关键区域;黑潮表层水向东海陆架的扩展、次表层水和中层水的涌升以及黑潮季节性流轴摆动是黑潮向东海输送化学物质的基本途径。黑潮主体生源要素的浓度随深度的增加而增大。黑潮对东海生源要素的影响夏季最弱、春季次之、秋冬季最强,其对东海生源要素的输入通量要远高于河流、大气等其他输入源,并且各水层中以中层水的生源要素输入通量为最大。痕量元素在黑潮主体的分布、对东海的输入通量等方面均表现出了与生源要素的差异,各痕量元素的分布及输入通量随痕量元素的不同而不尽相同,其中次表层水的涌升在对邻近海域痕量元素分布的影响中起到了重要作用。同位素可指示黑潮对东海陆架的入侵程度及变化规律,并与营养盐等有一定的相关性。黑潮是东海微量温室气体N2O,CH4等其他化学物质的重要输入源,进而对东海生态环境产生影响。进一步研究应着重从系统性外海观测、痕量元素及同位素等化学物质调查、黑潮对中国近海输入化学物质的控制过程等方面深入开展。 相似文献
16.
Effects of heat treatment on fluorescence properties of humic substances from sandy soil in arid land and their Hg(II) binding behaviors 总被引：1，自引：1，他引：0
Qinglong Fu Xiangliang Pan Daoyong Zhang Bin Zhou 《Environmental Earth Sciences》2012,66(8):2273-2279
The topsoil temperature in arid areas of Xinjiang, China can be up to about 80°C in summer. This may significantly affect the chemical properties of soil humic substances. However, the effects of high temperature on characteristics of soil humic substances and their complexation with toxic metals are still poorly known. In the present study, binding of Hg(II) to unheated soil humic substances and heated soil humic substances from sandy soils was comparatively investigated using three-dimensional excitation?Cemission matrix (EEM) fluorescence spectroscopy. Two fluorescent peaks (peak I at Ex/Em?=?365?C370/470?C474?nm; peak II at Ex/Em?=?270?C275/468?C472?nm) identified as humic-like fluorescence were observed in the EEM spectra of humic substances. Both peaks were clearly quenched by Hg(II), indicating the strong interaction of humic-like substances with Hg(II), and showed blue shifts after heat treatment. Heat treatment caused an increase of the fraction of accessible fluorophore (f a), binding sites number (n) and effective quenching constants (logK a), indicating that more binding sites in humic substances could bind Hg(II) and form more stable humic substances?CHg(II) complexes after heat treatment. However, a decrease of binding constants (logK b) suggested that heat treatment would reduce the binding capacity of each binding site of humic substances to Hg(II). This study implies the transport of Hg(II) may be affected by high temperature in the arid zone due to the modification of the physicochemical properties of humic substances in soil. 相似文献
17.
Shinya Inazumi Maya Manabe Ken-ichi Shishido 《Geotechnical and Geological Engineering》2017,35(5):2191-2203
The containment performance of impervious structures is considered the most important performance, which the toxic substances are enclosed in coastal landfill sites. The containment performance is evaluated generally by the hydraulic conductivity and the thickness of impervious structures to focus on an advection. However, the leakage of toxic substances is affected by a diffusion and a dispersion. The diffusion and the dispersion are considered to be easily distinguished on the impervious structure which has the low-hydraulic conductivity. Such phenomena should be considered due to evaluate the containment performance. This is because to improve the containment performance and comprehend leakage of the toxic substances. The containment performance is evaluated from the viewpoint of the diffusion and the dispersion in this research. Concretely, the influence which the toxic substances leaks from impervious structures on the diffusion and the dispersion is evaluated by the infiltration and advection–dispersion analysis on steel-made side impervious walls. In other word, The relation between the leaking amount of toxic substances and coefficient of molecular diffusion, the relation between the travel time or the flow velocity and the leaking amount and the change in the water-level difference are considered respectively. So, the leaking amount which is influenced by a diffusion and a dispersion is considered. Consideration about to secure the containment performance of impervious structure which is restrained leakage by a diffusion and a dispersion. 相似文献
18.
19.
Lichun LIU Yuting CHEN Kuanyu CHEN Jyhyih LEU Tsungkwei LIU 《中国地球化学学报》2006,25(B08):67-67
High concentrations of arsenic and humic substances in groundwater from the southwestern coastal plain of Taiwan were well known for their probable relationships with black-foot disease. In order to realize the relationships between the concentrations of humic substances and arsenic in this area, 24 well water samples were analyzed. After filtered through 0.45 μm glass fiber membrane in the field, samples were kept in the dark at 4℃ and then separated into six fractions with varying range of molecular weight （〈0.5, 0.5-1, 1-5, 5-10, 10-50 and 〉50 k Da） by ultrafiltration apparatus （Molecular/Por Stirred Cell system） in the lab. Concentrations of humic substances were measured by fluorescence spectrometer （HITACHI F-2000, ex=370, em=445） and arsenic by FIAS-AA （Perkin Elmer AAnalyst 100, FIAS-400）. On average, only 6.2% of the total arsenic in water existed in the fraction of 〉0.5 k Da. and the others were complexed with humic substances （including humic acid and fulvic acid）. The results demonstrated a distinct positive correlation between the concentrations of humic substances and arsenic. 相似文献