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1.
In situ LA-ICPMS U-Pb, trace element, and Hf isotope data in zircon demonstrate a Carboniferous age for eclogite-facies metamorphism in Siluro-Devonian protoliths in the Huwan shear zone, Dabie Mountains, Central China. This age contrasts with the more prevailing Triassic age for high- to ultrahigh pressure (HP to UHP) metamorphism in the Qinling-Dabie-Sulu orogen. Metamorphic zircon in two eclogite samples from Sujiahe is characterized by low Th/U ratios, small negative Eu anomalies, flat HREE patterns, and low 176Lu/177Hf ratios. These geochemical signatures suggest that the zircon crystallized in the presence of garnet and in the absence of plagioclase feldspar. Furthermore, temperatures of ~ 655 and ~ 638 °C, calculated using the Ti content of zircon, are consistent with their formation during eclogite-facies metamorphism. The weighted mean 206Pb/238U age of 309 ± 4 Ma (2δ) for this zircon improves previous age estimates for eclogite-facies metamorphism in the Huwan shear zone, ranging from 420 to 220 Ma. Metamorphic zircon from one eclogite sample from Hujiawan, most likely formed during prograde metamorphism, yields an equivalent age estimate of 312 ± 11 Ma. Magmatic zircon cores in the three samples yield ages for the magmatic protoliths of the eclogites ranging from 420 ± 7 to 406 ± 5 Ma, and post-dating the middle Paleozoic collision of the North China and the Qinling terrain. The zircon crystals in the three eclogite samples display a large variation of εHf (t) values of ? 4.9 to 21.3. The metamorphic zircon overgrowths show the same range of εHf (t) values as those of the inherited magmatic crystal interiors. This suggests that the metamorphic zircon overgrowths may have formed by dissolution-reprecipitation of pre-existing magmatic zircon thereby preserving their original Hf isotopic composition. The high εHf (t) values suggest that the protoliths were derived from depleted mantle sources, most likely Paleotethyan oceanic crust; while the low εHf (t) values are attributed to crustal contamination. Some eclogites in the Huwan shear zone have a distinctive signature of continental crust most probably derived from the Yangtze Craton. The coexistence of Paleozoic oceanic crust and Neoproterozoic continental crust with similar metamorphic ages in the Huwan shear zone implies that Paleozoic Paleotethyan oceanic crust was produced within a marginal basin of the northern Yangtze Craton. The opening of the Paleo-Tethyan ocean was slightly younger than the collision of the North China Craton and the Qinling terrain during the Late Paleozoic in the Qinling-Dabie-Sulu orogen. Subduction of the Paleo-Tethyan oceanic crust and associated continental basement resulted in the 309 ± 2 Ma (2σ) eclogite-facies metamorphism in the Huwan shear zone. The subsequent Triassic continent-continent collision led to the final coalescence of the Yangtze and Sino-Korean cratons. Amalgamation of the Yangtze and North China cratons was, therefore, a multistage process extending over at least 200 Ma.  相似文献   

2.
This study characterized the magnetic property and levels of heavy metals of the topsoils near a cement plant. The concentrations of five selected heavy metals (Pb, Cu, Zn and Cd) were measured on 32 topsoil samples (0–20 cm) collected near a cement plant via inductively coupled plasma/mass spectroscopy (ICP-MS). The orders of enrichment factors (EF), on average, were Cd (7.3) > Cu (3) > Zn (2.9) > Pb (2.1), respectively. A self-organizing map (SOM) was applied to the concentrations of heavy metals for “correlation hunting”. Mineral magnetic concentration parameters, such as the specific magnetic susceptibility (χ), susceptibility of anhysteretic remanent magnetization (χARM), saturation isothermal remanent magnetization (SIRM), together with interparametric ratios (such as IRM− 100mT/SIRM, SIRM/χ, χARM/SIRM) show that ferrimagnetic, superparamagnetic (SP) and multi-domain (MD) minerals dominated the soils. The results of correlation analysis indicate that copper showed a significant correlation with χ, χARM and SIRM but such a relationship with χ, χARM and SIRM was only weakly identified for Zn, Cd and Pb.  相似文献   

3.
We have measured magnetic hysteresis loops, zero-field-cooled (ZFC) and field-cooled (FC) remanence, and low-field AC susceptibility as a function of temperature between 2 and 40 K for a single crystal several mm in size and for two powders of manganese carbonate (mineral rhodochrosite, MnCO3), one ground from a natural precipitate (grainsize ∼100 μm) and another synthesized in the laboratory (grainsize ∼10 μm). For the single crystal, measurements carried out both in the basal (easy magnetization) plane and along the trigonal (hard magnetization) axis yielded, expectedly, grossly different magnetic properties. In the basal plane, hysteresis appears to be mostly controlled by domain wall movement at the two lowest temperatures studied, 5 and 15 K, as indicated by a fairly broad switching field distribution. At 25 K and above, however, magnetization reversal occurs at a single, well defined magnetic field, which we interpret as a characteristic field of the in-plane magnetic anisotropy. Hysteresis in the basal plane is observed up to 36 K which is above the nominal Néel temperature of rhodochrosite (34.3 K). In addition, a sharp coercivity peak occurs at 34.5 K. Rather unexpectedly, hysteresis is also observed for the magnetic field applied along the trigonal axis. It is very small at 5 K but develops gradually with increasing temperature, coercivity reaching maximum of 100 mT at 28 K and remanence peaking at slightly higher temperature (30–31 K). Hysteresis along the trigonal axis is observed up to 37 K. Hysteresis temperature dependence conforms with the AC susceptibility versus temperature curve which shows a maximum at 36.5 K. ZFC/FC remanence curves also closely match the temperature dependence of remanence extracted from hysteresis loops. We suggest that this behavior could be due to the presence of a minor, about 1 at.% amount of Fe2+ substituting for Mn in the crystalline lattice of rhodochrosite. Hysteresis measurements on powders have revealed a significant enhance in coercivity, up to 50 mT for the 100-μm powder and up to 150 mT for the 10-μm one. FC/ZFC ratio amounts to about 2 for the natural powder, while for the synthetic one, which is essentially pure material, it barely exceeds unity. FC/ZFC ratio can thus be viewed as a sensitive indicator of iron incorporation into rhodochrosite.  相似文献   

4.
Early in the history of planetary evolution portions of Martian crust became magnetized by dynamo-generated magnetic field. A lateral distribution of the secondary magnetic field generated by crustal remanent sources containing magnetic carriers of certain grain size and mineralogy is able to produce an ambient magnetic field of larger intensity than preexisting dynamo. This ambient field is capable of magnetizing portions of deeper crust that cools through its blocking temperatures in an absence of dynamo. We consider both magnetite (Fe3O4) and hematite (α-Fe2O3) as minerals contributing to the overall magnetization. Analysis of magnetization of magnetic minerals of various grain size and concentration reveals that magnetite grains less than 0.01 mm in size, and hematite grains larger than 0.01 mm in size can become effective magnetic source capable of magnetizing magnetic minerals contained in surrounding volume. Preexisting crustal remanence (for example ∼250 A/m relates to 25% of multi-domain hematite) can trigger a self-magnetizing process that can continue in the absence of magnetic dynamo and continue strengthening and/or weakening magnetic anomalies on Mars. Thickness of the primary magnetic layer and concentration of magnetic carriers allow specification of the temperature gradient required to trigger a self-magnetization process.  相似文献   

5.
Garnet geochronology was used to provide the first direct measurement of the timing of eclogitization in the central Himalaya. Lu–Hf dates from garnet separates in one relict eclogite from the Arun River Valley in eastern Nepal indicate an age of 20.7 ± 0.4 Ma, significantly younger than ultra-high pressure eclogites from the western Himalaya, reflecting either different origins or substantial time lags in tectonics along strike. Four proximal garnet amphibolites from structurally lower horizons are 14–15 Ma, similar to post-eclogitization ages published for rocks along strike in southern Tibet. P–T calculations indicate three metamorphic episodes for the eclogite: i) eclogite-facies metamorphism at ～ 670 °C and ≥ 15 kbar at 23–16 Ma; ii) a peak-T granulite event at ～ 780 °C and 12 kbar; and iii) late-stage amphibolite-facies metamorphism at ～ 675 °C and 6 kbar at ～ 14 Ma. The garnet amphibolites were metamorphosed at ～ 660 °C. Three models are considered to explain the observed P–T–t evolution. The first assumes that the Main Himalayan Thrust (basal thrust of the Himalayan thrust system) cuts deeper at Arun than elsewhere. While conceptually the simplest, this model has difficulty explaining both the granulite-facies overprint and the pulse of exhumation between 25 and 14 Ma. A second model assumes that (aborted) subduction, slab breakoff, and ascent of India's leading edge occurred diachronously: ～ 50 Ma in the western Himalaya, ～ 25 Ma in the central Himalaya of Nepal, and presumably later in the eastern Himalaya. This model explains the P–T–t path, particularly heating during initial exhumation, but implies significant along-strike diachroneity, which is generally lacking in other features of the Himalaya. A third model assumes repeated loss of mantle lithosphere, first by slab breakoff at ～ 50 Ma, and again by delamination at ～ 25 Ma; this model explains the P–T–t path, but requires geographically restricted tectonic behavior at Arun. The P–T–t history of the Arun eclogites may imply a change in the physical state of the Himalayan metamorphic wedge at 16–25 Ma, ultimately giving rise to the Main Central Thrust by 15–16 Ma.  相似文献   

6.
Eclogites and omphacite-bearing blueschists have been newly found in the eastern segment of the southwest Tianshan orogenic belt,Xinjiang,northwest China.After detailed petrological study,three samples including one fresh eclogite TK003,one blueschist sample TK026-8 and one retrograded eclogite TK027,were selected for phase equilibrium modeling under NC(K)MnFMASHO(N2O-CaO-K2O-MnO-FeO-MgO-Al2O3-SiO2-H2O-O)system,by thermocalc 3.33 software.Composition analyses of garnets in these three samples show typical growth zoning with Xpy and Xgrs increasing,Xspss decreasing from core to rim.Pseudosection modeling of the garnet zonation reflects that the eclogites and blueschist experienced a similar P-T evolution trajectory,with a near iso-baric heating in the early stage,and reached eclogite facies metamorphic field with peak P-T regime of 480–515°C,2.00–2.30 GPa.Subsequently the rocks experienced an early iso-thermal decompression retrograde stage with P-T conditions of 515–519°C,1.78–1.93 GPa.Variations of mineralogy and modes of these rocks are probably due to different retrograde paths as a consequence of different bulk-rock composition,as well as a variation in fluid activity during exhumation.P-T calculation and a peak geothermal gradient of 6–7°C/km indicate HP rocks in the Kekesu Valley experienced cold subducted eclogite facies metamorphism.Thus a huge oceanic subduction eclogite facies metamorphic belt in southwest Tianshan has been recognized,extending from the Kekesu Valley in the east to the Muzhaerte Valley in the west for nearly200 km.However,UHP evidence has not been found in the Kekesu terrane,perhaps because the slab in east part of southwest Tianshan did not subduct into such a great depth.  相似文献   

7.
Outcrops of the Cretaceous Upper sandstone formation some 375 km to the East of Addis Ababa on the motor Highway to Harar was paleomagnetically investigated. About seventy core samples were collected at various stratigraphic levels from 250–300 meters thick sedimentary formation. After standard sample preparations in the laboratory the resulting specimens were subjected to routine paleomagnetic demagnetization protocol. In the first steps of demagnetizations process the recent and viscous magnetizations were removed by heating until a temperature of level of 300 °C. Further demagnetization of the samples resulted in the isolation of the final magnetization with stable line segments that is directed towards the origin, which is interpreted as Characteristic Remanent Magnetization (ChRM). Rock – magnetic experiments have identified goethite (αFeOOH), hematite (αFe2O3), detritial hematite, and magnetite as the magnetic mineral phases carrying the remanence. The ChRM identified resulted in an average value of (Ds = 0.5°, Is = ?0.7°, α95 = 4.3°, N = 34) for the red sandstones while an average value of (Ds = 335.8°, Is = ?31.8°, α95 = 4.7°, N = 14) for the limestone intercalations. The former ChRM in the red sandstone is determined to be secondary while the latter ChRM is known to be primary. Comparison of these directional results and their pole equivalents with the African plate Apparent Polar Wander Path curve established by Besse and Courtillot (2003) give ages of between 115–130 Million years for the limestone intercalation and ages of 30 million years for red sandstone unit. These are interpreted respectively as estimates of the age of deposition and a later remagnetization respectively.  相似文献   

8.
Thermally acquired remanent magnetization is important for the estimation of the past magnetic field present at the time of cooling. Rocks that cool slowly commonly contain magnetic grains of millimeter scale. This study investigated 1-mm-sized magnetic minerals of iron, iron–nickel, magnetite, and hematite and concluded that the thermoremanent magnetization (TRM) acquired by these grains did not accurately record the ambient magnetic fields less than 1 μT. Instead, the TRM of these grains fluctuated around a constant value. Consequently, the magnetic grain ability to record the ambient field accurately is reduced. Above the critical field, TRM acquisition is governed by an empirical law and is proportional to saturation magnetization (Ms). The efficiency of TRM is inversely proportional to the mineral's saturation magnetization Ms and is related to the number of domains in the magnetic grains. The absolute field for which we have an onset of TRM sensitivity is inversely proportional to the size of the magnetic grain. These results have implications for previous reports of random directions in meteorites during alternating field demagnetization, or thermal demagnetization of TRM. Extraterrestrial magnetic fields in our solar system are weaker than the geomagnetic field by several orders of magnitude. Extraterrestrial rocks commonly contain large iron-based magnetic minerals as a common part of their composition, and therefore ignoring this behavior of multidomain grains can result in erroneous paleofield estimates.  相似文献   

9.
Abstract Eclogites occur in three districts of the northern and southern parts of Tien-Shan. Three eclogites collected from the Aktyuz, Makbal and Atbashy districts were analyzed; the P-T paths of three eclogites were estimated by analyzing compositional growth zoning and retrograde reaction of garnet and omphacite. Aktyuz and Makbal eclogites have not preserved the prograde path. An Aktyuz eclogite that underwent a quartz eclogite facies metamorphism (about T = 600°C, P = 12 kbar) has recorded three stages of retrograde metamorphism. Four stages of retrograde metamorphism were recognized in a Makbal eclogite; the garnet-omphacite geothermometer gave about T = 560°C at 20 kbar as the highest metamorphic condition. Garnet from a garnetchloritoid-talc schist of the Makbal district includes quartz pseudomorphs after coesite; some units evidently underwent a low-temperature part of coesite eclogite fades metamorphism. Prograde and retrograde paths were recognized in an Atbashy eclogite; five stages of metamorphic reaction were observed in the Atbashy sample. The prograde path from stage I to stage III has been recorded in garnet and omphacite in which quartz pseudomorphs after coesite are included. The peak metamorphism of stage III took place at about 660°C at 25 kbar. The stages IV and V are retrograde. UHP eclogite facies metamorphism took place twice in Kyrghyzstan. The Aktyuz and Atbashy eclogites gave Rb-Sr mineral-isochron ages of about 750 Ma and 270 Ma, respectively. The K-Ar age of paragonite from the Makbal eclogite is about 480 Ma.  相似文献   

10.
Three synthetic samples of six-line ferrihydrite (Fh5.4, Fh4.1, and Fh3.0), with average particle sizes of 5.4, 4.1, and 3.0 nm (respectively), have been studied by low-temperature magnetic techniques, Mössbauer spectroscopy, transmission electron microscopy, and X-ray absorption spectroscopy. Magnetic data indicate that these nanoparticles are not only antiferromagnetic, but that they also possess a ferromagnetic-like moment due to the presence of uncompensated spins. Both magnetic and Mössbauer data indicate that nanoparticles of six-line ferrihydrite are superparamagnetic at room temperature, with a low-temperature transition between blocked and unblocked magnetic states dependent on average particle size. In particular, low-field magnetic susceptibility data display a peak in amplitude at 45 K (Fh3.0), 55 K (Fh4.1), and 80 K (Fh5.4). Low-temperature induced magnetization data, acquired in magnetic fields up to 5 T, also display clearly a superparamagnetic behavior. These data were tentatively modeled as the sum of two contributions: a linear term due to the antiferromagnetic susceptibility and a nonlinear term due to the uncompensated spins. Model estimates of the magnetization carried by the uncompensated spins (Mnc) show a decrease in Mnc with increasing temperature. Extrapolation of Mnc values down to zero provided an estimate of the Néel temperature for six-line ferrihydrite on the order of 500 K.  相似文献   

11.
Low temperature eclogite facies metamorphism in Western Tianshan, Xinjiang   总被引：3，自引：0，他引：3  
According to the field occurrences and petrological study, the low temperature eclogite facies metamorphic rocks in Western Tianshan of Xinjiang can be divided into five types: (i) massive glaucophane-epidote eclogites and glaucophane-paragonite eclogites; (ii) schistose or gneissic mica eclogites; (iii) banded calcite eclogites; (iv) pillow glaucophane eclogites; (v) garnet-omphacite quartzites. Their eclogite facies metamorphism has undergone four stages of evolution: (i) pre-peak lawsonite-blueschist facies stage,T = 350–4000°C,P = 0.7–0.9 GPa; (ii) peak eclogite facies stage,T = 530 ± 20°C,P = 1.6–1.9 GPa; (iii) retrograde epidote-blueschist facies stage, T=500–530°C,P = 0.9–1.2 GPa and (iv) retrograde blueschist-greenschist facies stage,T= 450–550°C,P= 0.7–0.8 GPa. The metamorphic PT path of Western Tianshan eclogites is characterized by clockwise ITD resulting from the subduction of Tarim plate northward to Yili-Central Tianshan plate followed by fast uplift to the surface. But there were at least two stages of blueschist facies retrograde metamorphism overprinted during their uplift.  相似文献   

12.
Windsor–Essex County is a major cross-border truck and transportation route, with significant localized industrialization as well as rural and farming areas. Magnetic property measurements (in-field and laboratory susceptibility, frequency-dependent susceptibility, hysteresis properties, thermomagnetic and thermosusceptibility curves, anhysteretic and isothermal magnetizations) were made in order to determine the potential for using such variables to distinguish between natural and anthropogenic pollutants. In-field magnetic susceptibility measured on 324 soil sampling sites on a 0.5–2 km grid spacing through Windsor–Essex County ranged from 3.7 × 10− 6 to 305.2 × 10− 6 SI (average 36.2 ± 35.8 × 10− 6 SI), and showed that high magnetic susceptibility values were obtained on soil sampling sites in and around the cities/towns of Windsor, Harrow, Olinda and Oakland and near the beaches of Point Pelee National Park (PPNP) and Deerbrook, whereas lower susceptibility values were observed in near the towns of Lakeshore and Essex. On this grid spacing, Highway 401 (the major truck route) did not show anomalous susceptibility values; however, closer (1–3 m) sampling on other roads did show anomalously high values, suggesting that the coarser grid spacing may have missed anomalies. Laboratory measurements indicated that the dominant magnetic mineral in the Windsor–Essex County soils is magnetite; however, the grain size is variable. Pseudo-single domain (PSD)–multidomain (MD) magnetite is generally found on beaches and in PPNP, whereas single domain (SD)–PSD magnetite has been found near the City of Windsor and other towns. While certain correlations exist between some anthropogenic activities and the measured magnetic susceptibility and magnetic property values, no overall correlation can be made. A variety of geologic and anthropogenic factors must be considered when interpreting the origin of the magnetic signal in a particular area.  相似文献   

13.
Grain sizes in the range (10−4 to 10−1 mm) are common in some rocks. Because thermal and/or chemical remanent magnetization of hematite in this range approaches intensities of single domain (SD) magnetite, careful exploration of this transition, may serve to develop new applications in rock magnetism that relate to magnetic anomaly source identification, and various paleomagnetic and grain size-dependent investigations.Grain size-dependent magnetic behavior of hematite reveals a SD–multidomain (MD) transition at 0.1 mm. This transition is recognized by variation in magnetic coercivity and susceptibility and is related to an anomaly in remanence recovery when cycling through the Morin transition. The coercivity decrease with increasing grain size occurs much more gradually above 0.1 mm than below this value. Magnetic susceptibility of the grains smaller than 0.1 mm has negligible dependence on the amplitude of the applied alternating magnetic field. For the larger grains a new amplitude-dependent susceptibility component is observed. The grain size of 0.1 mm is also associated with loss of most of the remanence when cycling through the Morin transition. This behavior is ascribed to a transition from the metastable SD to the MD magnetic state. The increase in magnetized volume causes the demagnetizing energy to destabilize the SD state, resulting in a transition where the demagnetizing energy is reduced by nucleation of the domain wall for grains larger than 0.1 mm. The 0.1 mm transition has no significant effect on shape of the temperature-dependent coercivity and saturation magnetization.  相似文献   

14.
This study presents major-, trace-element, and rhenium–osmium (Re–Os) isotope and elemental data for basalts and gabbros from the Zermatt-Saas ophiolite, metamorphosed to eclogite-facies conditions during the Alpine orogeny. Igneous crystallisation of the gabbros occurred at 163.5 ± 1.8 Ma and both gabbro and basalt were subject to ‘peak’ pressure–temperature (P–T) conditions of > 2.0 GPa and ~ 600 °C at about 40.6 ± 2.6 Ma.Despite such extreme P–T conditions, Re–Os isotope and abundance data for gabbroic rocks suggest that there has been no significant loss of either of these elements during eclogite-facies metamorphism. Indeed, 187Re–187Os isotope data for both unaltered gabbros and gabbroic eclogites lie on the same best-fit line corresponding to an errorchron age of 160 ± 6 Ma, indistinguishable from the age of igneous crystallisation. In contrast, metamorphosed basalts do not yield age information; rather most possess 187Re/188Os ratios that cannot account for the measured 187Os/188Os ratios, given the time since igneous crystallisation. Taken with their low Re contents these data indicate that the basalts have experienced significant Re loss (∼ 50–60%), probably during high-pressure metamorphism. Barium, Rb and K are depleted in both gabbroic and basaltic eclogites. In contrast, there is no evident depletion of U in either lithology.Many ocean-island basalts (OIB) possess radiogenic Os and Pb isotope compositions that have been attributed to the presence of recycled oceanic crust in the mantle source. Published Re–Os data for high-P metabasaltic rocks alone (consistent with this study) have been taken to suggest that excessive amounts of oceanic crust are required to generate such signatures. However, this study shows that gabbro may exert a strong influence on the composition of recycled oceanic crust. Using both gabbro and basalt (i.e. a complete section of oceanic crust) calculations suggest that the presence of ≥ 40% of 2 Ga oceanic crust can generate the radiogenic Os compositions seen in some OIB. Furthermore, lower U/Pb ratios in gabbro (compared to basalt) serve to limit the 206Pb/204Pb ratios generated, while having a minimal effect on Os ratios. These results suggest that the incorporation of gabbro into recycling models provides a means of producing a range of OIB compositions having lower (and variable) 206Pb/204Pb ratios, but still preserving 187Os/188Os compositions comparable to HIMU-type OIB.  相似文献   

15.
The physical and chemical properties of soils are closely controlled by the climate factors and thus are significant for paleoclimate reconstruction.In this study,two adjacent soil profiles(LP and LPM) with different slopes from Yan'an,Shaanxi Province,were investigated using magnetic methods to determine the impact of topography on magnetic properties of soil.Our results show that although LP and LPM have similar magnetic minerals and grain size distribution,both the average and maximum magnetic susceptibility(x) of LP are almost doubled compared to those of LPM.In addition,the ratios of susceptibility enhancement to the background(Ex) for LP and LPM are 2.27 and 2.04,respectively;the ratios of saturation isothermal remnant magnetization(SIRM) enhancement(ESIRM) for these two profiles are 1.80 and 1.86,respectively.The slopes of the linear regression trends between frequency-dependent susceptibility(χFD) and "hard" isothermal remnant magnetization(HIRM)(χFD/HIRM),Anhysteretic remnant magnetization(ARM) and HIRM(ARM/HIRM),are almost free from the effect of parent material.χFD/HIRMs for LP and LPM are 28.7×10x5 and 28.9×10x5 A mx1,respectively;ARM/HIRMs are 0.35 and 0.33 for LP and LPM,respectively.These results demonstrate that parameters,χFD/HIRM,ARM/HIRM,Ex and ESIRM,are affected less by parent material and topography,which are better than the x for bulk samples to indicate the paleoclimatic conditions(e.g.,the paleorainfall) in a large-scale region.  相似文献   

16.
A new rapid method for identifying relative grain size variations in magnetic involves the parameter anhysteretic susceptibility (χARM, i.e. specific ARM obtained in a 1 Oe steady field), which is particularly sensitive to the single domain (SD) and small pseudo-single domain (PSD) grains of the finer magnetite fraction. A second parameter, low-field susceptibility (χ), is relatively more sensitive to the coarser magnetite fraction (larger PSD and smaller multidomain (MD) grains). We can then obtain a measure of the ratio of coarse- to fine-grain magnetite for large numbers of samples by plotting χARversusχ. A simple idealized model based on sized magnetite samples is proposed to explain the use of the χARMversusχ plot for detecting relative grain-size changes in the magnetic content of natural materials. The sediments of three lakes that contain magnetite or a similar magnetic carrier and have a wide range of values of χARM and χ are used to test the model.The model is used to interpret the magnetic variations observed, and the interpretations are supported by high-field hysteresis measurements of the same sediments. The combination of the high-field hysteresis method of Day et al. [1] and the χARM vs. χ method is a powerful technique allowing the rapid identification of both the relative grain size and domain state for large numbers of samples containing magnetite. The χARMvs.χ method should be used as an intial means of identifying distinct groups of samples.The high-field hysteresis method should then be applied to a few representative samples from each group to confirm the initial interpretation.  相似文献   

17.
The elastic moduli of polycrystalline ringwoodite, (Mg0.91Fe0.09)2SiO4, were measured up to 470 K by means of the resonant sphere technique. The adiabatic bulk (KS) and shear (μ) moduli were found to be 185.1(2) and 118.22(6) GPa at room temperature, and the average slopes of dKS/dT and dμ/dT in the temperature range of the study were determined to be −0.0193(9) and −0.0148(3) GPa/K, respectively. Using these results, we estimate seismic wave velocity jumps for a pure olivine mantle model at 520 km depth. We find that the jump for the S-wave velocity is about 1.5 times larger than that for the P-wave velocity at this depth. This suggests that velocity jumps at the 520 km discontinuity are easier to detect using S-waves than P-waves.  相似文献   

18.
《Geofísica Internacional》2014,53(4):411-423
An investigation of the effect of some human activities on the magnetic susceptibility and frequency dependent susceptibility was conducted on top soil samples from, a commercial area, a motor park and a school environment in Jalingo, Taraba State, N-E Nigeria. The purpose was to assess the variation of magnetic susceptibility with different land use, detect pollution hotspots using magnetic proxy parameters and evaluate the contribution of superparamagnetic (SP) grain size contribution to the magnetic susceptibility from calculation of the frequency dependence of magnetic susceptibility (MS). The results of the mass specific low frequency magnetic susceptibility measurements showed significant enhancement with values ranging from 67.8 − 495.3 × 10−8 m3kg−1 with a mean value of 191.61 × 10−8 × m3kg−1 for the Jalingo College of Education (JCOE) data; 520.1 − 1612.8 × 10−8 m3kg−1 with a mean value of 901.34 × 10−8 m3kg−1 for the Jalingo main Market (JMM) and 188.5 − 1203.6 × 10−8m3kg−1 with an average value of 574 92 × 10−6 m3kg−1 for the Jalingo Motor Park (JMP). The significant magnetic enhancement indicates high concentration of ferrimagnetic minerals in the soil and hence increased pollution. The magnetic susceptibility of the different land use studied decreased in the order commercial area (market) > motor park > school premises. The results of the percentage frequency dependence susceptibility showed that most of the samples had a mixture of SP and coarse multi domain grains or SP grains < 0.05 µm. The value of χfd% range from 2.68 to 13.80% with an average value of 8.67% in the JCOE samples, 0.49 to 10.04% with an a-verage of 5.05% in the JMM samples and 0.56 to 13.04% with an average value of 5.86% in the JMP samples.  相似文献   

19.
In this study we performed three categories of steady- and unsteady-state core-flooding experiments to investigate capillary trapping, relative permeability, and capillary pressure, in a scCO2 + SO2/brine/limestone system at elevated temperature and pressure conditions, i.e., 60 °C and 19.16 MPa. We used a Madison limestone core sample acquired from the Rock Springs Uplift in southwest Wyoming. We carried out two sets of steady-state drainage-imbibition relative permeability experiments with different initial brine saturations to study hysteresis. We found that the final scCO2 + SO2 drainage relative permeability was very low, i.e., 0.04. We also observed a rapid reduction in the scCO2-rich phase imbibition relative permeability curve, which resulted in a high residual trapping. The results showed that between 62.8% and more than 76% of the initial scCO2 + SO2 at the end of drainage was trapped by capillary trapping mechanism (trapping efficiency). We found that at higher initial brine saturations, the trapping efficiency was higher. The maximum initial and residual scCO2-rich phase saturations at the end of primary drainage and imbibition were 0.525 and 0.329, respectively. Each drainage-imbibition cycle was followed by a dissolution process to re-establish Sw = 1. The dissolution brine relative permeabilities for both cycles were also obtained. We characterized the scCO2 + SO2/brine capillary pressure hysteresis behavior through unsteady-state primary drainage, imbibition, and secondary drainage experiments. We observed negative imbibition capillary pressure curve indicative of possible wettability alteration throughout the experiments due to contact with scCO2 + SO2/brine fluid system. The trapping results were compared to those reported in literature for other carbonate core samples. We noticed slightly more residual trapping in our sample, which might be attributed to heterogeneity, different viscosity ratio, and pore-space topologies. The impact of dynamic effects, i.e., high brine flow rate imbibition tests, on trapping of the scCO2-rich phase was also explored. We performed two imbibition experiments with relatively high brine flow rates. The residual scCO2 saturation dropped to 0.291 and 0.262 at the end of the first and second imbibition tests, i.e., 11.5% and 20.4%, respectively, compared to 0.329 under capillary-dominated regime.  相似文献   

20.
Hot springs in the Marsyandi Valley, Nepal, vent CO2 sourced from metamorphic fluids that mix with shallow groundwaters before degassing near the Earth's surface. The δ13C of spring waters ranges up to + 13‰, while that of the coexisting free gas phase is close to ? 4‰. Empirical and thermodynamic modelling of this isotopic fractionation suggests > 97 ± 1% CO2 degassing. The calculated minimum total CO2 degassing in the Marsyandi catchment is 5.4 × 109 mol/yr from a Cl-based estimate of the spring water discharge to the Marsyandi River and the fraction of CO2 degassed. Extrapolated to the whole of the Himalayas, this implies a probable minimum metamorphic CO2 flux of 0.9 × 1012 mol/yr, or ～ 13% of solid Earth CO2 degassing. The calculated flux is a factor of three greater than the estimated CO2 drawdown by silicate weathering in the Himalayas. Himalayan metamorphic degassing contributes a significant fraction of the global solid Earth CO2 flux and implies that metamorphism may cause changes in long-term climate that oppose those resulting from the orogenic forcing of chemical weatherability.  相似文献   

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