Nitrogen and carbon cycling in the North Sea and exchange with the North Atlantic—A model study,Part II: Carbon budget and fluxes     

Wilfried Kühn  Johannes Pätsch  Helmuth Thomas  Alberto V. Borges  Laure-Sophie Schiettecatte  Yann Bozec  A.E. Friederike Prowe 《Continental Shelf Research》2010

The 3-d coupled physical–biogeochemical model ECOHAM (version 3) was applied to the Northwest-European Shelf (47°41′–63°53′N, 15°5′W–13°55′E) for the years 1993–1996. Carbon fluxes were calculated for the years 1995 and 1996 for the inner shelf region, the North Sea (511,725 km²). This period was chosen because it corresponds to a shift from a very high winter-time North Atlantic Oscillation Index (NAOI) in 1994/1995, to an extremely low one in 1995/1996, with consequences for the North Sea physics and biogeochemistry. During the first half of 1996, the observed mean SST was about 1 °C lower than in 1995; in the southern part of the North Sea the difference was even larger (up to 3 °C). Due to a different wind regime, the normally prevailing anti-clockwise circulation, as found in winter 1995, was replaced by more complicated circulation patterns in winter 1996. Decreased precipitation over the drainage area of the continental rivers led to a reduction in the total (inorganic and organic) riverine carbon load to the North Sea from 476 Gmol C yr⁻¹ in 1995 to 340 Gmol C yr⁻¹ in 1996. In addition, the North Sea took up 503 Gmol C yr⁻¹ of CO₂ from the atmosphere. According to our calculations, the North Sea was a sink for atmospheric CO₂, at a rate of 0.98 mol C m⁻² yr⁻¹, for both years. The North Sea is divided into two sub-systems: the shallow southern North Sea (SNS; 190,765 km²) and the deeper northern North Sea (NNS; 320,960 km²). According to our findings the SNS is a net-autotrophic system (net ecosystem production NEP>0) but released CO₂ to the atmosphere: 159 Gmol C yr⁻¹ in 1995 and 59 Gmol C yr⁻¹ in 1996. There, the temperature-driven release of CO₂ outcompetes the biological CO₂ drawdown. In the NNS, where respiratory processes prevail (NEP<0), 662 and 562 Gmol C yr⁻¹ were taken up from the atmosphere in 1995 and 1996, respectively. Stratification separates the productive, upper layer from the deeper layers of the water column where respiration/remineralization takes place. Duration and stability of the stratification are determined by the meteorological conditions, in relation to the NAO. Our results suggest that this mechanism controlling the nutrient supply to the upper layer in the northern and central North Sea has a larger impact on the carbon fluxes than changes in lateral transport due to NAOI variations. The North Sea as a whole imports organic carbon and exports inorganic carbon across the outer boundaries, and was found to be net-heterotrophic, more markedly in 1996 than in 1995.  相似文献   

Temporal and spatial variations of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) in the East China Sea and the Yellow Sea   总被引：5，自引：0，他引：5  

Gui-Peng Yang  Hong-Hai ZhangLi-Min Zhou  Jian Yang 《Continental Shelf Research》2011,31(13):1325-1335

Temporal and spatial distributions of dimethylsulfide (DMS) and its precursor dimethylsulfoniopropionate (DMSP) were determined in the East China Sea and the Yellow Sea during June-July, 2006 and January-February, 2007. The concentrations of DMS and total DMSP in surface water in the study area were 5.64 (1.79-12.24) and 28.25 (13.98-44.93) nmol L⁻¹ in summer, and were 1.79 (1.02-3.51) and 11.01 (6.90-17.98) nmol L⁻¹ in winter, respectively. The distributions of DMS and DMSP in the study area were obviously influenced by the Yangtze River effluent and the Kuroshio water. Even under highly variable hydrographic conditions, a significant relationship was observed between DMS and chlorophyll a concentrations in summer as well as in winter, suggesting that phytoplankton biomass might play an important role in controlling DMS distribution in the study area. The summer ratios of DMS/chlorophyll a and DMSP/chlorophyll a were approximately twofold higher than winter values, corresponding with the temporal variation in phytoplankton community structure between summer and winter. The sea-to-air fluxes of DMS were estimated to be 5.32 and 11.92 μmol m⁻² d⁻¹ using the equations of Liss and Merlivat (1986) and Wanninkhof (1992), respectively.  相似文献   

Air-sea CO₂ fluxes in the southern Yellow Sea: An examination of the continental shelf pump hypothesis   总被引：1，自引：0，他引：1  

Liang Xue  Longjun Zhang  Wei-Jun CaiLi-Qing Jiang 《Continental Shelf Research》2011,31(18):1904-1914

The southern Yellow Sea (SYS), located to the north of the East China Sea (ECS), was considered part of the ECS when Tsunogai et al. (1999) proposed the “continental shelf pump” (CSP) hypothesis. However, the original CSP carbon dioxide (CO₂) uptake flux (2.9 mol C m⁻² yr⁻¹) appears to have been overestimated, primarily due to the differences between the SYS and the ECS in terms of their CO₂ system. In this paper, we estimated air-sea CO₂ fluxes in the SYS using the surface water partial pressure of CO₂ (pCO₂) measured in winter, spring, and summer, as well as that estimated in fall via the relationship of pCO₂ with salinity, temperature, and chlorophyll a. The results indicate that overall, the entire investigated area was a net source of atmospheric CO₂ during summer, winter, and fall, whereas it was a net sink during spring. Spatially, the nearshore area was almost a permanent CO₂ source, while the central SYS shifted from being a CO₂ sink in spring to a source in the other seasons of the year. Overall, the SYS is a net source of atmospheric CO₂ on an annual scale, releasing ∼7.38 Tg C (1 Tg=10¹² g) to the atmosphere annually. Thus, the updated CO₂ uptake flux in the combined SYS and ECS is reduced to ∼0.86 mol C m⁻² yr⁻¹. If this value is extrapolated globally following Tsunogai et al. (1999), the global continental shelf would be a sink of ∼0.29 Pg C yr⁻¹, instead of 1 Pg C yr⁻¹ (1 Pg=10¹⁵ g).The SYS as a net annual source of atmospheric CO₂ is in sharp contrast to most mid- and high-latitude continental shelves, which are CO₂ sinks. We argue that unlike the ECS and the North Sea where carbon on the shelf could be exported to the open ocean, the SYS lacks the physical conditions required by the CSP to transport carbon off the shelf effectively. The global validity of the CSP theory is thus questionable.  相似文献   

Seasonal contribution of living phytoplankton carbon to vertical fluxes in a coastal upwelling system (Ría de Vigo, NW Spain)     

D. Zúñiga  F. Alonso-PérezC.G. Castro  B. ArbonesF.G. Figueiras 《Continental Shelf Research》2011,31(5):414-424

The aim of this study is to explore the contribution of living phytoplankton carbon to vertical fluxes in a coastal upwelling system as a key piece to understand the coupling between primary production in the photic layer and the transfer mechanisms of the organic material from the photic zone. Between April 2004 and January 2005, five campaigns were carried out in the Ría de Vigo (NW Iberian Peninsula) covering the most representative oceanographic conditions for this region. Measurements of particulate organic carbon (POC), chlorophyll-a (chl a), phaeopigments (phaeo), and identification of phytoplankton species were performed on the water column samples and on the organic material collected in sediment traps.The POC fluxes measured by the sediment traps presented no seasonal variation along the studied period ranging around a mean annual value of 1085±365 mg m⁻² d⁻¹, in the upper range of the previously reported values for other coastal systems. The fact that higher POC fluxes were registered during autumn and winter, when primary production rates were at their minimum levels points to a dominant contribution of organic carbon from resuspended sediments on the trap collected material. On the contrary, fluxes of living phytoplankton carbon (C_phyto) and chl a clearly presented a seasonal trend with maximum values during summer upwelling (546 mg m⁻² d⁻¹ and 22 mg chl a m⁻² d⁻¹, respectively) and minimum values during winter (22 mg m⁻² d⁻¹ and 0.1 mg chl a m⁻² d⁻¹, respectively). The contribution of C_phyto to the vertical flux of POC ranged between 2% and 49% in response to the pelagic phytoplankton community structure. Higher values of C_phyto fluxes were registered under upwelling conditions which favour the dominance of large chain-forming diatoms (Asterionellopsis glacialis and Detonula pumila) that were rapidly transferred to the sediments. By contrast, C_phyto fluxes decreased during the summer stratification associated with a pelagic phytoplankton community dominated by single-cell diatoms and flagellates. Minimal C_phyto fluxes were observed during the winter mixing conditions, when the presence of the benthic specie Paralia sulcata in the water column also points toward strong sediment resuspension.  相似文献   

Short and medium term dynamics of the carbon exchange between the Baltic Sea and the North Sea     

K. Kuliński  J. SheJ. Pempkowiak 《Continental Shelf Research》2011,31(15):1611-1619

A detailed analysis of the short and medium term dynamics of the carbon exchange between the Baltic Sea and the North Sea is presented. To quantify the carbon fluxes distinguishing the Baltic and North Sea water masses, the salinity-based End Members (EM) method was successfully applied. The results of 0.63±0.25×10¹² mol C year⁻¹ identify the Baltic Sea as a net source of carbon for the North Sea. Dissolved organic carbon (DOC) was found to contribute significantly (22%) to the bulk of exported carbon. The levels determined suggest the hydrology-dependence of the carbon fluxes in the Danish Straits, which stimulates the high variability of carbon fluxes at both interseasonal and interannual scales.  相似文献   

Dry deposition and particle-size distribution of phosphorus in the marine atmosphere over the northeastern coast of Taiwan     

Hung-Yu Chen  Chin-Chang Hung  Tien-Hsi Fang  Gwo-Ching Gong 《Continental Shelf Research》2008

This study is the first to measure the particulate phosphorus, including total inorganic phosphorus (TIP) and organic phosphorus (OP), in size-fractionated atmospheric particles. The results indicate that continental and marine sources are the key controls on the particle-size distribution of phosphorus species. For continental and local anthropogenic sources, both TIP and OP are associated with fine-mode aerosols during the winter and spring, and both are also associated with coarse particles during the summer and autumn. The coarse/fine ratios are low during periods with a non-oceanic source but high at other times, probably because of the biological growing season in the surface waters of the study area. The calculated annual fluxes based on estimates of dual-mode particles are 532±185, 435±172, and 96.8±48.8 μmol m⁻² yr⁻¹ for TP, TIP, and OP, respectively. Based on previously published solubility data for particulate phosphorus (34%), we calculated an annual flux of 180±63 μmol m⁻² yr⁻¹ for readily soluble particulate phosphorus.  相似文献   

Inter-annual and seasonal variations in the air–sea CO₂ balance in the central Baltic Sea and the Kattegat     

Karin Wesslander  Anders Omstedt  Bernd Schneider 《Continental Shelf Research》2010

We estimated the net annual air–sea exchange of carbon dioxide (CO₂) using monitoring data from the East Gotland Sea, Bornholm Sea, and Kattegat for the 1993–2009 period. Wind speed and the sea surface partial pressure of CO₂ (pCO₂^w), calculated from pH, total alkalinity, temperature, and salinity, were used for the flux calculations. We demonstrate that regions in the central Baltic Sea and the Kattegat alternate between being sinks (−) and sources (+) of CO₂ within the −4.2 to +5.2 mol m⁻² yr⁻¹ range. On average, for the 1994–2008 period, the East Gotland Sea was a source of CO₂ (1.64 mol m⁻² yr⁻¹), the Bornholm Sea was a source (2.34 mol m⁻² yr⁻¹), and the Kattegat was a sink (−1.16 mol m⁻² yr⁻¹). Large inter-annual and regional variations in the air–sea balance were observed. We used two parameterizations for the gas transfer velocity (k) and the choice varied the air–sea exchange by a factor of two. Inter-annual variations in pCO₂^w between summers were controlled by the maximum concentration of phosphate in winter. Inter-annual variations in the CO₂ flux and gas transfer velocity were larger between winters than between summers. This indicates that the inter-annual variability in the total flux was controlled by winter conditions. The large differences between the central Baltic Sea and Kattegat were considered to depend partly on the differences in the mixed layer depth.  相似文献   

Export fluxes of biogenic matter in the presence and absence of seasonal sea ice cover in the Chukchi Sea     

Catherine Lalande  Jacqueline M. Grebmeier  Paul Wassmann  Lee W. Cooper  Mikhail V. Flint  Valentina M. Sergeeva 《Continental Shelf Research》2007

Drifting sediment traps were deployed at 9 stations in May-June (ice-covered conditions) and July-August (ice-free conditions) 2004 in the Chukchi Sea to investigate the variability in export fluxes of biogenic matter in the presence and absence of sea ice cover. Measurements of chlorophyll-a (Chl-a), particulate organic carbon (POC), particulate nitrogen (PN), phytoplankton, zooplankton fecal pellets, and the stable carbon isotope composition (δ¹³C) of the sinking material were performed along Barrow Canyon (BC) and a parallel shelf-to-basin transect from East Hanna Shoal (EHS) to the Canada Basin. POC export fluxes were similarly high in the presence (378±106 mg C m⁻² d⁻¹) and in the absence of ice cover (442±203 mg C m⁻² d⁻¹) at the BC stations, while fluxes were significantly higher in the absence (129±98 mg C m⁻² d⁻¹) than in the presence of ice cover (44±29 mg C m⁻² d⁻¹) at the EHS stations. The C/N ratios and δ¹³C values of sinking organic particles indicated that POC export fluxes on the Chukchi continental shelf were mostly composed of freshly produced labile material, except at the EHS stations under ice cover where the exported matter was mostly composed of refractory material probably advected into the EHS region. Chl-a fluxes were higher under ice cover than in ice-free water, however, relatively low daily loss rates of Chl-a and similar phytoplankton carbon fluxes in ice-covered and ice-free water suggest the retention of phytoplankton in the upper water column. An increase in fecal pellet carbon fluxes in ice-free water reflected higher grazing pressure in the absence of ice cover. Elevated daily loss rates of POC at the BC stations confirmed other indications that Barrow Canyon is an important area of carbon export to the basin and/or benthos. These results support the conclusion that there are large spatial and temporal variations in export fluxes of biogenic matter on the Chukchi continental shelf, although export fluxes may be similar in the presence and in the absence of ice cover in highly productive regions.  相似文献   

Rapid physically driven inversion of the air–sea ice CO₂ flux in the seasonal landfast ice off Barrow,Alaska after onset of surface melt     

Daiki Nomura  Hajo Eicken  Rolf Gradinger  Kunio Shirasawa 《Continental Shelf Research》2010

The air–sea ice CO₂ flux was measured over landfast sea ice in the Chukchi Sea, off Barrow, Alaska in late May 2008 with a chamber technique. The ice cover transitioned from a cold early spring to a warm late spring state, with an increase in air temperature and incipient surface melt. During melt, brine salinity and brine dissolved inorganic carbon concentration (DIC) decreased from 67.3 to 18.7 and 3977.6 to 1163.5 μmol kg⁻¹, respectively. In contrast, the salinity and DIC of under-ice water at depths of 3 and 5 m below the ice surface remained almost constant with average values of 32.4±0.3 (standard deviation) and 2163.1±16.8 μmol kg⁻¹, respectively. The air–sea ice CO₂ flux decreased from +0.7 to −1.0 mmol m⁻² day⁻¹ (where a positive value indicates CO₂ being released to the atmosphere from the ice surface). During this early to late spring transition, brought on by surface melt, sea ice shifted from a source to a sink for atmospheric CO₂, with a rapid decrease of brine DIC likely associated with a decrease in the partial pressure of CO₂ of brine from a supersaturated to an undersaturated state compared to the atmosphere. Formation of superimposed ice coincident with melt was not sufficient to shut down ice–air gas exchange.  相似文献   

Matrix bound phosphine in sediments of the yellow sea and its coastal areas     

Jian-Bing Li  Gui-Ling Zhang  Jing Zhang  Su-Mei Liu  Jing-Ling Ren 《Continental Shelf Research》2010

Matrix bound phosphine (MBP), a kind of chemically reduced phosphorus, has received limited attention in prevailing modeling of the phosphorus biogeochemical cycle. MBP has been found to occur in marine sediments. MBP in the sediments of the Yellow Sea and its coastal areas was measured by gas chromatography from 2004 to 2007. MBP levels in surface sediments were 0.19–38.24 ng kg⁻¹ in the shelf of the Yellow Sea, 0.34–17.15 ng kg⁻¹ in the Jiaozhou Bay, 2.11–71.79 ng kg⁻¹ in the Sanggou Bay and 0.28–319.32 ng kg⁻¹ in the rivers around the Jiaozhou Bay. High levels of MBP occurred in the northern and middle areas of the Yellow Sea. Obvious seasonal variation of MBP was observed in surface sediments of the Sanggou Bay, with the highest MBP level occurring in summer and the lowest in winter. MBP in surface sediments of the inner Jiaozhou Bay was higher than those in the outer region. MBP levels increased with depth in the top 5–10 cm sediments of the Jiaozhou Bay and on the intertidal flats. Environmental factors such as type of sediments, temperature, organic matter and human activity were found to affect the concentrations and distribution of MBP in marine sediments.  相似文献   

Seasonal variations and trophic ecology of microzooplankton in the southeastern Arabian Sea     

C.R. Asha Devi  R. JyothibabuP. Sabu  Josia JacobH. Habeebrehman  M.P. PrabhakaranK.J. Jayalakshmi  C.T. Achuthankutty 《Continental Shelf Research》2010

The seasonal ecological response of microzooplankton in the southeastern Arabian Sea is presented. During the spring intermonsoon period, stratification and depletion of nitrate in the surface waters (nitracline was at 60 m depth) cause low integrated chlorophyll a (av. 19±11.3 mg m⁻²) and primary production (av. 164±91 mgC m⁻² d⁻¹). On the other hand, nutrient enrichment associated with coastal upwelling and river influx during the onset and peak summer monsoon resulted in high integrated chlorophyll a (av. 21±6 mg m⁻² and av. 29±21 mg m⁻², respectively) and primary production (av. 255±94 mgC m⁻² d⁻¹ and av. 335±278 mgC m⁻² d⁻¹, respectively). During all three periods, diazotropic cyanobacterium Trichodesmium erythraeum dominated in the nutrient depleted surface waters. A general increase in abundance of larger diatoms was evident in the surface waters of the inshore region during monsoon periods. The microzooplankton abundance was found to be significantly higher during the spring intermonsoon (av.241±113×10³ ind m⁻²) as compared to onset of summer monsoon (av. 105±89×10³ ind m⁻²) and peak summer monsoon (av.185±175×10³ ind m⁻²). Microzooplankton community during the spring intermonsoon was numerically dominated by ciliates while heterotrophic dinoflagellate was the dominant ones during the monsoon periods. The high abundance of ciliates during the spring intermonsoon could be attributed to the stratified environmental condition prevailed in the study area which favors high abundance of smaller phytoplankton and cyanobacteria, the most preferred food of ciliates. On the other hand, the dominance of heterotrophic dinoflagellates during the monsoon periods could be linked to their ability to graze larger diatoms which were abundant during the monsoon periods. The overall results show low abundance of microzooplankton in the eastern Arabian Sea during the monsoon periods mainly due to a decline in ciliates abundance. This decline during the monsoon periods could be the result of (a) low abundance of smaller phytoplankton and (b) high stock of mesozooplankton predators (av. 245 ml 100 m⁻³).  相似文献   

Abundance distribution and seasonal variations of Calanus sinicus (Copepoda: Calanoida) in the northwest continental shelf of South China Sea   总被引：2，自引：0，他引：2  

Jianqiang Yin  Liangmin HuangKaizhi Li  Shumin LianChaolun Li  Qiang Lin 《Continental Shelf Research》2011,31(14):1447-1456

The effect of monsoon, coastal current and temperature on the distribution and seasonal variations of Calanus sinicus abundance were studied. The samples from the northwest continental shelf of South China Sea were collected with 505 μm planktonic nets from July 2006 to October 2007. The abundance of C. sinicus made up 34.28% and 12.34% of all copepods in spring and summer, respectively. The distribution of C. sinicus varied seasonally and regionally. The distribution of C. sinicus ranged between east inshore and offshore waters from the Leizhou Peninsula to Hainan Island, with a mean of 23.00 (±77.78) ind. m⁻³ in spring. In summer it had a mean of 13.74 (±45.10) ind. m⁻³ occurring only in the east inshore waters from Leizhou Peninsula to Hainan Island. C. sinicus was not abundant during autumn and winter seasons. The surveyed area was divided into three sub-regions based on topographical analysis and water mass, region I (included the east inshore waters of Leizhou Peninsula), region II (included the east inshore waters of Hainan Island) and region III (included the offshore waters from Leizhou Peninsula to Hainan Island). The average abundance of C. sinicus within region I was determined to be 115.63 (±145.93) and 68.12 (±84.00) ind. m⁻³ in spring and summer, respectively, values higher than those of regions II and III. Our findings suggested that C. sinicus was transported from the East China Sea to the northwest continental shelf of South China Sea by the Guangdong Coastal Current, which was driven by the northeast monsoon in spring. The presence of a cold eddy, in addition to coastal upwelling driven by the southwest monsoon, provided suitable survival conditions for C. sinicus in summer. This species disappeared in autumn due to high temperatures (>27 °C) and did not begin to enter into the northwest continental shelf of South China Sea from the East China Sea during the period of investigation in winter. The frequency of C. sinicus was low in region III during the year as a result of the South China Sea Warm Current and pelagic waters with high temperature during the spring and summer months.  相似文献   

Benthic fluxes of dissolved inorganic carbon in the Tinto–Odiel system (SW of Spain)     

T. Ortega  R. PonceJ. Forja  A. Gómez-Parra 《Continental Shelf Research》2008

The benthic fluxes (diffusive and with chambers) of dissolved inorganic carbon (DIC), dissolved oxygen (DO) and total alkalinity (TA) have been calculated in summertime in the estuary system formed by the mouths of the Tinto and Odiel rivers (SW of Spain). An increase of DIC in interstitial water with depth was found for all stations showing values of up to 28 mM at a depth of 5 cm. The diffusive fluxes of DIC and TA obtained ranging between 1.8–7.8 and 1.5–7.3 mmol m⁻² d⁻¹, respectively. These intervals are in agreement with those found for other coastal systems. Considering the plots of DIC vs. alkalinity (ΔDIC/ΔTA) in the first 30 cm of interstitial water, it was deduced that sulphate reduction and the oxidation of sulphides seem to have special relevance in the sediments of the stations studied. The benthic fluxes of inorganic carbon and DO measured by benthic chambers were variable, presenting elevated values (309–433 mmol DIC m⁻² d⁻¹ and 50–120 mmol DO m⁻² d⁻¹). The most elevated fluxes of DIC were seen at the stations with high anthropogenic influence (close to populated areas and industrial discharges). A great proportion of these fluxes are due to CaCO₃ dissolution processes, which constitute an estimated 49% of total DIC flux. DIC and DO benthic flux quotients were far in excess of unity, indicating the significance processes of anaerobic degradation of organic material at the stations studied.  相似文献   

Nutrient distributions over the Southwestern South Atlantic continental shelf from Mar del Plata (Argentina) to Itajaí (Brazil): Winter–summer aspects     

Elisabete S. Braga  Vitor C. Chiozzini  Gláucia B.B. Berbel  João C.C. Maluf  Valquíria M.C. Aguiar  Marcela Charo  Daniel Molina  Sílvia I. Romero  Beatriz B. Eichler 《Continental Shelf Research》2008

Nutrient distributions observed at some depths along the continental shelf from 27°05′S (Brazil) to 39°31′S (Argentina) in winter, 2003 and summer, 2004 related to salinity and dissolved oxygen (mL L⁻¹) and saturation (%) data showed remarkable influences of fresh water discharge over the coastal region and in front of the La Plata estuary. In the southern portion of the study area different processes were verified. Upwelling processes caused by ocean dynamics typical of shelf break areas, eddies related to surface dynamics and regeneration processes confirmed by the increase of nutrients and the decrease of dissolved and saturation oxygen data were verified. High silicate concentrations in the surface waters were identified related to low salinities (minimum of 21.22 in winter and 21.96 in summer), confirming the importance of freshwater inputs in this region, especially in winter. Silicate concentration range showed values between 0.00 and 83.52 μM during winter and from 0.00 to 41.16 μM during summer. Phosphate concentrations worked as a secondary trace of terrestrial input and their values varied from 0.00 to 3.30 μM in winter and from 0.03 to 2.26 μM in summer; however, in shallow waters, phosphate indicated more clearly the fresh water influence. The most important information given by nitrate concentrations was the presence of water from SACW upwelling that represents a new source of nutrients for marine primary production. Nitrate maximum values reached 41.96 μM in winter and 33.10 μM in summer. At a depth ∼800 m, high nitrate, phosphate and silicate concentrations were related to Malvinas Current Waters, Subantarctic Shallow Waters and Antarctic Atlantic Intermediate Waters (AAIW). Dissolved oxygen varied from 3.41 to 7.06 mL L⁻¹ in winter and from 2.65 to 6.85 mL L⁻¹ in summer. The percentage of dissolved oxygen saturation in the waters showed values between 48% and 113% in winter and from 46% to135% in summer. The most important primary production was verified in the summer, and situations of undersaturation were mainly observed below 50 m depth and at some points near the coast. The anti-correlation between nutrients and dissolved oxygen which showed evident undersaturation also revealed important potential sites of remineralization processes. The nutrient behaviours showed some aspects of the processes that occur over the Southwestern South Atlantic continental shelf and in their land–sea interfaces between Mar del Plata and Itajaí.  相似文献   

Comparative sensitivity of harbour and grey seals to several environmental contaminants using in vitro exposure     

M.M. Dufresne  S. Pillet  S. De Guise 《Marine pollution bulletin》2010,60(3):344-145

In this study, we investigated the effects of cadmium chloride (CdCl₂), mercury chloride (HgCl₂), methylmercury chloride (CH₃HgCl), and PCBs on lymphocyte proliferation in phocids. PBMCs isolated from harbour and grey seals were exposed in vitro to varying concentrations of contaminants. A reduction of viability occurred when cells were exposed to 10⁻⁴ M HgCl₂ or CH₃HgCl or to 50 ppm of Aroclor 1254. In both grey and harbour seals, T-lymphocyte proliferation was suppressed when their cells were incubated with 5 × 10⁻⁵ M CdCl₂ or 10⁻⁴ M HgCl₂. An inhibition of proliferation occurred with CH₃HgCl from 10⁻⁶ M in grey seals and from 10⁻⁵ M in harbour seals. In grey seals, Aroclor 1254 reduced lymphocyte proliferation at 15 ppm. In both harbour and grey seals, CH₃HgCl was ten times more immunotoxic that HgCl₂. From IC₅₀, chemicals were ranked in terms of toxicity as followed: CH₃HgCl > CdCl₂ > HgCl₂ > Aroclor 1254.  相似文献   

Bio-optical characteristics of Cariaco Basin (Caribbean Sea) waters     

Laura Lorenzoni  Chuanmin HuRamón Varela  Glenda AriasLaurencia Guzmán  Frank Muller-Karger 《Continental Shelf Research》2011,31(6):582-593

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Volatile emissions and gas geochemistry of Hot Spring Basin,Yellowstone National Park,USA     

C. Werner  S. Hurwitz  W.C. Evans  J.B. Lowenstern  D. Bergfeld  H. Heasler  C. Jaworowski  A. Hunt 《Journal of Volcanology and Geothermal Research》2008

We characterize and quantify volatile emissions at Hot Spring Basin (HSB), a large acid-sulfate region that lies just outside the northeastern edge of the 640 ka Yellowstone Caldera. Relative to other thermal areas in Yellowstone, HSB gases are rich in He and H₂, and mildly enriched in CH₄ and H₂S. Gas compositions are consistent with boiling directly off a deep geothermal liquid at depth as it migrates toward the surface. This fluid, and the gases evolved from it, carries geochemical signatures of magmatic volatiles and water–rock reactions with multiple crustal sources, including limestones or quartz-rich sediments with low K/U (or ^40?Ar/^4?He). Variations in gas chemistry across the region reflect reservoir heterogeneity and variable degrees of boiling. Gas-geothermometer temperatures approach 300 °C and suggest that the reservoir feeding HSB is one of the hottest at Yellowstone. Diffuse CO₂ flux in the western basin of HSB, as measured by accumulation-chamber methods, is similar in magnitude to other acid-sulfate areas of Yellowstone and is well correlated to shallow soil temperatures. The extrapolation of diffuse CO₂ fluxes across all the thermal/altered area suggests that 410 ± 140 t d^− 1 CO₂ are emitted at HSB (vent emissions not included). Diffuse fluxes of H₂S were measured in Yellowstone for the first time and likely exceed 2.4 t d^− 1 at HSB. Comparing estimates of the total estimated diffuse H₂S emission to the amount of sulfur as SO₄²⁻ in streams indicates ~ 50% of the original H₂S in the gas emission is lost into shallow groundwater, precipitated as native sulfur, or vented through fumaroles. We estimate the heat output of HSB as ~ 140–370 MW using CO₂ as a tracer for steam condensate, but not including the contribution from fumaroles and hydrothermal vents. Overall, the diffuse heat and volatile fluxes of HSB are as great as some active volcanoes, but they are a small fraction (1–3% for CO₂, 2–8% for heat) of that estimated for the entire Yellowstone system.  相似文献   

Pelagic production and respiration in the Gulf of Papua during May 2004     

A.D. McKinnon  J.H. CarletonS. Duggan 《Continental Shelf Research》2007

The metabolic balance between production and respiration in plankton communities of the Gulf of Papua was investigated in May 2004. Water samples taken at 19 stations were allocated to groups on the basis of physico-chemical characteristics. Oxygen consumption and production in flasks incubated in the dark and in the light was determined by micro-Winkler titration. Dark bottle respiration in samples influenced by the estuarine plume averaged 3.09±1.92 (SD) mmol O₂ m⁻³ d⁻¹ and production within surface light bottles averaged 7.63±3.36 (SD)  mmol O₂ m⁻³ d⁻¹. Corresponding values in stations more typical of the central Gulf of Papua were 1.68±1.30 (SD) mmol O₂ m⁻³ d⁻¹ and 1.08±2.25 (SD) mmol O₂ m⁻³ d⁻¹. Despite a shallow (<10 m) euphotic zone within the plume stations, phytoplankton production in the surface layers was sufficiently high to subsidise total water column respiration. Integrating production and respiration over the water column resulted in a calculation of net community production (NCP) of 626±504 (SD) mg C m⁻² d⁻¹, and community respiration (CR) of 712±492 mg C m⁻² d⁻¹ at the plume stations, with an average P:R ratio of 1.97. In the offshore group NCP was 157±450 (SD) mg C m⁻² d⁻¹ and CR was 1620±1576 mg C m⁻² d⁻¹. The average P:R ratio was 1.27. Three of the 7 stations allocated to the offshore group were net heterotrophic. In contrast to earlier studies in the area indicating that the Gulf of Papua waters is heterotrophic [Robertson, A.I., Dixon, P., Alongi, D.M., 1998. The influence of fluvial discharge on pelagic production in the Gulf of Papua, Northern Coral Sea. Estuarine, Coastal and Shelf Science 46, 319–331], our data indicate that in May 2004 the Gulf was in positive metabolic balance, but by only ∼120 mg C m⁻² d⁻¹. We conclude that waters of the Gulf of Papua under riverine influence are net autotrophic, but that within the central Gulf there is a fine metabolic balance alternating between autotrophy and heterotrophy.  相似文献   

New insights into the spatial variability of the surface water carbon dioxide in varying sea ice conditions in the Arctic Ocean   总被引：1，自引：0，他引：1  

Agneta Fransson  Melissa Chierici  Yukihiro Nojiri 《Continental Shelf Research》2009

In the summer of 2005, continuous surface water measurements of fugacity of CO₂ (fCO₂^sw), salinity and temperature were performed onboard the IB Oden along the Northwest Passage from Cape Farwell (South Greenland) to the Chukchi Sea. The aim was to investigate the importance of sea ice and river runoff on the spatial variability of fCO₂ and the sea–air CO₂ fluxes in the Arctic Ocean. Additional data was obtained from measurements of total alkalinity (A_T) by discrete surface water and water column sampling in the Canadian Arctic Archipelago (CAA), on the Mackenzie shelf, and in the Bering Strait. The linear relationship between A_T and salinity was used to evaluate and calculate the relative fractions of sea ice melt water and river runoff along the cruise track. High-frequency fCO₂^sw data showed rapid changes, due to variable sea ice conditions, freshwater addition, physical upwelling and biological processes. The fCO₂^sw varied between 102 and 678 μatm. Under the sea ice in the CAA and the northern Chukchi Sea, fCO₂^sw were largely CO₂ undersaturated of approximately 100 μatm lower than the atmospheric level. This suggested CO₂ uptake by biological production and limited sea–air CO₂ gas exchange due to the ice cover. In open areas, such as the relatively fresh water of the Mackenzie shelf and the Bering Strait, the fCO₂^sw values were close to the atmospheric CO₂ level. Upwelling of saline and relatively warm water at the Cape Bathurst caused a dramatic fCO₂^sw increase of about 100 μatm relative to the values in the CAA. At the southern part of the Chukchi Peninsula we found the highest fCO₂^sw values and the water was CO₂ supersaturated, likely due to upwelling. In the study area, the calculated sea–air CO₂ flux varied between an oceanic CO₂ sink of 140 mmol m⁻² d⁻¹ and an oceanic source of 18 mmol m⁻² d⁻¹. However, in the CAA and the northern Chukchi Sea, the sea ice cover prevented gas exchange, and the CO₂ fluxes were probably negligible at this time of the year. Assuming that the water was exposed to the atmosphere by total melting and gas exchange would be the only process, the CO₂ undersaturated water in the ice-covered areas will not have the time to reach the atmospheric CO₂ value, before the formation of new sea ice. This study highlights the value of using high-frequency measurements to gain increased insight into the variable and complex conditions, encountered on the shelves in the Arctic Ocean.  相似文献   

Computing cross-isotherm volume transports from ocean temperature observations and surface heat fluxes,with application to the Barents Sea inflow     

Ole Henrik Segtnan  Tore Furevik  Alastair D. Jenkins 《Continental Shelf Research》2010

A method for determining the cross-isotherm ocean transport from surface heat flux and ocean temperature data is derived. By computing the volume flux through the isotherm that extend from 19°E, 74°N to the eastern part of the Kola Peninsula, the flow through the western entrance of the Barents Sea south of 74°N is estimated. Using three different surface heat flux datasets, the inflow is found to range from 2.9 to 4.5 Sv in winter (October–March) and from 0.4 to 1.4 Sv in summer (April–September; 1 Sv=10⁶ m³ s⁻¹). The seasonal variations are stronger than indicated by results from direct current measurements, probably because the seasonal cycle of the surface heat fluxes is overestimated along the considered isotherm. The annual mean inflow ranges from 1.9 to 2.2 Sv during a cold period (1986–1988), and from 2.4 to 3.0 Sv during a warm period (1990–1992), close to reported observations.  相似文献