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1.
凝析气藏在衰竭开发过程中存在复杂的相态变化,凝析油的析出使得地层呈现出油气两相混合渗流状态.针对目前凝析气藏无因次产能评价方程的研究较少的现状,在凝析气藏拟稳态流入动态方程的基础上,利用泰勒级数展开、多项式回归等一系列解析方法建立了一种新的凝析气藏无因次产能评价方程.首先对拟稳态流入动态方程中的拟压力函数定积分进行泰勒级数展开,然后利用稳态定理和多项式回归方法求解出泰勒展开式的各项系数,最后通过解析方法得到了凝析气藏的无因次产能评价方程.应用实例表明,该无因次产能方程与实际系统试井数据基本吻合,能够较好地描述凝析气藏的油气两相流入动态;无因次产能评价法所得到无阻流量比常规干气法低,且考虑高速效应的无因次产能评价法所得到的无阻流量要大于忽略高速流动的无因次产能评价法所得到的结果. 相似文献
2.
M. T. Abasov Z. Ya. Abbasov V. M. Fataliev N. N. Hamidov G. G. Mammadova 《Doklady Earth Sciences》2009,427(2):939-942
The phase behavior of a gas-condensate mixture in the pool depletion process and the influence of porosity on the amount of
extracted concentrate and gas and on the gas phase composition have been studied experimentally. A possible approach to the
differential condensation process has been determined. The substantial influence of the zone of condensate micronuclei formation
in a porous medium on the parameters of phase condensation and on the technological parameters of condensate pool development
have been established for the first time. 相似文献
3.
4.
The problem of the composition of absorption hydrocarbons and liquid condensate arises in the study of gas condensate reservoirs. From the examples of the gas condensate part of the Karachaganak, Astrakhan, and Yamburg deposits, it is shown that absorption hydrocarbons (absorption oil) contain polar components with S and O atoms in molecules. The differences in the physicochemical properties of absorbed oil and precipitated liquid condensate are revealed, as are the regularities in the composition and properties of the absorbed oil and condensate. The criteria for division of absorption oil and liquid condensate are given. 相似文献
5.
The effects of phase fractionation on the composition of oils, condensates and gases 总被引：1，自引：0，他引：1
The effects of phase fractionation on the composition of oils, condensates and gases have been studied in the laboratory by a differential evaporation experiment. The experiment was designed to simulate the behaviour of a single-charge petroleum during (upward) migration or in a reservoir undergoing uplift, scenarios thought to be typical for the Norwegian continental shelf. After each pressure reduction step, samples from all phases (oil, condensate, free and associated gas) were collected and analysed. The results show that, in general, small molecules are preferentially enriched in the gas phase, both at elevated pressure and temperature and under standard conditions (15°C, 1 bar). The solvent power of the gas phase for large molecules is drastically reduced at lower pressures (here below approx. 300 bar). Carbon isotope ratios of individual compound are not affected, while variations in isotope ratios of fractions can be explained by changes in the fraction compositions. Individual geochemical parameters behave as can be expected based on the molecular size and structure of the compounds involved. However, a generally valid, quantitative prediction of how geochemical parameters vary as a result of phase fractionation is very difficult, as this will depend not only on the pressure and temperature of fractionation, but also on the composition and amounts of the oil and gas that are involved. The observations from this study confirm the importance of phase fractionation as an important process to consider when interpreting geochemical data for both condensates and oils. 相似文献
6.
凝析气藏的成因类型与成藏模式 总被引：13，自引：0，他引：13
根据凝析气藏形成过程中相态变化,可将其分为原生凝析气藏和次生凝析气藏。原生凝析气藏是有机质直接生成凝析气,并以气相运移聚集成藏,成藏过程中不存在相态变化。次生凝析气藏是圈闭中轻质油溶解于天然气中形成的凝析气藏,成藏过程中流体相态发生了变化。本文从两类凝析气藏的地质、地球化学特征分析入手,分析了凝析气藏的成藏模式和剖面上的相态分布,最后指出了区分二者的意义。 相似文献
7.
An automated strategy for calculation of phase diagram sections and retrieval of rock properties as a function of physical conditions 总被引：9，自引：0，他引：9
We formulate an algorithm for the calculation of stable phase relations of a system with constrained bulk composition as a function of its environmental variables. The basis of this algorithm is the approximate representation of the free energy composition surfaces of solution phases by inscribed polyhedra. This representation leads to discretization of high variance phase fields into a continuous mesh of smaller polygonal fields within which the composition and physical properties of the phases are uniquely determined. The resulting phase diagram sections are useful for understanding the phase relations of complex metamorphic systems and for applications in which it is necessary to establish the variations in rock properties such as density, seismic velocities and volatile‐content through a metamorphic cycle. The algorithm has been implemented within a computer program that is general with respect to both the choice of variables and the number of components and phases possible in a system, and is independent of the structure of the equations of state used to describe the phases of the system. 相似文献
8.
The phase state of hydrocarbon accumulations was predicted using recent drilling data for three oil and gas complexes of the
northern regions of the West Siberian petroliferous basin: Lower and Middle Jurassic, Upper Jurassic, and Berriasian-lower
Valanginian (Achimov member); these results were compiled in simplified maps presented in the paper. In order to develop a
plausible model and distinguish the zones of hydrocarbon accumulation of various phase states, we analyzed and systematized
the existing concepts on the distribution of oil, oil-gas condensate, and gas condensate pools in the Mesozoic sequences of
this region, types of organic matter in rocks, and stages of catagenetic alterations. Based on the data of the Tyumen SG-6
superdeep well, the oil-generating capacity of source deposits was assessed. Three zones differing in the phase state of hydrocarbons,
oil, gas condensate-oil (transitional), and gas condensate, were distinguished in the map of the distribution of hydrocarbon
accumulations in the Early-Middle Jurassic petroliferous complex of northwestern Siberia. Only two zones of hydrocarbon accumulations,
oil and transitional, were detected in the Late Jurassic complex of the Nadym-Taz and Ust’-Yenisei regions. The same zones
but within different boundaries were distinguished in the Achimov sequence. In contrast to the Jurassic beds, the zone of
occurrence of oil accumulations in the Achimov member occupies a larger area and extends further north. In terms of density,
the oils of the Achimov deposits were subdivided into three types: ultralight, light, and medium. The zones of their occurrence
are shown in the map.
Original Russian Text ? S.A. Punanova, T.L. Vinogradova, 2006, published in Geokhimiya, 2006, No. 9, pp. 983–995. 相似文献
9.
储层烃类包裹体类型识别与PVT模拟方法 总被引：3，自引：1，他引：2
正确判识烃类包裹体的类型与准确的PVT模拟结果对于含油气盆地储层包裹体研究和应用有着重要的意义。目前有关烃类包裹体类型的分析方法有显微冷冻测温分析、荧光光谱分析、显微激光拉曼光谱分析及傅里叶变换红外光谱分析等方法。显微测温分析是研究包裹体相变特征的基本方法,也是判断烃类包裹体含油类型的简单而有力的工具。根据烃类包裹体的相变特征结合光谱分析结果可以识别不同类型的油气,如重质油、轻质油、湿气、干气和凝析气等。根据其临界点的高低也可以判断其含油类型。在对烃类包裹体判识的基础上,对包裹体进行PVT模拟是准确获取油气成藏温压条件的重要手段,但PVT模拟的难点是难以获取单个烃类包裹体的成分,这将是未来烃类包裹体研究的重要内容之一。 相似文献
10.
自然界中矿物多以固溶体形式存在,据其晶体化学特征计算热力学性质是开展矿物成因理论研究的基础。本文引入描述二元矿物固溶体热力学性质的假三元模型,计算得到了透辉石-硬玉固溶体系列的热力学性质。该模型通过构造一种高度有序的中间相,同时考虑长程和短程有序效应,基于热力学平衡态矿物固溶体自由能最低的规律,可以计算特定组分下矿物的平衡自由能、焓和熵等热力学参数。本文针对透辉石-硬玉固溶体体系,取绿辉石为其中间有序态,计算了其活度-成分关系和温度-组分相图等,发现绿辉石随温度升高的有序无序相变为一级相变,相变温度为1 148±25 K,与实验研究结果一致。本文获得的透辉石-绿辉石-硬玉体系的热力学参数可用于视剖面图方法研究MORB成分的岩石的榴辉岩相变质作用过程。 相似文献
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12.
A scheme for the spatial distribution of ground successions in the territory of Russia is constructed. Peculiarities of the ground composition and structure in the section of the succession, the character of the state of ground successions caused by the phase state of water in the successions, annual mean temperatures and degree of humidity for thawed and non-frozen rocks, as well as the degree of ice content for permafrost rocks, were used as qualification indicators. The variety of recognized ground successions, which differ in their genesis and specific features of structure, composition, and state, are demonstrated. Patterns of their distribution are discussed. 相似文献
13.
William V Boynton 《Geochimica et cosmochimica acta》1975,39(5):569-584
The condensation of Y and the rare earth elements (REE) from the solar nebula may be controlled by thermodynamic equilibrium between gas and condensed solids. Highly fractionated REE patterns may result if condensates are removed from the gas before condensation is complete. It is found that the fractionation is not a smooth function of REE ionic radius but varies in an extremely irregular pattern. Both Yb and Eu are predicted to be extremely depleted in the early condensate without the requirement of condensation in the divalent state. The model is discussed with respect to a highly fractionated pattern observed by Tanaka and Masuda (Icarus19, 523–530 1973), in a pink Ca-Al-rich inclusion from the Allende meteorite and can account for the abundances of each REE determined. According to the model this inclusion represents a condensate from a previously fractionated gas rather than from a gas of solar composition. Before the condensation of this inclusion, an earlier condensate was formed and was removed from equilibrium with the gas. 相似文献
14.
我国凝析油的成因类型及其地球化学特征和意义 总被引：5，自引：1，他引：5
近十几年的勘探实际表明，在我国一些含油气盆地中，许多天然气藏均伴生一定量的凝析油（或轻质油）。按母质类型可将凝析油分为海相腐泥型有机质生成的凝析油、煤系地层腐殖质有机质生成的凝析油、陆相混合型有机质生成的凝析油。本文较详细地从成因机理上讨论了这三种不同成因凝析油的形成特点。海相腐泥型有机质一般在有机质热演化达到高成熟－过成熟阶段，由干酪根或早期形成的高分子液态烃热裂解才形成凝析油。煤系地层中腐殖型有机质从低成熟到过成熟各个阶段所生成的一定量的液态烃一般主要以凝析油的状态与天然气相伴生。陆相混合型有机质从低成熟到过成熟阶段也都可能形成凝析油。利用凝析油单体烃的组份特征，石蜡指数和庚烷值对我国主要含油气盆地凝析油的成熟度进行了计算，所得结果，大都与地质实际相吻合。研究表明我国凝析油成熟度的分布范围从低成熟到过成熟均有。三种不同成因的凝析油其地球化学特征具有一定差异，煤系地层腐殖型有机质形成的凝析油从组份来讲相对富含芳烃，其芳烃含量一般为１６.２～２３.５%，饱和烃/芳烃值为３.２～５.２，同时其姥鲛烷/植烷值相对较高，通常均大于３；而海相腐泥型有机质生成的凝析油则相对富含饱和烃，其饱/芳比值为１１.８～１８.２，同时姥蛟烷/植烷值较低，一般小于1。陆相混合型有机质生成的凝析油则介于二者之间。三类不同成因的凝析油它们的芳烃组份(蔡系、联苯系和药系)和低分子生物标记物(菇类化合物)以及烷烃和芳烃组份的碳同位素组成都具有明显的差异。利用凝析油的这些地球化学特征可以有效地判识凝析油的成熟度和成因类型，从而确定与之相伴生的天然气的成因或来源。 相似文献
15.
为了明确渤海湾盆地渤中19-6大气田的地化特征和成因,选取研究区潜山凝析气藏7个凝析油样品进行全油色谱分析,剖析其轻烃组成特征,探讨轻烃参数在该区的地质应用.结果表明:渤中19-6凝析油的Mango轻烃参数K1和K2值相对稳定,表明研究区原油成因类型基本一致.C6~C8组成中正构烷烃具显著优势,甲基环己烷指数平均为39%;庚烷值与异庚烷值,正庚烷/甲基环己烷（F）比值较高,反映它们较高成熟度;轻烃参数计算原油生成温度为125.8~128.1 ℃,其相对偏低,可能与取样过程中凝析油的相态变化有关;2-甲基戊烷/3-甲基戊烷,2-甲基己烷/3-甲基己烷比值高,K2值低;凝析油正构烷烃摩尔浓度呈三段式分布,甲苯/正庚烷和原油蜡含量随深度而增加.结合饱和烃参数以及金刚烷参数揭示渤中19-6潜山油气为湖相腐泥Ⅱ1型母质在高成熟阶段（Ro=1.05%~1.30%）的产物,气藏形成后发生一定程度分馏造成油气组分调整. 相似文献
16.
周雯雯 《中国地球化学学报》1999,18(4):377-382
Studies of organic inclusions from the offshore oil and gas fields provide much information about the number of times,temperature,depth,time and phase state of oil-gas migration,as well as about the composition of organic inclusions.On the basis of the type,character,composition and distribution of organic inclusions in the Zhu-Ⅲ Depression at the Pearl River Mouth,information can be developed about the source rocks of oil and gas,and their evolution and migration. 相似文献
17.
《Russian Geology and Geophysics》2016,57(6):958-966
The pore space of reservoir rocks has a lot of active centers capable to form different types of bonds (from hydrogen to chemical). Therefore, almost any hydrocarbon can be adsorbed to a particular extent on the internal pore surface and form an adsorbed layer, which has a definite spatial configuration and makes contact with a certain part of the rock surface. Study of gas condensate reservoirs brings up the question of the composition of adsorbed hydrocarbons. The properties of such hydrocarbons in many giant gas condensate fields are of special interest as these compounds can serve as an additional source of resources after production of mobile-gas reserves. The performed study of gas condensate reservoirs of the Karachaganak, Astrakhan, and Yamburg fields has shown that their adsorbed hydrocarbons (adsorbed oil) have polar components with sulfur and oxygen atoms. 相似文献
18.
轻烃中C6族组成和芴系化合物与沉积环境的关系 总被引：1，自引：0，他引：1
本文对我国8个含油气盆地40多个凝析油、轻质油样品进行了气相色谱和色谱-质谱分析研究了不同沉积环境形成的凝析油和轻质油中的C6族组成和芳烃中芴系化合物（即芴、氧芴和硫芴）特征,探讨成气母质和沉积环境,并将其作为判识天然气成因的一种手段. 相似文献
19.
充分认识岩石的地质本质性是准确描述其物理力学特性的桥梁。岩石的地质本质性涵盖了岩石的物质性、结构性和赋存状态3个方面的内容。在综合考虑岩石上述3方面特征及其与单轴试验联系的基础上,以矿物组成、密度、纵波波速和含水状态为基本指标,采用回归和BP神经网络的方法对碳酸盐岩单轴抗压强度进行预测,并采用灰色关联分析法验证本研究所选用的预测基本指标的合理性。实例应用表明：本次采用的回归方法对该类岩石强度预测的最大误差为15.3%,BP神经网络方法预测的最大误差为8.5%。预测误差出现的原因为碳酸盐岩物质组成复杂,所选预测基本指标是实际情况的简化,同时泥灰质岩石所具有的膨胀性也导致实测和预测结果具有一定的差异。 相似文献
20.
渤海湾盆地油气资源十分丰富、类型多样。通过对渤中凹陷19个原油样品地球化学特征的系统研究,揭示了该区不同类型、不同性质原油在物理性质、化学组成、生物标志物分布与组成、正构烷烃单体烃碳同位素等方面的差异。研究表明,渤中凹陷存在凝析油、正常油和生物降解原油。凝析油具有低密度、低粘度、低含蜡、饱和烃含量高,非烃、沥青质和芳烃含量低的特征,生物降解原油则反之。凝析油和生物降解原油中的重排补身烷丰度都大于8β（H）-补身烷的丰度,C24四环萜烷丰度低。渤中凹陷原油正构烷烃单体烃碳同位素组成分为两类：一类具有较轻的碳同位素组成,其同位素值介于-2．75％～-2．95％之间;另一类的碳同位素组成则较重,一般介于-2．40％--2．75％之间。 相似文献