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1.
Hyperspectral remote sensing has demonstrated great potential for accurate retrieval of canopy water content (CWC). This CWC is defined by the product of the leaf equivalent water thickness (EWT) and the leaf area index (LAI). In this paper, in particular the spectral information provided by the canopy water absorption feature at 970 nm for estimating and predicting CWC was studied using a modelling approach and in situ spectroradiometric measurements. The relationship of the first derivative at the right slope of the 970 nm water absorption feature with CWC was investigated with the PROSAIL radiative transfer model and tested for field spectroradiometer measurements on two test sites. The first site was a heterogeneous floodplain with natural vegetation like grasses and various shrubs. The second site was an extensively grazed fen meadow.  相似文献   

2.
In this paper, we carried out a laboratory experiment to study changes in canopy reflectance of Tamarugo plants under controlled water stress. Tamarugo (Prosopis tamarugo Phil.) is an endemic and endangered tree species adapted to the hyper-arid conditions of the Atacama Desert, Northern Chile. Observed variation in reflectance during the day (due to leaf movements) as well as changes over the experimental period (due to water stress) were successfully modelled by using the Soil-Leaf-Canopy (SLC) radiative transfer model. Empirical canopy reflectance changes were mostly explained by the parameters leaf area index (LAI), leaf inclination distribution function (LIDF) and equivalent water thickness (EWT) as shown by the SLC simulations. Diurnal leaf movements observed in Tamarugo plants (as adaptation to decrease direct solar irradiation at the hottest time of the day) had an important effect on canopy reflectance and were explained by the LIDF parameter. The results suggest that remote sensing based assessment of this desert tree should consider LAI and canopy water content (CWC) as water stress indicators. Consequently, we tested fifteen different vegetation indices and spectral absorption features proposed in literature for detecting changes of LAI and CWC, considering the effect of LIDF variations. A sensitivity analysis was carried out using SLC simulations with a broad range of LAI, LIDF and EWT values. The Water Index was the most sensitive remote sensing feature for estimating CWC for values less than 0.036 g/cm2, while the area under the curve for the spectral range 910–1070 nm was most sensitive for values higher than 0.036 g/cm2. The red-edge chlorophyll index (CIred-edge) performed the best for estimating LAI. Diurnal leaf movements had an effect on all remote sensing features tested, particularly on those for detecting changes in CWC.  相似文献   

3.
In-situ spectral reflectance characteristics of soils were studied under field conditions with Multiband Ground Truth Radiometer covering 0.45?C0.52, 0.52?C0.59, 0.62?C0.68, and 0.77?C0.86 ??m spectral bands. Twenty-two surface soil samples were studied in laboratory for their spectral reflectance characteristics using ISCO Model S.R. Spectroradiometer in visible wavelength (450?C725 nm), with 25 nm bandwidth, and in infrared wavelength (750?C1550 nm), with 50 nm bandwidth. The Bidirectional reflectance factor representative of spectral reflectance varied from 3.78 to 11.3???m in band 1, 6.09 to 15.41???m in band 2, 8.05 to 19.41???m in band 3, and 12.18 to 31.2???m in band 4. In-situ spectral reflectance in general increases with the wavelength from visible to infrared bands for all the soils. Black soils have relatively lower reflectance as compared to red soils, which is attributed to the variation in the physicochemical properties of soils. Spectral reflectance, under laboratory conditions, for all the soils increases with wavelength from visible to infrared region except at 950 nm and 1200 nm, where reflectance decreased in all soils, due to weaker water absorption bands and also at 1350 nm, due to strong water absorption at this band. The spectral reflectance of red soils were higher, in-situ as well as under laboratory conditions, as compared to black soils, which is attributed to variation in soil colour, organic matter and clay content of soils. It is observed that the spectral reflectance decrease due to moisture content in soils in all the spectral bands because of darker appearance of soils at moist conditions. Laboratory reflectance measurements serve to define the extent to which intrinsic spectral information is available from soils as a consequence of their composition.  相似文献   

4.
The research evaluated the information content of spectral reflectance (laboratory and airborne data) for the estimation of needle chlorophyll (CAB) and nitrogen (CN) concentration in Norway spruce (Picea abies L. Karst.) needles. To identify reliable predictive models different types of spectral transformations were systematically compared regarding the accuracy of prediction. The results of the cross-validated analysis showed that CAB can be well estimated from laboratory and canopy reflectance data. The best predictive model to estimate CAB was achieved from laboratory spectra using continuum-removal transformed data (R2cv = 0.83 and a relative RMSEcv of 8.1%, n = 78) and from hyperspectral HyMap data using band-depth normalised spectra (R2cv = 0.90, relative RMSEcv = 2.8%, n = 13). Concerning the nitrogen concentration, we observed somewhat weaker relations, with however still acceptable accuracies (at canopy level: R2cv = 0.57, relative RMSEcv = 4.6%). The wavebands selected in the regression models to estimate CAB were typically located in the red edge region and near the green reflectance peak. For CN, additional wavebands related to a known protein absorption feature at 2350 nm were selected. The portion of selected wavebands attributable to known absorption features strongly depends on the type of spectral transformation applied. A method called “water removal” (WR) produced for canopy spectra the largest percentage of wavebands directly or indirectly related to known absorption features. The derived chlorophyll and nitrogen maps may support the detection and the monitoring of environmental stressors and are also important inputs to many bio-geochemical process models.  相似文献   

5.
The Normalized Area Over reflectance Curve (NAOC) is proposed as a new index for remote sensing estimation of the leaf chlorophyll content of heterogeneous areas with different crops, different canopies and different types of bare soil. This index is based on the calculation of the area over the reflectance curve obtained by high spectral resolution reflectance measurements, determined, from the integral of the red–near-infrared interval, divided by the maximum reflectance in that spectral region. For this, use has been made of the experimental data of the SPARC campaigns, where in situ measurements were made of leaf chlorophyll content, LAI and fCOVER of 9 different crops – thus, yielding 300 different values with broad variability of these biophysical parameters. In addition, Proba/CHRIS hyperspectral images were obtained simultaneously to the ground measurements. By comparing the spectra of each pixel with its experimental leaf chlorophyll value, the NAOC was proven to exhibit a linear correlation to chlorophyll content. Calculating the correlation between these variables in the 600–800 nm interval, the best correlation was obtained by computing the integral of the spectral reflectance curve between 643 and 795 nm, which practically covers the spectral range of maximum chlorophyll absorption (at around 670 nm) and maximum leaf reflectance in the infrared (750–800 nm). Based on a Proba/CHRIS image, a chlorophyll map was generated using NAOC and compared with the land-use (crops classification) map. The method yielded a leaf chlorophyll content map of the study area, comprising a large heterogeneous zone. An analysis was made to determine whether the method also serves to estimate the total chlorophyll content of a canopy, multiplying the leaf chlorophyll content by the LAI. To validate the method, use was made of the data from another campaign ((SEN2FLEX), in which measurements were made of different biophysical parameters of 7 crops, and hyperspectral images were obtained with the CASI imaging radiometer from an aircraft. Applying the method to a CASI image, a map of leaf chlorophyll content was obtained, which on, establishing comparisons with the experimental data allowed us to estimate chlorophyll with a root mean square error of 4.2 μg/cm2, similar or smaller than other methods but with the improvement of applicability to a large set of different crop types.  相似文献   

6.
The aim of this study was to monitor changes in leaf spectral reflectance due to phytoaccumulation of trace elements (Cd, Pb, and As) in sunflower mutant (M5 mutant line 38/R4-R6/15-35-190-04-M5) grown in spiked and in situ metal-contaminated potted soils. Reflectance spectra (350–2500 nm) of leaves were collected using portable ASD spectroradiometer, and respective leaves sample were analyzed for total metal contents. The spectral changes were quite noticeable and showed increased visible and decreased NIR reflectance for sunflower grown in soil spiked with 900 mg As kg?1, and in in situ metal-contaminated soils. These changes also involved a blue-shift feature of red-edge position in the first derivatives spectra, studied vegetation indices and continuum removed absorption features at 495, 680, 970, 1165, 1435, 1780, and 1925 nm wavelength. Correlograms of leaf-metal concentration and reflectance values show highest degrees of overall correlation for visible, near-infrared, and water-sensitive wavelengths. Partial least square and multiple linear regression statistical models (cross-validated), respectively, based on Savitzky–Golay filter first-order derivative spectra and combination of spectral feature such as vegetation indices and band depths yielded good prediction of leaf-metal concentrations.  相似文献   

7.
基于实测光谱估测密云水库水体叶绿素a浓度   总被引：2，自引：0，他引：2  
水中叶绿素a浓度是衡量水体初级生产力和富营养化程度的最基本的指标。利用野外便携式地物光谱仪对密云水库水体进行反射光谱测量并同步采集水样。通过分析叶绿素a浓度与光谱反射特征的相关关系,建立了叶绿素a反演模型。结果表明,利用单波段光谱反射率、光谱比值指数或微分光谱比值能够可靠反演叶绿素a浓度;但微分光谱与叶绿素a浓度相关性更高,更适用于密云水库水体叶绿素a浓度的高光谱反演。  相似文献   

8.
Information about the distribution of grass foliar nitrogen (N) and phosphorus (P) is important for understanding rangeland vitality and for facilitating the effective management of wildlife and livestock. Water absorption effects in the near-infrared (NIR) and shortwave-infrared (SWIR) regions pose a challenge for nutrient estimation using remote sensing. The aim of this study was to test the utility of water-removed (WR) spectra in combination with partial least-squares regression (PLSR) and stepwise multiple linear regression (SMLR) to estimate foliar N and P, compared to spectral transformation techniques such as first derivative, continuum removal and log-transformed (Log(1/R)) spectra. The study was based on a greenhouse experiment with a savanna grass species (Digitaria eriantha). Spectral measurements were made using a spectrometer. The D. eriantha was cut, dried and chemically analyzed for foliar N and P concentrations. WR spectra were determined by calculating the residual from the modelled leaf water spectra using a nonlinear spectral matching technique and observed leaf spectra. Results indicated that the WR spectra yielded a higher N retrieval accuracy than a traditional first derivative transformation (R2=0.84, RMSE = 0.28) compared to R2=0.59, RMSE = 0.45 for PLSR. Similar trends were observed for SMLR. The highest P retrieval accuracy was derived from WR spectra using SMLR (R2=0.64, RMSE = 0.067), while the traditional first derivative and continuum removal resulted in lower accuracy. Only when using PLSR did the first derivative result in a higher P retrieval accuracy (R2=0.47, RMSE = 0.07) than the WR spectra (R2=0.43, RMSE = 0.070). It was concluded that the water removal technique is a promising technique to minimize the perturbing effect of foliar water content when estimating grass nutrient concentrations.  相似文献   

9.
Hyperspectral sensing can provide an effective means for fast and non-destructive estimation of leaf nitrogen (N) status in crop plants. The objectives of this study were to design a new method to extract hyperspectral spectrum information, to explore sensitive spectral bands, suitable bandwidth and best vegetation indices based on precise analysis of ground-based hyperspectral information, and to develop regression models for estimating leaf N accumulation per unit soil area (LNA, g N m−2) in winter wheat (Triticum aestivum L.). Three field experiments were conducted with different N rates and cultivar types in three consecutive growing seasons, and time-course measurements were taken on canopy hyperspectral reflectance and LNA under the various treatments. Then, normalized difference spectral indices (NDSI) and ratio spectral indices (RSI) based on the original spectrum and the first derivative spectrum were constructed within the range of 350–2500 nm, and their relationships with LNA were quantified. The results showed that both LNA and canopy hyperspectral reflectance in wheat changed with varied N rates, with consistent patterns across different cultivars and seasons. The sensitive spectral bands for LNA existed mainly within visible and near infrared regions. The best spectral indices for estimating LNA in wheat were found to be NDSI (R860, R720), RSI (R990, R720), NDSI (FD736, FD526) and RSI (FD725, FD516), and the regression models based on the above four spectral indices were formulated as Y = 26.34x1.887, Y = 5.095x − 6.040, Y = 0.609 e3.008x and Y = 0.388x1.260, respectively, with R2 greater than 0.81. Furthermore, expanding the bandwidth of NDSI (R860, R720) and RSI (R990, R720) from 1 nm to 100 nm at 1 nm interval produced the LNA monitoring models with similar performance within about 33 nm and 23 nm bandwidth, respectively, over which the statistical parameters of the models became less stable. From testing of the derived equations, the model for LNA estimation on NDSI (R860, R720), RSI (R990, R720), NDSI (FD736, FD526) and RSI (FD725, FD516) gave R2 over 0.79 with more satisfactory performance than previously reported models and physical models in wheat. It can be concluded that the present hyperspectral parameters of NDSI (R860, R720), RSI (R990, R720), NDSI (FD736, FD526) and RSI (FD725, FD516) can be reliably used for estimating LNA in winter wheat.  相似文献   

10.
Spectral properties of volcanic materials in the optical region (350–2500 nm) of the electromagnetic spectrum are analyzed. The goal is to characterize air-fall deposits, recent lava flows, and old lava flows based on their spectral reflectance properties and on the textural characteristics (grain size) of pyroclastic deposits at an active basaltic volcano. Data were acquired during a spectroradiometric field survey at Mt. Etna (Italy) in summer 2003 and combined with hyperspectral satellite (Hyperion) and airborne LiDAR (Light Detection and Ranging) data. In addition, air-fall deposits produced by the highly explosive 2002–2003 eruption have been sampled and spectrally characterized at different distances from the new vents. The spectral analysis shows that air-fall deposits are characterized by low reflectance values besides variations in grain size. This distinguishes them from other surface materials. Old lava flows show highest reflectance values due to weathering and vegetation cover. The spectral data set derived from the field survey has been compared to corrected satellite hyperspectral data in order to investigate the Hyperion capabilities to differentiate the surface cover using the reflectance properties. This has allowed us to identify the 2002–2003 air-fall deposits in a thematic image just few months after their emplacement. Moreover, the observed differences in the field spectra of volcanic surfaces have been compared with differences in the signal intensity detected by airborne LiDAR survey showing the possibility to include information on the texture of volcanic surfaces at Mt. Etna. The approach presented here may be particularly useful for remote and inaccessible volcanic areas and also represents a potentially powerful tool for the exploration of extraterrestrial volcanic surfaces.  相似文献   

11.
Estimating forest structural attributes using multispectral remote sensing is challenging because of the saturation of multispectral indices at high canopy cover. The objective of this study was to assess the utility of hyperspectral data in estimating and mapping forest structural parameters including mean diameter-at-breast height (DBH), mean tree height and tree density of a closed canopy beech forest (Fagus sylvatica L.). Airborne HyMap images and data on forest structural attributes were collected from the Majella National Park, Italy in July 2004. The predictive performances of vegetation indices (VI) derived from all possible two-band combinations (VI(i,j) = (Ri − Rj)/(Ri + Rj), where Ri and Rj = reflectance in any two bands) were evaluated using calibration (n = 33) and test (n = 20) data sets. The potential of partial least squares (PLS) regression, a multivariate technique involving several bands was also assessed. New VIs based on the contrast between reflectance in the red-edge shoulder (756–820 nm) and the water absorption feature centred at 1200 nm (1172–1320 nm) were found to show higher correlations with the forest structural parameters than standard VIs derived from NIR and visible reflectance (i.e. the normalised difference vegetation index, NDVI). PLS regression showed a slight improvement in estimating the beech forest structural attributes (prediction errors of 27.6%, 32.6% and 46.4% for mean DBH, height and tree density, respectively) compared to VIs using linear regression models (prediction errors of 27.8%, 35.8% and 48.3% for mean DBH, height and tree density, respectively). Mean DBH was the best predicted variable among the stand parameters (calibration R2 = 0.62 for an exponential model fit and standard error of prediction = 5.12 cm, i.e. 25% of the mean). The predicted map of mean DBH revealed high heterogeneity in the beech forest structure in the study area. The spatial variability of mean DBH occurs at less than 450 m. The DBH map could be useful to forest management in many ways, e.g. thinning of coppice to promote diameter growth, to assess the effects of management on forest structure or to detect changes in the forest structure caused by anthropogenic and natural factors.  相似文献   

12.
基于反射光谱预测土壤重金属元素含量的研究   总被引：5，自引：0，他引：5  
本文利用实验室实测的土壤反射光谱以及铅、镉、汞等重金属元素数据,进行土壤重金属元素含量快速预测的可行性研究。本文利用偏最小二乘回归方法,研究了反射率(R)、一阶微分(FDR)、反射率倒数的对数(lg(1/R))和波段深度(BD)等对预测精度的影响,对这几种光谱指标预测土壤重金属含量的能力进行了分析和评价,同时分析了多光谱数据估算土壤重金属元素含量的可行性。结果表明,反射率倒数的对数lg(1/R)是估算土壤重金属元素含量最好的光谱指标,尤其是Cd和Pb,检验精度R超过0.82。有机质、铁锰氧化物和黏土矿物对土壤重金属元素的吸附是可见光—近红外—短波红外光谱估算其含量的机理。多光谱数据同样具有估算土壤重金属元素含量的能力,但实际数据则要考虑多种因素的影响。  相似文献   

13.
This study aims at discriminating eight mangrove species of Rhizophoraceae family of Indian east coast using field and laboratory spectra in spectral range (350–2500 nm). Parametric and non-parametric statistical analyses were applied on spectral data in four spectral modes: (i) reflectance (ii) continuum removed, (iii) additive inverse and (iv) continuum removed additive inverse. We introduced continuum removal of inverse spectra to utilize the advantage of continuum removal in reflectance region. Non-parametric test gave better separability than parametric test. Principal component analysis and stepwise discriminant analysis were applied for feature reduction and to identify optimal wavelengths for species discrimination. To quantify the separability, Jeffries–Matusita distance measure was derived. Green (550 nm), red edge (680–720 nm) and water absorption region (1470 and 1850 nm) were found to be optimal wavelengths for species discrimination. The continuum removal of additive inverse spectra gave better separability than the continuum removed spectra.  相似文献   

14.
In the present study, The Landsat 7 ETM satellite data was collected for the Sittampundi anorthosites complex and digital image analysis was carried out. The anorthositic rocks available at Sittampundi complex is considered as an equivalent of lunar highland rocks. Hence, a remote sensing study comprises of image analysis and spectral profile analysis was carried out. The satellite data was digitally processed and generated various outputs like band combinations, color composites, stretched outputs, and PCA. The suitable processed outputs were identified for delineating the anorthosite complex. The diagnostic absorption features of reflectance spectra are the sensitive indicators of mineralogy and chemical composition of rocks, which are interest to the planetary scientists. The spectral profile of Landsat ETM plotted for pure and mixed anorthosite pixels and compared with the field and lab reflectance spectra. The percentages of image spectra vary from 30% to 60% for Sittampundi anorthosite. The spectral bands 2, 4 and 6 have low reflectance and bands 3 and 5 have high reflectance. The spectral range of bands 2,3,4,5 and 6 are 525 nm–605 nm, 630 nm–690 nm, 750 nm–900 nm, 1550 nm–1750 nm and 10400 nm–12500 nm respectively. The field spectral curve has weak absorptions at 650 nm and 1000 nm due to the iron transition absorption and low ca- pyroxene respectively available in the anorthosite, matching with the image spectra. However, hyperspectal image with narrow bandwidth could be more useful in selecting the suitable spectrum for remotely mapping the anorthosite region, as equivalent test site for lunar highland region.  相似文献   

15.
This study presents an approach for chlorophyll content determination of small shallow water bodies (kettle holes) from hyperspectral airborne ROSIS and HyMap data (acquired on 15 May and 29 July 2008 respectively). Investigated field and airborne spectra for almost all kettle holes do not correspond to each other due to differences in ground sampling distance. Field spectra were collected from the height of 30–35 cm (i.e. area of 0.01–0.015 m2). Airborne pixels of ROSIS and HyMap imageries cover an area of 4 m2 and 16 m2 respectively and their spectra are highly influenced by algae or bottom properties of the kettle holes. Analysis of airborne spectra revealed that chlorophyll absorption near 677 nm is the same for both datasets. In order to enhance absorption properties, both airborne hyperspectral datasets were normalized by the continuum removal approach. Linear regression algorithms for ROSIS and HyMap datasets were derived using normalized average chlorophyll absorption spectra for each kettle hole. Overall accuracy of biomass mapping for ROSIS data was 71%, and for HyMap 64%. Biomass mapping results showed that, depending on the type of kettle hole, algae distribution, the ‘packaging effect’ and bottom reflection lead to miscalculations of the chlorophyll content using hyperspectral airborne data.  相似文献   

16.
Spectral library search is emerging as a viable approach for material identification and mapping by reusing spectral knowledge gained from hyperspectral remote sensing across space and time. The potential of retrieving meaningful spectral material identifications in the presence of reflectance of spectra of various material types and with various similarity metrics has been assessed in this study. Test reflectance spectra of various vegetation, minerals, soils and urban material types are identified by searching through the composite reflectance spectral library obtained by combining various institutional reflectance spectral libraries. The accuracy of material identifications under various conditions: (i) in the presence of identical, similar and dissimilar spectra; (ii) in the presence of only identical and dissimilar spectra; and (iii) in the presence of only dissimilar spectra has been assessed with several similarity metrics. Results indicate the possibility of obtaining 100% accurate material identifications by library search if the spectral library contains identical spectra. However, the presence of a large number of similar spectra, despite the presence of identical spectra, is found to increase false positives, thereby reducing the accuracy of retrievals to 82% at best. Further, the accuracy of material identifications in the presence of similar spectra is similarity metric-dependent and varied from about 52% (obtained from Binary Encoding) to 82% (obtained from Normalized Spectral Similarity Score). Overall, results support the possibility of using independent reflectance spectral libraries for material identification while calling for robust spectral similarity metrics.  相似文献   

17.
以福建省平和县琯溪蜜柚为研究对象，利用星载Hyperion高光谱遥感数据对蜜柚叶片进行氮浓度估测。在分析Hyperion数据特征的基础上进行大气校正、几何纠正等预处理，从而得到图像反射率；结合地面光谱测量和蜜柚叶片采样分析，通过逐步回归分析法研究叶片氮浓度与高光谱图像反射率及其衍生量的关系，最终建立其遥感定量监测模型。结果表明，图像反射率的对数变换更有利于氮浓度的定量反演，入选的波段是983 nm、1 245 nm、1 316 nm和1 457 nm，其中1 245 nm波段对氮浓度影响最大，1 457 nm波段最小。利用该模型对氮浓度进行估算的值域与地面调查结果一致，说明利用高光谱进行氮浓度定量反演具有一定的可行性。  相似文献   

18.
本文研究了山东省招远市台上金矿区与背景区赤松林的植物地球化学特征、赤松生长状况和光谱反射率特征的差异。结果表明，赤松对Ａｕ，Ａｇ，Ｃｕ，Ｐｂ等金属元素均呈强积累，赤松针叶中的Ａｕ、Ａｇ元素含量金矿区值和背景区值之比分别可达６和１８。重金属的过量吸收使金矿区赤松的生长状况变差，针叶内叶绿素含量减少，反射光谱特征明显变化。金矿区与背景区对比，赤松的红界蓝移幅度可达８—１２ｎｍ。随重金属污染程度的加重，近红外肩反射率值、叶绿素反射峰值与叶绿素吸收峰值之差均呈下降趋势，一阶导数谱７１０ｎｍ附近平顶斜率由正值变为负值，逐渐变小。反射光谱的这种变化规律可用以遥感探查赤松林下重金属矿藏。  相似文献   

19.
Soil contamination by heavy metals has been an increasingly severe threat to nature environment and human health. Efficiently investigation of contamination status is essential to soil protection and remediation. Visible and near-infrared reflectance spectroscopy (VNIRS) has been regarded as an alternative for monitoring soil contamination by heavy metals. Generally, the entire VNIR spectral bands are employed to estimate heavy metal concentration, which lacks interpretability and requires much calculation. In this study, 74 soil samples were collected from Hunan Province, China and their reflectance spectra were used to estimate zinc (Zn) concentration in soil. Organic matter and clay minerals have strong adsorption for Zn in soil. Spectral bands associated with organic matter and clay minerals were used for estimation with genetic algorithm based partial least square regression (GA-PLSR). The entire VNIR spectral bands, the bands associated with organic matter and the bands associated with clay minerals were incorporated as comparisons. Root mean square error of prediction, residual prediction deviation, and coefficient of determination (R2) for the model developed using combined bands of organic matter and clay minerals were 329.65 mg kg−1, 1.96 and 0.73, which is better than 341.88 mg kg−1, 1.89 and 0.71 for the entire VNIR spectral bands, 492.65 mg kg−1, 1.31 and 0.40 for the organic matter, and 430.26 mg kg−1, 1.50 and 0.54 for the clay minerals. Additionally, in consideration of atmospheric water vapor absorption in field spectra measurement, combined bands of organic matter and absorption around 2200 nm were used for estimation and achieved high prediction accuracy with R2 reached 0.640. The results indicate huge potential of soil reflectance spectroscopy in estimating Zn concentrations in soil.  相似文献   

20.
This paper assesses the capability of hyperspectral remote sensing to detect hydrocarbon leakages in pipelines using vegetation status as an indicator of contamination. A field experiment in real scale and in tropical weather was conducted in which Brachiaria brizantha H.S. pasture plants were grown over soils contaminated with small volumes of liquid hydrocarbons (HCs). The contaminations involved volumes of hydrocarbons that ranged between 2 L and 12.7 L of gasoline and diesel per m3 of soil, which were applied to the crop parcels over the course of 30 days. The leaf and canopy reflectance spectra of contaminated and control plants were acquired within 350–2500 nm wavelengths. The leaf and canopy reflectance spectra were mathematically transformed by means of first derivative (FD) and continuum removal (CR) techniques. Using principal component analysis (PCA), the spectral measurements could be grouped into either two or three contamination groups. Wavelengths in the red edge were found to contain the largest spectral differences between plants at distinct, evolving contamination stages. Wavelengths centred on water absorption bands were also important to differentiating contaminated from healthy plants. The red edge position of contaminated plants, calculated on the basis of FD spectra, shifted substantially to shorter wavelengths with increasing contamination, whereas non-contaminated plants displayed a red shift (in leaf spectra) or small blue shift (in canopy spectra). At leaf scale, contaminated plants were differentiated from healthy plants between 550–750 nm, 1380–1550 nm, 1850–2000 nm and 2006–2196 nm. At canopy scale, differences were substantial between 470–518 nm, 550–750 nm, 910–1081 nm, 1116–1284 nm, 1736–1786 nm, 2006–2196 nm and 2222–2378 nm. The results of this study suggests that remote sensing of B. brizantha H.S. at both leaf and canopy scales can be used as an indicator of gasoline and diesel contaminations for the detection of small leakages in pipelines.  相似文献   

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