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1.
Tungsten minerals (scheelite and wolframite) from two genetic types of granitoids show significant differences in REE distribution, probably due to different material sources and origins. Tungsten minerals in granite porphyry of the crust-mantle source are relatively high in ΣREE(1884ppm on average). Σ Ce is rich relative to Σ Y and Σ Ce/ΣY is relatively high (>1). The chondrite-normalized REE distribution patterns are characterized by a group of rightward-inclined curves. Tungsten minerals in quartz veins intruding the granites of crust origin have lower ΣREE (335 ppm on average). ΣY is rich relative to ΣCe and ΣCe/ΣY is relatively low (<1). The chondrite-normalized REE distribution patterns are characterized by a group of leftward-inclined curves. So the REE distribution patterns can be used to discriminate the sources of rock-and ore-forming materials and the genetic types of W deposits so as to provide clues to ore prospecting.  相似文献   

2.
More than 600 specimens of ∼3.5 Ga-old hydrothermal silica dikes from the North Pole area, Pilbara craton, Western Australia, have been studied petrographically. The kerogens in 44 samples have been analyzed isotopically (C and N) and chemically (C, N, and H). The silica dikes are composed mainly of fine-grained silica (modal abundance: >97%) and are classified into two types by minor mineral assemblages: B(black)-type and G(gray)-type. The B-type silica dikes contain kerogen (0.37 to 6.72 mgC/g; average 2.44 mgC/g, n = 21) and disseminated sulfides, dominantly pyrite and Fe-poor sphalerite. In some cases, carbonate and apatite are also present. Their silica-dominated and sulfide-poor mineral assemblages suggest precipitation from low-temperature reducing hydrothermal fluid (likely 100-200°C). On the other hand, the G-type silica dikes are sulfide-free and concentrations of kerogen are relatively low (0.05 to 0.41 mgC/g; average 0.17 mgC/g, n = 13). They typically contain Fe-oxide (mainly hematite) which commonly replaces cubic pyrite and rhombic carbonate. Some G-types occur along secondary quartz veins. These textures indicate that the G-type silica dikes were formed by postdepositional metasomatism (oxidation) of the B-types, and that the B-types probably possess premetasomatic signatures. The δ13C values of kerogen in the B-types are −38.1 to −33.1‰ (average −35.9‰, n = 21), which are ∼4‰ lower than those of the G-types (−34.5 to −30.0‰; average −32.2‰, n = 19), and ∼6‰ lower than bedded chert (−31.2 to −29.4‰; average −30.5‰, n = 4). This indicates the preferential loss of 12C during the metasomatism (estimated fractionation factor: 0.9985). Considering the metasomatic effect on carbon isotopes with probably minor diagenetic and metamorphic overprints, we conclude that the original δ13C values of the kerogen in the silica dikes would have been heterogeneous (∼5‰) and at least some material had initial δ13C values of ≤ −38‰. The inferred 13C-depletions of organic carbon could have been produced by anaerobic chemoautotrophs such as methanogen, but not by aerobic photoautotrophs. This is consistent with the estimated physical and chemical condition of the hydrothermal fluid, which was probably habitable for anaerobic and thermophilic/hyperthermophilic chemoautotrophs. Alternatively, the organic matter may have been possibly produced by abiological reaction such as Fischer-Tropsch Type (FTT) synthesis under the hydrothermal condition. However, the estimated condition is inconsistent with the presence of the effective catalysts for the FTT reaction (i.e., Fe-Ni alloy, magnetite, and hematite). These lines of evidence suggest the possible existence of biosphere in the ∼3.5 Ga sub-seafloor hydrothermal system.  相似文献   

3.
GOSCOMBE  BEN 《Journal of Petrology》1992,33(4):917-962
The poly-metamorphic evolution of the Strangways Range granulitesof central Australia has been constrained by the phase stabilityrelationships of silica-saturated aluminous gneisses in KFMASH,in conjunction with geothermobarometry and equilibrium thermodynamics.Two contrasting, but overlapping, P-T paths are proposed. Thefirst (M1, at 1800 Ma) had an ‘anticlockwise’ P-Tpath (i.e., increasing P/T with time) and was terminated byisobaric cooling from 850–950 C, at 8–9 kb, toa stable crustal geotherm (<700C). In contrast, the secondgranulite metamorphism (M2–M5, suggested to be at 1400–1500Ma; Goscombe, 1992a) followed a ‘clockwise’ P-Tpath(i.e., decreasing P/T with time) terminated by decompressionand cooling to {small tilde}6–7 kb on a stable crustalgeotherm. M2–M5 occurred during reworking of M, granulitesby compressional orogenesis (Goscombe, 1992a). Initially, loadingand prograde metamorphism accompanied non-coaxial ductile shearand fold repetition (D2–D3). Prograde metamorphism wasfollowed by uplift and retrogression accompanying oblique transpressionand shear zone development while still under compression (D4–D5)(Goscombe, 1992a). The poly-metamorphic evolution indicatesthat ductile deformation reworked the M1 granulites in an orogenicepisode unrelated, both temporally and tectonically, to M1,metamorphism (Goscombe, 1992b).  相似文献   

4.
Li behaviour and distribution in the mantle were investigated by ion microprobe in situ measurements on co-existing olivine (ol), orthopyroxene (opx), clinopyroxene (cpx) and amphibole (amp) in xenoliths from the French Massif Central. The fertile spinel lherzolites of this study record increasing degrees of mantle metasomatism, from unmetasomatised anhydrous samples through cryptically metasomatised samples to highly metasomatised amphibole-rich samples. In anhydrous lherzolites, Li is preferentially incorporated into olivine (1.1-1.4 ppm, average values) compared to pyroxenes (0.2-0.9 ppm). The hydrous samples clearly show enrichment of Li in ol (1.5-5.0 ppm), opx (1.1-2.4 ppm) and cpx (2.4-5.4 ppm), while amphibole incorporates less Li than the co-existing phases (0.8-1.3 ppm). Average δ7Li values range from +7.6 to +14.5‰ in ol, from 5.1 to +13.7‰ in opx and from 8.8 to +10.3‰ in cpx from the anhydrous lherzolites. A layered peridotite sample (Sdi) shows higher Li content in all phases, with lighter isotopic composition in opx and cpx (−0.6 and −2‰ average δ7Li values, respectively). In the hydrous lherzolites average δ7Li values both overlap and extend beyond these ranges in ol (up to 17.5 ‰) and in opx (up to 22.9‰), and vary widely in cpx (−2.7 to +9.7‰). Low δ7Li values are observed in some opx (−10.4‰) and cpx (−13‰) from sample Sdi, and in cpx from three hydrous samples (from −9.7 to −5.3‰). The different anhydrous phases from the hydrous samples show large intra-grain variations in Li isotopic ratios (e.g., up to 18‰) compared to the same phases from the anhydrous samples (mostly less than 6‰), excepting sample Sdi which has up to 20.4‰ variation in cpx. Similar to the anhydrous silicates, amphiboles show a wide variation of δ7Li values on the intra-grain scale (2-27‰). These variations are interpreted to result from fractionation processes during metasomatism by a silicate melt undergoing compositional changes as it percolates through and reacts with the peridotite phases. Thus Li abundances and isotopic in situ measurements are useful for tracing metasomatic processes but the heterogeneities observed in the samples preclude any identification of a specific mantle source by its Li signature.  相似文献   

5.
The Rio de La Plata craton in Argentina (Azul and Tandil regions)is characterized by Early Proterozoic (2·0 Ga) calc-alkalineand Middle Proterozoic (1·6 Ga) tholeiitic dyke swarmsintruding the crystalline basement involved in the TransamazonianOrogeny (2·2–1·9 Ga). The calc-alkalinedykes have andesitic and rhyolitic compositions and trend east–west,whereas the tholeiitic dykes mainly trend N30°W and arerepresented by basalts with low (0·9–1·7wt %) and high TiO2 (up to 3·7 wt %). The calc-alkalinedykes have primitive mantle (PM)-normalized trace element patternsenriched in Rb, Ba, K, La, Ce and Nd, and significant negativeNb and Ti anomalies. These dykes are characterized by  相似文献   

6.
Heavy metal pollution and their fractionations in the sediments of Changjiang River in Nanjing Reach was monitored for cadmium (Cd), lead (Pb), zinc (Zn), chromium (Cr), and copper (Cu). Moreover, the biological enrichment of metals by riverine plants was studied. The results demonstrated there were highly significant variations among different sampling stations for the concentrations of tested metals. The highest range was for Cu (38.8–120.4 mg kg−1), followed by Cr (74.4–120.0 mg kg−1), Zn (80.9–121.1 mg kg−1), Ni (26.0–55.5 mg kg−1), Pb (15.8–46.7 mg kg−1) and Cd (0.28–0.48 mg kg−1). Cd was the element with highest biological enrichment factor (BEF). The highest BEF of Cd in Erigeron bonariensis reached 3.0, indicating a significant Cd enrichment in this aquatic plant. In addition, 60% of Cd was found in reducible fraction and exchangeable and acid-soluble fraction, which was consistent with its high mobility. The consistency of Cd fraction in sediment and suspended particle indicated they came from the same source. Accumulated Cd concentration calculated according to the release curve showed significant relativity with the total Cd concentration in the sediment.  相似文献   

7.
Laguna de la Leche, north coastal Cuba, is a shallow (≤ 3 m), oligohaline (∼ 2.0-4.5‰) coastal lake surrounded by mangroves and cattail stands. A 227-cm core was studied using loss-on-ignition, pollen, calcareous microfossils, and plant macrofossils. From ∼6200 to ∼ 4800 cal yr BP, the area was an oligohaline lake. The period from ∼ 4800 to ∼ 4200 cal yr BP saw higher water levels and a freshened system; these changes are indicated by an increase in the regional pollen rain, as well as by the presence of charophyte oogonia and an increase in freshwater gastropods (Hydrobiidae). By ∼ 4000 cal yr BP, an open mesohaline lagoon had formed; an increase in salt-tolerant foraminifers suggests that water level increase was driven by relative sea level rise. The initiation of Laguna de la Leche correlates with a shift to wetter conditions as indicated in pollen records from the southeastern United States (e.g., Lake Tulane). This synchronicity suggests that sea level rise caused middle Holocene environmental change region-wide. Two other cores sampled from mangrove swamps in the vicinity of Laguna de la Leche indicate that a major expansion of mangroves was underway by ∼ 1700 cal yr BP.  相似文献   

8.
REE studies of apatites in two series of granites, including more than ten types of rock and several tens of rock masses in eight provinces of South China permit us to come to some new understanding and hence the following conclusions have been drawn. Apatites in granites of different series show significant differences in REE distribution pattern, probably due to different material sources. Therefore, REE partition characteristics can be used to discriminate granites of different sources. Apatite in granite of the Nanling series (of shallow-seated source) has a lower content ofΣ REE (4571 ppm on average). Y is the highest of the REE group.Σ Y is rich relative toΣ Ce, thus giving rise to relatively lowΣCe/ΣY ratio (0.68 on average). Eu shows strong depletion, andδ Eu is extremely low (0.135 on average). The REE distribution patterns are represented by a group of “V”-shaped symmetric curves. Apatite in granites of the Yangtze series are relatively high inΣ REE (8571.3 ppm on average). Ce is the highest of the REE. group.Σ Ce is rich relative toΣ Y and theΣCe/ΣY is relatively high (7.15 on average). The chondrite-normalized REE distribution patterns are characterized by a group of rightward-inclined curves.  相似文献   

9.
The aim of this interdisciplinary study is to examine a component of the hydrological cycle in Galapagos by characterizing soil properties. Nine soil profiles were sampled on two islands. Their physical and hydrodynamic properties were analyzed, along with their mineralogical composition. Two groups of soils were identified, with major differences between them. The first group consists of soils located in the highlands (>350 m a.s.l.), characterized by low hydraulic conductivity (<10−5 m s−1) and low porosity (<25%). These soils are thick (several meters) and homogeneous without coarse components. Their clay fraction is considerable and dominated by gibbsite. The second group includes soils located in the low parts of the islands (<300 m a.s.l.). These soils are characterized by high hydraulic conductivity (>10−3 m s−1) and high porosity (>35%). The structure of these soils is heterogeneous and includes coarse materials. The physical properties of the soils are in good agreement with the variations of the rainfall according to the elevation, which appears as the main factor controlling the soil development. The clayey alteration products constrain soils physical and hydrodynamic properties by reducing the porosity and consequently the permeability and also by increasing water retention.  相似文献   

10.
We present a detailed mineralogical, petrological and melt inclusion study of unusually fresh, primitive olivine + clinopyroxene phyric Lower Pillow Lavas (LPL) found near Analiondas village in the northeastern part of the Troodos ophiolite (Cyprus). Olivine phenocrysts in these primitive LPL show a wide compositional range (Fo82–92) and have higher CaO contents than those from the Upper Pillow Lavas (UPL). Cr-spinel inclusions in olivine are significantly less Cr-rich (Cr/Cr + Al = 28–67 mol%) compared to those from the UPL (Cr# = 70–80). These features reflect differences in melt compositions between primitive LPL and the UPL, namely higher CaO and Al2O3 and lower FeO* compared to the UPL at a given MgO. LPL parental melts (in equilibrium with Fo92) had ∼10.5 wt% MgO and crystallization temperatures ∼1210 °C, which are significantly lower than those previously published for the UPL (14–15 wt% MgO and ∼1300 °C for Fo92). The fractionation path of LPL parental melts is also different from that of the UPL. It is characterized initially by olivine + clinopyroxene cotectic crystallization joined by plagioclase at ∼9 wt% MgO, whereas UPL parental melts experienced a substantial interval of olivine-only crystallization. Primitive LPL melts were formed from a mantle source which was more fertile than that of tholeiites from well-developed intra-oceanic arcs, but broadly similar in its fertility to that of Mid-Ocean Ridge Basalt (MORB) and Back Arc Basin Basalts (BABB). The higher degrees of melting during formation of the LPL primary melts compared to average MORB were caused by the presence of subduction-related components (H2O). Our new data on the LPL coupled with existing data for the UPL support the existing idea that the LPL and UPL primary melts originated from distinct mantle sources, which cannot be related by progressive source depletion. Temperature differences between these sources (∼150 °C), their position in the mantle (∼10 kbar for the colder LPL source vs 15–18 kbar for the UPL source), and temporal succession of Troodos volcanism, all cannot be reconciled in the framework of existing models of mantle wedge processes, thermal structure and evolution, if a single mantle source is invoked. Possible tectonic settings for the origin of the Troodos ophiolite (forearc regions of intra-oceanic island arc, propagation of backarc spreading into arc lithosphere) are discussed. Received: 20 May 1996 / Accepted: 25 March 1997  相似文献   

11.
A detailed oxygen isotope study of detrital quartz and authigenic quartz overgrowths from shallowly buried (<1 km) quartz arenites of the St. Peter Sandstone (in SW Wisconsin) constrains temperature and fluid sources during diagenesis. Quartz overgrowths are syntaxial (optically continuous) and show complex luminescent zonation by cathodoluminescence. Detrital quartz grains were separated from 53 rocks and analyzed for oxygen isotope ratio by laser fluorination, resulting in an average δ18O of 10.0 ± 0.2‰ (1SD, n = 109). Twelve thin sections were analyzed by CAMECA-1280 ion microprobe (6-10 μm spot size, analytical precision better than ±0.2‰, 1SD). Detrital quartz grains have an average δ18O of 10.0 ± 1.4‰ (1SD, n = 91) identical to the data obtained by laser fluorination. The ion microprobe data reveal true variability that is otherwise lost by homogenization of powdered samples necessary for laser fluorination. Laser fluorination uses samples that are one million times larger than the ion microprobe. Whole rock (WR) samples from the 53 rocks were analyzed by laser fluorination, giving δ18O between 9.8‰ and 16.7‰ (n = 110). Quartz overgrowths in thin sections from 10 rocks were analyzed by ion microprobe and average δ18O = 29.3 ± 1.0‰ (1SD, n = 161).Given the similarity, on average, of δ18O for all detrital quartz grains and for all quartz overgrowths, samples with higher δ18O(WR) values can be shown to have more cement. The quartz cement in the 53 rocks, calculated by mass balance, varies from <1 to 21 vol.% cement, with one outlier at 33 vol.% cement. Eolian samples have an average of 11% cement compared to marine samples, which average 4% cement.Two models for quartz cementation have been investigated: high temperature (50-110 °C) formation from ore-forming brines related to Mississippi Valley Type (MVT) mineralization and formation as silcretes at low temperature (10-30 °C). The homogeneity of δ18O for quartz overgrowths determined by ion microprobe rules out a systematic regional variation of temperature as predicted for MVT brines and there are no other known heating events in these sediments that were never buried to depths >1 km. The data in this study suggest that quartz overgrowths formed as silcretes in the St. Peter Sandstone from meteoric water with δ18O values of −10‰ to −5‰ at 10-30 °C. This interpretation runs counter to conventional wisdom based on fibrous or opaline silica cements suggesting that the formation of syntaxial quartz overgrowths requires higher temperatures. While metastable silica cements commonly form at high degrees of silica oversaturation following rapid break-down reactions of materials such as of feldspars or glass, the weathering of a clean quartz arenite is slower facilitating chemical equilibrium and precipitation of crystallographically oriented overgrowths of α-quartz.  相似文献   

12.
The aim of this study was to design and test a new tool for (i) the quantitative in situ monitoring of Fe(III) reduction in soils and (ii) the tracking of the potential mineralogical changes of Fe-oxides. The tool consists of small (2 × 2 × 0.2 cm) striated polymer plates coated with synthetic pure ferrihydrite or As-doped ferrihydrite (Fh–As). These slides were then inserted within two different horizons (organo-mineral and albic) located in a wetland soil with alternating redox conditions. Dissolution was quantified by X-ray fluorescence (XRF) analyses of total metal contents before and after insertion into the soil. The crystallographic evolution of Fe-oxides was characterized by scanning electron microscope equipped with an energy-dispersive spectrometer (SEM–EDS). Over the months, the ferrihydrite progressively disappeared, at rates comparable to those previously measured in laboratory studies, i.e. in the 1–10 × 10−12 mol Fe m−2 s−1 range. SEM observations indicate that the supports were highly colonized by bacteria and biofilms in the organo-mineral horizon, suggesting a biological-mediated process, while the albic horizon appeared to be characterized by a mostly chemical-mediated process. In the albic horizon, Fe-sulphide and other micro-precipitates were formed after 7 months of incubation in balance with a quasi dissolution of initial Fe-oxides.  相似文献   

13.
Mercier's thermobarometer (Mercier 1980) and Saxena's thermometer (Dal Negro et al. 1982) were applied to single pyroxenes of both porphyroclastic (PF) and protogranular (PR) spinel peridotitic nodules enclosed in alkaline products related to necks of North-Eastern Brazil. Intercrystalline temperatures obtained using both orthopyroxene (opx) and clinopyroxene (cpx) compositions were in agreement, and were lower in protogranular than in porphyroclastic nodules (1051±57 and 1266±19°C respectively). In contrast, pressure estimates using cpx and opx were conflicting, in particular as regards PF nodules. In fact for PF nodules cpx compositions point to 27–32 kbar (mean 29±2) whereas opx compositions point to 17–19 kbar (mean 18±1). Conversely, PR nodule cpx and opx compositions point to similar values 17–24 and 15–18 kbar respectively (mean 19±4). The result obtained for PF nodules using cpx composition clearly contrasts with petrographic evidence and it is due to the peculiar composition of PF cpx (e.g. low Ca content, from 0.645 to 0.737 atoms per formula unit, a.f.u.) that strongly affects the barometric formulation. The PR and PF cpxs reveal similar mean intracrystalline temperature estimates (712±112 and 778±217°C, respectively). These, considering the difference of about 200°C in the intercrystalline temperature estimates, indicate that the exchange cation reaction between the M1 and M2 sites was a faster process in PF than in PR cpx, favoured by the low Ca content of PF cpx. Thus alternatively, the composition of PF cpx, characterized by a high rate of Ca » Mg substitution in the M2 site, may not affect the intercrystalline temperature. Therefore the difference of about 200°C found in intercrystalline temperatures between PR and PF cpxs, in spite of their same pressure values, may be interpreted as indicating an anomalous temperature gradient in the region.  相似文献   

14.
Thermally metamorphosed Tertiary age coals from Tanjung Enim in South Sumatra Basin have been investigated by means of petrographic, mineralogical and chemical analyses. These coals were influenced by heat from an andesitic igneous intrusion. The original coal outside the metamorphosed zone is characterized by high moisture content (4.13–11.25 wt.%) and volatile matter content (> 40 wt.%, daf), as well as less than 80 wt.% (daf) carbon and low vitrinite reflectance (VRmax = 0.52–0.76%). Those coals are of subbituminous and high volatile bituminous rank. In contrast the thermally metamorphosed coals are of medium-volatile bituminous to meta-anthracite rank and characterized by low moisture content (only < 3 wt.%) and volatile matter content (< 24 wt.%, daf), as well as high carbon content (> 80 wt.%, daf) and vitrinite reflectance (VRmax = 1.87–6.20%). All the studied coals have a low mineral matter content, except for those which are highly metamorphosed, due to the formation of new minerals.The coalification path of each maceral shows that vitrinite, liptinite and inertinite reflectance converge in a transition zone at VRmax of around 1.5%. Significant decrease of volatile matter occurs in the zone between 0.5% and 2.0% VRmax. A sharp bend occurs at VRmax between 2.0% and 2.5%. Above 2.5%, the volatile matter decreases only very slightly. Between VRr = 0.5% and 2.0%, the carbon content of the coals is ascending drastically. Above 2.5% VRr, the carbon content becomes relatively stable (around 95 wt.%, daf).Vitrinite is the most abundant maceral in low rank coal (69.6–86.2 vol.%). Liptinite and inertinite are minor constituents. In the high rank coal, the thermally altered vitrinite composes 82.4–93.8 vol.%. Mosaic structures can be recognized as groundmasss and crack fillings. The most common minerals found are carbonates, pyrite or marcasite and clay minerals. The latter consist of kaolinite in low rank coal and illite and rectorite in high rank coal. Change of functional groups with rank increase is reflected most of all by the increase of the ratio of aromatic C–H to aliphatic C–H absorbances based on FTIR analysis. The Oxygen Index values of all studied coals are low (OI < 5 mg CO2/g TOC) and the high rank coals have a lower Hydrogen Index (< 130 mg HC/g TOC) than the low rank coals (about 300 mg HC/g TOC). Tmax increases with maturity (420–440 °C for low rank coals and 475–551 °C for high rank coals).Based on the above data, it was calculated that the temperature of contact metamorphism reached 700–750 °C in the most metamorphosed coal.  相似文献   

15.
We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca2+ and Mg2+) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 104 to 3.2 × 106 M−1 s−1. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater.  相似文献   

16.
The effect of sulfur on the sorption of gold by carbonaceous matter (CM) was investigated under hydrothermal conditions (200–400°C and 1 kbar) using the autoclave-ampoule method. The model CM was represented by asphaltenes fractionated from the lignite of the Pavlovskoe coal field. The source of gold was the walls of the Au container, which were dissolved in water under the experimental conditions. Sulfur was added as finely ground pyrite (C-S-Fe-O-H-Au system) or elemental sulfur powder (C-S-O-H-Au system). The contents of Au were measured by atomic absorption spectrometry with electrothermal atomization in quenched aqueous solutions (WF), soluble organic fraction (SF), and insoluble residue (kerogen). The lowest Au concentration was detected in the WF, −8.96 < logmAu < −6.32. The Au concentration is higher in the SF (−5.02 < logmAu < −4.34) and increases by more then an order of magnitude in the kerogen, −3.94 < logmAu < −2.33. The IR spectra of the experimental products showed that sulfur was accumulated in the kerogen, whereas no C-S functional groups were observed in the SF. This is the reason for the negligible influence of sulfur in this system on Au concentration in the SF. The maximum Au concentration was detected in the kerogen in the presence of pyrite, which was transformed into pyrrhotite at 400°C. Thus, iron sulfides promote Au uptake by kerogen from ore-bearing hydrothermal fluids.  相似文献   

17.
In the present study sediment and water samples collected from Kowsar Dam reservoir in Kohkiluye and Boyerahmad Province, southwest of Iran, are subjected to bulk digestion and chemical partitioning. The concentrations of nickel, lead, zinc, copper, cobalt, cadmium, manganese and iron in water and bed sediment were determined by atomic absorption spectrometry. The concentrations of metals bounded to five sedimentary phases were estimated. On this basis, the proportions of natural and anthropogenic elements were calculated.The anthropogenic portion of elements are as follows: zinc (96 %)> cobalt (88 %)> iron (78 %)> magnesium (78 %)> nickel (78 %)> copper (66 %)> lead (63 %)> cadmium (59 %). The results show sediment contamination by nickel, cadmium and lead, according to the world aquatic sediments and mean earth crust values. Manganese and copper have strong association with organic matter and are of high portion of sulfide bounded ions. Finally, The degree of sediment contamination was evaluated using enrichment factor, geo-accumulation index (Igeo) and pollution index (IPoll). The sediments were identified to be of high cadmium and lead pollution index. The pattern of pollution intensity according to enrichment factor is as follows; manganese (1.25) < copper (1.63) < zinc (1.93) < cobalt (2.35) < nickel (3.83) < lead (12.63) < cadmium (78.32). Cluster analysis was performed in order to assess heavy metal interactions between water and sediment. Accordingly, nickel, cadmium and copper are earth originated. Zinc, copper and manganese are dominated by pH. All the elemental concentrations in water and sediment are correlated except for sedimental copper.  相似文献   

18.
We present Cu isotope data of hypogene and supergene minerals from the Late Paleocene Spence Cu-Mo porphyry in the Atacama Desert of northern Chile. Chalcopyrite displays a restricted range of δ65Cu values within the values reported for primary porphyry Cu sulfides (+ 0.28‰ to + 0.34‰, n = 6). Supergene chalcocite samples show heavier and remarkably homogeneous δ65Cu values, between + 3.91‰ and + 3.95‰ (n = 6), consistent with previous models of Cu leaching and enrichment in porphyry systems. Secondary Cu minerals from the oxide zone show a wider range of composition, varying from + 1.28‰ and + 1.37‰ for chrysocolla (n = 6) to very light Cu isotope signatures reported for atacamite between -5.72‰ to -6.77‰ (n = 17). These data suggest redox cycling of Cu during supergene enrichment of the Spence Cu deposit, characterized by a first stage of supergene chalcocite formation from acidic, isotopically-heavy leach fluids of meteoric origin down-flowing in a semi-arid climate (44 to ~ 15-9 Ma). Reworking of the initial supergene copper assemblage, during the Pleistocene, by rising neutral and chlorine-rich deep formation waters under well-established hyper-arid climate conditions lead to the formation of atacamite with extremely fractionated Cu compositions. Essentially coeval chrysocolla formed by dissolution of atacamite during short episodes of wetter climatic conditions occurring in the latest Pleistocene.  相似文献   

19.
Nitrogen addition to soil can play a vital role in influencing the losses of soil carbon by respiration in N-deficient terrestrial ecosystems. The aim of this study was to clarify the effects of different levels of nitrogen fertilization (HN, 200 kg N ha−1 year−1; MN, 100 kg N ha−1 year−1; LN, 50 kg N ha−1 year−1) on soil respiration compared with non-fertilization (CK, 0 kg N ha−1 year−1), from July 2007 to September 2008, in temperate grassland in Inner Mongolia, China. Results showed that N fertilization did not change the seasonal patterns of soil respiration, which were mainly controlled by soil heat-water conditions. However, N fertilization could change the relationships between soil respiration and soil temperature, and water regimes. Soil respiration dependence on soil moisture was increased by N fertilization, and the soil temperature sensitivity was similar in the treatments of HN, LN, and CK treatments (Q 10 varied within 1.70–1.74) but was slightly reduced in MN treatment (Q 10 = 1.63). N fertilization increased soil CO2 emission in the order MN > HN > LN compared with the CK treatment. The positive effects reached a significant level for HN and MN (P < 0.05) and reached a marginally significant level for LN (P = 0.059 < 0.1) based on the cumulative soil respiration during the 2007 growing season after fertilization (July–September 2007). Furthermore, the differences between the three fertilization treatments and CK reached the very significant level of 0.01 on the basis of the data during the first entire year after fertilization (July 2007–June 2008). The annual total soil respiration was 53, 57, and 24% higher than in the CK plots (465 g m−2 year−1). However, the positive effects did not reach the significant level for any treatment in the 2008 growing season after the second year fertilization (July–September 2008, P > 0.05). The pairwise differences between the three N-level treatments were not significant in either year (P > 0.05).  相似文献   

20.
The topographic evolution of the “passive” margins of the North Atlantic during the last 65 Myr is the subject of extensive debate due to inherent limitations of the geological, geomorphological and geophysical methods used for studies of uplift and subsidence. We have compiled a database of sign, time and amplitude (where possible) of topographic changes in the North Atlantic region during the Cenozoic (65–0 Ma). Our compilation is based on published results from reflection seismic studies, AFT (apatite fission track) studies, VR (vitrinite reflectance) trends, maximum burial, sediment supply studies, mass balance calculations and extrapolation of seismic profiles to onshore geomorphological features. The integration of about 200 published results reveal a clear pattern of topographic changes in the North Atlantic region during the Cenozoic: (1) The first major phase of Cenozoic regional uplift occurred in the late Palaeocene–early Eocene (ca 60–50 Ma), probably related to the break-up of the North Atlantic between Europe and Greenland, as indicated by the northward propagation of uplift. It was preceded by middle Palaeocene uplift and over-deepening of some basins of the North Sea and the surrounding areas. (2) A regional increase in subsidence in the offshore marginal areas of Norway, the northern North Sea, the northern British Isles and west Greenland took place in the Eocene (ca 57–35 Ma). (3) The Oligocene and Miocene (35–5 Ma) were characterized by regional tectonic quiescence, with only localised uplift, probably related to changes in plate dynamics. (4) The second major phase of regional uplift that affected all marginal areas of the North Atlantic occurred in the Plio-Pleistocene (5–0 Ma). Its amplitude was enhanced by erosion-driven glacio-isostatic compensation. Despite inconclusive evidence, this phase is likely to be ongoing at present.  相似文献   

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