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1.
The occurrence of submarine groundwater discharge (SGD) as well as its supply of many nutrients and metals to coastal seawaters is now generally known. However, previous studies have focused on the chemical and radiological analysis of groundwater, surface seawater, shallow marine sediments and their pore waters, as well as the measurement of upward flow through the marine sediments, as end members of the discharge process. In this study, chemical and isotopic analysis results of marine subsurface waters are reported. These were obtained from deep boreholes of an undersea liquefied petroleum gas (LPG) storage cavern, located about 8 km off the western coast of Korea. The cavern is about 130–150 m below the sea bottom, which is covered by a 4.8–19.5 m silty clay stratum. An isotopic composition (δ2H and δ18O) of the marine subsurface waters falls on a mixing line between terrestrial groundwater and seawater. Vertical EC profiling at the cavern boreholes revealed the existence of a fresh water zone. An increase in the contents of ferrous iron and manganese and a decrease in levels of nitrate, bicarbonate and cavern seepage were recorded in August 2006, indicating a decreased submarine groundwater flux originating from land, mainly caused by an elevated cavern gas pressure. It is suggested in this study that the main source of fresh waters in the man-made undersea cavern is the submarine groundwater discharge mainly originating from the land.  相似文献   

2.
There are many factors affecting submarine groundwater discharge (SGD). However, systematic study of the influences of these factors is still limited. In this study, numerical modeling is performed to quantitatively explore the influences of various factors on SGD in a coastal aquifer. In such locations, tidal and terrestrial hydraulic gradients are the primary forces driving fresh and salt water movement. Unlike steady-state flow, dynamic fresh and salt water mixing at the near-shore seafloor may form an intertidal mixing zone (IMZ) near the surface. By constructing a general SGD model, the effects of various model components such as boundary conditions, model geometry and hydraulic parameters are systematically studied. Several important findings are obtained from the study results: (1) Previous studies have indicated there will be a freshwater discharge tube between the classic transition zone and the IMZ. However, this phenomenon may become unclear with the increase of heterogeneity and anisotropy of the medium’s conductivity field. (2) SGD and IMZ are both more sensitive to the vertical anisotropy ratio of hydraulic conductivity (Kx/Kz) than to the horizontal ratio (Kx/Ky). (3) Heterogeneity of effective porosity significantly affects SGD and IMZ. (4) Increase of the storage coefficient decreases fresh water discharge but increases mixing salt water discharge and total SGD. The increase will also change the shape of the IMZ. (5) Variation of dispersivities does not affect SGD, but significantly changes the distributions of the IMZ and the whole mixing zone. These findings will be helpful to the sampling design of field studies of SGD and to the application of dynamic SGD models to field sites for model development and calibration.  相似文献   

3.
A large quantity of submarine groundwater discharge (SGD) of about 1000 m3 day?1 m?1 of the 600‐km‐long shoreline of South Atlantic Bight has been estimated by Moore (Global Biogeochemical Cycles, 2010b, 24, GB4005, doi: 10.1029/2009GB003747 ). However, there is great uncertainty in estimating the percentage of net, land‐originated groundwater recharge of SGD. Moreover, most previous studies considered the homogeneous case for the coastal superficial aquifers. Here, we investigated the terrestrial‐originated SGD through a multilayered submarine aquifer system, which comprises two confined aquifers and two semi‐permeable layers. The inland recharge includes a constant part representing the annual average and a periodical part representing its seasonal variation. An analytical solution was derived and used to analyse the distributions of the terrestrial‐originated SGD from the multilayered aquifers along the Winyah Bay transect, South Atlantic Bight. It is found that the width of the zone of SGD from the upper aquifer ranges from ~0.8 to ~8.0 km depending on the leakance of the seabed semi‐permeable layer. A head of the upper aquifer at a coastline 1.0 m higher than the mean sea level will cause a SGD of 1.82– 18.3 m3 day?1 m?1 from that aquifer as the seabed semi‐permeable layer's leakance varies from 0.001 to 0.1 day?1, providing considerable possibility for considerable land‐originated SGD. Seasonal terrestrial‐originated SGD variations predicted by the analytical model provide consistent explanation of the seasonal variation of 226Ra observed by Moore (Journal of Geophysics, 2007, 112, C10013, doi: 10.1029/2007JC004199 ). The contribution of the lower aquifer to SGD is only 1.2–12% of that of the upper aquifer. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

4.
Submarine groundwater discharge (SGD) is a global phenomenon that carries large volumes of groundwater and dissolved chemical species such as nutrient, metals, and organic compounds to coastal zones. We report the influence of SGD on the coastal waters of Jeju Island, Korea, using high‐resolution aerial thermal infrared (TIR) mapping techniques and field investigations. An aircraft‐based system was implemented using a cost‐effective TIR camera for aerial TIR mapping. Ground‐based calibrations and system integration with GPS/IMU (global positioning system/inertial measurement unit) were performed for the aerial systems. The aerial surveys showed distinct low‐temperature signatures of SGD along the coasts of Jeju Island, revealing large groundwater inputs from the coastal aquifers to the ocean. Multiple aerial surveys over a range of seasons and tidal stages revealed that SGD rates dynamically affect the sea surface temperature (SST) of the coastal zone. The in‐situ measurements supported that SGD has a substantial influence on the coastal water chemistry as well as SST. Our observations highlight the extent to which aerial‐based TIR mapping can serve as a powerful tool for studying SGD and other coastal processes. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

5.
Reliable estimation of the timescales of seawater retreat (SWR) in coastal aquifers has significant implications for sustainable groundwater management in coastal areas. Due to the complexity of coastal dynamics, analytical estimates of SWR timescales are limited in number, and numerical models are mainly utilized. Although numerical models allow for accurate analysis of the coastal systems, they concern particular aquifer cases, thus their results are not generally applicable. Here, we perform a dimensional analysis for the depth-integrated freshwater/seawater continuity equations and identify the dimensionless parameters that affect SWR in confined, homogeneous and flux-controlled aquifers. Based on numerical simulations, we gain insight into how these parameters affect SWR, and produce type curves which can be used as a simple tool for estimating SWR timescales in idealized coastal systems, independent of the hydraulic and geometric characteristics of the aquifer. The reliability of our estimates in real-world applications is also discussed.  相似文献   

6.
Caffeine, a biologically active drug, is recognized as a contaminant of freshwater and marine systems. We quantified caffeine concentrations in Oregon's coastal ocean to determine whether levels correlated with proximity to caffeine pollution sources. Caffeine was analyzed at 14 coastal locations, stratified between populated areas with sources of caffeine pollution and sparsely populated areas with no major caffeine pollution sources. Caffeine concentrations were measured in major water bodies discharging near sampling locations. Caffeine in seawater ranged from below the reporting limit (8.5 ng/L) to 44.7 ng/L. Caffeine occurrence and concentrations in seawater did not correspond with pollution threats from population density and point and non-point sources, but did correspond with storm event occurrence. Caffeine concentrations in rivers and estuaries draining to the coast ranged from below the reporting limit to 152.2 ng/L. This study establishes the occurrence of caffeine in Oregon's coastal waters, yet relative importance of sources, seasonal variability, and processes affecting caffeine transport into the coastal ocean require further research.  相似文献   

7.
The distinctly different, εNd(0) values of the Atlantic, Indian, and Pacific Oceans requires that the residence time of Nd in the ocean (i.e., τNd) be on the order of, or less than, the ocean mixing time of ∼ 500–1500 yr. However, estimates of τNd, based on river influxes, range from 4000 to 15,000 yr, thus exceeding the ocean mixing time. In order to reconcile the oceanic Nd budget and lower the residence time by roughly a factor of 10, an additional, as yet unidentified, and hence “missing Nd flux” to the ocean is necessary. Dissolution of materials deposited on continental margins has previously been proposed as a source of the missing flux. In this contribution, submarine groundwater discharge (SGD) is examined as a possible source of the missing Nd flux. Neodymium concentrations (n = 730) and εNd(0) values (n = 58) for groundwaters were obtained from the literature in order to establish representative groundwater values. Mean groundwater Nd concentrations and εNd(0) values were used along with recent estimates of the terrestrial (freshwater) component of SGD (6% of river discharge on a global basis) to test whether groundwater discharge to the coastal oceans could account for the missing flux. Employing mean Nd concentrations of the compiled data base (i.e., 31.8 nmol/kg for all 730 analyses and 11.3 nmol/kg for 141 groundwater samples from a coastal aquifer), the global, terrestrial-derived SGD flux of Nd is estimated to range between 2.9 × 107 and 8.1 × 107 mol/yr. These estimates are of the same order of magnitude, and within a factor of 2, of the missing Nd flux (i.e., 5.4 × 107 mol/yr). Applying the SGD Nd flux estimates, the global average εNd(0) of SGD is predicted to be − 9.1, which is similar to our estimate for the missing Nd flux (− 9.2), and in agreement with the mean (± S.D.) εNd(0) measured in groundwaters (i.e., εNd(0) = −8.9 ± 4.2). The similarities in the estimated SGD Nd flux and corresponding εNd(0) values to the magnitude and isotope composition of the missing Nd flux are compelling, and suggest that discharge of groundwater to the oceans could account for the missing Nd flux. Future investigations should focus on quantifying the Nd concentrations and isotope compositions of groundwater from coastal aquifers from a variety of coastal settings, as well as the important geochemical reactions that effect Nd concentrations in subterranean estuaries in order to better constrain contributions of SGD to the oceanic Nd budget.  相似文献   

8.
Fluxes of submarine groundwater discharge (SGD) were investigated into two tidal rivers on the north and south shore of Long Island, NY, during July 2015. Ground‐based handheld thermal infrared (TIR) imagery, combined with direct push‐point piezometer sampling, documented spatially heterogeneous small‐scale intertidal seepage zones. Pore waters were relatively fresh and enriched in nitrogen (N) within these small‐scale seeps. Pore waters sampled just 20 cm away, outside the boundary of the ground‐based TIR‐located seepage zone, were more saline and lower in N. These ground‐based TIR‐identified seeps geochemically represented the terrestrial fresh groundwater endmember, whereas N in pore waters sampled outside of the TIR‐identified seeps was derived from the remineralization of organic matter introduced into the sediment by tidal seawater infiltration. A 222Rn (radon‐222) time‐series was used to quantify fresh SGD‐associated N fluxes using the N endmembers sampled from the ground‐based TIR pore water profiles. N fluxes were up‐scaled to groundwater seepage zones identified from high‐resolution airborne TIR imagery using the two‐dimensional size of the airborne TIR surface water anomalies, relative to the N flux from the time‐series sampling location. Results suggest that the N load from the north‐shore tidal river to Long Island Sound is underrepresented by at least 1.6–3.6%, whereas the N load from SGD to a south‐shore tidal river may be up to 9% higher than previous estimates. These results demonstrate the importance of SGD in supplying nutrients to the lower reaches of tidal rivers and suggest that N loads in other tidal river environments may be underestimated if SGD is not accounted for.  相似文献   

9.
This article investigates the quantity of submarine groundwater discharge (SGD) from a coastal multi‐layered aquifer system in response to constant rainfall infiltration. The system comprises an unconfined aquifer, a leaky confined aquifer and an aquitard between them and terminates at the coastline. An approximate analytical solution is derived based on the following assumptions: (i) flow is horizontal in the aquifers and vertical in the aquitard, and (ii) flow in the unconfined aquifer is described by nonlinear Boussinesq equation. The analytical solution is compared with numerical solutions of the strictly two‐dimensional nonlinear model to validate the model assumptions used for the analytical solution. The SGD from the leaky confined aquifer increases with the inland rainfall infiltration recharge and the specific leakage of aquitard. The maximum SGD ranges from 1·87 to 10·37 m3 per day per meter of shoreline when rainfall infiltration ranges from 18·2 to 182 mm/year and the specific leakage of aquitard varies from 10?9 to 10?1 l/day. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

10.
Submarine groundwater discharge (SGD) introduces solute and nutrients to the global oceans, resulting in considerable nutrient cycling and dynamics in the coastal areas. We have conducted high‐resolution, spatio‐temporal, lunar tidal cycle patterns and variability of discharged solute/nutrient assessment to get an overview of seasonal nutrient flux to the Bay of Bengal in eastern parts of the Indian subcontinent. Whereas the premonsoon season SGD was found to be dominant in the marine influence (M‐SGD), the postmonsoon season was found to be predominated by the terrestrial component of SGD (T‐SGD), extending from coast to near offshore. The solute fluxes and redox transformation were found to be extensively influenced by tidal and diurnal cycles, overlapping on seasonal patterns. We have assessed the possible role of SGD‐associated solute/nutrient fluxes and their discharge mechanisms, and their associated temporal distributions have severe implications on the biological productivity of the Bay of Bengal. The estimated annual solute fluxes, using the average end‐member concentration of the SGD‐associated nutrients, were found to be 240 and 224 mM·m?2·day?1 for NO3? and Fetot, respectively. Together with huge freshwater flux from the Himalayan and Peninsular Indian rivers, the SGD has considerable influence on the bay water circulation, stratification, and solute cycling. Thus, the observation from this study implies that SGD‐associated nutrient flux to the Bay of Bengal may function as a nutrient sink, which might influence the long‐term solute/nutrient flux along the eastern coast of India.  相似文献   

11.
Phytoplankton community structure in coastal areas is a result of various environmental factors such as nutrients, light, grazing, temperature, and salinity. The Yucatan Peninsula is a karstic tropical region that is strongly influenced by submerged groundwater discharge (SGD) into the coastal zone. Phytoplankton community structure and its relationship with regional and local water quality variables were studied in four ports of the northwestern Yucatan Peninsula. Water quality was strongly related to SGD, and variations in phytoplankton community structure were related to local nutrient loading and hydrographic conditions, turbulence, and human impacts. Our study provides an ecological baseline for the Yucatan Peninsula and serves as a basis for establishing monitoring programs to predict changes at sites with high hydrological variation and in developing an early alert system for harmful toxic algal blooms.  相似文献   

12.
《Marine pollution bulletin》2014,78(1-2):118-129
There is a growing concern of seawater intrusion to freshwater aquifers due to groundwater overexploitation in the eastern coastal belt of Southern India. The problem becomes complex in the regions where industrial effluents are also contaminating the freshwater aquifers. In order to understand the hydrochemical complexity of the system, topographic elevation, static water level measurements, major ion chemistry, ionic cross plots, water type contours and factor analysis were applied for 144 groundwater samples of shallow and deep sources from Quaternary and Tertiary coastal aquifers, located within the industrial zone of 25 km2 area near Cuddalore, Southern India. The ionic cross plots indicates dissolution of halite minerals from marine sources and seawater mixing into inland aquifers up to the level of 9.3%. The factor analysis explains three significant factors totaling 86.3% of cumulative sample variance which includes varying contribution from marine, industrial effluent and freshwater sources.  相似文献   

13.
Coastal areas are usually the preferred place of habitation for human beings. Anthropogenic activities such as the construction of high‐rise buildings and underground transport systems usually require extensive deep foundations and ground engineering works, which may unintentionally modify the coastal groundwater system because the construction materials of foundations are usually of low hydraulic conductivity. In this paper, the impact of these building foundations on the groundwater regime is studied using hypothetical flow and transport models. Various possible realizations of foundation distributions are generated using stochastic parameters derived from a topographical map of an actual coastal area in Hong Kong. The effective hydraulic conductivity is first calculated for different realizations and the results show that the effective hydraulic conductivity can be reduced significantly. Then a hypothetical numerical model based on FEFLOW is set up to study the change of hydraulic head, groundwater discharge, and saltwater‐fresh water interface. The groundwater level and flow are modified to various degrees, depending on the foundations percentage and the distribution pattern of the buildings. When the foundations percentage is high and the building foundations are aggregated, the hydraulic head is raised significantly and the originally one‐dimensional groundwater flow field becomes complicated. Seaward groundwater discharge will be reduced and some groundwater may become seepage through the ground surface. The transport model shows that, after foundations are added, overall the seawater and fresh groundwater interface moves landward, so extensive foundations may induce seawater intrusion. It is believed that the modification of the coastal groundwater system by building foundations may have engineering and environmental implications, such as submarine groundwater discharge, foundation corrosion, and slope stability. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

14.
Seawater intrusion (SI) is a global issue, exacerbated by increasing demands for freshwater in coastal zones and predisposed to the influences of rising sea levels and changing climates. This review presents the state of knowledge in SI research, compares classes of methods for assessing and managing SI, and suggests areas for future research. We subdivide SI research into categories relating to processes, measurement, prediction and management. Considerable research effort spanning more than 50 years has provided an extensive array of field, laboratory and computer-based techniques for SI investigation. Despite this, knowledge gaps exist in SI process understanding, in particular associated with transient SI processes and timeframes, and the characterization and prediction of freshwater–saltwater interfaces over regional scales and in highly heterogeneous and dynamic settings. Multidisciplinary research is warranted to evaluate interactions between SI and submarine groundwater discharge, ecosystem health and unsaturated zone processes. Recent advances in numerical simulation, calibration and optimization techniques require rigorous field-scale application to contemporary issues of climate change, sea-level rise, and socioeconomic and ecological factors that are inseparable elements of SI management. The number of well-characterized examples of SI is small, and this has impeded understanding of field-scale processes, such as those controlling mixing zones, saltwater upconing, heterogeneity effects and other factors. Current SI process understanding is based mainly on numerical simulation and laboratory sand-tank experimentation to unravel the combined effects of tides, surface water–groundwater interaction, heterogeneity, pumping and density contrasts. The research effort would benefit from intensive measurement campaigns to delineate accurately interfaces and their movement in response to real-world coastal aquifer stresses, encompassing a range of geological and hydrological settings.  相似文献   

15.
Dzhamalov  R. G.  Safronova  T. I. 《Water Resources》2002,29(6):626-631
A quantitative estimate is made for the first time for the role of some chemicals discharged with groundwater into seas and oceans in the formation of hydrochemical regime in the coastal zone. The estimate is based on the regional and global regularities in the formation and distribution of submarine groundwater discharge into seas and oceans. A concept is proposed regarding the existence of geochemical and biological barriers on the submarine groundwater–seawater interface, which cause significant transformation and losses of many chemical elements.  相似文献   

16.
The shelf-break acts as a separator between the coastal ocean and the open ocean. Circulation (particularly deep near-bottom flow) is restricted from crossing the bathymetry. Eddies become elongated in the region of the shelf-break restricting exchange. An estimate of the horizontal eddy diffusivity over the shelf-break of less than 10m2s-1 is found from a numerical model. Various mechanisms are responsible for the weak cross-isobath flow that does occur. One is the increase of the Rossby number over small-scale topography such as submarine canyons. Along-shore flow (in the direction opposite to Kelvin wave propagation) generates upwelling through submarine canyons. A review of upwelling through submarine canyons is given. The deep cross-shelf flow generated by the canyons is shown to be as significant as the wind-driven upwelling in some regions. Examples for the reduction of flow across the shelf-break and for upwelling through canyons are taken from the West Coast of Vancouver Island.  相似文献   

17.
Population growth and changing climate continue to impact on the availability of natural resources. Urbanization of vulnerable coastal margins can place serious demands on shallow groundwater. Here, groundwater management requires definition of coastal hydrogeology, particularly the seawater interface. Electrical resistivity imaging (ERI) appears to be ideally suited for this purpose. We investigate challenges and drivers for successful electrical resistivity imaging with field and synthetic experiments. Two decades of seawater intrusion monitoring provide a basis for creating a geo-electrical model suitable for demonstrating the significance of acquisition and inversion parameters on resistivity imaging outcomes. A key observation is that resistivity imaging with combinations of electrode arrays that include dipole–dipole quadrupoles can be configured to illuminate consequential elements of coastal hydrogeology. We extend our analysis of ERI to include a diverse set of hydrogeological settings along more than 100 km of the coastal margin passing the city of Perth, Western Australia. Of particular importance are settings with: (1) a classic seawater wedge in an unconfined aquifer, (2) a shallow unconfined aquifer over an impermeable substrate, and (3) a shallow multi-tiered aquifer system over a conductive impermeable substrate. We also demonstrate a systematic increase in the landward extent of the seawater wedge at sites located progressively closer to the highly urbanized center of Perth. Based on field and synthetic ERI experiments from a broad range of hydrogeological settings, we tabulate current challenges and future directions for this technology. Our research contributes to resolving the globally significant challenge of managing seawater intrusion at vulnerable coastal margins.  相似文献   

18.
The proper management of coastal aquifers commonly requires an understanding of regional mass flow and complete seawater–freshwater circulation. In this study, time series observations of seawater intrusion and refreshing were conducted using a column experiment based on natural flow conditions in coastal groundwater and a sampled medium from a coastal sandy aquifer without chemical treatment. Ranges of hydrodynamic and hydrochemical variables were tested and analysed. The results showed that the zeta potential of suspended colloids in aqueous solution in an aquifer polluted with 0.5 g/kg of heavy metals exhibited an isoelectric point for pH values ranging from 5.70 to 6.07 when freshwater or seawater completely occupied the aquifer pores, which is representative of natural hydrochemical conditions. In this scenario, a high background concentration of heavy metals induced colloidal immobilization. Otherwise, seawater–freshwater circulation enabled colloid mobilization due to ionic strength and pH fluctuations. The migration of multiple heavy metals occurred at a characteristic time of approximately 1 pore volume after each intrusion stage began and when the peak rate of colloid release was reached. At these times, the colloid behaviour determined the quantity and pathway of heavy metal transport. On the basis of the influences of seawater and freshwater interactions, the quantity of mobilized particles generally decreased and was uniformly distributed in each fraction due to particle loss and decreased porous connectivity. We speculate that the decrease in the total surface area of the migratory colloids may cause colloid‐associated heavy metal transport to decrease. The experimental results provide a useful basis for testing coastal groundwater flow and mass transport models because these phenomena require full characterization to precisely evaluate the associated fluxes from the field scale to the microscopic dimension.  相似文献   

19.
Submarine groundwater discharge (SGD) plays an important role in coastal biogeochemical processes and hydrological cycles, particularly off volcanic islands in oligotrophic oceans. However, the spatial and temporal variations of SGD are still poorly understood owing to difficulty in taking rapid SGD measurements over a large scale. In this study, we used four airborne thermal infrared surveys (twice each during high and low tides) to quantify the spatiotemporal variations of SGD over the entire coast of Jeju Island, Korea. On the basis of an analytical model, we found a linear positive correlation between the thermal anomaly and squares of the groundwater discharge velocity and a negative exponential correlation between the anomaly and water depth (including tide height and bathymetry). We then derived a new equation for quantitatively estimating the SGD flow rates from thermal anomalies acquired at two different tide heights. The proposed method was validated with the measured SGD flow rates using a current meter at Gongcheonpo Beach. We believe that the method can be effectively applied for rapid estimation of SGD over coastal areas, where fresh groundwater discharge is significant, using airborne thermal infrared surveys.  相似文献   

20.
The time domain electromagnetic method (TDEM) is applied to monitor, to delineate and to map the saltwater intrusion zones in the Mediterranean Plio‐Quaternary aquifer. Forty‐two TDEM soundings were carried out in the coastal plain of Nabeul–Hammamet region (NE Tunisia). TDEM resistivity data were correlated with the existing borehole logging data to assign them to a particular lithology and to provide information about the position of the freshwater–seawater transition zone. The geoelectric sections showing the vertical configuration of seawater intrusion, with the brackish‐salty‐saturated zones, have a resistivity ranging from ~0.1 to 5 Ω?m and are detected at a depth lower than 1.5 m. The salinized zones are located at Nabeul (Sidi Moussa, Sidi El Mahrsi, Al Gasba and Mrazgua) and at Hammamet (Touristic zone of Hammamet north and south, Baraket Essahel) and reached a distance of 4 km from the coastline, indicating a severe state for the aquifer in these zones. These TDEM results are confirmed by the increase of chloride concentration content in the analysed water samples of monitoring wells. Moreover, in the northeastern part, the presence of a saltwater front located far from the coast and along the NW–SE major surface fault can be explained by two hypothesis: (i) this fault seems to provide a conduit for seawater to move readily towards the water wells and (ii) the clay and gypsum infiltration of marine Messinian deposits through the fault plane leads to low resistivities. Finally, it comes out from this study that TDEM survey has successfully depicted salinized zones of this coastal aquifer. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

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