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1.
Dissolved organic carbon (DOC) data are presented from three meridional transects conducted in the North Atlantic as part of the US Climate Variability (CLIVAR) Repeat Hydrography program in 2003. The hydrographic sections covered a latitudinal range of 6°S to 63°N along longitudes 20°W (CLIVAR line A16), 52°W (A20) and 66°W (A22). Over 3700 individual measurements reveal unprecedented detail in the DOC distribution and systematic variations in the mesopelagic and bathypelagic zones of the North Atlantic basin. Latitudinal gradients in DOC concentrations combined with published estimates of ventilation rates for the main thermocline and North Atlantic Deep Water (NADW) indicate a net DOC export rate of 0.081 Pg C yr−1 from the epipelagic zone into the mesopelagic and bathypelagic zones. Model II regression and multiple linear regression models applied to pairwise measures of DOC and chlorofluorocarbon (CFC-12) ventilation age, retrieved from major water masses within the main thermocline and NADW, indicate decay rates for exported DOC ranging from 0.13 to 0.94 μmol kg−1 yr−1, with higher DOC concentrations driving higher rates. The contribution of DOC oxidation to oxygen consumption ranged from 5 to 29% while mineralization of sinking biogenic particles drove the balance of the apparent oxygen utilization.  相似文献   

2.
Chlorofluorocarbon (CFC) inventories provide an independent method for calculating the rate of North Atlantic Deep Water (NADW) formation. From data collected between 1986 and 1992, the CFC-11 inventories for the major components of NADW are: 4.2 million moles for Upper Labrador Sea Water (ULSW), 14.7 million moles for Classical Labrador Sea Water (CLSW), 5.0 million moles for Iceland–Scotland Overflow Water (ISOW), and 5.9 million moles for Denmark Strait Overflow Water (DSOW). The inventories directly reflect the input of newly formed water into the deep Atlantic Ocean from the Greenland, Iceland and Norwegian Seas and from the surface of the subpolar North Atlantic during the time of the CFC-11 transient. Since about 90% of CFC-11 in the ocean as of 1990 entered the ocean between 1970 and 1990, the formation rates estimated by this method represent an average over this time period. Formation rates based on best estimates of source water CFC-11 saturations are: 2.2 Sv for ULSW, 7.4 Sv for CLSW, 5.2 Sv for ISOW (2.4 Sv pure ISOW, 1.8 Sv entrained CLSW, and 1.0 Sv entrained northeast Atlantic water) and 2.4 Sv for DSOW. To our knowledge, this is the first calculation for the rate of ULSW formation. The formation rate of CLSW was calculated for an assumed variable formation rate scaled to the thickness of CLSW in the central Labrador Sea with a 10 : 1 ratio of high to low rates. The best estimate of these rates are 12.5 and 1.3 Sv, which average to 7.4 Sv for the 1970–1990 time period. The average formation rate for the sum of CLSW, ISOW and DSOW is 15.0 Sv, which is similar to (within our error) previous estimates (which do not include ULSW) using other techniques. Including ULSW, the total NADW formation rate is about 17.2 Sv. Although ULSW has not been considered as part of the North Atlantic thermohaline circulation in the past, it is clearly an important component that is exported out of the North Atlantic with other NADW components.  相似文献   

3.
The realization of North Atlantic Deep Water (NADW) replacement in the deep northern Indian Ocean is crucial to the “conveyor belt” scheme. This was investigated with the updated 1994 Levitus climatological atlas. The study was performed on four selected neutral surfaces, encompassing the Indian deep water from 2000 to 3500 m. The Indian deep water comprises three major water masses: NADW, Circumpolar Deep Water (CDW) and North Indian Deep Water (NIDW). Since NADW flowing into the southwest Indian Ocean is largely blocked by the ridges (the Madagascar Ridge in the east and Davie Ridge in the north in the Mozambique Channel) and NIDW is the only source in the northern Indian Ocean that cannot provide a large amount of volume transport, CDW has to be a major source for the Indian deep circulation and ventilation in the north. Thus the question of NADW replacement becomes that of how the advective flows of CDW from the south are changed to be upwelled flows in the north—a water-mass transformation scenario. This study considered various processes causing motion across neutral surfaces. It is found that dianeutral mixing is vital to achieve CDW transformation. Basin-wide uniform dianeutral upwelling is detected in the entire Indian deep water north of 32°S, somewhat concentrated in the eastern Indian Ocean on the lowest surface. However, the integrated dianeutral transport is quite low, about a net of 0.2 Sv (1 Sv=106 m3 s-1) across the lowermost neutral surface upward and 0.4 Sv across the uppermost surface upward north of 32°S with an error band of about 10–20% when an uncertainty of half-order change in diffusivities is assumed. Given about 10–15% of rough ridge area where dianeutral diffusivity could be about one order of magnitude higher (10-4 m2 s-1) due to internal-wave breaking, the additional amount of increased net dianeutral transport across the lowest neutral surface is still within that error band. The averaged net upward transport in the north is matched with a net downward transport of 0.3 Sv integrated in the Southern Ocean south of 45°S across the lowermost surface. With the previous works of You (1996. Deep Sea Research 43, 291–320) in the thermocline and You (Journal of Geophysical Research) in the intermediate water combined, a schematic dianeutral circulation of the Indian Ocean emerges. The integrated net dianeutral upwelling transport shows a steady increase from the deep water to the upper thermocline (from 0.2 to 4.6) north of 32°S. The dianeutral upwelling transport is accumulated upward as the northward advective transport provided from the Southern Ocean increases. As a result, the dianeutral upwelling transport north of 32°S can provide at least 4.6 Sv to south of 32°S from the upper main thermocline, most likely to the Agulhas Current system. This amount of dianeutral upwelling transport does not include the top 150–200 m, which may contribute much more volume transport to the south.  相似文献   

4.
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5.
In the Eastern North Atlantic Ocean iron (Fe) speciation was investigated in three size fractions: the dissolvable from unfiltered samples, the dissolved fraction (<0.2 μm) and the fraction smaller than 1000 kDa (<1000 kDa). Fe concentrations were measured by flow injection analysis and the organic Fe complexation by voltammetry. In the research area the water column consisted of North Atlantic Central Water (NACW), below which Mediterranean Overflow Water (MOW) was found with the core between 800 and 1000 m depth. Below 2000 m depth the North Atlantic Deep Water (NADW) proper was recognised. Dissolved Fe and Fe in the <1000 kDa fraction showed a nutrient like profile, depleted at the surface, increasing until 500–1000 m depth below which the concentration remained constant. Fe in unfiltered samples clearly showed the MOW with high concentrations (4 nM) compared to the overlying NACW and the underlying NADW, with 0.9 nM and 2 nM Fe, respectively. By using excess ligand (Excess L) concentrations as parameter we show a potential to bind Fe. The surface mixed layer had the highest excess ligand concentrations in all size fractions due to phytoplankton uptake and possible ligand production. The ratio of Excess L over Fe proved to be a complementary tool in revealing the relative saturation state of the ligands with Fe. In the whole water column, the organic ligands in the larger colloidal fraction (between 0.2 μm and 1000 kDa) were saturated with Fe, whereas those in the smallest fraction (<1000 kDa) were not saturated with Fe, confirming that this fraction was the most reactive one and regulates dissolution and colloid aggregation and scavenging processes. This regulation was remarkably stable with depth since the alpha factor (product of Excess L and K′), expressing the reactivity of the ligands, did not vary and was 1013. Whereas, in the NACW and the MOW, the ligands in the particulate (>0.2 μm) fraction were unsaturated with Fe with respect to the dissolved fraction, thus these waters had a scavenging potential.  相似文献   

6.
Recently obtained World Ocean Circulation Experiment (WOCE) sections combined with a specially prepared pre-WOCE South Atlantic data set are used to study the dianeutral (across neutral surface) mixing and transport achieving Antarctic Intermediate Water (AAIW) being transformed to be part of the North Atlantic Deep Water (NADW) return cell. Five neutral surfaces are mapped, encompassing the AAIW from 700 to 1100 db at the subtropical latitudes.Coherent and significant dianeutral upwelling is found in the western boundary near the Brazil coast north of the separation point (about 25°S) between the anticyclonic subtropical and cyclonic south equatorial gyres. The magnitude of dianeutral upwelling transport is 10-3 Sv (1 Sv=106 m3 s-1) for 1°×1° square area. It is found that the AAIW sources from the southwestern South Atlantic and southwestern Indian Ocean do not rise significantly into the Benguela Current. Instead, they contribute to the NADW return formation by dianeutral upwelling into the South Equatorial Current. In other words, the AAIW sources cannot obtain enough heat/buoyancy to rise until they return to the western boundary region but north of the separation point. The basin-wide integration of dianeutral transport shows net upward transports, ranging from 0.25 to 0.6 Sv, across the lower and upper boundary of AAIW north of 40°S. This suggests that the equatorward AAIW is a slow rising water on a basin average. Given one order of uncertainty in evaluating the along-neutral-surface and dianeutral diffusivities from the assumed values, K=103 m2 s-1 and D=10-5 m2 s-1, the integrated dianeutral transport has an error band of about 10–20%. The relatively weak integrated dianeutral upwelling transport compared with AAIW in other oceans implies much stronger lateral advection of AAIW in the South Atlantic.Mapped Turner Angle in diagnosing the double-diffusion processes shows that the salty Central Water can flux salt down to the upper half of AAIW layer through salt-fingering. Therefore, the northward transition of AAIW can gain salt either through along-neutral-surface advection and diffusion or through salt fingering from the Central Water and heat through either along-neutral-surface advection and diffusion or dianeutral upwelling. Cabbeling and thermobaricity are found significant in the Antarctic frontal zone and contribute to dianeutral downwelling with velocity as high as −1.5×10-7 m s-1. A schematic AAIW circulation in the South Atlantic suggests that dianeutral mixing plays an essential role in transforming AAIW into NADW return formation.  相似文献   

7.
Year-long Lagrangian trajectories within the Labrador Sea Water of the eastern North Atlantic Ocean are analysed for basic flow statistics. Root-mean-square velocities at 1750 m depth are about 2 cm/s, except within the North Atlantic Current, where they are twice as large. These values are consistent with previous Eulerian measurements and extend those results to a much larger domain of the eastern basin. Mean flow estimates in boxes large enough to contain about 1 float-year of data indicate that Labrador Sea Water, having crossed the Mid- Atlantic Ridge (not resolved) near 50–55°N, presumably with the North Atlantic Current, partially recirculates to the north in the subpolar gyre, as well as entering the subtropical gyre and continuing south and west. The circulation of this water mass, as defined by the 1 yr average velocities, is stronger than traditional models of deep circulation would suggest, with an interior flow of roughly 1 cm/s. Mean speeds up to 3 cm/s were observed, with the highest values near the Azores Plateau. North of 45°N–55°N, mean eastward speeds closer to 0.2 cm/s were observed. Wind-generated barotropic fluctuations may be responsible for some part of the transport at this depth.  相似文献   

8.
Previous work has shown that methane anomalies frequently occur within the rift valley of the Mid-Atlantic Ridge (MAR). The plumes appear confined within the high, steep walls of the valley, and it is not known whether methane may escape to the open ocean outside. In order to investigate this question, the concentration and 13C/12C ratio of methane together with CCl3F concentration were measured in the northeastern Atlantic including the rift valley near 50°N. This segment contained methane plumes centered several 100 m above the valley floor with δ13C values mostly between –15‰ and –10‰. A limited number of helium isotope measurements showed that δ3He increased to 17% at the bottom of the valley, which suggests the helium and methane sources may be spatially separated. In the eastern Atlantic away from the ridge (48°N, 20°W), the methane concentration decreased monotonically from the surface to the bottom, but the methane δ13C exhibited a mid-water maximum of about –25‰. The bottom water methane contained a significantly lower δ13C of about –36‰. Thus, it appears that isotopically heavy methane escapes from the MAR into North Atlantic Deep Water (NADW) that contacts the ridge crest while circulating to the east. The formation of NADW supplies isotopically light methane that dilutes the input of heavy carbon from the ridge. We employed a time-dependent box model to calculate the extent of isotope dilution and thereby the flux of MAR methane into the NADW circulation. The degree of methane oxidation, which affects the 13C/12C of methane through kinetic isotope fractionation, was estimated by comparing methane and CFC-11 model results with observations. The model calculations indicate a MAR methane source of about 0.06×10−9 mol L−1 yr−1 to waters at the depth of the ridge crest. Assuming this extends to a 500 m thick layer over half of the entire Atlantic, the amount of methane escaping from the MAR to the open ocean is estimated to be about 1×109 mol yr−1. The total production of methane within the rift valley is likely much greater than the flux from the valley to the outside because of local oxidation. This implies that serpentinization of ultramafic rocks supports much of methane production in the rift valley because the amount expected from basalt degassing in association with mantle helium (<0.6×109 mol CH4 yr−1) is less than even the net amount escaping from the valley. The model results also indicate the methane specific oxidation rate is about 0.05 yr−1 in open waters of the northern Atlantic.  相似文献   

9.
The northward flowing Antarctic Intermediate Water (AAIW) is a major contributor to the large-scale meridional circulation of water masses in the Atlantic. Together with bottom and thermocline water, AAIW replaces North Atlantic Deep Water that penetrates into the South Atlantic from the North. On the northbound propagation of AAIW from its formation area in the south-western region of the Argentine Basin, the AAIW progresses through a complex spreading pattern at the base of the main thermocline. This paper presents trajectories of 75 subsurface floats, seeded at AAIW depth. The floats were acoustically tracked, covering a period from December 1992 to October 1996. Discussions of selected trajectories focus on mesoscale kinematic elements that contribute to the spreading of AAIW. In the equatorial region, intermittent westward and eastward currents were observed, suggesting a seasonal cycle of the AAIW flow direction. At tropical latitudes, just offshore the intermediate western boundary current, the southward advection of an anticyclonic eddy was observed between 5°S and 11°S. Farther offshore, the flow lacks an advective pattern and is governed by eddy diffusion. The westward subtropical gyre return current at about 28°S shows considerable stability, with the mean kinetic energy to eddy kinetic energy ratio being around one. Farther south, the eastward deeper South Atlantic Current is dominated by large-scale meanders with particle velocities in excess of 60 cm s-1. At the Brazil–Falkland Current Confluence Zone, a cyclonic eddy near 40°S 50°W seems to act as injector of freshly mixed AAIW into the subtropical gyre. In general, much of the mixing of the various blends of AAIW is due to the activity of mesoscale eddies, which frequently reoccupy similar positions.  相似文献   

10.
The deep-circulation current in the North Pacific carries lower circumpolar deep water (LCDW), which is characterized by high dissolved oxygen and low echo intensity of reflected sound pulses. Using the characteristics of LCDW, we examined a branch current of the deep circulation passing through the Main Gap of the Emperor Seamounts Chain (ESC) by analyzing conductivity temperature depth profiler (CTD) data and data of velocity and echo intensity from a lowered acoustic Doppler current profiler (LADCP), which were obtained along 170°E immediately west of the ESC, along 180°W and 175°W over the northern slope of the Hess Rise, and along 165°W. The velocity and water characteristics showed that the eastern branch current of the deep circulation, which has penetrated into the Northwest Pacific Basin (NWPB) through Wake Island Passage, bifurcates around 30°N, 170°E in the NWPB into the westward main stream and a northward branch current, and that the latter current proceeds along the western side of the ESC and passes through the Main Gap of the ESC, flowing eastward. The current in the Main Gap at 170°E flows southeastward with eastward velocity cores around 4000 dbar and at depths greater than 4800 dbar centered at 5400 dbar. The current in the deeper core is stronger and reaches a maximum velocity of approximately 10 cm s?1. The eastward current in the Main Gap enters the Northeast Pacific Basin (NEPB) and flows eastward along the northern slope of the Hess Rise. As the current flows downstream, the characteristics of LCDW carried by the current are diluted gradually. To the east of the Hess Rise, the branch current joins another branch current of the deep circulation from the south carrying less-modified LCDW. As a result, LCDW carried from the Main Gap is renewed by mixing with the less-modified LCDW coming from the south. Carrying the mixed LCDW, the confluence flows eastward south of 37°N at 165°W toward the northeastern region of the NEPB, where the LCDW overturns and changes to North Pacific Deep Water (NPDW). NPDW is probably carried by the westward current in the upper deep layer north of 37°N at 165°W.  相似文献   

11.
In support of the Deep Basin Experiment, part of the World Ocean Circulation Experiment, a large number of neutrally buoyant floats were released within the Brazil Basin during the 1990s in an attempt to measure directly the circulation in the deep ocean interior. Three levels corresponding to the three major subthermocline water masses were selected, and results from the deeper two (North Atlantic Deep Water, NADW, and Antarctic Bottom Water, AABW) are described. At this writing processing of acquired tracking data is incomplete. Hence, this paper reports on the progress of the observational program and gives our initial conclusions.It appears that the flow in the deep Brazil Basin is unlike previous conjectures in which the circulation patterns can be characterized as being primarily meridional, both along the western boundary and in the interior. The existence of a deep western boundary current (DWBC) is quite clear in the float data at the NADW level, but less prominent in the AABW, and the interior flow is dominantly zonal with unexpectedly small meridional space scales. Integral time scales are long, of order 20–30 days, and eddy kinetic energy levels are low, of order 1 cm2/s2. In spite of the low energy levels a surprising number of our floats became caught up in vortices.A line of seamounts extending offshore near 20°S, known as the Vitória–Trindade Seamounts, interrupts the DWBCs and is the location for eddy formation and apparent flow away from the boundary into the interior. Although it has been speculated that this could feed a narrow zonal current of NADW (the “Namib Col Current”) our float trajectories suggest a return to the western boundary, rather than a continuation to the east.  相似文献   

12.
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13.
The water mass structure and circulation of the continental shelf waters west of the Antarctic Peninsula are described from hydrographic observations made in March–May 1993. The observations cover an area that extends 900 km alongshore and 200 km offshore and represent the most extensive hydrographic data set currently available for this region. Waters above 100–150 m are composed of Antarctic Surface Water and its end member Winter Water. Below the permanent pycnocline is a modified version of Circumpolar Deep Water, which is a cooled and freshened version of Upper Circumpolar Deep Water. The distinctive signature of cold and salty water from the Bransfield Strait is found at some inshore locations, but there is little indication of significant exchange between Bransfield Strait and the west Antarctic Peninsula shelf. Dynamic topography at 200 m relative to 400 m indicates that the baroclinic circulation on the shelf is composed of a large, weak, cyclonic gyre, with sub-gyres at the northeastern and southwestern ends of the shelf. The total transport of the shelf gyre is 0.15 Sv, with geostrophic currents of order 0.01 m s-1. A simple model that balances across-shelf diffusion of heat and salt from offshore Upper Circumpolar Deep Water with vertical diffusion of heat and salt across the permanent pycnocline into Winter Water is used to explain the formation of the modified Circumpolar Deep Water that is found on the shelf. Model results show that the observed thermohaline distributions across the shelf can be maintained with a coefficient of vertical diffusion of 10-4 m2 s-1 and horizontal diffusion coefficients for heat and salt of 200 and 1200 m2 s-1, respectively. When the effects of double diffusion are included in the model, the required horizontal diffusion coefficients for heat and salt are 200 and 400 m2 s-1, respectively.  相似文献   

14.
We conducted full-depth hydrographic observations between 8°50′ and 44°30′N at 165°W in 2003 and analyzed the data together with those from the World Ocean Circulation Experiment and the World Ocean Database, clarifying the water characteristics and deep circulation in the Central and Northeast Pacific Basins. The deep-water characteristics at depths greater than approximately 2000 dbar at 165°W differ among three regions demarcated by the Hawaiian Ridge at around 24°N and the Mendocino Fracture Zone at 37°N: the southern region (10–24°N), central region (24–37°N), and northern region (north of 37°N). Deep water at temperatures below 1.15 °C and depths greater than 4000 dbar is highly stratified in the southern region, weakly stratified in the central region, and largely uniform in the northern region. Among the three regions, near-bottom water immediately east of Clarion Passage in the southern region is coldest (θ<0.90 °C), most saline (S>34.70), highest in dissolved oxygen (O2>4.2 ml l?1), and lowest in silica (Si<135 μmol kg?1). These characteristics of the deep water reflect transport of Lower Circumpolar Deep Water (LCDW) due to a branch current south of the Wake–Necker Ridge that is separated from the eastern branch current of the deep circulation immediately north of 10°N in the Central Pacific Basin. The branch current south of the Wake–Necker Ridge carries LCDW of θ<1.05 °C with a volume transport of 3.7 Sv (1 Sv=106 m3 s?1) into the Northeast Pacific Basin through Horizon and Clarion Passages, mainly through the latter (～3.1 Sv). A small amount of the LCDW flows northward at the western boundary of the Northeast Pacific Basin, joins the branch of deep circulation from the Main Gap of the Emperor Seamounts Chain, and forms an eastward current along the Mendocino Fracture Zone with volume transport of nearly 1 Sv. If this volume transport is typical, a major portion of the LCDW (～3 Sv) carried by the branch current south of the Wake–Necker and Hawaiian Ridges may spread in the southern part of the Northeast Pacific Basin. In the northern region at 165°W, silica maxima are found near the bottom and at 2200 dbar; the minimum between the double maxima occurs at a depth of approximately 4000 dbar (θ～1.15 °C). The geostrophic current north of 39°N in the upper deep layer between 1.15 and 2.2 °C, with reference to the 1.15 °C isotherm, has a westward volume transport of 1.6 Sv at 39–44°30′N, carrying silica-rich North Pacific Deep Water from the northeastern region of the Northeast Pacific Basin to the Northwest Pacific Basin.  相似文献   

15.
The circulation and transport of Antarctic Bottom Water (σ4<45.87) in the region of the Vema Channel are studied along three WOCE hydrographic lines, the geostrophic velocities referenced to previously published direct current measurements. The primary supply of water to the deep Vema Channel is from the Argentine Basin's deep western boundary current, with no indication of an inflow from the southeast. In the northern Argentine Basin, detachment of lower North Atlantic Deep Water from the continental slope is associated with a deep thermohaline front near 34°S. To the north of this front, the upper part of the AABW bound for the Vema Channel (σ4<46.01) exhibits a significant NADW influence. Further modification of the throughflow water occurs near 30°30′S, where the channel orientation changes by ∼50°. Southward flow of bottom water on the eastern flank of the Vema Channel, amounting to ∼1.5 Sv, represents a significant countercurrent to the deep channel transport. Inclusion of this countercurrent reduces the net flow of AABW through the Vema Channel from 3.2±0.7 to 1.7±1.1 Sv. Water properties imply that the near-zero net flow over the Santos Plateau results from a near-closed cyclonic circulation fed by the deep Vema Channel throughflow. A disruption of the northward boundary current in the upper AABW (lower circumpolar water) is required by this flow pattern. The extension of the cyclonic circulation on the Santos Plateau enters the Brazil Basin as a ∼1 Sv flow distinct from the outflow in the Vema Channel Extension (6.2 Sv). The high magnitude of the latter suggests a southward recirculation of bottom water near the western boundary to the north of the region of study.  相似文献   

16.
The Wyville Thomson Ridge forms part of the barrier to the meridional circulation across which cold Nordic Sea and Arctic water must traverse to reach the Atlantic Ocean. Overflow rates across the ridge are variable (but can be dramatic at times), and may provide a subtle indicator of significant change in the circulation in response to climate change. In spring 2003, a series of CTD sections were conducted during a large overflow event in which Norwegian Sea Deep Water (NSDW) cascaded down the southern side of the ridge into the Rockall Trough at a rate of between 1 and 2 Sv. The NSDW was partially mixed with overlying North Atlantic Water (NAW), and comprised about 1/3rd of the cascading water. The components of NAW and NSDW in the overflow were sufficiently large that there must have been a significant divergence of the inflow through the Faroe-Shetland Channel, and of the outflow through the Faroe Bank Channel.As the plume descended, its temperature near the sea bed warmed by over 3 °C in about a day. Although the slope was quite steep (0.03), the mean speed of the current (typically 0.36 m s−1) was too slow for significant entrainment of NAW to occur (the bulk Richardson number was of order 5). However, very large overturns (up to 50 m) were evident in some CTD profiles, and it is demonstrated from Thorpe scale estimates that the warming of the bottom waters was due to mixing within the plume. It is likely that some of the NSDW had mixed with NAW before it crossed the ridge. The overflow was trapped in a gully, which caused it to descend to great depth (1700 m) at a faster rate, and with less modification due to entrainment, than other overflows in the North Atlantic. The water that flowed into the northern part of the Rockall Trough had a temperature profile that ranged from about 3 to 8 °C. Water with a temperature of >6 °C probably escaped into the Iceland Basin, between the banks that line the north-western part of the Trough. Colder water (< 6 °C) must have travelled down the eastern side of the Rockall Bank, and may have had a volume flux of up to 1.5 Sv.  相似文献   

17.
The third in a series of cruises designed to establish the present-day concentrations of trace elements and synthetic organic compounds in major water masses of the ocean, the 1996 Intergovernmental Oceanographic Commission Contaminant Baseline Survey occupied six vertical profile stations in the subtropical and tropical Atlantic. Underway surface samples also were acquired in the transects between these stations. This paper uses the temperature, salinity, oxygen, nutrient, and chlorophyll results from the cruise to set the hydrographic background for the other papers in this special volume. Major features sampled during the surface transect include the Brazil Current, the South Equatorial Current, and the offshore Amazon Plume. Utilizing the above parameters to identify water masses, we observed Antarctic Bottom Water (AABW) that ranged from a relatively undiluted form at 33°S (Station 10) to a highly attenuated form at 8°N (Station 6). Similarly, North Atlantic Deep Water (NADW) was obtained in various mixing stages along its flow path, and samples of NADW and AABW exchanging through the Romanche Fracture Zone to the eastern Atlantic basins were also taken. In addition to these deep water masses, representative samples of Antarctic Intermediate Water and Circumpolar Deep Water were acquired. Besides standard hydrography, these data also were used to verify the sampling integrity of the trace metal-clean, Go Flo bottles deployed on a Kevlar hydrographic cable.  相似文献   

18.
In this paper we use a temperature and salinity based mixing model to assess the dilution of Antarctic Bottom Water (AABW) as it moves away from the Weddell Sea and into the Southwest Indian Ocean. By combining these results with CFC tracer measurements we have been able to make direct estimates of the large-scale translation rates of AABW in this region. We confirm that there is a major northward flow of AABW via a gap in the Southwest Indian Ridge at 30°E, and thence across the Agulhas Basin into the Mozambique Basin, with a translation rate from the Greenwich Meridian of 0.8–1.0 cm s−1 and a volume transport between the two basins of 1.5×106 m3 s−1. A second, smaller flow cuts the Del Cano Rise through the Prince Edward Fracture Zone but is indistinguishable from the general bottom waters once on the northern side of the rise. The third flow moves eastward along the southern flank of the Del Cano Rise to pass north of the Conrad Rise. This has bottom velocities of 0.7 cm s−1 and a volume transport of 1.6×106 m3 s−1. This water is probably the source of the AABW-rich Circumpolar Deep Water that flows through the gap to the west of Crozet Island, and which is traceable again at stations on the northern flanks of the ridge. Flow between the Conrad Rise and the Del Cano Rise is complicated by the influence of a fourth flow, the AABW that passes south of the former and thence into the Crozet Basin via the Crozet-Kerguelen Gap. We suggest that a portion of this flow loops into the channel between the Del Cano Rise and the Conrad Rise, modifying the bottom waters at the easternmost stations within this channel. We will go on in Part 2 of this paper to use these results to estimate the dissolution rates of silica in the SWINDEX area.  相似文献   

19.
The intermediate and deep waters of the Labrador Sea are dominated by recently ventilated water masses (ventilation ages <20 yr). Atmospheric gases such as CO2 and chlorofluorocarbons are incorporated into these water masses at the time of formation and subsequently transported via boundary currents into the North Atlantic interior. Recent measurements of total carbonate were used in tandem with total alkalinity and oxygen to estimate the levels of anthropogenic carbon dioxide in the Labrador Sea region. Upper water column anthropogenic CO2 estimated in this manner showed good agreement with levels calculated from CO2 increase in the atmosphere. In spring 1997, anthropogenic contributions to total carbonate (CTant) were 40±3 μmol/kg in water penetrated by deep convection the previous winter and slightly lower (37±2 μmol/kg) in the deeper convective layer formed in the winters of 1992–1994. Consistent with the concurrent profiles of CFC-11, levels decrease into the older NEADW (North East Atlantic Deep Water) with levels of 30±3 μmol/kg and then increase near bottom within the layer of DSOW (Denmark Strait Overflow Water). The distribution of CTant shows the flow of new LSW southwards with the western boundary current and also eastwards into the Irminger Sea. We estimate that 0.15–0.35 Gt carbon of anthropogenic origin flow through the Labrador Sea within the Western Boundary Undercurrent per year.  相似文献   

20.
The total organic carbon (TOC) and total inorganic carbon (CT) exchange between the Atlantic Ocean and the Mediterranean Sea was studied in the Strait of Gibraltar in September 1997. Samples were taken at eight stations from western and eastern entrances of the Strait and at the middle of the Strait (Tarifa Narrows). TOC was analyzed by a high-temperature catalytic oxidation method, and CT was calculated from alkalinity–pHT pairs and appropriate thermodynamic relationships. The results are used in a two-layer model of water mass exchange through the Strait, which includes the Atlantic inflow, the Mediterranean outflow and the interface layer in between. Our observations show a decrease of TOC and an increase of CT concentrations from the surface to the bottom: 71–132 μM C and 2068–2150 μmol kg−1 in the Surface Atlantic Water, 74–95 μM C and 2119–2148 μmol kg−1 in the North Atlantic Central Water, 63–116 μM C and 2123–2312 μmol kg−1 in the interface layer, and 61–78 μM C and 2307–2325 μmol kg−1 in the Mediterranean waters. However, within the Mediterranean outflow, we found that the concentrations of carbon were higher at the western side of the Strait (75–78 μM C, 2068–2318 μmol kg−1) than at the eastern side (61–69 μM C, 2082–2324 μmol kg−1). This difference is due to the mixing between the Atlantic inflow and the Mediterranean outflow on the west of the Strait, which results in a flux of organic carbon from the inflow to the outflow and an opposite flux of inorganic carbon. We estimate that the TOC input from the Atlantic Ocean to the Mediterranean Sea through the Strait of Gibraltar varies from (0.97±0.8)104 to (1.81±0.90)104 mol C s−1 (0.3×1012 to 0.56×1012 mol C yr−1), while outflow of inorganic carbon ranges from (12.5±0.4)104 to (15.6±0.4)104 mol C s−1 (3.99–4.90×1012 mol C yr−1). The high variability of carbon exchange within the Strait is due to the variability of vertical mixing between inflow and outflow along the Strait. The prevalence of organic carbon inflow and inorganic carbon outflow shows the Mediterranean Sea to be a basin of active remineralization of organic material.  相似文献   

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