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1.
There is an increasing interest in the distribution of rare earth elements (REEs) within soils, primarily as these elements can be used to identify pedogenetic processes and because soils may be future sources for REE extraction, despite much attention should be paid to the protection and preservation of present soils. Here, we evaluate the processes that control the distribution of REEs in subsoil horizons developed over differing lithologies in an area of low anthropogenic contamination, allowing estimates of the importance of source rocks and weathering. Specifically, this study presents new data on the distribution of REEs and other trace elements, including transition and high-field-strength elements, in subsoils developed on both Quaternary silica-undersaturated volcanic rocks and Pliocene siliciclastic sedimentary rocks within the Mt. Vulture area of the southern Apennines in Italy. The subsoils in the Mt. Vulture area formed during moderate weathering (as classified using the chemical index of alteration) and contain an assemblage of secondary minerals that is dominated by trioctahedral illite with minor vermiculite. The REEs, high-field-strength elements, and transition metals have higher abundances in subsoils that developed from volcanic rocks, and pedogenesis caused the Mt. Vulture subsoils to have REE concentrations that are an order of magnitude higher than typical values for the upper continental crust. This result indicates that the distribution of REEs in soils is a valuable tool for mineral exploration. A statistical analysis of inter-elemental relationships indicates that REEs are concentrated in clay-rich fractions that also contain significant amounts of low-solubility elements such as Zr and Th, regardless of the parent rock. This suggests that low-solubility refractory minerals, such as zircon, play a significant role in controlling the distribution of REEs in soils. The values of (La/Yb)N and (Gd/Yb)N fractionation indices are dependent on the intensity of pedogenesis; soils in the study area have values that are higher than typical upper continental crust ratios, suggesting that soils, especially those that formed during interaction with near neutral to acidic organic-rich surface waters, may represent an important source of both light REEs and medium REEs (MREEs). In comparison, MREE/heavy REE fractionation in soils that form during moderate weathering may be affected by variations in parent rock lithologies, primarily as MREE-hosting minerals, such as pyroxenes, may control (La/Sm)N index values. Eu anomalies are thought to be the most effective provenance index for sediments, although the anomalies within the soils studied here are not related to the alteration of primary minerals, including feldspars, to clay phases. In some cases, Eu/Eu* values may have a weak correlation with elements hosted by heavy minerals, such as Zr; this indicates that the influence of mechanical sorting of clastic particles during sedimentary transport on the Eu/Eu* values of siliciclastic sediments needs to be considered carefully.  相似文献   

2.
对天山成矿带中国境内的东天山地区和哈萨克斯坦境内的楚伊犁地区1∶100万比例尺的地球化学填图所揭示的信息进行了对比研究。造岩元素、铁族元素、稀有元素、稀土元素和分散元素在这2个地区的含量和富集程度都非常接近,说明天山地区具有相同的地质背景;贵金属元素Au在楚伊犁地区的含量和富集程度要显著高于东天山地区,楚伊犁地区的Au异常不仅与石英脉型金矿有关,还与黑色页岩微粒金矿化有关;有色金属元素在2个地区差别不大,不同的是Cu异常在东天山以独立或与其他有色金属元素伴生异常存在,而在楚伊犁主要以与贵金属元素伴生异常存在;铂族元素在2个地区含量比较接近,一类异常与基性和超基性岩有关,另一类与黑色岩系有关。尽管这2个地区都还未发现有经济价值的铂族元素矿床,但在楚伊犁地区已经发现与炭质硅质岩有关的微粒金、铂矿化。  相似文献   

3.
Primitive olivine-mica-K-feldspar lamprophyre dykes, dated at 1831 ± 6 Ma, intrude lower greenschist facies rocks of the Early Proterozoic Pine Creek Inlier, of northern Australia. They are spatially, temporally and probably genetically associated with a post-tectonic composite granite-syenite pluton (Mt. Bundey pluton). The dykes have unusually high contents of large-ion-lithophile (LILE) and LREE elements (e.g. Ba up to 10,000 ppm, Ce up to 550 ppm, K2O up to 7.5 wt. %) that resemble the concentrations found in the West Kimberley olivine and leucite lamproites. However, mineralogically the Mt. Bundey lamprophyres resemble shoshonitic lamprophyres and lack any minerals diagnostic of lamproites; leucite or leucite-pseudomorphs are absent. Mineral compositions are also unlike those in lamproites: micas contain higher Al2O3 than lamproitic mica; amphiboles are secondary actinolites after diopside; and oxides consist of zincian-chromian magnetite and groundmass magnetite. Heavy mineral concentrates contain mantle-derived xenocrysts of magnesiochromite, pyrope, Cr-diopside and rutile indicating a depth of sampling > 70 km. The Mt. Bundey lamprophyres are non-peralkaline to borderline peralkaline (molar (K + Na)/Al = 0.8 − 1.0) and potassic rather than ultrapotassic (molar K/Na < 2.5). They have distinctive major element compositions (≈46−49 wt. % SiO2, ≈1.5−2 wt. % MgO, ≈7 wt. % CaO), and element ratios (e.g. molar Al/Ti ≈10, K/Na ≈2) that indicate they are best classified amongst transitional lamproites, i.e. potassic rocks such as cocites, jumillites and Navajominettes, that have geochemical characteristics transitional between Groups I and III. (Foley et al., 1987). The Mt. Bundey lamprophyres have LILE enrichment patterns that resemble the W. Kimberley pamproites but have moderate negative Ta---Nb---Ti anomalies and HREE abundances that are closely similar to the jumillites of southeastern Spain and Mediterranean-type lamproites. Single-stage modelling of Rb---Sr data is consistent with enrichment of the source-region of the Mt. Bundey lamprophyres ≈ 120–170 Ma before partial melting; i.e. at 1.95–2.10 Ga. Source enrichment does not appear to be associated with subduction processes, but may instead relate to incipient rifting of the Archaean basement. Negative Ta---Nb---Ti anomalies in the Mt. Bundey dykes may, therefore, relate to stability of residual titanate minerals in an oxidized subcontinental mantle source. This view is supported by high Fe3+/ΣFe ratios of mantle-derived magnesiochromite xenocrysts which indicate oxidized mantle conditions (ƒo2 ≈ FMQ + 1 long units), and by the presence of xenocrystic Cr-bearing rutile. Although the Mt. Bundey dykes have sampled upper mantle material, the oxidized nature of the magma source-region, and of the magma itself, suggests that conditions may not be favourable for diamond survival at depth nor for diamond transport in transitional lamproite magmas of this kind.  相似文献   

4.
Petrology of Mt Etinde Nephelinite Series   总被引：3，自引：1，他引：2  
Mt Etinde is a volcano situated on the southwestern flank ofthe large Mt Cameroon. Its eruptions are dated at 065 Ma andtook place during the Mt Cameroon eruptive cycle (6 Ma withrecorded recent activity). The lava types, unrelated to theMt Cameroon alkali basalts, are melanephelinites, nephelinitessensu stricto, and numerous and varied nephelinites that containone or more of the following species: nosean, melilite, perovskite,garnet, aenigmatite, leucite, feldspar and haynophyres. Clinopyroxeneis the dominant mafic phase, with a variable composition betweenAl–Ti augite and aegirine. Zoning is also present in garnets,with conspicuous Ti enrichment in the border. Aenigmatite includesa fair proportion of Fe3+ Tschermak's component. Melilite issystematically Sr rich; its SrO contents increase continuouslywith MgO decrease, reaching 16 wt % in some facies. The chemicalcomposition of the lavas is extreme, with unusual concentrationsof volatiles (CO2, H2O, SO3), most incompatible elements, suchas Ba, Sr and Zr, and the light rare earth elements (LREE).The Mt Etinde lavas define two lineages (MgO poor and MgO rich)that partly overlap. The chemical evolution of these two lineagescan be reproduced for major elements using a simple model ofcrystal fractionation. The major fractionating phase is an aluminousclinopyroxene, in accord with the petrographical observations.The scheme proposed can only be validated if the alkalis arenot taken into account, a hypothesis warranted by observationsof other nephelinite provinces or ijolite massifs and theirfenite aureoles. Nephelinite magmas were obviously generatedat great mantle depth, but their exotic composition can onlybe produced by partial melting of a metasomatic mantle. Comparisonwith other provinces would point to a source that has undergonecarbonatitic mtasomatism. KEY WORDS: nephelinites; Mt Etinde; Cameroon; petrogenesis; differentiation *Present address: Dpartement des Sciences de la Terre, Facult des Sciences, Universit de Yaound, BP 812, Yaound, Cameroon.Corresponding author.  相似文献   

5.

The Mt Wright Volcanics are located in the Wonominta Block of northwestern New South Wales. Detailed regional mapping has shown that the block is a composite tectonic unit and that the metavolcanic rocks described as the Mt Wright Volcanics may have been emplaced at different time from Late Proterozoic (northern section: Packsaddle, Nundora) to Early Cambrian (southern section: Mt Wright). Geochemical investigations, including major and trace elements, as well as analyses of relic clinopyroxene, show that the rocks have affinities with alkali basalt with light‐rare‐earth‐element‐enriched compositions. An intra‐plate extensional environment (such as rift‐ and/or plume‐related) is considered most likely for the formation of the rocks. Though metamorphosed to various degrees, the rocks apparently retain much of their primary Sr isotopic character (initial 87Sr/86Sr about 0.7032) and, apart from their age, resemble the Tertiary intraplate volcanism in eastern Australia. The Nd isotope analyses yield remarkably similar results between the two sections of the Mt Wright Volcanics, with 143Nd/144Nd between 0.51260 to 0.51271 and εNd(T) 4.7 ±0.4 (calculated to 525 Ma). A kaersutite‐bearing xenolith found in the northern section of the volcanic sequence has a Nd isotope composition more depleted than its hosts with εNd(T) of 7.7. The isotope results suggest that the Mt Wright Volcanics were derived from a depleted mantle source without significant crustal contribution. It is proposed that the Mt Wright Volcanics possibly represent the products of a rifting event that led to the breakup of the Proterozoic supercontinent during Early Cambrian in eastern Australia.  相似文献   

6.
The rock types and mineral compositions of the Mt. Namjagbarwa region have been studied. Petro-chemical analyses and calculations show that there are two types of metamorphic rock: ortho-and para-rocks in this region with the former being dominant. The results of trace element and REE analyses indicate that the original rocks are of multiple source with the continental tholeiites as the main source.  相似文献   

7.
This paper traces the history of mineral exploration in Indonesia between 1967 and 1992, and discusses various technical aspects, such as area selection, exploration and discovery methods, and significant geologic features of the more important new discoveries.Exploration activity over the past 25 years can be divided into four main phases. Phase 1 (1967–1976) mostly involved investigations of mineral prospects and districts previously identified by the Dutch. These investigations resulted in many discoveries, including: a major copper-gold district (skarn-porphyry copper) in Irian Jaya, where exploration is still in progress (resources identified to date: 28 Mt Cu and 2,700 t Au); large nickel resources in Eastern Indonesia (13 Mt Ni); significant onshore and offshore tin resources in the Sumateran tin belt (0.13 Mt Sn); and large but low grade bauxite deposits in West Kalimantan (300 Mt Al2O3). Of the eight Contracts of Work signed between 1967 and 1972, six reached the mining stage. Phase 2 (1970–1975) consisted of an extensive porphyry copper search in the Sunda arc, the western arc of Sulawesi and the central belt of Irian Jaya. Best results were obtained from northern Sulawesi, where follow-up between 1976 and 1982 identified three potentially economic copper-gold deposits (1.7 Mt Cu and 140 t Au) and one subeconomic molybdenum porphyry system (0.8 Mt Mo). During Phase 3 (1981–1988) extensive coal exploration in South and East Kalimantan delineated over 5,000 Mt of coal of varying rank and quality, including 1,500 Mt as measured reserves in 17 deposits, eight of which have been developed to date. Phase 4 (1984–1990) involved a major gold rush, focused primarily on the Cenozoic magmatic belts of Kalimantan, Sulawesi, Moluccas and the Sunda arc. Over 80 primary and alluvial gold prospects were drill tested. Five of these were brought into production (two alluvial deposits, two new hard rock discoveries and one Dutch mine), containing approximately 135 tonnes of mineable gold, and several other projects are under development or undergoing feasibility studies. Total geological resources identified to date are estimated to contain about 700 tonnes of gold. Exploration during phase 4 also resulted in several gold-rich porphyry copper discoveries, including a major deposit in Sumbawa (2.7 Mt Cu and 250 t Au). Intermittent exploration for uranium, diamonds and lead/zinc since 1969 has been largely unsuccessful.Exploration is now passing to the next phase, which is likely to be multi-commodity in nature with a strong focus on gold, copper and coal. A number of deposits outlined during earlier phases will be developed.The unprecedented high level of mineral exploration activity over the past 25 years can be attributed to Indonesia's mineral prospectivity and favourable investment climate. Given a continued competitive commercial environment and sustained commodity prices, the next 25 years should see further strong development of the country's mineral resources.  相似文献   

8.
Mount Erebus is an active volcano in Antarctica located on Ross Island. A convecting lava lake occupies the summit crater of Mt. Erebus. Since December 1980 the seismic activity of Mt. Erebus has been continuously monitored using a radio-telemetered network of six seismic stations. The seismic activity observed by the Ross Island network during the 1982–1983 field season shows that: (1)Strombolian eruptions occur frequently at the Erebus summit lava lake at rates of 2–5 per day; (2)centrally located earthquakes map out a nearly vertical, narrow conduit system beneath the lava lake; (3)there are other source regions of seismicity on Ross Island, well removed from Mt. Erebus proper. An intense earthquake swarm recorded in October 1982 near Abbott Peak, 10 km northwest of the summit of Mt. Erebus, and volcanic tremor accompanying the swarm, may have been associated with new dike emplacement at depth.  相似文献   

9.
Hydrothermal ore deposits are typically characterised by footprints of zoned mineral assemblages that extend far beyond the size of the orebody. Understanding the mineral assemblages and spatial extent of these hydrothermal footprints is crucial for successful exploration, but is commonly hindered by the impact of regolith processes on the Earth's surface. Hyperspectral drill core (HyLogger?-3) data were used to characterise alteration mineralogy at the Mt Olympus gold deposit located 35 km southeast of Paraburdoo along the Nanjilgardy Fault within the northern margin of the Ashburton Basin in Western Australia. Mineralogy interpreted from hyperspectral data over the visible to shortwave (400–2500 nm) and thermal (6000–14500 nm) infrared wavelength ranges was validated with X-ray diffraction and geochemical analyses. Spaceborne multispectral (ASTER) and airborne geophysical (airborne electromagnetic, AEM) data were evaluated for mapping mineral footprints at the surface and sub-surface. At the deposit scale, mineral alteration patterns were identified by comparing the most abundant mineral groups detected in the HyLogger data against lithology logging and gold assays. Potential hydrothermal alteration phases included Na/K-alunite, kaolin phases (kaolinite, dickite), pyrophyllite, white mica, chlorite and quartz, representing low-T alteration of earlier greenschist metamorphosed sediments. The respective zoned mineral footprints varied depending on the type of sedimentary host rock. Siltstones were mainly characterised by widespread white-mica alteration with proximal kaolinite alteration or quartz veining. Sandstones showed (1) distal white mica, intermediate dickite, and proximal alunite + kaolinite or (2) widespread white-mica alteration with associated intervals of kaolinite. In both, sandstones and siltstones, chlorite was distal to gold mineralisation. Conglomerates showed distal kaolinite/dickite and proximal white-mica/dickite alteration. Three-dimensional visualisation of the gold distribution and spatially associated alteration patterns around Mt Olympus revealed three distinct categories: (1) several irregular, poddy, SE-plunging zones of >0.5 ppm gold intersected by the Zoe Fault; (2) sulfate alteration proximal to mineralisation, particularly on the northern side of the Mt Olympus open pit; and (3) varying AlIVAlVISiIV–1(Mg,Fe)VI–1 composition of white micas with proximity to gold mineralisation. Chlorite that developed during regional metamorphic or later hydrothermal alteration occurs distal to gold mineralisation. ASTER mineral mapping products, such as the MgOH Group Content used to map chlorite (±white mica) assemblages, showed evidence of correlation to mapped, local structural features and unknown structural or lithological contacts as indicated by inversion modelling of AEM data.  相似文献   

10.
 The aim of this paper is to verify whether lichens have the capacity to accumulate atmospheric contaminators linked to volcanic activity. About 100 lichens were collected in 1994 and 1995 from two active volcanic areas in Italy: Mount Etna and Vulcano Island. Twenty-seven elements were analyzed for each individual lichen using Instrumental Neutronic Activation Analysis and Inductively Coupled Plasma-Mass Spectrometry. Lichen composition reflects the contribution of the volcanic particulate material, and the two areas investigated can be distinguished on the basis of the concentration of some lithophile elements. Moreover, the distribution in lichens of the elements (As, Sb, Br, Pb) – derived from gas emissions (plume, fumaroles) – also shows different geochemical trends on Mt. Etna and Vulcano. Received: 20 April 1998 · Accepted: 4 July 1998  相似文献   

11.
The corundum‐rich metabauxites, found at the northwest limb of an NE–SW‐trending isoclinal recumbent fold at Mt. Ismail, are enclosed in thick‐bedded platform‐type marbles of Late Cretaceous age, surrounding the polymetamorphic core series in the southern part of the Menderes Massif (SW Turkey). The metabauxite horizons observed as typically boudine‐like structure, extend laterally over c. 3 km and are 1 to 5 m thick. These rocks have dominant mineral assemblages of corundum (～50 modal %), chloritoid (～30 modal %), white mica (margarite, muscovite), diaspore, Fe–Ti‐Oxides (ilmenite, ilmenohematite, rutile), and goethite, limonite, pyrite, tourmaline (uvite, schorl) as minor phases. Chemical analyses of whole rock samples and the mineral assemblage indicate that coexisting minerals of metabauxites are highly aluminous. A number of minerals (e.g. chloritoid and margarite) display a large compositional variation reflecting the initial chemical inhomogenetiy of the karstbauxites. The field observations, trace‐element accumulation coefficients, concentration of elements such as Cr, Zr, Ga and Ni and low amounts of immobile elements all suggest that the studied corundum‐rich metabauxites can be classified as karstbauxites, and are more likely to be a product of weathering of intermediate igneous or argillaceous parental rocks, similar to the karstic Tauric bauxites in the Central Taurides (Seydi ?ehir region) and probably are similar in age (Cenomanian–Turonian). In respect of tectono‐metamorphic evolution, the studied corundum‐rich metabauxites were regionally metamorphosed at ～5–6 kbar pressure and 500–600°C as a consequence of the Barrovian metamorphism referred to as the ‘Main Menderes Metamorphism’ related to the ophiolitic obduction onto the Menderes platform from the Izmir–Ankara Suture during the Middle Eocene.  相似文献   

12.
珠穆朗玛峰绒布冰川水文过程初步研究   总被引：9，自引：8，他引：1  
2005年4月8日至10月11日对珠峰地区绒布河水文过程进行了连续6个多月的观测.结果表明:该地区的水文过程与温度有较好的相关性,6~8月3个月流量约占观测期内总流量的80%.对比该地区1959年和2005年的水文观测数据,发现2005年同期总径流量比1959年有较大幅度增加,6~8月3个月月均流量2005年较1959年分别增加69%、35%、14%.分析冰芯恢复的降水量资料和珠峰附近长时间序列气象数据,降水自1950年以来保持下降趋势,而气温却呈缓慢升高.气温升高是径流量增大的关键因素.2005年观测期内控制流域径流深为622 mm,径流模数为38.52 L·s-1·km-2.  相似文献   

13.
安徽大别山腹地中生代火山岩的发现及其地质意义   总被引：10，自引：0，他引：10  
近期作者等在大别山腹地开展１∶５万区调过程时,于中深变质岩中发现一套中生代火山岩系;主要岩石类型为石英安山质晶屑凝灰熔岩、火山角砾岩及凝灰岩。通过详细观察、追索,其中查明火山岩系的空间分布及其与围岩的接触关系。对认识大别山的构造演化及热隆—顶蚀作用、超高压变质带的形成、折返机制等提供新的依据。  相似文献   

14.
Scheelite is a widespread accessory mineral in hydrothermal gold deposits, and its rare earth element (REE) patterns and Nd and Sr isotopic compositions can be used to constrain the path and origin of the mineralising fluids and the age of the hydrothermal activity. Micro-analyses by laser ablation high resolution inductively coupled mass spectroscopy and cathodoluminescence imaging reveal a very inhomogeneous distribution of the REE in single scheelite grains from the Mt. Charlotte and Drysdale Archaean gold deposits in Western Australia. Two end-member REE patterns are distinguished: type I is middle REE (MREE)-enriched, with no or minor positive Eu-anomaly, whereas type II is flat or MREE-depleted with a strong positive Eu-anomaly. The chemical inhomogeneity of these scheelites is related to oscillatory zoning involving type I and type II patterns, with zone widths varying from below 1 to 200 μm. Intra-sectorial growth discontinuities, syn-crystallisation brittle deformation, and variations in the relative growth velocities of crystallographically equivalent faces suggest a complex crystallisation history under dynamic hydraulic conditions. The co-existence of MREE-enriched and MREE-depleted patterns within single scheelite crystals can be explained by the precipitation of a mineral which strongly partitions MREE relative to light and heavy REE. Scheelite itself has such characteristics, as does fluorapatite, which is locally abundant and has REE contents similar to that of scheelite. In this context, the systematic increase of the Eu-anomaly between type I and type II patterns is produced by the difference between the partition coefficients of Eu2+ and Eu3+, and not by fluid mixing or redox reactions. Consequently, the high positive Eu-anomaly typical of scheelite from gold ores may not necessarily be inherited from the hydrothermal fluid, but may reflect processes occurring during ore deposition. This case study demonstrates that in hydrothermal systems characterised by low REE concentrations in the fluid, and by the precipitation of a REE-rich mineral which strongly fractionates the REE, the REE patterns of such a mineral will be highly sensitive to the dynamics of the hydrothermal system. Received: 1 November 1999 / Accepted: 4 February 2000  相似文献   

15.
Mafic dykes intrude the composite Mt. Abu granite batholith as a minor and the last phase of magmatism. The dykes are sub-vertical, variable in width and visibly compact, however, features of alteration and shearing can be seen. The dykes occurring within the recently identified and described, Delwara Shear Zone (DWSZ), from the western margin of the Mt. Abu batholith are intensely to moderately sheared and intricately mixed with the host granitoids. The mafic dykes occurring within the shear zone bear evidence of assimilating the host granitoids during their ascent, seen as relicts, streaks and sub-rounded K-feldspar clasts in mafic dykes. The hybridization has resulted in unusual geochemical signatures of the mafic dykes such as higher silica levels, erratic and high incompatible trace element abundances and lack of any systematic trends. Mixing line calculations on the mafic dyke samples reveal between 30 to 60% felsic input into the mafic dykes. Mafic dykes outside the shear zone in the Mt. Abu are meter scale in width and generally free of felsic inclusions owing to small volumes of mafic melts. Large volume of mafic melts are required for assimilating up to 60% felsic component which has been identified as approximately 100 m wide zone within the DWSZ. Shearing has played an important role in providing the channel ways and for sustained high temperatures to allow such hybridization.  相似文献   

16.
Groundwater sampling was accomplished in the basaltic sequence of the Rh?n mountain range, Germany, in order to investigate hydrochemical groundwater evolution and to delineate mineral alteration reactions involved in natural weathering. The hydrochemical compositions of near-surface groundwaters indicate a Ca/Mg–HCO3 type with near-neutral pH and evolve to a Na–HCO3 type with high pH at greater depth. Column experiments were performed with basaltic and phonolitic rock samples to determine individual mineral alteration reactions. The basic reactions could be related to the alteration of olivine, Ca-pyroxene, plagioclase, pyrrhotite, and feldspathoids under formation of secondary clay minerals (smectites, illite) and goethite. The mineral alteration reactions deduced from the leaching experiments by inverse modelling were found to be consistent with the mineral reactions associated with the natural groundwaters. The reactions calculated for groundwater evolution involve the alteration of primary and secondary minerals to produce low-T mineral phase. The conversion of secondary Na-beidellite to illite occurs at a later stage of groundwater evolution, reducing the concentrations of K+ and Mg2+. Near-surface groundwaters do not indicate significant cation exchange. Initial cation exchange requires elevated pH values, with Mg2+ removed from solution preferred to Ca2+. Na-alkalisation of the groundwaters at greater depth suggests the exchange of Na+ for Mg2+ and Ca2+ on Na-beidellite, supported by cation exchange on coatings of iron hydroxides as alteration products. Among the mature high-pH groundwater at greater depth, the dissolution of anorthite and albite has significant effect on groundwater composition.  相似文献   

17.
胡国辉  胡俊良  陈伟  赵太平 《岩石学报》2010,26(5):1563-1576
幔源岩浆侵位产生的基性岩墙群是地壳伸展裂解的重要标志。华北克拉通南缘中条山-嵩山地区出露有大量的中元古代基性岩墙群,对其研究将有助于深入了解华北克拉通中元古代构造演化特征。其岩石类型以辉绿岩为主,少量辉长辉绿岩和辉绿玢岩;主要造岩矿物为斜长石和单斜辉石,其它矿物包括角闪石、Fe-Ti氧化物、磷灰石、黑云母、碱性长石和石英。锆石SHRIMPU-Pb年龄为1785±18Ma,代表岩墙的结晶年龄。岩石K2O+Na2O含量为3.63%～6.18%,K2O/Na2O比值为0.73～1.38,FeOT含量较高(10.03%～13.59%),属于拉斑玄武岩系列。岩石的稀土元素含量高(142×10-6～381×10-6),亏损Nb、Ta、Zr、Hf等高场强元素,富集Rb、Ba、La等大离子亲石元素,全岩εNd(t)值为-6.2～-8.1。岩墙的固结指数(SI)和MgO含量呈明显的正相关关系,说明幔源岩浆发生过明显的结晶分异作用。地球化学分析表明,研究区基性岩墙属于板内拉斑玄武岩系列,与熊耳群火山岩有相似的地球化学特征;基于两者紧密的产出关系,我们认为该区岩墙可能是熊耳群火山岩的通道岩墙,共同代表了华北克拉通东、西陆块碰撞后伸展事件。  相似文献   

18.
在对等轴铁铂矿进行微区分析的过程中,发现其中有呈树枝或叶片状的因固溶体分离而形成的新的金属互化物矿物——铱铑钌矿,其化学式为Ru_(6·38)Rh_(1·70)Ir(1·20)Pt_(0·68)Os_(0·04)。  相似文献   

19.
The dacite pumice erupted from Mt. Pinatubo on June 15, 1991 (whole-rock, rhyolitic groundmass glasses and homogenized melt inclusions) has been analyzed using inductively coupled plasma-mass spectrometry (ICP-MS), nanosecond and femtosecond laser ablation ICP-MS and secondary ion mass spectrometry (SIMS) to evaluate its ore-forming potential. Data suggest that adakite magmas are metal-rich and concentrate ore metals during magmatic differentiation. Sulfides segregate in limited amounts under the hydrous, oxidizing conditions typical of adakitic magmas resulting in incompatible behavior for Au (6-22 ppb), Cu (26-77 ppm), and Pb, Mo, As, and Sb in melts of dacitic to rhyolitic compositions. Metal transfer from this adakite magma to the coexisting aqueous phase was favored by the peraluminous composition of the rhyolitic melt and high aqueous chloride concentrations. Mass balance calculations suggest that the pre-eruptive aqueous phase could have extracted a minimum of 100 t Au and 5 × 105 t Cu from the Mt. Pinatubo magma. Our data suggest that intrusives having adakitic signatures are genetically associated with Au-Cu and Cu-Mo mineralization, auriferous porphyry copper deposits, and epithermal gold veins. High H2O, Cl, Sr/Y, Pb/Ce, Mo/Ce, As/Ce and Sb/Ce in Mt. Pinatubo melts reflect the contribution of deep fluids derived from subducted sediments and altered MORBs in the dacite genesis. The slab-derived fluids carrying mobile elements are likely responsible for the enrichment of adakite magmas in gold, associated metals and H2O, and may explain the exceptional ore-forming potential of adakite magmatism.  相似文献   

20.
研究云母和长石等原生硅酸盐矿物的风化速率和风化产物对于深入理解土壤发生过程、营养元素循环以及全球气候变化具有重要的理论意义。本文从自然风化、人工化学风化和生物风化3方面总结了原生硅酸盐矿物风化作用及其产物的特点，重点阐述了微生物参与下的生物风化作用和生物矿化作用及其意义。野外观察和室内实验研究结果表明，微生物可以加速矿物的分解，而且其细胞表面及其产生的胞外多聚糖可以作为次生矿物成核的模板。  相似文献   

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