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1.
Microbial mats, located along the margins of hot-spring pools and outflow channels at Lake Bogoria, Kenya, are commonly silicified forming friable laminated crusts. Columnar microstromatolites composed of silica and calcite are also forming at several springs in sites of oscillating water level or spray. Silicification of the microbes involves impregnation of organic tissue by very fine amorphous silica particles and encrustation by small (< 2 μm) silica spheroids. Rapid silicification of the microbes, which may begin while some are still alive, can preserve sheaths and in some examples, the filaments, capsules and cells. Although this provides evidence of their general morphology, the biological features that are required for taxonomic identifications are commonly poorly preserved.
The silica precipitation results mainly from evaporative concentration and rapid cooling of spring waters that have been drawn upward through the mats and microstromatolites by capillary processes. Almost all the silica at the Loburu springs nucleates on microbial substrates. This affinity of silica for functional groups on microbial surfaces contributes to the rapid silicification of the microbes and their preservation in modern and ancient cherts.  相似文献   

2.
试论动物非矿化组织的保存   总被引:3,自引:0,他引:3  
动物非矿物化组织在特异埋葬条件下可保存为化石。缺氧和快速埋葬有利于非矿化组织的保存,但不能阻止微生物的破坏作用。无菌环境下可保存软躯体组织,但在构造变动和古气候变迁等因素的影响下会彻底破坏,不可能在地质历史时期长期存在。最稳定的保存形式是与成岩作用有关的保存类型和以碳化有机质薄膜形式的保存类型。与动物非矿化组织保存有关的常见成岩自生矿物有磷酸盐矿物、碳酸盐矿物和黄铁矿等。其中,磷酸盐矿物在成岩作用过程中结晶最早,可以保存动物的微细构造。这些矿物可以矿化交代动物的肉质和角质使其成为矿化实体;也可以呈假形、铸型或铸模等形式保存。布尔吉斯页岩保存类型中,非矿化组织以碳化有机质薄膜或含水的颧硅酸盐矿物两种形式保存。前可能与粘土矿物吸附有机质、阻止酶的降解作用有关,后可能由自生粘土矿物的交代作用造成。  相似文献   

3.
ABSTRACT Recent dolomitic sediment samples from Lagoa Vermelha, Brazil, were examined microscopically to study the process of bacterial fossilization in carbonate sediments. Bacteria‐like bodies were intimately associated with carbonate mineral surfaces, and coatings on the former demonstrate the calcification of single bacterial cells. The bacterial fossilization process in Lagoa Vermelha sediments was simulated in the laboratory by cultivation of mixed and pure cultures of sulphate‐reducing bacteria, which were isolated from the Lagoa Vermelha sediments. These cultures produced carbonate minerals that were studied to provide insight into the initiation of the fossilization process. In mixed culture experiments, bacterial colonies became calcified, whereas in pure culture experiments, single bacterial cells were associated with dolomite surfaces. Dolomite nucleated exclusively in bacterial colonies, intimately associated with extracellular organic matter and bacterial cells. Electrophoretic mobility measurements of the bacterial cells in electrolyte solutions demonstrated the specific adsorption of Ca2+ and Mg2+ onto the cell surfaces, indicating the role of the bacterial surface in carbonate nucleation and bacterial fossilization. The affinity of the cells for Mg2+ was related to the capability of the strains to mediate dolomite formation. Combined with sulphate uptake, which dissociates the [MgSO4]0 ion pair and increases the Mg2+ availability, the concentration of Mg2+ ions in the microenvironment around the cells, where the conditions are favourable for dolomite precipitation, may be the key to overcome the kinetic barrier to dolomite formation. These results demonstrate that bacterial fossilization is a consequence of the cell surface involvement in carbonate precipitation, implying that fossilized bacterial bodies can be used as a tool to recognize microbially mediated carbonates.  相似文献   

4.
In the course of experimenting on the laboratory silification of algal cells and algal mats a series of organosilicon compounds was employed in attempts to simulate fossilization. These compounds provided a silica source for emplacement in the organic matrices of the algae. It was found that during the silicification process silicon acetate, triethoxysilane propylamine and tetraethylorthosilicate (tetraethoxysilane) yielded hydrolytic products which supported growth of microbes. Large numbers of microorganisms: several fungi, including yeast and an Aspergillus sp. and Pseudomonas aeruginosa were isolated from salt solutions containing these organosilicon compounds as the sole source of carbon. The rate of hydrolysis yielding silica for emplacement was not affected by growth of these microorganisms. The isolation and growth of pure cultures of P. aeruginosa on either triethylsilane propylamine or tetraethylorthosilicate is described.  相似文献   

5.
动物非矿物化组织在特异埋葬条件下可保存为化石.最稳定的保存形式是与成岩作用有关的保存类型和以碳化有机质薄膜形式存在的保存类型.与动物非矿化组织保存有关的常见成岩自生矿物有磷酸盐矿物、碳酸盐矿物和黄铁矿等.其中,磷酸盐矿物在成岩作用过程中结晶最早,可以保存动物的微细构造.这些矿物可以矿化交代动物的肉质和角质使其成为矿化实体.特异埋葬的化学机理还需要古生物学家和地球化学家更紧密的合作,做进一步的研究.  相似文献   

6.
Most Ordovician source rocks consist of accumulation of a colonial marine microorganism, Gloeocapsomorpha prisca (G. prisca) whose nature, ecology and affinity with extant organisms have been in dispute for years. Furthermore, recent studies have shown major differences in phenol moieties between two G. prisca-rich samples. Examination of five G. prisca-rich kerogens by electron microscopy and pyrolysis studies revealed (i) the occurrence of two markedly distinct “morpho/chemical” types: a “closed/phenol-rich” type (Baltic samples) and an “open/phenol-poor” one (North American samples) and (ii) the selective preservation of the resistant micromolecular material building up the thick cell walls in the original organism. Comparison with extant Botryococcus braunii (a widespread green microalga) grown on media of increasing salinity suggests that G. prisca is likely to be a planktonic green microalga related to B. braunii, which can adapt to large salinity variations which, in turn, control its polymorphism. The large differences in colony morphology and in the content of phenol moieties observed in fossil G. prisca and the resulting occurrence of two “morpho/chemical” types, should therefore reflect depositional environments with different salinities. The presence of thick, highly aliphatic, resistant walls in G. prisca selectively preserved during fossilization, accounts for the major contribution of this organism to Ordovician organic-rich sediments and for the resulting typical signature of Ordovician oils.  相似文献   

7.
The fossilization of biota and formation of low- and high-temperature hydrothermally altered rocks were studied in solfataric fields, artificial hot lakes, at natural hot springs, and on heated beach within the present-day rift zone at the Reykjanes, Nesjavellir, Geysir, Landmannalaugar, Namafjall, and Oxarfjodur geothermal areas. The hydrothermally altered rocks can be divided into the following mineral types: (1) smectite assemblage with iron oxides and hydroxides; (2) smectite assemblage with sulfides (pyrite); (3) kaolinite-metahalloysite assemblage with sulfates, anatase, and boehmite; and (4) siliceous assemblage. The detailed study of the hydrothermally altered rocks allowed us to elucidate some environmental features of modern fossilization and replacement of organic matter with clay minerals, iron oxyhydroxides, and silica. The fossilized microstructures have been described in rocks of the smectite and siliceous assemblages. It has been shown that the pseudobiomorphic (actually, abiogenic) micro- and nannostructures are formed in the moving water of silica deposition zone.  相似文献   

8.
It is has been suggested that faunal remains at Florisbad were fossilized in a spring context due to the mineralized spring water. However, the environment conducive to the precipitation of CaCO3 and other authigenic minerals was formed largely through the salinization of the organic layers and clay, and the mineralization of the groundwater. Factors contributing to this favorable environment include: CaCO3 saturation, pH, the decomposition of halophytes, Eh, rainfall, biomineralization, and aeolian deposition. With the exception of pH, none of the above factors feature in a spring context, with evidence suggesting that the spring water may historically never have carried sufficient minerals for fossilization, and that contact with the spring water may actually have resulted in the demineralization of previously fossilized material. In light of this evidence, it is concluded that the fossilization of faunal remains at Florisbad took place in a sedimentary organic matter and clay environment and could not have taken place in the spring vents where there is an undersaturation of Ca.  相似文献   

9.
实验埋葬学及其研究进展   总被引:1,自引:0,他引:1  
实验埋葬学是涉及地质学、生物学、化学、物理学等学科的一门交叉渗透性研究科学。它是在实验条件下研究生物或生物残体由生物圈转变到岩石圈的一系列变化过程及其与环境因素之间的相互作用关系。通过对环境因素的控制,研究各生物类别和组织类型的保存潜力及可能的保存状态,以及各环境因素在化石形成过程中的作用和结果。近年来的实验研究已为解决软躯体化石库的成因、早期核生物的鉴定、牙形动物和伊迪卡拉生物群的属性等一系列古生物学上的难题提供了新的思路。  相似文献   

10.
Types and lateral and vertical distribution of silicification in Riphean (largely dolomitic) rocks of the Yurubcha-Tokhomo zone of the Siberian Craton are discussed. It is shown that quartz and pyroclastic material in sediments were subjected to intense dissolution in a highly alkaline Riphean basin with the release of silica. Rapid and abrupt decrease in alkalinity during hiatus and desiccation periods resulted in the precipitation of dissolved silica and silicification of near-surface sediments. Lateral distribution of silicification was controlled by the redistribution of silica during the pre-Vendian hiatus, when surface waters were filtered through a carbonate massif with the simultaneous karst formation and silica dissolution. In the water discharge area, secondary silica was precipitated owing to changes in pH values and other physicochemical conditions.  相似文献   

11.
The Tertiary sedimentary sequence of the Date Creek basin area of Arizona is composed principally of intertonguing alluvial-fan and lacustrine deposits. The lacustrine rocks contain large intermediate- to, locally, high-grade uranium deposits that form one of the largest uranium resources in the United States (an estimated 670,000 tons of U3O8 at an average grade of 0.023% is indicated by drilling to date). At the Anderson mine, about 50,000 tons of U3O8 occurs in lacustrine carbonaceous siltstones and mudstones (using a cutoff grade of 0.01%). The Anderson mine constitutes a new class of ore deposit, a lacustrine carbonaceous uranium deposit.Floral and faunal remains at the Anderson mine played a critical role in creating and documenting conditions necessary for uranium mineralization. Organic-rich, uraniferous rocks at the Anderson mine contain plant remains and ostracodes having remarkably detailed preservation of internal features because of infilling by opaline silica. This preservation suggests that the alkaline lake waters in the mine area contained high concentrations of dissolved silica and that silicification occurred rapidly, before compaction or cementation of the enclosing sediment. Uranium coprecipitated with the silica. Thinly laminated, dark-colored, siliceous beds contain centric diatoms preserved with carbonaceous material suggesting that lake waters at the mine were locally deep and anoxic. These alkaline, silica-charged waters and a stagnant, anoxic environment in parts of the lake were necessary conditions for the precipitation of large amounts of uranium in the lake-bottom sediments.Sediments at the Anderson mine contain plant remains and pollen that were derived from diverse vegetative zones suggesting about 1500 m of relief in the area at the time of deposition. The pollen suggests that the valley floor was semiarid and subtropical, whereas nearby mountains supported temperate deciduous forests.  相似文献   

12.
Bacteria and protoctists dominated the biosphere in the Archean and Proterozoic, their affinities being deduced by studies of their comparative morphology, palaeoecology, biogeochemistry, and wall ultrastructure. However, exact phylogenetic relationships are uncertain for most such microfossils. Because of the limitations imposed by the simple morphology and small dimensions of such microorganisms and their little known biochemistry, new techniques in microscopy, tomography and spectroscopy are applied to examine individual microfossils at the highest attainable spatial resolution. TEM/SEM studies of the wall ultrastructure of sphaero- and acanthomorphic acritarchs have revealed complex, single to multilayered walls, having a unique texture in sub-layers and an occasionally preserved trilaminar sheath structure (TLS) of the external layer. A variety of optical characteristics, the electron density and texture of fabrics of discrete layers, and the properties of biopolymers may indicate the polyphyletic affiliations of such microfossils and/or the preservation of various stages (vegetative, resting) in their life cycle. Primarily, wall ultrastructure allows discrimination between fossilized prokaryotic and eukaryotic cells. Composite wall ultrastructure provides evidence that some Proterozoic and Cambrian leiosphaerids are of algal affinities (but not, per se, that they are referable to “Leiosphaeridia”). Certain Cambrian specimens represent chlorophyceaens, having the multilayered composite wall with TLS structure known from vegetative and resting cells in modern genera of the Chlorococcales and Volvocales. The wall ultrastructure of the studied Cambrian and Proterozoic acanthomorphs resembles the resting cysts of green microalgae, but there is no evidence to suggest a close relationship of these taxa to dinoflagellates. It is apparent that although there is no single and direct method to recognize the precise phylogenetic relations of such microfossils, ultrastructural studies of their preserved cell walls and encompassing sheaths, combined with biochemical analyses and other advanced methods, may further elucidate their affinities to the modern biota.  相似文献   

13.
Distilled water was passed at a low rate down a temperature gradient through cylinders of Barre and Westerly Granite. Temperatures ranged from 80–100°C at the outer edges of the cylinders to 250–300°C in central, drilled holes which housed the heating coils. The measured permeabilities of the granite cylinders decreased by as much as two orders of magnitude in experiments of 1–3 weeks' duration. The amount of permeability decrease varied directly with temperature and inversely with the rate of fluid flow. The compositions of the fluids discharged from the granites were functions of temperature and flow rate as well as mineral composition, with dissolved silica concentrations showing trends different from those of the other analyzed species. Fluids from experiments run at higher temperatures but at much lower initial rates of fluid flow had higher concentrations of most ions but substantially lower dissolved silica contents. In contrast, an increase in temperature at similar rates of fluid flow resulted in higher silica concentrations. In the experiments, the distilled water acquired enough dissolved materials at high temperatures to become supersaturated with respect to several minerals at the low-temperature edges of the cylinders. Some of this material, particularly silica, was deposited along grain boundaries and microfractures, causing the observed permeability decreases. The very low rates of fluid flow in some high-temperature experiments significantly increased the rates of SiO2 precipitation and reduced dissolved silica concentrations relative to other species in the discharged fluids.  相似文献   

14.
Black smoker chimneys and biological vent communities have been identified at many sites on the deep seafloor, particularly along oceanic spreading centers. We report the largest and oldest known, microbe-rich sub-meter-sized black smoker chimneys and mounds from a 1.43 billion-year old sulfide deposit in a continental graben in northern China. These chimneys are especially well preserved, with characteristic morphology, internal textures and internal cylindrical mineralogical zonation. Four main types of chimneys are distinguished on textural and mineralogical criteria, exhibiting either Zn–Fe-sulfide or Pb–Zn–Fe-sulfide internal cylindrical mineralogical zones. The chimneys mark vent sites in submarine grabens indicating focused flow-venting processes. The fossil chimneys have mineralogical and geological evolutionary features similar to their counterparts on the modern seafloor and other submarine hydrothermal vents. Black smoker vent fluids and seafloor tectonism played important roles for formation of the massive sulfide deposits in the Mesoproterozoic.We also report the first known, remarkably diverse assemblage of fossil microbialites from around and inside Precambrian vent chimneys, demonstrating that Proterozoic life flourished around submarine hot vents and deep within the chimney vent passages. Filamentous, spherical, rod, and coccus-shaped fossil microbes are preserved preferentially on sulfide precipitates. Based on the depth and setting of the fossil biota, the organisms that produced the microbialites were likely sulfate-reducing chemosynthetic and thermophyllic microbes. Textural and mineralogical evidence shows that biomineralization processes enhanced chimney growth and sulfide precipitation.Close association of microorganisms with sulfide chimneys in modern deep-sea hydrothermal vents and younger ophiolites has sparked speculation about whether life may have originated at similar vents. However, little is known about fossil equivalents of vent microfossils and black smoker chimneys from Earth's early evolution. The fossilized microorganisms from the Gaobanhe black smoker chimney sulfide deposits include thread-like filaments with branching and twisted forms and preserved organic carbon, representing fossilized remnants of microbial mats metabolized at high temperatures characteristic of venting fluids. The preservation of fossil microorganisms provides evidence that microbial populations were closely associated with black smoker chimneys in Earth's early history. The microbial population clearly constitutes the site for mediating mineral formation. These ancient microbial fossils lead to a much better understanding of early life on the deep seafloor. The discovery of the Mesoproterozoic microfossils within black-smoker hydrothermal chimneys indicates that hydrothermal activity around sea-floor vents supported dense microbial communities, and supports speculation that vent sites may have hosted the origin of life.  相似文献   

15.
REINHARD HESSE 《Sedimentology》1987,34(6):1055-1077
In the diagenetic history of calcareous sandstones, silicacementation and silicification may be followed by carbonatecementation and replacement and vice versa, and the change-over from one to the other may occur more than once. This is well illustrated by calcareous and siliciclastic turbidites of the Gault Formation (Aptian to Albian) of the Eastern Alps which have been interpreted as deep-sea trench plain and deep-sea fan deposits. In these turbidites silicification selectively affects ooids and a few other biogenic carbonate fragments rich in organic matter (algae and bryozoans) which form a small fraction of the bulk sediment. The type and sequence of diagenetic changes are largely controlled by host-rock composition and may vary vertically within individual beds as a result of compositional grading. In the carbonate turbidites, silicification follows widespread calcite cementation. The process is slow, resulting in relatively coarsely crystalline replacement quartz. In ooids with quartz nuclei, rim-quartz forms mostly monocrystalline ‘overgrowths’ by outward replacement of the concentrically laminated carbonate cortex. This type of silicification is often incomplete leaving parts of the ooid cortices unaffected. In quartz arenites and sublitharenites silicification precedes calcite cementation. There the process is rapid, forming microcrystalline quartz. Even if the ooid nucleus consists of quartz, a syntaxial ‘overgrowth’ does not normally form. The replacement quartz is almost always polycrystalline. Late-stage diagenetic calcite and dolomite which develop euhedral crystal shapes and cut across grain boundaries may replace the earlier secondary rim-quartz of the ooids as well as other minerals. Possible sources of the silica are pressure-solution of quartz, dissolution of opaline silica of radiolarian tests and of sponge spicules, and feldspar in the host bed. In a number of examples an increase in the degree of silicification can be observed towards the lower bedding planes of individual turbidites requiring an additional external source of silica which seems to necessitate cross-formational flow of pore solutions. Silicification in both the carbonate and the siliciclastic turbidites probably took place at about the same time; in the carbonate turbidites it was preceded, however, by calcite cementation, which significantly reduced porosity and permeability before silicification took place. The greater degree of alteration experienced by the Gault turbidites of the Falknis and Tasna Nappes, which are more internal structural units of the Alps (compared to the Flysch Zone of the Eastern Alps), is reflected by the growth of quartz ‘beards’ and spikes from the ooids in the direction perpendicular to maximum stress. This is the only case observed where the rim quartz of the ooids grows beyond the original grain boundaries.  相似文献   

16.
Stratiform banded and massive Pb-Zn-F-Ba mineralizations in metasediments of the Westphalian Cinco Villas formation (Basque Pyrenees) show several features related to Hercynian deformation and low-grade regional metamorphism. However, some primary depositional textures and structures are preserved. Minerals like pyrite reveal preregional metamorphic textures (framboidal-colloform pyrite with automorphic overgrowths, dendritic and atoll textures), typical of rapid precipitation from supersaturated solutions during hydrothermal-sedimentary activity. Deformation and subsequent micro- and mesoscale remobilization have caused morphological and textural changes in the mineralizations producing folding, mineral foliation, transposition, boudinages, piercements, etc., as well as the development of veinlike orebodies. Pyrite shows a general tendency toward cataclasis whereas sphalerite, galena, and chalcopyrite exhibit a variety of microstructures (subgrains, twining, recrystallization, etc.) indicative of ductile deformation. Microscopy suggests the deformation of more plastic sulfide occurred mainly by a dislocation-type mechanism at low temperatures (350°C), which are compatible with the regional metamorphism recorded in the host rocks.  相似文献   

17.
The kerogen of a sample of Estonian Kukersite (Ordovician) was examined by spectroscopic (solid state 13C NMR, FTIR) and pyrolytic (“off-line”, flash) methods. This revealed an important contribution of long, linear alkyl chains in Kukersite kerogen. The hydrocarbons formed upon pyrolysis are dominated by n-alkanes and n-alk-1-enes and probably reflect a major contribution of selectivity preserved, highly aliphatic, resistant biomacromolecules from the outer cell walls of Gloeocapsomorpha prisca. This is consistent with the abundant presence of this fossilized organism in Kukersite kerogen. In addition high amounts of phenolic compounds were identified in the pyrolysates. Series of non-methylated, mono-, di- and trimethylated 3-n-alkylphenols, 5-n-alkyl-1,3-benzenediols and n-alkylhydroxybenzofurans were identified. All series of phenolic compounds contain long (up to C19), linear alkyl side-chains. Kukersite kerogen is, therefore, an aliphatic type II/I kerogen, despite the abundance of free phenolic moieties. This study shows that phenol-derived moieties are not necessarily associated with higher plant-derived organic matter.The flash pyrolysate of Kukersite kerogen was also compared with that of the kerogen of the Guttenberg Oil Rock (Ordovician) which is also composed of accumulations of fossilized G. prisca. Similarities in the distributions of hydrocarbons and sulphur compounds were noted, especially for the C1–C6 alkylbenzene and alkylthiophene distributions. However, no phenolic compounds were detected in the flash pyrolysate of the Guttenberg kerogen. Possible explanations for the observed similarities and differences are discussed.  相似文献   

18.
Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (Ea) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in Ea distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad Ea distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma−1 and the generation rate curves and cumulative yield curves thus obtained were compared.  相似文献   

19.
Proterozoic ministromatolites with radial-fibrous fabric   总被引:5,自引:0,他引:5  
Small digitate stromatolites with diameters in the range of 0·2–20 mm (ministromatolites) are common in Early and Middle Proterozoic carbonate sequences, and extend stratigraphically from the Archaean to the Holocene. An occurrence of columnar and stratiform types exhibiting a primary or early diagenetic radial-fibrous fabric and microscopically crinkled (microcrenate) lamination is described from the ? 1·9 Gyr old Belcher Supergroup (McLeary Formation) in southeastern Hudson Bay, Canada. The structures, which can be considered to be a variety of tufa, are unusually well preserved because of early diagenetic silicification. Columnar types are referable to Pseudogymnosolen (Asperia), and are morphologically similar to other occurrences of these taxa in coeval dolostones in northwestern and eastern Canada, where the fabric is normally preserved by a secondary mosaic of dolomite. The textural evidence of angulate cross-sections and rectilinear divergent patterns indicates that the radial-fibrous fabric represents primary or very early diagenetic precipitation, and that pseudogymnosolenids with mosaic dolomite originally also had radial-fibrous structure. The precipitation may have been within, or on, microbial mats.  相似文献   

20.
The paper develops the argument that quartz crystal aggregates formed in vugs along the underside of quartz veins, filling faults, cut across the strike trend of the metasediments of the Northern Urals crystalline section. Crystal growth in the vugs was possible because hydrothermal solutions, presumably rich in carbon dioxide, were able to leach large quantities of silica out of the wall rock. It is noted, also, that the silica which was emplaced as thin sheets along the cleavage planes did not react with the country rock. Presumably, this was consequent upon the fact that this (earlier) generation of hydrothermal solutions was supersaturated with respect to silica, and was therefore incapable of supporting leaching reactions. The quartz in the sheets which follow the cleavage planes is amorphous; this may be evidence of the supersaturated state of the solutions. — M.E. Burgunker  相似文献   

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