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1.
On July 8, 1976, eruptive activity broke out at la Soufrière de Guadeloupe (F.W.I) after about one year of increasing seismic activity. Seismic activity continued to increase until August 1976, reaching more than 1500 events (a 200-fold increase over the preceding quiet period of a few years) and an energy output of about 1017 ergs in a day. A total of 26 major phreatic eruptions similar to the July 8 outburst took place during an eight-months period. The steam blasts that characterized the eruptions gave rise to particle- and sometimes block-charged plumes that deposited an estimated 106 m3 of solids. The H2O-rich gases emitted during the blasts presumably contained other gases (H2S, SO2, CO2...) that were partly adsorbed on solid particles. All material was erupted at temperatures of the order of 100° to 200°C.The observation of vertical migration of earthquake foci in less than a few hours and over about 6 km depth, and of abnormal variations of the geomagnetic field, indicate a deep energy source for the phreatic eruptions. A small proportion of the gases adsorbed on solid particles had a magmatic origin. However, most of the steam and the tephra seemed to originate from superficial levels of a hydrothermal system. Similar phreatic eruptions have occurred several times in recorded history. In the case of la Soufrière, the origin of the phreatic eruptions is best described by an abnormal energy input (versus steady-state) from a crustal magma chamber. The occurrence of truly magmatic eruptions is presumably inhibited by an extensive hydrothermal system. The abrupt release of more power from the magma chamber could have resulted in an explosive pyroclastic eruption.Substantial improvement of the Guadeloupe volcano observatory has followed the 1975–1977 crisis. Permanent telemetered geophysical networks and regular geochemical observations have provided a five year data base of the volcano behavior in its noneruptive state which can be compared to crisis situations.  相似文献   

2.
Detailed geochemistry supported by geologic mapping has been used to investigate Sulphur Springs, an acid-sulfate hot spring system that issues from the western flank of the resurgent dome inside Valles Caldera. The most intense activity occurs at the intersection of faults offsetting caldera-fill deposits and post-caldera rhyolites. Three geothermal wells in the area have encountered pressures <1 MPa and temperatures of 200°C at depths of 600 to 1000 m. Hot spring and fumarole fluids may discharge at boiling temperatures with pH 1.0 and SO4 8000 mg/l. These conditions cause argillic alterations throughout a large area.Non-condensible gases consist of roughly 99% CO2 with minor amounts of H2S, H2, and CH4. Empirical gas geothermometry suggests a deep reservoir temperature of 215 to 280°C. Comparison of 13C and 18O between CaCO3 from well cuttings and CO2 from fumarole steam indicates a fractionation temperature between 200 and 300°C by decarbonation of hydrothermally altered Paleozoic limestone and vein calcite in the reservoir rocks. Tritium concentrations obtained from steam condensed in a mudpot and deep reservoir fluids (Baca #13, 278°C) are 2.1 and 1.0 T.U. respectively, suggesting the steam originates from a reservoir whose water is mostly >50 yrs old. Deuterium contents of fumarole steam, deep reservoir fluid, and local meteoric water are practically identical even though 18O contents range through 4‰, thus, precipitation on the resurgent dome of the caldera could recharge the hydrothermal system by slow percolation. From analysis of D and 18O values between fumarol steam and deep reservoir fluid, steam reaches the surface either (1) by vaporizing relatively shallow groundwater at 200°C or (2) by means of a two-stage boiling process through an intermediate level reservoir at roughly 200°C.Although many characteristics of known vapor-dominated geothermal systems are found at Sulphur Springs, fundamental differences exist in temperature and pressure of our postulated vapor-zone. We propose that the reservoir beneath Sulphur Springs is too small or too poorly confined to sustain a “true” vapor-dominated system and that the Sulphur Springs system may be a “dying” vapor-dominated system that has practically boiled itself dry.  相似文献   

3.
The Teide volcano (3717 m) is the central structure of the island of Tenerife and at present its morphology is that of a stratovolcano which has grown on a large caldera with a collapse 17 km in diameter, which was generated some 0.6 million years ago.The different studies that have been carried out seem to indicate that, in a oversimplified model, there is an intermediate magma chamber with an approximate volume of 30 km3 and located 2–3 km below the actual base of the caldera, i.e., almost at sea level, with a temperature of 430 ± 50°C, and a pressure of 400 ± 100 bar.The summit fumarole emissions are 85°C and are formed mainly of CO2 with small amounts of sulphur species, H2, CH4 and He. The water vapor (68–82%) emitted with the gases comes from the vaporization of a perched aquifer in the upper cone, as shown by the isotopic analyses.  相似文献   

4.
The Sierra La Primavera, a late Pleistocene rhyolitic caldera complex in Jalisco, México, contains fumaroles and large-discharge 65°C hot springs that are associated with faults related to caldera collapse and to later magma insurgence. The nearly-neutral, sodium bicarbonate, hot springs occur at low elevations at the margins of the complex, whereas the water-rich fumaroles are high and central.The Comisión Federal de Electricidad de México (CFE) has recently drilled two deep holes at the center of the Sierra (PR-1 and Pr-2) and one deep hole at the western margin. Temperatures as high as 285°C were encountered at 1160 m in PR-1, which produced fluids with 820 to 865 mg/kg chloride after flashing to one atmosphere. Nearby, PR-2 encountered temperatures to 307°C at 2000 m and yielded fluids with chloride contents fluctuating between 1100 and 1560 mg/kg after flashing. Neither of the high-temperature wells produced steam in commercial quantities. The well at the western margin of the Sierra produced fluids similar to those from the hot springs. The temperature reached a maximum of 100°C near the surface and decreased to 80°C at 2000 m.Various geothermometers (quartz conductive, Na/K, Na-K-Ca, δ18O(SO4-H2O) and D/H (steam-water) all yield temperatures of 170 ± 20°C when applied to the hot spring waters, suggesting that these spring waters flow from a large shallow reservoir at this temperature. Because the hot springs are much less saline than the fluids recovered in PR-1 and PR-2, the mixed fluid in the shallow reservoir can contain no more than 10–20% deep fluid. This requires that most of the heat is transferred by steam. There is probably a thin vapor-dominated zone in the central part of the Sierra, through which steam and gases are transferred to the overlying shallow reservoir. Fluids from this reservoir cool from 170°C to 65°C by conduction during the 5–7 km of lateral flow to the hot springs.  相似文献   

5.
Kawah Putih is a summit crater of Patuha volcano, West Java, Indonesia, which contains a shallow, 300 m-wide lake with strongly mineralized acid–sulfate–chloride water. The lake water has a temperature of 26–34°C, pH=<0.5–1.3, Stot=2500–4600 ppm and Cl=5300–12 600 ppm, and floating sulfur globules with sulfide inclusions are common. Sulfur oxyanion concentrations are unusually high, with S4O62−+S5O62−+S6O62−=2400 – 4200 ppm. Subaerial fumaroles (<93°C) on the lake shore have low molar SO2/H2S ratios (<2), which is a favorable condition to produce the observed distribution of sulfur oxyanion species. Sulfur isotope data of dissolved sulfate and native sulfur show a significant 34S fractionation (ΔSO4–Se of 20‰), probably the result of SO2 disproportionation in or below the lake. The lake waters show strong enrichments in 18O and D relative to local meteoric waters, a result of the combined effects of mixing between isotopically heavy fluids of deep origin and meteoric water, and evaporation-induced fractionation at the lake surface. The stable-isotope systematics combined with energy-balance considerations support very rapid fluid cycling through the lake system. Lake levels and element concentrations show strong seasonal fluctuations, indicative of a short water residence time in the lake as well.Thermodynamic modeling of the lake fluids indicates that the lake water is saturated with silica phases, barite, pyrite and various Pb, Sb, Cu, As, Bi-bearing sulfides when sulfur saturation is assumed. Precipitating phases predicted by the model calculations are consistent with the bulk chemistry of the sulfur-rich bottom sediments and their identified mineral phases. Much of the lake water chemistry can be explained by congruent rock dissolution in combination with preferential enrichments from entering fumarolic gases or brines and element removal by precipitating mineral phases, as indicated by a comparison of the fluids, volcanic rocks and lake bed sediment.Flank springs on the mountain at different elevations vary in composition, and are consistent with local rock dissolution as a dominant factor and pH-dependent element mobility. Discharges of warm sulfate- and chloride-rich water at the highest elevation and a near-neutral spring at lower level may contain a small contribution of crater-lake water. The acid fluid-induced processes at Patuha have led to the accumulation of elements that are commonly associated with volcano-hosted epithermal ore deposits. The dispersal of heavy metals and other potentially toxic elements from the volcano via the local drainage system is a matter of serious environmental concern.  相似文献   

6.
Shirouma-Oike volcano, a Quaternary composite volcano in central Japan, consists mostly of calc-alkaline andesitic lavas and pyroclastic rocks. Products of the earlier stage of the volcano (older group) are augite-hypersthene andesite. Hornblende crystallized during the later stage of this older group, whereas biotite and quartz crystallized in the younger group.Assemblages of phenocrysts in disequilibrium, such as magnesian olivine(Fo30)/quartz, iron-rich hypersthene(En55)/iron-poor augite(Wo43.5, En42.5, Fs14.0), and two different types of zoning on the rim of clinopyroxene are found in a number of rocks. Detailed microprobe analyses of coexisting minerals reveal that phenocrysts belong to two distinctly different groups; one group includes magnesian olivine + augite which crystallized from a relatively high-temperature (above 1000°C) basaltic magma; the second group, which crystallized from relatively low temperature (about 800°C) dacitic to andesitic magma, includes hypersthene + hornblende + biotite + quartz + plagioclase + titanomagnetite ± ilmenite (in the younger group) and hypersthene + augite + plagioclase + titanomagnetite ± hornblende (in the older group). The temperature difference between the two magmas is clarified by Mg/Fe partition between clinopyroxene and olivine, and Fe-Ti oxides geothermometer. The compositional zoning of minerals, such as normal zoning of olivine and magnesian clinopyroxene, and reverse zoning of orthopyroxene, indicate that the basaltic and dacitic-andesitic magmas were probably mixed in a magma reservoir immediately before eruption. It is suggested that the basaltic magma was supplied intermittently from a deeper part to the shallower magma reservoir, in in which dacitic-andesitic magma had been fractionating.  相似文献   

7.
Comparison of the chemical characteristics of spring and river water draining the flanks of Poa´s Volcano, Costa Rica indicates that acid chloride sulfate springs of the northwestern flank of the volcano are derived by leakage and mixing of acid brines formed in the summit hydrothermal system with dilute flank groundwater. Acid chloride sulfate waters of the Rio Agrio drainage basin on the northwestern flank are the only waters on Poa´s that are affected by leakage of acid brines from the summit hydrothermal system. Acid sulfate waters found on the northwestern flank are produced by the interaction of surface and shallow groundwater with dry and wet acid deposition of SO2 and H2SO4 aerosols, respectively. The acid deposition is caused by a plume of acid gases that is released by a shallow magma body located beneath the active crater of Poa´s.No evidence for a deep reservoir of neutral pH sodium chloride brine is found at Poa´s. The lack of discharge of sodium chloride waters at Poa´s is attributed to two factors: (1) the presence of a relatively volatile-rich magma body degassing at shallow depths (< 1 km) into a high level summit groundwater system; and (2) the hydrologic structure of the volcano in which high rates of recharge combine with rapid lateral flow of shallow groundwater to prevent deep-seated sodium chloride fluids from ascending to the surface. The shallow depth of the volatile-rich magma results in the degassing of large quantities of SO2 and HCl. These gases are readily hydrolyzed and quickly mix with meteoric water to form a reservoir of acid chloride-sulfate brine in the summit hydrothermal system. High recharge rates and steep hydraulic gradients associated with elevated topographic features of the summit region promote lateral flow of acid brines generated in the summit hydrothermal system. However, the same high recharge rates and steep hydraulic gradients prevent lateral flow of deep-seated fluids, thereby masking the presence of any sodium chloride brines that may exist in deeper parts of the volcanic edifice.Structural, stratigraphic, and topographic features of Poa´s Volcano are critical in restricting flow of acid brines to the northwestern flank of the volcano. A permeable lava-lahar sequence that outcrops in the Rio Agrio drainage basin forms a hydraulic conduit between the crater lake and acid chloride sulfate springs. Spring water residence times are estimated from tritium data and indicate that flow of acid brines from the active crater to the Rio Agrio source springs is relatively rapid (3 to 17 years). Hydraulic conductivity values of the lava-lahar sequence calculated from residence time estimates range from 10−5 to 10−7 m/s. These values are consistent with hydraulic conductivity values determined by aquifer tests of fractured and porous lava/pyroclastic sequences at the base of the northwestern flank of the volcano.Fluxes of dissolved rock-forming elements in Rio Agrio indicate that approximately 4300 and 1650 m3 of rock are removed annually from the northwest flank aquifer and the active crater hydrothermal system, respectively. Over the lifetime of the hydrothermal system (100's to 1000's of years), significant increases in aquifer porosity and permeability should occur, in marked contrast to the reduction in permeability that often accompanies hydrothermal alteration in less acidic systems. Average fluxes of fluoride, chloride and sulfur calculated from discharge and compositional data collected in the Rio Agrio drainage basin over the period 1988–1990 are approximately 2, 38 and 30 metric tons/day. These fluxes should be representative of minimum volatile release rates at Poa´s in the last 10 to 20 years.  相似文献   

8.
Ambae (also known as Aoba), is a 38 × 16 km2 lozenge-shaped island volcano with a coastal population of around 10 000. At the summit of the volcano is lake Voui — one of the largest active crater lakes worldwide, with 40 × 106 m3 of acidic water perched 1400 m a.s.l. After more than 300 years of dormancy, Ambae volcano reawakened with phreatic eruptions through Voui in 1995, and culminating in a series of surtseyan eruptions in 2005, followed by a rapid and spectacular colour change of the lake from light blue to red in 2006. Integrating lake water chemistry with new measurements of SO2 emissions from the volcano during the 2005–2006 eruptive period helps to explain the unusual and spectacular volcanic activity of Ambae — initially, a degassed magma approached the lake bed and triggered the surtseyan eruption. Depressurization of the conduit facilitated ascent of volatile-rich magma from the deeper plumbing system. The construction of a cone during eruption and the high degassing destabilised the equilibrium of lake stratification leading to a limnic event and subsequently the spectacular colour change.  相似文献   

9.
We examine seismic and eruptive activity at Fuego Volcano (14°29′N, 90° 53′W), a 3800-m-high stratovolcano located in the active volcanic arc of Guatemala. Eruptions at Fuego are typically short-lived vulcanian eruptions producing ash falls and ash flows of high-alumina basalt. From February 1975 to December 1976, five weak ash eruptions occurred, accompanied by small earthquake swarms. Between 0 and 140 (average ≈ 10) A-type or high-frequency seismic events per day with M > 0.5 were recorded during this period. Estimated thermal energies for each eruption are greater by a factor of 106 than cumulative seismic energies, a larger ratio than that reported for other volcanoes.Over 4000 A-type events were recorded January 3–7, 1977 (cumulative seismic energy ≈ 109 joules), yet no eruption occurred. Five 2-hour-long pulses of intense seismicity separated by 6-hour intervals of quiescence accounted for the majority of events. Maximum likelihood estimates of b-values range from 0.7 ± 0.2 to 2.1 ± 0.4 with systematically lower values corresponding to the five intense pulses. The low values suggest higher stress conditions.During the 1977 swarm, a tiltmeter located 6 km southeast of Fuego recorded a 14 ± 3 microradian tilt event (down to SW). This value is too large to represent a simple change in the elastic strain field due to the earthquake swarm. We speculate that the earthquake swarm and tilt are indicative of subsurface magma movement.  相似文献   

10.
Surface partial pressure of CO2 (pCO2), temperature, salinity, nutrients, and chlorophyll a were measured in the East China Sea (ECS; 31°30′–34°00′N to 124°00′–127°30′E) in August 2003 (summer), May 2004 (spring), October 2004 (early fall), and November 2005 (fall). The warm and saline Tsushima Warm Current was observed in the eastern part of the survey area during four cruises, and relatively low salinity waters due to outflow from the Changjiang (Yangtze River) were observed over the western part of the survey area. Surface pCO2 ranged from 236 to 445 μatm in spring and summer, and from 326 to 517 μatm in fall. Large pCO2 (values >400 μatm) occurred in the western part of the study area in spring and fall, and in the eastern part in summer. A positive linear correlation existed between surface pCO2 and temperature in the eastern part of the study area, where the Tsushima Warm Current dominates; this correlation suggests that temperature is the major factor controlling surface pCO2 distribution in that area. In the western part of the study area, however, the main controlling factor is different and seasonally complex. There is large transport in this region of Changjiang Diluted Water in summer, causing low salinity and low pCO2 values. The relationship between surface pCO2 and water stability suggests that the amount of mixing and/or upwelling of CO2-rich water might be the important process controlling surface pCO2 levels during spring and fall in this shallow region. Sea–air CO2 flux, based on the application of a Wanninkhof [1992. Relationship between wind speed and gas exchange over the ocean. Journal of Geophysical Research 97, 7373–7382] formula for gas transfer velocity and a set of monthly averaged satellite wind data, were −5.04±1.59, −2.52±1.81, 1.71±2.87, and 0.39±0.18 mmol m−2 d−1 in spring, summer, early fall, and fall, respectively, in the northern ECS. The ocean in this study area is therefore a carbon sink in spring and summer, but a weak source or in equilibrium with the atmosphere in fall. If the winter flux value is assumed to have been the mean of autumnal and vernal values, then the northern ECS absorbs about 0.013 Pg C annually. That result suggests that the northern ECS is a net sink for atmospheric CO2, a result consistent with previous studies.  相似文献   

11.
Secular variations in 13C/12C ratios and chemical compositions of gas samples from October 1986 to July 1992 are reported from a 92–95 °C steam well located about 3 km north of Mt. Mihara, an active volcano on Izu-Oshima Island, Japan. The δ13C value steeply increased from −2.97‰ (relative to PDB carbonate) in December 1986 to −1.15‰ in March 1988 and then gradually decreased to −1.75‰ in July 1992. Over the same period, the CO2 content changed similarly with time, even though the experimental error is relatively large. These variations are consistent with helium isotope changes. Initially rapid and then slow enhancements of 3He/4He ratio, δ13C value and CO2 content are invoked by violent eruptions of Izu-Oshima volcano from 15 November to 18 December 1986. After the eruptive activity, depletion of magmatic gas emission and subsequent mixing with crustal fluids in the hydrothermal system may produce the gradual decreases of 3He/4He ratio, δ13C value and CO2 content. Taking into account the rates of these decreases, we suggest that helium and carbon isotope ratios will return to the situation of before the magmatic eruption within 15 years.  相似文献   

12.
Submersible investigations along the East Rift segments, the Pito Deep and the Terevaka transform fault of the Easter microplate eastern boundary, and on a thrust-fault area of the Nazca Plate collected a variety of basalts and dolerites. The volcanics consist essentially of depleted (N-MORB), transitional (T-MORB) and enriched (E-MORB) basalts with low (0.01−0.1, < 0.7), intermediate (0.12–0.25, 0.7–1.2) and high (> 0.25, > 1.2–2) K/Ti and(La/Sm)N ratios, respectively. The Fe-Ti-rich ferrobasalt encountered among the N-MORBs are found on the Pito Deep Central volcano, on the Terevaka intra-transform ridge, on the ancient (< 2.5 Ma) Easter microplate (called EMP, comprising the East Rift Inner pseudofaults and Pito Deep west walls) and on thrust-fault crusts. The most enriched (T- and E-MORB) volcanics occur along the East Rift at 25 °50′–27 °S (called 26 °S East Rift) and on the Pito seamount located near the tip of the East Rift at 23 °00′–23 °40′S (called 23 °S East Rift). The diversity in incompatible element ratios of the basalts in relation to their structural setting suggests that the volcanics are derived from a similar heterogenous mantle which underwent variable degrees of partial melting and magma mixing. In addition the Pito seamount volcanics have undergone less crystal fractionation (< 20%) than the lavas from the other Easter microplate structures (up to 35–45%). The tectonic segmentation of the East Rift observed between 23 and 27 °S corresponds to petrological discontinuities related to Mg# variations and mantle melting conditions. The highest Mg# (> 61) are found on topographic highs (2000–2300 m) and lower values (Mg# < 56) at the extremities of the East Rift segments (2500–5600 m depths). The deepest area (5600 m) along the East Rift is located at 23 °S and coincides with a Central volcano constructed on the floor of the Pito Deep. Three major compositional variabilities of the volcanics are observed along the East Rift segments studied: (1) the 26 °S East Rift segment where the volcanics have intermediate Na8 (2.5–2.8%) and Fe8 (8.5–11%) contents; (2) the 23 °S East Rift segment (comprising Pito seamount and Pito Deep Central volcano) which shows the highest (2.9–3.4%) values of Na8 and a low (8–9%) Fe8 content; and (3) the 25 °S (at 24 °50′–26 °10′S) and the 24 °S (at 24 °10′–25 °S) East Rift segments where most of the volcanics have low to intermediate Na8 (2.6–2.0%) and a high range of Fe8 (9–13%) contents. When modeling mantle melting conditions, we observed a relative increase in the extent of partial melting and decreasing melting pressure. These localized trends are in agreement with a 3-D type diapiric upwelling in the sense postulated by Niu and Batiza (1993). Diapiric mantle upwelling and melting localized underneath the 26, 25 and 23 °S (Pito seamount and Central volcano) East Rift segments are responsable for the differences observed in the volcanics. The extent of partial melting varies from 14 to 19% in the lithosphere between 18 and 40 km deep as inferred from the calculated initial (Po=16kbar) and final melting (Pf=7kbar) pressures along the various East Rift segments. The lowest range of partial melting (14–16%) is confined to the volcanics from 23 °S East Rift segment including the Pito seamount and the Central volcano. The Thrust-fault area, and the Terevaka intra-transform show comparable mantle melting regimes to the 25 and 26 °S East Rift segments. The older lithosphere of the EMP interior is believed to have been the site of high partial melting (17–20%) confined to the deeper melting area (29–50 km). This increase in melting with increasing pressure is similar to the conditions encountered underneath the South East Pacific Rise (13–20 °S).  相似文献   

13.
Appalachian Deep Core Hole 2 (ADCOH-2) penetrated part of one of the most persistent and important tectonostratigraphic belts in the southern Appalachians—the Brevard-Chauga belt in South Carolina. The Brevard-Chauga belt is a subdivision of the Inner Piedmont and it includes the Brevard fault zone. The 307 m core contains four imbricated slices of Early Ordovician Henderson Gneiss and metasedimentary rocks of the Chauga River Formation. Aqueous (NaCl–CaCl2) inclusions and CO2–CH4-rich inclusions present in syntectonic quartz veins in the metasedimentary units, together with garnet-biotite geothermometry, provide information on the P-T conditions during uplift. Garnet-biotite geothermometry in the Brevard metasiltstone indicates a crystallization temperature of 466±52 °C, which together with published 40Ar/39Ar hornblende data from the Chauga belt, are interpreted as a Neoacadian (late Devonian) garnet crystallization age. High-density CO2-rich fluid inclusion isochores indicate a pressure of 4.5 kbar at 466±52 °C at this time. A Rb–Sr muscovite model age of 302 Ma in retrograde mylonitic Henderson Gneiss is interpreted as an Alleghanian recrystallization age. Fluid inclusions record a 2.5 kbar decompression event at this time, consistent with thrust assembly of the tectonostratigraphic units in the core.  相似文献   

14.
Geothermal gases from submarine and subaerial hot springs in Ensenada, Baja California Norte, Mexico, were sampled for determination of gas chemistry and helium, nitrogen and stable carbon isotope composition. The submarine hot spring gas is primarily nitrogen (56.1% by volume) and methane (43.5% by volume), whereas nearby subaerial hot spring gases are predominantly nitrogen (95–99% by volume). The N2/Ar ratios and σ 15N values of the subaerial hot spring gas indicate that it is atmospheric air, depleted in oxygen and enriched in helium. The submarine hot spring gas is most probably derived from marine sediments of Cretaceous age rich in organic matter. CH4 is a major component of the gas mixture (σ 13C = −44.05%0), with only minor amounts of CO2 (σ13C= −10.46%0). The σ15N of N2 is + 0.2%0 with a very high N2/Ar ratio of 160. The calculated isotopic equilibra tion temperature for CH4---CO2 carbon exchange at depth in the Punta Banda submarine geothermal field is approximately 200°C in agreement with other geothermometry estimates. The 3He/4He ratios of the hot spring gases range from 0.3 to 0.6 times the atmospheric ratio, indicating that helium is predominantly derived from the radioactive decay of U and Th within the continental crust. Thus, not all submarine hydrothermal systems are effective vehicles for mantle degassing of primordial helium.  相似文献   

15.
Paricutin volcano is a monogenetic volcano whose birth and growth were observed by modern volcanological techniques. At the time of its birth in 1943, the seismic activity in central Mexico was mainly recorded by the Wiechert seismographs at the Tacubaya seismic station in Mexico City about 320 km east of the volcano area. In this paper we aim to find any characteristics of precursory earthquakes of the monogenetic eruption. Though there are limits in the available information, such as imprecise location of hypocenters and lack of earthquake data with magnitudes under 3.0.The available data show that the first precursory earthquake occurred on January 7, 1943, with a magnitude of 4.4. Subsequently, 21 earthquakes ranging from 3.2 to 4.5 in magnitude occurred before the outbreak of the eruption on February 20. The (S - P) durations of the precursory earthquakes do not show any systematic changes within the observational errors. The hypocenters were rather shallow and did not migrate.The precursory earthquakes had a characteristic tectonic signature, which was retained through the whole period of activity. However, the spectra of the P-waves of the Paricutin earthquakes show minor differences from those of tectonic earthquakes. This fact helped in the identification of Paricutin earthquakes. Except for the first shock, the maximum earthquake magnitudes show an increasing tendency with time towards the outbreak. The total seismic energy released by the precursory earthquakes amounted to 2 × 1019 ergs. Considering that statistically there is a threshold of cumulative seismic energy release (1017–18ergs) by precursory earthquakes in polygenetic volcanoes erupting after long quiescence, the above cumulative energy is exceptionally large. This suggests that a monogenetic volcano may need much more energy to clear the way of magma passage to the earth surface than a polygenetic one.The magma ascent before the outbreak of Paricutin volcano is interpretable by a model of magma-filled crack formation proposed by Weertman, based on seismic data and other field observations.  相似文献   

16.
Medicine Lake Volcano (MLV), located in the southern Cascades ∼ 55 km east-northeast of contemporaneous Mount Shasta, has been found by exploratory geothermal drilling to have a surprisingly silicic core mantled by mafic lavas. This unexpected result is very different from the long-held view derived from previous mapping of exposed geology that MLV is a dominantly basaltic shield volcano. Detailed mapping shows that < 6% of the ∼ 2000 km2 of mapped MLV lavas on this southern Cascade Range shield-shaped edifice are rhyolitic and dacitic, but drill holes on the edifice penetrated more than 30% silicic lava. Argon dating yields ages in the range ∼ 475 to 300 ka for early rhyolites. Dates on the stratigraphically lowest mafic lavas at MLV fall into this time frame as well, indicating that volcanism at MLV began about half a million years ago. Mafic compositions apparently did not dominate until ∼ 300 ka. Rhyolite eruptions were scarce post-300 ka until late Holocene time. However, a dacite episode at ∼ 200 to ∼ 180 ka included the volcano's only ash-flow tuff, which was erupted from within the summit caldera. At ∼ 100 ka, compositionally distinctive high-Na andesite and minor dacite built most of the present caldera rim. Eruption of these lavas was followed soon after by several large basalt flows, such that the combined area covered by eruptions between 100 ka and postglacial time amounts to nearly two-thirds of the volcano's area. Postglacial eruptive activity was strongly episodic and also covered a disproportionate amount of area. The volcano has erupted 9 times in the past 5200 years, one of the highest rates of late Holocene eruptive activity in the Cascades. Estimated volume of MLV is ∼ 600 km3, giving an overall effusion rate of ∼ 1.2 km3 per thousand years, although the rate for the past 100 kyr may be only half that. During much of the volcano's history, both dry HAOT (high-alumina olivine tholeiite) and hydrous calcalkaline basalts erupted together in close temporal and spatial proximity. Petrologic studies indicate that the HAOT magmas were derived by dry melting of spinel peridotite mantle near the crust mantle boundary. Subduction-derived H2O-rich fluids played an important role in the generation of calcalkaline magmas. Petrology, geochemistry and proximity indicate that MLV is part of the Cascades magmatic arc and not a Basin and Range volcano, although Basin and Range extension impinges on the volcano and strongly influences its eruptive style. MLV may be analogous to Mount Adams in southern Washington, but not, as sometimes proposed, to the older distributed back-arc Simcoe Mountains volcanic field.  相似文献   

17.
Since late 2002, a continuous automatic monitoring network is operating in Tuscany, Central Italy, to investigate the geochemical response of selected aquifers to local seismic activity. The monitoring is aimed at identifying possible earthquake geochemical precursors. The network is currently constituted by six stations, all equipped with sensors for the measurement of temperature, pH, redox potential, electrical conductivity, CO2 and CH4 dissolved concentration, that have been installed in the areas of highest seismic risk of the region. By combining geochemical data gathered from the automatic station of Gallicano (Garfagnana, Northern Tuscany), and obtained via chemical analyses of spring water samples collected during periodic field surveys in the area surrounding this station, the most significant aspects of the deep fluid circulation paths feeding the Gallicano thermo-mineral system have been investigated, and the geochemical baseline of the Gallicano spring defined. The CO2 continuous signal recorded by the Gallicano automatic station has been then processed over the period 2003–2013 in the search for anomalies possibly related to local seismic activity. A substantial anomaly in CO2 content has been observed at Gallicano in conjunction with the Alpi Apuane earthquake (M = 5.2) of 21 June 2013.  相似文献   

18.
Prior to the recent discovery of high-temperature vanadium sublimates at the fumaroles of Izalco volcano, El Salvador, the only vanadium minerals known were those formed at low-temperature surface conditions. Six new vanadium compounds have already been discovered at Izalco volcano, and five of these have been elevated to mineral status. Two of the minerals are among the most vanadium-rich compounds known in nature.Field studies and studies of the crystal chemistry of the sublimate phases have allowed delineation of the conditions of exsolution of vanadium-bearing gases from the magma and conditions of sublimation of the vanadium compounds. A vanadium halogen or oxyhalogen gas phase was exsolved from a basaltic magma when the magma was 550 m below the summit crater. As the gas rose to the fumaroles and mixed with the atmosphere, the oxygen fugacity rose from that of the magma to at least 10−3,5 bar. At the fumaroles, the vanadium compounds sublimated at various temperatures, but a minimum temperature of 760° can be determined for one of the phases based on geothermometry determined from phase relations in the system CuO-V2O5. The studies have demonstrated that a vanadium-bearing gas can segregate from a magma with normal basaltic concentrations of vanadium.  相似文献   

19.
Concentrations of chloride and sulfate and pH in the hot crater lake (Laguna Caliente) at Poás volcano and in acid rain varied over the period 1993–1997. These parameters are related to changes in lake volume and temperature, and changes in summit seismicity and fumarole activity beneath the active crater. During this period, lake level increased from near zero to its highest level since 1953, lake temperature declined from a maximum value of 70°C to a minimum value of 25°C, and pH of the lake water increased from near zero to 1.8. In May 1993 when the lake was nearly dry, chloride and sulfate concentrations in the lake water reached 85,400 and 91,000 mg l−1, respectively. Minimum concentrations of chloride and sulfate after the lake refilled to its maximum volume were 2630 and 4060 mg l−1, respectively. Between January 1993 and May 1995, most fumarolic activity was focused through the bottom of the lake. After May 1995, fumarolic discharge through the bottom of the lake declined and reappeared outside the lake within the main crater area. The appearance of new fumaroles on the composite pyroclastic cone coincided with a dramatic decrease in type B seismicity after January 1996. Between May 1995 and December 1997, enhanced periods of type A seismicity and episodes of harmonic tremor were associated with an increase in the number of fumaroles and the intensity of degassing on the composite pyroclastic cone adjacent to the crater lake. Increases in summit seismic activity (type A, B and harmonic tremor) and in the height of eruption plumes through the lake bottom are associated with a period of enhanced volcanic activity during April–September 1994. At this time, visual observations and remote fumarole temperature measurements suggest an increase in the flux of heat and gases discharged through the bottom of the crater lake, possibly related to renewed magma ascent beneath the active crater. A similar period of enhanced seismic activity that occurred between August 1995 and January 1996, apparently caused fracturing of sealed fumarole conduits beneath the composite pyroclastic cone allowing the focus of fumarolic degassing to migrate from beneath the lake back to the 1953–1955 cone. Changes in the chemistry of summit acid rain are correlated changes in volcanic activity regardless of whether fumaroles are discharging into the lake or are discharging directly into the atmosphere.  相似文献   

20.
The edifice of Mount Rainier, an active stratovolcano, has episodically collapsed leading to major debris flows. The largest debris flows are related to argillically altered rock which leave areas of the edifice prone to failure. The argillic alteration results from the neutralization of acidic magmatic gases that condense in a meteoric water hydrothermal system fed by the melting of a thick mantle of glacial ice. Two craters atop a 2000-year-old cone on the summit of the volcano contain the world's largest volcanic ice-cave system. In the spring of 1997 two active fumaroles (T=62°C) in the caves were sampled for stable isotopic, gas, and geochemical studies.Stable isotope data on fumarole condensates show significant excess deuterium with calculated δD and δ18O values (−234 and −33.2‰, respectively) for the vapor that are consistent with an origin as secondary steam from a shallow water table which has been heated by underlying magmatic–hydrothermal steam. Between 1982 and 1997, δD of the fumarole vapor may have decreased by 30‰.The compositions of fumarole gases vary in time and space but typically consist of air components slightly modified by their solubilities in water and additions of CO2 and CH4. The elevated CO2 contents (δ13CCO2=−11.8±0.7‰), with spikes of over 10,000 ppm, require the episodic addition of magmatic components into the underlying hydrothermal system. Although only traces of H2S were detected in the fumaroles, most notably in a sample which had an air δ13CCO2 signature (−8.8‰), incrustations around a dormant vent containing small amounts of acid sulfate minerals (natroalunite, minamiite, and woodhouseite) indicate higher H2S (or possibly SO2) concentrations in past fumarolic gases.Condensate samples from fumaroles are very dilute, slightly acidic, and enriched in elements observed in the much higher temperature fumaroles at Mount St. Helens (K and Na up to the ppm level; metals such as Al, Pb, Zn Fe and Mn up to the ppb level and volatiles such as Cl, S, and F up to the ppb level).The data indicate that the hydrothermal system in the edifice at Mount Rainier consists of meteoric water reservoirs, which receive gas and steam from an underlying magmatic system. At present the magmatic system is largely flooded by the meteoric water system. However, magmatic components have episodically vented at the surface as witnessed by the mineralogy of incrustations around inactive vents and gas compositions in the active fumaroles. The composition of fumarole gases during magmatic degassing is distinct and, if sustained, could be lethal. The extent to which hydrothermal alteration is currently occurring at depth, and its possible influence on future edifice collapse, may be determined with the aid of on site analyses of fumarole gases and seismic monitoring in the ice caves.  相似文献   

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