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1.
Beach sediments in Sri Lanka contain industrial-grade heavy mineral occurrences. Samples of both offshore and onshore sediments were collected to examine the provenance, mineralogy and geochemical compositions of the heavy mineral occurrences. Coastal morphodynamic changes along the coastline of Sri Lanka were analyzed using the time-series satellite images. These coastal morphodynamic changes were used to identify the prominent directions of monsoon-influenced longshore currents, coastal sediment accretion and depositional trends and their relationships to the provenance of the heavy minerals. Results show the concentrations of detrital ilmenite, zircon, garnet, monazite, and rutile vary in the onshore and offshore sediments. The heavy mineral potential of the northeastern coast is high (average contents of about 45–50% in the Verugal deposit, 70–85% in the Pulmoddai deposit, and 3.5–5.0% in offshore samples stretching from Nilaveli to Kokkilai), compared to sediments in southwest (average content about 10% in onshore sediments and 2% in offshore sediments from the mouth of the Gin River). Therefore, no economic-grade heavy mineral placers were identified in the offshore environments. The high concentrations of heavy minerals in beach sediments and low concentrations in offshore sediments suggest operation of a panning system in the surf zone to form enriched placer deposits. Major and trace element compositions of beach sediments show marked enrichments of TiO2, Fe2O3, La, Ce, Zr, Cr, Nb, Th and V compared to average Upper Continental Crust (UCC) values. Analysis of prominent coastal longshore transport patterns identifies bidirectional sediment transport in the northeast coast of Sri Lanka. In the southwestern coast, two transport directions occur with anti-clockwise transport from Galle to Hambantota, and clockwise transport from Hikkaduwa to Wadduwa. The heavy minerals in the placers were mainly derived from Precambrian metamorphic rocks, and transported to the coast through the river systems of Sri Lanka.  相似文献   

2.
A coastwide study of the relationship between marsh aggradation and water level changes along the rapidly deteriorating Louisiana gulf coast was conducted. Rate of vertical marsh accretion determined from137Cs dating was compared to water level changes or submergence. Results identified marsh locations that are not keeping pace with submergence. Coastwide vertical accretion rates on the order of 0.7–0.8 cm/yr are not sufficient to keep pace with water level increases occurring at rates in most locations of over 1.0 cm/yr. Submergence rates were four to five times greater than eustatic sea level change for the Gulf of Mexico. Louisiana gulf coast marshes are likely to continue deteriorating unless means are implemented for distributing Mississippi River sediment to the marsh. It is estimated that sediment equivalent to less than 10 percent of the present annual suspended load of the Mississippi would provide enough sediment for marsh accretionary processes to compensate for submergence or water level increase.  相似文献   

3.
《Applied Geochemistry》1998,13(3):293-304
Distributions of 15 elements with depth in two sediment cores from Puck Bay in the Gulf of Gdansk show that Ag, Cd, Pb, Zn and possibly Cu and Ni are anthropogenically enriched in the sediments there. The concentrations of these elements decrease sharply with depth in the sediment column and the elements are preferentially enriched in the <2 μm size fraction of the sediment. The sequence of element enrichment depends on whether the enrichment factor (EF) and the anthropogenic factor (AF) are used to calculate the element enrichment. By contrast, the anthropogenic elements show no systematic decrease in concentration with depth in a sediment core taken from near the mouth of the Vistula River. This reflects the higher sedimentation rate there such that the entire upper 20 cm of the core was deposited during the major, post-war period of industrialization in Poland. In addition, these elements are enriched in the 2–63 μm fraction compared to the <2 μm fraction in these sediments. This suggests that the heavy metals are mainly adsorbed on Fe oxyhydroxide particles with diameters greater than 2 μm at the hydrological front where Vistula river water mixes with brackish Baltic water. It appears that heavy-metal pollution of sediments in parts of Puck Bay may be greater than that near the mouth of the Vistula River which may reflect, in part, the higher sedimentation rate near the mouth of the Vistula River. The mode of incorporation of heavy-metals into the sediments in the two areas may also be different.  相似文献   

4.
Exmouth Gulf is a major U‐shaped embayment on the northwestern coast of Western Australia, at a latitude of 22°S. Water temperatures are 18–31°C and normal oceanic salinity is maintained by strong tidal currents despite the hot, arid climate. A series of sediment grab samples were collected and analysed for particle‐size and foraminiferal diversity. Samples contained mud, quartzose fine sand and coarse carbonate sand fractions. The muddiest facies are located in the most sheltered areas of the gulf: mangrove channels, tidal flats, southwestern flanks and the deeper axial region. Quartzose fine sands probably have mixed origins which might include: southern aeolian dunes; cyclone‐related reworking of beach and near‐shore deposits; and reworked relict shelf alluvium. The shallow‐water fair‐weather wave climate may play a significant role in localised sediment dispersal and sorting along the eastern margin of the gulf. Sediment distributions within the gulf are complicated by low sedimentation rates through much of the central and western areas of the gulf, significant mixing, and possible inheritance of pre‐Holocene alluvium. The Holocene foraminiferal assemblage recorded from Exmouth Gulf is overwhelmingly dominated by benthic species: agglutinated, calcitic‐porcellaneous, and calcitic‐hyaline groups. The distribution of individual foraminiferal species shows relatively simple patterns, governed by environmental parameters. Live individuals are rare.  相似文献   

5.
The nature of Al Batinah coast beach sediments in the Sultanate of Oman was investigated by the analysis of grain size and mineralogy. The beach sediments, mostly light-medium gray green, were predominantly fine sands, with the average grain size of all samples about 200 μm. Some of the particles were gravel (2–16 mm), and some were even larger pebble-size particles (16–256 mm). Some mud (sediment <63 μm) was present, mostly in the sub-tidal sediments. The majority of the samples were skewed to the coarse size with coarse tail partly due to the presence of shell fragments. Approximately 50 % of the beach sediments were quartz with different varieties based on shape and size. The second major component of beach sediment was calcium carbonate which varied from 10 to 65 %. The other components in decreasing order consisted of microbreccia, feldspar, pyroxene, igneous rock fragments, biotite flakes, and heavy minerals. The levels of carbonate were lower in NW Al Batinah coast from Harmul to Al Khaburah but were higher in the SE from Al Khaburah to Al Ghubrah. This could be attributed to either lower carbonate production or more sediment input by wadis along the north-western part of Al Batinah coast. The unique and complex nature of these sediments is largely due to the geology of the terrestrial source area in the Hajar Mountains which contains the famous Samail ophiolite complex and the weak sorting along the shoreline in these tide-modified beaches.  相似文献   

6.
《Applied Geochemistry》2001,16(5):541-558
The Isonzo river mouth has been the source of Hg in the Gulf of Trieste (northern Adriatic sea) since the sixteenth century, making this shallow basin one of the most contaminated marine areas in the length of time and amount of metal accumulated. The occurrence and behaviour of total Hg (range 0.064–30.38 μg g−1; average 5.04 μg g−1; median 3.10 μg g−1, n=80) and related size fractions in sediments of this coastal area were investigated in detail. The relationship between total Hg and the fine silt-clay (< 16 μm) fraction has provided information on the hydrological and mineralogical fractionation process affecting this element, when compared to other heavy metals associated with fluvial inputs. Mercury contents are very high along the littoral zone of the northern (Italian) sector where this metal is present in detrital form (cinnabar) in sandy-silty sediments near the river mouth and the surrounding beaches. Within the sediments belonging to the Gulf area, Hg is bound either to fine particles or adsorbed onto the surface of clay minerals and/or partially complexed by colloids and organic matter. Recent accumulation of Hg in a 70 cm long 210Pb dated core, collected in the central part of the Gulf, was also compared to other heavy metals (Fe, Cr, Cu, Mn, Ni and Zn). A preliminary estimate of Hg enrichment shows that the first 50 cm of sediment in the central sector of the Gulf of Trieste are noticeably contaminated, reaching a maximum of up to 25-fold above the proposed natural regional background of 0.17 μg g−1. The vertical trend is well correlated to historical data of Hg extraction activity at the Idrija mine.  相似文献   

7.
福建安海湾表层沉积物粒度特征及其现代沉积过程分析   总被引：1，自引：0，他引：1  
通过对福建安海湾表层沉积物的粒度分析和对比,应用系统聚类分析、粒径趋势模型和切应力计算公式,探讨了研究区粒度的分布特征、沉积环境分区、表层沉积物输运趋势及其影响因素.研究结果表明,研究区包括6种表层沉积物类型,以黏土质粉砂和粉砂为主,沉积物大体呈现自海湾两侧潮滩向潮汐通道变粗的分布趋势.表层沉积物粒度的分布特征与水动力条件和物质来源密切相关,湾口附近及湾内深槽内,细颗粒的沉积物被再悬浮带走,粗颗粒的含量增大;在湾内潮滩上,悬浮物质因水动力作用逐渐减弱发生分选沉降,形成向岸变细的横向分异.海湾外泥沙随潮流不断地向海湾东侧岸滩运移,海湾周边陆源来沙由湾顶部往湾口方向下泄,两者是导致表层沉积物出现明显的顺时针方向汇聚趋势的原因之一;表层沉积物的输运趋势、悬浮泥沙的输运、潮滩植被与湾口沙嘴的遮蔽效应共同影响了研究区内浅滩地形的形成和变化.研究区可分为四类沉积环境区,以潮滩和潮汐通道环境为主,不同沉积区内的粒度参数、粒级频率和敏感粒级均有差异,动力条件差异和不同物源的影响程度是现代沉积环境格局的主要影响因素.  相似文献   

8.
The tsunami of 11th March 2011 was originated at the east coast of Japan and deposited ca.1 cm thick sediment layer along the coast of southwestern Mexico up to a maximum distance of 320 m from the beach. The sedimentological, mineralogical and geochemical characteristics of the sediments deposited during the tsunami (JT) are compared with the pre-tsunami sediments (PRT). JT sediments consist of dominant coarser fractions (>54% of medium to coarse sand), whereas PRT deposits comprise abundant finer fractions (>58% of fine sand). Assemblage of mafic and heavy minerals suggests similar provenance for both. The higher abundance and variation of heavy minerals along with higher concentrations of bromine (Br) and sodium (Na) in the JT deposits reveal the influence of high energy sea waves in transportation of heavy mineral rich coarse sediments onto the coastal lowlands.  相似文献   

9.
Physical properties, grain size, bulk mineralogy, elemental geochemistry and magnetic parameters of three sediment piston cores recovered in the Laurentian Channel from its head to its mouth were investigated to reconstruct changes in detrital sediment provenance and transport related to climate variability since the last deglaciation. The comparison of the detrital proxies indicates the succession of two sedimentary regimes in the Estuary and Gulf of St. Lawrence (EGSL) during the Holocene, which are associated with the melting history of the Laurentide Ice Sheet (LIS) and relative sea‐level changes. During the early Holocene (10–8.5 cal. ka BP), high sedimentation rates together with mineralogical, geochemical and magnetic signatures indicate that sedimentation in the EGSL was mainly controlled by meltwater discharges from the local retreat of the southeastern margin of the LIS on the Canadian Shield. At this time, sediment‐laden meltwater plumes caused the accumulation of fine‐grained sediments in the ice‐distal zones. Since the mid‐Holocene, postglacial movements of the continental crust, related to the withdrawal of the LIS (c. 6 cal. ka BP), have triggered significant variations in relative sea level (RSL) in the EGSL. The significant correlation between the RSL curves and the mineralogical, geochemical, magnetic and grain‐size data suggest that the RSL was the dominant force acting on the sedimentary dynamics of the EGSL during the mid‐to‐late Holocene. Beyond 6 cal. ka BP, characteristic mineralogical, geochemical, magnetic signatures and diffuse spectral reflectance data suggest that the Canadian Maritime Provinces and western Newfoundland coast are the primary sources for detrital sediments in the Gulf of St. Lawrence, with the Canadian Shield acting as a secondary source. Conversely, in the lower St. Lawrence Estuary, detrital sediments are mainly supplied by the Canadian Shield province. Finally, our results suggest that the modern sedimentation regime in the EGSL was established during the mid‐Holocene.  相似文献   

10.
Ilha Comprida is a regressive barrier island located in southeastern Brazil that was formed essentially by Quaternary sandy sediments. Ilha Comprida sediments were analyzed to assess heavy mineral indices and grain size variables. The spatial variation of heavy minerals and grain size was interpreted in terms of the present barrier dynamics and the barrier’s evolution since the Middle Holocene. These analyses allowed for the identification of the main factors and processes that control the variation of heavy minerals and grain size on the barrier. Rutile and zircon (RZi) and tourmaline and hornblende (THi) are significantly sensitive to provenance and exhibit the contributions of the Ribeira de Iguape River sediments, which reach the coast next to the northeastern end of Ilha Comprida. In addition to the influence of provenance, TZi responds mainly to hydraulic sorting processes. This agrees with a sediment transport pattern characterized by a divergence of two resultant net alongshore drifts southwest of the barrier. The sediments from the Ribeira de Iguape River reach the barrier directly through the river mouth and indirectly after temporary storage in the inner shelf. The combination of grain size and heavy mineral analyses is a reliable method for determining sediment transport patterns and provenance.  相似文献   

11.
Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na, B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles.  相似文献   

12.
本研究通过对长江口现代潮滩6个柱状样沉积物的粒度精细分析,试图提取研究区潮滩沉积相识别的粒度敏感指标,并通过对长江三角洲南部平原一个全新世钻孔(SL67孔)潮滩沉积物的粒度研究,检验现代沉积粒度敏感指标在全新世钻孔潮滩沉积相识别中的应用。研究显示,长江口现代高潮滩和中潮滩的黏性颗粒(8μm)和粗粉砂(32~63μm)含量差异显著,可以成为区分高潮滩和中潮滩的敏感组分;在开敞型的中、低潮滩之间,砂(63μm)和细粉砂含量(8~32μm)也差异明显。长江口现代潮滩沉积物的粒度频率曲线及众数值也可以有效协助区分高潮滩、中潮滩和低潮滩沉积物。利用上述粒度敏感组分和众数指标检验SL67孔全新世早中期在海平面波动控制下的潮滩演替过程,并揭示了7.5 cal ka BP前后的一次海平面加速上升事件。  相似文献   

13.
Detailed chemical and mineralogical data are presented for 37 samples of surface sediments collected from the Kalloni gulf, (eastern half), Lesvos island, northern Greece. The sediments are largely carbonate-rich muds, though near the eastern and northern coast of the gulf higher proportions of biogenic and lithogenic sands and gravels occur. The main minerals are quartz, feldspar (andesine), clay minerals (montmorillonite, illite, Kaolinite) and the carbonate minerals (calcite, Mg-calcite, aragonite). The mathematical method of factor analysis was applied in order to explain the mineralogical and geochemical variations. These variations can be interpreted in terms of variations in provenance and depositional environment. Six factors were produced accounting for 83.6 % of the total data variance: (a) a Si-Al-Na-K-Ti-Rb-Ba-Y-Zr factor controlled by clays and detrital minerals such as feldspars and zircon opposed by a CaCO2-Cu-Sc-Sr-La association (carbonate, minerals), (b) an organic carbon factor (C-Fe-Ce-Zn-Rb-Ni-Y-Nb), (c) a Fe-Mg-Cr-Ni factor representing control by peridotite, (d) a Ce-Nd-Fe-Ni-Zn-La factor controlled by silicate minerals, (e) a Al-Fe-Ti-P-V factor controlled by chlorite amphiboles or pyroxenes of volcanic or basaltic intrusions, (f) a Mn-Fe-Zn-factor controlled by iron-manganese oxides. Similarities in trace element composition among Kalloni gulf bottom sediments, and source lithologies indicate that the trace elements are derived from the adjacent landmasses. The AI/Ti ratio of the sediments is consistent with the terrigenous nature of sendimentation in the Kalloni gulf.  相似文献   

14.
Sediment in coastal Namibia to southern Angola is supplied dominantly from the Orange River with minor additional fluvial input and negligible modifications by chemical processes, which makes this a great test case for investigating physical controls on sand texture and composition. This study monitored textural, mineralogical and geochemical variability in beach and aeolian‐dune sands along a ca 1750 km stretch of the Atlantic coast of southern Africa by using an integrated set of techniques, including image analysis, laser granulometry, optical microscopy, Raman spectroscopy and bulk‐sediment geochemistry. These results contrast with previous reports that feldspars and volcanic detritus break down during transport, that sand grains are rounded rapidly in shallow‐marine environments, and that quartzose sands may be produced by physical processes. Mechanical wear is unable to modify the relative abundance of detrital components, including pyroxene and mafic volcanic rock fragments traditionally believed to be destroyed rapidly. The sole exceptions are poorly lithified or cleaved sedimentary/metasedimentary rock fragments, readily lost at the transition to the marine environment, and slow‐settling flaky micas, winnowed and deposited offshore. Coastal sediments tend to be depleted in relatively mobile amphibole, preferentially entrained offshore or re‐deposited in sheltered beaches, while less mobile garnet is retained onshore. No detrital mineral displays a significant increase in grain roundness after 300 to 350 km of longshore transport in high‐energy littoral environments from the Orange mouth to south of the Namib Erg, but all minerals get rapidly rounded after passing into the dunefield. Pyroxene and opaques get rounded faster than harder quartz and garnet, but sand mineralogy remains unchanged. Excepting strong transient selective‐entrainment effects, physical processes are unable to modify sand composition significantly. Selective mechanical breakdown can be largely neglected in quantitative provenance analysis of sand and sandstone even in the case of ultra‐long‐distance transport in high‐energy environments dominated by strong persistent winds and waves.  相似文献   

15.

Holocene sediments from southern Spencer Gulf are cool‐water carbonate‐rich gravels and sands, dominated by molluscs and Bryozoa. Five sedimentary fades are recognized: (i) molluscan gravel; (ii) branching coralline‐algal gravel, associated with shallow partially protected environments; (iii) molluscan‐biyozoan sand; (iv) mixed bioclastic sand, representative of the deeper central region of the lower gulf; and (v) bryozoan gravel, an isolated fades developed in a semi‐protected micro‐environment. The southern gulf is characterized by complex oceanographic conditions together with variations in water depth and substrate. The sediments share the characteristics of both the southern shelf and upper Spencer Gulf. Grain‐size distribution and sedimentary facies are controlled by a combination of all the above processes. Past sea level fluctuations are recognized from sea floor strand‐line deposits. The relic component of the palimpsest sediments has eroded from the Pleistocene aeolianite dunes. The sediments, therefore, reflect both the modern marine and past environments.  相似文献   

16.
This paper deals with the mineralogy of the continental shelf sediments of Abu-Quir Bay, N Coast of Egypt. The three dimentional distributions (normal to the shore line, in the breaker and offshore zones and along profiles E-W0 of different material individuals for twelve profiles were discussed. The patternal distribution of the recorded minerals along the bay was controlled by selective transport of the sediments by the E-W littoral current. A general trend for the decrease of the heaviest minerals from the source area (Rosetta Mouth) was observed. The opaques, garnet, zircon and epidote are concentrated in the breaker zone sediments, while the other (pyroxens and mica) are concentrated in the offshore zone sediments. Considerable amounts of opaques, amphiboles, monazite, garnet, staurolite and tourmaline were concentrated near Maadia Outlet, this is most probably attributed to the subsurface old sediments of Canopic Branch. Correlation between the present work (1978–1979) and other mineralogical work during (1971–1973), Rashed 1978) was attemptted.  相似文献   

17.
The aim of the present research was to investigate the seasonal impact on nearshore beach dynamics and the status of heavy mineral distribution along central Tamil Nadu coast, India. Beach profile measurements were made in 10 profiling sites between Thirukadaiyur and Velankanni on monthly and seasonal basis from January 2011 to July 2012. Using beach profile data, variation in beach width, slope and volumetric changes have been calculated. Beach slope and nearshore wave parameters were used to quantify the longshore sediment transport rate. Beaches between Thirukadaiyur and Karaikkal attained predominant transport rate in northern direction whereas, the rest of the beaches are in southern direction. The seasonal action of wind and wave currents create nearshore bar during northeast (NE) monsoon and frequent berms at tidal zone during southwest (SW) monsoon. Surface sediment samples were collected in each location for quantifying the heavy mineral weight percentage during the period of pre- and post-Thane cyclone. Sediments were also studied by X-ray diffraction (XRD) to evaluate the changes and occurrence of heavy minerals in beach sands. The XRD results show that sediments in the study area have enriched heavy mineral distribution even after strong cyclonic event. It confirms the redistribution of heavy mineral deposits present in the coast. The results suggested that monsoonal action has influenced the seasonal changes in beach morphology and it does not affect the heavy mineral distribution.  相似文献   

18.
The Gulf of Mannar along the Tuticorin coast is a coral base of the southeast coast of India. To obtain a preliminary view of its environmental conditions, geochemical distribution of major elements (Si, Al, Fe, Ca, Mg, Na, K, P), trace elements (Mn, Cr, Cu, Ni, Co, Pb, Zn, Cd) and acid leachable elements (Fe, Mn, Cr, Cu, Ni, Co, Pb, Zn, Cd) were analyzed in surface sediment samples from two seasons. Geochemical fractionation confirmed the lithogenic origin of metals, which were mainly associated with the detrital phase. The sediments in the gulf are sandy with abundant calcareous debris, which controls the distribution of total and acid leachable elements. Enrichment factors relative to crust vary by a magnitude of two to three and the presence of trace metals indicates the input of Cr, Pb, Cd, Cu and Zn in both forms through industrial activities. Factor analysis supports the above observation with higher loadings on acid leachable elements and its association with CaCO3. The increase in concentration of trace metals (Cr, Pb, Cd, Cu, Co, Ni, Zn) along the Gulf of Mannar indicates that the area has been contaminated by the input from riverine sources and the industries nearby. The present study indicates that other sources should be evaluated in the long-term monitoring program.  相似文献   

19.
We present a detailed study of the co-diagenesis of Fe and P in hydrothermal plume fallout sediments from ∼19°S on the southern East Pacific Rise. Three distal sediment cores from 340-1130 km from the ridge crest, collected during DSDP Leg 92, were analysed for solid phase Fe and P associations using sequential chemical extraction techniques. The sediments at all sites are enriched in hydrothermal Fe (oxyhydr)oxides, but during diagenesis a large proportion of the primary ferrihydrite precipitates are transformed to the more stable mineral form of goethite and to a lesser extent to clay minerals, resulting in the release to solution of scavenged P. However, a significant proportion of this P is retained within the sediment, by incorporation into secondary goethite, by precipitation as authigenic apatite, and by readsorption to Fe (oxyhydr)oxides. Molar P/Fe ratios for these sediments are significantly lower than those measured in plume particles from more northern localities along the southern East Pacific Rise, and show a distinct downcore decrease to a depth of ∼12 m. Molar P/Fe ratios are then relatively constant to a depth of ∼35 m. The Fe and P speciation data indicate that diagenetic modification of the sediments is largely complete by a depth of 2.5 m, and thus depth trends in molar P/Fe ratios can not solely be explained by losses of P from the sediment by diffusion to the overlying water column during early diagenesis. Instead, these sediments are likely recording changes in dissolved P concentrations off the SEPR, possibly as a result of redistribution of nutrients in response to changes in oceanic circulation over the last 10 million years. Furthermore, the relatively low molar P/Fe ratios observed throughout these sediments are not necessarily solely due to losses of scavenged P by diffusion to the overlying water column during diagenesis, but may also reflect post-depositional oxidation of pyrite originating from the volatile-rich vents of the southern East Pacific Rise. This study suggests that the molar P/Fe ratio of oxic Fe-rich sediments may serve as a proxy of relative changes in paleoseawater phosphate concentrations, particularly if Fe sulfide minerals are not an important component during transport and deposition.  相似文献   

20.
对杭州湾北岸芦潮港潮滩2007-2010年固定点沉积物进行了逐月的磁性测量和粒度分析,探讨了磁性特征的月际、年际变化及其与粒度的关系。结果显示,2007-2009年,芦潮港潮滩沉积物的磁性特征呈现出相似的季节性变化特征,磁性参数χ、χARM、SIRM以及比值χARM/SIRM总体上在12月次年7至月表现为高值,8-11月为低值,S-300变化趋势与之相反。粒度分析显示,每年12月至次年7月沉积物粒度总体较细,8-11月较粗,这说明潮滩较细沉积物中含有较多的亚铁磁性矿物,与已报道的2004-2005年研究结果相似。相比前三年,2010年1-7月及12月沉积物磁性矿物含量相对下降,8-11月份磁性矿物含量相对上升,导致2010年磁性参数月际变化幅度减小。同时,2010年沉积物粒度月际变化特征也发生了改变,即1-7月及12月沉积物粒度变粗,8-11月沉积物变细。相关分析表明,磁性参数与粒度之间的关系在2007-2010年中没有发生明显的变化,说明2010年沉积物粒度月际变化模式的改变是磁性特征月际变化改变的主导因素。尽管如此,长江流域来沙下降对河口潮滩沉积物物源的可能影响,仍需予以长期关注。  相似文献   

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