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1.
Research concerning chemical constitution of alluvial sediments was done in the lower course of the Obra river (Western Poland). The fragment of vertical profile, which consisted of various alluvial sediments (fine sands, peats, and sandy silts) was chosen for detailed analysis. The main research problem was to determine if lithology and chemical constitution of alluvial deposits are interconnected in a distinct way within studied section of the Obra river valley, and, if changes of chemical elements’ concentration could be used to illustrate depositional processes, which take place in riverbed and floodplain. Concentrations of Fe, Mn, Cu, Zn, Ca, Mg, and K were determined in collected sediment samples. Next, geochemical groups of alluvial sediments were distinguished using cluster analysis. Investigated changes of chemical elements’ concentration show that there is a distinct border between the environment of organic sediments, which marks the place of former functioning of the Obra riverbed, and sandy silts, which were deposited within floodplain during floods. Besides, floodplain sediments, riverbed sediments, and reductive environment within peat deposits were singled out on the basis of the analysis.  相似文献   

2.
A case study in the Canadian Arctic demonstrates how an organic geochemical signature in the regional bedrock can be transferred by erosion and redeposition to younger geological formations and surface sediments. The hydrocarbon composition recorded in Laurentian (Lower Palaeozoic) carbonate bedrock was incorporated into overlying Miocene and Quaternary formations, and modern mass waste, alluvium, snow/ice, and proglacial deposits, and further distant in ice-rafted detritus. The retention of the original geological organic signature is reflected in consistent thermal maturities (hopane ratios) and environmental indicators (sterane distributions). In the modern sediments, the geological signature is variably mixed with a modern microbial organic signature reflected in high values of carbon preference index and diploptene. These data show that hydrocarbon occurrences in bedrock may be detected by the analysis of surface detritus, especially in carbonate terrains. However they also indicate that environmental signatures may be misleading if they are inherited from older geological units.  相似文献   

3.
长江流域沿江镉异常源追踪与定量评估的研究框架   总被引：17，自引：1，他引：16  
Cd属于积蓄性有毒元素,引起慢性中毒的潜伏期可达10~30 年之久。中国正在进行的多目标地球化学调查成果显示,长江流域存在全流域的Cd异常。对长江上、中、下游冲洪积物中Cd质量分数的初步研究,发现长江流域Cd异常以自然风化作用为主。针对长江流域Cd异常的特点,在统一技术规范的基础上采用枯、丰水期悬浮物测量技术、河漫滩/泛滥平原沉积物沉积柱分层采样技术,同位素测年技术来建立长江各支流Cd输入通量的时空变化模型和定量评估方法,估算长江各支流的Cd输入通量,使分散于沿江各省的区域地球化学评价置于同一平台,从而为全面研究长江流域Cd异常的形成机理创造条件。  相似文献   

4.
Molybdenum mining in the Knabena—Kvina drainage basin (1918–1973) left more than eight million tons of tailings in two small lakes in the headwater area of the Knabena river. The piles, that reach above the water surface, were freely eroded until a dam was built to reduce the dispersion in 1976. Sampling of tailings and fluvial sediments took place almost 20 years later. Sampling media were natural sediment sources, 1-cm-thick slices of overbank sediments of various depths, material from the tailings pond, sandbars, stream sediments, fjord sediments, and integrated samples of floodplain surfaces (0–25 cm). In total 734 samples were collected. Chemical analysis (ICP-AES after aqua regia or HNO3 extraction) showed that overbank sediments at a certain depth represent the pre-industrial trace metal concentrations within the drainage basin. The tailings and recent fluvial sediments were enriched in approximately the same element suite. The highest enrichment factors were obtained for Cu (8–53) and Mo (22–57). Fluvial processes in the tailings pond have probably selectively eroded fine-grained, low-density particles. Thus, coarse chalcopyrite may have been left behind, while molybdate associated with fine-grained particles may have been selectively entrained causing dilution of Cu and enrichment of Mo in the downstream fluvial sediments. In the sandbars, the highest Cu and Mo concentrations were found in fine-grained sediments downstream of a low-gradient reach that act as a bedload trap. On the floodplains, it is seen that the first areas to be inundated in a flood situation (proximal to the river and in depressions) have the highest metal concentrations. For regional geochemical mapping it is suggested that overbank sediment profiles along river reaches with a laterally stable or slowly migrating channel, should be sampled. In such floodplains, pre-industrial overbank sediments are usually preserved at depth. In case of laterally unstable reaches upstream of the sampling point, polluted and unpolluted sediments may be interlayered or mixed. Therefore, samples should be collected from various depths or sedimentary units in such profiles. A similar sampling strategy should probably be adopted to detect vertical migration of elements especially in areas with acid rain and low bedrock buffer capacity. To obtain high contrasts between polluted and unpolluted drainage basins, the overbank sediment profiles should be within the proximal part of the floodplain.  相似文献   

5.
Geochemical investigations of till is a widely used method in metal exploration as the till commonly inherits the geochemical signature (including the metal contents) of the parent bedrock. In this investigation, over 2000 till samples were collected in the Sarvlaxviken area, southern Finland, where several polymetallic (Cu, Zn, Pb, As, Sn, W and In) veins recently have been discovered in Proterozoic crust along the border between Late Svecofennian granites and the Wiborg Batholith. The bedrock is commonly covered by compact and poorly sorted basal till, formed during the Late Weichselian glaciation event. Several glacial-transported boulders, with high contents of Cu, Zn, As, Sn, Mo and Bi and derived from the local bedrock, have also been discovered on top of the till and provide evidence for concealed mineralisation in the local bedrock under the till cover. The frequent distribution of till in the Sarvlaxviken area provides excellent conditions for the search of such hidden mineralisation by means of systematic till sampling, even if large farm field areas, composed of clay-rich sediments, and seawater-covered areas (Sarvlaxviken bay), had to be avoided in the sampling program. The till samples were collected during university courses and training programs led by the authors and were analysed in a cost-efficient and certified laboratory. Obtained geochemical data were statistically processed by using K-means clustering algorithms which can be used to treat large sets of geochemical data. The results provided anomalies that mainly occur in till with a thickness of <1 m and are considered to be derived from a local bedrock source. The discovered anomalies provide strong evidence for numerous undiscovered veins beneath the till cover.  相似文献   

6.
《Applied Geochemistry》2000,15(5):647-653
The problem of a geochemical baseline in areas differing in basic geology was studied by comparing the results of regional geochemical mapping programmes undertaken in Finland and Lithuania using different sample media and a variety of analytical methods. The authors discuss issues relevant to the definition of a geochemical baseline.Most of the differences in geochemical baselines between Lithuania and Finland are due to the dissimilarities in basic geology, which in Lithuania is controlled by Palaeozoic and Mesozoic sedimentary rocks, but in Finland by Archaean and Proterozoic metamorphic and intrusive rocks. Other important factors are the geological processes that after the last glaciation created the present surficial materials. In Finland, for instance, the abundances of potentially harmful elements derived from crystalline bedrock tend to be higher than in Lithuania. However, in both countries element concentrations are higher in finely-grained marine and lacustrine sediments than in glacial till, and they are also higher in the finer grain size fractions than in the coarser fractions of till samples. Only a small proportion of the total heavy metal concentrations is bioavailable. Thus the baseline concentrations depend not only on the basic geology, but also on sample material collected, its grain size and the extraction method.  相似文献   

7.
The Mike Horse Mine tailings dam in western Montana was partially breached in 1975 due to heavy rainfall and a failed drainage bypass. Approximately 90,000 tons of metal and arsenic-enriched tailings flowed into Beartrap Creek and the Blackfoot River. The spatial distribution of trace elements As, Cd, Cu, Mn, Pb, and Zn in floodplain alluvium of the upper Blackfoot River were examined along 20 transects in the upper 105 river kilometers downstream from the tailings dam. Trace element concentrations decrease with distance from the failed dam, with As reaching background concentrations 15 km from the Mike Horse dam, Cd and Pb at 21 km, Cu at 31 km, and Mn and Zn at 37 km. Distance from the Mike Horse tailings dam and mine area is the dominating factor in explaining trace element levels, with R 2 values ranging from 0.67 to 0.89. Maximum floodplain trace element concentrations in the upper basin exceed US. EPA ecological screening levels for plants, birds and other mammals, and reflect adverse hazard quotients for exposure to As and Mn for ATV/motorcycle use. Trace element concentrations in channel bank and bed alluvium are similar to concentrations in floodplain alluvium, indicating active transport of trace elements through the river and deposition on the floodplain. The fine fraction (<2 mm) of floodplain alluvium is dominated by sand-sized particles (2.0–0.05 mm), with Cu and Mn significantly correlated with silt-sized (0.05–0.002 mm) alluvium. Ongoing remediation in the headwaters area will not address metal contamination stored downstream in the channel banks and on the floodplain. Additionally, some trace elements (Cu, Mn and Zn) were conveyed farther downstream than were others (As, Cd, Pb).  相似文献   

8.
铜石金矿田地球化学找矿模型   总被引：6，自引：1，他引：6  
从基岩地球化学及水系沉积物地球化学的角度研究了铜石金矿田金的异常特征。运用对应聚类、因子分析和马氏距离等多元统计分析方法进一步研究了金组合元素异常特征，建立了归来庄金矿环、线叠加地球化学异常找矿模型。  相似文献   

9.
Lake sediments are integrators of watershed wide environmental information that includes bedrock geology, glacial overburden, vegetation, hydrology and land use. Lake sediments were collected from an area covering approximately 13,600 km2 from the Gowganda and Temagami regions to determine the geochemical background conditions representing different bedrock types. For the entire dataset, the median value for arsenic in lake sediment was 2.6 mg/kg, well within the prescribed limits indicating that the Canadian national objective for arsenic in sediments for the protection of aquatic life (17 mg/kg). Overall, the vast majority of lake sediment samples (97.2%) were below the 17 mg/kg Canadian objective for the protection of aquatic life, however, catchments with Nipissing Diabase had the highest background levels for arsenic (10 mg/kg) with some lakes ranging up to 30 mg/kg. The major geological controls influencing changes in lake sediment geochemistry were determined using random forest classification and principal component analysis (PCA). Random forest classification was able to identify which geological province the samples were derived from and the dominant rock types in the sample catchment with respectable accuracy. PCA revealed strong spatial relationships between lake sediment geochemistry and bedrock geology, particularly a strong relationship between Nipissing Diabase in the watershed of the lake and the cobalt-type mineralization indicator elements in the lake sediment including naturally higher levels of arsenic. Within the samples that exceeded regulatory standards, over half the samples that exceeded the regulatory objectives were located in watersheds that contained Nipissing Diabase in their catchment. This study demonstrates that unique geochemical assemblages can be associated with specific geological areas which is of interest to exploration geologists, for target generation and prospecting, and to environmental policy makers, for site-specific restoration targets.  相似文献   

10.
Although Paleoindian sites in Indiana, USA, are commonly located on late Wisconsin (Last Glacial Maximum) outwash terraces, drainage basin development since deglaciation often obscures the visibility of such sites on flood plains by either burying them under alluvium or destroying them through erosion. Significant clusters of Paleoindian and Early Archaic sites, however, have been identified proximal to the modern White River channel in central Indiana on what is mapped as “floodplain.” These site cluster locations are patterned. They typically occur within bedrock‐controlled river reaches but are rare along unconfined meandering reaches. Subsurface reconnaissance and chronology indicate that despite the fact that they often flood, portions of the so‐called flood plains within bedrock‐confined reaches are actually terraces constructed of late Wisconsin outwash with minimal overbank sedimentation. Terrace preservation in these settings is a result of bedrock structure that protects older sediments from lateral erosion and differentially preserves archaeological sites near the modern channel in bedrock‐controlled reaches. Comparisons of archaeological sites within bedrock‐controlled segments of the White River to those in unconfined meandering segments suggests that significant numbers of Paleoindian and Early Archaic sites may be missing from river settings across the midcontinent. These findings demonstrate that bedrock channel controls are important to recognize when assessing prehistoric settlement distributions.  相似文献   

11.
A geochemical survey of Belgium and Luxembourg was carried out as part of an international research project entitled ‘Regional geochemical mapping of Western Europe towards the year 2000'. The aim of this research was to map regional background geochemical patterns based on pristine or at least pre-industrial overbank samples and to deduce regional information on the degree of environmental pollution of floodplain and present-day river sediments. Over the entire study area (about 33,000 km2), 66 overbank sites have been sampled. Catchment areas range between 60 and 600 km2. At each site an overbank profile has been dug out in the immediate vicinity of the river and described in detail. A first composite sample was taken 5–25 cm below the surface. This sample is supposed to represent deposition over the last centuries. Human interferences in this interval are often inferable based on changed sedimentary characteristics and the presence of anthropogenic particles such as charcoal, slags and brick fragments. A second composite sample was taken at depth, usually >1.5 m below the surface over an interval of about 20 cm. In most sites, the profile characteristics allowed to assume pre-industrial or even pristine conditions for this lower overbank sample. In some profiles this was confirmed by 14C-dating and/or by the absence of anthropogenic particles. Finally, a present-day stream sediment was sampled on the site to infer the actual pollution status. After drying at 80°C, disaggregation and sieving, the <125 μm fractions of the three sediment samples were analysed by XRF for major elements and several trace elements. Lower overbank samples generally show a direct link with the geological substrate and allow to assess natural background concentrations. Results from the mapping exercise as well as from the statistical analyses display a clear contrast between the northern part of Belgium where Cenozoic unconsolidated sandy and silty formations dominate which are especially vulnerable for erosion, and the southern part of Belgium and Luxembourg where Paleozoic and Mesozoic sandstones, carbonates, marls and shales are the prevalent lithologies. Here the shales are the most intensively eroded lithologies. This is especially reflected in the element patterns of Al2O3, MgO, K2O, Ga, Ni, Rb, Sc and V which negatively correlate with SiO2. Despite the human related pollution, the geological contrast between north and south Belgium is still recognisable in the geochemical pattern of the upper overbank and present-day stream sediment samples for the above-mentioned elements. Furthermore there is a clear increase in heavy metal contents (Zn, Cd, Pb, Cu), As and in certain locations in Ba from the lower to the upper overbank sediment, as well as to the present-day stream sediment. The relative increase in element content allows to assess the degree of pollution and helps to define those drainage areas where more detailed research is needed.  相似文献   

12.
两淮矿区高承压厚松散含水层覆盖下煤炭储量巨大,在提高上限开采过程中常发生松散层突水事故,采用传统“上三带”理论难以合理解释此类事故发生的机理。本文在分析两淮矿区高承压松散层水文工程地质条件的基础上,建立近高承压松散层开采“双行裂隙”模型,采用室内实验、数值模拟、理论分析和工程应用检验等方法,研究“双行裂隙”发育规律,揭示两淮矿区高承压厚松散层突水致灾机理,结果显示:祁东煤矿松散层第四含水层（简称四含）水压与裂采比呈线性关系;在水压作用下,覆岩“上行裂隙”发育高度增大;利用裂隙受力分析推导的基岩风化带原生裂隙扩展渗透深度计算公式,表明高承压松散含水层对风化裂隙产生劈裂作用,是“下行裂隙”形成的主要因素。“双行裂隙”的综合作用使工作面更易发生松散层水突水事故,研究成果为近松散层煤层开采安全煤（岩）柱的合理留设提供科学依据。   相似文献   

13.
Correspondence cluster analysis, developed in this paper, regroups the main advantages of correspondence analysis and cluster analysis. The output of the method, correspondence cluster dendrograms, shows clearly the relationships between variables, between samples, and between variables and samples, on a single diagram. The technique has been applied successfully to distinguish geochemical anomalies from background, to recognize types of anomalies, to study the geochemical characteristics of deposits, etc. Several practical examples presented in this paper show that the method can be used to classify elements and samples into meaningful groups, and that the geochemical character of each sample group can be interpreted in terms of the corresponding element group. The results are consistent with the geological situations at hand, and are usually more elucidating than other classification methods.  相似文献   

14.
Extensive terrace and flood plain deposits occur along the Lower Macleay River. A sequence of terraces from oldest to youngest was named: Madron, Corangula, Mungay, Mooneba, Belgrave and Macleay deposits (contemporary). Basal sediments in the Mooneba terrace were dated by radiocarbon analysis at 3,280 ± 55 years; basal sediments of the Mungay terrace were dated at 6,425 ± 105 years. The Madron and Corangula terraces are considered very much older than the Mungay. The flood plain consists of two early cycles of aggradation buried under 23m of estuarine sediment, which in turn is overlain by up to 6m of alluvium. The estuarine sediments were dated at 8,530 ± 200 years at elevation —4m relative to mean sea level. The base of the overlying Smithtown alluvium was dated at 3,295 ± 95 years. A general chronology is presented for the Lower Macleay valley, and a sequence of terrace soils is discussed.  相似文献   

15.
Tracing sources of aeolian sediment is key to reconstructing earth surface processes in arid areas and interpreting the paleoenvironmental significance of aeolian sequences. However, the difference of geochemical characteristics between different fractions of sediments in the Yarlung Zangbo River Basin (YZRB) is still unclear, so we want to identify which fraction of sediments is more suitable for tracing sediment sources. Considering the long distance between different wide valleys in the YZRB, we wonder whether there is any difference between these wide valleys in terms of geochemical characteristics of sediments. Forty-three surface sediment samples in the YZRB are collected, and the grain-size distributions and the major-element composition for 37 samples and the trace and rare earth element composition for the coarse (75–500 μm) and fine (<?75 μm) fractions of all samples are determined. The results reveal the following: (1) the fine fractions of the deposits contain more environmental information, suggesting that the fine fractions cannot be directly compared between different climate zones for provenance identification and that appropriate coarse fractions, based on the grain-size distribution of the targeted sediments, are more ideal for tracing sediment sources; and (2) geochemical characteristics of various sediment types show spatial heterogeneity. The coarse and fine fractions of the loose sediment samples can be divided into two regional groups based on geochemical characteristics: the Maquanhe zone in the upper reach, the Xigaze, Shannan and Mainling zone in the middle reach, which is consistent with the geological background of the YZRB; (3) aeolian deposits in the YZRB are a local origin and predominantly derived from the adjacent loose sediments, and fluvial sediments in the upper reach contribute little to the aeolian sands in the middle reach.  相似文献   

16.
Geochemical maps can provide us with much information on geology, earth surface processes and anthropogenic pressure and are valuable tools for ore prospecting and land management. Stream sediments represent an integral of the various possible sources of sediments upstream from the sampling point therefore there can be multiple signal sources but generally the prevailing signal source is the one related to bedrock geology. Stream sediments collected from active second-order channels including singular geological units, were selected in order to determine the geochemical characteristics of each unit. The aim of this study was to analyse their potential for using them to integrate geological interpretation and produce a geologically-oriented geochemical map. From the 770 samples collected for a regional geochemical mapping program, we selected 149 samples whose catchment basin included only one of the members recognized within the Marnoso–Arenacea formation. This Middle-Upper Miocene (Langhian–Tortonian) turbiditic unit forms the backbone of the Romagna Apennines and has been subdivided into 14 members according to age and lithostratigraphic criteria. The results indicate that there are marked differences in the composition of the members of the Marnoso Arenecea formation which indicate the provenance of the sediment and the palaeogeographic evolution of the units. By means of univariate and multivariate statistical analyses (Factor analyses) two main types of sediment compositions are identified: Tortonian members are characterized by sialic coarse grain- sediments while the Langhian–Serravallian members are richer in carbonate fraction, slightly enriched in a mafic contribution. This study elaborated the geochemical data from a geological point of view by integrating the information available in literature to spatially extend the interpretation based on limited site observation as for petrographic studies. In general, the geochemical map based on a geological unit could be a useful tool for carrying out the geological reconstruction of a complex area.  相似文献   

17.
Grain size distribution data for a large number of basal tills from different areas are presented. The Norwegian tills can be divided in two major groups: Tills derived from Precambrian bedrock and tills derived from Cambro-Silurian sedimentary rocks. Both types are significantly different from Danish tills where unconsolidated sediments are incorporatcd. Chemical and mineralogical composition of the 125–250 μm fraction of tills derived from Precambrian rocks and tills derived from phyllites are presented. These data are used to determine transport distances for the till material.
Due to a marked relief and short distances from the ice-divides to the coast, the tills found in the Norwegian mountains have generally had a short transport and are, unless large amounts of unconsolidated sediments are incorporated, strongly influenced by the underlying bedrock.  相似文献   

18.
Geochemical maps can provide us with much information on geology, earth surface processes and anthropogenic pressure and are valuable tools for ore prospecting and land management. Stream sediments represent an integral of the various possible sources of sediments upstream from the sampling point therefore there can be multiple signal sources but generally the prevailing signal source is the one related to bedrock geology. Stream sediments collected from active second-order channels including singular geological units, were selected in order to determine the geochemical characteristics of each unit. The aim of this study was to analyze their potential for using them to integrate geological interpretation and produce a geologically-oriented geochemical map. From the 770 samples collected for a regional geochemical mapping program, we selected 149 samples whose catchment basin included only one of the members recognized within the Marnoso-arenacea formation. This middle–upper Miocene (Langhian–Tortonian) turbiditic unit forms the backbone of the Romagna Apennines and has been subdivided into 14 members according to age and lithostratigraphic criteria. The results indicate that there are marked differences in the composition of the members of the Marnoso arenecea formation which indicate the provenance of the sediment and the palaeogeographic evolution of the units. By means of univariate and multivariate statistical analyses (Factor analyzes) two main types of sediment compositions are identified: Tortonian members are characterized by sialic coarse grain-sediments while the Langhian–Serravallian members are richer in carbonate fraction, slightly enriched in a mafic contribution. This study elaborated the geochemical data from a geological point of view by integrating the information available in literature to spatially extend the interpretation based on limited site observation as for petrographic studies. In general, the geochemical map based on a geological unit could be a useful tool for carrying out the geological reconstruction of a complex area.  相似文献   

19.
This paper reports the results of a study of the geochemistry of bottom sediments from the zones of mixing between the freshwater of the Ob and Yenisei rivers and the saline water of the Kara Sea by means of neutron activation analysis. Using separate datasets for the sediments of the Ob and Yenisei estuaries accumulated under identical facies conditions, some characteristic features of the distribution of a number of chemical elements (mostly lithophile group elements) were established. The differences between them were attributed to distinctive regional geological and geochemical features of the catchments of the Ob and Yenisei, which are inherited by the geochemical characteristics of terrigenous material transported to the sea. The choice of the most informative indicator elements and their grouping on the basis of the character of behavior demonstrated that bottom sediments of the Ob or Yenisei origin can be identified in the marine region studied using the geochemical characteristics of a small group of samples.  相似文献   

20.
A high-resolution dataset of trace element concentrations is presented for the Murray–Darling Basin, Australia, Australia’s most important river system. The data were obtained by solution quadrupole ICP-MS resulting in concentrations for 44 elements. Of these, 21 were determined with a long-term external precision of better than 1% and a further 13 at a precision better than 2%. Trace element maps for the surface sediments constructed from such high precision data reveal small but coherent variations in the four major sub-catchments of the basin, even in ratios of elements with very similar geochemical behaviour, such as Y/Ho, Nb/Ta and Zr/Hf. The origin of these chemical fingerprints of drainage systems are discussed in terms of the geochemical character of the upper continental crust. The potential of trace element maps for palaeo-environmental and climatic reconstruction is then illustrated. First, a sample of dust collected in a trap located in the far southeastern corner of the study area is used to pinpoint the location of the dust source. Next the fine-scale change in down-stream alluvial sediment chemistry is analysed to estimate the importance of sediment contribution from tributaries with a view to reconstructing river flow dynamics. Finally, the chemistry of dune sediments is compared with surrounding floodplain alluvium to estimate relative age of deposition. These examples demonstrate that in low-elevation river systems, such as the Murray–Darling Basin, extended trace element maps of sediment offer substantially more applications than radiogenic isotope data alone.  相似文献   

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