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1.
The lack of paleoecological records from the montane Atlantic Rainforest of coastal Brazil, a hotspot of biological diversity, has been a major obstacle to our understanding of the vegetational changes since the last glacial cycle. We present carbon isotope and pollen records to assess the impact of the glaciation on the native vegetation of the Serra do Mar rainforest in São Paulo, Brazil. From ca. 28,000 to  22,000 14C yr BP, a subtropical forest with conifer trees is indicative of cool and humid conditions. In agreement carbon isotopic data on soil organic matter suggest the presence of C3 plants and perhaps C4 plants from  28,000 to  19,000 14C yr BP. The significant increase in the sedimentation rate and algal spores from  19,450 to  19,000 14C yr BP indicates increasing humidity, associated to an erosion process between  19,000 and  15,600 14C yr BP. From  15,600 14C yr BP to present there is a substantial increase in arboreal elements and herbs, indicating more humid and warmer climate. From  19,000 to  1000 14C yr BP, δ13C values indicated the predominance of C3 plants. These results are in agreement with studies in speleothems of caves, which suggest humid conditions during the last glacial maximum.  相似文献   

2.
Integration of on-land and offshore geomorphological and structural investigations coupled to extensive radiometric dating of co-seismically uplifted Holocene beaches allows characterization of the geometry, kinematics and seismotectonics of the Scilla Fault, which borders the eastern side of the Messina Strait in Calabria, Southern Italy. This region has been struck by destructive historical earthquakes, but knowledge of geologically-based source parameters for active faults is relatively poor, particularly for those running mostly offshore, as the Scilla Fault does. The  30 km-long normal fault may be divided into three segments of  10 km individual length, with the central and southern segments split in at least two strands. The central and northern segments are submerged, and in this area marine geophysical data indicate a youthful morphology and locally evidence for active faulting. The on-land strand of the western segment displaces marine terraces of the last interglacial (124 to 83 ka), but seismic reflection profiles suggest a full Quaternary activity. Structural data collected on bedrock faults exposed along the on-land segment provide evidence for normal slip and  NW-SE extension, which is consistent with focal mechanisms of large earthquakes and GPS velocity fields in the region. Detailed mapping of raised Holocene marine deposits exposed at the coastline straddling of the northern and central segments supplies evidence for two co-seismic displacements at  1.9 and  3.5 ka, and a possible previous event at  5 ka. Co-seismic displacements show a consistent site value and pattern of along-strike variation, suggestive of characteristic-type behaviour for the fault. The  1.5–2.0 m average co-seismic slips during these events document Me  6.9–7.0 earthquakes with  1.6–1.7 ka recurrence time. Because hanging-wall subsidence cannot be included into slip magnitude computation, these slips reflect footwall uplift, and represent minimum average estimates. The palaeoseismological record based on the palaeo-shorelines suggests that the last rupture on the Scilla Fault during the February 6, 1783 Mw = 5.9–6.3 earthquake was at the expected time but it may have not entirely released the loaded stress since the last great event at  1.9 ka. Comparison of the estimated co-seismic extension rate based on the Holocene shoreline record with available GPS velocities indicates that the Scilla Fault accounts for at least  15–20% of the contemporary geodetic extension across the Messina Strait.  相似文献   

3.
A detailed study of uplifted Middle–Late Pleistocene marine terraces on the eastern side of northern Calabria, southern Italy, provides insights into the temporal and spatial scale variability of vertical displacement rates over a time span of 400 ka. Calabria is located in the frontal orogen of southern Italy above the westerly-plunging Ionian slab, and a combination of lithospheric, crustal, and surface processes concurred to rapid Late Quaternary uplift. Eleven terrace orders and a raised Holocene beach were mapped up to 480 m a.s.l., and were correlated between the coastal slopes of Pollino and Sila mountain ranges across the Sibari Plain, facing the Ionian Sea side of northeastern Calabria. Precise corrections were applied to the measured shoreline angles in order to account for uncertainty in measurement, erosion of marine deposits, recent debris shedding, and bathymetric range of markers. Radiometric (ESR and 14C) dating of shells provides a crono-stratigraphic scheme, although many samples were found to be resedimented in younger terraces. Terrace T4, whose inner margin stands at elevations of 94–130 m, is assigned to MIS 5.5 (124 ka), based on new ESR dating and previous amino acid racemization estimations. The underlying terraces T3, T2 and T1 are attributed to MIS 5.3 (100 ka), 5.1 (80 ka) and 3 (60 ka), as inferred from their relative position supplemented by ESR and 14C age determinations. The age of higher terraces is poorly constrained, but conceivably is tracked back to MIS 11 (400 ka). The reconstructed depositional sequence of terraces attributed to MIS 5.5 and 7 reveals two regressive marine cycles separated by an alluvial fanglomerate, which, given the steady uplift regime, points to minor sub-orbital sea-level changes during interstadial highstands. Based on the terrace chronology, uplift in the last 400 ka occurred at an average rate of 1 mm/a, but was characterized by the alternation of more rapid (up to 3.5 mm/a) and slower (down to 0.5 mm/a) periods of displacement. Spatial variability in uplift rates is recorded by the deformation profile of terraces parallel to the coast, which document the growth of local fold structures.  相似文献   

4.
The small granite plutons occurring at the contact of the Singhbhum-Orissa Iron Ore craton (IOC) to the north and the Eastern Ghat Granulite Belt (EGGB) to the south in eastern Indian shield are characterised by the presence of enclaves of the granulites of EGGB and the greenschist facies rocks of IOC. These granites also bear the imprints of later cataclastic deformation which is present at the contact of the IOC and the EGGB. In situ Pb-Pb zircon dating of these granites gives minimum age of their formation 2.80 Ga. A whole-rock three point Rb-Sr isochron age of this rock is found to be 2.90 Ga. Therefore, the true age of formation of these granites will be around 2.90–2.80 Ga. These granitic rocks also contain xenocrystic zircon components of 3.50 Ga and show a later metasomatic or metamorphic effect 2.48 Ga obtained from the analyses on overgrowths developed on 2.80 Ga old zircon cores. The presence of granulitic enclaves within these contact zone granite indicates that the granulite facies metamorphism of the EGGB is 2.80 Ga or still older in age. The cataclastic deformations observed at the contact zone of the two adjacent cratons is definitely younger than 2.80 Ga and possibly related to 2.48 Ga event observed from the overgrowths. As 2.80 Ga granite plutons of small dimensions are also observed at the western margin of the IOC; it can be concluded that a geologic event occurred 2.80 Ga over the IOC when small granite bodies evolved at the marginal part of this craton after its stabilisation at 3.09 Ga.  相似文献   

5.
High velocity (1 m/s) friction experiments on bituminous coal gouge display several earthquake-related phenomena, including devolatilization by frictional heating, gas pressurization, and slip weakening. Stage I is characterized by sample shortening and reduction in the coefficient of friction (μ) from  1 to 0.6. Stage II is characterized by high frequency ( 5 Hz) oscillations in stress and strain records and by gas emissions. Stage III is marked by rapid weakening (μ  0.1 to 0.35) and sample shortening, together with continued gas emissions. Stage IV produces stable stress records and continued weakness (μ  0.2), but without gas emission. Stage I shortening is due to compaction of the gouge and the weakening is attributed to mechanical or thermal effects. Stage II behavior is interpreted as due to coal gasification and fluctuations in fluid pressure, resulting in high frequency stick-slip type behavior. Dramatic reduction in shear stress in stage III is attributed to gas pressurization by pore collapse and corresponds to a frictional instability, analogous to nucleation of an earthquake. Microstructural observations indicate the deformation was brittle during stages I and II but ductile during stages III and IV. Time dependent finite element frictional heat models indicate the center of the samples became hot ( 900 °C) during stage II, whereas the edge of samples remained relatively cold (< 300 °C). Vitrinite reflectance of coal samples shows an increase in reflectance from  0.5 to  0.8% over the displacement interval 20–40 m (20–40 s), indicating that the reflectance responds to frictional heating on a short time scale. The energy expended per unit area in these low stress, large displacement experiments is similar to that of higher stress ( 50 MPa), short displacement ( 1 m) earthquakes ( 107 J/m2).  相似文献   

6.
At a marsh on the hanging wall of the Seattle fault, fossil brackish water diatom and plant seed assemblages show that the marsh lay near sea level between 7500 and 1000 cal yr B.P. This marsh is uniquely situated for recording environmental changes associated with past earthquakes on the Seattle fault. Since 7500 cal yr B.P., changes in fossil diatoms and seeds record several rapid environmental changes. In the earliest of these, brackish conditions changed to freshwater 6900 cal yr B.P., possibly because of coseismic uplift or beach berm accretion. If coseismic uplift produced the freshening 6900 cal yr B.P., that uplift probably did not exceed 2 m. During another event about 1700 cal yr B.P., brackish plant and diatom assemblages changed rapidly to a tidal flat assemblage because of either tectonic subsidence or berm erosion. The site then remained a tideflat until the most recent event, when an abrupt shift from tideflat diatoms to freshwater taxa resulted from 7 m of uplift during an earthquake on the Seattle fault 1000 cal yr B.P. Regardless of the earlier events, no Seattle fault earthquake similar to the one 1000 cal yr B.P. occurred at any other time in the past 7500 years.  相似文献   

7.
The late Quaternary paleoclimate of eastern Beringia has primarily been studied by drawing qualitative inferences from vegetation shifts. To quantitatively reconstruct summer temperatures, we analyzed lake sediments for fossil chironomids, and additionally we analyzed the sediments for fossil pollen and organic carbon content. A comparison with the δ18O record from Greenland indicates that the general climatic development of the region throughout the last glaciation–Holocene transition differed from that of the North Atlantic region. Between  17 and 15 ka, mean July air temperature was on average 5°C colder than modern, albeit a period of near-modern temperature at  16.5 ka. Total pollen accumulation rates ranged between  180 and 1200 grains cm− 2 yr− 1. At  15 ka, approximately coeval with the Bølling interstadial, temperatures again reached modern values. At  14 ka, nearly 1000 yr after warming began, Betula pollen percentages increased substantially and mark the transition to shrub-dominated pollen contributors. Chironomid-based inferences suggest no evidence of the Younger Dryas stade and only subtle evidence of an early Holocene thermal maximum, as temperatures from  15 ka to the late Holocene were relatively stable. The most recognizable climatic oscillation of the Holocene occurred from  4.5 to 2 ka.  相似文献   

8.
Numerous cirques of the Lofoten–Vesterålen archipelago in northern Norway have distinct moraine sequences that previously have been assigned to the Allerød-Younger Dryas ( 13,400 to 11,700 yr BP) interval, constraining the regional distribution of the equilibrium-line altitude (ELA) of cirque and valley glaciers. Here we present evidence from a once glacier-fed lake on southern Andøya that contests this view. Analyses of radiocarbon dated lacustrine sediments including rock magnetic parameters, grain size, organic matter, dry bulk density and visual interpretation suggest that no glacier was present in the low-lying cirque during the Younger Dryas-Allerød. The initiation of the glacial retreat commenced with the onset of the Bølling warming ( 14,700 yr BP) and was completed by the onset of Allerød Interstade ( 13,400 yr BP). The reconstructed glacier stages of the investigated cirque coincide with a cool and dry period from  17,500 to 14,700 yr BP and a somewhat larger Last Glacial Maximum (LGM) advance possibly occurring between  21,050 and 19,100 yr BP.  相似文献   

9.
M. Faccenda  G. Bressan  L. Burlini   《Tectonophysics》2007,445(3-4):210-226
The compressional and shear wave velocities have been measured at room temperature and pressure up to 450 MPa on 5 sedimentary rock samples, representative of the most common lithologies of the upper crust in the central Friuli area (northeastern Italy). At 400 MPa confining pressure the Triassic dolomitic rock shows the highest velocities (Vp  7 km/s, Vs  3.6 km/s), the Jurassic and Triassic limestones samples intermediate velocities (Vp  6.3 /s, Vs  3.5 km/s) and the Cenozoic and Paleozoic sandstones the lowest velocities (Vp  6.15 km/s, Vs  3.35 km/s). The Paleozoic sandstone sample is characterized by the strongest anisotropy (10%) and significant birefringence (0.2 km/s) is found only on the Cenozoic sandstone sample. We elaborated the synthetic profiles of seismic velocities, density, elastic parameters and reflection coefficient, related to 4 one-dimensional geological models extended up to 22 km depth. The synthetic profiles evidence high rheological contrasts between Triassic dolomitic rocks and the soft sandstones and the Jurassic limestones. The Vp profiles obtained from laboratory measurements match very well the in-situ Vp profile measured by sonic log for the limestones and dolomitic rocks, supporting our one-dimensional modelling of the calcareous-carbonatic stratigraphic series. The Vp and Vs values of the synthetic profiles are compared with the corresponding ones obtained from the 3-D tomographic inversion of local earthquakes. The laboratory Vp are generally higher than the tomographic ones with major discrepancies for the dolomitic lithology. The comparison with the depth location of seismicity reveals that the seismic energy is mainly released in correspondence of high-contrast rheological boundaries.  相似文献   

10.
In Pennsylvania, the Taconic Orogeny lasted from 461 to 443 Ma as Cambro-Ordovician slope deposits were deformed into mountains edging the Laurentian craton at the same time that materials from an adjacent deep-water basin were being transported 50 –70 km across a carbonate platform into foreland basins. This paper focuses on shelf-edge hinterland features, mostly the Martic Zone as a folded, stack of imbricate thrust sheets of slope materials that corresponds to Vermont's Taconic Mountains and Southern Quebec's zone of Taconic allochthons. Work of the last century is summarized, corrected, and combined with a new 450 Ma radiometric date and fluid inclusion data from the Pequea Mine within the Martic Zone. These and abundant new graptolite and conodont dates in the foreland paint a revised Pennsylvania picture differing from the northern Taconic areas. Differences are: (1) transport of very large allochthonous masses of deep-water material, the Dauphin Formation, far across the carbonate platform, and (2) deformation migrating progressively across that platform during a 15 –20 m.y. period, incorporating it and its foreland cover into alpine-scale, recumbent folds and thrusts. The scenario has many analogies to Italy's modern Apennine Mountains minus the Latian volcanics.  相似文献   

11.
We have studied seismic surface waves of 255 shallow regional earthquakes recently recorded at GEOFON station ISP (Isparta, Turkey) and have selected these 52 recordings with high signal-to-noise ratio for further analysis. An attempt was made by the simultaneous use of the Rayleigh and Love surface wave data to interpret the planar crust and uppermost mantle velocity structure beneath the Anatolian plate using a differential least-square inversion technique. The shear-wave velocities near the surface show a gradational change from approximately 2.2 to 3.6 km s− 1 in the depth range 0–10 km. The mid-crustal depth range indicating a weakly developed low velocity zone has shear-wave velocities around 3.55 km s− 1. The Moho discontinuity characterizing the crust–mantle velocity transition appears somewhat gradual between the depth range  25–45 km. The surface waves approaching from the northern Anatolia are estimated to travel a crustal thickness of  33 km whilst those from the southwestern Anatolia and part of east Mediterranean Sea indicate a thicker crust at  37 km. The eastern Anatolia events traveled even thicker crust at  41 km. A low sub-Moho velocity is estimated at  4.27 km s− 1, although consistent with other similar studies in the region. The current velocities are considerably slower than indicated by the Preliminary Reference Earth Model (PREM) in almost all depth ranges.  相似文献   

12.
The crystalline terrane of the Tongbai–Dabie region, central China, comprising the Earth's largest ultrahigh-pressure (UHP) exposure was formed during Triassic collision between the Sino–Korean and Yangtze cratons. New apatite fission-track (AFT) data presented here from the UHP terrane, extends over a significantly greater area than reported in previous studies, and includes the (eastern) Dabie, the Hong'an (northwestern Dabie) and Tongbai regions. The new data yield ages ranging from 44 ± 3 to 142 ± 36 Ma and mean track lengths between 10 and 14.4 μm. Thermal history models based on the AFT data taken together with published 40Ar/39Ar, K–Ar, apatite and zircon (U–Th)/He and U–Pb data, exhibit a three-stage cooling pattern that is similar across the study region, commencing with an Early Cretaceous rapid cooling event, followed by a period of relative thermal stability during which rocks remained at temperatures within the AFT partial annealing zone (60–110 °C) and ending with a possible renewed phase of accelerated cooling during Pliocene to Recent time. The first cooling phase followed large-scale transtensional deformation between 140 and 110 Ma and is related to Early Cretaceous eastward tectonic escape and Pacific back arc extension. Between this phase and the subsequent slow cooling phase, a transition period from 120 to 80 Ma (to 70 to 45 Ma along the Tan–Lu fault) was characterised by a relatively low cooling rate (3–5 °C/Ma). This transition is likely related to a tectonic response associated with the mid-Cretaceous subduction of the Izanagi–Pacific plate as well as lithospheric extension and thinning in eastern Asia. The present regional AFT age pattern is therefore basically controlled by the Early Cretaceous rapid cooling event, but finally shaped through active Cenozoic faulting. Following the transition phase the subsequent slow cooling phase pattern implies a net reduction in horizontal compressional stress corresponding to increased extension rates along the continental margin due to the decrease in plate convergence. Modelling of the AFT data suggests a possible Pliocene–Recent cooling episode, which may be supported by increased rates of sedimentation observed in adjacent basins. This cooling phase may be interpreted as a response to the far-field effects of the frontal India–Eurasia collision to the west. Approximate estimates suggest that the total amount of post 120 Ma denudation across the UHP orogen ranged from 2.4 to 13.2 km for different tectonic blocks and ranged from 0.8 to 9.7 km during the Cretaceous to between 1.7 and 3.8 km during the Cenozoic.  相似文献   

13.
Our 12.81 m long record from Lake Ximencuo provides insight into the Lateglacial and Holocene evolution of the lake and the Nianbaoyeze glacier in its catchment, and the regional climate history since 19 kyr. Lake Ximencuo was a permanent deep lake throughout its history. In contrast to numerous lakes on the Tibetan Plateau which experienced shallow lake levels or even desiccation during the Lateglacial, Lake Ximencuo was fed by large quantities of meltwater in the Lateglacial. The existence of glaciated upper catchment areas is apparently a prerequisite for lakes on the Tibetan Plateau which maintained relatively high water levels during the generally cold and dry periods following the global LGM (21 kyr). A minor re-advance of the Nianbaoyeze glacier was recorded coeval with the Greenland Stadial 2a (16.4 and 14.5 kyr), followed by rapid warming apparently synchronous with the Greenland Interstadial 1. Warmest conditions were recorded at Lake Ximencuo during the early Holocene which was punctured by a remarkable pulse of climate deterioration around 8.3 kyr. This spell represents probably the 8.2 kyr event of the North Atlantic region, suggesting that it had a significant impact on the Tibetan Plateau. Colder conditions of longer duration occurred from 4.7 to 3.7 kyr, apparently in phase with numerous records signalling colder and drier conditions on the Tibetan Plateau. Two minor spells of colder conditions and probably catchment erosion were recorded in the late Holocene between 2.0 and 1.4 kyr and between 0.5 and 0.1 kyr with the latter representing the Little Ice Age. It is unclear, whether human activities may have accelerated or even solely triggered the late Holocene erosion events.  相似文献   

14.
Numerical modelling, incorporating coupling between surface processes and induced flow in the lower continental crust, is used to address the Quaternary evolution of the Gulf of Corinth region in central Greece. The post-Early Pleistocene marine depocentre beneath this Gulf overlies the northern margin of an older (Early Pleistocene and earlier) lacustrine basin, the Proto Gulf of Corinth Basin or PGCB. In the late Early Pleistocene, relief in this region was minimal but, subsequently, dramatic relief has developed, involving the creation of  900 m of bathymetry within the Gulf and the uplift by many hundreds of metres of the part of the PGCB, south of the modern Gulf, which forms the Gulf's main sediment supply. It is assumed that, as a result of climate change around 0.9 Ma, erosion of this sediment source region and re-deposition of this material within the Gulf began, both processes occurring at spatial average rates of  0.2 mm a− 1. Modelling of the resulting isostatic response indicates that the local effective viscosity of the lower crust is  4 × 1019 Pa s, indicating a Moho temperature of  560 °C. It predicts that the  10 mm a− 1 of extension across this  70 km wide model region, at an extensional strain rate of  0.15 Ma− 1, is partitioned with  3 mm a− 1 across the sediment source,  2 mm a− 1 across the depocentre, and  5 mm a− 1 across the ‘hinge zone’ in between, the latter value being an estimate of the extension rate on normal faults forming the major topographic escarpment at the southern margin of the Gulf. This modelling confirms the view, suggested previously, that coupling between this depocentre and sediment source by lower-crustal flow can explain the dramatic development in local relief since the late Early Pleistocene. The effective viscosity of the lower crust in this region is not particularly low; the strong coupling interpreted between the sediment source and depocentre results instead from their close proximity. In detail, the effective viscosity of the lower crust is expected to decrease northward across this model region, due to the northward increase in exposure of the base of the continental lithosphere to the asthenosphere; in the south the two are separated by the subducting Hellenic slab. The isostatic consequences of such a lateral variation in viscosity provide a natural explanation for why, since  0.9 Ma, the modern Gulf has developed asymmetrically over the northern part of the PGCB, leaving the rest of the PGCB to act as its sediment source.  相似文献   

15.
The Yidun Arc is a Triassic volcanic arc located between the Songpan Garzê Fold Belt and the Qiangtang Block, southwest China. To constrain the age of a number of the major granitic plutons from the Yidun Arc, laser ablation ICP-MS U/Pb analysis of zircon was conducted. Hafnium isotope data was also acquired through laser-ablation multicollector ICPMS analysis of zircon, with the aim of gaining insight into the age and nature of the source region of the plutons. Three age groups have been identified from seven granite samples: Early–Middle Triassic ( 245 to 229 Ma), Late Triassic ( 219 to 216 Ma) and Cretaceous ( 105 to 95 Ma). Hafnium analysis shows the Triassic granites to have negative and variable εHf values and Mesoproterozoic ( 1.6 Ga) depleted-mantle model ages, which is interpreted to reflect derivation from an isotopically heterogeneous, largely crustal source. The Cretaceous granite shows higher and less variable εHf values and slightly younger model ages ( 1.3 Ga), and is interpreted to be derived from melting of a more homogeneous crustal source. A depleted-mantle model age of  1.5 Ga is calculated from the pooled Triassic and Cretaceous samples. The source region for these magmas may be tentatively correlated with Mesoproterozoic material of the Yangtze Craton, which has been suggested to underlie the Yidun Arc; however, further work is necessary to demonstrate this suggestion.  相似文献   

16.
It has been generally accepted that the South China Block was formed through amalgamation of the Yangtze and Cathaysia Blocks during the Proterozoic Sibaoan orogenesis, but the timing and kinematics of the Sibao orogeny are still not well constrained. We report here SHRIMP U–Pb zircon geochronological and geochemical data for the Taohong and Xiqiu tonalite–granodiorite stocks from northeastern Zhejiang, southeastern margin of the Yangtze Block. Our data demonstrate that these rocks, dated at 913 ± 15 Ma and 905 ± 14 Ma, are typical amphibole-rich calc-alkaline granitoids formed in an active continental margin. Combined with previously reported isotopic dates for the  1.0 Ga ophiolites and  0.97 Ga adakitic rocks from northeastern Jiangxi, the timing of the Sibao orogenesis is thus believed to be between  1.0 and  0.9 Ga in its eastern segment. It is noted that the Sibao orogeny in South China is in general contemporaneous with some other early Neoproterozoic (1.0–0.9 Ga) orogenic belts such as the Eastern Ghats Belt of India and the Rayner Province in East Antarctica, indicating that the assembly of Rodinia was not finally completed until  0.9 Ga.  相似文献   

17.
Mineralizing fluids at the San Martín skarn show an evolution characterized by prograde and retrograde associations. The prograde mineral associations consist of (1) a massive garnet zone, (2) a tremolite ± garnet zone, and (3) a late association of quartz, sphalerite, calcite and fluorite lining the vugs in the garnet zone. The fluids of the prograde associations exhibit decreasing temperatures of homogenization (Th) and variable salinities. The fluids of the massive garnet zone have salinities of 36 wt.% NaCl equiv. and Th of 645 to 570 °C, corresponding to pressures of 1055 bar. At the tremolite ± garnet zone, Th range from 438 to 354 °C. In the late association at the endoskarn, the following evolution can be drawn: (a) salinities of 50 to 42 wt.% NaCl equiv., and Th of 455 to 346 °C in quartz, (b) salinities of 46 wt.% NaCl equiv., and Th of 415 to 410 °C in sphalerite, (c) salinities of 50 to 37 wt.% NaCl equiv., and Th of 479 to 310 °C in calcite, (d) salinities of 33 to 28 wt.% NaCl equiv. and of 24 to 22 wt.% KCl in fluorite, and (e) two types of fluids with salinities of 2 and 39 wt.% NaCl equiv. and Th 344 and 300 °C, respectively, in later saccharoidal quartz segregations. The retrograde mineral associations comprise pervasive propylitic alteration to carbonization, and mantos with sulfides. Fluids in epidote have salinities of 7.6 wt.% NaCl equiv. and Th of 287 to 252 °C, and in calcite have salinities of 9.2 to 1 wt.% NaCl equiv. and Th of 188 to 112 °C. Fluids in the sulfide assemblages in the mantos have salinities of 8 to 3 wt.% NaCl equiv. and Th 300 °C, with corresponding pressures of 94 bar. Fluids in late epithermal veins close to the intrusive body have salinities of 10 to 5 wt.% NaCl equiv. and Th of 275 to 200 °C, and distal veins show salinities of 2 to 1 wt.% NaCl equiv. and Th of 160 °C.  相似文献   

18.
Coaly source rocks are sufficiently different from marine and lacustrine source rocks in their organic matter characteristics to warrant separate guidelines for their assessment using Rock-Eval pyrolysis. The rank threshold for oil generation is indicated by the increase in BI (S1/TOC) at Rank(Sr)9–10 (Tmax 420–430 °C, Ro 0.55–0.6%), and the threshold for oil expulsion is indicated by the peak in QI ([S1+S2]/TOC) at Rank(Sr)11–12.5 (Tmax 430–440 °C, Ro 0.65–0.85%). The pronounced rank-related increase in HI (S2/TOC) prior to oil expulsion renders the use of immature samples inappropriate for source rock characterisation. A more realistic indication of the petroleum generative potential and oil expulsion efficiency of coaly source rocks can be gained from samples near the onset of expulsion. Alternatively, effective HI′ values (i.e. HIs near the onset of expulsion) can be estimated by translating the measured HIs of immature samples along the maturation pathway defined by the New Zealand (or other defined) Coal Band. Coaly source rocks comprise a continuum of coaly lithologies, including coals, shaly coals and coaly mudstones. Determination of the total genetic potential of coaly source rock sequences is best made using lithology-based samples near the onset of expulsion.  相似文献   

19.
In order to better understand the long-term speciation and fractionation of Zn in soils, we investigated three soils naturally enriched in Zn (237–864 mg/kg Zn) from the weathering of Zn-rich limestones (40–207 mg/kg Zn) using extended X-ray absorption fine structure (EXAFS) spectroscopy and sequential extractions. The analysis of bulk EXAFS spectra by linear combination fitting (LCF) indicated that Zn in the oolitic limestones was mainly present as Zn-containing calcite (at site Dornach), Zn-containing goethite (Gurnigel) and Zn-containing goethite and sphalerite (Liestal). Correspondingly, extraction of the powdered rocks with 1 M NH4-acetate at pH 6.0 mobilized only minor fractions of Zn from the Gurnigel and Liestal limestones (<30%), but most Zn from the Dornach rock (81%). In the Dornach soil, part of the Zn released from the dissolving limestone was subsequently incorporated into pedogenic hydroxy-interlayered vermiculite (Zn-HIV, 30%) and Zn-containing kaolinite (30%) and adsorbed or complexed by soil organic and inorganic components (40%). The Gurnigel and Liestal soils contained substantial amounts of Zn-containing goethite (50%) stemming from the parent rock, smaller amounts (20%) of Zn-containing kaolinite (and possibly Zn-HIV), as well as adsorbed or complexed Zn-species (30%). In the soil from Liestal, sphalerite was only found in trace amounts, indicating its dissolution during soil formation. In sequential extractions, large percentages of Zn (55–85%) were extracted in recalcitrant extraction steps, confirming that Zn-HIV, Zn-containing kaolinite and Zn-containing goethite are highly resistant to weathering. These Zn-bearing phases thus represent long-term hosts for Zn in soils over thousands of years. The capability of these phases to immobilize Zn in heavily contaminated soils may however be limited by their uptake capacity (especially HIV and kaolinite) or their abundance in soil.  相似文献   

20.
This paper explores the environmental conditions that faced the people of ancient Jawa during the Holocene, as well as previous prehistoric periods of the mid-late Pleistocene. Calcite speleothems in a lava tube are dated using the U-Th method, to marine oxygen isotope stage 7 from  250 to 240 ka and from  230 to  220 ka; and the stage 5/4 transition between  80 and 70 ka. The available evidence indicates general aridity of the Black Desert during most of the mid-late Quaternary, punctuated by short wetter periods, when the Mediterranean cyclonic systems intensified and penetrated the north Arabian Desert. These Mediterranean systems had a longer and more intense effect on the desert fringe closer to the Mediterranean and only rarely penetrated the Black Desert of Jawa. The results do not exclude some increase of rainfall which did not change water availability dramatically during the warm Holocene. The ancient Jawa city appears to have depended on technological ability to build elaborate runoff-collection systems, which became the prime condition for success.  相似文献   

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